US2788053A - Thermal insulating structures and methods for the production thereof - Google Patents
Thermal insulating structures and methods for the production thereof Download PDFInfo
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- US2788053A US2788053A US429611A US42961154A US2788053A US 2788053 A US2788053 A US 2788053A US 429611 A US429611 A US 429611A US 42961154 A US42961154 A US 42961154A US 2788053 A US2788053 A US 2788053A
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- insulation
- wicks
- barrier
- vapour barrier
- layer
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/14—Form or construction
- F01D5/18—Hollow blades, i.e. blades with cooling or heating channels or cavities; Heating, heat-insulating or cooling means on blades
- F01D5/187—Convection cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B64—AIRCRAFT; AVIATION; COSMONAUTICS
- B64C—AEROPLANES; HELICOPTERS
- B64C1/00—Fuselages; Constructional features common to fuselages, wings, stabilising surfaces or the like
- B64C1/40—Sound or heat insulation, e.g. using insulation blankets
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/64—Insulation or other protection; Elements or use of specified material therefor for making damp-proof; Protection against corrosion
- E04B1/644—Damp-proof courses
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/10—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products
- E04C2/24—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products laminated and composed of materials covered by two or more of groups E04C2/12, E04C2/16, E04C2/20
- E04C2/243—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products laminated and composed of materials covered by two or more of groups E04C2/12, E04C2/16, E04C2/20 one at least of the material being insulating
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/02—Blade-carrying members, e.g. rotors
- F01D5/08—Heating, heat-insulating or cooling means
- F01D5/081—Cooling fluid being directed on the side of the rotor disc or at the roots of the blades
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T50/00—Aeronautics or air transport
- Y02T50/60—Efficient propulsion technologies, e.g. for aircraft
Definitions
- This invention relates to thermally insulated structures and methods of producing thermal insulation.
- the range of temperatures in cold weather includes both freezing point and the dew point of the air inside the living or other space, and the inner surface of the insulation is above the dew point.
- water and occasionally ice may form in the insulation under these conditions, the sprayed asbestos will remain essentially dry because there is re-evaporation of condensed water to the inside air; but when the relative humidity begins to increase, as frequently happens in inadequately ventilated ships, the dew point will rise and so, within the layer, will approach the inner face For the same reason the rate of re-evaporation from the surface of the insulation will be reduced, so that the gain in weight will be greater than the loss by evaporation.
- the layer of insulation may absorb as much as ten times its weight of water, some of which may freeze in aircraft and some ships, so causing grave danger, in addition to great discomfort to those occupying the warm space, if it is a cabin or other living space, or damage to the goods contained in the space.
- Another object is to provide a novel method of producing an insulating structure.
- the function of the wicks is to conduct condensed water from the insulation to the warm side of the vapour barrier to be evaporated into the warm space.
- the vapour barrier itself should retard the passage of water vapour from the warm space to the insulation as far as possible, and there should be no spaces around the wicks through which vapour can easily pass from one face of the vapour barrier to the other.
- the invention allows some water vapour to enter the insulation (while reducing the amount as far as possible over the time during which the rate of buildup is greater than the rate of re-evaporation), and provides means by which the water condensed from this vapour in the insulation can be re-evaporated into the warm space immediately this is permitted by changes in the physical conditions of the air outside or inside or both, that is either a rise in the external temperature or a decrease in the relative humidity in the warm space, or even an increased flow of air over the inner face of the vapour barrier such as can be set up by fans.
- the preferred wick material is asbestos, the fibres of which have a remarkable capacity for transmitting water by capillary action.
- Other wick materials which may be used are bundles of parallel or twisted filaments, or fibres, of glass, rock wool, flax, silk, cotton or cellulose yarns made from any such filaments or fibres, or any other thread-like product with the necessary capillary value to produce an effective wick.
- any material which can be used as a lamp or lighter wick can be used in the present invention, and so also can plaster-like products having fibres so embedded in them as to form continuous paths for moisture from one face to the opposite face.
- Figure 1 is a section through part of a ships deck and side with insulation in place
- Figure 2 shows part of Figure 1 on a larger scale
- Figure 3 is a perspective view of one vapour barrier with wicks passing through it;
- Figure 4 is an enlarged section on the line IVIV in Figure 3;
- Figure 5 is a view, similar to Figure 3, of another vapour barrier
- Figure 6 is an enlarged section on the line IV--IV in Figure Figure 7 shows one stage in the production of another vapour barrier containing wicks;
- Figures 8 and 9 are cross-sections at right-angles to one another through the final vapour barrier made by the method illustrated in Figure 7, being taken on the lines VIII-VIII and IX-IX respectively;
- Figure 10 illustrates another way of producing a vapour barrier containing wicks
- Figure 11 is a perspective view showing the production of wicks in yet another vapour barrier in position on fibrous insulation
- Figure 12 is a view similar to Figure ll, showing another way of producing the wicks
- Figure 13 shows another kind of wick
- Figure 14 shows the wicks of Figure 13 in a vapour barrier.
- Figure 1 shows part of an exposed deck A of a ship at the point where it joins the side B of the ship to form the ceiling and outer wall of a cabin C, the floor of which is formed by a lower deck D.
- the underside of the deck A and the inner face of the side B are coated with layers of fibrous insulation 1 and 2 respectively by spraying asbestos in the well-known way.
- the insulation 2 ends above the deck D so as to leave a small gap 3 and thus to prevent any water spilt on the deck D from coming into contact with, and being absorbed by, the insulation 2.
- the warm face of the layer of insulation 2, i. e. that directed to the cabin is covered by a vapour barrier 4, and that of the insulation 1 by a vapour barrier 5.
- Wicks 6 pass through each vapour barrier to lead condensed water from the insulation to the space within the cabin C.
- the barrier and wicks are illustrated diagrammatically in Figure 2, and various forms they may take are shown in the other figures.
