US2496903A - Photographic developer containing a negatively substituted aralkylamine and process of development - Google Patents

Photographic developer containing a negatively substituted aralkylamine and process of development Download PDF

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Publication number
US2496903A
US2496903A US786816A US78681647A US2496903A US 2496903 A US2496903 A US 2496903A US 786816 A US786816 A US 786816A US 78681647 A US78681647 A US 78681647A US 2496903 A US2496903 A US 2496903A
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US
United States
Prior art keywords
development
color
developer
developing
photographic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US786816A
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English (en)
Inventor
William L Wasley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GAF Chemicals Corp
Original Assignee
General Aniline and Film Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE485786D priority Critical patent/BE485786A/xx
Application filed by General Aniline and Film Corp filed Critical General Aniline and Film Corp
Priority to US786816A priority patent/US2496903A/en
Priority to GB22075/48A priority patent/GB641405A/en
Priority to FR973438D priority patent/FR973438A/fr
Priority to DEP29336D priority patent/DE848911C/de
Application granted granted Critical
Publication of US2496903A publication Critical patent/US2496903A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C5/00Photographic processes or agents therefor; Regeneration of such processing agents
    • G03C5/26Processes using silver-salt-containing photosensitive materials or agents therefor
    • G03C5/29Development processes or agents therefor
    • G03C5/305Additives other than developers

Definitions

  • V 1 This invention relates to photographic deing color images in multi-color photographic velopers and particularly to accelerators for layers containing color-formers fast to diffusion, photographic developers. as disclosed in United States Patents 2,178,612;
  • these amines accelerate ellent quality- 7 the development so as to cause the developing
  • the developing e w th black and white agent to form the image (silver or color image) developers, for instance, solutions of hydromore rapidly than is possible without the presquinone and monomethylam ne- -p S111- ence of such amines.
  • an object of the present invention to provide a black and white and color p-chlorobenzylamine developer having an increased rate of development so that the developing time is substantially GENE decreased to about one-half of the normal time.
  • Example I Grams p-Monomethylamine-m-phenol sulfate 0.8 Sodium sulfite (anhydrous) 45 Hydroquinone 1.2 Sodium carbonate (monohydrate) 8 Potassium metabisulfite 4 Potassium bromide 1.5 p-Chlorobenzylamine 4 Water to make liter 1
  • This tank developer gives, on development at 20 C. of the usual roll film, a soft negative in about 6-10 minutes after fixing and washing. The time required to develop a similar roll in the same developer and at the same temperature, but containing no p-chlorobenzylamine, ranges from 15 to 20 minutes. Increasing the concentration of the p-chlorobenzylamine to '7 grams per liter effects a further decrease in time.
  • Example II The following developer requires 30 minutes at 20 C. to give a satisfactory degree of color development with color paper:
  • the color paper utilized in the foregoing example, consists of an integral tripack emulsion coated on either the usual paper base, or a clear cellulose acetate or nitrate film base, or in some cases an opaque white film base.
  • Each of the emulsion layers is sensitized to one of the primary colors of light; namely, blue, green and red.
  • the top layer is blue sensitive.
  • a filter layer, yellow in color and blue absorbing, lies under the top layer. Below this filter layer, lies a green sensitive emulsion layer, and below this a red sensitive emulsion layer.
  • Each of the three silver-halide emulsion layers contains dye-forming compounds which unite during the development of a silver image in an aromatic amine developing agent to form a dye with the oxidation product of the developing agent.
  • a yellow dye is formed in the blue sensitive emulsion; a magenta dye is formed in the green sensitive emulsion; and a cyan dye is formed in the red sensitive emulsion.
  • the combination of the dye images from these three printing primaries yields the color picture.
  • Suitable methods for the preparation of multicolor emulsion layers have been described in the literature relating to color photography, and
  • Example III The following developer requires 19 minutes at 20 C. to give a satisfactory degree of color development with color paper:
  • R is a group selected from the class consisting of methyl and ethyl groups
  • n is a positive integer of from 1 to 2
  • X is a negative group selected from the class consisting of nitro and halogen atoms, and the salts of said amines.
  • R is a group selected from the class consisting of methyl and ethyl groups
  • n is a positive integer of from 1 to 2
  • X is a negative group selected from the class consisting of nitro and halogen atoms, and the salts of said amines.
  • a color-forming photographic developer comprising a primary aromatic amino developing agent and a negatively substituted aralkylamine selected from the class consisting of those corresponding to the following formulae:
  • R is a group selected from the class consisting of methyl and ethyl groups
  • n is a positive integer of from 1 to 2
  • X is a negative group selected from the class consisting of nitro and halogen atoms, and the salts of said amines.
  • a color forming photographic developer REFERENCES CITED comprising a, primary aromatic amino develop- I ing agent and a negatively substituted aralkylg z Z ES i Rq i of record m the amine characterized by the following formula: p

