US2539096A - Electron tube and grid for the same - Google Patents

Electron tube and grid for the same Download PDF

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Publication number
US2539096A
US2539096A US116449A US11644949A US2539096A US 2539096 A US2539096 A US 2539096A US 116449 A US116449 A US 116449A US 11644949 A US11644949 A US 11644949A US 2539096 A US2539096 A US 2539096A
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United States
Prior art keywords
grid
cathode
electron tube
tube
gold
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Expired - Lifetime
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US116449A
Inventor
Harold D Miller
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Varian Medical Systems Inc
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Eitel Mccullough Inc
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Priority to US116449A priority Critical patent/US2539096A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J19/00Details of vacuum tubes of the types covered by group H01J21/00
    • H01J19/28Non-electron-emitting electrodes; Screens
    • H01J19/30Non-electron-emitting electrodes; Screens characterised by the material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J2893/00Discharge tubes and lamps
    • H01J2893/0001Electrodes and electrode systems suitable for discharge tubes or lamps
    • H01J2893/0012Constructional arrangements
    • H01J2893/0019Chemical composition and manufacture
    • H01J2893/002Chemical composition and manufacture chemical
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12806Refractory [Group IVB, VB, or VIB] metal-base component
    • Y10T428/12826Group VIB metal-base component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12861Group VIII or IB metal-base component
    • Y10T428/12875Platinum group metal-base component

Definitions

  • My invention relates to an improved .grid for electron tubes, and more particularly to a grid for tubes having an oxide coated type of cathode.
  • the grid of the tube is usually the limiting factor because of primary electron emission from the grid.
  • the problem of grid emission is especially bad because of activation of the grid by the active materials such as barium from the cathode.
  • gold coated grids which helps to suppress primary electron emission from the grid.
  • Such grids can only be operated up to about 500 C., however, because at higher temperatures grid emission develops and also there is sufficient vaporization of gold from the grid to destroy the cathode emission.
  • the principal object of my invention is to provide a grid material which may be safely operated to higher temperatures without excessive primary grid emission and without danger of destroying the cathode emission.
  • Figure 1 is a vertical sectional view of a tube embodying the improved grid.
  • Figure 2 is an enlarged cross-sectional view of the improved grid wire
  • Figure 3 is similar view of a modified grid material.
  • my electron tube comprises a plurality of electrodes including a grid having a core wire of refractory metal, preferably molybdenum, and a surface layer comprising a metal selected from the group consisting of ruthenium and palladium.
  • a modified grid material embodying the invention has an intermediate layer of gold between the core and surface layer.
  • Other electrodes of the tube include a cathode and anode, the cathode being of the oxide coated type.
  • my tube is illustrated as a triode having a control grid incorporating the improvements of my invention, it being understood that the improve, ments may be embodied in many different types of tube construction, including multi-grid tubes as well as those having external instead of internal anodes.
  • the tube illustrated comprises a glassenvelope 2 having a re-entrant stem 3 and provided with a base 4 with terminal prongs 6.
  • a plurality of electrodes including an anode I, cathode 8 and the improved grid 9 are disposed coaxially within the envelope.
  • the internal anode I is a metal cylinder having a cap I I connected to a supporting lead I2 which is sealed to the upper end of envelope 2.
  • the cathode 8 is of the oxide coated type comprising a metal sleeve, say of nickel, surfaced with the conventional barium-strontium oxide coating.
  • a lead I4 sealed to stem 3 carries a bracket I 5 which supports the cathode sleeve and provides the conductor for the cathode.
  • This cathode is heated by an inner heater or filament !5 supported by a pair of conductor leads I! sealed to the stem. These various leads are connected to the terminal prongs of base 4.
  • grid 9 is preferably of the cage type comprising vertical wire bars fastened to end rings I8 and supported by a lead I9 sealed to a side of the envelope.
  • the shape of the grid and its mounting may, of course, be varied depending upon the type of tube structure employed.
  • My improved grid has its bars made of a composite wire comprising a core ZI of a refractory metal such as molybdenum or tungsten, molybdenum being preferred.
  • the core wire has a surface layer 22 of a metal selected from the group consisting of ruthenium and palladium. I have found that these two metals function to inhibit grid emission in tubes having oxide cathodes when such metals are employed, either singly or in combination, as a surfacing on the grid.
  • the surface layer may be a plied to the grid in any suitable manner. as by electroplating. The thickness of this layer is not critical so long as complete coverage of the core Wire is obtainecl.
  • the improved grid with a surface layer of ruthenium or palladium is very superior to the gold surfaced type in tubes having an oxide coated cathode. Comparative tests show that the improved grid will operate satisfactorily without appreciable grid emission and without harming the cathode emission to temperatures of about 700 6., while similar tubes with a conventional gold surfaced grid fail at about 500 C. This increase of several hundred degrees in the safe grid operating temperature is extremely important when tubes for greater power output and for operation at higher frequencies are involved.
  • An electron tube comprising an oxide coated cathode and a grid having a core of a metal selected from the group consisting of molybdenum and tungsten and a surface layer of a metal se-* lected from the group consisting of ruthenium and palladium.
  • An electron tube comprising an oxide coated cathode and a grid having a core of a metal se- 4 lected from the group consisting of molybdenum and tungsten, an intermediate layer of gold and a surface layer of a metal selected from the group consisting of ruthenium and alladium.
  • a grid wire for an electron tube comprising a core of molybdenum, an intermediate layer of gold and a surface layer of ruthenium.
  • a grid wire for an electron tube comprising a core of molybdenum, an intermediate layer of gold and a surface layer of palladium.