- FIG 3 shows a vapour barrier of sheet material 7, which may consist of neoprene, chlorinated rubber, polythene, polyvinyl chloride or the like. Wicks are produced by stitching blue asbestos yarn 8 about inch in diameter through this in the manner shown. The points at which the wicks pass through the barrier 7 are 1 /2 inches apart in each line of stitches, and the stitch lines are themselves 1 /2 inches apart, thus making the number of wicks proper 6, i. e. lengths of yarn passing through the barrier from one face to the other, about 70 to the square foot.
- the wicks are preferably in contact with material which will spread the water over the warm face of the vapour barrier; such a material may be a layer of fibrous asbestos applied by spraying, a fabric, asbestos felt or paper, glass cloth, or even blotting paper. Any of these materials may be covered with a layer of water paint, which does not seriously interfere with the passage of water outwards.
- the warm face of the barrier may thus be covered by asbestos paper 9 as shown in Figures 3 and 4.
- the vapour barrier with the wicks in it must be stuck to the insulation 2.
- a polythene or similar sheet cannot easily be stuck to a layer of sprayed asbestos it is convenient to stick on the cold face of the barrier a layer of material which will adhere readily to the insulation and provide a key for an adhesive used to stick the vapour barrier in position.
- the layer used for these purposes may be of the same kind as that used on the warm face of the barrier, and Figures 3 and 4 show a sheet of asbestos paper 10 so used.
- the sheets of asbestos paper 9 and 10 may be stuck to the barrier sheet 7 by an adhesive or, if the barrier is thermoplastic, by subjecting the assembly to heat and pressure, e. g. by passing it between two heated rollers.
- the wicks are formed by asbestos yarn or the like 11 woven between strips of polyvinyl chloride or other thermoplastic sheet arranged edge to edge.
- a series of identical strips 12 is first put on a sheet of asbestos paper 35, being spaced apart from one another by the width of a strip.
- the wicks 11 are laid transversely across the strips at the desired spacing, and further strips 13 are laid on the wicks in the gaps between the strips 12.
- a sheet of asbestos paper 14 is laid on top, and the whole assembly is then subjected to heat and pressure adequate to force the abutting edges of the strips 12 and 13 into contact with one another, except of course where the wicks prevent contact, and to weld the edges together.
- thermoplastic sheet 7 is unwound from a roller 15 between sheets of asbestos paper 9 and 10 from rolls 16 and 17 respectively, and the three sheets are passed between two heated rollers 18 and 19.
- the roller 18 has a series of spikes 20. These spikes drive fibres of the paper into the sheet 7 to form wicks 21 while the three sheets are being united by passage between the rollers.
- the temperature to which the rollers are heated depends on the nature of the sheet 7.
- the asbestos paper shown in Figure 10 may be replaced by asbestos felt in thin sheet form.
- a thin covering of asbestos fibre may be formed on each side of the barrier.
- a chlorinated rubber sheet may be drawn from a roller through a pair of rollers which apply adhesive to both faces, asbestos fibre may be dusted onto both faces of the sheet and pressed into the adhesive by two further rollers, and then the coated sheet may pass between rollers such as 18 and 19 While they are unheated.
- the vapour barriers and wicks so far described must be preformed and then stuck to the insulation 2, which may first be provided with a hard, though porous, surface of a fibrous plaster.
- the sticking presents a problem, in that if a water-soluble adhesive is used it dissolves in the condensed water and is conveyed to the wicks and may choke them. If a water-insoluble adhesive is used, it forms a barrier against the passage of water and hinders or even prevents the desired movement of the condensed water to and through the wicks.
- the adhesive is water-insoluble, e. g. a resinous emulsion, but is applied only locally, through a stencil or otherwise, in amounts that will just cause the barrier assembly to adhere firmly to the insulation while large areas remain uncoated by it and ensure the desired movement of water.
- vapour barrier may be made from a plaster in which small pieces of asbestos are so embedded as to form continuous paths from one face of the plaster to the other. Such pieces or spicules of asbestos may be incorporated in a plastic asbestos-cement mass applied to the insulation in any convenient way, and this mass will then form the vapourbarrier. 'If a' vapourproofing compound is introduced into the plastic mass it will increase the resistance to the penetration of water vapour through the gaps between the fibre bundles, and yet have very little effect on the wick action, which depends on the existence of microscopic passages between the individual fibres. I
- bitumen or the like A better material applied in plastic form to act as a vapour barrier is bitumen or the like. With such a material the wicks are most easily formed by fibres from a fibrous material in contact with bitumen or the like.
- Figure 11 shows fibrous insulation 2 to which bitumen is applied by brushing or spraying and allowed to set to form a tough skin. Then another layer of bitumen is applied to form with the first layer the bituminous vapour barrier shown at 22. While this second layer is still sticky, asbestos 23 is sprayed on. Then a tool 24 is pushed into the asbestos 23 and pushes fibres before it to form wicks 25. Finally the exposed surface of the asbestos 23 is provided with a covering 26, which may be done by applying to it a reinforcing fabric such as cotton cloth, or trowelling on asbestos-cement composition, or merely painting with a water permeable coating. If the fibres that form the wicks are pushed through the bitumen before it dries, the covering 26 may be stuck to the bitumen without the use of heat to cause adhesion.
- a reinforcing fabric such as cotton cloth, or trowelling on asbestos-cement composition
- the tool 24 may have a blunt blade 27 about 3 inch thick and a collar 28 to limit the extent to which the blade is plunged into the asbestos.
- the wicks can be formed at high speed by using this tool manually.
- a layer of metal foil may be inserted between the two layers of bitumen, being applied on top of the first before it dries. This foil is easily penetrated by the tool 24, and renders the barrier even more resistant to the passage of vapour than it would be otherwise.
- Figure 12 shows the same layers as Figure 11, but in it wicks 29 are formed by pulling fibres from the main insulation 4 through a bituminous vapour barrier 22.
