US2694021A - Textile bearing a starch size - Google Patents
Textile bearing a starch size Download PDFInfo
- Publication number
- US2694021A US2694021A US218558A US21855851A US2694021A US 2694021 A US2694021 A US 2694021A US 218558 A US218558 A US 218558A US 21855851 A US21855851 A US 21855851A US 2694021 A US2694021 A US 2694021A
- Authority
- US
- United States
- Prior art keywords
- starch
- warp
- textile
- fatty acid
- size
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004753 textile Substances 0.000 title claims description 21
- 229920002472 Starch Polymers 0.000 title description 27
- 235000019698 starch Nutrition 0.000 title description 26
- 239000008107 starch Substances 0.000 title description 23
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 14
- 239000000194 fatty acid Substances 0.000 claims description 14
- 229930195729 fatty acid Natural products 0.000 claims description 14
- 150000004665 fatty acids Chemical class 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical class [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 15
- 238000004513 sizing Methods 0.000 description 11
- 238000009941 weaving Methods 0.000 description 9
- 229920000297 Rayon Polymers 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 125000002947 alkylene group Chemical group 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000010411 cooking Methods 0.000 description 4
- 229920000881 Modified starch Polymers 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002964 rayon Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 239000004368 Modified starch Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 235000019426 modified starch Nutrition 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 101100161882 Caenorhabditis elegans acr-3 gene Proteins 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229940053200 antiepileptics fatty acid derivative Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
- 229940100445 wheat starch Drugs 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2965—Cellulosic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
Definitions
- An object of the present invention is to provide a novel, improved textile bearing a starch warp sizing.
- Another object of the present invention is to provide a sized warp suitable for weaving at high pickages.
- a warp sizing is a protective coating applied to warp yarns prior to the weaving operation.
- the primary pu'rpose of the sizing is to protect the warp against breakage which develops as a result of the abrasive action of the shuttle, heddle, comb and threads among themselves.
- a size must adhere well to the textile, possess hardness or abrasive resistance, flexibility and the property of ready removal in. desizing operations.
- Starches and acid-modified starches have long been used in the role of warp sizes.
- the eflectiveness of a size is conveniently indicated by the weaving of a sized warp in continuously increasing pickages.
- Pickage is a term employed to indicate the number of filling threads per inch'of warp. It is obvious that when using higher pickages, the abrasive actions described above will occur more frequently and thus subject the warp to greater strain. As the pickage increases, breakage of warp threads increases until a critical point is reached where the weaving operation becomes impractical, since the loom must be stopped while each break is repaired.
- a novel, starch warp size composition has been developed which will permit weaving at extremely high pickages or alternatively will permit greater efiiciency at the lower standard pickages by virtue of decreased-warp thread breakage.
- novel composition incorporates minor amounts of polyoxyalkylene higher fatty acids in aqueous starch solu tions.
- the sizing composition of the present invention comprises an aqueous solution containing 5 to starch or acid modified starch and 0.05 to 2% polyoxyalkylene higher fatty acid.
- the type of starch is not critical. The effect noticeable upon all starches including sago. potato, maize, tapioca and wheat starch.
- the polyoxyalkylene higher fatty acid derivatives employed correspond to the polyether ester which result from the treatment of a higher fatty acid or mixture of higher fatty acids with an excess of alkylene oxide.
- higher fatty acid as employed herein is meant an aliphatic, carboxyl bearing organic compound containing from 11 to 21 carbon atoms.
- mixed fatty acid mixtures as they occur when obtained from natural sources as fats, soya-bean oil, peanut oil, cottonseed oil, castor oil and the like are likewise suitable.
- alkylene oxide derivatives suitable in the present composition include those formed by the addition of ethylene and propylene oxide to the fatty acid in a molar ratio of acid to alkylene oxide within the limits of 1:3 and 1:20. These compounds may be produced by the condensation of acid and alkylene oxide under atmospheric or subatmospheric conditions by heating the materials with agitation. Pressures higher than atmospheric and small amounts of alkaline material as catalyst, however, assist in obtaining a much more practical reaction rate at a lower temperature. Since the compounds are old, the procedure for their production will not be illustrated in detail. v l
- the warp sizing composition is prepared by mixing and cooking the water and starch in the conventional manner.
- the polyoxyalkylene higher fatty acid may be added at any time.
- a convenient procedure which avoids lump formation consists in adding suflicient water to the total amount of starch used to form a thin paste.
- the remaining water containing the polyoxyalkylene higher fatty acid dispersed therein is then added, and the batch cooked.
