US2508518A - Apparatus for forming integral fins on a length of stock - Google Patents

Apparatus for forming integral fins on a length of stock Download PDF

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US2508518A
US2508518A US771627A US77162747A US2508518A US 2508518 A US2508518 A US 2508518A US 771627 A US771627 A US 771627A US 77162747 A US77162747 A US 77162747A US 2508518 A US2508518 A US 2508518A
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fin
tube
stock
discs
length
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US771627A
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Walter P Hill
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CALUMET AND HECLA CONS COPPER
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CALUMET AND HECLA CONS COPPER
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Priority to US771627A priority Critical patent/US2508518A/en
Priority to ES0184625A priority patent/ES184625A1/en
Priority to ES0184626A priority patent/ES184626A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C37/00Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
    • B21C37/06Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of tubes or metal hoses; Combined procedures for making tubes, e.g. for making multi-wall tubes
    • B21C37/15Making tubes of special shape; Making tube fittings
    • B21C37/20Making helical or similar guides in or on tubes without removing material, e.g. by drawing same over mandrels, by pushing same through dies ; Making tubes with angled walls, ribbed tubes and tubes with decorated walls
    • B21C37/207Making helical or similar guides in or on tubes without removing material, e.g. by drawing same over mandrels, by pushing same through dies ; Making tubes with angled walls, ribbed tubes and tubes with decorated walls with helical guides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4935Heat exchanger or boiler making
    • Y10T29/49377Tube with heat transfer means
    • Y10T29/49378Finned tube
    • Y10T29/49382Helically finned
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4935Heat exchanger or boiler making
    • Y10T29/49377Tube with heat transfer means
    • Y10T29/49378Finned tube
    • Y10T29/49385Made from unitary workpiece, i.e., no assembly

