US2496903A - Photographic developer containing a negatively substituted aralkylamine and process of development - Google Patents
Photographic developer containing a negatively substituted aralkylamine and process of development Download PDFInfo
- Publication number
- US2496903A US2496903A US786816A US78681647A US2496903A US 2496903 A US2496903 A US 2496903A US 786816 A US786816 A US 786816A US 78681647 A US78681647 A US 78681647A US 2496903 A US2496903 A US 2496903A
- Authority
- US
- United States
- Prior art keywords
- development
- color
- developer
- developing
- photographic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/29—Development processes or agents therefor
- G03C5/305—Additives other than developers
Definitions
- V 1 This invention relates to photographic deing color images in multi-color photographic velopers and particularly to accelerators for layers containing color-formers fast to diffusion, photographic developers. as disclosed in United States Patents 2,178,612;
- these amines accelerate ellent quality- 7 the development so as to cause the developing
- the developing e w th black and white agent to form the image (silver or color image) developers, for instance, solutions of hydromore rapidly than is possible without the presquinone and monomethylam ne- -p S111- ence of such amines.
- an object of the present invention to provide a black and white and color p-chlorobenzylamine developer having an increased rate of development so that the developing time is substantially GENE decreased to about one-half of the normal time.
- Example I Grams p-Monomethylamine-m-phenol sulfate 0.8 Sodium sulfite (anhydrous) 45 Hydroquinone 1.2 Sodium carbonate (monohydrate) 8 Potassium metabisulfite 4 Potassium bromide 1.5 p-Chlorobenzylamine 4 Water to make liter 1
- This tank developer gives, on development at 20 C. of the usual roll film, a soft negative in about 6-10 minutes after fixing and washing. The time required to develop a similar roll in the same developer and at the same temperature, but containing no p-chlorobenzylamine, ranges from 15 to 20 minutes. Increasing the concentration of the p-chlorobenzylamine to '7 grams per liter effects a further decrease in time.
- Example II The following developer requires 30 minutes at 20 C. to give a satisfactory degree of color development with color paper:
- the color paper utilized in the foregoing example, consists of an integral tripack emulsion coated on either the usual paper base, or a clear cellulose acetate or nitrate film base, or in some cases an opaque white film base.
- Each of the emulsion layers is sensitized to one of the primary colors of light; namely, blue, green and red.
- the top layer is blue sensitive.
- a filter layer, yellow in color and blue absorbing, lies under the top layer. Below this filter layer, lies a green sensitive emulsion layer, and below this a red sensitive emulsion layer.
- Each of the three silver-halide emulsion layers contains dye-forming compounds which unite during the development of a silver image in an aromatic amine developing agent to form a dye with the oxidation product of the developing agent.
- a yellow dye is formed in the blue sensitive emulsion; a magenta dye is formed in the green sensitive emulsion; and a cyan dye is formed in the red sensitive emulsion.
- the combination of the dye images from these three printing primaries yields the color picture.
- Suitable methods for the preparation of multicolor emulsion layers have been described in the literature relating to color photography, and
- Example III The following developer requires 19 minutes at 20 C. to give a satisfactory degree of color development with color paper:
- R is a group selected from the class consisting of methyl and ethyl groups
- n is a positive integer of from 1 to 2
- X is a negative group selected from the class consisting of nitro and halogen atoms, and the salts of said amines.
- R is a group selected from the class consisting of methyl and ethyl groups
- n is a positive integer of from 1 to 2
- X is a negative group selected from the class consisting of nitro and halogen atoms, and the salts of said amines.
- a color-forming photographic developer comprising a primary aromatic amino developing agent and a negatively substituted aralkylamine selected from the class consisting of those corresponding to the following formulae:
- R is a group selected from the class consisting of methyl and ethyl groups
- n is a positive integer of from 1 to 2
- X is a negative group selected from the class consisting of nitro and halogen atoms, and the salts of said amines.
