US2734830A - - Google Patents
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- US2734830A US2734830A US2734830DA US2734830A US 2734830 A US2734830 A US 2734830A US 2734830D A US2734830D A US 2734830DA US 2734830 A US2734830 A US 2734830A
- Authority
- US
- United States
- Prior art keywords
- textile
- goods
- group
- alkali
- long
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000004753 textile Substances 0.000 claims description 33
- 239000004902 Softening Agent Substances 0.000 claims description 24
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 238000005406 washing Methods 0.000 claims description 12
- 239000007859 condensation product Substances 0.000 claims description 10
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 9
- 238000004900 laundering Methods 0.000 claims description 9
- 239000011707 mineral Substances 0.000 claims description 9
- 229910019142 PO4 Inorganic materials 0.000 claims description 6
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 6
- 239000000271 synthetic detergent Substances 0.000 claims description 6
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims description 5
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 claims description 5
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000004744 fabric Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 13
- 239000003513 alkali Substances 0.000 description 9
- 125000001931 aliphatic group Chemical group 0.000 description 6
- -1 aliphatic radicals Chemical class 0.000 description 5
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 5
- 150000004668 long chain fatty acids Chemical class 0.000 description 5
- 235000021317 phosphate Nutrition 0.000 description 5
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920000223 polyglycerol Polymers 0.000 description 3
- 229920000151 polyglycol Polymers 0.000 description 3
- 239000010695 polyglycol Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000009988 textile finishing Methods 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 229940117927 ethylene oxide Drugs 0.000 description 2
- 150000002462 imidazolines Chemical class 0.000 description 2
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- BYMLDDSUHIUIJZ-UHFFFAOYSA-M 1-dodecylpyridin-1-ium dodecyl sulfate Chemical compound CCCCCCCCCCCCOS([O-])(=O)=O.CCCCCCCCCCCC[N+]1=CC=CC=C1 BYMLDDSUHIUIJZ-UHFFFAOYSA-M 0.000 description 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- KNIUHBNRWZGIQQ-UHFFFAOYSA-N 7-diethoxyphosphinothioyloxy-4-methylchromen-2-one Chemical compound CC1=CC(=O)OC2=CC(OP(=S)(OCC)OCC)=CC=C21 KNIUHBNRWZGIQQ-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 229920002955 Art silk Polymers 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 108010009736 Protein Hydrolysates Proteins 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229940027983 antiseptic and disinfectant quaternary ammonium compound Drugs 0.000 description 1
- 150000008365 aromatic ketones Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 150000001556 benzimidazoles Chemical class 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 description 1
- 229960001927 cetylpyridinium chloride Drugs 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- ZXTSZHRYZXZJLS-UHFFFAOYSA-M dodecanoate 1-dodecylpyridin-1-ium Chemical compound C(CCCCCCCCCCC)(=O)[O-].C(CCCCCCCCCCC)[N+]1=CC=CC=C1 ZXTSZHRYZXZJLS-UHFFFAOYSA-M 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002780 morpholines Chemical class 0.000 description 1
- OMEMQVZNTDHENJ-UHFFFAOYSA-N n-methyldodecan-1-amine Chemical compound CCCCCCCCCCCCNC OMEMQVZNTDHENJ-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical class NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
- D06L4/657—Optical bleaching or brightening combined with other treatments, e.g. finishing, bleaching, softening, dyeing or pigment printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/332—Di- or polyamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/405—Acylated polyalkylene polyamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
Definitions
- the present invention relates to a treatment of textile fabrics and more particularly it concerns a method of treating textile goods which are usually laundered.
- the washing agents commonly applied in laundering consists of soap and/ or the so-called synthetic detergents for instance long-chain alkyl sulfates or sulfonates and fatty alcohol condensation products which are usually mixed with auxiliary agents, such as alkali carbonates, silicates and/or phosphates.
- auxiliary agents such as alkali carbonates, silicates and/or phosphates.
- These additional agents tend to react with the calcium and magnesium ions present in the ordinary washing water, whereby salts are precipitated which are liable to be deposited on the fibres of the textile fabrics during the washing step, especially if detergents are applied that are not capable of keeping the soil and other undissolved substances sufiiciently suspended in the washing liquor.
- the mineral salts deposited on the fibres render the fabrics liable to be weakened, particularly at those parts of the textile goods which are exposed to friction or rubbing, as for instance the edges of collars or sleeves.
- a further object is to provide a method for prolonging the useful life of textile fabrics which are frequently washed and to enhance their utility performance in general.
