US2483783A - Treatment of spinnerets to minimize contamination thereof - Google Patents
Treatment of spinnerets to minimize contamination thereof Download PDFInfo
- Publication number
- US2483783A US2483783A US644663A US64466346A US2483783A US 2483783 A US2483783 A US 2483783A US 644663 A US644663 A US 644663A US 64466346 A US64466346 A US 64466346A US 2483783 A US2483783 A US 2483783A
- Authority
- US
- United States
- Prior art keywords
- spinnerets
- treatment
- spinneret
- minimize contamination
- viscose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000011109 contamination Methods 0.000 title description 5
- 229920000297 Rayon Polymers 0.000 description 12
- 229910052710 silicon Inorganic materials 0.000 description 10
- 239000010703 silicon Substances 0.000 description 10
- 239000002253 acid Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- -1 silicon halides Chemical class 0.000 description 7
- 238000000034 method Methods 0.000 description 5
- 238000009987 spinning Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000002964 rayon Substances 0.000 description 3
- 239000005871 repellent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 229920006268 silicone film Polymers 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical class CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 1
- 239000005046 Chlorosilane Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical class Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 1
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 description 1
- 229960005215 dichloroacetic acid Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000012186 ozocerite Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D4/00—Spinnerette packs; Cleaning thereof
- D01D4/02—Spinnerettes
- D01D4/022—Processes or materials for the preparation of spinnerettes
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D4/00—Spinnerette packs; Cleaning thereof
- D01D4/02—Spinnerettes
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
Definitions
- the present invention relates to the manufacture of rayon and more particularly to spinnerets used in the production of viscose rayon which are treated to inhibit or minimize the contamination of the orifices of the spinnerets during the spin- 5
- spinnerets with the organening operation.
- silicon halides very much the same technical
- a major problem in the manufacture of viscose procedure should be adopted as that di l s d in rayon is encountered as a result of the containithe Patnode Patent No. 2,306,222. Initially, the nation of the spinnerets through which the spinp e a e thoroughly cl by s i g n ning solution is extruded into the spin bath.
- 2,100,581 is dipat t s h e d s s d these mp unds rerected to the provision of a film of wax-like mateact with the water adsorbed at the surface of rials such as ozocerite and ceresine on the spinhe spinneret and a very thin silicone him is denerets.
- United States Patent No. 2,294,154 dispo ted on the pinneret which is water-repel nt closes a method of treating spinnerets with a and is insoluble in the acid spin bath. After a cation active substance.
- the spinnerets tially clogged with impurities occurring in the d o have to be changed except per odic y system, including precipitated cellulose, sulphur when voluntary changes are made at the time deposits, secondary reaction products and the the spinning machines are shut down for cleanlike. ing and other repairs.
- This invention has for its purpose the applica- 2 tion of these substances, namel organo-sillcon halides, to the surface of the spinnerets and the use of the treated spinnerets in the production of rayon by the viscose process.
