US2593010A - Asbestos roofing felt and method of manufacture - Google Patents

Asbestos roofing felt and method of manufacture Download PDF

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US2593010A
US2593010A US63470A US6347048A US2593010A US 2593010 A US2593010 A US 2593010A US 63470 A US63470 A US 63470A US 6347048 A US6347048 A US 6347048A US 2593010 A US2593010 A US 2593010A
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sheet
asbestos
stearic acid
ply
felt
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George W Clarvoe
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Johns Manville Corp
Johns Manville
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B30/00Compositions for artificial stone, not containing binders
    • C04B30/02Compositions for artificial stone, not containing binders containing fibrous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • D06M7/005Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins made of asbestos
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249987With nonvoid component of specified composition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31652Of asbestos
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/50FELT FABRIC

Definitions

  • This invention relates to. flexible "and waterproof roofing felts, and is particularly concerned with asbestos roofing felts which are weather resistant, white and light reflecting, and to a method 'of manufacturing the same.
  • Anobject of the invention is to provide a weather resistant asbestos roofing felt the ex-- posed surface of which is white in color and light reflecting.
  • a further object is to provide a multi-ply as bestos roofing felt which is weatherproof and which is sufficiently flexible to be shipped in rolls and to be applied to a roof by conventional methods.
  • a feature of the invention is a flexible multiply asbestos roofing felt in which the base plies are asphalt saturated, and having a facing ply consisting of white relatively porous weather and stain resistant asbestos paper which is stronglyadhered to the base plies.
  • Another object is to provide a treatment for a white asbestos paper roofing felt which will impart thereto suitable waterproofing properties, flexibility, strong adhesiveness to asphalt, and resistance to staining by asphalt.
  • the invention consists in the improved flexible light-reflective roofing felt and method of manufacturo'which are hereinafter described and more particularly defined by the accompanying claims.
  • the principal novel element of the illustrated roofing felt consists of awhite comparatively porous unsaturated sheet Ill of asbestosaper contains a small amount or stearic' acid uniformly distributed in thin films throughout the pores. and. on the fibers of the sheet in amount sufilcienaiito render the sheet water repellent, resistant to staining by as halt oils in contact therewith, and resistant to deterioration or ex-- conventional plying methods. strongly plied product it maybe necessary to foliation under prolonged exposure to the weather.
  • a sheet of white asbestos paper of suitable width and length for rolling up and handling as roll roofing is impregnated with a solvent solution of stearic acid, followed by heat drying to remove the solvent.
  • the impregnatin solution may comprise stearic acid in anyone of a number of solvents such as benzol, gasoline, alcohol or carbon tetrachloride.
  • the strength of the impregnating solution may range between say 0.5% and 10% or higher.
  • a satisfactory impregnating solution has been found to comprise about 2% by weight of stearic acid dissolved in carbon tetrachloride.
  • the impregnating solution may be applied to the dry white asbestos paper sheet at normal temperature by any one of a number of conventional methods, such as by applicator rolls, spraying, or dipping the sheet in a bath of the solvent reduced stearic acid.
  • Alternative methods of introducing stearic acid into the paper sheet may include impregnation of the previously formed paper with an aqueous' dispersion of stearic acid, or by adding an aqueous dispersion of stearic acid to the asbestos fiber furnished during the paper manufacturing operation.
  • the treatment with stearic acid.- may' be followed by drying by means of heated rolls, or in a conventional drier or oven.
  • the dried sheet H1 thus treated cohtains only a small proper tion by weight (normally between 0.5% and 10%) ofstdi'ic acid distributed in thin films within prepares and on the surfaces of the fibers throughout the sheet.
  • the sheet thus formed is sufficiently water repellent and weather resistant, and has sufficient flexibility and strength, as to adapt it for use as a roofing felt.
  • a suitable procedure is as followsi
  • the dried stearic acid containing sheet In is applied as a fading sheet to underlying single or mutiple ply felts l2 of asphalt saturated paper, and a strongly plied felt is formed by passing the plied sheets through heated press rolls or by other To develop a first coatthe upper surface of the asphalt saturated base sheets 2 with an additional thin jcoa ng' of asphalt or equivalent waterproofing adhesive, before applying the facing sheet [0,