- the objects of the invention are accomplished by treating textile fabrics which are usually laundered, with a softening agent after the washing step has been performed.
- the softening agents may be added to the usual rinsing bath; it is, however, of greater advantage to add the softening agents to a separate bath following the rinsing bath.
- the amount of softening agent added to the bath and the proportion of textile goods to liquor may vary within wide limits; in most cases it will be sufiicient to adjust the concentration of the softening agent in the bath to about 1 gram per liter, while the proportion of goods to liquor is 1: 20.
- softening agents all those can be resorted to for carrying out the present invention which are known as softeners in the art of textile finishing; particularly suitable are those softeners which have substantive properties.
- softening agent includes also mixtures of softeners.
- Cation-active softeners which are soluble only in the form of salts obtained with inorganic or organic acids are preferably applied in mixture with emulsifying agents since the rinsing bath usually shows an alkaline reaction tending to render the cation-active softeners insoluble.
- Emulsifying agents of neutral nature such as esters or ethers of long-chain aliphatic acids or alcohols with polyglycols or polyglycerols are to be preferred; suitable anionic surface active agents may also be resorted to, such as for instance higher molecular alkyl or aralkyl sulfonates, but in this case an excess of the emulsifying agent has to be applied so that the precipitate which is previously formed by the reaction of the anionic and cationic surface active substances will be dispersed. If cation-active softening agents are used which contain hydroxy or amino groups the solubility of the compounds may be improved by reaction with ethylene oxide. The cation-active softeners exhibit pronounced substantive properties so that they can be applied at lower bath concentrations than the other softening agents in the performance of the present invention. V
- Example I -.affin sulfonate, 5%.isododecylphenylsulfonate, 40% sodium carbonate and 4% sodium silicate, the proportion of goods to liquor being 1:20; After each washing the textile fabric was rinsed and then treated in a bath containing per liter 1 gram of a weakly sulfonated tallow, the ratio of, goods to liquor being likewise 1:20. After this treatment the breaking number was found to be 6750. A comparative sample which had been washed ten times with the same detergent Without being subjected to a treatment with a softening agent after the rinsing step showed a breaking number of only 120. The breaking number was determined according to Bodenbender, Zellwolle, 3rd edition, Berlin 1939, p. 230.
- Example 2 The textile fabric of Example 1 was washed ten times as described in Example 1 and after the rising step was treated each time in a bath containing as softening agent 1 gram of oleyl sarcoside per liter. The breaking number was then found to be 5430. Without treatment with a softening agent the breaking number was reduced to 130 even when 2% of a long-chain fatty acid had been added to the detergent applied.
- Example 3 The textile fabric of Example 1 was washed ten timesas described in Example 1 and after the rinsing step was treated each time in a bath containing as softening agent per liter 1 gram of a fatty acid polyglycerol ester obtainable by causing 1 mol of a long-chain fatty acid to react withat least 2 mols of glycerol according to German Patent 575,911. After ten launderings the breaking number amounted to 6270.
- Example 4 The textile fabric of Example 1 was washed ten times as described in Example 1 and after the rising step was treated each time in a bath containing as softening agent per liter 0.3 gram of a mixture of equal parts of the monoand di-ester of triethanolamine with a saturated long-chain aliphatic acid in the form of their acetates. After this treatment a breaking number of 28,000 was determined, that is to say a considerable increase of the original breaking number of 12,000.
- Example 5 The textile fabric of Example 1 was washed ten times as described in Example 1 and after the rinsing step was treated each time in a bath containing as softening agent per liter 0.3 gram of a mixture of equal parts of distearic acid amide of triethylenetetramine in the form of 'the hydrochloride and oleyl polyglycol ether. After ten launderings the breaking number amount to 27,000.
- Example 7 Thetextile fabric of Example 1 was washed ten times as described in Example 1 and after the rinsing step was treated each time in a bath containing as softening agent per liter 0.2 gram of the acetate of a condensation productobtained by causing 1 mol of stearylamine to react with.2.0 ,mols of ethyleneoxide. The breaking number after :tenlaunderings was ,found to be 25,000.
- Therniethod of treating textile goods with softening 4 agents may be combined with the method of treating textile goods with fluorescent substances known in the art as capable of producing whitening effects on textile materials.
