US2419902A - Fluorescent electric discharge lamp - Google Patents

Fluorescent electric discharge lamp Download PDF

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Publication number
US2419902A
US2419902A US525865A US52586544A US2419902A US 2419902 A US2419902 A US 2419902A US 525865 A US525865 A US 525865A US 52586544 A US52586544 A US 52586544A US 2419902 A US2419902 A US 2419902A
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United States
Prior art keywords
lamp
electric discharge
discharge lamp
fluorescent
nitrogen
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Expired - Lifetime
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US525865A
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Eric L Mager
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GTE Sylvania Inc
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Sylvania Electric Products Inc
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Publication date
Application filed by Sylvania Electric Products Inc filed Critical Sylvania Electric Products Inc
Priority to US525865A priority Critical patent/US2419902A/en
Application granted granted Critical
Publication of US2419902A publication Critical patent/US2419902A/en
Priority to GB21083/47A priority patent/GB639013A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/38Devices for influencing the colour or wavelength of the light
    • H01J61/42Devices for influencing the colour or wavelength of the light by transforming the wavelength of the light by luminescence
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/12Selection of substances for gas fillings; Specified operating pressure or temperature
    • H01J61/18Selection of substances for gas fillings; Specified operating pressure or temperature having a metallic vapour as the principal constituent
    • H01J61/20Selection of substances for gas fillings; Specified operating pressure or temperature having a metallic vapour as the principal constituent mercury vapour

Definitions

  • This invention relates to electric gaseous discharge lamps, particularly of the type utilizing a fluorescent material, and to the gas filling utilized in such lamps.
  • An object of the invention is to increase the efliciency of such lamps, and to cause their efficiency to be maintained high during the life of the lamp.
  • a feature of the invention is the introduction into the lamp of a gas filling containing small percentages of oxygen or nitrogen.
  • the light-transmitting tubular envelope I of glass or the like coated on its interior urface with the fluorescent material 2 is sealed at each end by a steam 3, through which lead in wires 4 and 5 project into the interior of the bulb where they are connected to each filamentary cathode 6, which may be a coiled-coil tungsten wire coated with one or more of the alkaline earth oxides.
  • the ends of the lead-in wires external to the glass envelope may be attached to prongs l and 8 of base 9, aflixed to the envelope I by a cement Ill,
  • the interior of the bulb may contain a filling of inert gas such as one of the rare gases, at low pressure, for example, argon at 3 mm., and a drop of mercury II to provide mercury vapor.
  • the lamp will ordinarily be operated at a mercury vapor pressure between 1 and 20 microns.
  • the gas filling also contains a small amount of nitrogen, or oxygen, and preferably both, in addition to the argon.
  • the amount of oxygen is preferably about 0.1% by volume of the argon, while the nitrogen is preferably much greater, say 0.7%, but at least 0.3%.
  • the ogygen and nitrogen are preferably mixed into the argon in proper quantities land the 2 mixture then introduced into the lamp, so that all three are introduced together as the flnal lamp filling, but the gases may be introduced separately if desired.
  • the lamp Prior to the introduction of the gases, the lamp may be evacuated and the cathodes activated in the usual manner.
  • One method for example, is to evacuate the lamp while it is being kept at a high temperature, say 500 C., in an oven, flushing several times with argon or other inert gas at say 3 mm. pressure, and re-evacuating after each flush to as low a pressure as 30 microns, and preferably to 8 microns prior to the admis: sion of the final gas filling, which may be argon at a few millimeters pressure with small percentages of oxygen or nitrogen, or both.
  • the cathodes Prior to the admission of this filling the cathodes are activated by being heated in steps, with an evacuation and flushing after each step. The filament current is raised somewhat at each step, until a value about double normal is reached. The steps themselves may be about 8 seconds long.
  • the percentage of oxygen in the gasfilling is about 0.1% for optimum results, but a range from about 0.05% to 0.6% will give good results insofar as lamp efliciency is concerned. However, amounts larger than 0.1% increase the tendency of the lamp to form dark bands at its ends.
  • Nitrogen does not seem to increase the latter tendency and much larger quantities can be used. However, quantities larger than 1% do not increase the emciency greatly and do make the lamps much harder to start initially. About 0.7% has worked very well and as much as 1.5% may be used to advantage.
  • the oxygen improves the lumen maintenance of the lamp about 3% at 500 hours life; nitrogen has an efiect as great as 10% at this period.
  • fluorescent material such as magnesium tungstate and zinc silicate, the latter activated by manganese or beryllium, or both.
  • a fluorescent electric discharge lamp comprising a sealed light-transmitting envelope, oxidecoated electrodes therein, a small quantity of mer- 'curythereimamflllingthereineonslstinz of argon and 03% to 1.5% nitrogen, and a flucrescent ooetin on the interior surface of said envelope 2nd comprising at least one material of the group oi the fluorescent tung- 5 states and silicetes.

