US2388214A - Machining steels - Google Patents

Machining steels Download PDF

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Publication number
US2388214A
US2388214A US408493A US40849341A US2388214A US 2388214 A US2388214 A US 2388214A US 408493 A US408493 A US 408493A US 40849341 A US40849341 A US 40849341A US 2388214 A US2388214 A US 2388214A
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United States
Prior art keywords
steels
boron
sulphur
steel
percent percent
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Expired - Lifetime
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US408493A
Inventor
Murphy Donald William
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Bethlehem Steel Corp
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Bethlehem Steel Corp
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Publication date
Application filed by Bethlehem Steel Corp filed Critical Bethlehem Steel Corp
Priority to US408493A priority Critical patent/US2388214A/en
Priority to US609325A priority patent/US2388215A/en
Application granted granted Critical
Publication of US2388214A publication Critical patent/US2388214A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/60Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60

Definitions

  • My invention relates to machining steels.
  • My invention comprises free-machining or allied steels having a small percentage of boron. It also comprises such steels containing other elements to give machinability effects, such as sulphur, phosphorus or nitrogen.
  • I employ boron in amounts from 0.004% to 0.02%, usuall preferring to use in the neighborhood of 0.01%.
  • My invention is particularly eflicacious when both boron and sulphur are used in steels.
  • Such steels possess machinability properties considerably in excess of those containing sulphur alone and, moreover, the presence of the boron in such steels overcomes to a considerable degree certain disadvantages of sulphur in steel.
  • Sulphur because of certain deleterious efiects, is normally kept low in steels, the sulphur content ordinarily running from about 0.02% to about 0.04%.
  • These higher contents of sulphur render such steels capable of being machined to give longer tool life (conversely. greater speeds with the same tool life), and the machined surface is orbetter character.
  • the addition of these higher amounts of sulphur however, has the effect of producing a steel in which the sulphur tends to be more or less segregated. Furthermore, such steels are more or less hot short depending upon the amount of sulphur present.
  • a steel containing 0.15% sulphur possessed a cutting speed of 162 surface feet per minute for 100 minutes tool life.
  • the boron greatly reduces the tendency of the sulphur to segregate, thereby giving a much more uniform character to the steel.
  • boron content may be varied from 0.004% to 0.015%, using sulphur in amounts from 0.06% to 0.3%.
  • the carbon content will vary from low carbon up to 0.50%, ordinarily running between 0.10% and 0.50%.
  • the manganese will run from 0.4% to 1.60%, although higher or less manganese contents may be used. Ordinarily it is well to have a substantial content of manganese as'this element tends to overcome hot shortness. I have employed manganese as high as 2.5% without any disadvantageous counteractin effects upon the boron.
  • Boron may be used to contribute advantageous effects, recited above, in steels containing up to 16% chromium and I have found that it may be used in steels containing varying amounts of nickel, say up to 3%, or possibly higher. I have found that the boron addition contributes its useful efiects in nitrogen-chromium combinations including the austenitic varieties of these steels.
  • the boron is added in an alloy form either to the steel in the ladle or to the mold.
  • adding the ferro-boron to the mold is somewhat more economical than adding it to the ladle.
  • a free-machining steel containing carbon from 0.10% to 0.50%; sulphur from 0.06% to 0.30%; boron from 0.004% to 0.02% and the balance substantially all iron.
  • a free-machining steel containing carbon from 0.10% to 0.50%; sulphur from 0.06% to 0.30%; boron from 0.004% to 0.01% and the balance substantially all iron.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Description

