US2736737A - Phosphate partial ester-aldehyde condensation product and lubricant containing the same - Google Patents
Phosphate partial ester-aldehyde condensation product and lubricant containing the same Download PDFInfo
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- US2736737A US2736737A US180901A US18090150A US2736737A US 2736737 A US2736737 A US 2736737A US 180901 A US180901 A US 180901A US 18090150 A US18090150 A US 18090150A US 2736737 A US2736737 A US 2736737A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
- C10M137/04—Phosphate esters
- C10M137/10—Thio derivatives
- C10M137/105—Thio derivatives not containing metal
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- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/091—Esters of phosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
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- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/093—Polyol derivatives esterified at least twice by phosphoric acid groups
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- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/141—Esters of phosphorous acids
- C07F9/1411—Esters of phosphorous acids with hydroxyalkyl compounds with further substituents on alkyl
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- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/1651—Esters of thiophosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/1652—Polyol derivatives esterified at least twice by thiophosphoric acid groups
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/201—Esters of thiophosphorus acids
- C07F9/2015—Esters of thiophosphorus acids with hydroxyalkyl compounds with further substituents on alkyl
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/042—Metal salts thereof
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2225/02—Macromolecular compounds from phosphorus-containg monomers, obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/042—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/044—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for manual transmissions
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/046—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
Definitions
- This invention relates to a new class of organic phosphorus compounds and to compositions containing them. More particularly it relates to condensation products obtained by reacting phosphate partial esters with aldehydes and to lubricating compositions containing these condensation products.
- phosphate esters as addition agents in lubricating compositions to improve various characteristics of the lubricating compositions such as their resistance to oxidation, corrosiveness, detergency, oiliness, viscosity index and so forth. More recently it has been found that phosphate esters containing sulfur in direct linkage with the phosphorus are particularly valuable modifying agents for lubricants, and a large number of such compounds have been used, chiefly as multifunctional additives for extreme pressure lubricants. For example it is disclosed in U. S.
- a further object of this invention is to provide improved lubricants containing these compounds.
- Another object of the invention is to provide a novel class of multifunctional lubricant additives.
- Another object of the invention is to provide a class of compounds having the property of imparting improved lubricating characteristics to a lubricant composition without having undesirable or deleterious eifects upon other properties of the lubricant composition.
- novel compounds of my invention are the condensation products obtained by reacting partial esters and thio esters of phosphorus acids and thio acids of the types shown in the foregoing patents, with aldehydes. These compounds are preferably monomeric condensation products which may be represented by the general formula nix Y Y XE,
- RlX wherein X is oxygen or sulfur, Y is either oxygen or sulfur or is absent, and R, R1, R2, R3 and R4 represent hydrogen or organic radicals which may be the same or differeat, at least one organic radical being attached to each phosphorus atom through an oxygen or a sulfur atom.
- the organic radicals may be aliphatic groups, including open chain and cyclic, saturated and unsaturated aliphatic groups, aromatic groups, or substituted aliphatic or aromatic groups. Sufficient alkyl carbon atoms are contained in these organic groups to impart oil-solubility to the molecule. These organic groups may also contain any of the inorganic substituents commonly employed in lubricant additives, such as halogen atoms, hydroxyl groups, carboxyl groups, nitro groups, amino groups, mercaptan groups and so forth.
- My preferred compounds for use as lubricant additives may be represented by the following formula R2X' S H SI X114 i sg-s-i R x XR3 wherein X is oxygen or sulfur, R is hydrogen or an organic group and R1, R2, R3 and R4 are organic groups as described above.
- CoHia Addition agents of the above type have important advantages over the known types of phosphate ester additives, particularly in that they possess increased chemical stability and decreased acidity and corrosiveness and do not add to the non-volatile ash content of the lubricant. They are antioxidant and corrosion-inhibiting both when used alone and with other more corrosive additives.
- the amount of these phosphorus compounds which may be added to lubricating oils may be varied depending upon the effect desired and upon the characteristics of the base oil. In general, small proportions, for example from 0.1% to and preferably from about 0.5% to about 2%, are employed. However, either greater or less amounts may be used if desired.
- the compounds of my invention are preferably the monomeric condensation products as shown in the formula, a certain amount of more or less polymeric products may be formed when monoesters are present in the reaction mixture, and such compounds are also included within the purview of this invention, since it is conceived that useful resins and high molecular weight products having pour point-reducing and other valuable properties may be obtained by this condensation reaction.