  • the plied product is to be rolled it is delying plies 12 of asphalt saturated paper.
  • a white relatively porous asbestos paper facing sheet which has distributed therethrough a small proportion of stearic acid develops a strong adhesive bond when plied to underlying asphalt saturated sheets.
  • the presence of the stearic acid tends to enhance the adhesion of the asphalt to the asbestos.
  • Stearic acid is a polar compound and is particularly effective because it has a molecule with water Wetting properties on one end and asphalt or oil Wetting properties on the other. Hence the stearic acid acts to adhere the water wetted asbestos to the organophilic asphalt.
  • the stearic acid also imparts suitably permanent water-proofness to the facing sheet and renders such sheet resistant against staining by asphalt present as a saturant in or coating on the under-
  • the presence of a small amount of stearic acid in the facing sheet 19 also imparts thereto strong resistance against exfoliation or deterioration by prolonged weather exposure.
  • the weathering properties imparted by stearic acid are in part the result of its tendency to react with free alkali present in the asbestos and to thus form a metallic soap interface.
  • the product continues to exhibit weather resistance because of the waterproofing properties of insoluble magnesium or calcium stearates thus formed.
  • a white and relatively porous asbestos fiber roofing felt having uniformly distributed therethrough between 0.5% and 10% by weight of stearic acid in the form of thin fiber coating films,
  • said stearic acid imparting good weathering properties, resistance to exfoliation, and resistance to staining.
  • a light reflecting roofing felt comprising a sheet of white asbestos paper having stearic acid distributed throughout pores thereof in the form of thin fiber coating films in amount ranging from to 10% by weight of the paper.
  • a multi-ply flexible roofing felt having as its base member an asphalt saturated asbestos fiber felt, and having a top surface ply comprising comparatively white unsaturated asbestos paper having uniformly distributed throughout the pores thereof between 0.5% and 10% by weight of stearic acid in the form of thin fiber coating films, said stearic acid imparting water repellent and non-staining properties to the top ply and strengthening the bond between the top and base plies.
  • a light reflecting flexible roofing felt comprising a base sheet of asphalt saturated fiber felt and a top surface sheet of white asbestos paper adhered by asphalt adhesive to the base sheet to form a flexible multi-ply felt, said paper surface ply incorporating stearic acid in the form of thin fiber coating films throughout its porous structure in amount comprising to 10% by weight of the paper sheet.
  • a light reflecting waterproof roofing felt comprising, distributing stearic acid in amount ranging between 0.5% and 10% by weight, while diluted with a volatile liquid, throughout a sheet of white asbestos paper and subjecting said sheet to a heat drying treatment to eliminate volatile material and precipitate stearic acid in film form.
  • step 6 comprising, distributing stearic acid in amount ranging between 0.5% and 10% by weight, while diluted with a volatile liquid, throughout white asbestos paper, heat drying the paper to drive off volatiles, and by pressure adhering the thus waterproofed paper as a top surface ply to a base sheet of asphalt saturated roofing felt.
  • a multi-ply asbestos roofing felt the steps comprising, saturating base plies with an adhesive bituminous waterproofing saturant, saturating a surface ply of comparatively white porous asbestos paper with stearic' acid diluted with a volatile liquid, drying the thus saturated surface ply to drive off volatiles, applying the dry surface ply as a facing to the saturated base plies and consolidating under pressure to develop adhesion, and moistening the facing sheet of the thus plied felt with an aqueous alcohol solution prior to stretching the sheet in forming a multiple ply roll thereof.
  • a roll of light reflecting multiple ply asbestos roofing felt the steps which comprise, moistening a facing sheet of stearic acid containing white asbestos paper with an aqueous alcohol solution after adhering said sheet by pressure as a facing to a base ply sheet of asphalt saturated fibrous roofing felt, and rolling the plied felt.
  • a light reflecting flexible roofing felt comprising a base sheet of bitumen saturated fiber felt and a top surface sheet of white asbestos paper adhered by bituminous adhesive to the base sheet to form a flexible multi-ply felt, said paper surface ply incorporating stearic acid in the form of thin coating films throughout its porous struc ture in amount comprising to 10% byweight of the paper sheet.

