US2527686A - Mouthwash - Google Patents
Mouthwash Download PDFInfo
- Publication number
- US2527686A US2527686A US637257A US63725745A US2527686A US 2527686 A US2527686 A US 2527686A US 637257 A US637257 A US 637257A US 63725745 A US63725745 A US 63725745A US 2527686 A US2527686 A US 2527686A
- Authority
- US
- United States
- Prior art keywords
- fluoride
- employed
- zinc chloride
- water
- per gallon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
- A61K8/21—Fluorides; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/66—Enzymes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
Definitions
- Patented Oct. 31 1950 MOUTHWASH Max H. Sandberg, MattapamlMass.
- This invention relates to mouth washes and particularly to compositions of this character which may be utilized to have a very eflicacious effect against dental caries.
- compositions which can be utilized as mouth washes to prevent development of cavities in teeth.
- water soluble fluorides particularly of the alkali metals may be utilized in proper vehicles as a mouth wash or for related purposes, in limited concentrations in such mouth washes, to have a beneficial effect against development of cavities in teeth.
- the fluorides employed are desirably alkali metal fluorides of which ammonium fluoride or ammonium bifluoride has been found to be the best, while the sodium fluoride can be utilized. Potassium fluoride is the less efficacious.
- the fluoride is utilized in the vehicle which enables it to be carried into the enamel rods.
- Such composition there is employed papain which digests proteins and malt or diastase such as takadiastase which digests starches.
- These ferments may be employed in such composition and do not interfere with each other.
- Other ferments cannot be employed in lieu of the particular ferments mentioned above and those set forth, namely, the papain and malt must be employed to give the most desirable results in accordance with the present invention.
- Such ferments together with the fluorides are desirably used in an aqueous composition which also contains zinc chloride and formaldehyde, as for example, commercial formalin.
- the most desirable proportions have been found to be 1 mole of fluoride to 1 mole of zinc chloride to 1 mole of formaldehyde but other ratios may be employed.
- the amount of fluoride present should be carefully controlled and should lie within about to 30 grains per gallon of the final solution. Less than 15 grains per gallon does not give any substantial effect while more than 30 grains tends to give a mottling effect.
- the preferred range is from 15 to 25 grains per gallon.
- the stated ingredients are desirably used in an aqueous vehicle and since zinc chloride has a tendency to decompose in the presence of water, a water-soluble non-toxic alcohol may desirably be added to prevent this efiect.
- a water-soluble non-toxic alcohol may desirably be added to prevent this efiect.
- Ethyl alcohol is preferred, isopropyl and similar alcohols may be employed. Variation in the amount of alcohol and water proportions may, of course, be employed, but less alcohol than that indicated tends to give some undesirable feeling on the gums.
- Flavoring components as desired may be employed such as the flavoring oils like oil of cassia, oil of cloves, and saccharin may be included in small amounts.
- the composition may be colored with any suitable dye. If desired to impart a Wintergreen aroma, this may be done by permitting the composition to stand within an atmosphere containing such oil of Wintergreen for a period of about one week.
- the flavoring ingredients and vehicle components include:
- Saccharin .5 Ethyl alcohol 40 'Water 1000 The materials may be mixed in any desired way and the fluoride added to produce the stated concentration of from 15 to grains per gallon of solution, desirably 25 grains of sodium or ammonium fluoride being added for this purpose. While the fluoride may be incorporated together with all of the other ingredients, it is desirable to add it as the final component.
- the parts given in this example are by weight.
- compositions produced in accordance with the present invention have been proven to be a specific in preventing the formation of dental caries.
- This invention being a prophylactic only, does not have any action .on dental caries that are in active progress.
- a mouth wash as set forth in claim 1 containing an amount of a non-toxic aliphatic alcohol sufiicient to prevent decomposition of the zinc chloride.
- a mouth wash containing the following components in parts by weight: zinc chloride 2, formalin .5, papain 100, malt 100, ethyl alcohol 40, water 1000, and an alkali metal fluoride in an amount of 25 grains per gallon of solution.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Engineering & Computer Science (AREA)
- Biotechnology (AREA)
- Botany (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Description
Patented Oct. 31 1950 MOUTHWASH Max H. Sandberg, MattapamlMass.
