Classifications

• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
  • C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
  • C10G31/08—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by treating with water
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
  • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M175/00—Working-up used lubricants to recover useful products ; Cleaning
  • C10M175/0016—Working-up used lubricants to recover useful products ; Cleaning with the use of chemical agents

Definitions

• Lubricating oils generally contain undesirable constituents which render the oils darker and more opaque to light. This is considered a disadvantage from the sales point of view and, up to now, many oils have been treated to render them more translucent and hence of an improved appearance.
• the main method has been to pass the oil through a filter bed containing absorbent material which removes the bulk of these undesirable constituents. This method has the disadvantage of involving considerable extra plant and some loss of oil in the filter bed.
• the oxidation has been made practicable by the discovery that, in the presence of an oxidation inhibitor, oxidising agents react preferentially with the undesirable constituents and have no appreciable reaction with the oil itself.
• the method comprises positively treating a lubricating oil with an oxidising agent in the presence of an oxidation inhibitor.
• oxidation inhibitor we mean any compound which will inhibit or reduce the rate of the oxidation of lubricating oils, generally or of any given lubricating oil whose translucency is required to be improved by the present invention. Many such compounds are at present in commercial use and the term is well understood in the art.
• the inhibitors which are preferred for use with the present invention are positive metals; salts of highly positive metals with weak acids; and oxides, peroxides and hydroxides of highly positive metals. These prefered inhibitors are hereinafter referred to collectively by the term highly positive metal inhibitors.
• highly positive metals is meant magnesium and those metals of more positive potential than magnesium in the electromotive series.
• weak acids is meant those acids having a dissociation constant of 1X10. (at 20 C.) or less.
• the salts of highly positive metals with inorganic weak acids have ice been found particularly useful'in their inhibiting action, e. g. the borates and phosphates, though the acetates and benzoates have also shown good results.
• Sodium metal is also particularly useful.
• the preferred oxidising agent for use with the present invention is air or oxygen since these would be relatively economicaljbut hydrogen peroxide is equally efficacious in oxidising action.
• the proportions of treating agents will depend to a large extent on the type of oil treated.
• the proportion of inhibitor used is preferably not less than /2 by weight of the oil treated and that good results are obtained using a proportion of 2%.
• the amount of oxidising agent cannot be definitely stated in the case of using air or oxygen since these gases will normally be bubbled through the oil until the required translucency is obtained.
• hydrogen peroxide 5% of this agent by Weight of the oil treated has been found to give useful results.
• the treatment of the lubricating oil with an oxidising agent is essentially of a positive nature and the present invention thus excludes the effecting of this treatment by such slow and incidental oxidation which occurs when lubricating oil is circulated in an engine in the course of its normal use.
• the oxidation is preferably elfected at 200 C. for at least five minutes, though the invention is useful at temperatures outside this range.
• the resultant bleached oil When the oxidation is performed in the presence of one of the highly positive metal inhibitors, the resultant bleached oil is found to be somewhat cloudy due to the presence of a colloidal material whose nature is uncertain but which appears to be of a soap-like nature. Moreover, the resultant bleached oil showed a reduced resistance to further oxidation when not protected by an oxidation inhibitor.
• this resultant bleached oil may begiven improved transluceney, even to the point of complete transparency in some cases, and improved oxidation resistance by coagulating and removing the said colloidal material
• the coagulation is effected by adding to the bleached oil a hydrocarboninsoluble polar liquid and the coagulated material is removed by centrifuging or, less preferably, by filtration or settling.
• the coagulation could be effected electrically.
• polar liquids which may be used for coagulation in the manner described are water, methyl or ethyl alcohol, and glycerol. Glycerol promotes more rapid settling but water will generally be preferred for economy.
• the amount of coagulant does not appear to be critical provided sufficient is used to effect the coagulation desired.
• the amount of coagulant will generally be between 1% and 12% by weight of the oil treated. Up to 25% has been used successfully but it is uneconomical to use more coagulant than actually necessary to efiect the desired coagulation.
• the minimum necessary to achieve complete coagulation will depend onthe amount of colloidal material present which in turn will depend on the amount of impurities originally present in the oil and on the extent of the oxidation treatment given to the oil. Thus a greater amount of coagulant is necessary when treating an oil which has already received sub stantial use in an engine.
