US2559907A - Method for producing hydroxy cyclammonium quaternary salts - Google Patents

Method for producing hydroxy cyclammonium quaternary salts Download PDF

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US2559907A
US2559907A US18846A US1884648A US2559907A US 2559907 A US2559907 A US 2559907A US 18846 A US18846 A US 18846A US 1884648 A US1884648 A US 1884648A US 2559907 A US2559907 A US 2559907A
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cyclammonium
hydroxy
group
hydrobromic acid
quaternary salts
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Earl J Van Lare
Leslie G S Brooker
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Eastman Kodak Co
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Eastman Kodak Co
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Priority to FR1034559D priority patent/FR1034559A/fr
Priority to GB8929/49A priority patent/GB658560A/en
Priority to DEE2644A priority patent/DE882282C/de
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/02—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups
    • C09B23/06—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups three >CH- groups, e.g. carbocyanines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/04—Indoles; Hydrogenated indoles
    • C07D209/08—Indoles; Hydrogenated indoles with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to carbon atoms of the hetero ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
    • C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
    • C07D215/16—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D215/20—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
    • C07D277/84—Naphthothiazoles
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes

Definitions

  • This invention relates to method for producing hydroxy cyclammonium quaternary salts.
  • 5-, 6-, 7- and 8-hydroxyquinaldine are known and these can be quatermzed by heating with an alkyl salt, e. g. dimethyl sulfate.
  • an alkyl salt e. g. dimethyl sulfate.
  • the product is not pure hydroxyquinaldine methornethylsulfate, owing to some methylation of the hydroxyl group.
  • hydroxylepidines and hydroxy-2,3,3-trimethylindolenines are known and these can be quatermzed by heating with an alkyl salt, e. g. dimethyl sulfate.
  • Kiprianov et al. were forced to resort to treating the hydrochloride of 6 hydroxy 2 methylbenzothiazole with ethyl-p-toluenesulfonate which tends to contaminate the hydroxy quaternary salt owing to methylation of the hydroxyl group.
  • the alkobromides and the alkoiodides of quinaldines and of lepidines containing an alkoxyl group in the 5-, 6-, 7-- or 8-position can be hydrolyzed, in hydrobromic acid, to give the corresponding hydroxyl.
  • quaternary salt without the splitting out of alkyl halide.
  • an object of our invention to provide new hydroxy cyclammonium alkohalides.
  • a further object is to provide a process for preparing hydroxy cyclammonium quaternary salts free from contaminating alkoxy cyclammonium quaternary salts.
  • a still further object is to provide new hydroxy dyes free from com taminating alkoxy dyes. Still further objects will become apparent hereinafter.
  • hydroxy cyclammonium quaternary salts which are free from contaminating alkoxy cyclammonium quaternary salts by hydrolyzing, in hydrobromic acid, an alkoxy cyclammonium alkobromide or alkiodide selected from those represented by the following general formulas:
  • R1 represents an alkyl group, e. g. methyl, ethyl, npropyl, n-butyl, isobutyl, etc.
  • R1 represents an alkyl group, e. g. methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, etc.
  • R2 and R3 each represents a hydrogen atom or amethyl group, R2 and R3 always being diiierent
  • D represents an alkoxy-o-naphthylene group
  • X represents the bromide or the iodide anion.
  • the hydrobromic acid employed advantageously contains from 35 to 48 per cent by weight of hydrogen bromide, the remainder, of course, being water. Constant boiling hydrobromic acid, 1. e. the48 per cent, is most advantageously employed.
  • the hydrolysis is carried out most advantageously by refluxing the mixture of hydrobromic acid and alkoxy cyclammonium alkobromide or alkiodide. However, higher or lower temperatures canbe used, e. g. temperatures from to C.
  • the hydrolysis product is a hydroXy cyclammonium alkobromide and this in some cases is advantageously converted to the cyclammonium alkiodide by treating a solution of the hydrolysis product with an aqueous or alcoholic solution of a water-soluble metal iodide, e. g. an alkali metal iodide, e. g. sodium or potassium iodide.
  • a water-soluble metal iodide e. g. an alkali metal iodide, e. g. sodium or potassium iodide.