Application December 26, 1945, Serial No. 637,257
Claims.
This invention relates to mouth washes and particularly to compositions of this character which may be utilized to have a very eflicacious effect against dental caries.
Among the objects of the present invention is the production of compositions which can be utilized as mouth washes to prevent development of cavities in teeth.
Other objects and advantages will appear from the more detailed description set forth below, it being understood that such more detailed description is given by way of illustration and explanation only, and not by way of limitation since various changes therein may be made by those skilled in the art without departing from the scope and spirit of the present invention.
In accordance with the present invention it has been found that water soluble fluorides particularly of the alkali metals may be utilized in proper vehicles as a mouth wash or for related purposes, in limited concentrations in such mouth washes, to have a beneficial effect against development of cavities in teeth. The fluorides employed are desirably alkali metal fluorides of which ammonium fluoride or ammonium bifluoride has been found to be the best, while the sodium fluoride can be utilized. Potassium fluoride is the less efficacious. The fluoride is utilized in the vehicle which enables it to be carried into the enamel rods.
In such composition there is employed papain which digests proteins and malt or diastase such as takadiastase which digests starches. These ferments may be employed in such composition and do not interfere with each other. Other ferments cannot be employed in lieu of the particular ferments mentioned above and those set forth, namely, the papain and malt must be employed to give the most desirable results in accordance with the present invention. Such ferments together with the fluorides are desirably used in an aqueous composition which also contains zinc chloride and formaldehyde, as for example, commercial formalin. The most desirable proportions have been found to be 1 mole of fluoride to 1 mole of zinc chloride to 1 mole of formaldehyde but other ratios may be employed. The amount of fluoride present should be carefully controlled and should lie within about to 30 grains per gallon of the final solution. Less than 15 grains per gallon does not give any substantial effect while more than 30 grains tends to give a mottling effect. The preferred range is from 15 to 25 grains per gallon.
The stated ingredients are desirably used in an aqueous vehicle and since zinc chloride has a tendency to decompose in the presence of water, a water-soluble non-toxic alcohol may desirably be added to prevent this efiect. Ethyl alcohol is preferred, isopropyl and similar alcohols may be employed. Variation in the amount of alcohol and water proportions may, of course, be employed, but less alcohol than that indicated tends to give some undesirable feeling on the gums.
Flavoring components as desired may be employed such as the flavoring oils like oil of cassia, oil of cloves, and saccharin may be included in small amounts. The composition may be colored with any suitable dye. If desired to impart a Wintergreen aroma, this may be done by permitting the composition to stand within an atmosphere containing such oil of Wintergreen for a period of about one week.
The following is a preferred formula:
Parts Zinc chloride 2 Formalin (commercial) .5
Papain -l 100 Malt 100 The flavoring ingredients and vehicle components include:
Parts Oil of cassia 1.5 Oil of cloves .5
Saccharin .5 Ethyl alcohol 40 'Water 1000 The materials may be mixed in any desired way and the fluoride added to produce the stated concentration of from 15 to grains per gallon of solution, desirably 25 grains of sodium or ammonium fluoride being added for this purpose. While the fluoride may be incorporated together with all of the other ingredients, it is desirable to add it as the final component. The parts given in this example are by weight.
Compositions produced in accordance with the present invention have been proven to be a specific in preventing the formation of dental caries. This invention being a prophylactic only, does not have any action .on dental caries that are in active progress.
Having thus set forth my invention, I claim:
1. A mouth Wash containing zinc chloride, formaldehyde, papain, malt and water, and an alkali metal fluoride in an amount of from 15 to 30 grains per gallon of solution.
2. A composition as set forth inclaim 1,-in which the fluoride is ammonium fluoride.
(3. A composition as set forth in claim 1, in which the fluoride is sodium fluoride.
4. A mouth wash as set forth in claim 1 containing an amount of a non-toxic aliphatic alcohol sufiicient to prevent decomposition of the zinc chloride.
5. A mouth wash containing the following components in parts by weight: zinc chloride 2, formalin .5, papain 100, malt 100, ethyl alcohol 40, water 1000, and an alkali metal fluoride in an amount of 25 grains per gallon of solution.
MAX H. SANDBERG.