- a tool 30 resembling a crochet hook is used. Because of the difficulty of Working over a sticky layer, the outer layer of sprayed asbestos fibre 23 may be applied before fibres f the insulating layer are pulled through the barrier with the crochet hook 30.
- the vapour barrier is in effect embedded in the fibrous insulation instead of being on the surface of it.
- the barrier is thus protected against fire.
- the barrier must not lie so far inside the layer that the dew point would be on the warm side of it. If this were to happen, water condensing on the barrier would be transmitted to the cold side of it by the wicks. Therefore the insulation 2 must be thick enough to ensure that the dew point is on the cold side of the barrier.
- FIG 13 shows a preformed wick and Figure 14 shows how such wicks can be driven through a vapour barrier 7 and into the insulation 2 behind it.
- Each of these wicks consists of asbestos yarn 31 wrapped around the shank 32 of a nail having a head 33.
- a radial slot 34 is made in the head to receive one end of the yarn 31 and hold it in position.
- a large washer 34 of asbestos paper is provided under the head of each nail to spread the water laterally, these washers replacing the layer 9.
- the washers may be omitted and a layer such as 9 held in place by the nails.
- the wicks In all cases the wicks must be close enough together to ensure that all the water in the insulation 1 or 2 will flow to one or another wick.
- the insulation itself is preferably always in contact with the shell, though this is not necessary so far as the evaporative action of the wicks is concerned.
- This insulation need not consist of asbestos, but may be a mixture of rock wool and asbestos, or any other fibrous material such that water entering or formed in it by condensation will become distributed through it. This is important because for the best re- 3 sults the water should come into contact with all the wicks'and so should not be localised in'the insulation.
- a structure comprising an impermeable shell forming a wall between a warm space and the atmosphere, 2. vapour barrier, fibrous insulation of substantial capillarity separating the vapour barrier from the shell, and a plurality of wicks passing through the vapour barrier and in contact with said insulation to conduct condensed Water from the insulation to the warm side of the barrier to be evaporated into the warm space.
- a structure comprising an impermeable shell forming a wall between a warm 'space and the atmosphere, a vapour barrier, fibrous insulation of substantial capillarity separating the vapour barrier from the shell, a plurality of wicks passing through the vapour barrier and in contact with said insulation to conduct condensed water from the insulation to the warm side of the barrier, and liquid-spreading material in contact with the wicks on the warm face of the vapour barrier and adapted to spread water from the wicks over that face to be evaporated into the warm space.
- a structure comprising an impermeable shell forming a wall between a warm space and the atmosphere, a vapour barrier, fibrous insulation of substantial capillarity separating the vapour barrier from the shell, a plurality of wicks passing through the vapour barrier and in contact with said insulation to conduct condensed water from the insulation to the warm side of the barrier, and a layer of material interposed between the vapour barrier and the fibrous insulation, the said layer adhering to this insulation and the vapour barrier being adhesively keyed to the said layer.
- a structure comprising an impermeable shell forming a wall between a warm space and the atmosphere, fibrous insulation of substantial capillarity in contact with the shell, a vapour barrier of a plastic material adherent to the fibrous insulation, and a plurality of wicks passing through the vapour barrier and adapted to conduct condensed water from the insulation to the warm side of the barrier to be evaporated into the warm space.
- vapour barrier is bituminous.
- a structure comprising an impermeable shell forming a wall betwen a warm space and the atmosphere, a vapour barrier, fibrous insulation separating the vapour barrier from the shell, a fibrous layer on the warm face of the vapour barrier, and fibres extending from said fibrous layer through the vapour barrier and forming a plurality of wicks in contact with said insulation to conduct condensed water from the insulation to the warm side of the barrier to be evaporated into the warm space.
- the method which comprises applying an impermeable material to the face of fibrous insulation to form a vapour barrier and pulling fibres through the vapour barrier from the insulation to form wicks.
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Description
AP" 9, 1957 N. L DOLBEY ETAL 2,788,053 THERMAL msuuwmc STRUCTURES AND msmous FOR THE PRODUCTION THEREOF Filed lay 13. 1954 2 Sheets-Shoot 1 I VII/III!!! rllfllffll vlfflillflf ,lllllllflivllla A ttorn gs N. L. DOLBEY ETAL Apnl 1957 THERMAL msuwrmc s'mucwuass mm moms 2788o53 FOR THE PRODUCTION THEREOF I 2' Shaw-Shoot 2 Filed Kay 13. 1954 Horn v THERMAL INSULATING STRUCTURES AND METHODS FOR THE PRGDUCTION THEREOF Norman Louis Dolliey, Armley, Leeds, England, and Frank C. Hooper, Toronto, Ontario, Canada, assignors to J. W. Roberts Limited, Armley, Leeds, England, a British company Application May 13, 1954, Serial No. 429,611
Claims priority, application Great Britain May 15, 1953 Claims. (Cl. 154-28) This invention relates to thermally insulated structures and methods of producing thermal insulation.