- esters used in preparing the condensation prodnets of my invention may be one or more of the following types: mono-esters of phosphorous and phosphoric acids, di-esters of phosphorous and phosphoric acids, mono-thio esters of phosphorous and phosphoric acids, di-thio esters of phosphorous and phosphoric acids, monoand di-esters of tri-thio phosphorous acids, monoand di-thio esters of tri-thio phosphorous acids, monoand di-esters of tetra-thio phosphoric acid, and monoand dithio esters of tetra-thio phosphoric acids.
- Esters of the above types may be obtained by any of the familiar esterification reactions between an aliphatic or aromatic alcohol or mercaptan and an oxygen and/ or sulfur-containing phosphorus acid, such as phosphorous acid, phosphoric acid, thio phosphorous acid, thio phosphoric acid, phosphorus pentoxide, or a phosphorus sulfide such as phosphorus pentasulfide, phosphorus trisulfide or phosphorus heptasulfide, or by other ester-forming reactions such as the reaction between a halogenated hydrocarbon and a phosphorus acid salt such as di-sodium hydrogen phosphate.
- phosphorus acid such as phosphorous acid, phosphoric acid, thio phosphorous acid, thio phosphoric acid, phosphorus pentoxide, or a phosphorus sulfide such as phosphorus pentasulfide, phosphorus trisulfide or phosphorus heptasulf
- Esters suitable for preparing the preferred compounds of my invention may be readily obtained by re 1 acting an alcohol or a mercaptan with phosphorus pentasulfide.
- the reaction of an alcohol with phosphorus pentasulfide and the condensation of the ester obtained with an aldehyde take place according to the following equations:
- R is an organic group and R is an organic group or hydrogen.
- the alcohols employed in the above reaction may be aliphatic alcohols, including straight or branched chain or cyclic alcohols, preferably those containing from about 4 to about 20 carbon atoms in the molecule, aromatic alcohols, preferably alkylated aromatic alcohols, or heterocyclic alcohols and such alcohols containing substituent groups in so far as these do not interfere to any appreciable extent with the esterification or condensation reaction.
- Suitable alcohols which may be mentioned include amyl alcohol, octyl alcohol, cetyl alcohol, lauryl alcohol, stearyl alcohol, benzyl alcohol, phenyl ethyl alcohol, diamyl phenoxy ethanol, cyclohexanol, methyl cyclohhexanol, terpineol, cardanol, phenol, naphthol, cresol, xylenol, chlorophenol, octyl phenol, diamyl phenol and hydroquinone.
- the corresponding mercaptans and thio phenols may be used in place of these alcohols.
- mixtures of two or more different alcohols or mercaptans or mixtures of both alcohols and mercaptans may be employed in the esterification reaction in order to obtain mixed esters.
- aldehydes employed in the condensation reaction may likewise be aliphatic, aromatic or heterocylic in character and may contain substituent groups such as those mentioned above in so far as these do not interfere with the condensation reaction.
- Suitable aldehydes which may be mentioned include formaldehyde, acetaldehyde, trichloroacetaldehyde, butyraldehyde, benzaldehyde, salicylaldehyde and furfural.
- the condensation reaction is carried out by reacting a phosphate partial ester of the type described above, or a salt of the ester such as the sodium salt, with an aldehyde, preferably in an alcohol solution in the presence of hydrochloric acid.
- the molar ratio of phosphate ester: aldehyde employed in the reaction may range from about 2:1 to about 2:6. It is preferably about 2: 1.
- the value of this compound as a lubricant additive has been demonstrated by means of a special test which was designed to show the corrosiveness and oxidation stability of a lubricating oil under the bearing lubrication conditions existing in an internal combustion engine.
- a lubricating oil at an elevated temperature is continuously circulated and recirculated over a bearing specimen in the presence of air and of catalytic metal surfaces, and the corrosiveness of the oil determined by measuring the loss in weight of the bearing at two hour intervals, up to ten hours.
- the test apparatus comprises a stainless steel motor-driven spinner enclosing a copperlead bearing specimen and a stationary stainless steel shaft connected to a base plate assembly.
- Copper baflles are also attached to the base plate assembly for the purpose of imparting turbulence to the oil and to act as oxidation catalysts.
- the bearing specimen is connected to the spinner by means of a special non-wearing bushing, so that the entire weight loss of the bearing is attributable to the corrosive action of the oil.
- the spinner enclosing the bearing specimen is immersed in a sample of the test oil maintained at 350 F. in a glass vessel and is rotated at a speed of 3000 revolutions per minute about the stainless steel stationary shaft.
- the oil is forced through the bearing clearance by capillary attraction and centrifugal force and is sprayed into the air through holes near the periphery of the rotating spinner.
