US2463422A - Method and apparatus for coating articles by electrostatic deposition - Google Patents

Method and apparatus for coating articles by electrostatic deposition Download PDF

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Publication number
US2463422A
US2463422A US575956A US57595645A US2463422A US 2463422 A US2463422 A US 2463422A US 575956 A US575956 A US 575956A US 57595645 A US57595645 A US 57595645A US 2463422 A US2463422 A US 2463422A
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United States
Prior art keywords
articles
coating
booth
conveyor
electrode
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US575956A
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Harold P Ransburg
Richard E Helmuth
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Ransburg Corp
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Ransburg Corp
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Priority to BE463400D priority Critical patent/BE463400A/xx
Application filed by Ransburg Corp filed Critical Ransburg Corp
Priority to US575956A priority patent/US2463422A/en
Priority to GB2301/46A priority patent/GB645612A/en
Priority to GB8558/48A priority patent/GB645629A/en
Priority to FR922540D priority patent/FR922540A/en
Application granted granted Critical
Publication of US2463422A publication Critical patent/US2463422A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/08Plant for applying liquids or other fluent materials to objects
    • B05B5/082Plant for applying liquids or other fluent materials to objects characterised by means for supporting, holding or conveying the objects
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/08Plant for applying liquids or other fluent materials to objects
    • B05B5/087Arrangements of electrodes, e.g. of charging, shielding, collecting electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S99/00Foods and beverages: apparatus
    • Y10S99/13Electrical deposition

Definitions

  • This invention relates to electrostatic coating and is especially directed to improved methods and apparatus for handling articles to be coated, to the positioning and construction of discharge electrodes, and to the provision of various safety factors.
  • Objects of the invention are to provide methods and apparatus which achieve greater uniformity of coating, greater economy in utilization of coating material, speedier and more efficient coating production and greater safety to personnel and property.
  • the articles to be coated are conveyed in spaced relation successively through a precoat zone and a finish-coat zone over a path which includes portions lying respectively within such two zones and disposed at an angle to each other. Coating material in finely divided condition is discharged into the finish zone toward the precoat zone and with sufficient velocity to cause at least some of the particles of coating material to be carried into the precoat zone.
  • a discharge electrode possessing several novel features and disposed in spaced relation to the article path is employed in creating an electrostatic field promoting the deposition of coating material on the articles.
  • the discharge electrode may include a section disposed to redirect toward the article-path coating-material particles which are carried across the article-path through the spaces between adjacent articles.
  • the apparatus includes means for rotating the articles as they pass through the coating zones.
  • such means is desirably arranged to rotate the articles at a relatively high speed in that portion of the coatin zones where the concentration of coating material is relatively great and at a lower speed in those regions when the concentration of coating material is relatively low.
  • each article may be supported therefrom through the medium of an improved twopart hook, and guide means may be provided to reduce such swaying of the articles as would vary their distance from the discharge electrode.
  • Ventilating means employed to withdraw air from the booth in which the coating operation is customarily performed is soarranged as to maintain the air at a relatively low velocity invention comwithin the coating zones and at a higher velocity after it has left such zones. whereby any adverse eifect of the moving air on the deposition of coating material within the coating zones will be reduced, while volatilized solvents and any coating material which does escape deposition on the articles will be rapidly carried away.
  • Safety features of the invention include the use of an isolating fence, a gate therein, and a gate-operated switch controlling energization of the field-creatin means and the use of interlocking electrical circuits which prevent energization of the field-creating means except while the ventilating means is in operation.
  • Fig. 1 is a front elevation of the spray b with a portion broken away and parts remo iig plan view of the spray booth.
  • Fig. 2 is a schematic illustration showing Fig. 3 is a schematic illustration showing a plan view of the spray booth on a reduced scale with the isolating fence and associated apparatus.
  • Fig. 4 is a cross section through a portion of the conveyor mechanism.
  • Fig. 5 is an enlarged elevational view of a portion of the article supporting hook with its associated idler wheel in section.
  • Fig. 6 is a sectional detail of the spinner hook.
  • Fig. 7 is a wiring diagram of the electrical control circuits.
  • the articles While inside the booth, the articles are surrounded with a fog of coating material finely atomized by suitable atomizing means such as the air guns indicated at it into an electrostatic field established between the articles and a fine wire discharge electrode I.
  • suitable atomizing means such as the air guns indicated at it into an electrostatic field established between the articles and a fine wire discharge electrode I.
  • This fleld which charges and electrically precipitates the material onto the article, is maintained by a suitable voltage source l8 connected to the discharge electrode by a lead-in conductor i'l.
  • the articles While in this held the articles are rotated by a mechanism. to be hereinafter described, as they move along the conveyor support.
  • the nature 01 the atomized spray is controlled by suitable regulators contained in a control cabinet generally indicated at iii.
  • a general convection through the booth past the items is maintained by a fan Is and is further distributed by the baflies indicated at in Fig. 2.
  • the entire assembly of booth and voltage supply is electrostatically isolated from its surroundings by an isolating. shield 2
  • the spray booth I3 is constructed of electrically non-conducting material. It is approximately rectangular in shape with its exit end open. and is fitted with an air outlet chamber 22 that is fronted with a series of non-conducting bailles 20 to control the flow of air through the booth. This results in a lower air velocity within the electrostatic field, a still lower air velocity at the air entrance end and a higher air velocity where the air leaves the electrostatic held. The slow air movement within the field aids electrostatic deposition, and the air that has left the field carrying residual particles is sped-up to minimize settling of the residual particles.
  • the fan I 9 providing this ventilation is of non-conducting material so that the tendency of charged material to collect on it will be reduced to a minimum.
  • the entrance opening l2 oi. the booth is silhouetted generally to the shape of the articles l0, and is located on one side adjacent the air outlet chamber 22. This opening is extended outward from the booth wall so that the amount of air entering therethrough will be reduced to a minimum.
  • the booth has a ceiling and floor to complete the enclosure.
  • the discharge electrodes I 5 are located in the booth adjacent to and conforming with the path of travel of the. articles. They are composed of a plurality of frames Ilia suspended from the booth ceiling by electrical strain insulators 24. These frames supply the supports across which a series of .010" diameter wires llib are stretched for producing the necessary ionizing and precipitating fields. These wires are equally spaced from each other on centers thirds of the distance of the electrode plane from the surface of the article.
  • a number or such names iia form each complete discharge electrode II and are arranged adjacent to the articles on both sides and about the bottom as they pass through the booth. The electrode is thus, in eil'ect. U-shaped or trough-like. conforming to the bottom and sides of the article being coated.
  • the electrostatic field is established between the insulated discharge electrodes it and the to block and reduce any which are about two charge electrode grounded articles by connecting them to a in able high voltage source.
  • the source her disclosed and indicated at l8 consists of a he wave. over controlled, limited current rectii capable of converting normal line voltage pulsating high voltage direct current.
  • One t minal of this source is connected by an insula1 lead H to the electrode system and the otl terminal is grounded. Since the conveyor. a thus the articles, are grounded, such a soul will establish an electrical field of consideral strength between the discharge electrode wii l5b and the surface of the articles.
  • the leadconductor l1 between said source and the d should be of reasonable si 8" or larger) in order that parasitic coro: losses will be reducefi to a minimum.
  • the conveyor guide rail I I is of the ordina I-beam type and is electrically grounded. In: path through the booth it makes a horizo: tal turn, entering through the entrance l2 d scribed above, and leaving through the 091 booth exit.
  • the conveyor system mounted the booth is surrounded with a grounded col ducting shield 25 which insures that it will n have any material electrically precipitated up: it as it passes through the booth.
  • Suitable hooks 26 depend from a conveyl chain 21 of the conveyor system at regular 11 tervals to support the articles in columnar space relation.
  • the hooks are so designed that the are free to rotate on a bearing situated in spinner 28 near the top.
  • Below this spinner an arranged to idle on the shank of the hook is a idler guide wheel 29.
  • the wheel 29, together wit its depending sleeve 29a, is arranged to act as looking collar and shield over 9.
  • the spring guide plates 22 Insure that the article enters without swinging.
  • the spinner 22 is in contact with shoe 32 the idler wheel 28 is in contact with pressurebar 30a located on the opposite side 01' the conveyor from the shoe 22.
  • the bar Ila insures frictional contact of the spinner 28 with the shoe 32 and also prevents lateral swinging of the article due to rotation. This swinging must be avoided in order to maintain the distance between the article and the discharge electrodes to avoid sparking therebetween.
  • the spinner through the speed reduction gear box 35, drive shaft 35 and driven pulley 31, which, with its idler pulley 38 is supported by the shield 25.
  • the spinner belt passes around these, two pulleys and over suitable guide surfaces or pulleysindicated at 39 to insure that the passing spinner wheels will contact it.
  • This guide surface will be mounted so as to insure some degree of contact flexibility between the spinners and the belt.
  • This shield protects the conveyor over its entire path through the spray booth. It isolates the conveyor, spinners and idler wheels from the forces of the electrostatic field, since the lines of force thereof will terminate on its surface.
  • the spray gun I4 is arranged at the open or exit end of the booth where it will be readily accesible for adjustment by the operator. It is supported on suitable rigid supports 40, 4
  • the gun is situated to distribute its discharged material in a fairly uniform manner into the finish zone of the electrostatic field established between the discharge electrode and the article.