In some structures considerable temperature differences are likely to arise between an internal space and the outer atmosphere, e. g. in ships during cold weather, in highflying aircraft and in some types of building during winter the interior may be at a much higher temperature than the atmosphere. In all such structures there is a metal or other impermeable shell forming a wall between the warm space and the atmosphere. This may be the side or deck of a ship, the skin of an airplane, or the roof of a building, such as corrugated iron or asphalt-coated concrete roof. It is common to line this shell with fibrous insulating material. In ships this is often done by spraying the undersides of exposed decks and the inside faces of exposed ships sides with asbestos so as to form a layer varying in thickness from V2" to l" or more. However, as the temperature of the outside air in cold weather is often below freezing point, and is almost always below the dew point of the air inside the warm space, some condensation will take place inside the porous layer of insulation, and if the outside temperature is low enough the condensed water in contact with and near to the outer shell will turn to ice. The amount of ice and condensed water collecting in the insulation depends partly on the thickness and density of the insulation and partly on the difference in the water vapour pressure at the opposite faces of the insulation. Under normal conditions there is a temperature gradient through the fibrous layer of insulation, the temperature rising from that of the cold plates to very nearly that of the inside air. Inside the layer of insulation, therefore, the range of temperatures in cold weather includes both freezing point and the dew point of the air inside the living or other space, and the inner surface of the insulation is above the dew point. Although water and occasionally ice may form in the insulation under these conditions, the sprayed asbestos will remain essentially dry because there is re-evaporation of condensed water to the inside air; but when the relative humidity begins to increase, as frequently happens in inadequately ventilated ships, the dew point will rise and so, within the layer, will approach the inner face For the same reason the rate of re-evaporation from the surface of the insulation will be reduced, so that the gain in weight will be greater than the loss by evaporation. In consequence, the amount of water or ice or both in the layer will increase, and this added weight is very disadvan tageous. If these conditions are maintained for an appreciable time, the layer of insulation may absorb as much as ten times its weight of water, some of which may freeze in aircraft and some ships, so causing grave danger, in addition to great discomfort to those occupying the warm space, if it is a cabin or other living space, or damage to the goods contained in the space.
Attempts to prevent build-up of ice or condensed water in the fibrous insulation by sealing its exposed face, i. e. forming a vapour barrier, are generally fruitless and only result in an initial delay in arriving at the dangerous States Pact state because it is practically impossible to provide a barrier that is effective under the conditions prevailing in ships, aircraft and the like, where the outer shell is of metal or other non-permeable material so that the moisture is trapped between the barrier and the outer shell because it cannot escape to the outside air. These conditions do not arise in normal housing and building construction where the outer shell is porous and the effectiveness of a vapour barrier merely depends on reducing the rate of inlet of moisture to a figure less than that at which it can escape through the outer porous shell, though they may arise in certain types of buildings where the roofs are of metal or the normal masonry has been rendered substantially impervious to water vapour, e. g. by rendering it so with a layer of roofing felt or asphalt,
it is an object of this invention to provide an insulated structure from which condensed water may be re-evaporated into a warm space so as to avoid the hazzards referred to above.
Another object is to provide a novel method of producing an insulating structure.
In my invention I pass wicks through a vapour barrier separated from an impermeable shell by fibrous insulation. The function of the wicks is to conduct condensed water from the insulation to the warm side of the vapour barrier to be evaporated into the warm space. The vapour barrier itself should retard the passage of water vapour from the warm space to the insulation as far as possible, and there should be no spaces around the wicks through which vapour can easily pass from one face of the vapour barrier to the other.
Whereas the effect of a vapour barrier as used hitherto has been to permit saturation of the insulation in a longer or shorter time, even though it has been designed to prevent the passage of water vapour, the invention allows some water vapour to enter the insulation (while reducing the amount as far as possible over the time during which the rate of buildup is greater than the rate of re-evaporation), and provides means by which the water condensed from this vapour in the insulation can be re-evaporated into the warm space immediately this is permitted by changes in the physical conditions of the air outside or inside or both, that is either a rise in the external temperature or a decrease in the relative humidity in the warm space, or even an increased flow of air over the inner face of the vapour barrier such as can be set up by fans.
The preferred wick material is asbestos, the fibres of which have a remarkable capacity for transmitting water by capillary action. Other wick materials which may be used are bundles of parallel or twisted filaments, or fibres, of glass, rock wool, flax, silk, cotton or cellulose yarns made from any such filaments or fibres, or any other thread-like product with the necessary capillary value to produce an effective wick. Broadly, any material which can be used as a lamp or lighter wick can be used in the present invention, and so also can plaster-like products having fibres so embedded in them as to form continuous paths for moisture from one face to the opposite face.
The invention will be more readily understood by reference to the accompanying drawings, in which:
Figure 1 is a section through part of a ships deck and side with insulation in place;
Figure 2 shows part of Figure 1 on a larger scale;
Figure 3 is a perspective view of one vapour barrier with wicks passing through it;
Figure 4 is an enlarged section on the line IVIV in Figure 3;
Figure 5 is a view, similar to Figure 3, of another vapour barrier;
Figure 6 is an enlarged section on the line IV--IV in Figure Figure 7 shows one stage in the production of another vapour barrier containing wicks;
Figures 8 and 9 are cross-sections at right-angles to one another through the final vapour barrier made by the method illustrated in Figure 7, being taken on the lines VIII-VIII and IX-IX respectively;
Figure 10 illustrates another way of producing a vapour barrier containing wicks;
Figure 11 is a perspective view showing the production of wicks in yet another vapour barrier in position on fibrous insulation;
Figure 12 is a view similar to Figure ll, showing another way of producing the wicks;
Figure 13 shows another kind of wick; and
Figure 14 shows the wicks of Figure 13 in a vapour barrier.
Figure 1 shows part of an exposed deck A of a ship at the point where it joins the side B of the ship to form the ceiling and outer wall of a cabin C, the floor of which is formed by a lower deck D. The underside of the deck A and the inner face of the side B are coated with layers of fibrous insulation 1 and 2 respectively by spraying asbestos in the well-known way. The insulation 2 ends above the deck D so as to leave a small gap 3 and thus to prevent any water spilt on the deck D from coming into contact with, and being absorbed by, the insulation 2. The warm face of the layer of insulation 2, i. e. that directed to the cabin, is covered by a vapour barrier 4, and that of the insulation 1 by a vapour barrier 5. Wicks 6 pass through each vapour barrier to lead condensed water from the insulation to the space within the cabin C. The barrier and wicks are illustrated diagrammatically in Figure 2, and various forms they may take are shown in the other figures.