  • the hydroxy cyclammonium alkiodide can be converted to the hydroxy cyclammonium alkochloride by heating the hydroxy cyclammonium alkiodide with a suspension of silver chloride in methyl alcohol, or with a suspension of silver chloride in a phenol, according to the process described in United States Patent 2,245,249, dated June 10, 1941.
  • the alkobromide can be regenerated from the alkochloride by treating a solution ofthe alkochloride with a concentrated aqueous solution of sodium or potassium bromide.
  • Example 1.6-hydromyquinalcline ethioclzde 49.4 g. of G-methoxyquinaldine ethiodide were refluxed for three hours with 75 cc., 48 per cent hydrobromic acid.
  • the brown solution was chilled and the solid which separated was filtered oil. It was dissolved in 200 cc. of ethyl alcohol and to the hot solution was added a solution of 33.8 g. sodium iodide in a minimum of ethyl alcohol.
  • the resulting solution was cooled, the solid was filtered off. It was washed with a small amount of cold ethyl alcohol and dried. A yield of 35.2 g., 74 per cent was obtained. Melting point 257-450 C. with decomposition-tan crystals.
  • Example 2.7hydro:cyquinaldine methobromide 15.75 grams of 'l-methoxyquinaldine methiodide and 35 cc. of 43 per cent hydrobromic acid were mixed in a 200 cc. flask and refluxed for 1 hours. The reaction mixture was chilled to C. On stirring, it set to a solid mass. It was chilled again to 0 C. and then filtered, washed with acetone and dried. A yield of 9.2 grams of colorless material was obtained.
  • Example 3.7hydroa:yquinaldine ethobromide NfCH 16.5 grams of 7-methoxyquinaldine ethiodide and 30 cc. of 48 per cent hydrobromic acid were mixed in a 200 cc. flask and refluxed 1 /2 hours. The solution was chilled to 0 C. and diluted with 3.volumes of acetone and chilled for 2 hours at 0 C. The separated solid was filtered off, washed with acetone and dried. A yield of 9.8 grams of colorless material was obtained.
  • Example 4.6-hydr0ryle31idine methobromide 4 Example 5.--6-hydro:cylepidine ethob'romide (lg H5 B1 grams of G-methoxylepidine ethiodide and cc. of 48 per cent hydrobromic acid were mixed in a 200 cc. flask and refluxed 1 hour. The reaction mixture was cooled to room temperature and 250 cc. of acetone added and the mixture chilled to 0 C. The separated solid was filtered off, washed with acetone and dried. A yield of 19.3 grams of colorless material was obtained.
  • Example 7 --5-hydrory-2,3,3-trimethylindolenine ethiodide CH CH3 a s I 34.5 grams of 5-methoxy-2,3,3trimethylindolenine ethiodide and 60 cc. of 48 per cent hydrobromic acid were mixed in a 200 cc. flask and refluxed 1 hours. The solution was chilled to 0 C. and stirred to prevent supercooling. The separated solid was filtered as dry as possible. The crude material was dissolved in 200 cc. ethyl alcohol in the hot and treated with 15 grams. of sodium iodide. Some solid separated immediately and was filtered ofi. The filtrate was chilled to 0 C. The solid which separated was filtered off and dried. A yield of 17.5 grams of colorless solid of melting point 210-213 C. with decomposition was obtained.
  • thiazole methobro'mz'de 17.5 grams of 5-methoxy-2-methyl naphtha- [1,2lthiazole methiodide and 30 cc. of 48 per cent hydrobromic acid were mixed in a 200 cc. flask and refluxed 1 hours. The reaction mixture was chilled and the solid which separated was filtered ofi and washed with acetone and dried. A yield of grams of colorless material was obtained.
  • 5-hydroxyquinaldine ethiodide can be prepared by replacing the 6-methoxyquinaldine ethiodide with a molecularly equivalent amount of 5-ethoxyquinaldine ethiodide
  • S-hydroxyquinaldine n-propiodide can be prepared by replacing the G-methoxyquinaldine ethiodide with the n-propiodide
  • G-hydroxyquinaldine n-butiodide can be prepared by replacing the 6-methoxyquinaldine ethiodide with the n-butobromide, etc.
  • alkoxy cyclammonium quaternary salts which we employ in our process can be prepared by heating the corresponding alkoxy heterocyclic nitrogen bases with an alkyl bromide or alkyl iodide, e. g. methyl iodide, ethyl iodide, n-propyl iodide, n-butyl bromide, n-propyl bromide, isobutyl bromide, n-butyl iodide, etc., using a closed tube where higher temperatures are desired or the volatility of the reactants demands.
  • an alkyl bromide or alkyl iodide e. g. methyl iodide, ethyl iodide, n-propyl iodide, n-butyl bromide, n-propyl bromide, isobutyl bromide, n-butyl iodide, etc.
  • the alkoxy heterocyclic nitrogen bases are known in several instances, dines can be prepared by the interaction of an alkoxyaniline with paraldehyde (or aldol) nitrobenzene and sulfuric acid, according to the process given by Doebner and Miller, Ber. 16, 2465 (1886) dine gives 6-methoxyquinaldine. See also Braunholtz, J. Chem. Soc. 121, 169 (1922).