Description

Jan. 23, 1951 H. D. MILLER ELECTRON TUBE AND GRID FOR THE SAME Filed Sept. 19, 1949 r We m. WM 0 M m ATTORNEY Patented Jan. 23, 1951 ELECTRON TUBE AND GRID FOR THE'SAME Harold D. Miller, San Bruno, Calif, assignor to Eitel-McCullough, Inc., San Bruno, Calif a corporation of California Application September 19, 1949, Serial No. 116,440
4 claims. "(01. 250- 215) My invention relates to an improved .grid for electron tubes, and more particularly to a grid for tubes having an oxide coated type of cathode.
In electron tubes used for transmission purposes where relatively high electrode temperatures are apt to be involved, the grid of the tube is usually the limiting factor because of primary electron emission from the grid. With tubes having the conventional oxide coated cathode involving a combination of barium and strontium oxides the problem of grid emission is especially bad because of activation of the grid by the active materials such as barium from the cathode. In an effort to alleviate this problem it is common practice to use gold coated grids which helps to suppress primary electron emission from the grid. Such grids can only be operated up to about 500 C., however, because at higher temperatures grid emission develops and also there is sufficient vaporization of gold from the grid to destroy the cathode emission.
The principal object of my invention is to provide a grid material which may be safely operated to higher temperatures without excessive primary grid emission and without danger of destroying the cathode emission.
The invention possesses other objects and features of advantage, some of which, with the foregoing, will be set forth in the following description of my invention. It is to be understood that I do not limit myself to this disclosure of species of my invention as I may adopt variant embodiments thereof within the scope of the claims.
Referring to the drawing:
Figure 1 is a vertical sectional view of a tube embodying the improved grid.
Figure 2 is an enlarged cross-sectional view of the improved grid wire; and
Figure 3 is similar view of a modified grid material.
In terms of broad inclusion, my electron tube comprises a plurality of electrodes including a grid having a core wire of refractory metal, preferably molybdenum, and a surface layer comprising a metal selected from the group consisting of ruthenium and palladium. A modified grid material embodying the invention has an intermediate layer of gold between the core and surface layer. Other electrodes of the tube include a cathode and anode, the cathode being of the oxide coated type.
In greater detail, and referring to the drawing, my tube is illustrated as a triode having a control grid incorporating the improvements of my invention, it being understood that the improve, ments may be embodied in many different types of tube construction, including multi-grid tubes as well as those having external instead of internal anodes. The tube illustrated 'comprises a glassenvelope 2 having a re-entrant stem 3 and provided with a base 4 with terminal prongs 6.
A plurality of electrodes including an anode I, cathode 8 and the improved grid 9 are disposed coaxially within the envelope. In the radiation cooled type of tube shown the internal anode I is a metal cylinder having a cap I I connected to a supporting lead I2 which is sealed to the upper end of envelope 2.
