US2427022A - Surgical adhesive tape - Google Patents

Surgical adhesive tape Download PDF

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Publication number
US2427022A
US2427022A US464894A US46489442A US2427022A US 2427022 A US2427022 A US 2427022A US 464894 A US464894 A US 464894A US 46489442 A US46489442 A US 46489442A US 2427022 A US2427022 A US 2427022A
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United States
Prior art keywords
adhesive tape
salt
adhesive
acid
coating composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US464894A
Inventor
Walter R Russ
Hoffman Charles
Thomas R Schweitzer
Dalby Gaston
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ward Baking Co
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Ward Baking Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ward Baking Co filed Critical Ward Baking Co
Priority to US464894A priority Critical patent/US2427022A/en
Application granted granted Critical
Publication of US2427022A publication Critical patent/US2427022A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42Use of materials characterised by their function or physical properties
    • A61L15/58Adhesives

Definitions

  • Our present invention relates to improvements in adhesive plaster or tape.
  • adhesive plasters as heretofore made were applied to the skin of a patient they frequently gave rise to skin disturbances and irritations, such as itching or pruritis, or otherirritations, which in some cases necessitated leaving off the plaster. This tend- 4 Claims. (Cl. 16784) ency to irritation was, of course, more pronounced in cases in which the application of the plaster was continued over an extended period of time.
  • an adsesive plaster or tape on which this tendency toward irritation or skin disturbances is substantially eliminated.
  • fatty acids may be either branch or straight chain, saturated or unsaturated, or may be halogen derivatives of such acids.
  • the saturated acids include propionic, butyric, valeric, caproic, heptylic, caprylic, nonylic or pelargonic, and capric.
  • the unsaturated acids include acrylic, crotonic, angelic, undecylenic, etc.
  • Any member or members of the above group of acids and salts may be incorporated in the adhesive plaster or coating composition of an adhesive tape in such a manner that it will be present in sumcient amounts on the exposed surface of the coating.
  • the coating composition of the adhesive tape is composed basically of a gum, such as caoutchouc, and a suitable softener, such as an oil or fat, resins and a filler, such as zinc oxide, which may itself have some value as a medicament. Also a small amount of any suitable antiseptic may be incorporated.
  • the .fatty acid or acids and its salt or salts may be incorporated in the coating composition either as a substitute in part for zinc oxide, or if the selected acid or its salt is of a sticky or viscous nature, it might be substituted in part for the softener or resin or gum.
  • the amount of the fatty acid required at the surface need be very small because it acts in an aqueous solution in the moisture of the skin, which is necessarily very small in quantity.
  • the concentration of the'fatty acid or its salt may range, therefore, from one just sufficient to provide suflicient surface concentration to the point where the adhesiveness or other properties of the coating may be affected.
  • An example of an adhesive tape coating to which the invention may be applied is one having Parts Caoutchouc 34 Dammar. '7 Colophony 3.5 Lanolin neutral 24.5 Zinc oxide 30
  • Examples of the application of the invention to an adhesive tape coating of the above composition are as follows:
  • Example I Example 11 a From 0.3% to 10% of sodium undecylenate, an unsaturatedfatty acid or its salt is admixed to the coating composition and applied to the backme in the usual manner.
  • Example III In this example from 0.3% to 10% sodium caprate is incorporated in the coating composition.
  • Example IV In this example from .01% to 5% beta iodopropionic acid is incorporated in the coating composition to be applied to the fabric coating. Or the corresponding bromin or chlorine substitution products of the series may be employed.
  • the pus formation, irritation or disturbance of the skin or wound appears to be either caused directly or indirectl by certain pathogenic fungi, or to a condition brought about by their growth or development.
  • the fatty acid or its salt oi. the above group acts with the moisture or fluids of the skin or wound to whichit is applied, forming a liquid medium of the proper acidity or pH value that either kills the fungus or arrests its further growth or development.
  • fatty acids are effective in slightly acid condition. namely a pH value of about 5 to 8, to prevent the development of those pathogenic fungi.
  • Certain of the fatty acids and their salts also have a germicidal action, at least against certain pathogenic organisms, and they may also have an additional value in this way in addition to, or associated with, their fungicidal or fungistatic properties.
  • any particular adhesive in such a way as to bring the fatt acid or its salt into contact with the moisture of the skin or portion of the body to be treated.
  • Any particular acid may be selected either because it is readily available or has properties desired for a particular use as, for example, its viscosity, freedom from irritating eilects on the skin, odor or lack of odor, whether solid or liquid, etc.
  • a surgical adhesive tape having an adhesive coating composition containing from 0.3 to of a member of the group consisting of the stralsht chain, branched, saturated, unsaturated and halogen substitution products of. fatty acids of from three to eleven carbon atoms inclusive and their salts.
  • a surgical tape having an adhesive coating composition containing from 0.3% to 10% by weight of a salt of propionic acid.
  • a surgical adhesive tape having an adhesive coating composition containing from 0.3% to 10% of its weight of a salt of undecylenic acid.
  • a surgical adhesive tape having an adhesive coating composition containing from 0.3% to 10% of its weight of a salt of capric acid.