Patented Oct. 30, 1945 2.388.214 momma STEELS Donald William Murphy, Bethlehem, Pa., assignor to Bethlehem Steel Company, a corporation of Pennsylvania Application August 27, 1941, aria] No. 408,493
No Drawing.s
2 Claims.
My invention relates to machining steels. My invention comprises free-machining or allied steels having a small percentage of boron. It also comprises such steels containing other elements to give machinability effects, such as sulphur, phosphorus or nitrogen.
I have discovered that boron in very small amounts in steel contributes markedly to its machinability. As is well known, there are definite limits to the life of a cutting tool when used to machine steels, and definite limits to the speed at which the tool may be used. As the speed is increased, the life of the tool is shortened. I have found that when 0.01% or even lesser amounts of boron are added to steels the life of the tool used thereon is greatly increased for a given speed, and conversely, for a particular tool life, the speed may be greatly increased.
I employ boron in amounts from 0.004% to 0.02%, usuall preferring to use in the neighborhood of 0.01%.
My invention is particularly eflicacious when both boron and sulphur are used in steels. Such steels possess machinability properties considerably in excess of those containing sulphur alone and, moreover, the presence of the boron in such steels overcomes to a considerable degree certain disadvantages of sulphur in steel.
Sulphur, because of certain deleterious efiects, is normally kept low in steels, the sulphur content ordinarily running from about 0.02% to about 0.04%. However, it is well known practice to make free-machining steels by increasing the sulphur content so that the sulphur in open hearth steels runs from about 0.07% to 0.20% and, in the case of Bessemer steels, from about 0.10% to 0.30%. These higher contents of sulphur render such steels capable of being machined to give longer tool life (conversely. greater speeds with the same tool life), and the machined surface is orbetter character. The addition of these higher amounts of sulphur, however, has the effect of producing a steel in which the sulphur tends to be more or less segregated. Furthermore, such steels are more or less hot short depending upon the amount of sulphur present.
By including boron in such steels of higher sulphur content, I greatly increase the machinability characteristics and I overcome to a considerable degree some of the disadvantages of the higher sulphur contents.
For example, a steel containing 0.15% sulphur possessed a cutting speed of 162 surface feet per minute for 100 minutes tool life. A steel containing the same sulphur content, namely, 0. 15%
sulphur, but also containing 0.01% boron, possessed a cutting speed of 219 surface feet per minute for minutes tool life, an increase of about 35%.
In addition to increasing the machinability of sulphur containing steels, the boron greatly reduces the tendency of the sulphur to segregate, thereby giving a much more uniform character to the steel.
I obtain substantial effects on sulphur-bearing steels as regards machinability and uniformity of product, by the use of various amounts of boron. The boron content may be varied from 0.004% to 0.015%, using sulphur in amounts from 0.06% to 0.3%.
As indicated above, sulphur renders steels more or less hot short, this characteristic increas ng with increasing amounts of sulphur. Steels are frequently needed possessing a high degree of machinability and, at the same time, having a low order of hot shortness. But to obtain the necessary machinability by means of sulphur it frequently happens that such large amounts of this element are required as to be incompatible with- C Mn P 8 Si Per cent Per cent Per cent Per cent Per cent 2 ll 73 077 304 .009 $3 l0 67 08 19 0i 4 20 .85 08 l3 05 (5 .20 85 015 .13 05 (6 .20 86 016 l3 05 the boron content of these analyses varying between 0.004% and 0.02%.
I have also found that boron and nitrogen cooperate very-efiectively in steels having free-cutting characteristlcs. Nitrogen by itself, when used in suiilcient amount, gives good surface to machined steels and also causes the steel to chip eflectively during the cutting operation. Nitrogen by itself, however, apparently somewhat decreases cutting speeds, as nitrogen increases the hardness. The addition of boron to'steels congen steels, I submit the following:
Mn s N 3 Percent Percent Percent Percent Percent (l) 0.18 0.60 0.029 0.01 0. 007 (2) l5 80 041 000 007 I have found suitable combinations of sulphur,
nitrogen and boron to give excellent efiects, giving steels capable of being machined at high speed and producing products with excellent finish. As specific examples of these combinations of sulphur, nitrogen and boron, I submit the followin analyses:
c Mn 0 s N B Percent Percent Percent Percent Percent (l) 0. l8 0. 78 0.148 0. 009 0. 01 (2) .15 1.03 .216 .011 .007
I have also found that effective steels for machining purposes may be produced by using phosphorus over the normal amount in conjunction with boron. In steels of this sort I prefer to use boron between 0.004% and 0.02%, and phosphorus between 0.035% and 0.12%. As a specific example I give the following analysis:
0 Mn S P 13 Percent Percent Percent Percent Percent 2,sas,214
In my steels the carbon content will vary from low carbon up to 0.50%, ordinarily running between 0.10% and 0.50%.
Normally, with my steels. the manganese will run from 0.4% to 1.60%, although higher or less manganese contents may be used. Ordinarily it is well to have a substantial content of manganese as'this element tends to overcome hot shortness. I have employed manganese as high as 2.5% without any disadvantageous counteractin effects upon the boron.
Boron may be used to contribute advantageous effects, recited above, in steels containing up to 16% chromium and I have found that it may be used in steels containing varying amounts of nickel, say up to 3%, or possibly higher. I have found that the boron addition contributes its useful efiects in nitrogen-chromium combinations including the austenitic varieties of these steels.
In preparing my steels, containing boron, the boron is added in an alloy form either to the steel in the ladle or to the mold. I usually employ ferro-boron containing 10-20% of elemental boron. I have found that adding the ferro-boron to the mold is somewhat more economical than adding it to the ladle. When adding to the ladle it is usually necessary to employ somewhat more ferroboron than when adding it to the mold, to get the same boron content in the finished product.
Having thus described my invention, what I claim as new and desire to secure by Letters Patentis:
1. A free-machining steel containing carbon from 0.10% to 0.50%; sulphur from 0.06% to 0.30%; boron from 0.004% to 0.02% and the balance substantially all iron.
2. A free-machining steel containing carbon from 0.10% to 0.50%; sulphur from 0.06% to 0.30%; boron from 0.004% to 0.01% and the balance substantially all iron.
DONALD WILLIAM MURPHY.
US408493A 1941-08-27 1941-08-27 Machining steels Expired - Lifetime US2388214A (en)

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US609325A US2388215A (en) 1941-08-27 1945-08-06 Machining steels

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4572747A (en) * 1984-02-02 1986-02-25 Armco Inc. Method of producing boron alloy
EP0265402A1 (en) * 1986-09-29 1988-04-27 Ovako Steel Oy AB Calcium treated boron alloyed steel with improved machinability

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4572747A (en) * 1984-02-02 1986-02-25 Armco Inc. Method of producing boron alloy
EP0265402A1 (en) * 1986-09-29 1988-04-27 Ovako Steel Oy AB Calcium treated boron alloyed steel with improved machinability

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