US2489042A - Recovery of naphthalene and homologues from petroleum products - Google Patents
Recovery of naphthalene and homologues from petroleum products Download PDFInfo
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- US2489042A US2489042A US7956A US795648A US2489042A US 2489042 A US2489042 A US 2489042A US 7956 A US7956 A US 7956A US 795648 A US795648 A US 795648A US 2489042 A US2489042 A US 2489042A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
- C10G21/06—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
- C10G21/12—Organic compounds only
- C10G21/20—Nitrogen-containing compounds
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- ncovnmr oF NAPHTHALENE AND aoMoLoGUEs Fnou PETROLEUM PRODUCTS Filed Feb. 12. 1948 2 Sheets-Sheet 1 Patented Nov. 22, 1949 RECOVERY OF NAPHTHALENE AND HOMO- LOGUES FROM PETROLEUM PRODUCTS Eugene C. Medcalf and Hal B. H. Cooper, Bound Brook, and William ⁇ E asslgnors to American York, N.
- fractions which contain various amounts of condensed nuclei aromatics which fractions are often referred to aslight cycle gas oils from the fact that the fraction can be recycled through a catalytic process if necessary.
- This fraction usually has an aromatic content which will vary from about 1% to 30% or more.
- the aromatics of the fraction are predominantly condensed nuclei compounds, for the most part naphthalene and its homologues. In most cases the content of naphthalene and its homologues is at least 50% and sometimes as high as 80% or slightly more. Petroleum products from somewhat diierent cracking cycles are also known which contain aromatics although the light cycle gas oil is the largest available source having substantial content of naphthalene and its homologues.
- the present invention is based on the discovery that iminodipropionitrile having the formula CHzCHzCN CHsCHiCN possesses an extraordinarily high selective solvent action for condensed nuclei aromatics such as naphthalene and its homologues.
- the selectivity is so high that even with raw materials having high content of naphthalene, non-aromatic hydrocarbons are practically immiscible at room temperature.
- the process of the present invention can be used to separate naphthalenes from petroleum products containing them in widely varying proportions from very lean products having as low as 1% of aromatics up to relatively richer products which have 30 or more per cent aromatics.
- An additional advantage of the present invention is the high overall emciency based on the solvent.
- the negligible solubility in non-aromatic hydrocarbons makes the recovery problem Very simple.
- the amount of iminodipropionitrile in the non-aromatic fraction may be so low that it can be neglected, but if it is desired to recover it, the recovery presents no problem as treatment with water removes any traces of iminodipropionitrile from the non-aromatic ranate and the recovery from the water layer is simple because the iminodipropionitrile does not have any material vapor pressure below the boiling point of water. A complete separation by distillation is, therefore, a simple matter.
- the recovery of the naphthalenes from the iminodipropionitrile extract is simple. Typical methods are vacuum distillation, steam stripping, and separation by means of Water. In the latter two cases the negligible volatility of the iminodipropionitrile makes the recovery of the solvent from the associated water easy.
- the process of the present invention can be used with a wide range vof petroleum products containing varying contents of condensed nuclei aromatics.
- the composition of the aromatics recovered depends, of course, on the source. If it is desired to obtain a high proportion of naphthalene itself, petroleum products may be sharply fractionated so that the naphthalene is not associated with large amounts of homologues. On the other hand, in many cases it is preferable to use the process of the present invention to separate a product which is a mixture of naphthalene f and its homologues, the separation of the diiferent aromatics being effected in a later stage.
- the reduced pressure distillation method is used in isolating the naphthalene from other iminodipropionitrile extracts, this may be carried out if desired as a fractional distillation in order to produce a product which is substantially free from non-aromatic hydrocarbons.
- This renders further purification of the naphthaene very simple and is of special interest where the naphthalene is to be transformed into a product of very high purity for use inthe dyestuff industry.
- the thorough removal of non-aromatic hydrocarbons is particularly useful as they present a serious problem for separation when fractional distillation processes are used. Many of the typical non-aromatic hydrocarbons, such as, for example, n-dodecane, tend to form azeotropes with the naphthalenes which defeats fractional distillation.
- the solubility of naphthalenes in iminodipropionitrile is not materially increased by high temperatures, even up to 200 C.
- the solubility of alicyclic compounds does become-quite extensive at higher temperatures.
- most alicycllc compounds. such as, for example. hydrogenated naphthalenes, are quite soluble in iminodlpropionitrile and the solubility is still high at about 100 C.
