US2411767A - Infrared treatment of oils - Google Patents

Infrared treatment of oils Download PDF

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US2411767A
US2411767A US2411767DA US2411767A US 2411767 A US2411767 A US 2411767A US 2411767D A US2411767D A US 2411767DA US 2411767 A US2411767 A US 2411767A
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oil
oils
viscosity
agitation
wrinkling
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09FNATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
    • C09F7/00Chemical modification of drying oils
    • C09F7/06Chemical modification of drying oils by polymerisation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/47Preparation of carboxylic acid esters by telomerisation

Definitions

  • This invention relates to treatment of oils, more particularly wrinkling oils, by infrared radiation, whereby the viscosity of the oil is materially increased over a shorter period of time as compared with hitherto known methods for bodying oils.
  • Tung oil and oiticica oil are natural wrinkling oils; that is to say, they possess the characteristic of yielding a wrinkled or uneven surface when they are incorporated in coating compositions and the latter are applied on a surface and baked.
  • oils while usable in their natural state, are generally subjected to processing prior to being incorporated in a coating composition.
  • the purpose of this processing or pretreatment is to enhance or bring out their desirable wrinkling tendency for the purpose of obtaining a more uniform and better defined textural pattern, or in order to reduce the time required for cooking the varnish of which they form a part and thus increasing the output of the varnish kettles.
  • This pretreatment leads to a marked increase in viscosity of the oil, and may be accomplished either by heating alone or by heating and simultaneously blowing with air.
  • the former method is called kettling or "heat bodying and the latter is generally known as blowing.
  • Blown tung oil for example, possesses an enhanced wrinkling effect as compared with unblown or raw tung oil. Blowing, however, produces certain undesirable efiects. Blown oils exhibit a tendency to gel, and coating compositions prepared with them frequently precipitate out of solution. This appears to be due to the fact that a portion of the air bubbled through the oil body remains chemically uncombined and intermolecularly dispersed, leading to auto-oxidation of the oil in storage and ultimately to precipitation of a portion thereof.
  • Heat bodied oils do not possess the increased wrinkling tendency which is evident in the case of blown oils; however, their use proves advantageous to the varnish maker since they make possible a marked reduction in cooking time and thereby permit increasing the output of the varnish kettles.
  • our invention we are able to increase the viscosity or body of wrinkling oils by treatment with infrared radiation, and the time required to produce an oil having any predetermined desirable viscosity or body, according to our process, is reduced as compared with hitherto known-methods. At the same time, our invention makes it possible to produce wrinkling 2 oils having all the desirable characteristics of heat bodied oils without the undesirable characteristics of blown oils.
  • Tung oil was submitted to infrared radiation with agitation for a period of time totaling nine hours. Another sample of the same oil was submitted to heat bodying and agitation for a period of nine hours. In each case samples were withdrawn at intervals of time and viscosity determinations made thereon. At the same time samples were withdrawn for viscosity determinations the temperature of the oil under treatment was determined. The results are tabulated in Table I.
  • the temperature of treatment was substantially the-same in both tests and that the sample treated with infrared and agitation'had a viscosity of 41.4 seconds at the end of five and one-half hours, as compared with a viscosity of 24.0 seconds at the end of eight hours and 56.0 seconds at the end of nine hours for the sample treated with heat and agitation. It will be further noted that the sample treated with infrared and agitation had a viscosity of 17.8 seconds at the end of four and one-half EXAMPLE II A sample of crude oiticica oil was treated with infrared and agitation for a period of nine hours. A second sample of the same oil was treated with heat and agitation for the same length of time. The results obtained are tabulated in Table II.
  • sample treated with infrared and agitation had a viscosity of 24.6 seconds at the end of four hours, while the sample treated with heat and agitation had a viscosity of 26.0 seconds at the'end of nine hours. Furthermore, it will be noted that the sample treated with infrared and agitation had a viscosity of 18.2 seconds at the end of three hours, while the sample treated with heat and agitation had a viscosity of 18.0 seconds at the end of seven hours. In other words, here, again, the time required to obtain a given viscosity was reduced approximately one-half by using the method of our invention.
  • the viscosity was measured by filling a Gardner-Holdt tube 10.60 mm. inside. diameter and approximately 110 mm. in length. The time in' seconds required for the bubble to travel the length of the tube was determined by stop Watch, and the reading in seconds is indicated as viscosity in Tables I and II.
  • Wrinkling oils treated according to our invention may be used in formulating wrinkling varnishes and other coating compositions adapted to yield uniform, well textured, wrinkled surfaces when sprayed or otherwise applied and baked; such coating compositions, including wrinkling oils treated according to the method of our invention, have a tendency to give a rapid initial set and yield a better defined and more uniform Wrinkle pattern than the same formulations when compounded with wrinklin oils bodied according to other methods.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Lubricants (AREA)
  • Fats And Perfumes (AREA)