Figure 3 shows a vapour barrier of sheet material 7, which may consist of neoprene, chlorinated rubber, polythene, polyvinyl chloride or the like. Wicks are produced by stitching blue asbestos yarn 8 about inch in diameter through this in the manner shown. The points at which the wicks pass through the barrier 7 are 1 /2 inches apart in each line of stitches, and the stitch lines are themselves 1 /2 inches apart, thus making the number of wicks proper 6, i. e. lengths of yarn passing through the barrier from one face to the other, about 70 to the square foot.
It is desirable to present as large an evaporating surface on the warm face of the vapour barrier as possible. Accordingly the wicks are preferably in contact with material which will spread the water over the warm face of the vapour barrier; such a material may be a layer of fibrous asbestos applied by spraying, a fabric, asbestos felt or paper, glass cloth, or even blotting paper. Any of these materials may be covered with a layer of water paint, which does not seriously interfere with the passage of water outwards.
Assuming that the vapour barrier shown in Figure 3 is applied to the insulation z on the side 3 of the ship, the warm face of the barrier may thus be covered by asbestos paper 9 as shown in Figures 3 and 4.
The vapour barrier with the wicks in it must be stuck to the insulation 2. As a polythene or similar sheet cannot easily be stuck to a layer of sprayed asbestos it is convenient to stick on the cold face of the barrier a layer of material which will adhere readily to the insulation and provide a key for an adhesive used to stick the vapour barrier in position. The layer used for these purposes may be of the same kind as that used on the warm face of the barrier, and Figures 3 and 4 show a sheet of asbestos paper 10 so used.
The sheets of asbestos paper 9 and 10 may be stuck to the barrier sheet 7 by an adhesive or, if the barrier is thermoplastic, by subjecting the assembly to heat and pressure, e. g. by passing it between two heated rollers.
It is, of course, desirable to ensure that water in the insulation 2 will pass to the wicks 6 as readily as possible, and the asbestos paper 10 interrupts the transmis sion somewhat. It is better to ensure that there are stitches of asbestos yarn in direct contact with the insulation 2, and accordingly the yarn may be stitched through a composite material consisting of a barrier 7 and sheets of asbestos paper 9 and 10 as shown in Figures 5 and 6.
in the method illustrated by Figures 7 to 9, the wicks are formed by asbestos yarn or the like 11 woven between strips of polyvinyl chloride or other thermoplastic sheet arranged edge to edge. In carrying out this method, a series of identical strips 12 is first put on a sheet of asbestos paper 35, being spaced apart from one another by the width of a strip. Then the wicks 11 are laid transversely across the strips at the desired spacing, and further strips 13 are laid on the wicks in the gaps between the strips 12. A sheet of asbestos paper 14 is laid on top, and the whole assembly is then subjected to heat and pressure adequate to force the abutting edges of the strips 12 and 13 into contact with one another, except of course where the wicks prevent contact, and to weld the edges together.
It is not necessary to make the wicks of yarn or other material separate from the remaining elements of the whole assembly. Instead they may be produced by pulling or pushing fibres through the vapour barrier from a fibrous layer on one or other side of the vapour barrier. One way of doing this is shown in Figure 10. Here a thermoplastic sheet 7 is unwound from a roller 15 between sheets of asbestos paper 9 and 10 from rolls 16 and 17 respectively, and the three sheets are passed between two heated rollers 18 and 19. The roller 18 has a series of spikes 20. These spikes drive fibres of the paper into the sheet 7 to form wicks 21 while the three sheets are being united by passage between the rollers. The temperature to which the rollers are heated depends on the nature of the sheet 7.
The asbestos paper shown in Figure 10 may be replaced by asbestos felt in thin sheet form. Again, instead of using sheet material, a thin covering of asbestos fibre may be formed on each side of the barrier. For instance, a chlorinated rubber sheet may be drawn from a roller through a pair of rollers which apply adhesive to both faces, asbestos fibre may be dusted onto both faces of the sheet and pressed into the adhesive by two further rollers, and then the coated sheet may pass between rollers such as 18 and 19 While they are unheated.
All the vapour barriers and wicks so far described must be preformed and then stuck to the insulation 2, which may first be provided with a hard, though porous, surface of a fibrous plaster. The sticking presents a problem, in that if a water-soluble adhesive is used it dissolves in the condensed water and is conveyed to the wicks and may choke them. If a water-insoluble adhesive is used, it forms a barrier against the passage of water and hinders or even prevents the desired movement of the condensed water to and through the wicks. Preferably the adhesive is water-insoluble, e. g. a resinous emulsion, but is applied only locally, through a stencil or otherwise, in amounts that will just cause the barrier assembly to adhere firmly to the insulation while large areas remain uncoated by it and ensure the desired movement of water.
All difiiculty with regard to an adhesive may be overcome by making the vapour barrier from a plastic ma terial which will adhere to the fibrous insulation without difficulty. Thus the vapour barrier may be made from a plaster in which small pieces of asbestos are so embedded as to form continuous paths from one face of the plaster to the other. Such pieces or spicules of asbestos may be incorporated in a plastic asbestos-cement mass applied to the insulation in any convenient way, and this mass will then form the vapourbarrier. 'If a' vapourproofing compound is introduced into the plastic mass it will increase the resistance to the penetration of water vapour through the gaps between the fibre bundles, and yet have very little effect on the wick action, which depends on the existence of microscopic passages between the individual fibres. I
A better material applied in plastic form to act as a vapour barrier is bitumen or the like. With such a material the wicks are most easily formed by fibres from a fibrous material in contact with bitumen or the like.
Figure 11 shows fibrous insulation 2 to which bitumen is applied by brushing or spraying and allowed to set to form a tough skin. Then another layer of bitumen is applied to form with the first layer the bituminous vapour barrier shown at 22. While this second layer is still sticky, asbestos 23 is sprayed on. Then a tool 24 is pushed into the asbestos 23 and pushes fibres before it to form wicks 25. Finally the exposed surface of the asbestos 23 is provided with a covering 26, which may be done by applying to it a reinforcing fabric such as cotton cloth, or trowelling on asbestos-cement composition, or merely painting with a water permeable coating. If the fibres that form the wicks are pushed through the bitumen before it dries, the covering 26 may be stuck to the bitumen without the use of heat to cause adhesion.
