US2771033A - Ventless delay electric initiators - Google Patents
Ventless delay electric initiators Download PDFInfo
- Publication number
- US2771033A US2771033A US305906A US30590652A US2771033A US 2771033 A US2771033 A US 2771033A US 305906 A US305906 A US 305906A US 30590652 A US30590652 A US 30590652A US 2771033 A US2771033 A US 2771033A
- Authority
- US
- United States
- Prior art keywords
- delay
- ventless
- silicon
- weight
- red lead
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003999 initiator Substances 0.000 title description 4
- 239000000203 mixture Substances 0.000 claims description 33
- 229910052710 silicon Inorganic materials 0.000 claims description 14
- 239000010703 silicon Substances 0.000 claims description 14
- 239000000020 Nitrocellulose Substances 0.000 claims description 11
- 229920001220 nitrocellulos Polymers 0.000 claims description 11
- 230000000977 initiatory effect Effects 0.000 claims description 6
- 239000004753 textile Substances 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 11
- 239000004411 aluminium Substances 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 150000001540 azides Chemical class 0.000 description 3
- -1 for example Substances 0.000 description 3
- AGUIVNYEYSCPNI-UHFFFAOYSA-N N-methyl-N-picrylnitramine Chemical group [O-][N+](=O)N(C)C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O AGUIVNYEYSCPNI-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- WETZJIOEDGMBMA-UHFFFAOYSA-L lead styphnate Chemical compound [Pb+2].[O-]C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C([O-])=C1[N+]([O-])=O WETZJIOEDGMBMA-UHFFFAOYSA-L 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000012815 thermoplastic material Substances 0.000 description 2
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 1
- 229940072049 amyl acetate Drugs 0.000 description 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B3/00—Blasting cartridges, i.e. case and explosive
- F42B3/10—Initiators therefor
- F42B3/16—Pyrotechnic delay initiators
Definitions
- the object of the present invention is to provide series of ventless short delay electric detonators having delay intervals between successive delay numbers for example of the order 25 or 50 milliseconds which, when the ventless container consists at least essentially of copper, have the advantage that single detonators of any such practical series when fired freely suspended in an inflammable gas mixture, for example, 9% methane/ air mixture, show no tendency to cause ignition of the gas mixture, and which when the ventless container is of aluminium or copper or copper alloys are cheaper to produce than has heretofore been possible.
- the ventless short delay electric detonator comprising an electrically actuated igniting charge, an initiating charge, and an interposed short delay element enclosed in a ventless container
- the said short delay element comprises a cut-ofi length of fuse comprising a flexible envelope surrounding a core comprising a preferably graphite-glazed, nitrocellulose bonded granular rmxture of silicon and red lead.
- ventless container consists essentially of copper.
- the bonded granular mixture of the core of the delay fuse element may contain red lead in an amount from 65 to 95 percent by weight, silicon in amount from to 35 percent by Weight and nitrocellulose in amount up to 5 percent by weight of the red lead plus silicon. It is preferred, however, generally for the compositions to consist of 70 parts red lead, 30 parts silicon and 0.25 part nitrocellulose by weight.
- mixtures are preferably made by first dry nnxing the red lead and silicon, then mixing the resulting mixture with a solution of nitrocellulose in a suitable solvent, for example, amyl acetate, in sufiicient amount to give a dry crumbly mass which is then sieved, for example, through a 25 B. S. S. mesh sieve and dried to give the bonded granular mixture.
- a suitable solvent for example, amyl acetate
- the bonded granular mixture is preferably glazed by tumbling with graphite in a drum or other suitable container, for example, for a time of the order of eight hours to give a final composition containing less than 1 percent of graphite.
- the step of glazing enables the granular compositions to be incorporated into fuse more easily than the same compositions unglazed.
- the flexible envelope may be formed of glass or textile yarns and may be provided with an outer coating which may consist of an organic thermoplastic material such as, for example, polyethylene, polyvinyl chloride or polystyrene.
- the textile covering may be spun around a core of the glazed material and compressed against it by passage through a die and the fuse thereafter finished in the manner known in the manufacture of safety fuse.