Description

April 15, 1952 G. w. CLARVOE 2,593,010
ASBESTOS ROOFING FELT AND METHOD OF MANUFACTURE Filed Dec. 4, 1948 INVENTOR m= 6242/06.
ATTORNEY Patented Apr. 15, 1952 2,593,91 OFFICE ASBESTOS ROOFING FELT AND METHO OF MANUFACTURE George W. Clarvoe, Somerville, N. L, assignor to JbhhS-Mitifilille Corporation, New York, N. Y., a corporation of New York Application December 4, 1948, Serial No. 83,470
9 Claims. (Cl. 154-142) This invention relates to. flexible "and waterproof roofing felts, and is particularly concerned with asbestos roofing felts which are weather resistant, white and light reflecting, and to a method 'of manufacturing the same.
Anobject of the invention is to provide a weather resistant asbestos roofing felt the ex-- posed surface of which is white in color and light reflecting.
A further object is to provide a multi-ply as bestos roofing felt which is weatherproof and which is sufficiently flexible to be shipped in rolls and to be applied to a roof by conventional methods.
A feature of the invention is a flexible multiply asbestos roofing felt in which the base plies are asphalt saturated, and having a facing ply consisting of white relatively porous weather and stain resistant asbestos paper which is stronglyadhered to the base plies.
Attempts heretofore made to ply an unsaturated asbestos paper facing sheet to a base felt of asphalt saturated asbestos after impregnating the facin sheet with insoluble silicates such as calcium silicate or zinc silicate, have encoun teredmdifiiculties because such silicates tend to preventl strong adhesion of asphalt to asbestos and fail. to prevent staining of the white asbestos facing sheet by asphaltic oils intheplied product. Furthermore silicatesof the type of zinc silicate tend to impart brittleness to asbest-os sheets treated therewith and do not impart suitable waterproof properties when used in the limited amounts permissible when it is desired to retain some measure of flexibility.
Another object is to provide a treatment for a white asbestos paper roofing felt which will impart thereto suitable waterproofing properties, flexibility, strong adhesiveness to asphalt, and resistance to staining by asphalt.
With the aforesaid objects and feature in view the invention consists in the improved flexible light-reflective roofing felt and method of manufacturo'which are hereinafter described and more particularly defined by the accompanying claims.
In ,the following description reference will be made to'the attached drawing, which presents a perspective view of" a roll of multi-ply roofing felt in accordance with the present invention, showing' o'ne' end of the felt unrolled and with a corner of the white asbestos" paper facing sheet torn away from the base sheet to show the ply construction. J
The principal novel element of the illustrated roofing felt consists of awhite comparatively porous unsaturated sheet Ill of asbestosaper contains a small amount or stearic' acid uniformly distributed in thin films throughout the pores. and. on the fibers of the sheet in amount sufilcienaiito render the sheet water repellent, resistant to staining by as halt oils in contact therewith, and resistant to deterioration or ex-- conventional plying methods. strongly plied product it maybe necessary to foliation under prolonged exposure to the weather.
According to a preferred method of manufacture, a sheet of white asbestos paper of suitable width and length for rolling up and handling as roll roofing, is impregnated with a solvent solution of stearic acid, followed by heat drying to remove the solvent. The impregnatin solution may comprise stearic acid in anyone of a number of solvents such as benzol, gasoline, alcohol or carbon tetrachloride. The strength of the impregnating solution may range between say 0.5% and 10% or higher. A satisfactory impregnating solution has been found to comprise about 2% by weight of stearic acid dissolved in carbon tetrachloride. The impregnating solution may be applied to the dry white asbestos paper sheet at normal temperature by any one of a number of conventional methods, such as by applicator rolls, spraying, or dipping the sheet in a bath of the solvent reduced stearic acid.
Alternative methods of introducing stearic acid into the paper sheet may include impregnation of the previously formed paper with an aqueous' dispersion of stearic acid, or by adding an aqueous dispersion of stearic acid to the asbestos fiber furnished during the paper manufacturing operation.
The treatment with stearic acid.- may' be followed by drying by means of heated rolls, or in a conventional drier or oven. The dried sheet H1 thus treated cohtains only a small proper tion by weight (normally between 0.5% and 10%) ofstdi'ic acid distributed in thin films within prepares and on the surfaces of the fibers throughout the sheet. The sheet thus formed is sufficiently water repellent and weather resistant, and has sufficient flexibility and strength, as to adapt it for use as a roofing felt. Normally, however, it is contemmated that such sheet shall serve as the top facing sheet of a inul'ti-ply; rc'io'fing felt such as inustrated in which the hasepiies consist of asphalt saturated roofiiig felts as,- for example, asphalt saturated asbestos paper.
In assembling a plied roofing felt having a steari acid treated white asbestor paper facihg'; a suitable procedure is as followsi The dried stearic acid containing sheet In is applied as a fading sheet to underlying single or mutiple ply felts l2 of asphalt saturated paper, and a strongly plied felt is formed by passing the plied sheets through heated press rolls or by other To develop a first coatthe upper surface of the asphalt saturated base sheets 2 with an additional thin jcoa ng' of asphalt or equivalent waterproofing adhesive, before applying the facing sheet [0,
order to provide an adequate'amountof binder at the interface between the two felts.
If the plied product is to be rolled it is delying plies 12 of asphalt saturated paper.