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  • Vessels And Coating Films For Discharge Lamps (AREA)
  • Manufacture Of Electron Tubes, Discharge Lamp Vessels, Lead-In Wires, And The Like (AREA)
  • Luminescent Compositions (AREA)

Description

April 29, 1947. E. L. MAGER 2,419,902
FLUORESCENT ELECTRIC DISCHARGE LAMP Filed March 10, 1944 INVENTOR. E210 L meme Trrokuzr Patented Apr. 29, 1947 FLUORESCENT ELECTRIC DISCHARGE LAMP Eric L. Mager, Lcominster, Mass., asslgnor to Sylvania Electric Products Inc., Salem, Masa, a corporation of Massachusetts Application March 10, 1944, Serial No. 525,865
1 Claim. (Cl. 176-122) This invention relates to electric gaseous discharge lamps, particularly of the type utilizing a fluorescent material, and to the gas filling utilized in such lamps.
An object of the invention is to increase the efliciency of such lamps, and to cause their efficiency to be maintained high during the life of the lamp.
A feature of the invention is the introduction into the lamp of a gas filling containing small percentages of oxygen or nitrogen. Other features, advantages and objects of the invention will be apparent from the following specification, taken in conjunction with the accompanying drawing, in which the figure represents a lamp according to my invention.
In the drawing, the light-transmitting tubular envelope I of glass or the like coated on its interior urface with the fluorescent material 2, is sealed at each end by a steam 3, through which lead in wires 4 and 5 project into the interior of the bulb where they are connected to each filamentary cathode 6, which may be a coiled-coil tungsten wire coated with one or more of the alkaline earth oxides. The ends of the lead-in wires external to the glass envelope may be attached to prongs l and 8 of base 9, aflixed to the envelope I by a cement Ill, The interior of the bulb may contain a filling of inert gas such as one of the rare gases, at low pressure, for example, argon at 3 mm., and a drop of mercury II to provide mercury vapor. The lamp will ordinarily be operated at a mercury vapor pressure between 1 and 20 microns.
According to my invention, the gas filling also contains a small amount of nitrogen, or oxygen, and preferably both, in addition to the argon. The amount of oxygen is preferably about 0.1% by volume of the argon, while the nitrogen is preferably much greater, say 0.7%, but at least 0.3%.
I have found that the addition of these active gases to the inert gas may produce a lamp having, after 500 hours of life, an efflciency more than 10% greater than that of similar lamps at similar life without the active gases. The percentage gain in efliciency becomes still greater at longer life, because the active gases have the efiect of reducing the drop in efiiciency which normally occurs during the life of the lamp. The lamp life itself does not appear to be deleteriously affected, because lamps according to my invention have given lives well over 3500 hours.
The ogygen and nitrogen are preferably mixed into the argon in proper quantities land the 2 mixture then introduced into the lamp, so that all three are introduced together as the flnal lamp filling, but the gases may be introduced separately if desired.
Prior to the introduction of the gases, the lamp may be evacuated and the cathodes activated in the usual manner. One method, for example, is to evacuate the lamp while it is being kept at a high temperature, say 500 C., in an oven, flushing several times with argon or other inert gas at say 3 mm. pressure, and re-evacuating after each flush to as low a pressure as 30 microns, and preferably to 8 microns prior to the admis: sion of the final gas filling, which may be argon at a few millimeters pressure with small percentages of oxygen or nitrogen, or both. Prior to the admission of this filling the cathodes are activated by being heated in steps, with an evacuation and flushing after each step. The filament current is raised somewhat at each step, until a value about double normal is reached. The steps themselves may be about 8 seconds long.
After introduction of the active gases, the voltage necessary to start the lamp will be higher than normal. Application of sufficient starting voltage and the operation of the lamp for a few minutes will return it to its normal starting conditions.
In my tests with various quantities of oxygen and nitrogen I used spectroscopically pure argon to insure the correctness of my results.
The percentage of oxygen in the gasfilling is about 0.1% for optimum results, but a range from about 0.05% to 0.6% will give good results insofar as lamp efliciency is concerned. However, amounts larger than 0.1% increase the tendency of the lamp to form dark bands at its ends.
Nitrogen does not seem to increase the latter tendency and much larger quantities can be used. However, quantities larger than 1% do not increase the emciency greatly and do make the lamps much harder to start initially. About 0.7% has worked very well and as much as 1.5% may be used to advantage. The oxygen improves the lumen maintenance of the lamp about 3% at 500 hours life; nitrogen has an efiect as great as 10% at this period.
In my invention, I have used fluorescent material such as magnesium tungstate and zinc silicate, the latter activated by manganese or beryllium, or both.
What I claim is:
A fluorescent electric discharge lamp compris ing a sealed light-transmitting envelope, oxidecoated electrodes therein, a small quantity of mer- 'curythereimamflllingthereineonslstinz of argon and 03% to 1.5% nitrogen, and a flucrescent ooetin on the interior surface of said envelope 2nd comprising at least one material of the group oi the fluorescent tung- 5 states and silicetes.
ERIC L. MAGER;
WCESCITED The following reierehees are of record in the ille of this potent:
4 7 tmrrm sum m'rni'm Number v Name Date Gaidies Dec. 21, 1937 Blackburn Feb. 13, 1940 Fouike July 10, 1934 Case Aug. 14, 1934 Foerste Apr. 20. 1943 Smith Oct. 9, 1945 Gordon Oct. 31, 1939 Frech July 18, 1944 Myers Nov. 28, 1939 Holman 008 20, 1940 Hitchcock Mar. 13. 1934
US525865A 1944-03-10 1944-03-10 Fluorescent electric discharge lamp Expired - Lifetime US2419902A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US525865A US2419902A (en) 1944-03-10 1944-03-10 Fluorescent electric discharge lamp
GB21083/47A GB639013A (en) 1944-03-10 1947-08-01 Fluorescent electric discharge lamp