- Delay elements of differing delay periods can be obtained either by using different lengths containing the same composition or by varying the composition.
- the delay element be secured in position by pressing an inverted perforated metal cup over the end thereof remote from the initiating composi- I 2,711,033 Patented Nov. 20, 1956 'ice tion, instead of relying on a friction fit between the outer envelope and the wall of the tubular container.
- the use of such a cup also prevents the envelope, if ignitible, from being ignited by the igniting charge.
- the soft and somewhat compressible nature of the envelope renders the attainment of the necessary tight fit easy without the application of loading pressures so high as to damage the structure of the delay element. An expansion space should be left between the end of the delay element and the igniting charge.
- a small supplementary charge of, preferably gasless, igniting composition may be interposed between the end of the delay element and the initiating charge. It is also sometimes desirable to press a small charge of a gasless igniting composition directly on top of the delay element in order to ensure its ignition from the electrically actuated igniting charge, which will usually be spaced from it.
- the electrically actuated igniting charge may take the form of an electric fusehead.
- 1 is an aluminium detonator tube
- 2 is a detonating explosive charge of tetryl compressed into the end of the tube
- 3 is a more sensitive detonating charge compressed on top of charge 2 and consisting essentially of a mixture of aluminium, lead azide and lead 'styphnate and constituting the initiating charge
- 4 is the flexible envelope
- 5 is a covering of polyethylene
- 6 is a core of a glazed bonded granular mixture.
- 7 and 8 are layers of gasless igniting composition consisting of silicon and red lead in the weight ratio 30 to 70
- 9 is an inverted perforated metal cup pressed over the composition 8 and over the top of the delay element so as to secure the delay element longitudinally in the tube
- 10 is an electric fusehead
- 11 is an axially perforated sealing plug of rubber-like material crimped between the aluminium tube 1 and the insulated electric leading wires 12 and 12' as shown at 13 whereby there is attained a seal capable of withstanding an internal pressure greater than the maximum pressure that can be produced as a result of the combustion of the contents of the detonator tube with the exception of the detonating explosive charges 2 and 3.
- the space 14 between the end of the plug 11 and the inverted cup 9 and hence the length of the tube 1 is accordingly made sufficient to ensure that the maximum pressure that can even temporarily be developed in the initiator by the successive consumption of the compositions of the electric fusehead 10, the igniting charge 8, the delay composition 6, and the igniting charge 7 will not unseal the tube.
- the invention is also illustrated by the following examples in Table 1 in which are recorded lengths of delay elements, mean delay times, and the number of ignitions given when single detonators are fired freely suspended in a 9 percent methane/ air mixture.
- the delay composition consists of 70 parts red lead, 30 parts silicon and 0.25 nitrocellulose.
- the detonators are commercial lead azide/lead styphnate/aluminium/tetryl delay detonators in copper tubes without any supplementary igniting charges top and bottom.
- the invention is further illustrated by the following examples in Tables 2 and 3 in which are recorded delay periods of delay fuse elements ofthe lengths shown made from fuse whose core consists of a nitrocellulose bonded granular mixture having the composition given when used in commercial lead azide/lead styphnate/aluminium delay detonators without any supplementary igniting charges top and bottom.
- a ventless short delay electric detonator comprising an electrically actuated igniting charge, an initiating charge and an interposed short delay element enclosed in a ventless container essentially of copper wherein the said short delay element comprises a cut-ofi length of fuse comprising a flexible textile envelope around a core comprising a dry crumbly graphite-glazednitrocellulose bonded granular mixture of silicon and red lead, said red lead being in amount of from about 65% to 95% by weight, the silicon in amount of from about 5% to 35% by weight, and the nitrocellulose in amount up to about 5% by weight of the red lead andsilicon.
