US2635974A - Decorating strip with heat activated adhesive - Google Patents

Decorating strip with heat activated adhesive Download PDF

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Publication number
US2635974A
US2635974A US127306A US12730649A US2635974A US 2635974 A US2635974 A US 2635974A US 127306 A US127306 A US 127306A US 12730649 A US12730649 A US 12730649A US 2635974 A US2635974 A US 2635974A
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US
United States
Prior art keywords
carrier
heat activated
edges
decorative
adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US127306A
Inventor
Samuel M Terry
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Publishing Co
US Playing Card Co
Original Assignee
National Publishing Co
US Playing Card Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Publishing Co, US Playing Card Co filed Critical National Publishing Co
Priority to US127306A priority Critical patent/US2635974A/en
Application granted granted Critical
Publication of US2635974A publication Critical patent/US2635974A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/35Heat-activated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31678Of metal
    • Y10T428/31681Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31678Of metal
    • Y10T428/31714Next to natural gum, natural oil, rosin, lac or wax
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31801Of wax or waxy material
    • Y10T428/31804Next to cellulosic

Definitions

  • This invention pertains to a carrier-backed decorating material, and more particularly to a carrier-backed decorating material having incorporated therewith a heat activated adhesive.
  • a carrier,- backing ill of suitable material such as plastic, cellulose acetate, cellophane, or the like has applied thereto a film or coating of release material II.
  • This film ofarelease material may be applied in a variety of ways, vacuum evaporation being a very satisfactory method.
  • the only requirements for the backing strip are thatit be fiexiblahavea smoothsurface and be substantially non-elastic.
  • Alkali halide salts such as potassium bromide (KBr), potassium iodide (KI), and waxes are good release materials.
  • a film or coating of decorative material [2, such as gold, silver, aluminum, brass, or other material is then applied to the release material. This may also be applied by vacuum evaporation. Thereafter a heat activated adhesive I3 is applied to the decorative material.
  • the primary requisites for an adhesive are that it be stronger than the release material, so that when the carrier is stripped from the decorative film, the decorative film will remain attached to the adhesive, and that the adhesive be not rubbery or elastic.
  • the second requirement is essential in the case of book page edges or card edges.
  • the adhesive must be of such a nature that, while fixably securing the decorative film to each individual sheet edge, it will still fracture or separate along lines of strain.
  • the decorative film should also separate so that the edges of the book sheets or cards will be decorated in such a manner as to present a continuously decorated surface when the book sheets or card edges are realigned in side-by-side relation.
  • Polyamide adhesives formed from ethylene diamine and dimerized, trimerized linoleic and linolenic acids have proven very successful as heat activated adhesives.
  • This type of polyamide, used singly, or mixed with other resins, may be applied to the decorative film by brushing, dipping, spraying, or any other satisfactory means.
  • the carrier-backed decorative strip having the adhesive incorporated therewith, is merely placed with the adhesive side down on a prepared surface, such as a fiat leather surface, or the 3 smooth surface formed by the edges of playin cards or book leaves assembled in side-by-side relation. Thereafter, heat, or heat and pressure, is applied tothecarrier side of the-carrier-backed decorative material and the carrier is then removed, leaving the decorative foil firmly adhered to the prepared surface.
  • a prepared surface such as a fiat leather surface, or the 3 smooth surface formed by the edges of playin cards or book leaves assembled in side-by-side relation.
  • heat, or heat and pressure is applied tothecarrier side of the-carrier-backed decorative material and the carrier is then removed, leaving the decorative foil firmly adhered to the prepared surface.
  • the leaves. oncards may then be rifiled and separated, and when-re'alinged will present a continuously decorated surface.
  • Playing cards usually have ashellac or shellac and wax surface.
  • the heat-'usedin activating the polyamide adhesive in the case .of playing cards therefore must be carefully :controlled. Only enough heat should be used to activate the adhesive, and not enough detrimentally to affect the surface of the p1aying-ca'rds.
  • Carrier-backed decorative strips having polyamide type adhesives are ideally suited for the edge gliding of booksysince water soluble or organic :solvent type adhesives may deleteriously affect book sheets.