REFERENCES CITED The following references are of record in the file of this patent:
Number 0 Number 4 UNITED STATES PATENTS Name Date Monroe Dec. 29, 1925 Cross Jan. 16, 1934 FOREIGN PATENTS Country Date France Dec. 1, 1910 Great Britain of 1914 Austria Apr. 10, 1922 Great Britain Apr. 13, 1942
Claims (1)
1. A MOUTH WASH CONTAINING ZINC CHLORIDE, FORMALDEHYDE, PAPAIN, MALT AND WATER, AND AN ALKALI METAL FLUORIDE IN AN AMOUNT OF FROM 15 TO 30 GRAINS PER GALLON OF SOLUTION.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US637257A US2527686A (en) | 1945-12-26 | 1945-12-26 | Mouthwash |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US637257A US2527686A (en) | 1945-12-26 | 1945-12-26 | Mouthwash |
Publications (1)
Publication Number | Publication Date |
---|---|
US2527686A true US2527686A (en) | 1950-10-31 |
Family
ID=24555186
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US637257A Expired - Lifetime US2527686A (en) | 1945-12-26 | 1945-12-26 | Mouthwash |
Country Status (1)
Country | Link |
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US (1) | US2527686A (en) |
Cited By (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2829086A (en) * | 1954-09-21 | 1958-04-01 | Colgate Palmolive Co | Dental preparations comprising higher aliphatic perfluorinated acid compounds |
US2913373A (en) * | 1957-08-28 | 1959-11-17 | Walter S Weisz | Fluoride mouth wash composition |
US3072532A (en) * | 1958-11-04 | 1963-01-08 | Innerfield Irving | Administration of enzymic composition |
US3852432A (en) * | 1971-01-18 | 1974-12-03 | Department Of Health Education | Diagnostic device and method of treatment |
US4082841A (en) * | 1975-10-10 | 1978-04-04 | Lever Brothers Company | Dentifrice |
US4096241A (en) * | 1975-06-24 | 1978-06-20 | Ed. Geistlich Sohne A.G. Fur Chemische Industrie | Tooth preparations |
US4152418A (en) * | 1970-04-01 | 1979-05-01 | Lever Brothers Company | Zinc and enzyme mouthwash and mouthwash concentrate for reducing dental plaque and calculus formation |
US4339432A (en) * | 1979-06-20 | 1982-07-13 | Lever Brothers Company | Oral mouthwash containing zinc and glycine |
EP0075446A2 (en) * | 1981-09-17 | 1983-03-30 | Johnson & Johnson Products Inc. | Anticaries composition |
US4416867A (en) * | 1979-06-20 | 1983-11-22 | Lever Brothers Company | Oral compositions |
US4425325A (en) | 1979-06-20 | 1984-01-10 | Lever Brothers Company | Oral compositions |
US4469674A (en) * | 1981-09-03 | 1984-09-04 | Richardson-Vicks Inc. | Stable oral compositions containing zinc and fluoride compounds |
US4473550A (en) * | 1981-01-16 | 1984-09-25 | Rosenbaum Robert S | Bactericidal compositions and methods |
US4476108A (en) * | 1981-01-16 | 1984-10-09 | Kessler Jack H | Bactericidal method |
US4588586A (en) * | 1983-01-03 | 1986-05-13 | Kessler Jack H | Method for disinfecting a contact lens |
US4847089A (en) * | 1986-07-16 | 1989-07-11 | David N. Kramer | Cleansing and distinfecting compositions, including bleaching agents, and sponges and other applicators incorporating the same |
USRE33465E (en) * | 1981-07-31 | 1990-11-27 | Method for reducing the duration of the common cold | |
US5002970A (en) * | 1981-07-31 | 1991-03-26 | Eby Iii George A | Flavor masked ionizable zinc compositions for oral absorption |
US5405836A (en) * | 1993-03-02 | 1995-04-11 | Nabisco, Inc. | Pet foods with water-soluble zinc compound coating for controlling malodorous breath |
WO1997040812A1 (en) * | 1996-04-26 | 1997-11-06 | Warner-Lambert Company | Enhanced zinc containing oral composition |