- the solubility becomes sufficiently great to be a material factor at about 404i C. This differential solubility of the alicyclics at various temperatures may be utilized to effect a three-product separation.
- the petroleum product may be ex tracted with iminodipropionitrile at 100 C., or higher, the two layers separated and the extract cooled, for example, to room temperature.
- iminodipropionitrile at 100 C., or higher
- the two layers separated and the extract cooled, for example, to room temperature.
- This will separate out from the extract practically all of the alicyclic compounds which can be recovered by separation, the aromatics remaining in solution at room temperature'being then recovered in the usual manner.
- Another way of using the differential solubility of aiicyclics with temperature is to extract first at room temperature, producing an extract containing only the aromatics.
- the two layers are separated and the raiiinate can then be extracted with iminodipropionitrile at a high temperature such as 1GO-125 C., in order to obtain a hot extract containing the major portion of the alicyclic compounds in the raiiinate.
- the alicyclics may be removed from the extract by cooling, treatment with water, or other means.
- Fig. 1 is a series of chromatographic adsorption curves comparing the adsorption of furfural with that of iminodipropionitrile, and
- Fig. 2 is a similar set of chromatographic adsorption curves showing aromatic and alicyclic extracts.
- Example 1 A light cycle gas oil from Texas crude having a 30% aromatic content, of which approximately 80% was naphthalene and homologues, was divided into three portions. One portion was subjected to a diierential chromatographic adsorption by adsorping a unit quantity in silica gel and progressively driving it out with methyl alcohol as a desorbing liquid. The refractive indices of A second portion of the light cycle gas oil was treated at 1.25 volumes of wet furfural to produce an extract and a rafiinate. The furfural was then removed from the aromatic extract by the customary bisulte solution, the aromatics dried and subjected to the same chromatographic adsorption and desorption in silica gel as described above in conjunction with the starting material. A chromatographic curve was obtained and is shown in dotted lines on the drawing. The refractive index of the aromaticextract before chromatographic treatment is shown by the dotted arrow.
- a third sample of the gas oil was subjected to a single stage extraction with an equal volume of iminodipropionitrile producing an aromatic extract and a raihnate, and the aromatic extract after separation was washed with water to remove the solvent, dried, and subjected to chromatographic adsorption and desorption as described above.
- the chromatographic curve is shown on the drawings in full lines, the refractive index of the extract as a whole being indicated by the full line arrow.
- the chromatographic curves, material having a refractive index below 1 5 is aliphatic and for the most part parailins. Between a refractive index of 1.50 and 1.56 the products are predominantly alicyclic and above 1.56 they are predominantiy aromatic. A small amount of highly alkylated benzenes appear in the broad range of the refractive indices typical of the alicyclics.
- the process of the present invention using iminodipropionitrile produced an extract in which the non-aromatics have been reduced to about '7%. and the aliphatics are not more than about 4%. In other Words, almost all of the aliphatics, such as dodecane, have been removed, thus eliminating any purification problem due to azeotrope formation.
- the alicyclics are present in equally small amounts and their removal is a simple matter. Losses of iminodipropionitrile in the ramnate are negligible as it is present only in traces. The amount is so small that it is not essential to recover it.
- Example 2 I The relative. solubilities of aliphatics and naphthalene in iminodipropionitrile was tested as follows.
- a 50-50 mixture of naphthalene and iminodipropionitrile was prepared. This product forms a completely homogeneous liquid at 69 C. With lower contents of naphthalene, homogenecus liquids are obtainable at temperatures ranging down to room temperature and below.
- Example 3 Light cycle gas oil was fractionally distilled to produce a fraction containing substantially naphthalene as its aromatic content. This fraction had a crystallizing point of 32.6 C. and had a naphthalene content of about 20%. The product was subjected to a single stage extraction with an equal volume of iminodipropionitrile at room temperature and the solvent layer steam stripped. A naphthalene was obtained having a crystallizing point of 58.9 C. which represents a naphthalene content of approximately 60%.
- Example 4 The eiect of various concentractions of methyl naphthalenes in a mixture, the non-aromatic portion of which was mainly n-dodecane, was determined.
- the methyl naphthalene which had a high content of the alpha isomer had a refractive index of 1.6142, the dodecane 1.4211.
