US3725254A - Process for the separation of aromatic hydrocarbons from a mixed hydrocarbon feedstock - Google Patents
Process for the separation of aromatic hydrocarbons from a mixed hydrocarbon feedstock Download PDFInfo
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- US3725254A US3725254A US00162178A US3725254DA US3725254A US 3725254 A US3725254 A US 3725254A US 00162178 A US00162178 A US 00162178A US 3725254D A US3725254D A US 3725254DA US 3725254 A US3725254 A US 3725254A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/10—Purification; Separation; Use of additives by extraction, i.e. purification or separation of liquid hydrocarbons with the aid of liquids
Definitions
- the primary solvent is a watersoluble organic solvent, which has a higher boiling point than and is non-azeotropic with the feedstock
- the secondary solvent is selected from the group consisting of paraiiinic and naphthenic hydrocarbons and mixtures thereof, said hydrocarbons having higher boiling points than and being non-azeotropic with the feedstock, and wherein the primary solvent is maintained in sufficient amount to extract essentially all of the aromatic hydrocarbons from the feedstock and the secondary solvent is maintained in sufficient amount to act as a reiiux for the feedstock;
- step (c) Contacting said primary extract with the secondary solvent in a secondary extraction zone wherein the temperature and pressure are in the same range as in step (a) and the secondary solvent is maintained in suicient amount to extract essentially all of the aromatic hydrocarbons from the primary extract;
- step (i) withdrawing the vapor phase mixture of benzene and toluene from the aromatics distillation zone in step (h) 3,725,254 Patented Apr. 3, 1973 ice and subjecting same to distillation to separate the benzene from the toluene;
- step (j) withdrawing the liquid phase C8 aromatics, benzene, and toluene from the aromatics distillation zone in step (h) and subjecting same to distillation in a side-distillation zone, said side-distillation zone containing about 40 to 60 percent of the number of equilibrium stages contained in the aromatics distillation zone and having a maximum temperature of at least C. less than the maximum temperature of the aromatics distillation zone, and separating the C8 aromatics from the benzene and toluene;
- step (k) Recycling the benzene and toluene from step (j) to the aromatics distillation zone;
- step (l) withdrawing the secondary solvent from the aromatics distillation zone of step (h) and recycling such secondary solvent to at least one of the extnaction zones.
- This invention relates to an improvement in a process for the separation of aromatic hydrocarbons from a mixed hydrocarbon feedstock and, more particularly, to the recovery of aromatic hydrocarbons using minimal distillatron requirements.
- BTX benzene-toluene-C8 aromatics fraction
- An object of this invention is to provide a process for the separation of aromatic hydrocarbons from a mixed hydrocarbon feedstock whereby high purity and high recovery of aromatics are achieved while reducing the amount of apparatus and the external heating requirements.
- aromatic hydrocarbons are effectively separated from mixed hydrocarbon feedstocks containing aliphatic and aromatic hydrocarbons, said aromatic hydrocarbons being comprised of benzene, toluene, and C8 aromatics by a continuous process comprising the following steps:
- the primary solvent is a water-soluble organic solvent, which has a higher boiling point than and is non-azeotropic with the feedstock
- the secondary solvent is selected from the group consisting of paraflinic and naphthenic hydrocarbons and mixtures thereof, said hydrocarbons having higher boiling points than and being non-azeotropic with the feedstock, and wherein the primary solvent is maintained in sufficient amount to extract essentially all of the aromatic hydrocarbons from the feedstock and the secondary solvent is maintained in sufficient amount to act as a reflux for the feedstock;
- step (c) Contacting said primary extract with the secondary solvent in a secondary extraction zone wherein the temperature and pressure are in the same range as in step (a) and the secondary solvent is maintained in sufficient amount to extract essentially all of the aromatic hydrocarbons from the primary extract;
- step (i) Withdrawing the vapor phase mixture of benzene and toluene from the aromatics distillation zone in step (h) and subjecting same to distillation to separate the benzene from the toluene;
- step (l) Withdrawing the liquid phase C8 aromatics, benzene, and toluene from the aromatics distillation zone in step (h) and subjecting same to distillation in a sidedistillation zone, said side-distillation zone containing about 40 to 60 percent of ⁇ the number ⁇ of equilibrium stages contained in the aromatics distillation zone and lhaving a maximum temperature of at least 75 C. less than the maximum temperature of the aromatics distillation zone, and separating the C8 aromatics from the benzene and toluene;
- step (k) Recycling the benzene and toluene from step (j) to the aromatics distillation zone;
- step (l) Withdrawing the secondary solvent from the aromatics distillation zone of step (h) and recycling such secondary solvent to at least one of the extraction zones.