Applications Claiming Priority (1)

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US525865A US2419902A (en) 1944-03-10 1944-03-10 Fluorescent electric discharge lamp

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GB (1) GB639013A (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2671184A (en) * 1949-12-01 1954-03-02 Gen Electric Flashing discharge device
US2732513A (en) * 1952-01-31 1956-01-24 anderson
US2736711A (en) * 1951-07-31 1956-02-28 Gooding Pamela Elfrida Luminescent silicates
DE1184009B (en) * 1963-03-15 1964-12-23 Pintsch Licht G M B H Fluorescent lamp with argon as filling gas
US3728004A (en) * 1971-06-25 1973-04-17 Gte Sylvania Inc Method of employing mercury-dispensing getters in fluorescent lamps
US4341977A (en) * 1980-02-04 1982-07-27 Leo Gross Arc spreading with initiators
US4929868A (en) * 1989-01-05 1990-05-29 Gte Products Corporation Glow discharge lamp containing nitrogen
US5132590A (en) * 1985-04-24 1992-07-21 Masaaki Kimoto Gas discharge tube capable of lighting in different colors
US5410216A (en) * 1986-04-23 1995-04-25 Kimoto; Masaaki Gas discharge tube capable of lighting in different colors
WO2004032180A2 (en) * 2002-10-04 2004-04-15 Koninklijke Philips Electronics N.V. Low-pressure mercury vapour discharge lamp
WO2003085695A3 (en) * 2002-04-11 2005-05-06 Koninkl Philips Electronics Nv Low-pressure mercury vapor discharge lamp
US20050126274A1 (en) * 2002-04-17 2005-06-16 Martin Griesser Method for identifying tire characteristics
US7276853B2 (en) 2002-04-11 2007-10-02 Koninklijke Philips Electronics, N.V. Low-pressure mercury vapor discharge lamp