- Four mixtures were prepared containing 2%, 25%, 50%, and 75% methyl naphthalene. These were then subjected to a single stage extraction with iminodipropionitrile as described in Example 1, producing a rafnate and an extract from which the 20 methyl naphthalenes were removed.
- the following table shows the refractive indices of the original mixture of railinate and methyl naphthalenes recovered from the extract.
- Example 5 A sample of light cycle gas oil having a refractive index of 1.5138 was extracted at 125 C. with 50 an equal volume of iminodipropionitrile. Two layers were produced and separated, yielding a ranate with a refractive index of 1.4995; in other words, one which contains substantially only aliphatics, and an extract. The extract was then cooled to room temperature, a separate layer formed which was recovered by separation and had a refractive index of 1.5246. In other words, this product was substantially alicyclics. The iminodipropionitrile solution was then treated w with water to recover the hydrocarbons which had a refractive index of 1.5782. These Were substantially all aromatics. The alicyclic product obtained by cooling the hot iminodipropionitrile extract amounted to about 4-5% of the Weight of 65 the gas oil, whereas the aromatics were about 11%.
- Example 6 Light cycle gas oil of Example 5 was subjected 70 to an extraction with an equal amount of iminodipropionitrile at room temperature.
- the extract and raffinate were separated and the hydrocarbons recovered from the extract as described in the preceding example. They showed extract and a second ralnate which were'separated, the rafnate had a refractive index of 1.4750, and thus was substantially aliphatic in nature.
- the extract was then cooled to room temperature, a hydrocarbon separated out and was recovered and showed a refractive index of 1.5152. It was, therefore, mainly alicyclic.
- the iminodipropionitrile extract still contained a small amount of hydrocarbon which was removed as described in the preceding example and showed a refractive index of 1.5643. In other words, it was a mixture of alicyclics and aromatics with the latter predominating.
- Example 7 A petroleum product was used as the test material, containing about 25% of tetrahydronaphthalene having a refractive index of 1.5414; 25% of alphamethylnaphthalene having a refractive index of 1.614; and 50% of aliphatic hydrocarbons predominantly n-dodecane having a refractive index of 1.4272. This mixture was extracted at room temperature with an equal volume of iminodipropionitrile. The extract and raffinate were separated and the hydrocarbons recovered from the extract as described above. They had a refractive index of 1.5762 and, therefore, showed a high content of aromatics.
- the rainate was then extracted at 125 C. with an equal volume of iminodipropionitrile.
- the two layers were separated, one being a second rainate having a refractive index of 1.4632 and being substantially aliphatic in nature.
- the extract was slowly cooled. Turbidity began to be noticeable at about C. and at 40-50 C. the major portion of the tetrahydronaphthalene had separated out leaving a small amount of extract from which the hydrocarbon was removed in the usual manner and possessed a refractive index of 1.5616. It was thus a mixture of alphamethylnaphthalene and tetrahydronaphthalene.
- the cooling should preferably be continued to 40-50 C. as at temperatures above this point, the solubility of the alicyclics is quite appreciable.
- the method of recovering condensed nuclei aromatics and alicyclics from petroleum products containing the same in admixture with aliphatic hydrocarbons which comprises extracting the mixture with iminodipropionitrile at a temperature of at least about 100 C. to produce rainate and extract layers, separating the layers, cooling the extract to a temperature not above 40-50 C. whereby alicyclics separate, recovering the separated liquids and recovering the condensed nuclei aromatics from the remaining solution.
- the method of recovering naphthalenes and hydrogenated naphthalenes from petroleum products containing the same in admixture with aliphatic hydrocarbons which comprises extracting the mixture with iminodipropionitrile at a temperature of at least about 100 C. to produce raffinate and extract layers, separating the layers, cooling the extract to a temperature not above 40-50" C. whereby hydrogenated naphthalenes separate, recovering the separated liqnids and recovering the naphthalenes from the remaining solution.
- the method of recovering naphthalenes and hydrogenated naphthalenes from petroleum products containing the same in admixture with laliphatic hydrocarbons which comprises extract- 5.
- the method of recovering naphthalene and hydrogenated naphthalenes from petroleum products containing the same in admixture with aliphatic hydrocarbons which comprises extracting the mixture with iminodipropionitrile at a temperature of at least 100 C. to produce raftinate and extract layers, separating the layers, cooling the extract to a temperature not above -50 C. whereby hydrogenated naphthalenes separate, recovering the separated liquids and recovering the naphthalene from the remaining solution.