Description

April 21, 1953 s, TERRY 2,6355974- DECORATING STRIP WITH HEAT ACTIVATED ADHESIVE Fi led Nov. 15, 1949 IN VEN TOR. Samuel M. Terry By r- #4 AGENTS.
Patented Apr. 21, u 1953 DECORATING s'rmr WITH HEAT ACTIVATED ADHESIVE Samuel M. Terry, Columbus, Ohio, assignor, by mesne assignments, to The United States-Play-v ing Card Company, Cincinnati, Ohio, at corpo-; ration of Ohio, and National Publishing Company, Philadelphia, P
sylvania a., acorporation of Penn Application'November 15, i949, Serial No. 127,306
This invention pertains to a carrier-backed decorating material, and more particularly to a carrier-backed decorating material having incorporated therewith a heat activated adhesive.
It was originally the practice to decorate fiat surfaces or the edges of book sheets, playing cards or the like with a thin metallic. leaf, such as gold, silver or the like, by first cleaning and otherwise preparing the surface, applying an ad- 'hesive thereto, .and then applying the unsup.
ported leaf to the adhesively treated surface. If desired, pressure or heat and pressure were used. This is a tedious, time-consuming andcostly job and requires specially trained and skilled workmen. Such practice is still followed in the decorating of the edges of book sheets and cards in particular, and to a great extent in decorating and/or embossing other items. Unsuccessful attempts have been made to facilitate the application of such decorative metal foil to the edges of book sheets, playing cards, or the like, by providing a carrier-backing strip to which the foil is held by a release material, the carrier-backed foil being applied to a continuously adhesively treated surface, and fixed thereto by pressure or heat and pressure, and the carrier-backing then stripped or peeled from the foil, leaving that surface of the foil adjacent the carrierbacking exposed.
From the foregoing it should be apparent that the decoration of fiat surfaces, the edges of playing cards, or book sheets with a metallic foil has been an expensive and time-consuming procedure. It is therefore one object of this invention to provide a material for decorating the edges of book sheets, playing cards, or the like, and other surfaces, in a relatively simple and substantially inexpensive manner such as to eliminate the expensive and time-consuming operations heretofore necessary.
It is another object of this invention to provide a carrier-backed decorative foil having a heat activated adhesive incorporated therewith adaptable to the decoration of the edges of book sheets, playing cards or the like.
It is a further object of this invention to provide a material for decorating the edges of book sheets, playing cards, or the like, which is simple to use, inexpensive, and which will permit the decoration of at least one entire side edge of a group of book sheets, playing cards, or the like, assembled en masse, all in one operation.
Various other objects and advantageous features of the invention may be had from the following description, when read in conjunction with the following drawing, which is a fragmentary perspective view showing a carrier-backed decorative strip, the individualparts being exaggerated in size for purposes of clarity.
In accordance with this. invention, a carrier,- backing ill of suitable material such as plastic, cellulose acetate, cellophane, or the like has applied thereto a film or coating of release material II. This film ofarelease material may be applied in a variety of ways, vacuum evaporation being a very satisfactory method. The only requirements for the backing strip are thatit be fiexiblahavea smoothsurface and be substantially non-elastic. Alkali halide salts such as potassium bromide (KBr), potassium iodide (KI), and waxes are good release materials. Having had a film or coating of release material ll applied to said carrier, a film or coating of decorative material [2, such as gold, silver, aluminum, brass, or other material is then applied to the release material. This may also be applied by vacuum evaporation. Thereafter a heat activated adhesive I3 is applied to the decorative material.
The primary requisites for an adhesive are that it be stronger than the release material, so that when the carrier is stripped from the decorative film, the decorative film will remain attached to the adhesive, and that the adhesive be not rubbery or elastic. The second requirement is essential in the case of book page edges or card edges. In this latter case, the adhesive must be of such a nature that, while fixably securing the decorative film to each individual sheet edge, it will still fracture or separate along lines of strain. For example, when the leaves of a book or individual cards are separated the decorative film should also separate so that the edges of the book sheets or cards will be decorated in such a manner as to present a continuously decorated surface when the book sheets or card edges are realigned in side-by-side relation.
Polyamide adhesives formed from ethylene diamine and dimerized, trimerized linoleic and linolenic acids have proven very successful as heat activated adhesives. This type of polyamide, used singly, or mixed with other resins, may be applied to the decorative film by brushing, dipping, spraying, or any other satisfactory means.
In using this novel carrier-backed decorative film, the carrier-backed decorative strip, having the adhesive incorporated therewith, is merely placed with the adhesive side down on a prepared surface, such as a fiat leather surface, or the 3 smooth surface formed by the edges of playin cards or book leaves assembled in side-by-side relation. Thereafter, heat, or heat and pressure, is applied tothecarrier side of the-carrier-backed decorative material and the carrier is then removed, leaving the decorative foil firmly adhered to the prepared surface. In the case of playing cards or book leaves, the leaves. oncards may then be rifiled and separated, and when-re'alinged will present a continuously decorated surface.
Playing cards usually have ashellac or shellac and wax surface. The heat-'usedin activating the polyamide adhesive in the case .of playing cards therefore must be carefully :controlled. Only enough heat should be used to activate the adhesive, and not enough detrimentally to affect the surface of the p1aying-ca'rds.
Carrier-backed decorative strips having polyamide type adhesives are ideally suited for the edge gliding of booksysince water soluble or organic :solvent type adhesives may deleteriously affect book sheets.
It should be apparent from the above description that there has'b'een' devised a novel and extremely useful-carrier-backed decorative strip having incorporated therewith a heat activated like.
' While this inventionhas been described inits preferred 'embo'dimentdt is-to be understood that the words that have been used are words of description rather than of limitation, and that changes within the purview of the appended claim may be made without departing from the true scope and-spirit of the invention.
What is claimed is: A carrier-backed decorative material characterized by itsability, upon application to a surface formed from the edges of a plurality of relatively thin sheets and release or the backing portion; to 'maintain a decorative film on each individual sheetsedge yet fracture uniformly upon separation 0f=such sheet edges, and comprising a carrier backing, a release material directly bonded to'saidjcarrier backing, a film of metallic decorative material directly bonded to said release material.andapolyamide adhesive, formed from ethylene diamine and dimerized, trimerized,
linoleic' and linolenic acids, directly bonded to said film of decorativematerial.
SAMUEL M.. TERRY.
References" Cited in .the file of this patent UNITED-STATES PATENTS
US127306A 1949-11-15 1949-11-15 Decorating strip with heat activated adhesive Expired - Lifetime US2635974A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2964867A (en) * 1957-12-18 1960-12-20 Lewis A Kingsley Imprinting of perfluorocarbon polymers
US2970076A (en) * 1957-01-14 1961-01-31 Meyercord Co Vitreous decalcomania and method of decorating ceramic articles
US3043732A (en) * 1957-01-02 1962-07-10 Dennison Mfg Co Top label surprinting
US3235395A (en) * 1962-03-27 1966-02-15 Walter G Scharf Transfers for metallic coatings
US3340121A (en) * 1963-12-20 1967-09-05 Carl F Lawrenz Method of applying decorative coatings to metal parts
US3396180A (en) * 1964-01-31 1968-08-06 Gen Mills Inc Polyamide resin compositions of ethylene-diamine and fractionated polymeric fat acids
DE2043692A1 (en) * 1969-09-19 1971-04-01 Polymark Ltd , London Process for permanent labeling of flexible objects, especially textiles and heat sealable labels
US3870539A (en) * 1971-10-06 1975-03-11 Noridem Sa Temporary printing carriers
US3926707A (en) * 1971-08-04 1975-12-16 Noridem Sa Use of temporary printing carriers