Description

Patented Sept. 9, 1947 SURGICAL ADHESIVE TAPE Walter R. Russ, Little Falls, N. 1., and Charles Hoffman, Scarsdale, Thomas R. Schweitzer, Bellaire, and Gaston Dalby, New York, N. Y.,' assignors to Ward Baking Company, New York, N. Y., a corporation of New York No Drawing. Application November 7, 1942, Serial No. 464,894
Our present invention relates to improvements in adhesive plaster or tape. When adhesive plasters as heretofore made were applied to the skin of a patient they frequently gave rise to skin disturbances and irritations, such as itching or pruritis, or otherirritations, which in some cases necessitated leaving off the plaster. This tend- 4 Claims. (Cl. 16784) ency to irritation was, of course, more pronounced in cases in which the application of the plaster was continued over an extended period of time.
In our present invention there is provided an adsesive plaster or tape on which this tendency toward irritation or skin disturbances is substantially eliminated.
In our invention we incorporate in the adhesive plaster or tape one or more members of the mono carboxylic alkyl fatty acid series containing from 3 to 11 carbon atoms. These fatty acids may be either branch or straight chain, saturated or unsaturated, or may be halogen derivatives of such acids.
The saturated acids include propionic, butyric, valeric, caproic, heptylic, caprylic, nonylic or pelargonic, and capric.
The unsaturated acids include acrylic, crotonic, angelic, undecylenic, etc.
Any suitable salt of any of these acids may be used.
.Any member or members of the above group of acids and salts may be incorporated in the adhesive plaster or coating composition of an adhesive tape in such a manner that it will be present in sumcient amounts on the exposed surface of the coating.
The coating composition of the adhesive tape is composed basically of a gum, such as caoutchouc, and a suitable softener, such as an oil or fat, resins and a filler, such as zinc oxide, which may itself have some value as a medicament. Also a small amount of any suitable antiseptic may be incorporated.
In applying the invention, therefore, the .fatty acid or acids and its salt or salts may be incorporated in the coating composition either as a substitute in part for zinc oxide, or if the selected acid or its salt is of a sticky or viscous nature, it might be substituted in part for the softener or resin or gum. The amount of the fatty acid required at the surface need be very small because it acts in an aqueous solution in the moisture of the skin, which is necessarily very small in quantity.
Any excess over the amount required to form this very small amount of solution is of no disadvantage and the fatty acid or its salt may be the following composition:
incorporated up to any amount, therefore, which does not interfere with the adhesive qualities or strength or body of the coating material.
The concentration of the'fatty acid or its salt may range, therefore, from one just sufficient to provide suflicient surface concentration to the point where the adhesiveness or other properties of the coating may be affected.
An example of an adhesive tape coating to which the invention may be applied is one having Parts Caoutchouc 34 Dammar. '7 Colophony 3.5 Lanolin neutral 24.5 Zinc oxide 30 Examples of the application of the invention to an adhesive tape coating of the above composition are as follows:
Example I Example 11 a From 0.3% to 10% of sodium undecylenate, an unsaturatedfatty acid or its salt is admixed to the coating composition and applied to the backme in the usual manner.
Example III In this example from 0.3% to 10% sodium caprate is incorporated in the coating composition.
Example IV In this example from .01% to 5% beta iodopropionic acid is incorporated in the coating composition to be applied to the fabric coating. Or the corresponding bromin or chlorine substitution products of the series may be employed.