- a method of laundering finished textile goods that are already soft to the touch and are usually repeatedly laundered which comprises washing said textile goods in a bath containing a synthetic detergent of the group consisting of long chain alkyl sulfates, long chain alkyl sulfonates and fatty alcohol-condensation products and an auxiliary mineral agent of the group consisting of alkali carbonates, alkali silicates and alkali phosphates, and subsequently rinsing the goods in a separate bath containing a cation-active textile softening agent.
- a synthetic detergent of the group consisting of long chain alkyl sulfates, long chain alkyl sulfonates and fatty alcohol-condensation products and an auxiliary mineral agent of the group consisting of alkali carbonates, alkali silicates and alkali phosphates and subsequently rinsing the goods in a separate bath containing a cation-active textile softening agent.
- a method of laundering finished textile goods that are already soft to the touch and are usually repeatedly laundered which comprises washing said textile goods in a bath containing a synthetic detergent of the group consisting of long chain alkyl sulfates, long chain alkyl sulfonates and fatty alcohol condensation products and an auxiliary mineral agent of the group consisting of alkali carbonates, alkali silicates and alkali phosphates, and subsequently rinsing the goods in a-scparate bath containing as the textile softening agent a member of the group consisting of higher molecular amines, diguanidcs and imidazolines.
- a method of laundering finished textile goods that are already soft to the touch and are usually repeatedly laundered which comprises washing said textile goods in a bath containing a synthetic detergent of the group consisting of long chain alkyl sulfates, long chain alkyl sulfonates and fatty alcohol condensation products and an auxiliary mineral agent of the group consisting of alkali carbonates, alkali silicates and alkali phosphates, and subsequently rinsing the goods in a separate bath containing as the textile softening agent a member of the group consisting of monoand polylongchain fatty acid amides of alkylpolyamines.
- a method of laundering finished textile goods that are already soft to the touch and are usually repeatedly laundered which comprises washing said textile goods in a bath containing a synthetic detergent of the group consisting of long chain alkyl sulfates, long chain alkyl sulfonates and fatty alcohol condensation products and an auxiliary mineral agent of the group consisting of alkali carbonates, alkali silicates and alkali phosphates, and subsequently rinsing the goods in a separate bath containing as the textile softening agent a material having substantive properties and selected from the group consisting of monoand polyesters of long-chain fatty acids with a member of the group consisting of monoand polyoxyarnines.
- auxiliary mineral agent includes sodium silicate.
- the softening agent is made up of the mono and -diesters of triethanolaminc acetate with a saturated long-chain aliphatic acid.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE293411X | 1950-01-13 | ||
DE170150X | 1950-01-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
US2734830A true US2734830A (en) | 1956-02-14 |
Family
ID=25754636
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US2734830D Expired - Lifetime US2734830A (en) | 1950-01-13 |
Country Status (5)
Country | Link |
---|---|
US (1) | US2734830A (is") |
BE (1) | BE500598A (is") |
CH (1) | CH293411A (is") |
FR (1) | FR1030923A (is") |
GB (1) | GB705672A (is") |
Cited By (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2924549A (en) * | 1955-12-15 | 1960-02-09 | Bayer Ag | Paper containing an organic fluorescent dye |
US2925639A (en) * | 1953-11-30 | 1960-02-23 | Deering Milliken Res Corp | Method of fulling and scouring wool |
US2972330A (en) * | 1956-02-15 | 1961-02-21 | Nat Steel Corp | Vacuum seal for coating apparatus |
US2995523A (en) * | 1958-02-17 | 1961-08-08 | Grace W R & Co | Detergent-softener compositions |
US3003954A (en) * | 1957-07-19 | 1961-10-10 | Staley Mfg Co A E | Methods and compositions of matter for softening textile fibers, yarns, and fabrics |
