US2495237A - Method of making sponge-forming compositions - Google Patents
Method of making sponge-forming compositions Download PDFInfo
- Publication number
- US2495237A US2495237A US765649A US76564947A US2495237A US 2495237 A US2495237 A US 2495237A US 765649 A US765649 A US 765649A US 76564947 A US76564947 A US 76564947A US 2495237 A US2495237 A US 2495237A
- Authority
- US
- United States
- Prior art keywords
- fibers
- sponge
- viscose
- forming composition
- forming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 26
- 238000004519 manufacturing process Methods 0.000 title description 5
- 239000000835 fiber Substances 0.000 description 29
- 229920000297 Rayon Polymers 0.000 description 18
- 239000000243 solution Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 7
- 229920002678 cellulose Polymers 0.000 description 6
- 239000001913 cellulose Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000011282 treatment Methods 0.000 description 6
- 238000009736 wetting Methods 0.000 description 6
- 235000011837 pasties Nutrition 0.000 description 5
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 5
- 239000002993 sponge (artificial) Substances 0.000 description 5
- 241000243142 Porifera Species 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 238000009827 uniform distribution Methods 0.000 description 3
- 244000025254 Cannabis sativa Species 0.000 description 2
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 2
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 235000009120 camo Nutrition 0.000 description 2
- 235000005607 chanvre indien Nutrition 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 239000011487 hemp Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- BDKLKNJTMLIAFE-UHFFFAOYSA-N 2-(3-fluorophenyl)-1,3-oxazole-4-carbaldehyde Chemical compound FC1=CC=CC(C=2OC=C(C=O)N=2)=C1 BDKLKNJTMLIAFE-UHFFFAOYSA-N 0.000 description 1
- PJAIMBYNTXNOCN-UHFFFAOYSA-N 3,6-dibromo-1h-indole Chemical compound BrC1=CC=C2C(Br)=CNC2=C1 PJAIMBYNTXNOCN-UHFFFAOYSA-N 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000408495 Iton Species 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- XYQRXRFVKUPBQN-UHFFFAOYSA-L Sodium carbonate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]C([O-])=O XYQRXRFVKUPBQN-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- LUTSRLYCMSCGCS-BWOMAWGNSA-N [(3s,8r,9s,10r,13s)-10,13-dimethyl-17-oxo-1,2,3,4,7,8,9,11,12,16-decahydrocyclopenta[a]phenanthren-3-yl] acetate Chemical compound C([C@@H]12)C[C@]3(C)C(=O)CC=C3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)C)C1 LUTSRLYCMSCGCS-BWOMAWGNSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- DGLRDKLJZLEJCY-UHFFFAOYSA-L disodium hydrogenphosphate dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].OP([O-])([O-])=O DGLRDKLJZLEJCY-UHFFFAOYSA-L 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- -1 dodecahydrate Chemical compound 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000004686 pentahydrates Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- VZOPRCCTKLAGPN-ZFJVMAEJSA-L potassium;sodium;(2r,3r)-2,3-dihydroxybutanedioate;tetrahydrate Chemical compound O.O.O.O.[Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O VZOPRCCTKLAGPN-ZFJVMAEJSA-L 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229940087562 sodium acetate trihydrate Drugs 0.000 description 1
- 229940018038 sodium carbonate decahydrate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2301/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
Definitions
- This invention relates to artificial. sponges. More particularly, it relates to an artificial sponge-forming composition wherein the fibers are uniformly distributed throughout the mass.
- a pasty orplastic sponge-forming composition comprising a solution of a cellulosic or other substance, fibers, and a pore-forming material such as a fusible and/or soluble granular material, was molded into a desired shape and, after coagulation, subjected to appropriate finishing treatments.
- the sponge-forming composition was prepared by mixing the solution with the fibers and thereafter the pore-forming substance was incorporated.
- the fibers of the sponge-forming composition were poorly distributed throughout the mass and even tended in part to form agglomerates which were of course prejudicial to the mechanical strength of the finished sponges.
- An object of this invention is to provide a new and improved method of making spongeforming compositions.
- Another object of this invention is to make a sponge-forming composition free of agglomerates of fibers.
- An additional object of this invention is to provide a method of incorporating the fibers uniformly throughout the sponge-forming mass.
- the solution for preliminarily treating the fibers is a solution of medium viscosity, i. e. 10 to 40 centipoises, and is preferably of the same nature as but more dilute than the liquid vehicle of the pasty or plastic sponge-forming composition.
- medium viscosity i. e. 10 to 40 centipoises
- the preliminary wetting of the fibers is obtained with a viscose solution which is more dilute than the viscose of the sponge-forming composition.