- BTX which is available in high proportion, e.g., greater than 30 percent by weight, in a wide variety of hydrocarbon feedstocks such as reformed gasolines; coke oven light Oils; cracked gasolines; and dripolenes, which, after hydrogenation, can contain as much as 70 to 98 percent BTX.
- feedstocks also contain both aliphatic and cycloaliphatic hydrocarbons. Since the individual hydrocarbon compounds whichmake up these feedstocks are well known, they will not be discussed extensively; however, it can be pointed out that the major components of the feedstocks are hydrocarbons with boiling points ranging from 60 C. to 200 C. including straight-chain and branched-chain parafiins and naphthenes, such as n-heptane, isooctane, and methyl cyclohexane, and aromatics such as BTX.
- the BTX fraction can include, benzene, toluene, the C8 aromatics including ortho-xylene, meta-xylene, paraxylene, and ethyl benzene, and C9 aromatics, which, if present at all, appear in the smallest proportion in relation to the other components.
- the process described herein can be applied to feeds containing, in the aromatics portion, per se mixtures of benzene and toluene or toluene and C8 aromatics. This feature will be discussed further below.
- the primary solvent is defined above as a water-soluble oragnic solvent, which has a higher boiling point than and is non-azeotropic with the feedstock. It is also polar.
- sol-vents which may be used in the process of this invention as primary solvents are dipropylene glycol, tripropylene glycol, dibutylene glycol, tributylene glycol, ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, sulfolane, N-methyl pyrrolidone, triethylene glycol, tetraethylene glycol, ethylene glycol diethyl ether, propylene glycol monoethyl ether, pentaethylene glycol, hexaethylene glycol, and mixtures thereof.
- the preferred group of solvents are polyalkylene glycols and the preferred solvent is tetraethylene glycol. It should be noted that the feedstock and primary solvent must be selected so that the definition of the primary solvent, set forth above, is satisfied, i.e., with respect to boiling point and azeotropic characteristics.
- the secondary solvent is defined above as a solvent selected from the group consisting of paraffinic and naphthenic hydrocarbons and mixtures thereof, said hydrocarbons having higher boiling points than and being nonazeotropic with the feedstock.
- the primary solvent both the feedstock and secondary solvent must be selected so that the definition of the secondary solvent is satisfied.
- secondary solvents which may be used alone or together are n-decane, n-dodecane, 2-rnethyl decane, 2,2-dimethyl decane, n-hexyl cyclohexane, Z-methyl hexyl cyclohexane, tridecane, n-tetradecane, n-pentadecane, nhexadecane, n-heptadecane, n-octadecane and n-nonadecane, Generally, a mixture in the form of a fraction wherein the components boil within a particular range is used.
- the apparatus used in the process both for extraction and distillation is conventional, eg., an extraction co1- umn of the multistage reciprocating type containing a plurality of perforated plates centrally mounted on a vertical shaft driven by a motor in an oscillatory manner can be used as well as columns containing pumps with settling zones, sieve trays with upcomers, or even a hollow tube while the distillation can be conducted in a packed or bubble plate fractionating column. Countercurrent ows are utilized in both extraction and distillation columns.
- the feedstock is introduced through line 1 at about the middle tray of primary extractor 2; primary solvent, essentially free of water (trace amounts may be present), is introduced at the top tray of primary extractor 2; and secondary solvent is introduced below the bottom tray of primary extractor 2.
- the function of the secondary solvent in the primary extractor is to act as a reflux, i.e., to purify the aromatics present in the feedstock.
- the primary solvent is introduced into and maintained in the primary extractor in siricient amount to extract essentially all of the aromatic hydrocarbons from the feedstock and the secondary solvent is introduced into and maintained therein in sufficient amount to act as a reflux for the feedstock.