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Description
NOV- 22, 1949 E. c. MEDcALF ErAL 2,489,042
ncovnmr oF NAPHTHALENE AND aoMoLoGUEs Fnou PETROLEUM PRODUCTS Filed Feb. 12. 1948 2 Sheets-Sheet 1 Patented Nov. 22, 1949 RECOVERY OF NAPHTHALENE AND HOMO- LOGUES FROM PETROLEUM PRODUCTS Eugene C. Medcalf and Hal B. H. Cooper, Bound Brook, and William`E asslgnors to American York, N.
Sisco, Somerville, N. J., Cyanamid Company, New Y., a corporation of Maine Application February 12, 1948, Serial No. 7,956 6 Claims. (Cl. 260-674) 'I'his invention relates to a process of recovering condensed nuclei aromatic compounds from petroleum products containing the same, and more particularly the recovery of naphthalene and its homologues.
In the catalytic cracking of petroleum, there are produced fractions which contain various amounts of condensed nuclei aromatics which fractions are often referred to aslight cycle gas oils from the fact that the fraction can be recycled through a catalytic process if necessary. This fraction usually has an aromatic content which will vary from about 1% to 30% or more. The aromatics of the fraction are predominantly condensed nuclei compounds, for the most part naphthalene and its homologues. In most cases the content of naphthalene and its homologues is at least 50% and sometimes as high as 80% or slightly more. Petroleum products from somewhat diierent cracking cycles are also known which contain aromatics although the light cycle gas oil is the largest available source having substantial content of naphthalene and its homologues.
Various methods have been used in the past to produce concentrates containing higher proportions of aromatics from the petroleum products of the type referred to above. One of the best known involves the use of wet furfural as a selective solvent for aromatics.V While furfural has been practically used, its selectivity leaves much to be desired and particularly when used with a raw material having a high aromatic content. In such cases, the selectivity drops off more sharply.
The present invention is based on the discovery that iminodipropionitrile having the formula CHzCHzCN CHsCHiCN possesses an extraordinarily high selective solvent action for condensed nuclei aromatics such as naphthalene and its homologues. The selectivity is so high that even with raw materials having high content of naphthalene, non-aromatic hydrocarbons are practically immiscible at room temperature.
The process of the present invention can be used to separate naphthalenes from petroleum products containing them in widely varying proportions from very lean products having as low as 1% of aromatics up to relatively richer products which have 30 or more per cent aromatics.
process to a large products is an important alect the separation. It is, however, not necessary to have any particular water content and this lack of critical composition makes the practical operating control much simpler.
An additional advantage of the present invention is the high overall emciency based on the solvent. The negligible solubility in non-aromatic hydrocarbons makes the recovery problem Very simple. In some cases, the amount of iminodipropionitrile in the non-aromatic fraction may be so low that it can be neglected, but if it is desired to recover it, the recovery presents no problem as treatment with water removes any traces of iminodipropionitrile from the non-aromatic ranate and the recovery from the water layer is simple because the iminodipropionitrile does not have any material vapor pressure below the boiling point of water. A complete separation by distillation is, therefore, a simple matter.
The recovery of the naphthalenes from the iminodipropionitrile extract is simple. Typical methods are vacuum distillation, steam stripping, and separation by means of Water. In the latter two cases the negligible volatility of the iminodipropionitrile makes the recovery of the solvent from the associated water easy.
The process of the present invention can be used with a wide range vof petroleum products containing varying contents of condensed nuclei aromatics. The composition of the aromatics recovered depends, of course, on the source. If it is desired to obtain a high proportion of naphthalene itself, petroleum products may be sharply fractionated so that the naphthalene is not associated with large amounts of homologues. On the other hand, in many cases it is preferable to use the process of the present invention to separate a product which is a mixture of naphthalene f and its homologues, the separation of the diiferent aromatics being effected in a later stage.