Definitions

  • the invention relates to an apparatus for forming integral fins on a length of stock and forms a continuation in o!- my pending application for patent Serial No. 619,112 flled'October 1, 1945. It is the primary object of the invention to avoid any appreciable rubbing and bending of the fins during the-developing of the same which would have a detrimental effect in hardening and reducing the ductility of the-material or otherwise overworking .the same; To" this end the invention consists inthe-novelemethod and apparatus as hereinafter set forth.
  • Figure 1 is a semi-diagrammatic cross sectional view through a tube and one type of apparatus for forming fins on the tube:
  • Figure 2 is an exaggerated fragmentary sectional view showing one of the rollers in Figure 1 in fin forming operative relation to the tube and taken substantially on the line 2-2 of .
  • Figure 3 is an enlarged fragmentary sectional view illustrating a partof one of the rollers in operative relation to the tube:
  • Each roller comprises a plurality of axially spaced annular portions ,arranged to apply a generally radially inwardly directed pressure on axially spaced helically aligned peripheral portions of the blank of sufilcient. magnitude to displace material from the peripheral portion of the tubular blank and extrudethe displaced material outwardly into the spaces or grooves provided between the axially spaced peripheral portions of the rollers to form a helical fln.
  • This fin is fashioned to the desired cross sectional contour by the surfaces of the roller forming the opposite sides of the space'or groove into which it the material is extruded.
  • ' 'It' hasbeen the practice in the past to form these ⁇ roller surfaces conical and substantially straight in radial contour from the root to the periphery of the fin.
  • the helicoidal surface of a fin thus developed is not conjugate to the surface of revolution of the roller, and consequently the latter tends to distort the former, producing a bending back and .forth of the fin and a rubbing action thereon which has a hardening eflect.
  • Figure s a greatly n rged fragmentary It is the object of the instant invention to overcross sectional view showing one of the roller sections in fin forming relationship with the tube;
  • Figure 5 is a sectional'yiew taken substantially on the line H of Figured.
  • Figure 6 is an enlarged sectional view taken on the line H of Figure 5. 1
  • ai'plurality of forming rollers suitably supported for rotation with their respective axes extending in the general direction of the axis of the'tubular blank and spaced equal distances-from each "other around the tubular blank.
  • the axes of the rollers are arranged at such an angle to the axis of the tubular blank as to enable the rollers to travel a come this defect by fashioning the extruded material with surfaces of revolution which are conjugate to the helicoidal surface of the fin developed thereby. This necessitates a change in the radial contour of said surface of revolution from a rectilinear to a predetermined nonrectilinear curved form.
  • I0 is a tube a mandrel-,9 and I I is a helicalfin formed on said .tube by the operation of rollers II. II and It.
  • the method and the apparatus of developing these fins are generally the same as in the above referred to application for patent, and may be briefly described as follows.
  • the rollers-l2, [ll and It may be substantially alike in construction and are distributed about the circumference of the tube, preferably spaced apart.
  • Each roller comprises a series of individual circular porhelical path around corresponding to u tions or discs centrally apertured' toreceive an suitably supported on roller discs.
  • the axes of the arbors It, or in other words, the axes of the rollers are crossed with respect to the axis of the tube and are also arranged at such an angle to the axis of the tube In as to travel a hellcal path about the tube corresponding generally to the helix angle or. the fin to be formed on the tube.
  • the construction is such that the discs or circular portions on the respective rollers actually track with each other and cooperate to form a continuous helical fin on the peripheral surface of the tube in a manner to be more fully hereinafter described.
  • the arbors are respective ly supported on swinging arms I! enabling the rollers to be moved in directions toward and away from the axis of the tube.
  • the arbors are driven and suitable driving means (not shown) is universally connected to, the swinging arbors for this purpose.
  • each roller is shown as comprising seven discs designated in Figure 2 of the drawings by the numerals II to 23 inclusive.
  • the opposite sides of the peripheral portions of the discs are relieved to a mannerto be more fully hereinafter described, to provide spaces or grooves 24 between adjacent discs.
  • the peripheral portions of the discs are progressively increased in width slightly, say for example, .004 of an inch, from the first disc [1 to the final disc 23 with the result that the widths of the grooves 24 between the discs are correspondingly reduced.
  • This di- ⁇ mension will, of course, vary considerably depending upon the type of finned tube to be formed.
  • the arbors I! to-' gether with the rollers are swung inwardly toward the periphery of the tube and are locked in their innermost positions shown in Figure 1 oi! the drawings by any suitable means not shown.
  • the roller Owing to the. angular relationship between the axes of the rollers l2 and the tube It, the roller by gradually increasing the diameter of the discs of each roller from the first disc I! to the final disc 23.
  • the diameter differential of the first two or three discs of each roller is preferably somewhat greater than the diiferential existing between the diameters of the remaining discs, so as to assist penetration of the first discs into the surface of the tube In.
  • the roller discs apply a generally radially inwardly directed pressure on axially spaced-helically aligned peripheral portions or the tube and depresses the material from which the tube is formed against the mandrel 9 sufiiciently to displace this material first axially and then radially outwardly into the grooves 24 between adjacent termined generally by the radial contour of the surfaces 26 forming opposite sides of the grooves 24, nevertheless the cross sectional contour of the fin does not conform exactly to the cross sectional contour of the grooves 24, as evidenced by the By virtue of the frictional contact of the Although the form of the fin i i is de- 4 drawings. displacement of the material axially of the tube during the extruding operation, and the existence of these spaces clearly indicates the lack of axial compression on the material during the forming operation.
  • the side surfaces 26 are not straight in radial contour from the root to the periphery of the fin as has been the practice in the past, but on the contrary, are spheroidal in contour, or in other words, are relieved by grinding or some other process so that the disc will pass through the helicoidal path between adjacent convolutions of the fin without laterally displacing the fin or working the material to such an extent that the latter is embrittled or otherwise aiiected. There is, of course, contact between the forming discs and material forming the fin I i.
  • a typical forming disc is shown in relation to the fin, and it will be noted that the spheroidal surface 26 at one side of the disc contacts the fin at 21 above the axis of the tube l0, and the spheroidal surface at the opposite side of the disc contacts the fin at 28 below the axis of the tube.
  • the curvature of the spheroidal surfaces on opposite sides of the discs is such that no part of either surface will interfere with or displace the formed fin ll.
  • the rollers do not exe'cessively work harden the extruded material during the tin forming operation, but on the other hand, merely serve to, in effect, guide the material as it is extruded outwardly into the grooves 24. Consequently, finned tubing having such great height as to result in a ratio of outside to inside area of 10 to 1 or greater may be readily formed without the danger of detrimentally work hardening the metal forming the fins, and thus one of the chief causes of cracks or checks developing in the tubing during use is eliminated.
  • the annular side portions of said rings being convex on a curve extending radially of said rings and to an extent at least equal to the height of a formed fin, the convexity extending completely around said annular rings and said covexity being so shaped with respect to the fin to be formed that it will generate a helical path for the free but confined movement of the fin through the spaces between WALTER P. HILL.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Shaping Of Tube Ends By Bending Or Straightening (AREA)
  • Rolls And Other Rotary Bodies (AREA)