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1515722A (en) * 1924-05-13 1924-11-18 Peerless Roll Leaf Co Inc Transfer metallized medium
US1974883A (en) * 1933-06-29 1934-09-25 Swift & Sons Inc M Manufacture of gold leaf carrier
US2017367A (en) * 1934-02-01 1935-10-15 Kurz Konrad Method of producing an embossing foil by providing a support adapted to be embossed with a mirror coating
US2099641A (en) * 1933-02-06 1937-11-16 Bach Stefan Gold leaf substitute
US2191367A (en) * 1937-02-15 1940-02-20 E I Du Point De Nemours & Comp Laminated product
US2279774A (en) * 1938-09-29 1942-04-14 Du Pont Coated product
US2426462A (en) * 1944-06-07 1947-08-26 Merle Hughey Decalcomania manufacture

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1515722A (en) * 1924-05-13 1924-11-18 Peerless Roll Leaf Co Inc Transfer metallized medium
US2099641A (en) * 1933-02-06 1937-11-16 Bach Stefan Gold leaf substitute
US1974883A (en) * 1933-06-29 1934-09-25 Swift & Sons Inc M Manufacture of gold leaf carrier
US2017367A (en) * 1934-02-01 1935-10-15 Kurz Konrad Method of producing an embossing foil by providing a support adapted to be embossed with a mirror coating
US2191367A (en) * 1937-02-15 1940-02-20 E I Du Point De Nemours & Comp Laminated product
US2279774A (en) * 1938-09-29 1942-04-14 Du Pont Coated product
US2426462A (en) * 1944-06-07 1947-08-26 Merle Hughey Decalcomania manufacture

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3043732A (en) * 1957-01-02 1962-07-10 Dennison Mfg Co Top label surprinting
US2970076A (en) * 1957-01-14 1961-01-31 Meyercord Co Vitreous decalcomania and method of decorating ceramic articles
US2964867A (en) * 1957-12-18 1960-12-20 Lewis A Kingsley Imprinting of perfluorocarbon polymers
US3235395A (en) * 1962-03-27 1966-02-15 Walter G Scharf Transfers for metallic coatings
US3340121A (en) * 1963-12-20 1967-09-05 Carl F Lawrenz Method of applying decorative coatings to metal parts
US3396180A (en) * 1964-01-31 1968-08-06 Gen Mills Inc Polyamide resin compositions of ethylene-diamine and fractionated polymeric fat acids
DE2043692A1 (en) * 1969-09-19 1971-04-01 Polymark Ltd , London Process for permanent labeling of flexible objects, especially textiles and heat sealable labels
US3926707A (en) * 1971-08-04 1975-12-16 Noridem Sa Use of temporary printing carriers
US3870539A (en) * 1971-10-06 1975-03-11 Noridem Sa Temporary printing carriers

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