- the sizing composition can be prepared as a high or low viscosity material depending on the temperature at which the cooking is carried out. By heating the composition with agitation below its boiling point within the range of from about to C., for from'20 to 40 minutes a low viscosity starch suspension is obtained.
- the liquid composition itself both in the high and low viscosity forms possesses other advantages over conventional starch suspensions which make it much easier to handle in the plant.
- the residue which remains in the slashing bath and upon the slashing equipment is more readily removable than that from the conventional starch size.
- Light hosing is sutficient to remove all traces, the additive apparently assisting in the resuspension of the starch in the wash water. Furthermore, during the use of these sizes no problems of skimming were apparent. Stability toward decomposition on storage appears markedly improved.
- the size is useful as a coating for the protection of cords, threads, yarns, pellicles, filaments and fabrics of both natural and synthetic-origin.
- spun yarns which may be so sized may be mentioned wool, cotton, linen, glass, asbestos, viscose rayon, acetate rayon, cuprammonium rayon, casein fiber and copolymerization products such as those from adipic acid, hexamethylenediamine and vinyl chloride, vinyl acetate.
- continuous filaments are amenable to the size.
- the sizing composition may be applied to the textile with the conventional starch sizing equipment.
- the composition is placed in a steam heated trough and the warp is drawn from the warp beam and immersed in the sizing solution by a series of rollers.
- the excess size is squeezed from the textile and it is led to the drying cylinders.
- After drying the textile passes split rods to separate the various warp ends prior to winding on the loom beam. During the drying operation there was no tendency of the sized textile to stick to the drum. Furthermore, flake off at the split rods was negligible. No tendency of the sized textile strands to adhere together on the loom beam was observed.
- the sizing compositions employed in the examples were compounded with an acid treated corn starch by mixing the ingredients in the manner described above. Cooking was continued for one-half hour at a temperature of 95 C.
- a Z spun 30/1 viscose rayon, 1.5/1-9/16 two-inch warp ribbons are slashed with the desired sizes and after drying are woven on a nine placev .3 ribbon loom.
- the weaving is started at 40 picks and increased after every V2 yard until-the number of threads failing at any one setting is. over 10.
- A. tex ile as efined in cla m 7 wh r in th w p yarn is; a synthetic polymerization product.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE510131D BE510131A (xx) | 1951-03-30 | ||
US218558A US2694021A (en) | 1951-03-30 | 1951-03-30 | Textile bearing a starch size |
FR1052555D FR1052555A (fr) | 1951-03-30 | 1952-03-18 | Perfectionnements apportés aux apprêts pour des matières textiles |
GB7072/52A GB731260A (en) | 1951-03-30 | 1952-03-19 | Improvements in or relating to textile sizes |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US218558A US2694021A (en) | 1951-03-30 | 1951-03-30 | Textile bearing a starch size |
Publications (1)
Publication Number | Publication Date |
---|---|
US2694021A true US2694021A (en) | 1954-11-09 |
Family
ID=22815572
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US218558A Expired - Lifetime US2694021A (en) | 1951-03-30 | 1951-03-30 | Textile bearing a starch size |
Country Status (4)
Country | Link |
---|---|
US (1) | US2694021A (xx) |
BE (1) | BE510131A (xx) |
FR (1) | FR1052555A (xx) |
GB (1) | GB731260A (xx) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2826506A (en) * | 1952-12-05 | 1958-03-11 | Davies Young Soap Company | Composition for treating fibrous materials |
US3066383A (en) * | 1957-02-14 | 1962-12-04 | Owens Corning Fiberglass Corp | Finish for staple glass fibers and yarns manufactured thereof |
US4169062A (en) * | 1977-05-12 | 1979-09-25 | Southern Sizing Co. | Random copolymers of polyoxyethylene polyoxypropylene glycol monoester, process of making the same and textile fiber containing the same |
US4640946A (en) * | 1984-08-20 | 1987-02-03 | E. I. Du Pont De Nemours And Company | Polyvinyl alcohol based wax-free size composition |