- a color forming photographic developer REFERENCES CITED comprising a, primary aromatic amino develop- I ing agent and a negatively substituted aralkylg z Z ES i Rq i of record m the amine characterized by the following formula: p
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE485786D BE485786A (fr) | 1947-11-18 | ||
US786816A US2496903A (en) | 1947-11-18 | 1947-11-18 | Photographic developer containing a negatively substituted aralkylamine and process of development |
GB22075/48A GB641405A (en) | 1947-11-18 | 1948-08-21 | Photographic developer containing a negatively substituted aralkylamine and process of development |
FR973438D FR973438A (fr) | 1947-11-18 | 1948-10-12 | Révélateurs photographiques |
DEP29336D DE848911C (de) | 1947-11-18 | 1949-01-01 | Entwickler fuer Schwarzweiss- und Mehrfarbenbilder |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US786816A US2496903A (en) | 1947-11-18 | 1947-11-18 | Photographic developer containing a negatively substituted aralkylamine and process of development |
Publications (1)
Publication Number | Publication Date |
---|---|
US2496903A true US2496903A (en) | 1950-02-07 |
Family
ID=25139663
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US786816A Expired - Lifetime US2496903A (en) | 1947-11-18 | 1947-11-18 | Photographic developer containing a negatively substituted aralkylamine and process of development |
Country Status (5)
Country | Link |
---|---|
US (1) | US2496903A (fr) |
BE (1) | BE485786A (fr) |
DE (1) | DE848911C (fr) |
FR (1) | FR973438A (fr) |
GB (1) | GB641405A (fr) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2605183A (en) * | 1949-11-16 | 1952-07-29 | Gen Aniline & Film Corp | Heterocyclic alkylamines as accelerators for photographic developers |
DE1106444B (de) * | 1955-03-30 | 1961-05-10 | California Research Corp | Verfahren zur Veredelung einer Erdoelfraktion mit verhaeltnismaessig niedrigem Stickstoffgehalt |
US4189319A (en) * | 1975-07-18 | 1980-02-19 | Gaf Corporation | Arginine or salt thereof as a development accelerator of color development of color photographic materials |
EP0202616A2 (fr) | 1985-05-16 | 1986-11-26 | Konica Corporation | Procédé pour le développement couleur d'un matériau photographique à l'halogénure d'argent sensible à la lumière |
EP0204530A2 (fr) | 1985-05-31 | 1986-12-10 | Konica Corporation | Procédé de formation d'une image directement positive en couleur |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2410644A (en) * | 1943-09-02 | 1946-11-05 | Eastman Kodak Co | Development of photographic emulsions |
-
0
- BE BE485786D patent/BE485786A/xx unknown
-
1947
- 1947-11-18 US US786816A patent/US2496903A/en not_active Expired - Lifetime
-
1948
- 1948-08-21 GB GB22075/48A patent/GB641405A/en not_active Expired
- 1948-10-12 FR FR973438D patent/FR973438A/fr not_active Expired
-
1949
- 1949-01-01 DE DEP29336D patent/DE848911C/de not_active Expired
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2410644A (en) * | 1943-09-02 | 1946-11-05 | Eastman Kodak Co | Development of photographic emulsions |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2605183A (en) * | 1949-11-16 | 1952-07-29 | Gen Aniline & Film Corp | Heterocyclic alkylamines as accelerators for photographic developers |
DE1106444B (de) * | 1955-03-30 | 1961-05-10 | California Research Corp | Verfahren zur Veredelung einer Erdoelfraktion mit verhaeltnismaessig niedrigem Stickstoffgehalt |
US4189319A (en) * | 1975-07-18 | 1980-02-19 | Gaf Corporation | Arginine or salt thereof as a development accelerator of color development of color photographic materials |
EP0202616A2 (fr) | 1985-05-16 | 1986-11-26 | Konica Corporation | Procédé pour le développement couleur d'un matériau photographique à l'halogénure d'argent sensible à la lumière |
EP0204530A2 (fr) | 1985-05-31 | 1986-12-10 | Konica Corporation | Procédé de formation d'une image directement positive en couleur |
Also Published As
Publication number | Publication date |
---|---|
DE848911C (de) | 1952-09-08 |
GB641405A (en) | 1950-08-09 |
FR973438A (fr) | 1951-02-09 |
BE485786A (fr) |
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