- the preliminary treatment is obtained by impregnating the fibers with the dilute viscose solution and removing the excess solution in any convenient manner, such as by centrifuging.
- Example 1 or pasty mass, and then 40o gs. of sodium sulfate decahydrate were incorporated into the mass with vigorous malaxing.
- the fibers in fthe resulting: pasty or plastic sponge-forming composition were uniformly dispersed and distributed throughout the mass.
- ihe sponge-forming composition was extruded from a press irrto molds which were subjected to a coagulating treatment, with. a saturatedsolution of sodium sulfate at C,., in an autoclave.
- the coagulated blocks were removed from the molds and then subjected to the usual finishing treatments.
- the artificial sponges obtained by cutting the molded blocks were characterized by an extremely uniform distribution of the fibers and had a breaking strength in all three directions of 0.1 to 0.2 kg/cm. greater than that of artificial sponges manufactured by the prior art processes wherein the fibers were not preliminarily wetted.
- the viscose solution which is employed for the preliminary wetting of the fibers is not restricted to the composition set forth in the example. In general, dilute viscose containing 0.5% to 3.0% cellulose can be used for the wetting of the fibers. However, viscose containing more than 3% and less than 0.5% of cellulose can be used.
- the viscose employed for the wetting is preferably made by diluting the concentrated viscose which is to constitute the vehicle of the sponge-forming com-
- the dilute viscose employed for the preliminary wetting of the fibers may contain all or part of the soluble colors or pigments which are to be incorporated in-the final sponge. -It may also contain all or a part of any other appropriate ad- .dition, such as wetting agents, fillers, etc., to be incorporated in the sponge-forming composition.
- the pore-forming substance is sodium sulfate decahydrate or fused sodium sulfate decahydrate, itflis to be understood that the invention is not restricted. thereto" and that various other poreforming substances can be used;;: In general, crystalline or amorphous substances-which melt .01" dissolve easily can be used.
- pore-forming substances which may be'used.
- the pore-forming substance may be "selectedas to size and shape so as to produce a texture very similar to natural sponges.
- hemp fibers disclosed in the exam- 4 ple other textile fibers, such as linen, jute, cotton and the like, of any appropriate dimension can be used.
- the proportions of the components of the sponge-forming composition are not restricted to that set forth in the example since they can be modified and varied as is well known in the art.
- the sponge-forming composition can be molded into blocks of the desired shape by the use of any appropriate press.
- the composition is especially suitable for molding in a press, such as is disclosed in French patent of addition No. 43,394 to French Patent 812,502.
- Theinvention provides a simple and economical process of producing a sponge-forming composition wherein the fibers are uniformly distributed throughout the mass of the composition.
- the uniform distribution of the fibers in the sponge-forming composition there is obtained artificial sponges in which the fibers are uniformly distributed throughout the mass and have improved mechanical properties.
- an artificial spongeforming composition comprising viscose, fibers and pore-forming materials
- the steps which comprise wetting the fibers with a viscose solution containing 1.8% cellulose, removing the excess cellulose solution and thoroughly dispersing said fibers while still wet in a sponge-forming composition containing 16% cellulose and. a crystal- .line, water-soluble, pore-forming material.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Description
Patented Jan. 24, 1950 METHOD OF MAKING SPONGE-FORMING COMPOSITIONS Andre C. Petiton, St. Just-les-Marais, France, assignor, by mesne assignments, to Societe Ncvacel, Paris, France, a corporation of France No Drawing. Application August 1, 1947, Serial No. 765,649. In France October 14, 1946 This invention relates to artificial. sponges. More particularly, it relates to an artificial sponge-forming composition wherein the fibers are uniformly distributed throughout the mass.
In the most generally employed process for the manufacture of artificial sponges, a pasty orplastic sponge-forming composition comprising a solution of a cellulosic or other substance, fibers, and a pore-forming material such as a fusible and/or soluble granular material, was molded into a desired shape and, after coagulation, subjected to appropriate finishing treatments. The sponge-forming composition was prepared by mixing the solution with the fibers and thereafter the pore-forming substance was incorporated.
In the manufacture of artificial sponges from viscose, the pasty or plastic sponge-forming composition, which consisted essentially of viscose, appropriate length fibers of flax, hemp, etc. and
crystals of sodium sulfate decahydrate, was molded. After coagulation by means of a hot concentrated solution of sodium sulfate, the molded product was fixed with acid and then subjected to the appropriate finishing treatments. In such process, a concentrated viscose, such as one containing to 14% of cellulose or even more, was utilized.
The fibers of the sponge-forming composition were poorly distributed throughout the mass and even tended in part to form agglomerates which were of course prejudicial to the mechanical strength of the finished sponges.