The tool 24 may have a blunt blade 27 about 3 inch thick and a collar 28 to limit the extent to which the blade is plunged into the asbestos. The wicks can be formed at high speed by using this tool manually.
A layer of metal foil may be inserted between the two layers of bitumen, being applied on top of the first before it dries. This foil is easily penetrated by the tool 24, and renders the barrier even more resistant to the passage of vapour than it would be otherwise.
Figure 12 shows the same layers as Figure 11, but in it wicks 29 are formed by pulling fibres from the main insulation 4 through a bituminous vapour barrier 22. A tool 30 resembling a crochet hook is used. Because of the difficulty of Working over a sticky layer, the outer layer of sprayed asbestos fibre 23 may be applied before fibres f the insulating layer are pulled through the barrier with the crochet hook 30.
In the products shown in Figures 11 and 12, the vapour barrier is in effect embedded in the fibrous insulation instead of being on the surface of it. The barrier is thus protected against fire. Of course, the barrier must not lie so far inside the layer that the dew point would be on the warm side of it. If this were to happen, water condensing on the barrier would be transmitted to the cold side of it by the wicks. Therefore the insulation 2 must be thick enough to ensure that the dew point is on the cold side of the barrier.
Figure 13 shows a preformed wick and Figure 14 shows how such wicks can be driven through a vapour barrier 7 and into the insulation 2 behind it. Each of these wicks consists of asbestos yarn 31 wrapped around the shank 32 of a nail having a head 33. A radial slot 34 is made in the head to receive one end of the yarn 31 and hold it in position. A large washer 34 of asbestos paper is provided under the head of each nail to spread the water laterally, these washers replacing the layer 9. Alternatively, the washers may be omitted and a layer such as 9 held in place by the nails.
In all cases the wicks must be close enough together to ensure that all the water in the insulation 1 or 2 will flow to one or another wick. The insulation itself is preferably always in contact with the shell, though this is not necessary so far as the evaporative action of the wicks is concerned. This insulation need not consist of asbestos, but may be a mixture of rock wool and asbestos, or any other fibrous material such that water entering or formed in it by condensation will become distributed through it. This is important because for the best re- 3 sults the water should come into contact with all the wicks'and so should not be localised in'the insulation.
We claim:
1. A structure comprising an impermeable shell forming a wall between a warm space and the atmosphere, 2. vapour barrier, fibrous insulation of substantial capillarity separating the vapour barrier from the shell, and a plurality of wicks passing through the vapour barrier and in contact with said insulation to conduct condensed Water from the insulation to the warm side of the barrier to be evaporated into the warm space.
2. A structure according to claim 1 in which the Wicks consist of asbestos.
3. A structure according to claim 1 in which the fibrous insulation is directly adherent to the shell.
4. A structure comprising an impermeable shell forming a wall between a warm 'space and the atmosphere, a vapour barrier, fibrous insulation of substantial capillarity separating the vapour barrier from the shell, a plurality of wicks passing through the vapour barrier and in contact with said insulation to conduct condensed water from the insulation to the warm side of the barrier, and liquid-spreading material in contact with the wicks on the warm face of the vapour barrier and adapted to spread water from the wicks over that face to be evaporated into the warm space.
5. A structure according to claim 4 in which the spreading material is asbestos paper.
6. A structure according to claim 4 in which the spreading material is fibrous insulation.
7. A structure comprising an impermeable shell forming a wall between a warm space and the atmosphere, a vapour barrier, fibrous insulation of substantial capillarity separating the vapour barrier from the shell, a plurality of wicks passing through the vapour barrier and in contact with said insulation to conduct condensed water from the insulation to the warm side of the barrier, and a layer of material interposed between the vapour barrier and the fibrous insulation, the said layer adhering to this insulation and the vapour barrier being adhesively keyed to the said layer.
8. A structure according to claim 7 in which a waterinsoluble adhesive is used to stick the vapour barrier to the insulation and is applied only locally.
9. A structure comprising an impermeable shell forming a wall between a warm space and the atmosphere, fibrous insulation of substantial capillarity in contact with the shell, a vapour barrier of a plastic material adherent to the fibrous insulation, and a plurality of wicks passing through the vapour barrier and adapted to conduct condensed water from the insulation to the warm side of the barrier to be evaporated into the warm space.
10. A structure according to claim 9 in which the vapour barrier is bituminous.
11. A structure according to claim 9 in which the wicks are constituted by fibres extending out of a fibrous layer in contact with the vapour barrier.
12. A structure comprising an impermeable shell forming a wall betwen a warm space and the atmosphere, a vapour barrier, fibrous insulation separating the vapour barrier from the shell, a fibrous layer on the warm face of the vapour barrier, and fibres extending from said fibrous layer through the vapour barrier and forming a plurality of wicks in contact with said insulation to conduct condensed water from the insulation to the warm side of the barrier to be evaporated into the warm space.
13. In the production of an insulating structure, the method which comprises applying an impermeable material to the face of fibrous insulation to form a vapour barrier and pulling fibres through the vapour barrier from the insulation to form wicks.
14. In the production of an insulating structure, the method which comprises applying an impermeable material to the face of fibrous insulation to form a vapour References Cited in the file of this patent UNITED STATES PATENTS Gillies Ian. 6, 'Spaiford Apr. 17, Weyerhaeuser et a1. Feb. 11, Collins Dec. 20, Winkler July 18, Van Saun May 26,
Claims (2)
14. IN THE PRODUCTION OF AN INSULATING STRUCTURE, THE METHOD WHICH COMPRISES APPLYING AN IMPERMEABLE MATERIAL TO THE FACE OF FIBROUS INSULATION TO FORM A VAPOUR BARRIER, COVERIG THE IMPERMEABLE MATERIAL WITH A FIBROUS LAYER, AND PUSHING FIBERS FROM THIS LAYER THROUGH THE IMPERMEABLE MATERIAL INTO CONTACT WITH THE FIBROUS INSULATION TO FORM WICKS.