sirable to wet the stearic acid containing sheet with an aqueous solution of alcohol after it has been plied as a facing sheet to the underlying sheets. This alcohol wetting treatment'is not necessary where the plied sheets are to be cut to final form for application as roofing, without being rolled. Wetting of the facing sheet with the aqueous alcohol solution (for example a solution of 50% ethyl alcohol and 50% water), after plying, serves to temporarily overcome or reduce the waterproofing properties of the stearic acid to an extent which allows the white facing sheet to stretch sufficiently to permit rolling of the assembled plied product Without any serious danger of rupturing the facing sheet. i
A white relatively porous asbestos paper facing sheet which has distributed therethrough a small proportion of stearic acid develops a strong adhesive bond when plied to underlying asphalt saturated sheets. The presence of the stearic acid tends to enhance the adhesion of the asphalt to the asbestos. Stearic acid is a polar compound and is particularly effective because it has a molecule with water Wetting properties on one end and asphalt or oil Wetting properties on the other. Hence the stearic acid acts to adhere the water wetted asbestos to the organophilic asphalt. The stearic acid also imparts suitably permanent water-proofness to the facing sheet and renders such sheet resistant against staining by asphalt present as a saturant in or coating on the under- The presence of a small amount of stearic acid in the facing sheet 19 also imparts thereto strong resistance against exfoliation or deterioration by prolonged weather exposure. The weathering properties imparted by stearic acid are in part the result of its tendency to react with free alkali present in the asbestos and to thus form a metallic soap interface. Thus, even though there may be gradual displacement of stearic acid as a result of weathering, the product continues to exhibit weather resistance because of the waterproofing properties of insoluble magnesium or calcium stearates thus formed.
The invention which has been thus described by detailed example is not limited as to such de- 1 tails and it is to be understood that variations, changes and modifications are contemplated within the scope of the invention as defined by the following claims.
What I claim is:
l. A white and relatively porous asbestos fiber roofing felt having uniformly distributed therethrough between 0.5% and 10% by weight of stearic acid in the form of thin fiber coating films,
said stearic acid imparting good weathering properties, resistance to exfoliation, and resistance to staining.
2. A light reflecting roofing felt comprising a sheet of white asbestos paper having stearic acid distributed throughout pores thereof in the form of thin fiber coating films in amount ranging from to 10% by weight of the paper.
3. A multi-ply flexible roofing felt having as its base member an asphalt saturated asbestos fiber felt, and having a top surface ply comprising comparatively white unsaturated asbestos paper having uniformly distributed throughout the pores thereof between 0.5% and 10% by weight of stearic acid in the form of thin fiber coating films, said stearic acid imparting water repellent and non-staining properties to the top ply and strengthening the bond between the top and base plies.
4. A light reflecting flexible roofing felt comprising a base sheet of asphalt saturated fiber felt and a top surface sheet of white asbestos paper adhered by asphalt adhesive to the base sheet to form a flexible multi-ply felt, said paper surface ply incorporating stearic acid in the form of thin fiber coating films throughout its porous structure in amount comprising to 10% by weight of the paper sheet.
5. In manufacturing a light reflecting waterproof roofing felt the steps comprising, distributing stearic acid in amount ranging between 0.5% and 10% by weight, while diluted with a volatile liquid, throughout a sheet of white asbestos paper and subjecting said sheet to a heat drying treatment to eliminate volatile material and precipitate stearic acid in film form.
6. In manufacturing light reflecting waterproof and flexible roofing felt the steps comprising, distributing stearic acid in amount ranging between 0.5% and 10% by weight, while diluted with a volatile liquid, throughout white asbestos paper, heat drying the paper to drive off volatiles, and by pressure adhering the thus waterproofed paper as a top surface ply to a base sheet of asphalt saturated roofing felt.
7. In manufacturing a multi-ply asbestos roofing felt the steps comprising, saturating base plies with an adhesive bituminous waterproofing saturant, saturating a surface ply of comparatively white porous asbestos paper with stearic' acid diluted with a volatile liquid, drying the thus saturated surface ply to drive off volatiles, applying the dry surface ply as a facing to the saturated base plies and consolidating under pressure to develop adhesion, and moistening the facing sheet of the thus plied felt with an aqueous alcohol solution prior to stretching the sheet in forming a multiple ply roll thereof.
8. In manufacturing a roll of light reflecting multiple ply asbestos roofing felt the steps which comprise, moistening a facing sheet of stearic acid containing white asbestos paper with an aqueous alcohol solution after adhering said sheet by pressure as a facing to a base ply sheet of asphalt saturated fibrous roofing felt, and rolling the plied felt. i
9. A light reflecting flexible roofing felt comprising a base sheet of bitumen saturated fiber felt and a top surface sheet of white asbestos paper adhered by bituminous adhesive to the base sheet to form a flexible multi-ply felt, said paper surface ply incorporating stearic acid in the form of thin coating films throughout its porous struc ture in amount comprising to 10% byweight of the paper sheet.
GEORGE W. CLARVOE.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS

Claims (1)

  1. 7. IN MANUFACTURING A MULTI-PLY ASBESTOS ROOFING FELT THE STEPS COMPRISING, SATURATING BASE PLIES WITH AN ADHESIVE BITUMINOUS WATERPROOFING SATURANT, SATURATING A SURFACE PLY OF COMPARATIVELY WHITE POROUS ABSESTOS PAPER WITH STEARIC ACID DILUTED WITH A VOLATILE LIQUID, DRYING THE THUS SATURATED SURFACE PLY TO DRIVE OFF VOLATILES, APPLYING THE DRY SURFACE PLY AS A FACING TO THE SATURATED BASE PLIES AND CONSLIDATING UNDER PRESSURE TO DEVELOIP ADHESION, AND MOISTENING THE FACING SHEET OF THE THUS PLIED FELT WITH AN AQUE-
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2868685A (en) * 1954-07-26 1959-01-13 Thilmany Pulp & Paper Company Paper and method of making same
US2977267A (en) * 1955-12-06 1961-03-28 Texaco Development Corp Packaging of tacky materials
US4422878A (en) * 1982-11-29 1983-12-27 Hercules Incorporated Asphalt compositions
US4492781A (en) * 1983-05-19 1985-01-08 Duszak Francis J Method and composition for maintaining and repairing asphalt-and rubber-containing surfaces

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US333138A (en) * 1885-12-29 Combination of asbestus board
US1261280A (en) * 1914-11-09 1918-04-02 Flintkote Co Fireproof roofing.
US1881435A (en) * 1921-09-06 1932-10-11 Carey Philip Mfg Co Adhering fabrics
US1958202A (en) * 1931-12-19 1934-05-08 Raybestos Manhattan Inc Method of making sizing material
US1983622A (en) * 1931-06-26 1934-12-11 Arden Box Toe Company Shoe stiffener and method of making the same
US2025486A (en) * 1933-07-18 1935-12-24 Victor Mfg & Gasket Co Impregnating material
US2068219A (en) * 1933-04-14 1937-01-19 Johns Manville Water-resistant product and method of making the same
US2068208A (en) * 1935-01-18 1937-01-19 Johns Manville Electrical insulation
US2107284A (en) * 1936-02-20 1938-02-08 Owens Illinois Glass Co Method and product for treating glass wool
US2296712A (en) * 1939-09-28 1942-09-22 Lion Oil Refining Company Laminated product
US2493845A (en) * 1945-07-02 1950-01-10 Johns Manville Method of waterproofing mineral wool

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US333138A (en) * 1885-12-29 Combination of asbestus board
US1261280A (en) * 1914-11-09 1918-04-02 Flintkote Co Fireproof roofing.
US1881435A (en) * 1921-09-06 1932-10-11 Carey Philip Mfg Co Adhering fabrics
US1983622A (en) * 1931-06-26 1934-12-11 Arden Box Toe Company Shoe stiffener and method of making the same
US1958202A (en) * 1931-12-19 1934-05-08 Raybestos Manhattan Inc Method of making sizing material
US2068219A (en) * 1933-04-14 1937-01-19 Johns Manville Water-resistant product and method of making the same
US2025486A (en) * 1933-07-18 1935-12-24 Victor Mfg & Gasket Co Impregnating material
US2068208A (en) * 1935-01-18 1937-01-19 Johns Manville Electrical insulation
US2107284A (en) * 1936-02-20 1938-02-08 Owens Illinois Glass Co Method and product for treating glass wool
US2296712A (en) * 1939-09-28 1942-09-22 Lion Oil Refining Company Laminated product
US2493845A (en) * 1945-07-02 1950-01-10 Johns Manville Method of waterproofing mineral wool

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2868685A (en) * 1954-07-26 1959-01-13 Thilmany Pulp & Paper Company Paper and method of making same
US2977267A (en) * 1955-12-06 1961-03-28 Texaco Development Corp Packaging of tacky materials
US4422878A (en) * 1982-11-29 1983-12-27 Hercules Incorporated Asphalt compositions
US4492781A (en) * 1983-05-19 1985-01-08 Duszak Francis J Method and composition for maintaining and repairing asphalt-and rubber-containing surfaces

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