Many attempts have been made to obtain uniform distribution of the fibers in the viscose sponge-forming composition. One of the proposals contemplated adding a wetting agent to the viscose, but no agent which improved the distribution of the fibers appreciably was found. Preliminary alkaline treatments of the fibers prior to incorporation in the viscose also did not produce satisfactory results.
An object of this invention is to provide a new and improved method of making spongeforming compositions.
Another object of this invention is to make a sponge-forming composition free of agglomerates of fibers.
An additional object of this invention is to provide a method of incorporating the fibers uniformly throughout the sponge-forming mass.
Other and additional objects will become apparent hereinafter.
The objects of this invention are accomplished,
in general, by preliminarily treating the fibers 1 Claim. (Cl. 106-122).
with a solution to wet the same and thereafter incorporating the wetted fibers in the spongeforming composition. The solution for preliminarily treating the fibers is a solution of medium viscosity, i. e. 10 to 40 centipoises, and is preferably of the same nature as but more dilute than the liquid vehicle of the pasty or plastic sponge-forming composition. Thus, in a viscose sponge-forming composition, the preliminary wetting of the fibers is obtained with a viscose solution which is more dilute than the viscose of the sponge-forming composition.
In the preferred embodiment, the preliminary treatment is obtained by impregnating the fibers with the dilute viscose solution and removing the excess solution in any convenient manner, such as by centrifuging.
The details and manner of practicing the invention will become apparent by reference to the following specific example, it being understood that the example is merely an illustrative embodiment of the invention and that the scope of the invention is not limited thereto. Throughout the example, the proportions of the ingredients are parts by weight. 1
Example 1 or pasty mass, and then 40o gs. of sodium sulfate decahydrate were incorporated into the mass with vigorous malaxing.
The fibers in fthe resulting: pasty or plastic sponge-forming composition were uniformly dispersed and distributed throughout the mass.
ihe sponge-forming composition was extruded from a press irrto molds which were subjected to a coagulating treatment, with. a saturatedsolution of sodium sulfate at C,., in an autoclave. The coagulated blocks were removed from the molds and then subjected to the usual finishing treatments.
The artificial sponges obtained by cutting the molded blocks were characterized by an extremely uniform distribution of the fibers and had a breaking strength in all three directions of 0.1 to 0.2 kg/cm. greater than that of artificial sponges manufactured by the prior art processes wherein the fibers were not preliminarily wetted.
The viscose solution which is employed for the preliminary wetting of the fibers is not restricted to the composition set forth in the example. In general, dilute viscose containing 0.5% to 3.0% cellulose can be used for the wetting of the fibers. However, viscose containing more than 3% and less than 0.5% of cellulose can be used. The viscose employed for the wetting is preferably made by diluting the concentrated viscose which is to constitute the vehicle of the sponge-forming com- The dilute viscose employed for the preliminary wetting of the fibers may contain all or part of the soluble colors or pigments which are to be incorporated in-the final sponge. -It may also contain all or a part of any other appropriate ad- .dition, such as wetting agents, fillers, etc., to be incorporated in the sponge-forming composition.
Instead of the use of sodium sulfate decahydrate of the example, the semi-fused sulfate disclosed in copending application of Nicolas Drisch, Serial No. 631,473, filed November 28, 1945, now Patent No. 2,464,772, can be used as the poreforming substance.
Though in the preferred form of the invention the pore-forming substance is sodium sulfate decahydrate or fused sodium sulfate decahydrate, itflis to be understood that the invention is not restricted. thereto" and that various other poreforming substances can be used;;: In general, crystalline or amorphous substances-which melt .01" dissolve easily can be used. .Paraifin, stearin and salts rich in water of crystallization and readily fusible, such as sodium acetate trihydrate, sodium carbonate decahydrate, trisodium phosphate, dodecahydrate, disodium phosphate dodecahydrate, potassium sodium tartrate tetrahydrate, potassium fluoride dihydrate, and sodium thicsulfate pentahydrate, are illustrative examples of pore-forming substances which may be'used." The pore-forming substance may be "selectedas to size and shape so as to produce a texture very similar to natural sponges. Instead of hemp fibers disclosed in the exam- 4 ple, other textile fibers, such as linen, jute, cotton and the like, of any appropriate dimension can be used.
The proportions of the components of the sponge-forming composition are not restricted to that set forth in the example since they can be modified and varied as is well known in the art.
The sponge-forming composition can be molded into blocks of the desired shape by the use of any appropriate press. The composition is especially suitable for molding in a press, such as is disclosed in French patent of addition No. 43,394 to French Patent 812,502.
Theinvention provides a simple and economical process of producing a sponge-forming composition wherein the fibers are uniformly distributed throughout the mass of the composition. By virtue of the uniform distribution of the fibers in the sponge-forming composition, there is obtained artificial sponges in which the fibers are uniformly distributed throughout the mass and have improved mechanical properties.