US20070293466A1 (en) * | 2004-11-03 | 2007-12-20 | Thompson Robert C | Antimicrobial Chelates |
US20080152601A1 (en) * | 2002-08-28 | 2008-06-26 | Colgate-Palmolive Company | Dual Component Dental Composition Containing Enzyme |
US20080213195A1 (en) * | 2002-05-10 | 2008-09-04 | Szeles Lori H | Antibacterial Dentifrice Exhibiting Antiplaque and Breath Freshening Properties |
US7687650B2 (en) | 2006-02-03 | 2010-03-30 | Jr Chem, Llc | Chemical compositions and methods of making them |
US7867522B2 (en) | 2006-09-28 | 2011-01-11 | Jr Chem, Llc | Method of wound/burn healing using copper-zinc compositions |
US7897800B2 (en) | 2006-02-03 | 2011-03-01 | Jr Chem, Llc | Chemical compositions and methods of making them |
US7927614B2 (en) | 2006-02-03 | 2011-04-19 | Jr Chem, Llc | Anti-aging treatment using copper and zinc compositions |
US8273791B2 (en) | 2008-01-04 | 2012-09-25 | Jr Chem, Llc | Compositions, kits and regimens for the treatment of skin, especially décolletage |
WO2014193251A1 (en) | 2013-05-30 | 2014-12-04 | Warszawski Uniwersytet Medyczny | Preparation for maintenance of oral cavity hygiene and prevention of plaque formation |
US8952057B2 (en) | 2011-01-11 | 2015-02-10 | Jr Chem, Llc | Compositions for anorectal use and methods for treating anorectal disorders |
US9427397B2 (en) | 2009-01-23 | 2016-08-30 | Obagi Medical Products, Inc. | Rosacea treatments and kits for performing them |
US9498421B2 (en) | 2012-12-19 | 2016-11-22 | Colgate-Palmolive Company | Two component compositions containing tetrabasic zinc-amino acid halide complexes and cysteine |
US9504858B2 (en) | 2012-12-19 | 2016-11-29 | Colgate-Palmolive Company | Zinc amino acid halide complex with cysteine |
US9572756B2 (en) | 2012-12-19 | 2017-02-21 | Colgate-Palmolive Company | Teeth whitening methods, visually perceptible signals and compositions therefor |
US9675823B2 (en) | 2012-12-19 | 2017-06-13 | Colgate-Palmolive Company | Two component compositions containing zinc amino acid halide complexes and cysteine |
US9750670B2 (en) | 2012-12-19 | 2017-09-05 | Colgate-Palmolive Company | Zinc amino acid complex with cysteine |
US9757316B2 (en) | 2012-12-19 | 2017-09-12 | Colgate-Palmolive Company | Zinc-lysine complex |
US9763865B2 (en) | 2012-12-19 | 2017-09-19 | Colgate-Palmolive Company | Oral gel comprising zinc-amino acid complex |
US9775792B2 (en) | 2012-12-19 | 2017-10-03 | Colgate-Palmolive Company | Oral care products comprising a tetrabasic zinc-amino acid-halide complex |
US9827177B2 (en) | 2012-12-19 | 2017-11-28 | Colgate-Palmolive Company | Antiperspirant products with protein and antiperspirant salts |
US9861563B2 (en) | 2012-12-19 | 2018-01-09 | Colgate-Palmolive Company | Oral care products comprising tetrabasic zinc chloride and trimethylglycine |
US9901523B2 (en) | 2012-12-19 | 2018-02-27 | Colgate-Palmolive Company | Oral care products comprising zinc oxide and trimethylglycine |
US9925130B2 (en) | 2012-12-19 | 2018-03-27 | Colgate-Palmolive Company | Composition with zinc amino acid/trimethylglycine halide precursors |
US9943473B2 (en) | 2012-12-19 | 2018-04-17 | Colgate-Palmolive Company | Zinc lysine halide complex |
US9980890B2 (en) | 2012-12-19 | 2018-05-29 | Colgate-Palmolive Company | Zinc amino acid halide mouthwashes |
US10105303B2 (en) | 2012-12-19 | 2018-10-23 | Colgate-Palmolive Company | Oral care composition comprising zinc amino acid halides |