  • the alkoxylepidines can be prepared by heating an alkoxyaniline with methyl vinyl ketone, Campbell et al., J. Am. Chem. Soc. 67, 86 (1945).
  • Alkoxy-2,3,3-trimethylindolenines can be prepared by heating an alkoxyphenylhydrazine with methyl isopropyl ketone and refluxing the resulting mixture with glacial acetic acid. The following example will serve to illustrate further the preparation of the alkoxy- 2,3,3-trimethylindolenines.
  • the reaction mixture was The alkoxyquinal- Thus p-methoxyaniline (p-anisii 33.8 grams of p-methoxyphenylhydrazine and 23.3 grams of methylisopropyl ketone were mixed in a 200 cc. flask and warmed on a steam bath until water was formed as shown by the appearance of water droplets. cc. of glacial acetic acid was then added and the solution was refluxed 3 hours. The solvent was removed under reduced pressure on a steam bath and the residue taken up in dilute hydrochloric acid (240 cc.'of about 6 per cent hydrochloric acid). The solution was filtered and the filtrate was made alkaline with sodium carbonate solution.
  • p-methoxyaniline p-anisii 33.8 grams of p-methoxyphenylhydrazine and 23.3 grams of methylisopropyl ketone were mixed in a 200 cc. flask and warmed on a steam bath until water was
  • the hydroxy cyclammonium alkohalides of our invention can be employed to prepare cyanine, styryl and merocyanine dyes.
  • the hydroxy cyclammonium alkohalides can be condensed with cyclammonium alkyl quaternary salts containing an iodine atom or a thioether group in a reactive position (i. e. the aor 'y-position) to give monomethine cyanine dyes containin a hydroxyl group.
  • the condensations are advantageously effected in the presence of a basic condensing agent, e. g. a tertiary amine, e. g.
  • a trialkylamine such as triethylamine, trin-propylamine, triisoamylamine, N-methylpiperidine, N-ethylpiperidine, etc.
  • Typical cyclammonium alkyl quaternary salts containing an iodine atom or thioether group are: 2-iodoquinoline ethiodide, 2-iodoquinoline n-butiodide, 2 methylmercaptobenzothiazole metho ptoluenesulfonate, 2 methylbenzoxazole etho ptoluenesulfonate, 2-methylmercapto c-naphthothiazole etho-p-toluenesulfonate, etc.
  • the hydroxy cyclammonium alkohalides can be condensed with alkyl orthocarboxylates, e. g. ethyl orthoformate, ethyl orthoacetate, ethyl orthoproprionate methyl orthoformate, etc., in pyridine, to give symmetrical carbocyanine dyes.
  • alkyl orthocarboxylates e. g. ethyl orthoformate, ethyl orthoacetate, ethyl orthoproprionate methyl orthoformate, etc.
  • the hydroxy cyclammonium alkohalides can be condensed with cyclammonium' quaternary salts containing, in a reactive position, a fi-arylaminovinyl or a p-acylated arylaminovinyl group to give unsymmetrical carbocyanine dyes.
  • the condensations are advantageously effected in the presence of a basic condensing agent, e. g. the tertiary amines set forth above.
  • Typical cyclammonium quaternary salts containing a p-arylaminovinyl or c-acylated arylaminovinyl group are: ⁇ 3 acetanilidovinylbenzoxazole ethiodide, li-anilinovinylthiazoline methiodide, fl-acetanilidovinylbenzothiazole ethiodide, 4 ([3 anilinevinyl) quinoline n-butiodide, 2 [2 (N methylanilino) vinyllbenzothlazole ethiodide, 2 fi acetanilidovinyl-4-methylthiazo1e ethiodide, etc.
  • the hydroxycyclammonium alkohalides can be condensed with B-anilinoacrolein anilhydrochloride or with glutaconic dianilide hydrochloride, in the presence of a basic condensing agent, e. g. a tertiary amine, e. g. those set forth above, to give diand tricarbocyanine dyes.
  • a basic condensing agent e. g. a tertiary amine, e. g. those set forth above, to give diand tricarbocyanine dyes.
  • the hydroxy cyclammonium alkohalides can be condensed with heterocyclic compounds containing a, ketomethylene group (CHz-CO) and alkyl orthocarboxylates, e. g. ethyl orthoformate, ethyl orthoacetate, ethyl orthopropionate, etc., in the presence of pyridine, to give mercarbocyanine dyes.
  • Typical ketomethylene compounds include rhodanine, 3-ethylrhodanine, 3-;8-hydroxyethylrhodanine, 3-phenylrhodanine,
  • the hydroxy cyclammonium alkohalides can be condensed with heterocyclic compounds containing, substituted on the methylene group, an acylated arylaminomethylene group, e. g. 5-acetanilidomethylenerhodanines, 5 acetanilidomethylene 2 thiohydantoins, 5 acetanilidomethylene 9 thio 2, l(3,5) -oxazolediones, etc., in the presence of a basic condensing agent, e. g. the tertiary amines set forth above.
  • a basic condensing agent e. g. the tertiary amines set forth above.
  • the hydroxy cyclammonium alkohalides can be condensed with dialkylaminobenzaldehydes, e. g. p-dimethylaminobenzaldehyde, p-diethylaminobenzaldehyde, etc. to give styryl dyes.
  • dialkylaminobenzaldehydes e. g. p-dimethylaminobenzaldehyde, p-diethylaminobenzaldehyde, etc.