Since. it is obvious that various changes and modifications can be made in the above description without departing from the nature or spirit thereof, this invention is not restricted thereto except as set forth in the appended claim.
I claim:
In the method of preparing an artificial spongeforming composition comprising viscose, fibers and pore-forming materials, the steps which comprise wetting the fibers with a viscose solution containing 1.8% cellulose, removing the excess cellulose solution and thoroughly dispersing said fibers while still wet in a sponge-forming composition containing 16% cellulose and. a crystal- .line, water-soluble, pore-forming material.
ANDRE: c'. PE'I'ITON.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 602,797 Annison Apr. 19, 1898 1,611,056 Mostny Dec. 14, 1926 2,016,719 Huey Oct. 8, 1935 2,295,823 Banigan Sept. 15, 1942 2,341,509 Bley Feb. 15, 1944
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR934767T | 1946-10-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2495237A true US2495237A (en) | 1950-01-24 |
Family
ID=9456400
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US765649A Expired - Lifetime US2495237A (en) | 1946-10-14 | 1947-08-01 | Method of making sponge-forming compositions |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US2495237A (en) |
| BE (1) | BE474133A (en) |
| FR (1) | FR934767A (en) |
| GB (1) | GB638530A (en) |
| NL (1) | NL67685C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2706159A (en) * | 1951-03-09 | 1955-04-12 | American Enka Corp | Manufacture of artificial sponges |
| US2853395A (en) * | 1954-03-12 | 1958-09-23 | Du Pont | Cellulosic sponge process |
| US3110602A (en) * | 1960-04-20 | 1963-11-12 | Nylonge Corp | The method of producing a regenerated cellulose sponge |
| US7563239B1 (en) * | 2005-09-02 | 2009-07-21 | Rebecca W. Hudson, legal representative | Ear exfoliating swab system |
| CN106008724A (en) * | 2016-06-27 | 2016-10-12 | 恒天海龙（潍坊）新材料有限责任公司 | Cellulose foam material and method for improving tensile strength of cellulose foam material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US602797A (en) * | 1898-04-19 | Frederick george annison | ||
| US1611056A (en) * | 1925-02-25 | 1926-12-14 | Mostny Ludwig | Process of making artificial sponges |
| US2016719A (en) * | 1930-06-27 | 1935-10-08 | Sayles Finishing Plants Inc | Viscose coating and filling |
| US2295823A (en) * | 1940-06-05 | 1942-09-15 | Du Pont | Artificial structure |
| US2341509A (en) * | 1937-11-06 | 1944-02-15 | North American Rayon Corp | Viscose solution |
-
1946
- 1946-10-14 FR FR934767D patent/FR934767A/en not_active Expired
-
1947
- 1947-05-27 NL NL132432A patent/NL67685C/en active
- 1947-06-26 BE BE474133A patent/BE474133A/en unknown
- 1947-08-01 US US765649A patent/US2495237A/en not_active Expired - Lifetime
- 1947-10-14 GB GB27515/47A patent/GB638530A/en not_active Expired
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US602797A (en) * | 1898-04-19 | Frederick george annison | ||
| US1611056A (en) * | 1925-02-25 | 1926-12-14 | Mostny Ludwig | Process of making artificial sponges |
| US2016719A (en) * | 1930-06-27 | 1935-10-08 | Sayles Finishing Plants Inc | Viscose coating and filling |
| US2341509A (en) * | 1937-11-06 | 1944-02-15 | North American Rayon Corp | Viscose solution |
| US2295823A (en) * | 1940-06-05 | 1942-09-15 | Du Pont | Artificial structure |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2706159A (en) * | 1951-03-09 | 1955-04-12 | American Enka Corp | Manufacture of artificial sponges |
| US2853395A (en) * | 1954-03-12 | 1958-09-23 | Du Pont | Cellulosic sponge process |
| US3110602A (en) * | 1960-04-20 | 1963-11-12 | Nylonge Corp | The method of producing a regenerated cellulose sponge |
| US7563239B1 (en) * | 2005-09-02 | 2009-07-21 | Rebecca W. Hudson, legal representative | Ear exfoliating swab system |
| CN106008724A (en) * | 2016-06-27 | 2016-10-12 | 恒天海龙（潍坊）新材料有限责任公司 | Cellulose foam material and method for improving tensile strength of cellulose foam material |
Also Published As
| Publication number | Publication date |
|---|---|
| BE474133A (en) | 1947-07-31 |
| FR934767A (en) | 1948-06-01 |
| NL67685C (en) | 1951-04-16 |
| GB638530A (en) | 1950-06-07 |
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