- a Mid-Continent paraflinic base lubricating oil was used in the example, the use of my compounds as lubricant additives is not limited to any particular base stock, since these compounds may be employed in mineral lubricating oil bases of a wide variety obtained from various types of crudes or synthetic oils by any of the conventional refining methods and also in other oleaginous materials such as animal or vegetable oils.
- Other compounding ingredients may also be present in the lubricant composition such as pour point depressors, oiliness agents, corrosion inhibitors, antioxidants, extreme pressure agents, viscosity index improving agents and thickening agents such as soaps either in minor amounts or in grease-forming proportions.
- my novel compounds is furthermore not limited to their use as lubricant additives, since it is to be expected from a consideration of their properties that they will find a number of other uses such as, for example, antioxidants and corrosion inhibitors in various types of industrial oils and in gasoline, as modifying agents in plastics and so forth.
Description
United John R. Morris, Fishkiil, N. Y., assignor to The Texas Company, New York, N. Y., a corporation of Delaware No Drawing. Application August 22, 195%, Serial No. 180,901
8 Claims. (Cl. 260-461) This invention relates to a new class of organic phosphorus compounds and to compositions containing them. More particularly it relates to condensation products obtained by reacting phosphate partial esters with aldehydes and to lubricating compositions containing these condensation products.
It is old in the art to employ phosphate esters as addition agents in lubricating compositions to improve various characteristics of the lubricating compositions such as their resistance to oxidation, corrosiveness, detergency, oiliness, viscosity index and so forth. More recently it has been found that phosphate esters containing sulfur in direct linkage with the phosphorus are particularly valuable modifying agents for lubricants, and a large number of such compounds have been used, chiefly as multifunctional additives for extreme pressure lubricants. For example it is disclosed in U. S. 2,242,260, to Prutton, that extreme pressure agents are produced by reacting phosphorus pentasuhide with various organic compounds including stearic acid, lauryl alcohol, benzyl alcohol, naphthenic acid, butyl stearate, phenol and chlorophenol. Extremepressure agents are also prepared by the method of U. S. 2,396,719 to Musselmanet al., whereby phosphorus pentasulfide is reacted with an alcohol. The reaction product is preferably further reacted with a base such as ammonia, an'amine, or a metal oxide or hydroxide. U. S. 2,252,985, to Rutherford et al., disclosesthat the oxidation resistance of a lubricant is increased by the addition of alkaline earth metal salts of esters obtained by reacting aliphatic or aromatic alcohols or mercaptans with sulfur-containing acids of phosphorus. U. S. 2,470,405, to Leland, discloses that the load bearing quality of cutting oils is improved by the addition of esters having the formulas P(XR)3 and XP(XR)3, wherein X is either oxygen or sulfur, at least one R is hydrogen and the remaining Rs are aliphatic or aromatic hydrocarbon radicals. U. S. 2,368,000, to Cook, discloses anti-foaming agents prepared by reacting phosphorus pentasulfide with branched chain alcohols and neutralizing the product with heavy metal salts. U. S. 2,343,-
831, to Osborne, discloses dialkyl and diaryl dithiophosphate polysulfides as extreme pressure agents.
While compounds of the above type are very effective in improving a number of lubricant properties, they also possess certain disadvantages which are more or less serious depending upon the purpose for which the lubricant is to be employed. The esters themselves are highly acidic and corrosive, so that they must usually be employed in the form of their salts or other compounds. However, many of these compounds heretofore proposed hydrolyze or otherwise decompose at high temperatures, and the use of metal salts is undesirable in many cases, as for example where there are rigid restrictions upon the CgHu 2,736,737 ?atented Feb. 28, 1956 permissible amount of non-volatile ash remaining after combustion.
It is an object of the present invention to provide improved organic phosphorus compounds. A further object of this invention is to provide improved lubricants containing these compounds. Another object of the invention is to provide a novel class of multifunctional lubricant additives. Another object of the invention is to provide a class of compounds having the property of imparting improved lubricating characteristics to a lubricant composition without having undesirable or deleterious eifects upon other properties of the lubricant composition.
The novel compounds of my invention are the condensation products obtained by reacting partial esters and thio esters of phosphorus acids and thio acids of the types shown in the foregoing patents, with aldehydes. These compounds are preferably monomeric condensation products which may be represented by the general formula nix Y Y XE,
RlX wherein X is oxygen or sulfur, Y is either oxygen or sulfur or is absent, and R, R1, R2, R3 and R4 represent hydrogen or organic radicals which may be the same or differeat, at least one organic radical being attached to each phosphorus atom through an oxygen or a sulfur atom. The organic radicals may be aliphatic groups, including open chain and cyclic, saturated and unsaturated aliphatic groups, aromatic groups, or substituted aliphatic or aromatic groups. Sufficient alkyl carbon atoms are contained in these organic groups to impart oil-solubility to the molecule. These organic groups may also contain any of the inorganic substituents commonly employed in lubricant additives, such as halogen atoms, hydroxyl groups, carboxyl groups, nitro groups, amino groups, mercaptan groups and so forth.