While the beneficial action of incorporating or associating a member or members of the above group of fatty acids or their salts may be complex, it is believed that they have the effect generally or acting as fungicides or fungistats to 3 pathogenic fungi that may be present 'on t l skin or wound being treated by the dressing or suture or tape.
The pus formation, irritation or disturbance of the skin or wound appears to be either caused directly or indirectl by certain pathogenic fungi, or to a condition brought about by their growth or development.
The fatty acid or its salt oi. the above group acts with the moisture or fluids of the skin or wound to whichit is applied, forming a liquid medium of the proper acidity or pH value that either kills the fungus or arrests its further growth or development.
These fatty acids are effective in slightly acid condition. namely a pH value of about 5 to 8, to prevent the development of those pathogenic fungi. Certain of the fatty acids and their salts also have a germicidal action, at least against certain pathogenic organisms, and they may also have an additional value in this way in addition to, or associated with, their fungicidal or fungistatic properties.
It will be apparent that the above examples are given merely by way of example and that 5 1,784,740
they may be used in connection with any particular adhesive in such a way as to bring the fatt acid or its salt into contact with the moisture of the skin or portion of the body to be treated.
Any particular acid may be selected either because it is readily available or has properties desired for a particular use as, for example, its viscosity, freedom from irritating eilects on the skin, odor or lack of odor, whether solid or liquid, etc.
What we claim is:
1. A surgical adhesive tape having an adhesive coating composition containing from 0.3 to of a member of the group consisting of the stralsht chain, branched, saturated, unsaturated and halogen substitution products of. fatty acids of from three to eleven carbon atoms inclusive and their salts.
2. A surgical tape having an adhesive coating composition containing from 0.3% to 10% by weight of a salt of propionic acid.
3. A surgical adhesive tape having an adhesive coating composition containing from 0.3% to 10% of its weight of a salt of undecylenic acid.
4. A surgical adhesive tape having an adhesive coating composition containing from 0.3% to 10% of its weight of a salt of capric acid.
WALTER R. RUSS. CHARLES HOFFMAN. THOMAS R. SCHWEITZER. GASTON DALBY.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date Mathey Dec. 9, 1930 1,814,221 Metcali'e July 14, 1931 1,955,052 Burnell Apr. 17, 1934 1,981,561 Lloyd .a. Nov. 20, 1934 2,063,218 Zisserman Dec. 8, 1936 2,217,905 Hoffman Oct. 15, 1940 2,272,397 Becher Feb. 10, 1942 OTHER REFERENCES "Role of Sweat as a Fungicide, by Peck et al., American Medical Assoc, Jan. 1939, pages 12 to 21.
Manufacturing Chemist, Oct. 1939, page 324. (Copies of the above in 167-58R in Division 43.)
US464894A 1942-11-07 1942-11-07 Surgical adhesive tape Expired - Lifetime US2427022A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2511032A (en) * 1949-07-07 1950-06-13 Wallace & Tiernan Inc Zinc salts of mono-olefinic acids as antimycotics
US2689809A (en) * 1951-10-08 1954-09-21 Permachem Corp Self-sterilizing article and its preparation
US2791518A (en) * 1955-03-21 1957-05-07 Permachem Corp Process for making a microbicidal article
US2835628A (en) * 1957-04-01 1958-05-20 Jacob A Saffir Means for treating teeth
EP0011471A1 (en) * 1978-11-17 1980-05-28 SMITH & NEPHEW RESEARCH LIMITED Adhesive-coated sheet material incorporating anti-bacterial substances
EP0023395A1 (en) * 1979-07-31 1981-02-04 Minnesota Mining And Manufacturing Company Pressure-sensitive adhesive having a broad spectrum anti-microbial therein
EP0024107A1 (en) * 1979-07-31 1981-02-25 Minnesota Mining And Manufacturing Company A pressure-sensitive adhesive containing iodine

