US2403437A - Process for making artificial wool imitation filaments and artificial wool filaments - Google Patents
Process for making artificial wool imitation filaments and artificial wool filaments Download PDFInfo
- Publication number
- US2403437A US2403437A US258498A US25849839A US2403437A US 2403437 A US2403437 A US 2403437A US 258498 A US258498 A US 258498A US 25849839 A US25849839 A US 25849839A US 2403437 A US2403437 A US 2403437A
- Authority
- US
- United States
- Prior art keywords
- filaments
- viscose
- wool
- spinning
- cellulose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 210000002268 wool Anatomy 0.000 title description 53
- 238000000034 method Methods 0.000 title description 37
- 229920000297 Rayon Polymers 0.000 description 84
- 238000009987 spinning Methods 0.000 description 57
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 32
- 229920002678 cellulose Polymers 0.000 description 32
- 239000001913 cellulose Substances 0.000 description 32
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 27
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 21
- 239000011686 zinc sulphate Substances 0.000 description 21
- 235000009529 zinc sulphate Nutrition 0.000 description 20
- 239000000835 fiber Substances 0.000 description 17
- 229910052938 sodium sulfate Inorganic materials 0.000 description 16
- 235000011152 sodium sulphate Nutrition 0.000 description 16
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 12
- 239000012991 xanthate Substances 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 11
- 239000002253 acid Substances 0.000 description 9
- 230000032683 aging Effects 0.000 description 9
- 235000011121 sodium hydroxide Nutrition 0.000 description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 239000011521 glass Substances 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 239000001117 sulphuric acid Substances 0.000 description 7
- 235000011149 sulphuric acid Nutrition 0.000 description 7
- 239000003513 alkali Substances 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 230000015271 coagulation Effects 0.000 description 3
- 238000005345 coagulation Methods 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010981 drying operation Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000009960 carding Methods 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000009992 mercerising Methods 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- XPQXBTYQDZUYSF-UHFFFAOYSA-L sodium zinc sulfate Chemical compound S(=O)(=O)([O-])[O-].[Zn+2].[Na+] XPQXBTYQDZUYSF-UHFFFAOYSA-L 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- -1 sulphate sulphate Aluminum Nickel sulphate Cobalt Magnesium Ammonium sulphate sulphate sulphate Chemical compound 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S57/00—Textiles: spinning, twisting, and twining
- Y10S57/905—Bicomponent material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2922—Nonlinear [e.g., crimped, coiled, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2922—Nonlinear [e.g., crimped, coiled, etc.]
- Y10T428/2924—Composite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2965—Cellulosic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2973—Particular cross section
- Y10T428/2978—Surface characteristic
Definitions
- This invention relate to the manufacture of filaments, threads, yarns, ribbons, staple, or similar fibres and the products made therefrom, having the characteristics of natural wool in respect to appearance, feel, serimetric and physical properties.
- I produce such wool imitation filaments, etc., from cellulose containing vegetable sources according to the viscose method.
- Fig. 2 is a cross-sectional view of the improved filaments produced by the invention.
- the viscosity referred to hereinafter is determined according to the ball-fall method, carried out-gin the following manner: The viscose under examination is poured into a vertical glass tube of 300 mm. length and 25 mm. diameter.
- the composition of the viscose and of the spinning bath cause the filaments produced to have a rough or cracked surface, similar to the scales of natural wool. Furthermore, the filaments twist in such a manner as to have a cross sectionsimilar to a horse shoe, the ends of which touch or overlap, as illustrated in Fig. 2 and Fig. i.
- Zinc sulphate retards the complete regeneration of the cellulose by quickly forming be able to treat the filaments in the surface, and a hollow, air-enclosing space or canal in the center, as shown in Figs. 2, 3, and 4.