Description

May 23," 1950 w. P. HILL 2,508,518 APPARATUS FOR FORMING INTEGRAL mus on A LENGTH OF STOCK Filed Sept. 2, 1947 2 Sheets-Sheet l IN VEN TOR.
W04 r54 A A044 BY Pressed May23,l950 g I APPARATUS FOR FORMING INTEGRAL FINS ON A LENGTH OF STOCK Walter P. Hill, Detroit, Mlcln, asslgnor to Calumet and Reel: Consolidated Copper Company, Calumet, mieh a corporation of Michigan Application September 2, 1941, Serial No. 771,621
2 Claims. 1
The invention relates to an apparatus for forming integral fins on a length of stock and forms a continuation in o!- my pending application for patent Serial No. 619,112 flled'October 1, 1945. It is the primary object of the invention to avoid any appreciable rubbing and bending of the fins during the-developing of the same which would have a detrimental effect in hardening and reducing the ductility of the-material or otherwise overworking .the same; To" this end the invention consists inthe-novelemethod and apparatus as hereinafter set forth.
In the drawings: r
Figure 1 is a semi-diagrammatic cross sectional view through a tube and one type of apparatus for forming fins on the tube:
Figure 2 is an exaggerated fragmentary sectional view showing one of the rollers in Figure 1 in fin forming operative relation to the tube and taken substantially on the line 2-2 of .Figure 1; v
Figure 3 is an enlarged fragmentary sectional view illustrating a partof one of the rollers in operative relation to the tube:
the helix angle of the fin to be formed on the blank. Each roller comprises a plurality of axially spaced annular portions ,arranged to apply a generally radially inwardly directed pressure on axially spaced helically aligned peripheral portions of the blank of sufilcient. magnitude to displace material from the peripheral portion of the tubular blank and extrudethe displaced material outwardly into the spaces or grooves provided between the axially spaced peripheral portions of the rollers to form a helical fln. This fin is fashioned to the desired cross sectional contour by the surfaces of the roller forming the opposite sides of the space'or groove into which it the material is extruded.' 'It'hasbeen the practice in the past to form these} roller surfaces conical and substantially straight in radial contour from the root to the periphery of the fin. However, the helicoidal surface of a fin thus developed is not conjugate to the surface of revolution of the roller, and consequently the latter tends to distort the former, producing a bending back and .forth of the fin and a rubbing action thereon which has a hardening eflect.
Figure s a greatly n rged fragmentary It is the object of the instant invention to overcross sectional view showing one of the roller sections in fin forming relationship with the tube;
Figure 5 is a sectional'yiew taken substantially on the line H of Figured; and
Figure 6 is an enlarged sectional view taken on the line H of Figure 5. 1
In the present state of' the art, methods and apparatus of two types have been used for the development of integral hellcabfins on plain tubing. In the one, the outer portion of the tube wall is scored to form a helical groove and the material between the adjacent convolutions of the groove is compressed axially'tn reduce the a thickness thereof'and to: displace the same radially outwardly. In carrying out this method the metal is subjected to considerable working and may become hardened to such an extent as to damage ,the tube, especially in instances where fins of substantial-height are formed. In the other method, which forms the subject matter of the application for patent mentioned, a tubular blank is engaged by. ai'plurality of forming rollers suitably supported for rotation with their respective axes extending in the general direction of the axis of the'tubular blank and spaced equal distances-from each "other around the tubular blank. The axes of the rollers are arranged at such an angle to the axis of the tubular blank as to enable the rollers to travel a come this defect by fashioning the extruded material with surfaces of revolution which are conjugate to the helicoidal surface of the fin developed thereby. This necessitates a change in the radial contour of said surface of revolution from a rectilinear to a predetermined nonrectilinear curved form. The: term conjugate as used in this connection means that no portion of the roller surface which forms the fin will, during its continued rotation, interfere with or displace the fin fashioned thereby. In brief, the rollers thus modified will roll through the helical groove or space between adjacent convolutions of the fin without interference with the latter. Consequently. the liin thus formed is not work-hardened to a detrimental extent as is the case where non-conjugate rollers are used in its development.
- As illustrated I0 is a tube a mandrel-,9 and I I is a helicalfin formed on said .tube by the operation of rollers II. II and It. The method and the apparatus of developing these fins are generally the same as in the above referred to application for patent, and may be briefly described as follows. The rollers-l2, [ll and It may be substantially alike in construction and are distributed about the circumference of the tube, preferably spaced apart. Each roller comprises a series of individual circular porhelical path around corresponding to u tions or discs centrally apertured' toreceive an suitably supported on roller discs.
arbor l andhaving hubs keyed or otherwise secured to the arbor in juxtaposition to each other. The axes of the arbors It, or in other words, the axes of the rollers are crossed with respect to the axis of the tube and are also arranged at such an angle to the axis of the tube In as to travel a hellcal path about the tube corresponding generally to the helix angle or. the fin to be formed on the tube. The construction is such that the discs or circular portions on the respective rollers actually track with each other and cooperate to form a continuous helical fin on the peripheral surface of the tube in a manner to be more fully hereinafter described. In practice the arbors are respective ly supported on swinging arms I! enabling the rollers to be moved in directions toward and away from the axis of the tube. In the present instance the arbors are driven and suitable driving means (not shown) is universally connected to, the swinging arbors for this purpose.
The number of discs embodied in each roller may vary considerably, but for the purpose of iilustration, each roller is shown as comprising seven discs designated in Figure 2 of the drawings by the numerals II to 23 inclusive. The opposite sides of the peripheral portions of the discs are relieved to a mannerto be more fully hereinafter described, to provide spaces or grooves 24 between adjacent discs. Also the peripheral portions of the discs are progressively increased in width slightly, say for example, .004 of an inch, from the first disc [1 to the final disc 23 with the result that the widths of the grooves 24 between the discs are correspondingly reduced. This di-} mension will, of course, vary considerably depending upon the type of finned tube to be formed.