  • the gun is maintained at ground potential which permits free adjustment during operation without hazard, and also permits it to be placed as close as needed to the article itself. If the gun is not positively grounded, it, as a free conducting body, would accumulate acharge proportional to its electrical capacity, and this charge would be liberated as a hazardous spark when it is approached by an operator or an article.
  • the gun is connected by suitable hose 42 to the appropriate sources 45 of coating material, operating air and atomizing air;
  • the operating air, atomizing air, and fluid pressure are controlled in turn by suitable controls situated in the control panel Ill.
  • the gun is operated, fluid pressure adjusted, atomizing air controlled, and electrical devices activated from this one position.
  • the electrical circuit is so arranged that switches for the conveyor, ventilating fan, and voltage supply are all located on the panel. The operator in this position thus has immediate control of all phases of the operation.
  • the article supporting hooks comprise two parts, a lower shank portion 26 and an upper the idler wheel with its depending sleeve not only serves to guide and steady the hook -and its sup-, ported article to prevent swinging, but also to lock the two portions of the shank'together when in operative position.
  • the unit By suitably cross connecting the various electrical circuits, as shown in Fig. l, the unit is so arranged that power will not be available to the voltage source until after the ventilating fan is running. This insures adequate removal of inflammable materials before the voltage source can be turned on.
  • a limit switch ahead of the booth is also installed to shut off the conveyor and voltage source in case an article which is too large to enter the silhouetted entrance should be hung on the conveyor.
  • a safety gate switch is also installed on the entrance gate of the field isolating shield 2!, that surrounds the booth, which electrically turns off the voltage when this gate is opened. This guards against a person entering the area when the field is on. Warning lights in parallel with those in the control panel are located on the front of the booth which constantly warn of the operating or non-operating condition of the unit.
  • lead-in wires 46 are connected. with the usual 220 volt electric current. They are connected through a normally open fan starter switch 41, a normally closed fan stopping switch 48 and solenoid 49 with the motor for driving the ventilating fan I9.
  • the solenoid 49 upon being energized by closing switch 41, moves the contact members 50 to circuit closing position, thereby not only closing the circuit to the ventilating fan, but also energizing the circuit II connected to the circuit 52 through the switch 53 and thence to the control panel II for operating the source of high voltage IS.
  • the control panel i8 is provided with a switch 54 to control the source of voltage I.
  • the power lines 48 are also connected through the manually operated switch 55' with a circuit leading to the manually operated switch 55a for energizing the motor 51 which drives the conveyor.
  • a solenoid I! is energized to close switch 53, as well as switch 5! in the conveyor drive motor circuit Ell.
  • the solenoid energizing circuit is provided with normally closed switches I, 62 and 83.
  • Switch M is conveniently located for manual operation to break the circuit through the solenoid 58 for stopping the conveyor and simultaneously breaking the circuit to the high voltage source ii.
  • the switch 82 is a limit switch mounted in the entrance opening I2 of the booth for stopping the conveyor and breaking the circuit through the high voltage source in event one of the articles is not properly mounted on the conveyor, or is of improper size.
  • the switch 83 is mounted upon the gate indicated at O5 in Fig. 3 and is so arranged that when the gate is open the conveyor and high voltage source are inoperative.
  • a signal lamp 68 mounted in a conspicuous position upon the isolating fence 2i. such as to provide a warning signal when the source of high voltage is on.
  • switch St in the control panel I 8 must be closed, whereupon signal light 68 will give warning.
  • all parts of the apparatus must be func- Switch 55a permits the operation of the voltage pack without the conveyor being in operation.
  • the electrostatic field may be disconnected at the control panel by opening switch 54 continue to function, the conveyor being controlled independently of the ventilator fan.
  • the isolating fence is of conducting material and is maintained at ground while the remaining apparatus will 10 8 of the electrostatic field urge them toward article.
  • the force of gravity constantly te to pull them downward. If the atomizing fc is too large relative to the other forces, the p .tioning and the personnel warned thereof. 5 tlcle will be blown through the field. Ifthe e1 trostatic field is not continuous about the it but there exists regions where this force is l or zero, particles in these voids will be carr away from the article by the other two forr If the gravitational force is not properly b anced by the action of the other two, many pi ticles will fall away from the article as unm material.
  • the coating will be completed as the article makes Other angles either greater or less than 90 dezone out of the booth past the spray guns.
  • the spray as it leaves the gun, is far from homogeneous in particle size and grees can be used to realize the advantages herein disclosed in cases where they are more suited to the conveyor travel before and after the coating operation. It is in this zone that those particles will contain both small and large part cles which 00 which have reasonable velocity and are small are spray which are introduced into the field and 70 ionized by the action of the discharge electrode have their motion controlled by three forces. They are projected away from the gun in a direction substantially tangential to the surface to be coated by the atomizing forces.
  • the mutual action of the three forces mentioned above is accomplished by the form and arrangement of the discharge electrode. Being constructed of fine wire elements with small radii which surround the article on three sides, it forms an electrostatic trough, so to speak, inside of. which the electrostatic field will be continuous and complete and inside of which the ionization of all particles will be assured and maintained. Since the gravitational force is downward into this trough, and since the electrostatic forces are all directed toward the item, coating material in this trough will be maintained therein until effective precipitation results. Particles which rebound from the surface or have their ionization neutralized by collision, are reionized and redeposited by successive elements of the U-shaped discharge electrode as they are carried along this trough by the velocity given them by the atomizing means. 7
  • This type of electrode is of particular benefit for the deposition of that material which is atomized into the field intended for coating the bottom of an article.
  • Apparatus for electrostatically coating articles comprising a-discharge electrode mounted to provide an L-shaped coating zone having an inlet portion and an exit portion extending substantially at right angles thereto, a conveyor operable to convey said articles into the inlet portion of said zone and through a curved path into and" through said exit portion thereof, means for establishing an electrosatic field between said electrode and articles and an atomizing means mounted to direct a spray of coating material into and longitiudinally of the exit portion of said coating zone toward the transverse inlet portion which it is intended is overcome by the increased electrostatic forces created on this surface. This unobstructed.
  • the article is herein considered as comprising the collecting electrode on which the coating material is gradually accumulated.
  • Such gradual application ofv coating material permits one to obtain a finish film which is more uniform, heavier and consequently of thereof for electrostatic deposition on said articles as they pass therethrough.
  • Apparatus for electrostatically coating articles including a discharge electrode having a Precoat section extendingin a curve to a finish section thereof, a conveyor conforming to said electrode operable to convey said articles in a direction to first pass adjacent to said pre-coat section and then said finish section and in predetermined spaced relation thereto, means for establishing an electrostatic field between said electrode and articles, and an atomizing means mounted adjacent the end of said finish section to direct said material adjacent thereto and toward said pre-coat section for electrostatic depopening in the sidewall thereof and an open exit end, means for conveying the articles to be coated greater hiding power. It is a one operation process which is superior in economy, durability and appearance to the coating normally applied by hand operation where a dust or mist pre-coat is first applied to the article before the application of the final or. finish coat.
  • the method of electrostatically coating articles consisting in conveying the articles through a pre-coating zone into a finish coating zone wherein said zones extend substantiallyat right angles to each other and one is a continuation of the other, revolving said articles at a greater "speed of rotation during their passage through said finish coating zone than during their passage through said pre-coating zone, establishing an electrostatic field in said zones wherein said articles coniprise the collecting electrode, and directing atomized coating material into and substantially longitudinally of said finish coating zone, counter to the direction of movement of the articles conveyed therethrough, and toward and into said pre-coating zone for electrostatic deposition on said articles passing through both of said zones.
  • the method of electrostatically coating articles consisting in conveying the articles through a coating zone from an inlet end to an exit end, revolving said articles at a greater speed into said booth through said inlet opening and in a direction substantially at right angles thereto through said exit end, a substantially L-shaped discharge electrode mounted in said booth to conform with the path ,of travel of said articles through said booth in spaced relation thereto, means for establishing an electrostatic field between said electrode and articles, and an atomizing means mounted adjacent the exit end of said booth operable to direct a spray of coating material therein along the adjacent path of said articles toward their angularly disposed path for electrostatic deposition thereon.
  • Apparatus for electrostaticaliy coating articles including a spray booth having an inlet opening in the side wall thereof and an open exit end, a substantially L-shaped coating zone therein extending from adjacent said inlet opening to said exit end defined by spaced discharge electrodes mounted in said booth, means for conveying the articles to be coated in a path leading from the inlet opening to the exit end of said booth substantially medially of said zone and electrodes, means for establishing an electrostatic field between said electrodes and articles throughout said coating zone, and an atomizing means positioned to direct a spray of coating material through that portion of said coating zone extending to and terminating with the exit end of the booth, and toward the portion thereof extending from said inlet opening.
  • Apparatus for coating articles including an guide members prevent lateral hooks having a spliced of the lower portion discharge elements, means for conveying a column of articles to be coated through said trough-like electrode, said articles having bottom andside surfaces to be coated, meansfor suspending said articles from said conveyor to present an unobstructed bottom surface in predetermined spaced relation to the bottom portion of said electrode with the side surfaces thereof similarly spaced from the side portions of said spray booth having enclosing and confining walls,
  • one of said walls being provided with a restricted inlet opening, a conveyorhaving means for suspending article therefrom to be coated, saidconveyor extending through said booth for conveying the articles to be coated into said booth through said restricted inlet openingand through an outlet opening out of the booth, a pair of yielding mounted in said inlet opening spaced from each other to permit passage of said articles therebetween to steady said articles and swinging thereof upon entering said booth, a coating zone through which said articles are conveyed in said booth, means for establishing an electrostatic field in said zone, and an atomizing means for atomizing a coating material into said field for electrostatic deposition onto said articles.