The cathode 8 is of the oxide coated type comprising a metal sleeve, say of nickel, surfaced with the conventional barium-strontium oxide coating. A lead I4 sealed to stem 3 carries a bracket I 5 which supports the cathode sleeve and provides the conductor for the cathode. This cathode is heated by an inner heater or filament !5 supported by a pair of conductor leads I! sealed to the stem. These various leads are connected to the terminal prongs of base 4.
From the structural standpoint grid 9 is preferably of the cage type comprising vertical wire bars fastened to end rings I8 and supported by a lead I9 sealed to a side of the envelope. The shape of the grid and its mounting may, of course, be varied depending upon the type of tube structure employed.
My improved grid has its bars made of a composite wire comprising a core ZI of a refractory metal such as molybdenum or tungsten, molybdenum being preferred. The core wire has a surface layer 22 of a metal selected from the group consisting of ruthenium and palladium. I have found that these two metals function to inhibit grid emission in tubes having oxide cathodes when such metals are employed, either singly or in combination, as a surfacing on the grid. The surface layer may be a plied to the grid in any suitable manner. as by electroplating. The thickness of this layer is not critical so long as complete coverage of the core Wire is obtainecl.
The improved grid with a surface layer of ruthenium or palladium is very superior to the gold surfaced type in tubes having an oxide coated cathode. Comparative tests show that the improved grid will operate satisfactorily without appreciable grid emission and without harming the cathode emission to temperatures of about 700 6., while similar tubes with a conventional gold surfaced grid fail at about 500 C. This increase of several hundred degrees in the safe grid operating temperature is extremely important when tubes for greater power output and for operation at higher frequencies are involved.
In some types of grid construction where the presence of gold is desired for brazing purposes, I find that the composite wire shown in Figure 3 is very satisfactory, comprising an intermediate layer 23 of gold interposed between the core 2| and the surface layer 22. This type of grid wire also operates satisfactorily at the higher grid temperatures because the surface layer of rutheniurn or palladium serves the additional purpose of retarding vaporization of the gold and thereby preventing contamination of the cathode.
I claim:
1. An electron tube comprising an oxide coated cathode and a grid having a core of a metal selected from the group consisting of molybdenum and tungsten and a surface layer of a metal se-* lected from the group consisting of ruthenium and palladium.
2. An electron tube comprising an oxide coated cathode and a grid having a core of a metal se- 4 lected from the group consisting of molybdenum and tungsten, an intermediate layer of gold and a surface layer of a metal selected from the group consisting of ruthenium and alladium.
3. A grid wire for an electron tube comprising a core of molybdenum, an intermediate layer of gold and a surface layer of ruthenium.
4. A grid wire for an electron tube comprising a core of molybdenum, an intermediate layer of gold and a surface layer of palladium.
HAROLD D. MILLER.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 2,486,436 Rothstein Nov. 1, 1949 FOREIGN PATENTS Number Country Date 356,436 Great Britain Mar. 4, 1930

Claims (1)