In operatiomafter a length of tube It is properly supported on the mandrel l, the arbors I! to-' gether with the rollers are swung inwardly toward the periphery of the tube and are locked in their innermost positions shown in Figure 1 oi! the drawings by any suitable means not shown. Owing to the. angular relationship between the axes of the rollers l2 and the tube It, the roller by gradually increasing the diameter of the discs of each roller from the first disc I! to the final disc 23. The diameter differential of the first two or three discs of each roller is preferably somewhat greater than the diiferential existing between the diameters of the remaining discs, so as to assist penetration of the first discs into the surface of the tube In.
In any case the above construction is such that the roller discs apply a generally radially inwardly directed pressure on axially spaced-helically aligned peripheral portions or the tube and depresses the material from which the tube is formed against the mandrel 9 sufiiciently to displace this material first axially and then radially outwardly into the grooves 24 between adjacent termined generally by the radial contour of the surfaces 26 forming opposite sides of the grooves 24, nevertheless the cross sectional contour of the fin does not conform exactly to the cross sectional contour of the grooves 24, as evidenced by the By virtue of the frictional contact of the Although the form of the fin i i is de- 4 drawings. displacement of the material axially of the tube during the extruding operation, and the existence of these spaces clearly indicates the lack of axial compression on the material during the forming operation.
The side surfaces 26 are not straight in radial contour from the root to the periphery of the fin as has been the practice in the past, but on the contrary, are spheroidal in contour, or in other words, are relieved by grinding or some other process so that the disc will pass through the helicoidal path between adjacent convolutions of the fin without laterally displacing the fin or working the material to such an extent that the latter is embrittled or otherwise aiiected. There is, of course, contact between the forming discs and material forming the fin I i. In Figures 4 and 5 of the drawings, a typical forming disc is shown in relation to the fin, and it will be noted that the spheroidal surface 26 at one side of the disc contacts the fin at 21 above the axis of the tube l0, and the spheroidal surface at the opposite side of the disc contacts the fin at 28 below the axis of the tube. However, the curvature of the spheroidal surfaces on opposite sides of the discs is such that no part of either surface will interfere with or displace the formed fin ll. Thus, re ardless of the diameter of the fins being formed, the rollers do not exe'cessively work harden the extruded material during the tin forming operation, but on the other hand, merely serve to, in effect, guide the material as it is extruded outwardly into the grooves 24. Consequently, finned tubing having such great height as to result in a ratio of outside to inside area of 10 to 1 or greater may be readily formed without the danger of detrimentally work hardening the metal forming the fins, and thus one of the chief causes of cracks or checks developing in the tubing during use is eliminated.
Attention is further called to the fact that while the spaces or grooves 24 progressively decrease in width from the first groove between the ad- Jacent discs 11 and It to the last groove between the adjacent discs 22 and 23,-nevertheless, no appreciable axial compression of the displaced material takes place because the shape of the radial surfaces 26 and the depth of the grooves are such that the material flows relatively freely into the grooves during the extruding operation. Thus the density of the material forming the fins is very little, if any, greater than the normal density of tne material prior to the finning opera ion.
What I claim as my invention is:
l. A roll for rolling up from the peripheral surface of a length of stock of circular cross section a helically extending fin that has a smallhelix angle in comparison to its radial height, said roll comprising a mounting aflording an axis of rotation and aseries of projections effectively forming a plurality of annular rings axially spaced along said mounting creating annular spaces therebetween, each of said rings being defined by an edge portion at the periphery of the roll and an annular side portion at each side of said edge, said rings, when the mounting is at crossed axis with the length of stock, creating a rolling pressure on the stock to progressively displace material from the stock into said annular spaces to form the helical fin, the annular side portions of said rings being convex on a curve extending radially of said rings and to an extent clearanc Spaces 2 h wn in 8 3 0f h at least equal to the height of a formed fin, the
These clearance spaces result from aaoaue 5 convexity extending completely around said annular rings and said convexity being so shaped with respect to the fin to be formed that it will generate a helical path for the free but confined movement of the fin through the spaces between the rings.
2.Apparatus for rolling up from the peripheral surface of a length of stock of circular cross section a helically extending fin that has a small helix angle in comparison to its height, comprising avplurality of rolls distributed around the length of stock with their axes extending generally in the direction of the length of the stock, each roll comprising a mounting affording an axis of rotation and a series of projections effectively forming a plurality of annular rings axially spaced along said mounting creating annular spaces therebetween, each of said rings being delined by an edge portion at the periphery of the roll and an annular side portion at each side of said edge, said rings, when the mounting is at crossed axis with the length of stock, creating a rolling pressure on the stock to progressively displace material from the stock; into said annular the rings.
spaces to form the helical fin, the annular side portions of said rings being convex on a curve extending radially of said rings and to an extent at least equal to the height of a formed fin, the convexity extending completely around said annular rings and said covexity being so shaped with respect to the fin to be formed that it will generate a helical path for the free but confined movement of the fin through the spaces between WALTER P. HILL.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS
US771627A 1947-09-02 1947-09-02 Apparatus for forming integral fins on a length of stock Expired - Lifetime US2508518A (en)