My preferred compounds for use as lubricant additives may be represented by the following formula R2X' S H SI X114 i sg-s-i R x XR3 wherein X is oxygen or sulfur, R is hydrogen or an organic group and R1, R2, R3 and R4 are organic groups as described above.
As specific examples of such compounds which are particularly suitable for use as lubricant additives are the following:
0 9E250 S S 00121125 CsHn aHn
CoHia Addition agents of the above type have important advantages over the known types of phosphate ester additives, particularly in that they possess increased chemical stability and decreased acidity and corrosiveness and do not add to the non-volatile ash content of the lubricant. They are antioxidant and corrosion-inhibiting both when used alone and with other more corrosive additives.
The amount of these phosphorus compounds which may be added to lubricating oils may be varied depending upon the effect desired and upon the characteristics of the base oil. In general, small proportions, for example from 0.1% to and preferably from about 0.5% to about 2%, are employed. However, either greater or less amounts may be used if desired.
While the compounds of my invention are preferably the monomeric condensation products as shown in the formula, a certain amount of more or less polymeric products may be formed when monoesters are present in the reaction mixture, and such compounds are also included within the purview of this invention, since it is conceived that useful resins and high molecular weight products having pour point-reducing and other valuable properties may be obtained by this condensation reaction.
These esters used in preparing the condensation prodnets of my invention may be one or more of the following types: mono-esters of phosphorous and phosphoric acids, di-esters of phosphorous and phosphoric acids, mono-thio esters of phosphorous and phosphoric acids, di-thio esters of phosphorous and phosphoric acids, monoand di-esters of tri-thio phosphorous acids, monoand di-thio esters of tri-thio phosphorous acids, monoand di-esters of tetra-thio phosphoric acid, and monoand dithio esters of tetra-thio phosphoric acids. Esters of the above types may be obtained by any of the familiar esterification reactions between an aliphatic or aromatic alcohol or mercaptan and an oxygen and/ or sulfur-containing phosphorus acid, such as phosphorous acid, phosphoric acid, thio phosphorous acid, thio phosphoric acid, phosphorus pentoxide, or a phosphorus sulfide such as phosphorus pentasulfide, phosphorus trisulfide or phosphorus heptasulfide, or by other ester-forming reactions such as the reaction between a halogenated hydrocarbon and a phosphorus acid salt such as di-sodium hydrogen phosphate. Esters suitable for preparing the preferred compounds of my invention may be readily obtained by re 1 acting an alcohol or a mercaptan with phosphorus pentasulfide. The reaction of an alcohol with phosphorus pentasulfide and the condensation of the ester obtained with an aldehyde take place according to the following equations:
wherein R is an organic group and R is an organic group or hydrogen.
The alcohols employed in the above reaction may be aliphatic alcohols, including straight or branched chain or cyclic alcohols, preferably those containing from about 4 to about 20 carbon atoms in the molecule, aromatic alcohols, preferably alkylated aromatic alcohols, or heterocyclic alcohols and such alcohols containing substituent groups in so far as these do not interfere to any appreciable extent with the esterification or condensation reaction. Suitable alcohols which may be mentioned include amyl alcohol, octyl alcohol, cetyl alcohol, lauryl alcohol, stearyl alcohol, benzyl alcohol, phenyl ethyl alcohol, diamyl phenoxy ethanol, cyclohexanol, methyl cyclohhexanol, terpineol, cardanol, phenol, naphthol, cresol, xylenol, chlorophenol, octyl phenol, diamyl phenol and hydroquinone. The corresponding mercaptans and thio phenols may be used in place of these alcohols. Instead of a single alcohol or mercaptan, mixtures of two or more different alcohols or mercaptans or mixtures of both alcohols and mercaptans may be employed in the esterification reaction in order to obtain mixed esters.
The aldehydes employed in the condensation reaction may likewise be aliphatic, aromatic or heterocylic in character and may contain substituent groups such as those mentioned above in so far as these do not interfere with the condensation reaction. Suitable aldehydes which may be mentioned include formaldehyde, acetaldehyde, trichloroacetaldehyde, butyraldehyde, benzaldehyde, salicylaldehyde and furfural.
The condensation reaction is carried out by reacting a phosphate partial ester of the type described above, or a salt of the ester such as the sodium salt, with an aldehyde, preferably in an alcohol solution in the presence of hydrochloric acid. The molar ratio of phosphate ester: aldehyde employed in the reaction may range from about 2:1 to about 2:6. It is preferably about 2: 1.