US5334639A (en) * | 1992-01-30 | 1994-08-02 | Ppg Industries, Inc. | Starch oil sizing composition and glass fibers treated therewith |
EP0905301A1 (de) * | 1997-09-02 | 1999-03-31 | Chimitex S.A.R.L. | Schlichte für das Niedertemperatur-Schlichtsystem |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL113407C (xx) * | 1957-02-20 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1311964A (en) * | 1919-08-05 | Venor | ||
US1970578A (en) * | 1930-11-29 | 1934-08-21 | Ig Farbenindustrie Ag | Assistants for the textile and related industries |
US2103205A (en) * | 1935-10-19 | 1937-12-21 | Emery Industries Inc | Art of shrinking fabrics |
US2174760A (en) * | 1934-04-19 | 1939-10-03 | Ig Farbenindustrie Ag | Condensation products derived from carboxylic acids and method of producing them |
US2359750A (en) * | 1941-04-19 | 1944-10-10 | American Viscose Corp | Viscose spinning solution |
-
0
- BE BE510131D patent/BE510131A/xx unknown
-
1951
- 1951-03-30 US US218558A patent/US2694021A/en not_active Expired - Lifetime
-
1952
- 1952-03-18 FR FR1052555D patent/FR1052555A/fr not_active Expired
- 1952-03-19 GB GB7072/52A patent/GB731260A/en not_active Expired
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1311964A (en) * | 1919-08-05 | Venor | ||
US1970578A (en) * | 1930-11-29 | 1934-08-21 | Ig Farbenindustrie Ag | Assistants for the textile and related industries |
US2174760A (en) * | 1934-04-19 | 1939-10-03 | Ig Farbenindustrie Ag | Condensation products derived from carboxylic acids and method of producing them |
US2103205A (en) * | 1935-10-19 | 1937-12-21 | Emery Industries Inc | Art of shrinking fabrics |
US2359750A (en) * | 1941-04-19 | 1944-10-10 | American Viscose Corp | Viscose spinning solution |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2826506A (en) * | 1952-12-05 | 1958-03-11 | Davies Young Soap Company | Composition for treating fibrous materials |
US3066383A (en) * | 1957-02-14 | 1962-12-04 | Owens Corning Fiberglass Corp | Finish for staple glass fibers and yarns manufactured thereof |
US4169062A (en) * | 1977-05-12 | 1979-09-25 | Southern Sizing Co. | Random copolymers of polyoxyethylene polyoxypropylene glycol monoester, process of making the same and textile fiber containing the same |
US4640946A (en) * | 1984-08-20 | 1987-02-03 | E. I. Du Pont De Nemours And Company | Polyvinyl alcohol based wax-free size composition |
US5334639A (en) * | 1992-01-30 | 1994-08-02 | Ppg Industries, Inc. | Starch oil sizing composition and glass fibers treated therewith |
EP0905301A1 (de) * | 1997-09-02 | 1999-03-31 | Chimitex S.A.R.L. | Schlichte für das Niedertemperatur-Schlichtsystem |
Also Published As
Publication number | Publication date |
---|---|
BE510131A (xx) | |
FR1052555A (fr) | 1954-01-26 |
GB731260A (en) | 1955-06-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3472825A (en) | Alkali metal salts of ethylene-acrylic acid interpolymers | |
US2807865A (en) | Sized textile and method of fabricating yarn into fabric | |
US2838455A (en) | Textiles and conditioning compositions therefor | |
US2826514A (en) | Treatment of textile materials and composition therefor | |
US2694021A (en) | Textile bearing a starch size | |
EP0198291B1 (en) | Textile warp size | |
US2717842A (en) | Antistatic treatment and treated products | |
US3634295A (en) | Textile sizing composition | |
US1709662A (en) | Process of degumming | |
US3519477A (en) | Sizing cellulosic and acrylic staple fiber yarns with acrylonitrile/acrylic acid copolymer | |
US2142688A (en) | Artificial silk fabric | |
JPS61124683A (ja) | 織糸用のサイジング方法 | |
US2845689A (en) | Warp size containing dicyandiamide and a polyacrylate salt | |
US3711323A (en) | Textile size | |
US2909447A (en) | Process of treating textile yarns | |
US2343308A (en) | Textile fiber and method of producing | |
US2348552A (en) | Textile fiber and method of producing | |
US2570830A (en) | Method of sizing textile warp yarns | |
US4167485A (en) | Water-soluble alkaline earth metal salts of polymers of acrylic acid, and their use as sizes | |
US4859509A (en) | Textile warp size | |
US2484545A (en) | Shrinkage control of cellulosic fibers | |
US2499477A (en) | Vinyl resin textile article | |
US2244704A (en) | Sizing of textile materials | |
US5397633A (en) | Process for sizing spun cotton yarns | |
US2646412A (en) | Textile size comprising an aqueous solution of urea and a poly alphaalkyl acrylic acid or a partial salt thereof |