- the ratio of primary solvent to feedstock in the primary extractor is in the range of about 6 to about 16 parts by weight of primary solvent to one part by weight of feedstock. This broad range can be expanded upon Where non-preferred solvents are used.
- a broad range of about 8 to about 14 parts by weight of primary solvent to one part by weight of feedstock and a preferred range of about 9 parts to about ll parts of primary solvent per part of feedstock can be used successfully for the solvent of preference and other like solvents.
- the ratio is selected by the technician based on experience with the particular feedstock and depends in part upon whether high recovery or high purity is being emphasized.
- the suggested ratio of primary solvent to secondary solvent in the primary extractor being in the range of about ⁇ 0.5 part to about 20' parts by weight of primary solvent to one part by weight of secondary solvent and, preferably, about parts to about l5 parts by weight of primary solvent per part of secondary solvent.
- the temperature in the primary extractor is in the range of about 50 C. to about 150 C. and is preferably in the range of about 80 C. to about 110 C., especially for the solvent of preference.
- the pressure in the primary extractor is in the range of about atmospheric pressure to about 200 pounds per square inch absolute (p.s.i.a.). As is well known in the art, however, one selected pressure is not maintained throughout the extraction zone, but, rather, a high pressure within the stated range is present at the bottom of the zone and a low pressure again within the stated range is present at the top of the zone with an intermediate pressure in the middle of the zone.
- the pressures in the zone depend on the design of the equipment and the temperature, both of which are adjusted to maintain the pressure within the stated range, which is important if the preferred mode of taking a liquid overhead in the extraction Zones is to be achieved.
- the raffinate is such a liquid taken overhead. It includes the feed aliphatics, essentially all of the reflux secondary solvent, some entrained primary solvent, and may contain C9 aromatics in very small proportion.
- the raffinate leaves the primary extractor via overhead line 3 and passes to heat exchanger 4 where it is heated to about its boiling point and may be partially vaporized if desired thus reducing the heating requirements in the raflinate stripper.
- the raffinate then passes into raffinate stripper 7 via line 6 where the bulk of the aliphatics along with some C9 aromatics, if any, are removed as a vapor overhead and pass through condenser 8.
- a portion of the condensate is returned to the top tray of rainate stripper 7 as a reflux which aids in purifying the raflinate by knocking down the high boilers.
- the secondary solvent (including entrained primary solvent and which may include other high boiling aliphatics from the feed) is removed as bottoms and passes through line 9 where part is diverted through reboiler 11 and returns to ratnate stripper 7 below the bottom tray as a vapor to provide most of the heating requirement.
- the balance of the secondary solvent proceeds via line 9 to heat exchanger 4 where it is cooled to the extraction ternperature.
- the secondary solvent continues via line 12 to a point below the bottom tray of the primary extractor.
- the primary extract which includes the feed aromatics, the bulk of the primary solvent, a small amount of secondary solvent entrained in the primary solvent, and possibly some high boiling aliphatics, passes as bottoms from primary extractor 2 through line 13 to the top of secondary extractor 14.
- secondary solvent is fed into secondary extractor 14 at the bottom from a reservoir to provide secondary solvent in sufcient amount to extract essentially all of the aromatic hydrocarbons from the primary extract.
- the ratio of secondary solvent to primary solvent is in the range of about 0.11 part to about 5 parts by weight of secondary solvent per part by weight of primary solvent and, preferably, about 0.3 part to about 0.7 part by weight of secondary solvent for each part by weight of primary solvent. These ratios are especially relevant for the solvent of preference or like solvents; however, although such ratios may be used for other solvents, it is suggested that the technician select ratios based on experience with particular feedstocks as mentioned for the other ratios above.
- the same reservoir is used to provide make-up secondary solvent to maintain the described ratio in the secondary extractor. After the cycle has started up, however, the bulk of the secondary solvent is that which is recycled from the distillation zones.
- the temperature and pressure in the secondary extractor is kept within the same range as that described for the primary extractor.
- the primary solvent essentially free of aromatics, with the small amount of dissolved and entrained secondary solvent becomes the bottoms of the secondary extractor l and returns to the top of the primary extractor via line 16.