  • Apparatus for coating articles including a conveyor including means for suspending articles therefrom for conveying the articles to be coated through a coating zone, means including a dis charge electrode for establishing an electrostatic field in said zone between said electrode and articles.
  • a guide rail extending along and adjacent said conveyor in fixed spaced relation to said electrode, a guide roller associated with said first mentioned means engageable with said guide rail to maintain said articles in a predetermined path of travel through said zone and prevent swinging movement thereof toward said electrode, and an atomizing means for atomizing a coating material into said field for electrostatic deposition onto said articles.
  • Apparatus for coating articles including a conveyor for conveying the articles to be coated through a coating zone, a series of hooks depending from said conveyor means for removably suspending said articles therefrom, each of said shank to permit removal of the lower shank portion from the upper shank portion, a protective shielding sleeve slidably sup ported to envelop the spliced portion of said shank when in lowered position to prevent accumulation of coating material thereon, said sleeve being slidable upwardly to permit removal portion thereof, means for establishing an electrostatic field in said coating zone, and an atomizing means for atomizing a coating material into said field for electrostatic deposition onto said articles.
  • Apparatus for coating. articles including a conveyor for conveying the articles to be coated through a coatingzone, a series of hooks depending from said conveyor means for removably suspending said articles therefrom, each of said hooks having a spliced shank to permit removal of the lower shank portion from the upper shank portion, a protective shielding sleeve slidably supported to envelop the spliced portion of said shank when in lowered position to prevent accumulation of coating material thereon, said sleeve being slidable upwardly to permit removal of the lower portion of the shank from the upper portion thereof, a guide rail extending along said conveying means, an idler roller rotatably mounted on said sleeve engageable with said guide rail to guide said articles along their path of travel, means for establishing an electrostatic field in said zone, and an atomizing means for atomizing a coating material into said field for electrostatic deposition onto said articles.
  • Apparatus for coating articles including a spray booth, means for conveying said articles through said spray booth, a discharge electrode mounted in said booth in spaced relation to the 1 path of travel of said articles, a source of high of the shank from the upper voltage having one terminal connected with said electrode and the other terminal connected with said articles to establish an electrostatic field therebetween, an atomizing means mounted to direct a spray of coating material into said field for electrostatic-deposition on said articles passing through said booth; an isolating fence surrounding said booth and extending therefrom,
  • said fence being of conducting material electrically connected with said last-mentioned terminal of the source of high voltage, a gate in said fence to permit access therethrough, and a control switch operable by said gate to break the circuit between said source of high voltage and said electrode when said gate is in open position.
  • Apparatus for electrostatically coatingarticles including a spray booth having enclosing and confining walls, a conveyor extending through said booth for conveying the articles tobe coated therethrough, a'fan for exhausting said booth, a discharge electrode extending along the path of travel of said articles and spaced therefrom, a source ofhigh voltage having one terminal electrically connected with said electrode and the other terminal with said conveyor to establish an electrostatic field between the articles carried thereby and said electrode, an atomizing means for atomizing a coating material into said field for electrostatic deposition onto said articles, a motor for driving said fan, a motor for driving said conveyor, electric circuit interconnectng a source of current with said motors and source of high voltage, and control switches in series in said circuits operable to maintain the circuit to said high voltage source open until said motor circuits are closed.
  • Apparatus for electrostatically coating articles including a spray booth, a shielding fence surrounding and spaced from said booth having a gate for permitting access thereto, a conveyor extending through said booth for conveying articles to be coated therethough, a motor for driving said conveyor, an exhaust fan for said boot'h, a motor for driving said fan, a discharge electrode mounted in said booth extending in spaced relation to said conveyor and the articles conveyed thereby, a high voltage source having one terminal electrically connected with said electrode and the other terminal with said conveyor for establishing an electrostatic field between said electrode and the articles carried .said article.
  • an atomizing means for atomizing a coating material into said field for electrostatic deposition on said articles, electric circuits interconnecting a source of current with said motors and high voltage source, a switch in said circuits operated by the gate of said shielding fence forcontrolling said circuits, and control switches in said circuitsin series with said first switch arranged to maintain the circuit to the high voltage source open until said motor circuits and gate switch are closed.
  • An apparatus comprising a boothhaving an electrostatic field between said electrode and articles, and atomizing means to direct a spray of coating material through said zone.
  • Apparatus for electrostatically --coating articles including a discharge electrode having a pre-coatsection extending at'an angle to a finish section thereof, a conveyor conforming to said electrode operable to move said articles in a direction to first pass adjacent to said pre-coat section and then said finish section, means for establishing an electrostatic field between said electrode and articles, an atomizing means mounted adjacent the end of said finish section to direct coating material adjacent thereto and towards said pre-coat section for electrostatic deposition on said articles, and means for exhausting air from the finish'section through the pre-coat section.
  • An apparatus comprising a generally U- shaped discharge electrode, conveyor means to move a column of articles having bottom and side surfaces'to be coated through said U-shaped said conveyor means to present an unobstructed bottom surface in predetermined spaced relation to the bottom portion of said electrode with the side surfaces thereof similarly spaced from the side portions of said electrode, a source of high voltage having one terminal connected with said electrode and the other terminal with said conveyor m'eans to establish an electrostatic field having lines of force directed upwardly to terminate with the bottom of said article and lines of force directed laterally to terminate with the side surfaces thereof, and means for introducing finely divided coating material into said field for electrostatic deposition over the surfaces of 18.
  • Apparatus for coating articles comprising a booth having confining walls and provided with a main air-inlet opening, means for drawing air into said inlet opening and through the booth, one of said booth walls being provided with an auxiliary air-inlet opening materially smaller than said main opening and located between said main opening and said air-drawing means, a conveyor for moving articles to be coated through said booth over a path extending through said auxiliary opening and including a portion extending generally normal to the path of air fiow between the main opening and said air-drawing means, a discharge electrode having a portion spaced laterally from said path-portion, means for creating an electrostatic field between said electrode portion and the articles conveyed past it, and means located near the main inlet finely divided coating material into said field! 19.
  • An apparatus comprising means for supporting in a coating zone an article to be coated.
  • an ionizing electrode having a portion disposed at one side of and spaced from an article on said support, a source of high electrical potential having opposite terminals respectively associated with the article and electrode to create an electrostatic field therebetween, and means for introducing into such field finely divided coatin material for electrostatic deposition on the article,
  • said electrode having a generally horizontal portion disposed below the article to repel upwardly coating material particles which tend to settle from the coating zoneunder the influence ofgravity.
  • Apparatus for coating articles comprising a conveyor having two portions arranged at an angle to each other, a discharge electrode disposed at one side of one of said conveyor portions in spaced relation to articles carried thereby, a discharge electrode disposed at the opposite side of the other of said-conveyor portions, means for establishing'an electrostatic field between said electrodes and articles conveyed past them .by the conveyor, means for spraying finely divided coating material into the space between the first mentioned electrode and its adjacent conveyor portion and toward said other conveyor portion and its adjacent electrode, the latter serving to repel coating material particles carried through said space.
  • Appa'ratus for electrostatically coating articles including a discharge electrode having a prc-coat section extending at an angle to a finish section thereof, a conveyor conforming to said electrode operable to move said articles in a direction to first pass adjacent to said pre-coat 40 section and then said finish section, means for electrode, means for suspending said articles from V .mounted adjacent the endof said finish section to direct said material adjacent thereto and towards said pre-coat section for electrostatic deposition on said articles.
  • An apparatus comprising a discharge electrode, means for conveying articles in spaced relation to said electrode, a source of high voltage having one terminal connected with said electrode and the other terminal connected with said articles to establish an electrostatic field therebetween, atomizing means mounted to direct a spray of coating material into said field, an isolating fence for said electrode electrically connected .to said articles, a. gate in said fence, and a control switch operable by said gate to disestablish said field-between said electrode and said articles when the gate is open.
  • An apparatus comprising, an electrode frame carrying a plurality of fine wires adapted to be connected to a high voltage source to provide an ionizing discharge, means to move an article past said wires, the spacing between the wires on the frame being about two thirds the minimum distance between a wire and a surface of anarticle to be coated, and means for atomizing a coating material in said discharge for opening for discharging.
  • said hook-portions being of electrically conductive material
  • a sleeve enveloping the interlock of said shank, said sleeve being slidable along the shank to permit removal of the lower portion of the shank from the upper portion thereof, an electrode disposed in the coating zone in spaced relation to articles conveyed by said conveyor, a source ofihigh-voltage having its terminals connected respectively with said electrode and with the upper hook-portions for establishing an electrostatic field in said coating zone, and means for atomizing a coating material into said field for electrostatic deposition onto said articles.
  • An apparatus comprising electrode means for producing an ionizing field, a conveyor operable to move articles to be coated through said field, means outside of said field for revolving said articles at a predetermined speed of rotation while conveyed through said field, guide means between said latter means and said field, and atomizing means mounted to direct a' spray of coating material into said field for electrostatic deposition on said articles.