15. A METHOD ACCORDING TO CLAIM 14 IN WHICH THE IMPERMEABLE MATERIAL IS BITUMINOUS AND IS APPLIED AS TWO LAYERS, THE FIRS LAYER IS ALLOWED TO FORM A SKIN BEFORE THE SECOND IS APPLIED, FIBRE IS SPRAYED ONTO THE SECOND LAYER WHILE IT IS STILL STICKY, AND THE WICKS ARE THEN FORMED BY PUSHING SOME OF THE SPRAYED FIBRE THROUGH BOTH LAYERS.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB318289X | 1952-10-31 | ||
GB325000X | 1953-05-15 | ||
GB231053X | 1953-10-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
US2788053A true US2788053A (en) | 1957-04-09 |
Family
ID=27258181
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US388303A Expired - Lifetime US2920865A (en) | 1952-10-31 | 1953-10-26 | Bladed stator or rotor constructions with means to supply a fluid internally of the blades |
US429611A Expired - Lifetime US2788053A (en) | 1952-10-31 | 1954-05-13 | Thermal insulating structures and methods for the production thereof |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US388303A Expired - Lifetime US2920865A (en) | 1952-10-31 | 1953-10-26 | Bladed stator or rotor constructions with means to supply a fluid internally of the blades |
Country Status (6)
Country | Link |
---|---|
US (2) | US2920865A (en) |
CH (2) | CH318289A (en) |
DE (1) | DE1035341B (en) |
FR (2) | FR1090193A (en) |
GB (1) | GB743680A (en) |
NL (1) | NL88170C (en) |
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US3152034A (en) * | 1960-02-29 | 1964-10-06 | Johns Manville | Reinforced thermal insulation having facing sheets secured to the reinforcement |
US3521628A (en) * | 1966-01-31 | 1970-07-28 | Michel F Piel | Material for the manufacture of fitted diving suits and suits made thereof |
US3658612A (en) * | 1969-10-24 | 1972-04-25 | Unicor Inc | Method of fabricating cellular foam core structure assembly |
US3933546A (en) * | 1973-07-25 | 1976-01-20 | Sumitomo Chemical Company, Limited | Method for draining water or moisture from substratum for waterproofing layer |
US4106144A (en) * | 1977-01-27 | 1978-08-15 | Chabot Bernard T | Sea rescue chamber and methods of constructing and utilizing same |
US4490952A (en) * | 1982-01-04 | 1985-01-01 | Winston Emanuel A | Apparatus for eliminating moisture |
US4625486A (en) * | 1985-01-22 | 1986-12-02 | Dickinson Thomas C | Laminated vapor barrier material and methods of use |
US4670318A (en) * | 1983-05-20 | 1987-06-02 | Toshiba Monofrax Company, Ltd. | Laminar block and method of and apparatus for producing the laminar block |
WO2007072027A3 (en) * | 2005-12-22 | 2008-03-06 | Hal Errikos Calamvokis | Aircraft fuselage heating |
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US2991973A (en) * | 1954-10-18 | 1961-07-11 | Parsons & Marine Eng Turbine | Cooling of bodies subject to a hot gas stream |
GB855058A (en) * | 1957-02-22 | 1960-11-30 | Rolls Royce | Improvements in or relating to bladed rotor or stator constructions for axial-flow fluid machines for example for compressors or turbines of gas-turbine engines |
US3266770A (en) * | 1961-12-22 | 1966-08-16 | Gen Electric | Turbomachine rotor assembly |
NL295165A (en) * | 1962-07-11 | |||
GB1053420A (en) * | 1964-08-11 | |||
US3627448A (en) * | 1969-12-31 | 1971-12-14 | Westinghouse Electric Corp | Locking arrangement for side-entry blades |
US3891348A (en) * | 1972-04-24 | 1975-06-24 | Gen Electric | Turbine blade with increased film cooling |
DE2617927A1 (en) * | 1976-04-23 | 1977-11-03 | Bbc Brown Boveri & Cie | FLOW MACHINE SHOVEL |
US4536129A (en) * | 1984-06-15 | 1985-08-20 | United Technologies Corporation | Turbine blade with disk rim shield |
US5238368A (en) * | 1991-01-16 | 1993-08-24 | Ortolano Ralph J | Converting grouped blading to equivalent integral covered blading |
US5350277A (en) * | 1992-11-20 | 1994-09-27 | General Electric Company | Closed-circuit steam-cooled bucket with integrally cooled shroud for gas turbines and methods of steam-cooling the buckets and shrouds |
US5536143A (en) * | 1995-03-31 | 1996-07-16 | General Electric Co. | Closed circuit steam cooled bucket |
GB2319308B (en) * | 1996-11-12 | 2001-02-28 | Rolls Royce Plc | Gas turbine engine turbine system |
US5915923A (en) * | 1997-05-22 | 1999-06-29 | Mitsubishi Heavy Industries, Ltd. | Gas turbine moving blade |
GB9723268D0 (en) * | 1997-11-05 | 1998-01-07 | Rolls Royce Plc | Turbine |
US6179554B1 (en) | 1999-10-29 | 2001-01-30 | Elvin A. Stafford | Low friction fluid bearing and turbine using same |
US6378287B2 (en) | 2000-03-17 | 2002-04-30 | Kenneth F. Griffiths | Multi-stage turbomachine and design method |
US6260349B1 (en) | 2000-03-17 | 2001-07-17 | Kenneth F. Griffiths | Multi-stage turbo-machines with specific blade dimension ratios |
DE10131073A1 (en) * | 2000-12-16 | 2002-06-20 | Alstom Switzerland Ltd | Cooling system for cover strip of gas turbine blade comprises cooling channels which open on one side, perforated baffle plate fitted over these being pressed against them by gas-permeable spring and cover plate being fitted above spring |