  • the condensations are advantageously carried out in the presence of a secondary amine, e. g. piperidine, methylpiperidines, etc.
  • the hydroxy cyclammonium alkohalides can be condensed with pyrrole carboxaldehydes to give pyrrolocarbocyanine dyes.
  • the condensations are advantageously carried out in a solvent, e. g. methyl, ethyl, n-propyl, isopropyl, isobutyl or n-butyl alcohol.
  • Pyrrole carboxaldehydes can be prepared by the method of Nenitzescu and Isacescu, Bull. soc. chim. Romania 11, 135 (1929). See also Brooker and Sprague, J. Am. Chem. Soc. 67, 1869 (1945).
  • the hereindescribed cyanine, merocyanine and styryl dyes sensitize photographic silver halide emulsions, especially the customarily employed gelatino-silver-chloride, chlorobromide, chlorobromoiodide, bromide and bromoiodide emulsions, when incorporated therein, e. g. in a concentration of from 10 to 40 mg. per liter of emulsion.
  • the dyes can be added to the emulsions from their solutions in methyl alcohol.
  • the pyrrolocyanine dyes described herein can be employed for the preparation of overcoating layers, filter layers and anti-halation layers for photographic elements.
  • the dyes that have been prepared from the hereindescribed hydroxycyclammonium salts are 6,6' dihydroxy 3,3 dimethyl 4,5,4,5' dibenzothiacarbocyanine bromide, fine dark crystals, M. P. greater than 300 C.
  • a process for preparing a hydroxy cyclammonium quaternary salt comprising hydrolyzing at a temperature of from to C., in the presence of hydrobromic acid, an alkoxy Cyclammonium salt selected from the group consisting of those represented by the following general formula:
  • R represents an alkyl group
  • R1 represents an alkyl group
  • R2 and R3 each represents a member selected from the group consisting of a hydrogen atom and a methyl group, R2 and R3 always being different
  • D represents an alkoxy-onaphthylene group
  • X represents a number selected from the group consisting of the bromide and the iodide anion.
  • a process for preparing a hydroxy cyclammonium quaternary salt comprising hydrolyzing at a temperature of from 80 to 150 C., in the presence of hydrobromic acid, an alkoxy cyclammonium salt selected from the group consisting of those represented by the following general formula:
  • R representsd a primary alkyl group of the formula CnI-I2n+1 wherein n represents a positive integer of from 1 to 4;
  • R1 represents an alkyl group of the formula.
  • R2 and R3 each represents a member selected from the group consisting of a hydrogen atom and a methyl group, R2 and R3 always being different.
  • a process for preparing a hydroxy cyclammonium quaternary salt comprising hydrolyzing at a temperature of from 80 to 150 C., in the presence of hydrobromic acid, an alkoxy cyclammonium quaternary salt selected from the group consisting of those represented by the following general formula:
  • R represents a primary alkyl group of the formula C'nHznH wherein n represents a positive integer of from 1 to 4, and R1 represents a positive integer of the formula CnH2n+l wherein n represents a positive integer of from 1 to 2.
  • a process for preparing a hydroxyquinaldine quaternary salt comprising hydrolyzing at a temperature of from 80 to 150 C., in the presence of constant boiling hydrobromic acid, fi-methoxyquinaldine ethiodide.
  • a process for preparing a hydroxy cyclammonium quaternary salt comprising hydrolyzing at a temperature of from 80 to 150 C., in the presence of hydrobromic acid, an alkoxy cyclammonium quaternary salt selected from the group consisting of those represented by the following general formula:
  • D represents an alkoxy-o-naphthylene group
  • R represents a primary alkyl group of the formula CnH2n+1 wherein n represents a positive integer of from 1 to 4.
  • a process for preparing a hydroxynaphthothiazole quaternary salt comprising hydrolyzing at a temperature of from 80 to 150 C., in the presence of constant boiling hydrobromic acid, 5-methoxy-2-methylnaphtha [1,2] thiazole ethiodide.
  • R represents a primary alkyl group of the formula CnH2n+1 wherein n represents a, positive integer of from 1 to 4 and R1 represents an alky group of the formula CnH2n+1 wherein n represents a positive integer of from 1 to 2.
  • a process for preparing a hydroxy-2,3,3- trimethylindolenine quaternary salt comprising hydrolyzing at a temperature of from to C., in the presence of constant boiling hydrobromic acid, 5-methoxy-2,3,3-trimethylinclolenine ethioclide.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Hydrogenated Pyridines (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
US18846A 1948-04-03 1948-04-03 Method for producing hydroxy cyclammonium quaternary salts Expired - Lifetime US2559907A (en)