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Air Bags (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2771033X | 1951-11-22 | ||
GB2741951A GB711815A (en) | 1952-07-16 | 1952-07-16 | Improvements in or relating to ventless delay electric initiators |
Publications (1)
Publication Number | Publication Date |
---|---|
US2771033A true US2771033A (en) | 1956-11-20 |
Family
ID=32328129
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US305906A Expired - Lifetime US2771033A (en) | 1951-11-22 | 1952-08-22 | Ventless delay electric initiators |
Country Status (4)
Country | Link |
---|---|
US (1) | US2771033A (en, 2012) |
BE (1) | BE514360A (en, 2012) |
CH (1) | CH310832A (en, 2012) |
FR (1) | FR1062887A (en, 2012) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3041972A (en) * | 1958-12-15 | 1962-07-03 | Atlas Chem Ind | Arc resistant electric initiator |
US3102474A (en) * | 1961-04-14 | 1963-09-03 | Du Pont | Sonic pulse generating device |
US3112699A (en) * | 1961-04-14 | 1963-12-03 | Du Pont | Sonic pulse generator |
US4369708A (en) * | 1979-09-21 | 1983-01-25 | E. I. Du Pont De Nemours And Company | Delay blasting cap |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1825224A (en) * | 1930-02-28 | 1931-09-29 | Ensignbickford Co | Safety fuse |
US1999820A (en) * | 1931-06-24 | 1935-04-30 | Hercules Powder Co Ltd | Delay cap |
US2079777A (en) * | 1934-04-07 | 1937-05-11 | Ici Ltd | Safety igniter for blasting explosive devices |
US2410801A (en) * | 1945-03-13 | 1946-11-12 | Ludwig F Audrieth | Igniting composition |
US2416639A (en) * | 1944-07-08 | 1947-02-25 | Ensign Bickford Co | Slow-burning powder composition |
US2478501A (en) * | 1945-08-01 | 1949-08-09 | Ici Ltd | Ignition compositions |
US2513391A (en) * | 1943-10-06 | 1950-07-04 | Ici Ltd | Waterproof fuse |
US2586959A (en) * | 1949-09-16 | 1952-02-26 | Canadian Ind | Delay electric blasting cap |
US2619035A (en) * | 1947-12-31 | 1952-11-25 | Ici Ltd | Production of ventless delay initiators for explosive or other charges capable of exothermic reaction |
-
0
- BE BE514360D patent/BE514360A/xx unknown
-
1952
- 1952-08-22 US US305906A patent/US2771033A/en not_active Expired - Lifetime
- 1952-09-11 FR FR1062887D patent/FR1062887A/fr not_active Expired
- 1952-11-12 CH CH310832D patent/CH310832A/de unknown
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1825224A (en) * | 1930-02-28 | 1931-09-29 | Ensignbickford Co | Safety fuse |
US1999820A (en) * | 1931-06-24 | 1935-04-30 | Hercules Powder Co Ltd | Delay cap |
US2079777A (en) * | 1934-04-07 | 1937-05-11 | Ici Ltd | Safety igniter for blasting explosive devices |
US2513391A (en) * | 1943-10-06 | 1950-07-04 | Ici Ltd | Waterproof fuse |
US2416639A (en) * | 1944-07-08 | 1947-02-25 | Ensign Bickford Co | Slow-burning powder composition |
US2410801A (en) * | 1945-03-13 | 1946-11-12 | Ludwig F Audrieth | Igniting composition |
US2478501A (en) * | 1945-08-01 | 1949-08-09 | Ici Ltd | Ignition compositions |
US2619035A (en) * | 1947-12-31 | 1952-11-25 | Ici Ltd | Production of ventless delay initiators for explosive or other charges capable of exothermic reaction |
US2586959A (en) * | 1949-09-16 | 1952-02-26 | Canadian Ind | Delay electric blasting cap |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3041972A (en) * | 1958-12-15 | 1962-07-03 | Atlas Chem Ind | Arc resistant electric initiator |
US3102474A (en) * | 1961-04-14 | 1963-09-03 | Du Pont | Sonic pulse generating device |
US3112699A (en) * | 1961-04-14 | 1963-12-03 | Du Pont | Sonic pulse generator |
US4369708A (en) * | 1979-09-21 | 1983-01-25 | E. I. Du Pont De Nemours And Company | Delay blasting cap |
Also Published As
Publication number | Publication date |
---|---|
BE514360A (en, 2012) | |
FR1062887A (fr) | 1954-04-28 |
CH310832A (de) | 1955-11-15 |
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