DE10217389A1 (en) * | 2002-04-18 | 2003-10-30 | Siemens Ag | turbine blade |
US7137782B2 (en) * | 2004-04-27 | 2006-11-21 | General Electric Company | Turbulator on the underside of a turbine blade tip turn and related method |
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US8016561B2 (en) * | 2006-07-11 | 2011-09-13 | General Electric Company | Gas turbine engine fan assembly and method for assembling to same |
US7568887B1 (en) | 2006-11-16 | 2009-08-04 | Florida Turbine Technologies, Inc. | Turbine blade with near wall spiral flow serpentine cooling circuit |
US7641445B1 (en) | 2006-12-01 | 2010-01-05 | Florida Turbine Technologies, Inc. | Large tapered rotor blade with near wall cooling |
US7914257B1 (en) | 2007-01-17 | 2011-03-29 | Florida Turbine Technologies, Inc. | Turbine rotor blade with spiral and serpentine flow cooling circuit |
US8047790B1 (en) * | 2007-01-17 | 2011-11-01 | Florida Turbine Technologies, Inc. | Near wall compartment cooled turbine blade |
US7740445B1 (en) | 2007-06-21 | 2010-06-22 | Florida Turbine Technologies, Inc. | Turbine blade with near wall cooling |
US9022727B2 (en) * | 2010-11-15 | 2015-05-05 | Mtu Aero Engines Gmbh | Rotor for a turbo machine |
US9249669B2 (en) * | 2012-04-05 | 2016-02-02 | General Electric Company | CMC blade with pressurized internal cavity for erosion control |
JP6245740B2 (en) * | 2013-11-20 | 2017-12-13 | 三菱日立パワーシステムズ株式会社 | Gas turbine blade |
US9777575B2 (en) * | 2014-01-20 | 2017-10-03 | Honeywell International Inc. | Turbine rotor assemblies with improved slot cavities |
US10323524B2 (en) * | 2015-05-08 | 2019-06-18 | United Technologies Corporation | Axial skin core cooling passage for a turbine engine component |
US10502066B2 (en) | 2015-05-08 | 2019-12-10 | United Technologies Corporation | Turbine engine component including an axially aligned skin core passage interrupted by a pedestal |
US20170234543A1 (en) * | 2015-05-25 | 2017-08-17 | Ceragy Engines Inc. | High G-field Combustion |
US10753210B2 (en) * | 2018-05-02 | 2020-08-25 | Raytheon Technologies Corporation | Airfoil having improved cooling scheme |
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-
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- 1953-05-15 GB GB13707/53A patent/GB743680A/en not_active Expired
- 1953-10-26 US US388303A patent/US2920865A/en not_active Expired - Lifetime
- 1953-10-29 FR FR1090193D patent/FR1090193A/en not_active Expired
- 1953-10-31 CH CH318289D patent/CH318289A/en unknown
-
1954
- 1954-05-05 DE DER14145A patent/DE1035341B/en active Pending
- 1954-05-06 CH CH325000D patent/CH325000A/en unknown
- 1954-05-12 FR FR1105247D patent/FR1105247A/en not_active Expired
- 1954-05-13 US US429611A patent/US2788053A/en not_active Expired - Lifetime
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US1942546A (en) * | 1931-01-07 | 1934-01-09 | Union Asbestos & Rubber Co | Insulating material |
US1955443A (en) * | 1931-06-17 | 1934-04-17 | Wood Conversion Co | Insulating structure and liner |
US2030668A (en) * | 1932-08-26 | 1936-02-11 | Wood Conversion Co | Means for insulating walls |
US2140689A (en) * | 1936-09-18 | 1938-12-20 | Ingleside Company | Insulated wall |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3152034A (en) * | 1960-02-29 | 1964-10-06 | Johns Manville | Reinforced thermal insulation having facing sheets secured to the reinforcement |
US3521628A (en) * | 1966-01-31 | 1970-07-28 | Michel F Piel | Material for the manufacture of fitted diving suits and suits made thereof |
US3658612A (en) * | 1969-10-24 | 1972-04-25 | Unicor Inc | Method of fabricating cellular foam core structure assembly |
US3933546A (en) * | 1973-07-25 | 1976-01-20 | Sumitomo Chemical Company, Limited | Method for draining water or moisture from substratum for waterproofing layer |
US4106144A (en) * | 1977-01-27 | 1978-08-15 | Chabot Bernard T | Sea rescue chamber and methods of constructing and utilizing same |
US4490952A (en) * | 1982-01-04 | 1985-01-01 | Winston Emanuel A | Apparatus for eliminating moisture |
US4670318A (en) * | 1983-05-20 | 1987-06-02 | Toshiba Monofrax Company, Ltd. | Laminar block and method of and apparatus for producing the laminar block |
US4625486A (en) * | 1985-01-22 | 1986-12-02 | Dickinson Thomas C | Laminated vapor barrier material and methods of use |
WO2007072027A3 (en) * | 2005-12-22 | 2008-03-06 | Hal Errikos Calamvokis | Aircraft fuselage heating |
US20080302910A1 (en) * | 2005-12-22 | 2008-12-11 | Hal Errikos Calamvokis | Aircraft Fuselage Heating |
Also Published As
Publication number | Publication date |
---|---|
FR1105247A (en) | 1955-11-29 |
CH325000A (en) | 1957-10-31 |
US2920865A (en) | 1960-01-12 |
NL88170C (en) | 1900-01-01 |
GB743680A (en) | 1956-01-18 |
FR1090193A (en) | 1955-03-28 |
CH318289A (en) | 1956-12-31 |
DE1035341B (en) | 1958-07-31 |
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