  • Apparatus for coating articles including means for establishing an electrostatic field a conveyor extending through the field, a series of hooks depending from said conveyor for carrying articles to be coated through said field, each of said hooks having a shank including upper and lower interlocking' portions to permit removal of the lower portion from the upper portion, a sleeve enveloping the interlock of said shank, said sleeve being slidable along the shank to permit removal of the lower portion of the shank from the upper portion thereof, an idler wheel mounted upon said sleeve, guide means extending substantially parallel to the conveyor at said field in position to be engaged by the idler wheels associated with articles passing through the field whereby to restrict lateral swinging of the hooks supporting such articles, and means for atomizing a coatingmaterial into said field for electrostatic deposition onto said articles.
  • Apparatus for electrostatically coating articles including a discharge electrode having a pre-coat section and extending in a curve to a finish section thereof, a conveyor operable to con- .vey said articles through said sections, means for revolving said articles while conveyed around said curve, means for establishing an electrostatic field in said sections with said articles comprisinga collecting electrode therein, and atomizing means mounted to direct a spray of coating material into said finish section for electrostatic deposition on said articles.
  • Apparatus for coating articles including a spray booth having confining walls and an exit, one of said walls being provided with an inlet opening, a conveyor extending through said booth for conveying the articles to be coated into said booth through said inlet opening and out of said booth through said exit, means for establishing an electrostatic field in said booth, means mounted adjacent said opening for limiting lateral movement of said articles, as they are conveyed toward the field, and means for atomizing a coating material into said field for electrostatic deposition onto said articles.
  • Apparatus for electrostatically coating articles including a discharge electrode, a conveyor operable to convey articles in a curved path to pass adjacent to said electrode, means for establishing an electrostatic field between said electrode and articles, and atomizing means mounted to direct said material into said field on the concave side of the conveyor for electrostatic deposition on said said articles.
  • the method of coating articles which comprises moving the articles in spaced relation in a column over a predetermined path, discharging finely divided coating material on one side of the article-column for deposition on the articles, withdrawing air from the region on the opposite side of the article-column whereby to induce a flow of air generally transversely of the column and to cause some of the finely divided coating material to pass by the articles through the spaces therebetween to the opposite side of the column, and maintaining on such opposite side of the column and spaced therefrom a plurality of ionizing zones to charge and redirect such by-passing coating material back toward of coating material thereinto for the column fortelectrostatic deposition on the articles therein.
  • Apparatus for electrostatically coating articles comprising a discharge electrode providing a coating zone having an inlet end and an exit end, a conveyor operable to convey said articles through said zone from the inlet to the exit end thereof, an atomizing means arranged at one end of said coating zone to direct a spray electrostatic deposition on the articles, means for revolving said articles at a relatively high rate of speed at the end of the zone where the concentration of coating material is highest, and means for revolving said articles at a relatively low rate of speed at the other end of the zone.

Description

Filed Feb. 3. 1945 BY ELECTROSTATIC DEPOSITION ARTICLES 4 Sheets-Sheet 1 HIVI uvmvrom.
H PJRANS BURG ET AL METHOD AND APPARATUS FOR CO 4 Sheets-Sheet 2 Filed Feb. 3, 1945 I V g min N M Mm 7 D Hm lv W Y B March 1, 1949. s uR ETAL 2,463,422
METHOD AND APPARATUS FOR COATING ARTICLES BY ELECTROSTATIC DEPOSITION Filed Feb. 3, 1945 4 Sheets-Sheet 3 March 1, 1949. H. P. RANSBURG EI'AL 2,453,422
METHOD AND APPARATUS FOR COATING ARTICLES BY ELECTROSTATIC DEPOSITION 4 Sheets-Sheet 4 Filed Feb. 5, 1945 SE26 MFG w R x2528 1P5 6 5? QNN W 9 Patented Mar. 1, 1949 METHOD AND APPARATUS FOR COATING ARTICLES BY ELECTROSTATIC DEPOSI- TION Harold P. Bansbnrg and Richard E. Helmnth,
Indianapolis, Ind, assignors, by mesne assignments, to Hamburg Electro-Coating Corp., 111- dianapolis, Ind., a corporation of Indiana Application February 3, 1945, Serial No. 575,956
31 Claims. (Cl. 117-93) This invention relates to electrostatic coating and is especially directed to improved methods and apparatus for handling articles to be coated, to the positioning and construction of discharge electrodes, and to the provision of various safety factors.
Objects of the invention are to provide methods and apparatus which achieve greater uniformity of coating, greater economy in utilization of coating material, speedier and more efficient coating production and greater safety to personnel and property.
A preferred embodiment of my prises a number of novel features of method and apparatus, but many of the advantages of the invention can be attained through the use of less than all of such novel features. In the preferred embodiment, which is described in detail hereinafter, the articles to be coated are conveyed in spaced relation successively through a precoat zone and a finish-coat zone over a path which includes portions lying respectively within such two zones and disposed at an angle to each other. Coating material in finely divided condition is discharged into the finish zone toward the precoat zone and with sufficient velocity to cause at least some of the particles of coating material to be carried into the precoat zone. A discharge electrode possessing several novel features and disposed in spaced relation to the article path is employed in creating an electrostatic field promoting the deposition of coating material on the articles. The discharge electrode may include a section disposed to redirect toward the article-path coating-material particles which are carried across the article-path through the spaces between adjacent articles. Where the apparatus includes means for rotating the articles as they pass through the coating zones. such means is desirably arranged to rotate the articles at a relatively high speed in that portion of the coatin zones where the concentration of coating material is relatively great and at a lower speed in those regions when the concentration of coating material is relatively low.
Where the articles are moved by an overhead conveyor, each article may be supported therefrom through the medium of an improved twopart hook, and guide means may be provided to reduce such swaying of the articles as would vary their distance from the discharge electrode.
Ventilating means employed to withdraw air from the booth in which the coating operation is customarily performed is soarranged as to maintain the air at a relatively low velocity invention comwithin the coating zones and at a higher velocity after it has left such zones. whereby any adverse eifect of the moving air on the deposition of coating material within the coating zones will be reduced, while volatilized solvents and any coating material which does escape deposition on the articles will be rapidly carried away.
Safety features of the invention include the use of an isolating fence, a gate therein, and a gate-operated switch controlling energization of the field-creatin means and the use of interlocking electrical circuits which prevent energization of the field-creating means except while the ventilating means is in operation.
Other features of the invention will be described hereinafter and pointed out in the appended claims.
The full nature of the invention will be understood from the accompanying drawings and the following description and claims:
Fig. 1 is a front elevation of the spray b with a portion broken away and parts remo iig plan view of the spray booth.
Fig. 2 is a schematic illustration showing Fig. 3 is a schematic illustration showing a plan view of the spray booth on a reduced scale with the isolating fence and associated apparatus.
Fig. 4 is a cross section through a portion of the conveyor mechanism.
Fig. 5 is an enlarged elevational view of a portion of the article supporting hook with its associated idler wheel in section.
Fig. 6 is a sectional detail of the spinner hook.
Fig. 7 is a wiring diagram of the electrical control circuits.
In the drawings. illustrative of one arrangement'and application of the invention, there are shown articles ill to be coated which are hung in spaced relationship from a conveyor support II which carries them through an entrance opening I! in the side of a spray booth l3 constructed of insulating material. Once inside the booth the path of travel of the articles changes by (as shown in Fig. 2) and they are carried toward the open exit end of the booth and out of it. havll'lg been coated with finishing material in the process.
While inside the booth, the articles are surrounded with a fog of coating material finely atomized by suitable atomizing means such as the air guns indicated at it into an electrostatic field established between the articles and a fine wire discharge electrode I. This fleld, which charges and electrically precipitates the material onto the article, is maintained by a suitable voltage source l8 connected to the discharge electrode by a lead-in conductor i'l. While in this held the articles are rotated by a mechanism. to be hereinafter described, as they move along the conveyor support.
The nature 01 the atomized spray is controlled by suitable regulators contained in a control cabinet generally indicated at iii. A general convection through the booth past the items is maintained by a fan Is and is further distributed by the baflies indicated at in Fig. 2. The entire assembly of booth and voltage supply is electrostatically isolated from its surroundings by an isolating. shield 2|.
' In the modification shown the spray booth I3 is constructed of electrically non-conducting material. It is approximately rectangular in shape with its exit end open. and is fitted with an air outlet chamber 22 that is fronted with a series of non-conducting bailles 20 to control the flow of air through the booth. This results in a lower air velocity within the electrostatic field, a still lower air velocity at the air entrance end and a higher air velocity where the air leaves the electrostatic held. The slow air movement within the field aids electrostatic deposition, and the air that has left the field carrying residual particles is sped-up to minimize settling of the residual particles. The fan I 9 providing this ventilation is of non-conducting material so that the tendency of charged material to collect on it will be reduced to a minimum. The entrance opening l2 oi. the booth is silhouetted generally to the shape of the articles l0, and is located on one side adjacent the air outlet chamber 22. This opening is extended outward from the booth wall so that the amount of air entering therethrough will be reduced to a minimum. The booth has a ceiling and floor to complete the enclosure.
Situated in the entrance opening l2, and attached thereto is a series of removably mounted spring guide plates 23 between which the articles pass to arrest and control any lateral swinging movement of the articles transverse to their path of travel. Such motion must be restricted during the articles travel through the booth so that the distance between the surface oi the article and the discharge electrode will remain fixed. 11' this distance does not remain constant a hazardous spark may result. Said guide plates also serve air current through the opening l2.