- the primary solvent thus avoids high distillation ternperatures which lead to its degradation.
- the feed aromatics extracted from the primary extract together with the bulk of the secondary solvent make up the secondary extract, which passes as a liquid overhead via line 17.
- a portion of the secondary extract may be diverted from line 17 in accordance with the improvement described in the application of G. Atwood, Ser. No. 146,952, led on May 26, 1971, for an Improvement in a Process for the Separation of Aromatic Hydrocarbons from a Mixed Hydrocarbon Feedstock, and returned to primary extractor 2 to provide the reflux requirement, i.e., the amount of secondary extract returned to the primary extractor is sufficient to provide the secondary solvent required to act as a reflux for the feedstock as discussed above.
- the balance of the secondary extract continues via line 17 to heat exchanger 18 where it is heated to its boiling point and may be partially vaporized and then passes into about the middle of aromatics stripper ⁇ 21 through line 19.
- the temperature at the top of aromatics stripper 21 is suicient to vaporize benzene and toluene while the temperature at the bottom of the stripper is not permitted to exceed 225 C. in order to avoid degradation of primary solvent entrained in the secondary solvent. Since the highest temperatures are at the bottom of the stripper this means that the temperature in the distilla* tion zone is not permitted to exceed 225 C.
- the tem' perature of reboiler 24 is maintained at 225 C. in order to maintain the high temperature required in stripper 21.
- Raffinate stripper 7 and reboiler 11 follow the same temperature requirement as the aromatics stripper and its attendant reboiler. It will be seen later that the other reboilers used in the process require much lower temperatures thus saving a great deal of reboiler heat duty. Also temperatures at the bottom of the other columns used in this process are a good deal lower than strippers 21 and 7.
- Atmospheric pressure is generally used in all of the distillation columns, but other pressures, both superatmospheric and subatmospheric, can be used.
- the secondary extract passes as a liquid through line 19 into about the middle of aromatics stripper 21. From this point, the secondary solvent proceeds downward in the stripper to line 23.
- Aromatics stripper 21 performs three functions in the instant process. The top third of the column separates the benzene-toluene from the C8 and higher aromatics; the middle third essentially removes the last traces of secondary solvent from the C8 and higher aromatics; and the bottom third separates essentially the last traces of C8 and higher aromatics from the secondary solvent.
- Stripper 21 performs its functions :by virtue of a temperature gradient in the column ranging from the stated maximum temperature to the temperature necessary for the vaporization of benzene and toluene. Through this temperature gradient, a high concentration of liquid C8 aromatics also builds up in the upper half of the column as discussed below and the secondary solvent passes as bottoms.
- the benzene-toluene product is carried overhead as a vapor to avoid revaporization and passes through line 2S.
- a portion of the vapor is diverted through condenser 22 and is returned as a condensate to the top tray of aromatics stripper 21 to provide reflux.
- the ratio of the amount of product returned as reflux to the amount of product recovered from the distillation column is known as the reux ratio of the distillation column. It is advatageous to have a low reflux ratio since less heat is then needed to vaporize the product in the column.
- the reux ratio in stripper 21 generally is in the range of 1.5 to 2.5 in the instant process, but varies according to the amount of aromatics in the feed, eg., the lower the aromatics content of the feed the higher the ratio.
- the side-stripper can also be referred to as a side-distillation zone.
- the liquid draw-off also contains a small portion of benzene and toluene. Generally, about 90 to 99 percent by weight of the benzene-toluene in the secondary extract goes into the vapor phase and is carried overhead and about l to l percent -by ⁇ weight of the benzene-toluene in the secondary extract becomes a part of the liquid drawoff.
- the location of the draw-olf is determined by the point at which the C8 (and C9) aromatics are present as a liquid in highest concentration with respect to the rest of the column. This point is usually approximated by the technician based on an analysis of the components of the secondary extract in the column and their location with respect to the column.
- liquid C8 (and C9) aromatics pass ldown the column 26 to the top stage of side-stripper 27 which contains about 40 to 60 percent of the number of equilibrium stages contained in the aromatics distillation zone and does not need condenser apparatus.