The following detailed procedure illustrates a method which may be used for preparing the compounds of my invention.
EXAMPLE Preparation of a condensation product between diamyl phenol-P285 reaction product and formaldehyde, having A diamyl phenol-P285 reaction product was prepared by adding 96 g. of P285 slowly to a solution of 500 g. of diamyl phenol in 250 cc. of xylene, refluxing the reaction mixture for 3 hours and permitting it to stand until the reaction was complete. The solution was finally filtered and the solvent removed by stripping. 587 g. of reaction product was obtained having a neutralization number of 82.3. 560 g. of this product was dissolved in 860 cc. of absolute alcohol and 100 g. of aqueous formaldehyde (37% by weight) and 50 cc. of concentrated I-lCl added. Gaseous HCl was passed in and the reaction mixture refiuxed for 3 hours. It was then cooled and shaken with 1 liter of water in a separatory funnel. After separation of the water layer the product remaining was dissolved in ether, the ether solution washed repeatedly with water and an aqueous salt solution until the washings were new tral to litmus and the ether finally removed by steam stripping. 544 g. of product was obtained having a specific gravity of 0.991 and a neutralization number of 23.8.
The value of this compound as a lubricant additive has been demonstrated by means of a special test which was designed to show the corrosiveness and oxidation stability of a lubricating oil under the bearing lubrication conditions existing in an internal combustion engine. In this test a lubricating oil at an elevated temperature is continuously circulated and recirculated over a bearing specimen in the presence of air and of catalytic metal surfaces, and the corrosiveness of the oil determined by measuring the loss in weight of the bearing at two hour intervals, up to ten hours. The test apparatus comprises a stainless steel motor-driven spinner enclosing a copperlead bearing specimen and a stationary stainless steel shaft connected to a base plate assembly. Copper baflles are also attached to the base plate assembly for the purpose of imparting turbulence to the oil and to act as oxidation catalysts. The bearing specimen is connected to the spinner by means of a special non-wearing bushing, so that the entire weight loss of the bearing is attributable to the corrosive action of the oil. The spinner enclosing the bearing specimen is immersed in a sample of the test oil maintained at 350 F. in a glass vessel and is rotated at a speed of 3000 revolutions per minute about the stainless steel stationary shaft. The oil is forced through the bearing clearance by capillary attraction and centrifugal force and is sprayed into the air through holes near the periphery of the rotating spinner. The following table shows results obtained by carrying out this test with a solvent-refined, dewaxed, Mid-Continent lubricating oil of S. A. E. 30 grade containing 1.0% of the phosphate ester-aldehyde condensation product described.
Corrosion test results Weight loss in mg.
Hours of test Base 011 Base oil additive The above table shows the substantial improvement in the corrosiveness of a mineral lubricating oil obtained by the addition of a small amount of a phosphorus compound of my invention.
In the standard Almen test for measuring the extreme pressure properties of lubricating compositions, a blend of 1.0% of this condensation product with the same base oil as described above, had an Almen value of 13 pounds, as compared with 9 pounds for the base oil alone.
According to the particular compound of this class selected, improvements in anticorrosiveness and extreme pressure properties, as well as other properties such as detergency and so forth which are exhibited by the phosphate esters generally, may be obtained in varying degrees.
Although a Mid-Continent paraflinic base lubricating oil was used in the example, the use of my compounds as lubricant additives is not limited to any particular base stock, since these compounds may be employed in mineral lubricating oil bases of a wide variety obtained from various types of crudes or synthetic oils by any of the conventional refining methods and also in other oleaginous materials such as animal or vegetable oils. Other compounding ingredients may also be present in the lubricant composition such as pour point depressors, oiliness agents, corrosion inhibitors, antioxidants, extreme pressure agents, viscosity index improving agents and thickening agents such as soaps either in minor amounts or in grease-forming proportions.
The use of my novel compounds is furthermore not limited to their use as lubricant additives, since it is to be expected from a consideration of their properties that they will find a number of other uses such as, for example, antioxidants and corrosion inhibitors in various types of industrial oils and in gasoline, as modifying agents in plastics and so forth.
Obviously many modifications and variations of the invention as hereinbefore set forth, may be made without departing from the spirit and scope thereof and, therefore, only such limitations should be imposed as are indicated in the appended claims.
I claim: 1. A compound having the formula sHu Us n g2 0\ /0 0 H o H o H" ii c n 6 ll 5 ll 2. The condensation product resulting from the reaction of a phosphoric acid partial ester with an aldehyde, said phosphoric acid partial ester being selected from the group consisting of monoand diaryl esters of phosphoric thioacids.