The discharge electrodes I 5 are located in the booth adjacent to and conforming with the path of travel of the. articles. They are composed of a plurality of frames Ilia suspended from the booth ceiling by electrical strain insulators 24. These frames supply the supports across which a series of .010" diameter wires llib are stretched for producing the necessary ionizing and precipitating fields. These wires are equally spaced from each other on centers thirds of the distance of the electrode plane from the surface of the article. A number or such names iia form each complete discharge electrode II and are arranged adjacent to the articles on both sides and about the bottom as they pass through the booth. The electrode is thus, in eil'ect. U-shaped or trough-like. conforming to the bottom and sides of the article being coated.
The electrostatic field is established between the insulated discharge electrodes it and the to block and reduce any which are about two charge electrode grounded articles by connecting them to a in able high voltage source. The source her disclosed and indicated at l8 consists of a he wave. over controlled, limited current rectii capable of converting normal line voltage pulsating high voltage direct current. One t minal of this source is connected by an insula1 lead H to the electrode system and the otl terminal is grounded. Since the conveyor. a thus the articles, are grounded, such a soul will establish an electrical field of consideral strength between the discharge electrode wii l5b and the surface of the articles. The leadconductor l1 between said source and the d should be of reasonable si 8" or larger) in order that parasitic coro: losses will be reducefi to a minimum.
The conveyor guide rail I I is of the ordina I-beam type and is electrically grounded. In: path through the booth it makes a horizo: tal turn, entering through the entrance l2 d scribed above, and leaving through the 091 booth exit. The conveyor system mounted the booth is surrounded with a grounded col ducting shield 25 which insures that it will n have any material electrically precipitated up: it as it passes through the booth.
Suitable hooks 26 depend from a conveyl chain 21 of the conveyor system at regular 11 tervals to support the articles in columnar space relation. The hooks are so designed that the are free to rotate on a bearing situated in spinner 28 near the top. Below this spinner an arranged to idle on the shank of the hook is a idler guide wheel 29. The wheel 29, together wit its depending sleeve 29a, is arranged to act as looking collar and shield over 9. splice in th shank oi the hook 28. The splice is so arrange that the shank of the hook is continuous who the wheel is in place, but when it is raised th lower portion of the hook may be readily re moved. This permits removal of the expose portion of the hook from the conveyor so tha it may be easily cleaned of excess coating mate rial accumulation. Said wheel, in addition t4 supplying mechanical rigidity, also electrical]: shields the splice of the two sections 01' the hool shank to prevent it from becoming coated an: thus insures continuous and certain electrica' contact between the two sections.
When a hook bearing an article enters the spray booth, the spring guide plates 22 insure that the article enters without swinging. The friction spinner wheel 28 pinned to the upper section 26a 01' the hook shank for rotating the article during its travel through the coating zones contacts the shoe 32 to rotate the article in accordance with its linear movement through the pre-coating zone of the electrostatic field. In actual practice the article will be rotated during its pre-coating operation at about one to one and one-half revolutions per foot of linear movement. While the spinner 22 is in contact with shoe 32 the idler wheel 28 is in contact with pressurebar 30a located on the opposite side 01' the conveyor from the shoe 22. Thus the bar Ila insures frictional contact of the spinner 28 with the shoe 32 and also prevents lateral swinging of the article due to rotation. This swinging must be avoided in order to maintain the distance between the article and the discharge electrodes to avoid sparking therebetween.
As the article is conveyed into the straight exit portion of its path, comprising the finish coating zone, said wheel It will contact and be I described by sliding upwardly the Depending upon a 44 extending through the shank 28 supports said sleeve in position to embrace the splice 41. Thus,
of rotation along this portion of its travel ispreferably about four to six times per foot of forward motion. The speeds of rotation through these two zones may be varied according to the surface being coated. While spinner 28 is in contact with belt 33, idler 29 is in contact with pressure bar 30 to insure frictional contact and to prevent swin g.
The spinner through the speed reduction gear box 35, drive shaft 35 and driven pulley 31, which, with its idler pulley 38 is supported by the shield 25. The spinner belt passes around these, two pulleys and over suitable guide surfaces or pulleysindicated at 39 to insure that the passing spinner wheels will contact it. This guide surface will be mounted so as to insure some degree of contact flexibility between the spinners and the belt.
This entire drive unit, as well as the conveyor, is enclosed in the conducting shield 25 mentioned belt 33 is driven by the motor. I4
above to insure that during operation no coatin material will be deposited upon them by the electrostatic field. This shieldprotects the conveyor over its entire path through the spray booth. It isolates the conveyor, spinners and idler wheels from the forces of the electrostatic field, since the lines of force thereof will terminate on its surface.
The spray gun I4 is arranged at the open or exit end of the booth where it will be readily accesible for adjustment by the operator. It is supported on suitable rigid supports 40, 4|, and
is situated to distribute its discharged material in a fairly uniform manner into the finish zone of the electrostatic field established between the discharge electrode and the article. The gun is maintained at ground potential which permits free adjustment during operation without hazard, and also permits it to be placed as close as needed to the article itself. If the gun is not positively grounded, it, as a free conducting body, would accumulate acharge proportional to its electrical capacity, and this charge would be liberated as a hazardous spark when it is approached by an operator or an article.
The gun is connected by suitable hose 42 to the appropriate sources 45 of coating material, operating air and atomizing air; The operating air, atomizing air, and fluid pressure are controlled in turn by suitable controls situated in the control panel Ill. The gun is operated, fluid pressure adjusted, atomizing air controlled, and electrical devices activated from this one position. The electrical circuit is so arranged that switches for the conveyor, ventilating fan, and voltage supply are all located on the panel. The operator in this position thus has immediate control of all phases of the operation.
As shown in Fig. 5 and as has previously been mentioned, the article supporting hooks comprise two parts, a lower shank portion 26 and an upper the idler wheel with its depending sleeve not only serves to guide and steady the hook -and its sup-, ported article to prevent swinging, but also to lock the two portions of the shank'together when in operative position.
By suitably cross connecting the various electrical circuits, as shown in Fig. l, the unit is so arranged that power will not be available to the voltage source until after the ventilating fan is running. This insures adequate removal of inflammable materials before the voltage source can be turned on. A limit switch ahead of the booth is also installed to shut off the conveyor and voltage source in case an article which is too large to enter the silhouetted entrance should be hung on the conveyor. A safety gate switch is also installed on the entrance gate of the field isolating shield 2!, that surrounds the booth, which electrically turns off the voltage when this gate is opened. This guards against a person entering the area when the field is on. Warning lights in parallel with those in the control panel are located on the front of the booth which constantly warn of the operating or non-operating condition of the unit.
In the wiring diagram shown in Fig. '1, the
lead-in wires 46 are connected. with the usual 220 volt electric current. They are connected through a normally open fan starter switch 41, a normally closed fan stopping switch 48 and solenoid 49 with the motor for driving the ventilating fan I9. The solenoid 49, upon being energized by closing switch 41, moves the contact members 50 to circuit closing position, thereby not only closing the circuit to the ventilating fan, but also energizing the circuit II connected to the circuit 52 through the switch 53 and thence to the control panel II for operating the source of high voltage IS. The control panel i8 is provided with a switch 54 to control the source of voltage I. The power lines 48 are also connected through the manually operated switch 55' with a circuit leading to the manually operated switch 55a for energizing the motor 51 which drives the conveyor. Upon switches 55, 58 being closed, a solenoid I! is energized to close switch 53, as well as switch 5! in the conveyor drive motor circuit Ell. The solenoid energizing circuit is provided with normally closed switches I, 62 and 83. Switch M is conveniently located for manual operation to break the circuit through the solenoid 58 for stopping the conveyor and simultaneously breaking the circuit to the high voltage source ii. The switch 82 is a limit switch mounted in the entrance opening I2 of the booth for stopping the conveyor and breaking the circuit through the high voltage source in event one of the articles is not properly mounted on the conveyor, or is of improper size. The switch 83 is mounted upon the gate indicated at O5 in Fig. 3 and is so arranged that when the gate is open the conveyor and high voltage source are inoperative. Also, in the circuit of the high voltage source there is a signal lamp 68 mounted in a conspicuous position upon the isolating fence 2i. such as to provide a warning signal when the source of high voltage is on.
With this safety circuit the electrostatic field cannot be established until after the ventilating fan 19 is placed in operation by closing switch 41, and then only after closing the switch 55, the gate for actuating switch 63 and starting the conveyor by closing switch 50. Additionally,
switch St in the control panel I 8 must be closed, whereupon signal light 68 will give warning. Thus, before the electrostatic field can be established, all parts of the apparatus must be func- Switch 55a permits the operation of the voltage pack without the conveyor being in operation. However, the electrostatic field may be disconnected at the control panel by opening switch 54 continue to function, the conveyor being controlled independently of the ventilator fan.
As mentioned above, the isolating fence is of conducting material and is maintained at ground while the remaining apparatus will 10 8 of the electrostatic field urge them toward article. The force of gravity constantly te to pull them downward. If the atomizing fc is too large relative to the other forces, the p .tioning and the personnel warned thereof. 5 tlcle will be blown through the field. Ifthe e1 trostatic field is not continuous about the it but there exists regions where this force is l or zero, particles in these voids will be carr away from the article by the other two forr If the gravitational force is not properly b anced by the action of the other two, many pi ticles will fall away from the article as unm material.