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1951150A (en) * 1929-06-25 1934-03-13 Gen Electric Gas conduction device
US1965585A (en) * 1929-10-07 1934-07-10 Gen Electric Vapor Lamp Co Electric gaseous discharge device
US1970223A (en) * 1929-06-28 1934-08-14 Case Res Lab Inc Sound recording glow lamp
US2103073A (en) * 1936-06-24 1937-12-21 Gen Electric Gaseous electric discharge lamp device
US2177710A (en) * 1938-04-22 1939-10-31 Gen Electric Fluorescent sign lamp
US2181305A (en) * 1938-12-22 1939-11-28 Hygrade Sylvania Corp Fluorescent lamp
US2190308A (en) * 1937-10-27 1940-02-13 Westinghouse Electric & Mfg Co Crater lamp as a spotlight
US2299720A (en) * 1940-10-26 1942-10-20 Sylvania Electric Prod Luminescent coating for electric lamps
US2317265A (en) * 1940-07-26 1943-04-20 Foerste William Fluorescent lamp
US2353660A (en) * 1942-12-17 1944-07-18 Gen Electric Starting control for electric discharge devices
US2386277A (en) * 1942-02-24 1945-10-09 Raytheon Mfg Co Fluorescent lamp

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1951150A (en) * 1929-06-25 1934-03-13 Gen Electric Gas conduction device
US1970223A (en) * 1929-06-28 1934-08-14 Case Res Lab Inc Sound recording glow lamp
US1965585A (en) * 1929-10-07 1934-07-10 Gen Electric Vapor Lamp Co Electric gaseous discharge device
US2103073A (en) * 1936-06-24 1937-12-21 Gen Electric Gaseous electric discharge lamp device
US2190308A (en) * 1937-10-27 1940-02-13 Westinghouse Electric & Mfg Co Crater lamp as a spotlight
US2177710A (en) * 1938-04-22 1939-10-31 Gen Electric Fluorescent sign lamp
US2181305A (en) * 1938-12-22 1939-11-28 Hygrade Sylvania Corp Fluorescent lamp
US2317265A (en) * 1940-07-26 1943-04-20 Foerste William Fluorescent lamp
US2299720A (en) * 1940-10-26 1942-10-20 Sylvania Electric Prod Luminescent coating for electric lamps
US2386277A (en) * 1942-02-24 1945-10-09 Raytheon Mfg Co Fluorescent lamp
US2353660A (en) * 1942-12-17 1944-07-18 Gen Electric Starting control for electric discharge devices

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2671184A (en) * 1949-12-01 1954-03-02 Gen Electric Flashing discharge device
US2736711A (en) * 1951-07-31 1956-02-28 Gooding Pamela Elfrida Luminescent silicates
US2732513A (en) * 1952-01-31 1956-01-24 anderson
DE1184009B (en) * 1963-03-15 1964-12-23 Pintsch Licht G M B H Fluorescent lamp with argon as filling gas
US3728004A (en) * 1971-06-25 1973-04-17 Gte Sylvania Inc Method of employing mercury-dispensing getters in fluorescent lamps
US4341977A (en) * 1980-02-04 1982-07-27 Leo Gross Arc spreading with initiators
US5132590A (en) * 1985-04-24 1992-07-21 Masaaki Kimoto Gas discharge tube capable of lighting in different colors
US5410216A (en) * 1986-04-23 1995-04-25 Kimoto; Masaaki Gas discharge tube capable of lighting in different colors
US4929868A (en) * 1989-01-05 1990-05-29 Gte Products Corporation Glow discharge lamp containing nitrogen
WO2003085695A3 (en) * 2002-04-11 2005-05-06 Koninkl Philips Electronics Nv Low-pressure mercury vapor discharge lamp
US7276853B2 (en) 2002-04-11 2007-10-02 Koninklijke Philips Electronics, N.V. Low-pressure mercury vapor discharge lamp
US20050126274A1 (en) * 2002-04-17 2005-06-16 Martin Griesser Method for identifying tire characteristics
US7263878B2 (en) 2002-04-17 2007-09-04 Continental Teves Ag & Co. Ohg Method for identifying tire characteristics
WO2004032180A2 (en) * 2002-10-04 2004-04-15 Koninklijke Philips Electronics N.V. Low-pressure mercury vapour discharge lamp
WO2004032180A3 (en) * 2002-10-04 2005-08-25 Koninkl Philips Electronics Nv Low-pressure mercury vapour discharge lamp

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Publication number Publication date
GB639013A (en) 1950-06-21

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