US10188112B2 (en) | 2012-12-19 | 2019-01-29 | Colgate-Palmolive Company | Personal cleansing compositions containing zinc amino acid/trimethylglycine halide |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR420705A (en) * | 1910-09-06 | 1911-02-06 | Benedict Kritchewsky | Chemicals that destroy dental tartar |
GB191403034A (en) * | 1914-02-05 | 1915-02-05 | Cecil Rudolph Lidgey | Improvements in or relating to Dentifrices. |
AT87896B (en) * | 1914-03-28 | 1922-04-10 | Otto Dr Perl | Process for the manufacture of dentifrices. |
US1567974A (en) * | 1923-06-01 | 1925-12-29 | Monroe Charles Wesley | Treatment of pyorrhea |
US1943856A (en) * | 1929-07-10 | 1934-01-16 | Silica Products Company | Dental preparation |
GB544405A (en) * | 1939-06-28 | 1942-04-13 | James Howard Cummings | An improved proteolytic dentifrice |
-
1945
- 1945-12-26 US US637257A patent/US2527686A/en not_active Expired - Lifetime
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR420705A (en) * | 1910-09-06 | 1911-02-06 | Benedict Kritchewsky | Chemicals that destroy dental tartar |
GB191403034A (en) * | 1914-02-05 | 1915-02-05 | Cecil Rudolph Lidgey | Improvements in or relating to Dentifrices. |
AT87896B (en) * | 1914-03-28 | 1922-04-10 | Otto Dr Perl | Process for the manufacture of dentifrices. |
US1567974A (en) * | 1923-06-01 | 1925-12-29 | Monroe Charles Wesley | Treatment of pyorrhea |
US1943856A (en) * | 1929-07-10 | 1934-01-16 | Silica Products Company | Dental preparation |
GB544405A (en) * | 1939-06-28 | 1942-04-13 | James Howard Cummings | An improved proteolytic dentifrice |
Cited By (63)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2829086A (en) * | 1954-09-21 | 1958-04-01 | Colgate Palmolive Co | Dental preparations comprising higher aliphatic perfluorinated acid compounds |
US2913373A (en) * | 1957-08-28 | 1959-11-17 | Walter S Weisz | Fluoride mouth wash composition |
US3072532A (en) * | 1958-11-04 | 1963-01-08 | Innerfield Irving | Administration of enzymic composition |
US4152418A (en) * | 1970-04-01 | 1979-05-01 | Lever Brothers Company | Zinc and enzyme mouthwash and mouthwash concentrate for reducing dental plaque and calculus formation |
US3852432A (en) * | 1971-01-18 | 1974-12-03 | Department Of Health Education | Diagnostic device and method of treatment |
US4096241A (en) * | 1975-06-24 | 1978-06-20 | Ed. Geistlich Sohne A.G. Fur Chemische Industrie | Tooth preparations |
US4082841A (en) * | 1975-10-10 | 1978-04-04 | Lever Brothers Company | Dentifrice |
US4425325A (en) | 1979-06-20 | 1984-01-10 | Lever Brothers Company | Oral compositions |
US4339432A (en) * | 1979-06-20 | 1982-07-13 | Lever Brothers Company | Oral mouthwash containing zinc and glycine |
US4416867A (en) * | 1979-06-20 | 1983-11-22 | Lever Brothers Company | Oral compositions |
US4476108A (en) * | 1981-01-16 | 1984-10-09 | Kessler Jack H | Bactericidal method |
US4473550A (en) * | 1981-01-16 | 1984-09-25 | Rosenbaum Robert S | Bactericidal compositions and methods |
USRE33465E (en) * | 1981-07-31 | 1990-11-27 | Method for reducing the duration of the common cold | |
US5002970A (en) * | 1981-07-31 | 1991-03-26 | Eby Iii George A | Flavor masked ionizable zinc compositions for oral absorption |
US4469674A (en) * | 1981-09-03 | 1984-09-04 | Richardson-Vicks Inc. | Stable oral compositions containing zinc and fluoride compounds |
EP0075446A3 (en) * | 1981-09-17 | 1984-07-11 | Johnson & Johnson Products Inc. | Anticaries composition |
EP0075446A2 (en) * | 1981-09-17 | 1983-03-30 | Johnson & Johnson Products Inc. | Anticaries composition |
US4588586A (en) * | 1983-01-03 | 1986-05-13 | Kessler Jack H | Method for disinfecting a contact lens |