The degree to which a given particle of COl potential so that it provides a means of effectively lng material will be influenced toward an eff:
restricting and isolating the electrostatic field. In most factories there are a large number of dust particles constantly circulating in the air. As'these approach a spray booth, even though the discharge electrode may have substantial in- 2 sulation surrounding it, they will pick up a charge. Because of this, they are precipitated onto grounded items in the area and in sustained production the zone or area of an electrostatic spray unit by reason of these charged dust particles, will be dirtler and require more maintenance than other portions of the factory. We have found that an isolating fence such as the one herein described, will efiectively minimize the precipitationof dust particles onto other items in the vicinity and will'itself become the collector of these particles. This isolating fence will perform such functions completely if it encloses the booth about the top and sides. However, it has been found that one partially enclosing or surrounding a spray zone performs sufllciently well so that complete enclosure is not always necessary.
Furthermore, when ungrounded conducting items are stationed near the coating zone, such tive deposition by the electrostatic field will c pend upon its velocity, size and direction 9.: upon the proper correlation of the above thr forces. It is therefore the purpose of the prese 0 invention to provide a method and apparatus 1 regimenting these particles whereby they becor effective as coating material and will be event ally deposited upon the article.
The larger particles and those with the grea 25 est velocity will not be deposited as readily will those which are smaller and slower. The larger or higher velocity particles will travel greater distance before their velocity has at creased to the point where the field can depos them. We are able to assure the deposition 1 a muc larger percentage of these particles l: constructing the conveyor sothat it enters tl booth at the side and follows the path show through a pre-coating zone. With this arrange ment many of the particles, aided and directe by the force of the field, will be deposited b direct impact upon the article shortly after i enters the booth. Others which pass betwee:
items, unless the electrostatic field is intercepted, 4:) will be reionized by the discharge electrode, am
ations, is sprayed into the finish coating zone of the electrostatic field established between the discharge electrodes and the articles. Some material will be deposited onto the articles immediately as they enter the pre-coating zone and after having their direction reversed, will bi returned to the article for deposition. The artlcl is rotated to insure uniformity of this rathe: light pre-coating. The rate of this rotation mus 45 be relatively low to prevent undesirable turbu lence but still high enough to insure a uniforn deposit of the material.
As the article the booth it is carried around the curved path sively more dense. In this disclosure the direction of travel of the articles in these two zones is shown to be substantially at right angles.
the coating will be completed as the article makes Other angles either greater or less than 90 dezone out of the booth past the spray guns.
The spray, as it leaves the gun, is far from homogeneous in particle size and grees can be used to realize the advantages herein disclosed in cases where they are more suited to the conveyor travel before and after the coating operation. It is in this zone that those particles will contain both small and large part cles which 00 which have reasonable velocity and are small are spray which are introduced into the field and 70 ionized by the action of the discharge electrode have their motion controlled by three forces. They are projected away from the gun in a direction substantially tangential to the surface to be coated by the atomizing forces.
The forces 76 deposited. Because of the increased density of sprayed material the articles in this zone must be rotated more rapidly to obtain uniformitv. This is permissible because the turbulence is not as objectionable inasmuch as particles lost from the process here will be precipitated later in the pre-coating zone where the rate of rotation is not large. Furthermore the size and velocity of the particles precipitated here is such that the field is more effective and greater turbulence can be tolerated.
The mutual action of the three forces mentioned above is accomplished by the form and arrangement of the discharge electrode. Being constructed of fine wire elements with small radii which surround the article on three sides, it forms an electrostatic trough, so to speak, inside of. which the electrostatic field will be continuous and complete and inside of which the ionization of all particles will be assured and maintained. Since the gravitational force is downward into this trough, and since the electrostatic forces are all directed toward the item, coating material in this trough will be maintained therein until effective precipitation results. Particles which rebound from the surface or have their ionization neutralized by collision, are reionized and redeposited by successive elements of the U-shaped discharge electrode as they are carried along this trough by the velocity given them by the atomizing means. 7
This type of electrode is of particular benefit for the deposition of that material which is atomized into the field intended for coating the bottom of an article. The natural tendency of the material to fall away from the surface for 10 of rotation toward the exit end of said coating zone than nearer the inlet end thereof, establishing an electrostatic field in said zones wherein said articles comprise the collecting electrode,
and directing atomized coating material into said coating zone in a direction from the exit end toward the inlet end for electrostatic deposition on said revolving articles.
3. Apparatus for electrostatically coating articles, comprising a-discharge electrode mounted to provide an L-shaped coating zone having an inlet portion and an exit portion extending substantially at right angles thereto, a conveyor operable to convey said articles into the inlet portion of said zone and through a curved path into and" through said exit portion thereof, means for establishing an electrosatic field between said electrode and articles and an atomizing means mounted to direct a spray of coating material into and longitiudinally of the exit portion of said coating zone toward the transverse inlet portion which it is intended is overcome by the increased electrostatic forces created on this surface. This unobstructed. upward force due to the bottom section of the electrode also aids materially in counteracting the normal settling tendency of the coating material which is in position for deposition on the sides of the article because it allows the 'mutual repulsion of the charged particles to be effective in a vertical direction.
From the above description it will be evident that the coating obtained from the application of this method and apparatus will result from a gradual accumulation of material over a relatively long period of time. Whereas the article to be coated is shown and described herein as a bucket, it may be of any charactercomprlsing.
either conducting or non-conducting material. In either case so long as the material is precipitatedonto the article, the article is herein considered as comprising the collecting electrode on which the coating material is gradually accumulated. Such gradual application ofv coating material permits one to obtain a finish film which is more uniform, heavier and consequently of thereof for electrostatic deposition on said articles as they pass therethrough.
4. Apparatus for electrostatically coating articles, including a discharge electrode having a Precoat section extendingin a curve to a finish section thereof, a conveyor conforming to said electrode operable to convey said articles in a direction to first pass adjacent to said pre-coat section and then said finish section and in predetermined spaced relation thereto, means for establishing an electrostatic field between said electrode and articles, and an atomizing means mounted adjacent the end of said finish section to direct said material adjacent thereto and toward said pre-coat section for electrostatic depopening in the sidewall thereof and an open exit end, means for conveying the articles to be coated greater hiding power. It is a one operation process which is superior in economy, durability and appearance to the coating normally applied by hand operation where a dust or mist pre-coat is first applied to the article before the application of the final or. finish coat.
The invention claimed is:
l. The method of electrostatically coating articles consisting in conveying the articles through a pre-coating zone into a finish coating zone wherein said zones extend substantiallyat right angles to each other and one is a continuation of the other, revolving said articles at a greater "speed of rotation during their passage through said finish coating zone than during their passage through said pre-coating zone, establishing an electrostatic field in said zones wherein said articles coniprise the collecting electrode, and directing atomized coating material into and substantially longitudinally of said finish coating zone, counter to the direction of movement of the articles conveyed therethrough, and toward and into said pre-coating zone for electrostatic deposition on said articles passing through both of said zones.
2. The method of electrostatically coating articles consisting in conveying the articles through a coating zone from an inlet end to an exit end, revolving said articles at a greater speed into said booth through said inlet opening and in a direction substantially at right angles thereto through said exit end, a substantially L-shaped discharge electrode mounted in said booth to conform with the path ,of travel of said articles through said booth in spaced relation thereto, means for establishing an electrostatic field between said electrode and articles, and an atomizing means mounted adjacent the exit end of said booth operable to direct a spray of coating material therein along the adjacent path of said articles toward their angularly disposed path for electrostatic deposition thereon.
6. Apparatus for electrostaticaliy coating articles including a spray booth having an inlet opening in the side wall thereof and an open exit end, a substantially L-shaped coating zone therein extending from adjacent said inlet opening to said exit end defined by spaced discharge electrodes mounted in said booth, means for conveying the articles to be coated in a path leading from the inlet opening to the exit end of said booth substantially medially of said zone and electrodes, means for establishing an electrostatic field between said electrodes and articles throughout said coating zone, and an atomizing means positioned to direct a spray of coating material through that portion of said coating zone extending to and terminating with the exit end of the booth, and toward the portion thereof extending from said inlet opening.
7. Apparatus for coating articles, including an guide members prevent lateral hooks having a spliced of the lower portion discharge elements, means for conveying a column of articles to be coated through said trough-like electrode, said articles having bottom andside surfaces to be coated, meansfor suspending said articles from said conveyor to present an unobstructed bottom surface in predetermined spaced relation to the bottom portion of said electrode with the side surfaces thereof similarly spaced from the side portions of said spray booth having enclosing and confining walls,
one of said walls being provided with a restricted inlet opening, a conveyorhaving means for suspending article therefrom to be coated, saidconveyor extending through said booth for conveying the articles to be coated into said booth through said restricted inlet openingand through an outlet opening out of the booth, a pair of yielding mounted in said inlet opening spaced from each other to permit passage of said articles therebetween to steady said articles and swinging thereof upon entering said booth, a coating zone through which said articles are conveyed in said booth, means for establishing an electrostatic field in said zone, and an atomizing means for atomizing a coating material into said field for electrostatic deposition onto said articles.