3. Claim 2 wherein the phosphoric acid partial ester is a diaryldithiophosphoric acid diester.
4. The condensation product according to claim 2 in which said phosphoric acid partial ester is reacted; with an aldehyde in a molar ratio of from about 2:1 to about 2:6 in the presence of an acid catalyst.
5. The condensation product according to claim 2 wherein the aldehyde is formaldehyde.
6. The condensation product of an 0,0-dialkylphenyl diester of dithiophosphoric acid and a low molecular weight aliphatic aldehyde.
7. The condensation product according to claim 6, wherein the aldehyde is formaldehyde.
8. The condensation product of a diamylphenol-PzSs reaction product and formaldehyde.
References Cited in the file of this patent UNITED STATES PATENTS 2,266,514 Romieux Dec. 16, 1941 1 2,343,831 Osborne Mar. 7, 1944 2,382,622 Ton Toy Aug. 14, 1945 2,436,141 Goebel Feb. 17, 1948 2,443,264 Mikeska June 15, 1948 2,531,129 Hook Nov. 21, 1950 2,565,920 Hook Aug. 28, 1951 2,586,655 Hook V Feb. 19, 1952 2,589,675 Cook Mar. 18, 1952
Claims (1)
1. A COMPOUND HAVING THE FORMULA
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US180902A US2736738A (en) | 1950-08-22 | 1950-08-22 | Phosphate partial ester-aldehyde-amine condensation product and lubricant containing the same |
US180901A US2736737A (en) | 1950-08-22 | 1950-08-22 | Phosphate partial ester-aldehyde condensation product and lubricant containing the same |
US295344A US2736707A (en) | 1950-08-22 | 1952-06-24 | Lubricant containing phosphate partial ester - aldehyde - amine condensation product |
US300757A US2736706A (en) | 1950-08-22 | 1952-07-24 | Lubricant containing a phosphorus acid ester-aldehyde condensation product |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US180902A US2736738A (en) | 1950-08-22 | 1950-08-22 | Phosphate partial ester-aldehyde-amine condensation product and lubricant containing the same |
US180901A US2736737A (en) | 1950-08-22 | 1950-08-22 | Phosphate partial ester-aldehyde condensation product and lubricant containing the same |
US295344A US2736707A (en) | 1950-08-22 | 1952-06-24 | Lubricant containing phosphate partial ester - aldehyde - amine condensation product |
US300757A US2736706A (en) | 1950-08-22 | 1952-07-24 | Lubricant containing a phosphorus acid ester-aldehyde condensation product |
Publications (1)
Publication Number | Publication Date |
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US2736737A true US2736737A (en) | 1956-02-28 |
Family
ID=32303692
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US180901A Expired - Lifetime US2736737A (en) | 1950-08-22 | 1950-08-22 | Phosphate partial ester-aldehyde condensation product and lubricant containing the same |
US180902A Expired - Lifetime US2736738A (en) | 1950-08-22 | 1950-08-22 | Phosphate partial ester-aldehyde-amine condensation product and lubricant containing the same |
US295344A Expired - Lifetime US2736707A (en) | 1950-08-22 | 1952-06-24 | Lubricant containing phosphate partial ester - aldehyde - amine condensation product |
US300757A Expired - Lifetime US2736706A (en) | 1950-08-22 | 1952-07-24 | Lubricant containing a phosphorus acid ester-aldehyde condensation product |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US180902A Expired - Lifetime US2736738A (en) | 1950-08-22 | 1950-08-22 | Phosphate partial ester-aldehyde-amine condensation product and lubricant containing the same |
US295344A Expired - Lifetime US2736707A (en) | 1950-08-22 | 1952-06-24 | Lubricant containing phosphate partial ester - aldehyde - amine condensation product |
US300757A Expired - Lifetime US2736706A (en) | 1950-08-22 | 1952-07-24 | Lubricant containing a phosphorus acid ester-aldehyde condensation product |
Country Status (1)
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US (4) | US2736737A (en) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2841520A (en) * | 1956-07-16 | 1958-07-01 | Fmc Corp | Pesticidal phosphorus esters |
US2873228A (en) * | 1956-07-16 | 1959-02-10 | Fmc Corp | Pesticidal phosphorus esters |