Where the reduced pressure distillation method is used in isolating the naphthalene from other iminodipropionitrile extracts, this may be carried out if desired as a fractional distillation in order to produce a product which is substantially free from non-aromatic hydrocarbons. This renders further purification of the naphthaene very simple and is of special interest where the naphthalene is to be transformed into a product of very high purity for use inthe dyestuff industry. The thorough removal of non-aromatic hydrocarbons is particularly useful as they present a serious problem for separation when fractional distillation processes are used. Many of the typical non-aromatic hydrocarbons, such as, for example, n-dodecane, tend to form azeotropes with the naphthalenes which defeats fractional distillation. p
While it is an important advantage of the present invention that the solubility of naphthalenes in iminodipropionitrile is not materially increased by high temperatures, even up to 200 C., the solubility of alicyclic compounds does become-quite extensive at higher temperatures. At 125 C. most alicycllc compounds. such as, for example. hydrogenated naphthalenes, are quite soluble in iminodlpropionitrile and the solubility is still high at about 100 C. The solubility becomes sufficiently great to be a material factor at about 404i C. This differential solubility of the alicyclics at various temperatures may be utilized to effect a three-product separation. Thus, for example, the petroleum product may be ex tracted with iminodipropionitrile at 100 C., or higher, the two layers separated and the extract cooled, for example, to room temperature. This will separate out from the extract practically all of the alicyclic compounds which can be recovered by separation, the aromatics remaining in solution at room temperature'being then recovered in the usual manner.
Another way of using the differential solubility of aiicyclics with temperature is to extract first at room temperature, producing an extract containing only the aromatics. The two layers are separated and the raiiinate can then be extracted with iminodipropionitrile at a high temperature such as 1GO-125 C., in order to obtain a hot extract containing the major portion of the alicyclic compounds in the raiiinate. After separation of the two layers, the alicyclics may be removed from the extract by cooling, treatment with water, or other means.
The invention will be described in connection with the following specic examples which are typical and in connection with the drawings in which:
Fig. 1 is a series of chromatographic adsorption curves comparing the adsorption of furfural with that of iminodipropionitrile, and
Fig. 2 is a similar set of chromatographic adsorption curves showing aromatic and alicyclic extracts.
Example 1 A light cycle gas oil from Texas crude having a 30% aromatic content, of which approximately 80% was naphthalene and homologues, was divided into three portions. One portion was subjected to a diierential chromatographic adsorption by adsorping a unit quantity in silica gel and progressively driving it out with methyl alcohol as a desorbing liquid. The refractive indices of A second portion of the light cycle gas oil was treated at 1.25 volumes of wet furfural to produce an extract and a rafiinate. The furfural was then removed from the aromatic extract by the customary bisulte solution, the aromatics dried and subjected to the same chromatographic adsorption and desorption in silica gel as described above in conjunction with the starting material. A chromatographic curve was obtained and is shown in dotted lines on the drawing. The refractive index of the aromaticextract before chromatographic treatment is shown by the dotted arrow.
A third sample of the gas oil was subjected to a single stage extraction with an equal volume of iminodipropionitrile producing an aromatic extract and a raihnate, and the aromatic extract after separation was washed with water to remove the solvent, dried, and subjected to chromatographic adsorption and desorption as described above. The chromatographic curve is shown on the drawings in full lines, the refractive index of the extract as a whole being indicated by the full line arrow.
y0n the chromatographic curves, material having a refractive index below 1 5 is aliphatic and for the most part parailins. Between a refractive index of 1.50 and 1.56 the products are predominantly alicyclic and above 1.56 they are predominantiy aromatic. A small amount of highly alkylated benzenes appear in the broad range of the refractive indices typical of the alicyclics.
It will be noted that the aromatics constituted 30% of the original gas oil and the aliphatics about 45%. Furfural extraction produced a product in which the aliphatic content was reduced only to about 18 to 20%, the aromatic content being raised to about 50%, leaving almost 30% of contaminating alicyclics.
The process of the present invention using iminodipropionitrile produced an extract in which the non-aromatics have been reduced to about '7%. and the aliphatics are not more than about 4%. In other Words, almost all of the aliphatics, such as dodecane, have been removed, thus eliminating any purification problem due to azeotrope formation. The alicyclics are present in equally small amounts and their removal is a simple matter. Losses of iminodipropionitrile in the ramnate are negligible as it is present only in traces. The amount is so small that it is not essential to recover it.
Example 2 I The relative. solubilities of aliphatics and naphthalene in iminodipropionitrile was tested as follows.
A 50-50 mixture of naphthalene and iminodipropionitrile was prepared. This product forms a completely homogeneous liquid at 69 C. With lower contents of naphthalene, homogenecus liquids are obtainable at temperatures ranging down to room temperature and below.
When an equal mixture of n-dodecane and iminodipropionitrile was heated at 55 C., complete separation into layers resulted and on dilution of the iminodipropionitrile with water only traces of dodecane could be observed.