- spinnerets are intended for treating spinnerets may be mentioned the alkyl silicon halides such as methyl, ethyl, propyl, and butyl chlorides or bromides, the aryl silicon halides such as phenyl silicon halides, aralkyl silicon halides such as phenyl- Means such as tolyl silicon halides, and similar alkyl,
- halosilanes such as chlorosilanes.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL62699D NL62699C (en(2012)) | 1946-01-31 | ||
BE469811D BE469811A (en(2012)) | 1946-01-31 | ||
US644663A US2483783A (en) | 1946-01-31 | 1946-01-31 | Treatment of spinnerets to minimize contamination thereof |
GB35822/46A GB625748A (en) | 1946-01-31 | 1946-12-03 | Improvements in or relating to the spinning of rayon |
ES176020A ES176020A1 (es) | 1946-01-31 | 1946-12-06 | Un método para el perfeccionamiento de la hilatura de la viscosa en rayón |
CH263618D CH263618A (fr) | 1946-01-31 | 1946-12-23 | Procédé pour l'obtention de soie artificielle par filature de viscose et fibre obtenue par ce procédé. |
FR938556D FR938556A (fr) | 1946-01-31 | 1946-12-27 | Perfectionnements à la filature de la viscose en rayonne aux filières employées à cet effet et à la rayonne filée ainsi obtenue |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US644663A US2483783A (en) | 1946-01-31 | 1946-01-31 | Treatment of spinnerets to minimize contamination thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
US2483783A true US2483783A (en) | 1949-10-04 |
Family
ID=24585862
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US644663A Expired - Lifetime US2483783A (en) | 1946-01-31 | 1946-01-31 | Treatment of spinnerets to minimize contamination thereof |
Country Status (7)
Country | Link |
---|---|
US (1) | US2483783A (en(2012)) |
BE (1) | BE469811A (en(2012)) |
CH (1) | CH263618A (en(2012)) |
ES (1) | ES176020A1 (en(2012)) |
FR (1) | FR938556A (en(2012)) |
GB (1) | GB625748A (en(2012)) |
NL (1) | NL62699C (en(2012)) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2588200A (en) * | 1950-02-23 | 1952-03-04 | North American Rayon Corp | Method of spinning filaments and spinneret for use therewith |
US3110551A (en) * | 1962-04-10 | 1963-11-12 | Du Pont | Process for producing colored regenerated cellulose film |
WO2018090370A1 (zh) * | 2016-11-15 | 2018-05-24 | 东华大学 | 低阻尼聚合物高效熔融纺丝方法 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB666199A (en) * | 1948-10-28 | 1952-02-06 | Onderzoekings Inst Res | Improvements in or relating to the manufacture of threads and fibres from molten polymeric organic compounds |
US4878822A (en) * | 1988-04-01 | 1989-11-07 | Wetch Terry L | Tire recapping curing jacket |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2100581A (en) * | 1935-10-18 | 1937-11-30 | American Enka Corp | Spinneret treatment in the manufacture of artificial silk |
US2273638A (en) * | 1939-03-24 | 1942-02-17 | Du Pont | Spinnerette lubricant |
US2306222A (en) * | 1940-11-16 | 1942-12-22 | Gen Electric | Method of rendering materials water repellent |
-
0
- NL NL62699D patent/NL62699C/xx active
- BE BE469811D patent/BE469811A/xx unknown
-
1946
- 1946-01-31 US US644663A patent/US2483783A/en not_active Expired - Lifetime
- 1946-12-03 GB GB35822/46A patent/GB625748A/en not_active Expired
- 1946-12-06 ES ES176020A patent/ES176020A1/es not_active Expired
- 1946-12-23 CH CH263618D patent/CH263618A/fr unknown
- 1946-12-27 FR FR938556D patent/FR938556A/fr not_active Expired
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2100581A (en) * | 1935-10-18 | 1937-11-30 | American Enka Corp | Spinneret treatment in the manufacture of artificial silk |
US2273638A (en) * | 1939-03-24 | 1942-02-17 | Du Pont | Spinnerette lubricant |
US2306222A (en) * | 1940-11-16 | 1942-12-22 | Gen Electric | Method of rendering materials water repellent |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2588200A (en) * | 1950-02-23 | 1952-03-04 | North American Rayon Corp | Method of spinning filaments and spinneret for use therewith |
US3110551A (en) * | 1962-04-10 | 1963-11-12 | Du Pont | Process for producing colored regenerated cellulose film |
WO2018090370A1 (zh) * | 2016-11-15 | 2018-05-24 | 东华大学 | 低阻尼聚合物高效熔融纺丝方法 |
Also Published As
Publication number | Publication date |
---|---|
ES176020A1 (es) | 1947-03-16 |
CH263618A (fr) | 1949-09-15 |
BE469811A (en(2012)) | |
NL62699C (en(2012)) | |
FR938556A (fr) | 1948-10-19 |
GB625748A (en) | 1949-07-04 |
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