- the liquid C8 (and C9) aromatics pass down the column and are taken oif as bottoms through line 28 where a portion is diverted into reboiler 32 and returns to a point below the bottom tray of side-stripper 27 to provide most of the side-strippers heating requirements and assist in 8 purification of the C8 (and C9) aromatics in the sidestripper.
- the bottoms can be further distilled to separate the C8 (and C9) aromatics, if desired.
- the temperature of reboiler 32 and also the maximum temperature of stripper 27 is at least 75 C. less than the temperature of reboiler 24. Consequently, there is a great saving in reboiler heat duty in the substitution of a sidestripper for a distillation column similar to stripper 21. Further, the condensers associated with strippers such as 21 and 36 are not needed here since reflux is provided by the liquid draw-off itself entering side-stripper 27 through line 26. The side-stripper strips essentially the last trace of benzene and toluene from the C8 (and C8) aromatics and, in so doing, generates some of the vapor needed to provide heat in stripper 21.
- the secondary solvent which still includes lsome dissolved and entrained primary solvent, passes as bottoms from stripper 21 via line 23 where a portion of it is directed into reboiler 24 and returns as a vapor to a point below the bottom tray of stripper 21 to provide most of its heating requirement while the balance of the secondary solvent passes through heat exchanger 18 where it is ic ooled to the extraction temperature and continues through line 38 until it reenters the bottom of secondary extractor 14.
- make-up secondary solvent is introduced at this point, if needed, to maintain the proper ratio.
- the undiverted benzene-toluene vapor passes through line 25 to the middle of benzene-toluene fractionator 36 where the benzene is carried overhead through condenser 37. A portion of the condensate is returned to the top stage of fractionator 36 as a reflux and the balance of the liquid benzene is collected as high purity product.
- the toluene passes as bottoms through line 38 where a portion of it is diverted into reboiler 39 and returns to a point below the bottom tray of fractionator 36 to provide most of the fractionators heating requirement and assist in the purification of the benzene.
- the reboiler (maximum) temperature is at least 75 C. less than the reboiler (maximum) temperature of stripper 21, a considerable saving of reboiler heat duty.
- a variation of the described process is a case where either benzene, toluene, or the C8 aromatics are not present in the initial feed.
- stripper 21 is operated to take the low boiler as a vapor overhead and the liquid draw-olf to side-stripper 27 is mainly the high boiler.
- Stripper 36 is not needed in this variation; however, the basic process remains essentially the same.
- Example l The process is carried out in a continuous manner using the system illustrated in the drawing and as heretofore described.
- Tetraethylene glycol is employed as the primary solvent and an aliphatic fraction boiling in the range of 204 C. to 257 C. and containing in part dodecane is employed as the secondary solvent.
- the feedstock has the following composition:
- the drums containing primary solvent and secondary solvent are maintained at about 110 C. so that the solvents will enter the extraction columns at about 100 C.
- the primary extract is a twenty-eight stage mixer-settler thermostated at 100 C.
- the primary solvent, feedstock, and secondary solvent are fed into the primary extractor at the first stage, tenth stage, and below the twenty-eighth stage, respectively.
- the primary extract then passes to the iirst stage at the top of the secondary extractor where it enters at a temperature of about 100 C.
- This secondary extractor is identical to the primary extractor in all respects except that it has only eighteen stages.
- the secondary solvent also enters the secondary extractor at about 100 C. at a point below the eighteenth stage.
- the primary raflinate passes to the raffinate stripper, which is made of glass and has a section packed with stainless steel packing.
- the aromatics-laden secondary solvent is withdrawn from the first stage of the secondary extractor and passes to the aromatics stripper, which is made of glass and has a section packed with extruded stainless steel packing.
- Atmospheric pressure is maintained in each of the col umns and a maximum operating temperature of 110 C. is maintained inthe extractors.
- the ratio of primary solvent to feedstock in the primary extractor is maintained at :1 (by weight); the ratio of primary solvent to secondary solvent in the primary extractor is maintained at 10:1 (by weight); and the ratio of secondary solvent to primary solvent in the secondary extractor .is maintained at 0.4821 (by weight).
- the reboiler temperature is 225 C. in the aromatics and raffinate strippers and is 146 C. and 130 C. in the side-stripper and benzene-toluene fractionator, respectively. These temperatures represent the bottoms and maximum temperatures in the respective strippers.