An equal mixture of n-dodecane and iminodipropionitrile was heated to 200 C. Even at this temperature there was no appreciable solubility of the dodecane in the nitrile.
Example 3 Light cycle gas oil was fractionally distilled to produce a fraction containing substantially naphthalene as its aromatic content. This fraction had a crystallizing point of 32.6 C. and had a naphthalene content of about 20%. The product was subjected to a single stage extraction with an equal volume of iminodipropionitrile at room temperature and the solvent layer steam stripped. A naphthalene was obtained having a crystallizing point of 58.9 C. which represents a naphthalene content of approximately 60%.
Example 4 The eiect of various concentractions of methyl naphthalenes in a mixture, the non-aromatic portion of which was mainly n-dodecane, was determined. The methyl naphthalene which had a high content of the alpha isomer had a refractive index of 1.6142, the dodecane 1.4211. Four mixtures were prepared containing 2%, 25%, 50%, and 75% methyl naphthalene. These were then subjected to a single stage extraction with iminodipropionitrile as described in Example 1, producing a rafnate and an extract from which the 20 methyl naphthalenes were removed. The following table shows the refractive indices of the original mixture of railinate and methyl naphthalenes recovered from the extract.
Nn No2@ N D2 Methyl Naphthalene Mixture Ranate Extract 2 percent 1.4251 l. 4213 1.6115 25 percent 1.4704 l. 4543 1.6102 50 percent 1. 5130 l. 487() l. 6120 30 75 percent 1. 5660 1. 5279 1. 6110 It will be noted that the reduction of the dodecane was just as complete with the mixture containing the enormous proportion of 75% of 35 methyl naphthalene, far in excess of any petroleum fraction, but, of course, there are limits to the amount of methyl naphthalene which can be extracted with the relatively small volume of iminodipropionitrile. This is reflected in the index of the raffinate which shows that when there was more than methyl naphthalene, some of the naphthalene could not be dissolved in the small amount of iminodipropionitrile used, but even in this case the reduction of the dodecane 4.5 was just as complete.
Example 5 A sample of light cycle gas oil having a refractive index of 1.5138 was extracted at 125 C. with 50 an equal volume of iminodipropionitrile. Two layers were produced and separated, yielding a ranate with a refractive index of 1.4995; in other words, one which contains substantially only aliphatics, and an extract. The extract was then cooled to room temperature, a separate layer formed which was recovered by separation and had a refractive index of 1.5246. In other words, this product was substantially alicyclics. The iminodipropionitrile solution was then treated w with water to recover the hydrocarbons which had a refractive index of 1.5782. These Were substantially all aromatics. The alicyclic product obtained by cooling the hot iminodipropionitrile extract amounted to about 4-5% of the Weight of 65 the gas oil, whereas the aromatics were about 11%.
Example 6 Light cycle gas oil of Example 5 was subjected 70 to an extraction with an equal amount of iminodipropionitrile at room temperature. The extract and raffinate were separated and the hydrocarbons recovered from the extract as described in the preceding example. They showed extract and a second ralnate which were'separated, the rafnate had a refractive index of 1.4750, and thus was substantially aliphatic in nature. The extract was then cooled to room temperature, a hydrocarbon separated out and was recovered and showed a refractive index of 1.5152. It was, therefore, mainly alicyclic. At
room temperature, the iminodipropionitrile extract still contained a small amount of hydrocarbon which was removed as described in the preceding example and showed a refractive index of 1.5643. In other words, it was a mixture of alicyclics and aromatics with the latter predominating.
Chromatographic adsorption curves of the aromatic and alicyclic extracts described in Figs. 5 and 6, are shown in Fig. 2 of the drawings. It will be apparent that the aromatic extract was substantiallyfree from aliphatic constituents and that the alicyclic extract shows a marked enrichment in alicyclic material over the original light cycle gas oil.
Example 7 A petroleum product was used as the test material, containing about 25% of tetrahydronaphthalene having a refractive index of 1.5414; 25% of alphamethylnaphthalene having a refractive index of 1.614; and 50% of aliphatic hydrocarbons predominantly n-dodecane having a refractive index of 1.4272. This mixture was extracted at room temperature with an equal volume of iminodipropionitrile. The extract and raffinate were separated and the hydrocarbons recovered from the extract as described above. They had a refractive index of 1.5762 and, therefore, showed a high content of aromatics.