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Application Number Priority Date Filing Date Title
BE488233D BE488233A (enrdf_load_stackoverflow) 1948-04-03
US18846A US2559907A (en) 1948-04-03 1948-04-03 Method for producing hydroxy cyclammonium quaternary salts
US18863A US2571775A (en) 1948-04-03 1948-04-03 Pyrro-colinocarbocyanine dyes and process for the preparation thereof
FR1034559D FR1034559A (fr) 1948-04-03 1949-03-31 Nouveaux colorants, procédé pour les préparer et produits en résultant
GB8929/49A GB658560A (en) 1948-04-03 1949-04-01 Process for the preparation of pyrrocolinocarbocyanine dyes
DEE2644A DE882282C (de) 1948-04-03 1950-10-01 Verfahren zur Herstellung von Pyrrocolincarbocyanin-Farbstoffen

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2787551A (en) * 1954-02-24 1957-04-02 Eastman Kodak Co Compositions stabilized with hydroxyindole
US5039823A (en) * 1990-08-10 1991-08-13 Ppg Industries, Inc. Method for preparing indoleninium halide

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2332517A (en) * 1943-10-26 Ctanine djtesttjff intermediates
US2394069A (en) * 1943-01-01 1946-02-05 Ilford Ltd Dyestuff intermediates

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2332517A (en) * 1943-10-26 Ctanine djtesttjff intermediates
US2394069A (en) * 1943-01-01 1946-02-05 Ilford Ltd Dyestuff intermediates

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2787551A (en) * 1954-02-24 1957-04-02 Eastman Kodak Co Compositions stabilized with hydroxyindole
US5039823A (en) * 1990-08-10 1991-08-13 Ppg Industries, Inc. Method for preparing indoleninium halide
WO1992002499A1 (en) * 1990-08-10 1992-02-20 Ppg Industries, Inc. Method for preparing indoleninium halide

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FR1034559A (fr) 1953-07-27
GB658560A (en) 1951-10-10
DE882282C (de) 1953-08-24
BE488233A (enrdf_load_stackoverflow)

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