- the side-stripper is of smaller diameter than the other columns.
- the liquid stream from the aromatics stripper to the side-stripper is taken off at a point halfway between the point at which the feed enters the aromatics stripper and the top stage of the aromatics stripper. This point is selected on the basis of an analysis of the point of maximum liquid concentration in the aromatic stripper.
- the benzene-toluene vapor passes overhead from the aromatics stripper to the benzene-toluene stripper.
- the recoveries, in percent by weight, for benzene, toluene, and the C3 aromatics are 99.9, 99.9, and 96+, respectively, and the purity for the same feed components is 998+.
- Example 2 Example 1 is repeated except that the system is revised to substitute a column with condenser similar to the aromatics stripper for the side-stripper. The aromatics stripper is then used as the benzene stripper, the new column is fused as the toluene stripper, and the benzene-toluene fractionator becomes the C8 aromatics stripper.
- the primary solvent is a water-soluble organic solvent, which has a higher boiling point than and is non-azeotropic with the feedstock
- the secondary solvent is selected from the group consisting of parafnic and naphthenic hydrocarbons and mixtures thereof, said hydrocarbons having higher boiling points than and being non-azeotropic with the feedstock, and wherein the primary solvent is maintained in suicient amount to extract essentially all of the .aromatic hydrocarbons from the feedstock and the secondary solvent is maintained in sufficient amount to act as a reflux for the feedstock;
- step (c) contacting said primary extract with the secondary solvent in a secondary extraction zone wherein the temperature and pressure are in the same range as in step (a) and the secondary solvent is maintained in sufficient amount to extract essentially all of the aromatic hydrocarbons from the primary extract;
- step (i) withdrawing the vapor phase mixture of benzene and toluene from the aromatics distillation zone in step (h) and subjecting same to distillation to separate the benzene from the toluene;
- step (j) withdrawing the liquid phase C8 aromatics, benzene, and toluene from the aromatic distillation zone in step (h) and subjecting same to distillation in a sidedistillation Zone, said side-distillation Zone containing about 40 to 60 percent of the number of equilibrium stages contained in the aromatics distillation zone and having a maximum temperature of at least 75 C. less than the maximum temperature of the aromatics distillation zone, and separating the C8 aromatics from the benzene and toluene;
- step (k) recycling the benzene and toluene from step (j) to the aromatics distillation zone;
- step (l) withdrawing the secondary solvent from the aromatics distillation zone of step (h) and recycling such secondary solvent to at least one of the extraction Zones.
- ratio of primary solvent to feedstock in the primary extraction zone is maintained in the range of about 6 parts to about 16 parts by weight of primary solvent to one part by weight of feedstock; the ratio of primary solvent to secondary solvent in the primary extraction zone is maintained in the range of about 0.5 part to about 20 parts by weight of primary solvent to one part by weight of secondary solvent; and the ratio of secondary solvent to primary solvent in the secondary extraction zone is maintained in the range of about 0.1 to about parts by weight of secondary solvent to one part by weight of primary solvent.
- ratio of primary solvent to feedstock in the primary extraction zone is maintained in the range of about 9 to about 11 parts by weight of primary solvent to one part by weight of feedstock; the ratio of primary solvent to secondary solvent in the primary extraction zone is maintained in the range of about 5 parts to about 15 parts by weight of primary solvent to one part by weight of secondary solvent; and the ratio of secondary solvent to primary solvent in the secondary extraction Zone is maintained in the range of about 0.3 to about 0.7 part by wei-ght of secondary solvent to one part by weight of primary solvent.