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
US786816A 1947-11-18 1947-11-18 Photographic developer containing a negatively substituted aralkylamine and process of development Expired - Lifetime US2496903A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BE485786D BE485786A (fr) 1947-11-18
US786816A US2496903A (en) 1947-11-18 1947-11-18 Photographic developer containing a negatively substituted aralkylamine and process of development
GB22075/48A GB641405A (en) 1947-11-18 1948-08-21 Photographic developer containing a negatively substituted aralkylamine and process of development
FR973438D FR973438A (fr) 1947-11-18 1948-10-12 Révélateurs photographiques
DEP29336D DE848911C (de) 1947-11-18 1949-01-01 Entwickler fuer Schwarzweiss- und Mehrfarbenbilder

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US786816A US2496903A (en) 1947-11-18 1947-11-18 Photographic developer containing a negatively substituted aralkylamine and process of development

Publications (1)

Publication Number Publication Date
US2496903A true US2496903A (en) 1950-02-07

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
US786816A Expired - Lifetime US2496903A (en) 1947-11-18 1947-11-18 Photographic developer containing a negatively substituted aralkylamine and process of development

Country Status (5)

Country Link
US (1) US2496903A (fr)
BE (1) BE485786A (fr)
DE (1) DE848911C (fr)
FR (1) FR973438A (fr)
GB (1) GB641405A (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2605183A (en) * 1949-11-16 1952-07-29 Gen Aniline & Film Corp Heterocyclic alkylamines as accelerators for photographic developers
DE1106444B (de) * 1955-03-30 1961-05-10 California Research Corp Verfahren zur Veredelung einer Erdoelfraktion mit verhaeltnismaessig niedrigem Stickstoffgehalt
US4189319A (en) * 1975-07-18 1980-02-19 Gaf Corporation Arginine or salt thereof as a development accelerator of color development of color photographic materials
EP0202616A2 (fr) 1985-05-16 1986-11-26 Konica Corporation Procédé pour le développement couleur d'un matériau photographique à l'halogénure d'argent sensible à la lumière
EP0204530A2 (fr) 1985-05-31 1986-12-10 Konica Corporation Procédé de formation d'une image directement positive en couleur

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2410644A (en) * 1943-09-02 1946-11-05 Eastman Kodak Co Development of photographic emulsions

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2410644A (en) * 1943-09-02 1946-11-05 Eastman Kodak Co Development of photographic emulsions

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2605183A (en) * 1949-11-16 1952-07-29 Gen Aniline & Film Corp Heterocyclic alkylamines as accelerators for photographic developers
DE1106444B (de) * 1955-03-30 1961-05-10 California Research Corp Verfahren zur Veredelung einer Erdoelfraktion mit verhaeltnismaessig niedrigem Stickstoffgehalt
US4189319A (en) * 1975-07-18 1980-02-19 Gaf Corporation Arginine or salt thereof as a development accelerator of color development of color photographic materials
EP0202616A2 (fr) 1985-05-16 1986-11-26 Konica Corporation Procédé pour le développement couleur d'un matériau photographique à l'halogénure d'argent sensible à la lumière
EP0204530A2 (fr) 1985-05-31 1986-12-10 Konica Corporation Procédé de formation d'une image directement positive en couleur

Also Published As

Publication number Publication date
DE848911C (de) 1952-09-08
GB641405A (en) 1950-08-09
FR973438A (fr) 1951-02-09
BE485786A (fr)

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