The rainate was then extracted at 125 C. with an equal volume of iminodipropionitrile. The two layers were separated, one being a second rainate having a refractive index of 1.4632 and being substantially aliphatic in nature. The extract was slowly cooled. Turbidity began to be noticeable at about C. and at 40-50 C. the major portion of the tetrahydronaphthalene had separated out leaving a small amount of extract from which the hydrocarbon was removed in the usual manner and possessed a refractive index of 1.5616. It was thus a mixture of alphamethylnaphthalene and tetrahydronaphthalene.
It will be noted that when it is desired to separate the alicyclics from aromatics in a hot iminodipropionitrile extract, the cooling should preferably be continued to 40-50 C. as at temperatures above this point, the solubility of the alicyclics is quite appreciable.
We claim:
1. The method of recovering condensed nuclei aromatics and alicyclics from petroleum products containing the same in admixture with aliphatic hydrocarbons which comprises extracting the mixture with iminodipropionitrile at a temperature of at least about 100 C. to produce rainate and extract layers, separating the layers, cooling the extract to a temperature not above 40-50 C. whereby alicyclics separate, recovering the separated liquids and recovering the condensed nuclei aromatics from the remaining solution.
2. The method of recovering condensed nuclei aromatics and alicyclics from petroleum prod-` ucts containing the same in admixture with aliphatic hydrocarbons which comprises extracting the mixture with iminodipropionitrile at room temperature to produce raffinate and extract layers, separating the layers, recovering the condensed Anuclei aromatics from the extract, extracting the ramnate with iminodipropionitrile at a temperature at least as high as 100 C. to produce raffinate and extract layers, separating the layers and recovering alicyclic compounds from the extracts.
3. The method of recovering naphthalenes and hydrogenated naphthalenes from petroleum products containing the same in admixture with aliphatic hydrocarbons which comprises extracting the mixture with iminodipropionitrile at a temperature of at least about 100 C. to produce raffinate and extract layers, separating the layers, cooling the extract to a temperature not above 40-50" C. whereby hydrogenated naphthalenes separate, recovering the separated liqnids and recovering the naphthalenes from the remaining solution.
4. The method of recovering naphthalenes and hydrogenated naphthalenes from petroleum products containing the same in admixture with laliphatic hydrocarbons which comprises extract- 5. The method of recovering naphthalene and hydrogenated naphthalenes from petroleum products containing the same in admixture with aliphatic hydrocarbons which comprises extracting the mixture with iminodipropionitrile at a temperature of at least 100 C. to produce raftinate and extract layers, separating the layers, cooling the extract to a temperature not above -50 C. whereby hydrogenated naphthalenes separate, recovering the separated liquids and recovering the naphthalene from the remaining solution.
6. The method of recovering naphthalene and hydrogenated naphthalenes from petroleum products containing the same in admixture with aliphatic hydrocarbons which comprises extracting the mixture with iminodipropionitrile at room temperature to produce raffinate and ex'- REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Name Date Wilkes; Jr Apr. 13, 1948 Number
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US7956A US2489042A (en) | 1948-02-12 | 1948-02-12 | Recovery of naphthalene and homologues from petroleum products |
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US7956A US2489042A (en) | 1948-02-12 | 1948-02-12 | Recovery of naphthalene and homologues from petroleum products |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2652436A (en) * | 1949-12-07 | 1953-09-15 | Texas Co | Process for separating polycyclic aromatic compounds from organic mixtures |
US2652435A (en) * | 1949-11-14 | 1953-09-15 | Texas Co | Process for separating polycyclic aromatic compounds from organic mixtures |
US2735874A (en) * | 1956-02-21 | Separation of hydrocarbons and other |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2439534A (en) * | 1945-04-07 | 1948-04-13 | Carbide & Carbon Chem Corp | Extraction of hydrocarbons |
-
1948
- 1948-02-12 US US7956A patent/US2489042A/en not_active Expired - Lifetime
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2439534A (en) * | 1945-04-07 | 1948-04-13 | Carbide & Carbon Chem Corp | Extraction of hydrocarbons |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2735874A (en) * | 1956-02-21 | Separation of hydrocarbons and other | ||
US2652435A (en) * | 1949-11-14 | 1953-09-15 | Texas Co | Process for separating polycyclic aromatic compounds from organic mixtures |
US2652436A (en) * | 1949-12-07 | 1953-09-15 | Texas Co | Process for separating polycyclic aromatic compounds from organic mixtures |
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