US3033704A (en) * | 1959-05-19 | 1962-05-08 | Armour & Co | Rendering fabric anti-static, soft, and microorganisms resistant |
US3048539A (en) * | 1959-06-29 | 1962-08-07 | American Cyanamid Co | Antistatic textile lubricant finishes |
US3083118A (en) * | 1958-03-04 | 1963-03-26 | Tee Pak Inc | Method of depositing a polymer of olefinically unsaturated monomer within a polymeric material and the resulting product |
US3095373A (en) * | 1959-01-30 | 1963-06-25 | Wyandotte Chemicals Corp | Fabric softeners |
US3131147A (en) * | 1959-06-16 | 1964-04-28 | Ciba Ltd | Process for imparting a soft handle to textile materials and aqueous dispersions suitable therefor |
US3329609A (en) * | 1965-03-22 | 1967-07-04 | Wyandotte Chemicals Corp | Compositions containing quaternary ammonium salts |
US3351483A (en) * | 1963-02-14 | 1967-11-07 | Little Inc A | Method of softening textile fabrics |
US3442692A (en) * | 1965-08-13 | 1969-05-06 | Conrad J Gaiser | Method of conditioning fabrics |
US3451844A (en) * | 1965-01-20 | 1969-06-24 | Bayer Ag | Cationic active agent and a method for softening a washable textile fabric therewith |
US3454494A (en) * | 1965-08-03 | 1969-07-08 | Standard Chem Products Inc | Textile softener compositions |
US3468697A (en) * | 1966-03-02 | 1969-09-23 | Colgate Palmolive Co | Method of treating textile articles which are usually laundered |
US3637496A (en) * | 1966-10-25 | 1972-01-25 | Procter & Gamble | Phosphiniminosulfoxonium compounds and process for preparing the same |
US3668136A (en) * | 1969-07-07 | 1972-06-06 | Witco Chemical Corp | Compatible anionic-catonic surfactant compositions |
US3965015A (en) * | 1972-08-01 | 1976-06-22 | Colgate-Palmolive Company | Bleach-resistant fabric softener |
US4137044A (en) * | 1977-07-08 | 1979-01-30 | Economics Laboratory, Inc. | Method of washing |
US4214038A (en) * | 1979-01-22 | 1980-07-22 | The Procter & Gamble Company | Fabric treatment compositions containing polyglycerol esters |
US4255294A (en) * | 1975-04-01 | 1981-03-10 | Lever Brothers | Fabric softening composition |
US4304610A (en) * | 1979-06-22 | 1981-12-08 | S. C. Johnson & Son, Inc. | Carpet cleaning method |
US5525261A (en) * | 1994-10-18 | 1996-06-11 | Henkel Corporation | Anti-static composition and method of making the same |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1902833A (en) * | 1929-04-23 | 1933-03-28 | Du Pont Rayon Co | Method of treating textile threads |
US2046242A (en) * | 1929-12-13 | 1936-06-30 | American Hyalsol Corp | Process for preventing the detrimental formation of lime and magnesia soaps |
US2089212A (en) * | 1936-06-08 | 1937-08-10 | Kritchevsky Wolf | Hydrotropic fatty material and method of making same |
GB472473A (en) * | 1936-03-17 | 1937-09-17 | Ultrazell G M B H | Starch preparation |
US2201041A (en) * | 1938-03-01 | 1940-05-14 | Warwick Chemical Company | Fatty derivatives of alkylated amines |
US2205042A (en) * | 1937-10-26 | 1940-06-18 | Du Pont | Softening of textile materials and compositions therefor |
US2304113A (en) * | 1940-08-03 | 1942-12-08 | Arnold Hoffman & Co Inc | Treated textile product |
US2316379A (en) * | 1938-06-28 | 1943-04-13 | Procter & Gamble | Process of removing impurities from washed textiles |
US2320281A (en) * | 1938-06-02 | 1943-05-25 | Mathieson Alkali Works Inc | Process for cleaning rugs |
US2443782A (en) * | 1944-04-07 | 1948-06-22 | Pacific Mills | Textile material of comparatively low electric resistance and method of producing the same |
US2524219A (en) * | 1947-09-16 | 1950-10-03 | Frederick C Bersworth | Germicidally active deionizing agents for alkaline ph solutions |
-
0
- US US2734830D patent/US2734830A/en not_active Expired - Lifetime
- BE BE500598D patent/BE500598A/xx unknown
-
1951
- 1951-01-12 FR FR1030923D patent/FR1030923A/fr not_active Expired
- 1951-01-13 CH CH293411D patent/CH293411A/de unknown
- 1951-01-15 GB GB1136/51A patent/GB705672A/en not_active Expired
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1902833A (en) * | 1929-04-23 | 1933-03-28 | Du Pont Rayon Co | Method of treating textile threads |
US2046242A (en) * | 1929-12-13 | 1936-06-30 | American Hyalsol Corp | Process for preventing the detrimental formation of lime and magnesia soaps |