- the primary solvent is a water-soluble organic solvent, which has a higher boiling point than and is nonazeotropic with the feedstock
- the secondary solvent is selected from the group consisting of parafnic and naphthenic hydrocarbons and mixtures thereof, said hydrocarbons having higher boiling points than and being non-azeotropic with the feedstock, and wherein the primary solvent is maintained in suicient amount to extract essentially all of the aromatic hydrocarbons from the feedstock and the secondary solvent is maintained in suicient amount to act as a reflux for the feedstock;
- step (c) contacting said primary extract with the secondary solvent in a secondary extraction zone wherein the temperature and pressure are in the same range as in step (a) and the secondary solvent is maintained in suiicient amount to extract essentially all of the aromatic hydrocarbons from the primary extract;
- step (i) withdrawing the vapor phase lowest boiling member from the aromatics distillation zone in step (h);
- step (j) withdrawing the liquid phase mixture of highest boiling member and lowest boiling member from the aromatics distillation zone in step (h) and subjecting same to distillation in a side-distillation zone, said side-distillation zone containing about 40 to 60 percent of the number of equilibrium stages contained in the aromatics distillation zone and having a maximum temperature of at least 75 C. less than the maximum temperature of the aromatics distillation zone, and separating the highest boiling member from the lowest boiling member;
- step (l) withdrawing the secondary solvent from the aromatics distillation zone of step (h) and recycling such secondary solvent to at least one of the extraction zones.
- ratio of primary solvent to feedstock in the primary extraction zone is maintained in the range of about 6 parts to about 16 parts by weight of primary solvent to one part by weight of feedstock; the ratio of primary solvent to secondary solvent in the primary extraction zone is maintained in the range of about 0.5 part to about 20 parts by weight of primary solvent to one part by weight of secondary solvent; and the ratio of secondary solvent to primary solvent in the secondary extraction zone is maintained in the range of about 0.1 to about 5 parts by weight of secondary solvent to one part by weight of primary solvent.
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Abstract
Description
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US16217871A | 1971-07-13 | 1971-07-13 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3789077A (en) * | 1972-10-06 | 1974-01-29 | Union Carbide Corp | Process for the separation of aromatic hydrocarbons from a mixed hydrocarbon feedstock |
FR2412602A1 (en) * | 1977-12-22 | 1979-07-20 | Exxon Research Engineering Co | PROCESS FOR DESASPHALTING AND SIMULTANEOUSLY EXTRACTING MINERAL OILS |
US4325818A (en) * | 1980-07-17 | 1982-04-20 | Texaco, Inc. | Dual solvent refining process |
US4981579A (en) * | 1986-09-12 | 1991-01-01 | The Standard Oil Company | Process for separating extractable organic material from compositions comprising said extractable organic material intermixed with solids and water |
US5066386A (en) * | 1987-07-09 | 1991-11-19 | The Standard Oil Company | Extraction of oil from stable oil-water emulsions |
US5092983A (en) * | 1986-09-12 | 1992-03-03 | The Standard Oil Company | Process for separating extractable organic material from compositions comprising said extractable organic material intermixed with solids and water using a solvent mixture |
US5186817A (en) * | 1986-09-12 | 1993-02-16 | The Standard Oil Company | Process for separating extractable organic material from compositions comprising oil-in-water emulsions comprising said extractable organic material and solids |
-
1971
- 1971-07-13 US US00162178A patent/US3725254A/en not_active Expired - Lifetime
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3789077A (en) * | 1972-10-06 | 1974-01-29 | Union Carbide Corp | Process for the separation of aromatic hydrocarbons from a mixed hydrocarbon feedstock |
FR2202063A1 (en) * | 1972-10-06 | 1974-05-03 | Union Carbide Corp | |
FR2412602A1 (en) * | 1977-12-22 | 1979-07-20 | Exxon Research Engineering Co | PROCESS FOR DESASPHALTING AND SIMULTANEOUSLY EXTRACTING MINERAL OILS |
US4325818A (en) * | 1980-07-17 | 1982-04-20 | Texaco, Inc. | Dual solvent refining process |
US4981579A (en) * | 1986-09-12 | 1991-01-01 | The Standard Oil Company | Process for separating extractable organic material from compositions comprising said extractable organic material intermixed with solids and water |
US5092983A (en) * | 1986-09-12 | 1992-03-03 | The Standard Oil Company | Process for separating extractable organic material from compositions comprising said extractable organic material intermixed with solids and water using a solvent mixture |
US5186817A (en) * | 1986-09-12 | 1993-02-16 | The Standard Oil Company | Process for separating extractable organic material from compositions comprising oil-in-water emulsions comprising said extractable organic material and solids |
US5066386A (en) * | 1987-07-09 | 1991-11-19 | The Standard Oil Company | Extraction of oil from stable oil-water emulsions |
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