• the transparency achieved as described above may even be of the degree of water whiteness and acceptable to the public as a medicinal oil; To achieve maximum Water whiteness, it may be useful to combine the treatment of the present invention with one of the prior art decolourising methods, e. g. a clay treatment; The latter would preferably follow the treatment of the present invention. Whereas a clay treatment is wasteful of oil and relatively uneconomical for merely improving the translucency of lubricating oils, as described above, such waste can be tolerated for the more expensive and refined product of medicinal oil.
• Example 1 The following experimental results were obtained by treating in accordance with the invention an oil of the type sold under the registered trademark Marvelube 30 but which has not previously been treated to render it translucent.
• the translucency obtained in this oil is expressed as a percentage of the translucency f the oil sold under the registered trademark Marrvelube 10 as already treated with clay according to prior art methods to render it translucent and ready for salt to the public.
• a red filter was used.
• Example 2 A number of samples of unclayed Marvelube 30 (registered trademark) were bleached by bubbling air through them at different temperatures and for different times in the presence of a highly positive metal inhibitor. The samples of bleached oil, except for two samples, were then given a further treatment by adding different amounts of water to coagulate the colloidal material therein and thereafter centrifuging to remove the coagulated material.
• the following table indicates the light transmission values of the final samples calculated as percentages of the light transmission of the white oil sold under the registered trademark Stanolax through both red and green filters.
• the table also indicates the same values obtained from Marvelube 20 (registered trademark) as already treated with clay according to prior art methods to render it translucent and ready for sale to the public.
• the table indicates the temperature, time of oxidation, amount and type of inhibitor, and amount of water coagulant used in thetreatment of each sample.
• Example 3 The oils sold under the names Marvelube 20 (registered trademark) and Canadian Tire Corporation 10, both oils already treated with clay according to prior art methods to render them translucent and ready for sale to the public, were separately used in an automobile engine with no filter for 1500 miles, Samples of the dirty oils were then treated by adding 5% ofsodium and bubbling air through the oil at 160 C. for different durations of time. The resultant bleached samples were then further treated by adding 10% of water to coagulate the colloidal material therein and centrifuging to remove the coagulated material.
• Marvelube 20 registered trademark
• Canadian Tire Corporation 10 both oils already treated with clay according to prior art methods to render them translucent and ready for sale to the public
• a sample of unclayed Marvelube 30 (registered trademark) was treated to render it of such water whiteness as to be saleable as medicinal oil. Air was bubbled through the sample for 12 hours at C., 5% of vsodium having been added to the sample.
• the colorimeterused in the'above examples for the type commonly known as atransmission tests was the Lumit'ron Model 400.
• the present invention serves to refine the oils treated as well as improve their translucency. After treatment according to the present inven- 10% of water was then added and the coagulated material was -re-' This oil' sample 1 tion, it is found that there is a definite improvement in the viscosity index of the oils.
• colloidal material As a by-product of one aspect of the present invention, it is found that the colloidal material, coagulated and removed from the oil as described above, is useful as a sur- 7 face active agent.
• a method for improving a lubricating oil comprising adding sodium to the oil; bubbling air through the oil to oxidize impurities; adding Water to the oil to coagulate colloidal material therein; and removing the coagulated material from the oil.
• a method for improving a lubricating oil comprising treating the oil with an oxidising agent in the presence of sodium metal.
• a method as claimed in claim 2 efiected at 100- 200 C. for at least five minutes.
• a method for improving a lubricating oil comprising bubbling air through the oil in the presence of sodium metal at a temperature of at least 120 C.
• a method for improving a lubricating oil comprising bubbling air through the oil at a temperature of at least 120 C. in the presence of sodium metal; coagulating coloidal material therein; and removing the coagulated material from the oil.
• a method for improving a lubricating oil comprising bubbling air through the oil at a temperature of at least 120 C. in the presence of sodium metal; adding Water to the oil to coagulate colloidal material therein; and removing the coagulated material from the oil.
• a method for improving a lubricating oil comprising intimately contacting the oil at 200 C. with air in the presence of sodium metal, then treating the oil with water to coagulate colloidal material therein and removing the coagulated material therefrom.

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• Chemical & Material Sciences (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Engineering & Computer Science (AREA)
• Chemical Kinetics & Catalysis (AREA)
• General Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Combustion & Propulsion (AREA)
• Lubricants (AREA)

Applications Claiming Priority (1)

Publications (1)

Family

ID=10914953

Family Applications (1)

Country Status (2)

Cited By (2)

Citations (7)

• 0
  • NL NL86219D patent/NL86219C/xx active
• 1953
  • 1953-06-29 US US364926A patent/US2767122A/en not_active Expired - Lifetime

Patent Citations (7)

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