Description

Patented Nov. 26, 1946 INFRARED TREATMENT OF OILS William A. Waldie and Harry A. Toulmin, Jr., Dayton, Ohio, assignors to New Wrinkle, Inc., Wilmington, Del., a corporation of Delaware No Drawing. Application January 15, 1942, Serial No. 426,898
2 Claims.
This invention relates to treatment of oils, more particularly wrinkling oils, by infrared radiation, whereby the viscosity of the oil is materially increased over a shorter period of time as compared with hitherto known methods for bodying oils.
Tung oil and oiticica oil are natural wrinkling oils; that is to say, they possess the characteristic of yielding a wrinkled or uneven surface when they are incorporated in coating compositions and the latter are applied on a surface and baked.
These oils, while usable in their natural state, are generally subjected to processing prior to being incorporated in a coating composition. The purpose of this processing or pretreatment is to enhance or bring out their desirable wrinkling tendency for the purpose of obtaining a more uniform and better defined textural pattern, or in order to reduce the time required for cooking the varnish of which they form a part and thus increasing the output of the varnish kettles.
This pretreatment leads to a marked increase in viscosity of the oil, and may be accomplished either by heating alone or by heating and simultaneously blowing with air. The former method is called kettling or "heat bodying and the latter is generally known as blowing.
Blown tung oil, for example, possesses an enhanced wrinkling effect as compared with unblown or raw tung oil. Blowing, however, produces certain undesirable efiects. Blown oils exhibit a tendency to gel, and coating compositions prepared with them frequently precipitate out of solution. This appears to be due to the fact that a portion of the air bubbled through the oil body remains chemically uncombined and intermolecularly dispersed, leading to auto-oxidation of the oil in storage and ultimately to precipitation of a portion thereof.
Heat bodied oils, on the other hand, do not possess the increased wrinkling tendency which is evident in the case of blown oils; however, their use proves advantageous to the varnish maker since they make possible a marked reduction in cooking time and thereby permit increasing the output of the varnish kettles.
According to our invention, we are able to increase the viscosity or body of wrinkling oils by treatment with infrared radiation, and the time required to produce an oil having any predetermined desirable viscosity or body, according to our process, is reduced as compared with hitherto known-methods. At the same time, our invention makes it possible to produce wrinkling 2 oils having all the desirable characteristics of heat bodied oils without the undesirable characteristics of blown oils.
Without thereby intending to limit our invention, the following are given as typical examples of the application of the method of our invention to the bodying of wrinkling oils:
EXAMPLE I Tung oil was submitted to infrared radiation with agitation for a period of time totaling nine hours. Another sample of the same oil was submitted to heat bodying and agitation for a period of nine hours. In each case samples were withdrawn at intervals of time and viscosity determinations made thereon. At the same time samples were withdrawn for viscosity determinations the temperature of the oil under treatment was determined. The results are tabulated in Table I.
1 At room temperature. I ould not flow after tube had been inverted 4 hours.
It will be noted that the temperature of treatment was substantially the-same in both tests and that the sample treated with infrared and agitation'had a viscosity of 41.4 seconds at the end of five and one-half hours, as compared with a viscosity of 24.0 seconds at the end of eight hours and 56.0 seconds at the end of nine hours for the sample treated with heat and agitation. It will be further noted that the sample treated with infrared and agitation had a viscosity of 17.8 seconds at the end of four and one-half EXAMPLE II A sample of crude oiticica oil was treated with infrared and agitation for a period of nine hours. A second sample of the same oil Was treated with heat and agitation for the same length of time. The results obtained are tabulated in Table II.
1 At room temperature.