US4847089A (en) * | 1986-07-16 | 1989-07-11 | David N. Kramer | Cleansing and distinfecting compositions, including bleaching agents, and sponges and other applicators incorporating the same |
US5405836A (en) * | 1993-03-02 | 1995-04-11 | Nabisco, Inc. | Pet foods with water-soluble zinc compound coating for controlling malodorous breath |
WO1997040812A1 (en) * | 1996-04-26 | 1997-11-06 | Warner-Lambert Company | Enhanced zinc containing oral composition |
US20080213195A1 (en) * | 2002-05-10 | 2008-09-04 | Szeles Lori H | Antibacterial Dentifrice Exhibiting Antiplaque and Breath Freshening Properties |
US7939306B2 (en) | 2002-05-10 | 2011-05-10 | Colgate-Palmolive Company | Antibacterial dentifrice exhibiting antiplaque and breath freshening properties |
US20080152601A1 (en) * | 2002-08-28 | 2008-06-26 | Colgate-Palmolive Company | Dual Component Dental Composition Containing Enzyme |
EP2172187A1 (en) | 2002-08-28 | 2010-04-07 | Colgate-Palmolive Company | Dual component dental composition containing enzyme |
US20100266514A9 (en) * | 2002-08-28 | 2010-10-21 | Colgate-Palmolive Company | Dual Component Dental Composition Containing Enzyme |
US20070293466A1 (en) * | 2004-11-03 | 2007-12-20 | Thompson Robert C | Antimicrobial Chelates |
US7582418B2 (en) | 2004-11-03 | 2009-09-01 | Albion Laboratories, Inc. | Antimicrobial chelates |
US7897800B2 (en) | 2006-02-03 | 2011-03-01 | Jr Chem, Llc | Chemical compositions and methods of making them |
US7927614B2 (en) | 2006-02-03 | 2011-04-19 | Jr Chem, Llc | Anti-aging treatment using copper and zinc compositions |
US7687650B2 (en) | 2006-02-03 | 2010-03-30 | Jr Chem, Llc | Chemical compositions and methods of making them |
US8148563B2 (en) | 2006-02-03 | 2012-04-03 | Jr Chem, Llc | Chemical compositions and methods of making them |
US7867522B2 (en) | 2006-09-28 | 2011-01-11 | Jr Chem, Llc | Method of wound/burn healing using copper-zinc compositions |
US8273791B2 (en) | 2008-01-04 | 2012-09-25 | Jr Chem, Llc | Compositions, kits and regimens for the treatment of skin, especially décolletage |
US8505730B2 (en) | 2008-01-04 | 2013-08-13 | Jr Chem, Llc | Compositions, kits and regimens for the treatment of skin, especially décolletage |
US9427397B2 (en) | 2009-01-23 | 2016-08-30 | Obagi Medical Products, Inc. | Rosacea treatments and kits for performing them |
US8952057B2 (en) | 2011-01-11 | 2015-02-10 | Jr Chem, Llc | Compositions for anorectal use and methods for treating anorectal disorders |
US9775792B2 (en) | 2012-12-19 | 2017-10-03 | Colgate-Palmolive Company | Oral care products comprising a tetrabasic zinc-amino acid-halide complex |
US9943473B2 (en) | 2012-12-19 | 2018-04-17 | Colgate-Palmolive Company | Zinc lysine halide complex |
US9504858B2 (en) | 2012-12-19 | 2016-11-29 | Colgate-Palmolive Company | Zinc amino acid halide complex with cysteine |
US9572756B2 (en) | 2012-12-19 | 2017-02-21 | Colgate-Palmolive Company | Teeth whitening methods, visually perceptible signals and compositions therefor |
US9675823B2 (en) | 2012-12-19 | 2017-06-13 | Colgate-Palmolive Company | Two component compositions containing zinc amino acid halide complexes and cysteine |
US9750670B2 (en) | 2012-12-19 | 2017-09-05 | Colgate-Palmolive Company | Zinc amino acid complex with cysteine |
US9757316B2 (en) | 2012-12-19 | 2017-09-12 | Colgate-Palmolive Company | Zinc-lysine complex |
US9763865B2 (en) | 2012-12-19 | 2017-09-19 | Colgate-Palmolive Company | Oral gel comprising zinc-amino acid complex |
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