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US771627A US2508518A (en) 1947-09-02 1947-09-02 Apparatus for forming integral fins on a length of stock
ES0184625A ES184625A1 (en) 1947-09-02 1948-07-19 A METHOD FOR FORMING FULL FINS ON SMOOTH TUBE
ES0184626A ES184626A1 (en) 1947-09-02 1948-07-19 AN APPLIANCE FOR FORMING INTEGRAL FINS ON SMOOTH TUBE

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2713375A (en) * 1950-10-12 1955-07-19 Aerofin Corp Fin straightening devices
US2779223A (en) * 1955-08-24 1957-01-29 Herman A Schuster Apparatus for forming fins
US2779222A (en) * 1954-01-05 1957-01-29 Ray C Edwards Apparatus for making heat exchange tubes
US3149512A (en) * 1960-06-30 1964-09-22 William H Leinbach Method of rolling a tubing with a controlled wall thickness
US4915166A (en) * 1983-08-04 1990-04-10 Wolverine Tube, Inc. Titanium heat exchange tubes

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1761733A (en) * 1927-12-05 1930-06-03 Wolverine Tube Company Integral finned tubing and method of manufacturing the same
US1865575A (en) * 1928-11-30 1932-07-05 Wolverine Tube Company Apparatus for manufacturing integral finned tubing
US1901516A (en) * 1929-11-14 1933-03-14 Kellogg M W Co Method and machine for rolling fins on tubes
US1909005A (en) * 1930-06-16 1933-05-16 Wolverine Tube Company Method of making corrugated wall tubing
US2238798A (en) * 1937-03-10 1941-04-15 Kurt Lenk Method of and means for the production of ribbed tubes

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1761733A (en) * 1927-12-05 1930-06-03 Wolverine Tube Company Integral finned tubing and method of manufacturing the same
US1865575A (en) * 1928-11-30 1932-07-05 Wolverine Tube Company Apparatus for manufacturing integral finned tubing
US1901516A (en) * 1929-11-14 1933-03-14 Kellogg M W Co Method and machine for rolling fins on tubes
US1909005A (en) * 1930-06-16 1933-05-16 Wolverine Tube Company Method of making corrugated wall tubing
US2238798A (en) * 1937-03-10 1941-04-15 Kurt Lenk Method of and means for the production of ribbed tubes

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2713375A (en) * 1950-10-12 1955-07-19 Aerofin Corp Fin straightening devices
US2779222A (en) * 1954-01-05 1957-01-29 Ray C Edwards Apparatus for making heat exchange tubes
US2779223A (en) * 1955-08-24 1957-01-29 Herman A Schuster Apparatus for forming fins
US3149512A (en) * 1960-06-30 1964-09-22 William H Leinbach Method of rolling a tubing with a controlled wall thickness
US4915166A (en) * 1983-08-04 1990-04-10 Wolverine Tube, Inc. Titanium heat exchange tubes

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Publication number Publication date
ES184625A1 (en) 1948-12-16
ES184626A1 (en) 1948-12-16

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