- a method for the production of artificial wool imitation filaments and the like comprise ing projecting viscose with undcosity of at least 500 into an acid spinning bath containing at least 4% zinc sulphate and approximately 28% sodium-sulphate, withdrawing the filaments under as little tension as possibie by means 0! a first godet wheel and then applying stretch to through a spinneret by'precipitating said viscose into an acid spinning bath containing more than 4%- zinc sulphate and approximately 23% so* chum-sulphate to form filaments, and stretching said filaments to cause said membranes to burst in circumferential .direction of the filaments to impart to the filaments a rough surface.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Artificial Filaments (AREA)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL62057D NL62057C (enrdf_load_stackoverflow) | 1939-02-25 | ||
US258498A US2403437A (en) | 1939-02-25 | 1939-02-25 | Process for making artificial wool imitation filaments and artificial wool filaments |
US339117A US2302077A (en) | 1939-02-25 | 1940-06-06 | Artificial wool filament and yarn |
FR930155D FR930155A (fr) | 1939-02-25 | 1946-07-02 | Perfectionnements apportés aux procédés et dispositifs pour fabriquer des filaments en une matière artificielle et qui imitent la laine naturelle |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US258498A US2403437A (en) | 1939-02-25 | 1939-02-25 | Process for making artificial wool imitation filaments and artificial wool filaments |
US339117A US2302077A (en) | 1939-02-25 | 1940-06-06 | Artificial wool filament and yarn |
Publications (1)
Publication Number | Publication Date |
---|---|
US2403437A true US2403437A (en) | 1946-07-09 |
Family
ID=26946675
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US258498A Expired - Lifetime US2403437A (en) | 1939-02-25 | 1939-02-25 | Process for making artificial wool imitation filaments and artificial wool filaments |
US339117A Expired - Lifetime US2302077A (en) | 1939-02-25 | 1940-06-06 | Artificial wool filament and yarn |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US339117A Expired - Lifetime US2302077A (en) | 1939-02-25 | 1940-06-06 | Artificial wool filament and yarn |
Country Status (3)
Country | Link |
---|---|
US (2) | US2403437A (enrdf_load_stackoverflow) |
FR (1) | FR930155A (enrdf_load_stackoverflow) |
NL (1) | NL62057C (enrdf_load_stackoverflow) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2736946A (en) * | 1952-07-03 | 1956-03-06 | Dow Chemical Co | Polyacrylonitrile fibers having a scaly integument |
US2799895A (en) * | 1951-11-17 | 1957-07-23 | American Enka Corp | Spinning apparatus |
US2834093A (en) * | 1954-05-21 | 1958-05-13 | Du Pont | Regenerated cellulose filaments and products therefrom |
US2838364A (en) * | 1955-01-07 | 1958-06-10 | Eastman Kodak Co | Dry spinning process |
US3194861A (en) * | 1957-03-25 | 1965-07-13 | Beaunit Corp | Viscose spinning process and bath |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2433325A (en) * | 1942-08-19 | 1947-12-23 | Extruded Plastics Inc | Extruded resinous bristles |
US2517694A (en) * | 1943-09-14 | 1950-08-08 | American Viscose Corp | Crimped artificial filament |
US2439039A (en) * | 1944-09-26 | 1948-04-06 | American Viscose Corp | Process of producing medullated artificial filaments |
US2511060A (en) * | 1945-10-05 | 1950-06-13 | American Viscose Corp | Water-sensitive cellulose derivatives |
US2499501A (en) * | 1945-10-05 | 1950-03-07 | American Viscose Corp | Cellulose derivatives |
NL242714A (enrdf_load_stackoverflow) * | 1958-08-26 | |||
US3233019A (en) * | 1962-08-07 | 1966-02-01 | Du Pont | Process of multiple neck drawing while simultaneously infusing modifying agent |
US3957936A (en) * | 1971-07-22 | 1976-05-18 | Raduner & Co., Ag | High temperature process for modifying thermoplastic filamentous material |
US4937141A (en) * | 1987-08-03 | 1990-06-26 | Newell Operating Company | Microcellular synthetic paintbrush bristles |
DE68925259T2 (de) * | 1988-10-05 | 1996-09-19 | Asahi Chemical Ind | Viskosefaser mit vorzüglichem Aussehen |
-
0
- NL NL62057D patent/NL62057C/xx active
-
1939
- 1939-02-25 US US258498A patent/US2403437A/en not_active Expired - Lifetime
-
1940
- 1940-06-06 US US339117A patent/US2302077A/en not_active Expired - Lifetime
-
1946
- 1946-07-02 FR FR930155D patent/FR930155A/fr not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2799895A (en) * | 1951-11-17 | 1957-07-23 | American Enka Corp | Spinning apparatus |
US2736946A (en) * | 1952-07-03 | 1956-03-06 | Dow Chemical Co | Polyacrylonitrile fibers having a scaly integument |
US2834093A (en) * | 1954-05-21 | 1958-05-13 | Du Pont | Regenerated cellulose filaments and products therefrom |
US2838364A (en) * | 1955-01-07 | 1958-06-10 | Eastman Kodak Co | Dry spinning process |
US3194861A (en) * | 1957-03-25 | 1965-07-13 | Beaunit Corp | Viscose spinning process and bath |
Also Published As
Publication number | Publication date |
---|---|
NL62057C (enrdf_load_stackoverflow) | 1900-01-01 |
FR930155A (fr) | 1948-01-19 |
US2302077A (en) | 1942-11-17 |
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