US2882198A (en) * | 1956-07-16 | 1959-04-14 | Fmc Corp | Pesticidal phosphorus esters |
US2928862A (en) * | 1956-07-16 | 1960-03-15 | Fmc Corp | Pesticidal phosphorus esters |
US2959546A (en) * | 1956-08-28 | 1960-11-08 | Exxon Research Engineering Co | Silver corrosion inhibited lubricating composition |
US3169903A (en) * | 1961-06-26 | 1965-02-16 | Shell Oil Co | Organophosphorus insecticide |
US3370110A (en) * | 1964-02-24 | 1968-02-20 | Shell Oil Co | Process for preparing toluene-alpha, alpha-dithiol bis(o, o-di loweralkyl phosphorodithioates) |
US3869526A (en) * | 1972-06-13 | 1975-03-04 | Ciba Geigy Corp | Bis(phosphates) |
US4000101A (en) * | 1970-07-14 | 1976-12-28 | Weston Chemical Corporation | Thiophosphites and ultraviolet light stabilizer for olefin polymers |
US4056480A (en) * | 1975-06-10 | 1977-11-01 | Monsanto Company | Hydraulic fluids |
US4220611A (en) * | 1978-06-29 | 1980-09-02 | Sandoz, Inc. | Polyoxyalkylene bridged phosphate esters |
EP0090506A2 (en) * | 1982-03-26 | 1983-10-05 | Mobil Oil Corporation | Lubricant compositions containing a dithiophosphoric acid ester-aldehyde reaction product |
US4800030A (en) * | 1985-12-28 | 1989-01-24 | Idemitsu Kosan Company Limited | Refrigerator oil composition |
US5547614A (en) * | 1989-11-14 | 1996-08-20 | Akzo Nobel N.V. | Flame retardant mixture of polybrominated diphenyl oxide and organic diphosphate |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3017422A (en) * | 1958-01-08 | 1962-01-16 | Universal Oil Prod Co | Composition of matter |
US3238131A (en) * | 1960-12-23 | 1966-03-01 | Shell Oil Co | Lubricating compositions containing bis(phosphono-methyl) disulfides |
US3105819A (en) * | 1959-12-21 | 1963-10-01 | Shell Oil Co | Lubricating compositions |
US3240704A (en) * | 1961-01-30 | 1966-03-15 | Sinclair Research Inc | Lubricating compositions having oilsoluble phosphorus-containing condensation products |
US3256190A (en) * | 1962-10-18 | 1966-06-14 | Texaco Inc | Thiophosphonoxyalkanes |
US3263000A (en) * | 1962-11-19 | 1966-07-26 | Universal Oil Prod Co | Diisopropyl-dithiophosphatyl thioketals |
US3243371A (en) * | 1962-12-10 | 1966-03-29 | Shell Oil Co | Lubricating composition |
US3354195A (en) * | 1964-01-29 | 1967-11-21 | Stauffer Chemical Co | Phosphoro (mono or di) thioate thiocarbonates |
DE1670711C3 (en) * | 1966-06-25 | 1974-03-21 | Bayer Ag, 5090 Leverkusen | Process for the production of Thionothiolphosphor - (- phosphonic, phosphinic) acide star |
US3865740A (en) * | 1972-05-22 | 1975-02-11 | Chevron Res | Multifunctional lubricating oil additive |
US3909430A (en) * | 1972-08-07 | 1975-09-30 | Chevron Res | Lubricating composition |
US3859219A (en) * | 1972-11-17 | 1975-01-07 | Chevron Res | Bisphosphoramide-sulfur compound containing lubricant |
US3919095A (en) * | 1973-07-30 | 1975-11-11 | Mobil Oil Corp | Organic compositions containing antioxidant and antiwear additives |
US4010144A (en) * | 1974-03-13 | 1977-03-01 | Hooker Chemicals & Plastics Corporation | Flame retardant phosphate ester derivatives of ortho novolaks |
US4208357A (en) * | 1974-09-06 | 1980-06-17 | The Lubrizol Corporation | Process for preparing phosphorus and sulfur containing amides and thioamides |
US4032461A (en) * | 1974-09-06 | 1977-06-28 | The Lubrizol Corporation | Phosphorus and sulfur containing amides and thioamides as lubricating oil additives and lubricating oil compositions containing same |
DE3025277A1 (en) * | 1979-07-06 | 1981-01-08 | Ciba Geigy Ag | LUBRICANT ADDITIVES |
RU2737740C2 (en) * | 2016-04-27 | 2020-12-02 | Чайна Петролеум Энд Кемикал Корпорейшн | Benzotriazole derivative, a method for production and use thereof |
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US2266514A (en) * | 1938-09-09 | 1941-12-16 | American Cyanamid Co | Esters of dithiophosphoric acids |
US2343831A (en) * | 1941-06-26 | 1944-03-07 | American Cyanamid Co | Lubricating composition |
US2382622A (en) * | 1944-01-03 | 1945-08-14 | Victor Chemical Works | Glycol esters of phenylphosphonic acid |