9. Apparatus for coating articles including a conveyor including means for suspending articles therefrom for conveying the articles to be coated through a coating zone, means including a dis charge electrode for establishing an electrostatic field in said zone between said electrode and articles. a guide rail extending along and adjacent said conveyor in fixed spaced relation to said electrode, a guide roller associated with said first mentioned means engageable with said guide rail to maintain said articles in a predetermined path of travel through said zone and prevent swinging movement thereof toward said electrode, and an atomizing means for atomizing a coating material into said field for electrostatic deposition onto said articles.
10. Apparatus for coating articles including a conveyor for conveying the articles to be coated through a coating zone, a series of hooks depending from said conveyor means for removably suspending said articles therefrom, each of said shank to permit removal of the lower shank portion from the upper shank portion, a protective shielding sleeve slidably sup ported to envelop the spliced portion of said shank when in lowered position to prevent accumulation of coating material thereon, said sleeve being slidable upwardly to permit removal portion thereof, means for establishing an electrostatic field in said coating zone, and an atomizing means for atomizing a coating material into said field for electrostatic deposition onto said articles. I
11. Apparatus for coating. articles including a conveyor for conveying the articles to be coated through a coatingzone, a series of hooks depending from said conveyor means for removably suspending said articles therefrom, each of said hooks having a spliced shank to permit removal of the lower shank portion from the upper shank portion, a protective shielding sleeve slidably supported to envelop the spliced portion of said shank when in lowered position to prevent accumulation of coating material thereon, said sleeve being slidable upwardly to permit removal of the lower portion of the shank from the upper portion thereof, a guide rail extending along said conveying means, an idler roller rotatably mounted on said sleeve engageable with said guide rail to guide said articles along their path of travel, means for establishing an electrostatic field in said zone, and an atomizing means for atomizing a coating material into said field for electrostatic deposition onto said articles.
12. Apparatus for coating articles including a spray booth, means for conveying said articles through said spray booth, a discharge electrode mounted in said booth in spaced relation to the 1 path of travel of said articles, a source of high of the shank from the upper voltage having one terminal connected with said electrode and the other terminal connected with said articles to establish an electrostatic field therebetween, an atomizing means mounted to direct a spray of coating material into said field for electrostatic-deposition on said articles passing through said booth; an isolating fence surrounding said booth and extending therefrom,
said fence being of conducting material electrically connected with said last-mentioned terminal of the source of high voltage, a gate in said fence to permit access therethrough, and a control switch operable by said gate to break the circuit between said source of high voltage and said electrode when said gate is in open position. 13. Apparatus for electrostatically coatingarticles including a spray booth having enclosing and confining walls, a conveyor extending through said booth for conveying the articles tobe coated therethrough, a'fan for exhausting said booth, a discharge electrode extending along the path of travel of said articles and spaced therefrom, a source ofhigh voltage having one terminal electrically connected with said electrode and the other terminal with said conveyor to establish an electrostatic field between the articles carried thereby and said electrode, an atomizing means for atomizing a coating material into said field for electrostatic deposition onto said articles, a motor for driving said fan, a motor for driving said conveyor, electric circuit interconnectng a source of current with said motors and source of high voltage, and control switches in series in said circuits operable to maintain the circuit to said high voltage source open until said motor circuits are closed.
14. Apparatus" for electrostatically coating articles including a spray booth, a shielding fence surrounding and spaced from said booth having a gate for permitting access thereto, a conveyor extending through said booth for conveying articles to be coated therethough, a motor for driving said conveyor, an exhaust fan for said boot'h, a motor for driving said fan, a discharge electrode mounted in said booth extending in spaced relation to said conveyor and the articles conveyed thereby, a high voltage source having one terminal electrically connected with said electrode and the other terminal with said conveyor for establishing an electrostatic field between said electrode and the articles carried .said article.
. i3 by said conveyor, an atomizing means for atomizing a coating material into said field for electrostatic deposition on said articles, electric circuits interconnecting a source of current with said motors and high voltage source, a switch in said circuits operated by the gate of said shielding fence forcontrolling said circuits, and control switches in said circuitsin series with said first switch arranged to maintain the circuit to the high voltage source open until said motor circuits and gate switch are closed.
15. An apparatus comprising a boothhaving an electrostatic field between said electrode and articles, and atomizing means to direct a spray of coating material through said zone.
16. Apparatus for electrostatically --coating articles, including a discharge electrode having a pre-coatsection extending at'an angle to a finish section thereof, a conveyor conforming to said electrode operable to move said articles in a direction to first pass adjacent to said pre-coat section and then said finish section, means for establishing an electrostatic field between said electrode and articles, an atomizing means mounted adjacent the end of said finish section to direct coating material adjacent thereto and towards said pre-coat section for electrostatic deposition on said articles, and means for exhausting air from the finish'section through the pre-coat section.
1'7. An apparatus comprising a generally U- shaped discharge electrode, conveyor means to move a column of articles having bottom and side surfaces'to be coated through said U-shaped said conveyor means to present an unobstructed bottom surface in predetermined spaced relation to the bottom portion of said electrode with the side surfaces thereof similarly spaced from the side portions of said electrode, a source of high voltage having one terminal connected with said electrode and the other terminal with said conveyor m'eans to establish an electrostatic field having lines of force directed upwardly to terminate with the bottom of said article and lines of force directed laterally to terminate with the side surfaces thereof, and means for introducing finely divided coating material into said field for electrostatic deposition over the surfaces of 18. Apparatus for coating articles, comprising a booth having confining walls and provided with a main air-inlet opening, means for drawing air into said inlet opening and through the booth, one of said booth walls being provided with an auxiliary air-inlet opening materially smaller than said main opening and located between said main opening and said air-drawing means, a conveyor for moving articles to be coated through said booth over a path extending through said auxiliary opening and including a portion extending generally normal to the path of air fiow between the main opening and said air-drawing means, a discharge electrode having a portion spaced laterally from said path-portion, means for creating an electrostatic field between said electrode portion and the articles conveyed past it, and means located near the main inlet finely divided coating material into said field! 19. An apparatus comprising means for supporting in a coating zone an article to be coated.
an ionizing electrode having a portion disposed at one side of and spaced from an article on said support, a source of high electrical potential having opposite terminals respectively associated with the article and electrode to create an electrostatic field therebetween, and means for introducing into such field finely divided coatin material for electrostatic deposition on the article,
said electrode having a generally horizontal portion disposed below the article to repel upwardly coating material particles which tend to settle from the coating zoneunder the influence ofgravity.
20. Apparatus for coating articles, comprising a conveyor having two portions arranged at an angle to each other, a discharge electrode disposed at one side of one of said conveyor portions in spaced relation to articles carried thereby, a discharge electrode disposed at the opposite side of the other of said-conveyor portions, means for establishing'an electrostatic field between said electrodes and articles conveyed past them .by the conveyor, means for spraying finely divided coating material into the space between the first mentioned electrode and its adjacent conveyor portion and toward said other conveyor portion and its adjacent electrode, the latter serving to repel coating material particles carried through said space.
21. Appa'ratus for electrostatically coating articles, including a discharge electrode having a prc-coat section extending at an angle to a finish section thereof, a conveyor conforming to said electrode operable to move said articles in a direction to first pass adjacent to said pre-coat 40 section and then said finish section, means for electrode, means for suspending said articles from V .mounted adjacent the endof said finish section to direct said material adjacent thereto and towards said pre-coat section for electrostatic deposition on said articles.
22. An apparatus comprising a discharge electrode, means for conveying articles in spaced relation to said electrode, a source of high voltage having one terminal connected with said electrode and the other terminal connected with said articles to establish an electrostatic field therebetween, atomizing means mounted to direct a spray of coating material into said field, an isolating fence for said electrode electrically connected .to said articles, a. gate in said fence, and a control switch operable by said gate to disestablish said field-between said electrode and said articles when the gate is open.
23. An apparatus comprising, an electrode frame carrying a plurality of fine wires adapted to be connected to a high voltage source to provide an ionizing discharge, means to move an article past said wires, the spacing between the wires on the frame being about two thirds the minimum distance between a wire and a surface of anarticle to be coated, and means for atomizing a coating material in said discharge for opening for discharging.
upper portion, said hook-portions being of electrically conductive material, and a sleeve enveloping the interlock of said shank, said sleeve being slidable along the shank to permit removal of the lower portion of the shank from the upper portion thereof, an electrode disposed in the coating zone in spaced relation to articles conveyed by said conveyor, a source ofihigh-voltage having its terminals connected respectively with said electrode and with the upper hook-portions for establishing an electrostatic field in said coating zone, and means for atomizing a coating material into said field for electrostatic deposition onto said articles.
25. An apparatus comprising electrode means for producing an ionizing field, a conveyor operable to move articles to be coated through said field, means outside of said field for revolving said articles at a predetermined speed of rotation while conveyed through said field, guide means between said latter means and said field, and atomizing means mounted to direct a' spray of coating material into said field for electrostatic deposition on said articles.
26. Apparatus for coating articles including means for establishing an electrostatic field a conveyor extending through the field, a series of hooks depending from said conveyor for carrying articles to be coated through said field, each of said hooks having a shank including upper and lower interlocking' portions to permit removal of the lower portion from the upper portion, a sleeve enveloping the interlock of said shank, said sleeve being slidable along the shank to permit removal of the lower portion of the shank from the upper portion thereof, an idler wheel mounted upon said sleeve, guide means extending substantially parallel to the conveyor at said field in position to be engaged by the idler wheels associated with articles passing through the field whereby to restrict lateral swinging of the hooks supporting such articles, and means for atomizing a coatingmaterial into said field for electrostatic deposition onto said articles.