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1784740A (en) * 1927-06-03 1930-12-09 Johnson & Johnson Adhesive
US1814221A (en) * 1928-05-31 1931-07-14 Roy M Metcalfe Hosiery protecting compound
US1955052A (en) * 1933-05-08 1934-04-17 Alox Chemical Corp Insecticidal, fungicidal and bactericidal compositions
US1981561A (en) * 1933-01-14 1934-11-20 Nat Super Products Corp Bandage
US2063218A (en) * 1932-07-26 1936-12-08 Zisserman Leon Antiseptic or medicated dressing or material and the manufacture thereof
US2217905A (en) * 1937-01-13 1940-10-15 Ward Baking Co Therapeutic agent
US2272397A (en) * 1935-12-21 1942-02-10 Antiseptics Inc Method of making rubber compounds or products

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1784740A (en) * 1927-06-03 1930-12-09 Johnson & Johnson Adhesive
US1814221A (en) * 1928-05-31 1931-07-14 Roy M Metcalfe Hosiery protecting compound
US2063218A (en) * 1932-07-26 1936-12-08 Zisserman Leon Antiseptic or medicated dressing or material and the manufacture thereof
US1981561A (en) * 1933-01-14 1934-11-20 Nat Super Products Corp Bandage
US1955052A (en) * 1933-05-08 1934-04-17 Alox Chemical Corp Insecticidal, fungicidal and bactericidal compositions
US2272397A (en) * 1935-12-21 1942-02-10 Antiseptics Inc Method of making rubber compounds or products
US2217905A (en) * 1937-01-13 1940-10-15 Ward Baking Co Therapeutic agent

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2511032A (en) * 1949-07-07 1950-06-13 Wallace & Tiernan Inc Zinc salts of mono-olefinic acids as antimycotics
US2689809A (en) * 1951-10-08 1954-09-21 Permachem Corp Self-sterilizing article and its preparation
US2791518A (en) * 1955-03-21 1957-05-07 Permachem Corp Process for making a microbicidal article
US2835628A (en) * 1957-04-01 1958-05-20 Jacob A Saffir Means for treating teeth
EP0011471A1 (en) * 1978-11-17 1980-05-28 SMITH & NEPHEW RESEARCH LIMITED Adhesive-coated sheet material incorporating anti-bacterial substances
WO1980001041A1 (en) * 1978-11-17 1980-05-29 Smith & Nephew Res Adhesive-coated sheet material incorporating anti-bacterial substances
US4340043A (en) * 1978-11-17 1982-07-20 Smith & Nephew Research Ltd. Adhesive-coated sheet material incorporating anti-bacterial substances
US4460369A (en) * 1978-11-17 1984-07-17 Smith & Nephew Research Ltd. Adhesive-coated sheet material incorporating anti-bacterial substances
EP0023395A1 (en) * 1979-07-31 1981-02-04 Minnesota Mining And Manufacturing Company Pressure-sensitive adhesive having a broad spectrum anti-microbial therein
EP0024107A1 (en) * 1979-07-31 1981-02-25 Minnesota Mining And Manufacturing Company A pressure-sensitive adhesive containing iodine
US4310509A (en) * 1979-07-31 1982-01-12 Minnesota Mining And Manufacturing Company Pressure-sensitive adhesive having a broad spectrum antimicrobial therein
US4323557A (en) * 1979-07-31 1982-04-06 Minnesota Mining & Manufacturing Company Pressure-sensitive adhesive containing iodine

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