  1. 3. A GRID WIRE FOR AN ELECTRON TUBE COMPRISING A CORE OF MOLYBDENUM, AN INTERMEDIATE LAYER OF GOLD AND A SURFACE LAYER OF RUTHENIUM.
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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2691116A (en) * 1953-03-31 1954-10-05 Rca Corp Color-kinescopes, etc.
US2719797A (en) * 1950-05-23 1955-10-04 Baker & Co Inc Platinizing tantalum
US2793423A (en) * 1954-04-19 1957-05-28 Baker & Co Inc Compound metal stock
US2844868A (en) * 1954-06-01 1958-07-29 Sylvania Electric Prod Method of joining refractory metals
US2879429A (en) * 1956-03-19 1959-03-24 Gen Electric High power electron tube
US2886499A (en) * 1957-01-07 1959-05-12 Glenn R Schaer Protective metal coatings for molybdenum
US2897584A (en) * 1957-05-22 1959-08-04 Sel Rex Corp Gold plated electrical contact and similar elements
US3044155A (en) * 1957-08-02 1962-07-17 Engelhard Ind Inc Spinnerette
US3114071A (en) * 1960-03-21 1963-12-10 Westinghouse Electric Corp Electron discharge device having improved electrode support
US3200284A (en) * 1960-07-26 1965-08-10 Philips Corp Platinum coated molybdenum grid having an intermediate layer of nickel
US3547600A (en) * 1968-05-28 1970-12-15 Kdi Chloro Guard Corp Composite electrode having a base of titanium or columbium,an intermediate layer of tantalum or columbium and an outer layer of platinum group metals
US3635760A (en) * 1968-11-18 1972-01-18 Thermo Electron Corp Formation of planes facilitating thermionic emission
US3753665A (en) * 1970-11-12 1973-08-21 Gen Electric Magnetic film plated wire
US3772561A (en) * 1970-04-23 1973-11-13 Gte Sylvania Inc Electron discharge device grid having enhanced thermal conductivity and reduced secondary emission characteristics

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB356436A (en) * 1929-08-19 1931-09-10 Guenther Wagner
US2486436A (en) * 1946-05-10 1949-11-01 Rothstein Jerome Contamination control

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB356436A (en) * 1929-08-19 1931-09-10 Guenther Wagner
US2486436A (en) * 1946-05-10 1949-11-01 Rothstein Jerome Contamination control

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2719797A (en) * 1950-05-23 1955-10-04 Baker & Co Inc Platinizing tantalum
US2691116A (en) * 1953-03-31 1954-10-05 Rca Corp Color-kinescopes, etc.
US2793423A (en) * 1954-04-19 1957-05-28 Baker & Co Inc Compound metal stock
US2844868A (en) * 1954-06-01 1958-07-29 Sylvania Electric Prod Method of joining refractory metals
US2879429A (en) * 1956-03-19 1959-03-24 Gen Electric High power electron tube
US2886499A (en) * 1957-01-07 1959-05-12 Glenn R Schaer Protective metal coatings for molybdenum
US2897584A (en) * 1957-05-22 1959-08-04 Sel Rex Corp Gold plated electrical contact and similar elements
US3044155A (en) * 1957-08-02 1962-07-17 Engelhard Ind Inc Spinnerette
US3114071A (en) * 1960-03-21 1963-12-10 Westinghouse Electric Corp Electron discharge device having improved electrode support
US3200284A (en) * 1960-07-26 1965-08-10 Philips Corp Platinum coated molybdenum grid having an intermediate layer of nickel
US3547600A (en) * 1968-05-28 1970-12-15 Kdi Chloro Guard Corp Composite electrode having a base of titanium or columbium,an intermediate layer of tantalum or columbium and an outer layer of platinum group metals
US3635760A (en) * 1968-11-18 1972-01-18 Thermo Electron Corp Formation of planes facilitating thermionic emission
US3772561A (en) * 1970-04-23 1973-11-13 Gte Sylvania Inc Electron discharge device grid having enhanced thermal conductivity and reduced secondary emission characteristics
US3753665A (en) * 1970-11-12 1973-08-21 Gen Electric Magnetic film plated wire

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