27. Apparatus for electrostatically coating articles, including a discharge electrode having a pre-coat section and extending in a curve to a finish section thereof, a conveyor operable to con- .vey said articles through said sections, means for revolving said articles while conveyed around said curve, means for establishing an electrostatic field in said sections with said articles comprisinga collecting electrode therein, and atomizing means mounted to direct a spray of coating material into said finish section for electrostatic deposition on said articles.
28. Apparatus for coating articles including a spray booth having confining walls and an exit, one of said walls being provided with an inlet opening, a conveyor extending through said booth for conveying the articles to be coated into said booth through said inlet opening and out of said booth through said exit, means for establishing an electrostatic field in said booth, means mounted adjacent said opening for limiting lateral movement of said articles, as they are conveyed toward the field, and means for atomizing a coating material into said field for electrostatic deposition onto said articles.
29. Apparatus for electrostatically coating articles, including a discharge electrode, a conveyor operable to convey articles in a curved path to pass adjacent to said electrode, means for establishing an electrostatic field between said electrode and articles, and atomizing means mounted to direct said material into said field on the concave side of the conveyor for electrostatic deposition on said said articles.
30. The method of coating articles which comprises moving the articles in spaced relation in a column over a predetermined path, discharging finely divided coating material on one side of the article-column for deposition on the articles, withdrawing air from the region on the opposite side of the article-column whereby to induce a flow of air generally transversely of the column and to cause some of the finely divided coating material to pass by the articles through the spaces therebetween to the opposite side of the column, and maintaining on such opposite side of the column and spaced therefrom a plurality of ionizing zones to charge and redirect such by-passing coating material back toward of coating material thereinto for the column fortelectrostatic deposition on the articles therein.
- 31, Apparatus for electrostatically coating articles, comprising a discharge electrode providing a coating zone having an inlet end and an exit end, a conveyor operable to convey said articles through said zone from the inlet to the exit end thereof, an atomizing means arranged at one end of said coating zone to direct a spray electrostatic deposition on the articles, means for revolving said articles at a relatively high rate of speed at the end of the zone where the concentration of coating material is highest, and means for revolving said articles at a relatively low rate of speed at the other end of the zone.
HAROLD P. RANSBURG.
RICHARD E. HELMUTH.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS
US575956A 1945-02-03 1945-02-03 Method and apparatus for coating articles by electrostatic deposition Expired - Lifetime US2463422A (en)

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BE463400D BE463400A (en) 1945-02-03
US575956A US2463422A (en) 1945-02-03 1945-02-03 Method and apparatus for coating articles by electrostatic deposition
GB2301/46A GB645612A (en) 1945-02-03 1946-01-23 Method and apparatus for coating articles by electrostatic deposition
GB8558/48A GB645629A (en) 1945-02-03 1946-01-23 Method and apparatus for coating articles by electrostatic deposition
FR922540D FR922540A (en) 1945-02-03 1946-02-19 Method and apparatus for coating objects

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US2565454A (en) * 1947-09-20 1951-08-21 Raytheon Mfg Co Electrostatic smoking device
US2585799A (en) * 1947-02-11 1952-02-12 Glenn A Lawrence Apparatus for smoking fish
US2693166A (en) * 1952-05-26 1954-11-02 Kelsey Hayes Wheel Co Flux applying apparatus
US2718477A (en) * 1950-03-20 1955-09-20 Ransburg Electro Coating Corp Method and apparatus for electrostatic atomization
US2723646A (en) * 1950-04-01 1955-11-15 Ransburg Electro Coating Corp Apparatus for electrostatic atomization and coating
US2741218A (en) * 1950-11-10 1956-04-10 Ransburg Electro Coating Corp Electrostatic coating apparatus
DE971564C (en) * 1952-03-26 1959-02-19 Metallgesellschaft Ag Process for applying top coats to base coats in an electrostatic field
US2884341A (en) * 1955-03-07 1959-04-28 Ransburg Electro Coating Corp Electrostatic spray coating method
US2893894A (en) * 1958-11-03 1959-07-07 Ransburg Electro Coating Corp Method and apparatus for electrostatically coating
US2893893A (en) * 1950-01-31 1959-07-07 Ransburg Electro Coating Corp Method and apparatus for electrostatic coating
DE1136620B (en) * 1952-03-05 1962-09-13 Harper J Ransburg Company Device for electrostatic coating
US3376156A (en) * 1964-03-19 1968-04-02 Douglas C. Whitaker Spray painting employing high voltage charging
US3384048A (en) * 1964-06-01 1968-05-21 Mc Graw Edison Co Automatic glazing and sanding machine
US4099486A (en) * 1977-03-28 1978-07-11 Owens-Illinois, Inc. Electrostatically coating hollow glass articles
US4120261A (en) * 1977-11-25 1978-10-17 Caterpillar Tractor Co. Electrostatic coating system
WO1979000267A1 (en) * 1977-11-09 1979-05-17 Caterpillar Tractor Co Electrostatic coating system
US5843536A (en) * 1992-12-03 1998-12-01 Ransburg Corporation Coating material dispensing and charging system
DE10344135A1 (en) * 2003-09-24 2005-05-04 Karlsruhe Forschzent Device for applying electro-spray coatings to electrically non-conducting surfaces has electrospray capillary for introducing, electrically charging electrospray onto surfaces, periodically repeats compensation, dissipation of charges
US20050103210A1 (en) * 2002-03-01 2005-05-19 Peter King Product coating method and apparatus

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DE2551659A1 (en) * 1975-11-18 1977-10-13 Malkmus Doernemann Carola SYSTEM FOR ELECTROSTATIC POWDER COATING OF HANGING MOVING PARTS
CN106493018A (en) * 2016-12-30 2017-03-15 天津赛智科技发展有限公司 A kind of double-disk electrostatic spraying apparatus

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US1855869A (en) * 1928-12-31 1932-04-26 Western Electric Co Method of and apparatus for coating articles
US2217444A (en) * 1938-04-06 1940-10-08 Westinghouse Electric & Mfg Co Method of and means for the manufacture of abrasive cloth
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US1855869A (en) * 1928-12-31 1932-04-26 Western Electric Co Method of and apparatus for coating articles
US2222539A (en) * 1934-12-11 1940-11-19 Behr Manning Corp Method of and apparatus for making pile-surfaced sheets
US2217444A (en) * 1938-04-06 1940-10-08 Westinghouse Electric & Mfg Co Method of and means for the manufacture of abrasive cloth
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Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2585799A (en) * 1947-02-11 1952-02-12 Glenn A Lawrence Apparatus for smoking fish
US2565454A (en) * 1947-09-20 1951-08-21 Raytheon Mfg Co Electrostatic smoking device
US2893893A (en) * 1950-01-31 1959-07-07 Ransburg Electro Coating Corp Method and apparatus for electrostatic coating
US2718477A (en) * 1950-03-20 1955-09-20 Ransburg Electro Coating Corp Method and apparatus for electrostatic atomization
US2723646A (en) * 1950-04-01 1955-11-15 Ransburg Electro Coating Corp Apparatus for electrostatic atomization and coating
US2741218A (en) * 1950-11-10 1956-04-10 Ransburg Electro Coating Corp Electrostatic coating apparatus
DE1136620B (en) * 1952-03-05 1962-09-13 Harper J Ransburg Company Device for electrostatic coating
DE971564C (en) * 1952-03-26 1959-02-19 Metallgesellschaft Ag Process for applying top coats to base coats in an electrostatic field
US2693166A (en) * 1952-05-26 1954-11-02 Kelsey Hayes Wheel Co Flux applying apparatus
US2884341A (en) * 1955-03-07 1959-04-28 Ransburg Electro Coating Corp Electrostatic spray coating method
US2893894A (en) * 1958-11-03 1959-07-07 Ransburg Electro Coating Corp Method and apparatus for electrostatically coating
US3376156A (en) * 1964-03-19 1968-04-02 Douglas C. Whitaker Spray painting employing high voltage charging
US3384048A (en) * 1964-06-01 1968-05-21 Mc Graw Edison Co Automatic glazing and sanding machine
US4099486A (en) * 1977-03-28 1978-07-11 Owens-Illinois, Inc. Electrostatically coating hollow glass articles
WO1979000267A1 (en) * 1977-11-09 1979-05-17 Caterpillar Tractor Co Electrostatic coating system
US4158344A (en) * 1977-11-09 1979-06-19 Caterpillar Tractor Co. Electrostatic coating system
US4120261A (en) * 1977-11-25 1978-10-17 Caterpillar Tractor Co. Electrostatic coating system
US5843536A (en) * 1992-12-03 1998-12-01 Ransburg Corporation Coating material dispensing and charging system
US20050103210A1 (en) * 2002-03-01 2005-05-19 Peter King Product coating method and apparatus
DE10344135A1 (en) * 2003-09-24 2005-05-04 Karlsruhe Forschzent Device for applying electro-spray coatings to electrically non-conducting surfaces has electrospray capillary for introducing, electrically charging electrospray onto surfaces, periodically repeats compensation, dissipation of charges

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Publication number Publication date
FR922540A (en) 1947-06-11
GB645612A (en) 1950-11-01
BE463400A (en)
GB645629A (en) 1950-11-01

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