GB472473A (en) * | 1936-03-17 | 1937-09-17 | Ultrazell G M B H | Starch preparation |
US2089212A (en) * | 1936-06-08 | 1937-08-10 | Kritchevsky Wolf | Hydrotropic fatty material and method of making same |
US2205042A (en) * | 1937-10-26 | 1940-06-18 | Du Pont | Softening of textile materials and compositions therefor |
US2201041A (en) * | 1938-03-01 | 1940-05-14 | Warwick Chemical Company | Fatty derivatives of alkylated amines |
US2320281A (en) * | 1938-06-02 | 1943-05-25 | Mathieson Alkali Works Inc | Process for cleaning rugs |
US2316379A (en) * | 1938-06-28 | 1943-04-13 | Procter & Gamble | Process of removing impurities from washed textiles |
US2304113A (en) * | 1940-08-03 | 1942-12-08 | Arnold Hoffman & Co Inc | Treated textile product |
US2443782A (en) * | 1944-04-07 | 1948-06-22 | Pacific Mills | Textile material of comparatively low electric resistance and method of producing the same |
US2524219A (en) * | 1947-09-16 | 1950-10-03 | Frederick C Bersworth | Germicidally active deionizing agents for alkaline ph solutions |
Cited By (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2925639A (en) * | 1953-11-30 | 1960-02-23 | Deering Milliken Res Corp | Method of fulling and scouring wool |
US2924549A (en) * | 1955-12-15 | 1960-02-09 | Bayer Ag | Paper containing an organic fluorescent dye |
US2972330A (en) * | 1956-02-15 | 1961-02-21 | Nat Steel Corp | Vacuum seal for coating apparatus |
US3003954A (en) * | 1957-07-19 | 1961-10-10 | Staley Mfg Co A E | Methods and compositions of matter for softening textile fibers, yarns, and fabrics |
US2995523A (en) * | 1958-02-17 | 1961-08-08 | Grace W R & Co | Detergent-softener compositions |
US3083118A (en) * | 1958-03-04 | 1963-03-26 | Tee Pak Inc | Method of depositing a polymer of olefinically unsaturated monomer within a polymeric material and the resulting product |
US3095373A (en) * | 1959-01-30 | 1963-06-25 | Wyandotte Chemicals Corp | Fabric softeners |
US3033704A (en) * | 1959-05-19 | 1962-05-08 | Armour & Co | Rendering fabric anti-static, soft, and microorganisms resistant |
US3131147A (en) * | 1959-06-16 | 1964-04-28 | Ciba Ltd | Process for imparting a soft handle to textile materials and aqueous dispersions suitable therefor |
US3048539A (en) * | 1959-06-29 | 1962-08-07 | American Cyanamid Co | Antistatic textile lubricant finishes |
US3351483A (en) * | 1963-02-14 | 1967-11-07 | Little Inc A | Method of softening textile fabrics |
US3451844A (en) * | 1965-01-20 | 1969-06-24 | Bayer Ag | Cationic active agent and a method for softening a washable textile fabric therewith |
US3329609A (en) * | 1965-03-22 | 1967-07-04 | Wyandotte Chemicals Corp | Compositions containing quaternary ammonium salts |
US3454494A (en) * | 1965-08-03 | 1969-07-08 | Standard Chem Products Inc | Textile softener compositions |
US3442692A (en) * | 1965-08-13 | 1969-05-06 | Conrad J Gaiser | Method of conditioning fabrics |
US3468697A (en) * | 1966-03-02 | 1969-09-23 | Colgate Palmolive Co | Method of treating textile articles which are usually laundered |
US3637496A (en) * | 1966-10-25 | 1972-01-25 | Procter & Gamble | Phosphiniminosulfoxonium compounds and process for preparing the same |
US3668136A (en) * | 1969-07-07 | 1972-06-06 | Witco Chemical Corp | Compatible anionic-catonic surfactant compositions |
US3965015A (en) * | 1972-08-01 | 1976-06-22 | Colgate-Palmolive Company | Bleach-resistant fabric softener |
US4255294A (en) * | 1975-04-01 | 1981-03-10 | Lever Brothers | Fabric softening composition |
US4137044A (en) * | 1977-07-08 | 1979-01-30 | Economics Laboratory, Inc. | Method of washing |
US4214038A (en) * | 1979-01-22 | 1980-07-22 | The Procter & Gamble Company | Fabric treatment compositions containing polyglycerol esters |
US4304610A (en) * | 1979-06-22 | 1981-12-08 | S. C. Johnson & Son, Inc. | Carpet cleaning method |
US5525261A (en) * | 1994-10-18 | 1996-06-11 | Henkel Corporation | Anti-static composition and method of making the same |
Also Published As
Publication number | Publication date |
---|---|
CH293411A (de) | 1953-09-30 |
FR1030923A (fr) | 1953-06-18 |
BE500598A (is") | |
GB705672A (en) | 1954-03-17 |
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