It will be noted that the sample treated with infrared and agitation had a viscosity of 24.6 seconds at the end of four hours, while the sample treated with heat and agitation had a viscosity of 26.0 seconds at the'end of nine hours. Furthermore, it will be noted that the sample treated with infrared and agitation had a viscosity of 18.2 seconds at the end of three hours, while the sample treated with heat and agitation had a viscosity of 18.0 seconds at the end of seven hours. In other words, here, again, the time required to obtain a given viscosity was reduced approximately one-half by using the method of our invention.
In carrying out the tests tabulated in Tables I and II, a definite quantity of oil was placed in a metal container. In the case of the samples treated according to the method of our invention, a General Electric reflector type infrared R- l, 250 watt lamp was placed bearing vertical about six inches above the surface of the oil, and the sample was agitated at a uniform speed using an electrically driven stirring machine. In the case ofthe heat bodied samples, the same procedure was used except for the fact that the sample was heated on a hot plate instead of by the use of infrared radiation.
The viscosity was measured by filling a Gardner-Holdt tube 10.60 mm. inside. diameter and approximately 110 mm. in length. The time in' seconds required for the bubble to travel the length of the tube was determined by stop Watch, and the reading in seconds is indicated as viscosity in Tables I and II.
It will be noted from the foregoing that it is possible, according to the method of our invention, to make a substantial reduction in the time required to give an oil a predetermined increase in viscosity and that it is, therefore, possible by oil selected from the group consisting of tung oil and crude oiticica oil which consists in exposing said oil to light consisting essentially of infra red radiations of such intensity whereby the time:
the practice of the method of our invention substantially to increase the output of bodied oil from any given installation.
Wrinkling oils treated according to our invention may be used in formulating wrinkling varnishes and other coating compositions adapted to yield uniform, well textured, wrinkled surfaces when sprayed or otherwise applied and baked; such coating compositions, including wrinkling oils treated according to the method of our invention, have a tendency to give a rapid initial set and yield a better defined and more uniform Wrinkle pattern than the same formulations when compounded with wrinklin oils bodied according to other methods.
In other words, while We have no proof to ofier, it is believed that the method of our invention brings about or induces changes in the molecular structure of the oil under treatment, and that these changes lead to superior ultimate results when such oils are used in wrinkling coating compositions of various sorts. I
While we have set forth above results obtained by subjecting tung oil and oiticica oil to infrared radiation with agitation, it is to be understood that similar results may be obtained by subjecting these oils to infrared radiation without agitation, so long as means are provided whereby the oil is exposed to the infrared radiation. This may be accomplished, for example, by cascading the oil tobe treated through a suitable irradiating apparatus. This application, however, is not concerned with apparatus wherein the method of our invention may be carried out and is limited solely to the process and the product resulting from the practice thereof.
It will be understood that while we have de-:
conditions without departing from the spirit of 3 this description and the scope of our invention as defined in the appended claims. v
' We claim:
1. The method of bodying a vegetable drying required to obtain a givendeg'ree of body is sub} stantially reduced. 7
2. The method of increasing the bodying rate of a vegetable drying oil selected from the group consisting of tung oil and crude oiticica oil which consists in exposing said oil to infrared radiation, whereby said oil is bodied substantially twice more rapidly than by heat-bodying at substantially the same temperature.
WILLIAM A. WALDIE. HARRY A. TOULMIN, JR.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2567106A (en) * 1951-09-04 Method of treating oils
US3314813A (en) * 1963-02-05 1967-04-18 Continental Can Co Printable polyolefin compositions and products

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2567106A (en) * 1951-09-04 Method of treating oils
US3314813A (en) * 1963-02-05 1967-04-18 Continental Can Co Printable polyolefin compositions and products

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