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US2531129A (en) * | 1948-03-26 | 1950-11-21 | American Cyanamid Co | Mineral lubricating oil compositions containing dialkyldithio-phosphoric acid-formaldehyde condensation products |
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US2328570A (en) * | 1938-08-16 | 1943-09-07 | Eastman Kodak Co | Azo compounds and material colored therewith |
US2389718A (en) * | 1943-01-07 | 1945-11-27 | American Cyanamid Co | Disubstituted dithiophosphates |
US2586656A (en) * | 1949-08-18 | 1952-02-19 | American Cyanamid Co | S-aminoalkylidene dithiophosphoric acid triesters |
US2566288A (en) * | 1950-06-03 | 1951-08-28 | American Cyanamid Co | Dialkyldithiophosphatomethylureas |
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- 1950-08-22 US US180901A patent/US2736737A/en not_active Expired - Lifetime
- 1950-08-22 US US180902A patent/US2736738A/en not_active Expired - Lifetime
-
1952
- 1952-06-24 US US295344A patent/US2736707A/en not_active Expired - Lifetime
- 1952-07-24 US US300757A patent/US2736706A/en not_active Expired - Lifetime
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US2266514A (en) * | 1938-09-09 | 1941-12-16 | American Cyanamid Co | Esters of dithiophosphoric acids |
US2343831A (en) * | 1941-06-26 | 1944-03-07 | American Cyanamid Co | Lubricating composition |
US2382622A (en) * | 1944-01-03 | 1945-08-14 | Victor Chemical Works | Glycol esters of phenylphosphonic acid |
US2443264A (en) * | 1944-02-19 | 1948-06-15 | Standard Oil Dev Co | Compounded lubricating oil |
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US2531129A (en) * | 1948-03-26 | 1950-11-21 | American Cyanamid Co | Mineral lubricating oil compositions containing dialkyldithio-phosphoric acid-formaldehyde condensation products |
US2565920A (en) * | 1948-03-26 | 1951-08-28 | American Cyanamid Co | Triesters of dithiophosphoric acid |
US2586655A (en) * | 1948-03-26 | 1952-02-19 | American Cyanamid Co | S-alkoxymethyl-o, o'-dialkyldithiophosphates |
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Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2841520A (en) * | 1956-07-16 | 1958-07-01 | Fmc Corp | Pesticidal phosphorus esters |
US2873228A (en) * | 1956-07-16 | 1959-02-10 | Fmc Corp | Pesticidal phosphorus esters |
US2882198A (en) * | 1956-07-16 | 1959-04-14 | Fmc Corp | Pesticidal phosphorus esters |
US2928862A (en) * | 1956-07-16 | 1960-03-15 | Fmc Corp | Pesticidal phosphorus esters |
US2959546A (en) * | 1956-08-28 | 1960-11-08 | Exxon Research Engineering Co | Silver corrosion inhibited lubricating composition |
US3169903A (en) * | 1961-06-26 | 1965-02-16 | Shell Oil Co | Organophosphorus insecticide |
US3370110A (en) * | 1964-02-24 | 1968-02-20 | Shell Oil Co | Process for preparing toluene-alpha, alpha-dithiol bis(o, o-di loweralkyl phosphorodithioates) |
US4000101A (en) * | 1970-07-14 | 1976-12-28 | Weston Chemical Corporation | Thiophosphites and ultraviolet light stabilizer for olefin polymers |
US3869526A (en) * | 1972-06-13 | 1975-03-04 | Ciba Geigy Corp | Bis(phosphates) |
US4056480A (en) * | 1975-06-10 | 1977-11-01 | Monsanto Company | Hydraulic fluids |
US4220611A (en) * | 1978-06-29 | 1980-09-02 | Sandoz, Inc. | Polyoxyalkylene bridged phosphate esters |
EP0090506A2 (en) * | 1982-03-26 | 1983-10-05 | Mobil Oil Corporation | Lubricant compositions containing a dithiophosphoric acid ester-aldehyde reaction product |
EP0090506A3 (en) * | 1982-03-26 | 1985-08-14 | Mobil Oil Corporation | Lubricant compositions containing a dithiophosphoric acid ester-aldehyde reaction product |
US4800030A (en) * | 1985-12-28 | 1989-01-24 | Idemitsu Kosan Company Limited | Refrigerator oil composition |
US5547614A (en) * | 1989-11-14 | 1996-08-20 | Akzo Nobel N.V. | Flame retardant mixture of polybrominated diphenyl oxide and organic diphosphate |
Also Published As
Publication number | Publication date |
---|---|
US2736706A (en) | 1956-02-28 |
US2736707A (en) | 1956-02-28 |
US2736738A (en) | 1956-02-28 |
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