US2369567A - Method of producing printing plates - Google Patents
Method of producing printing plates Download PDFInfo
- Publication number
- US2369567A US2369567A US356190A US35619040A US2369567A US 2369567 A US2369567 A US 2369567A US 356190 A US356190 A US 356190A US 35619040 A US35619040 A US 35619040A US 2369567 A US2369567 A US 2369567A
- Authority
- US
- United States
- Prior art keywords
- metal
- printing
- plate
- image
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000007639 printing Methods 0.000 title description 27
- 238000000034 method Methods 0.000 title description 11
- 229910052751 metal Inorganic materials 0.000 description 49
- 239000002184 metal Substances 0.000 description 49
- 238000007792 addition Methods 0.000 description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 16
- 238000005188 flotation Methods 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000003921 oil Substances 0.000 description 11
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 9
- 229910052725 zinc Inorganic materials 0.000 description 9
- 239000011701 zinc Substances 0.000 description 9
- 229910001369 Brass Inorganic materials 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 239000010951 brass Substances 0.000 description 8
- 229910017052 cobalt Inorganic materials 0.000 description 8
- 239000010941 cobalt Substances 0.000 description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 8
- 238000005530 etching Methods 0.000 description 8
- 150000002739 metals Chemical class 0.000 description 8
- 229910052759 nickel Inorganic materials 0.000 description 8
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 229910000861 Mg alloy Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 239000004922 lacquer Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000012991 xanthate Substances 0.000 description 4
- 229910000531 Co alloy Inorganic materials 0.000 description 3
- FCSHMCFRCYZTRQ-UHFFFAOYSA-N N,N'-diphenylthiourea Chemical compound C=1C=CC=CC=1NC(=S)NC1=CC=CC=C1 FCSHMCFRCYZTRQ-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 description 3
- LSSAUVYLDMOABJ-UHFFFAOYSA-N [Mg].[Co] Chemical compound [Mg].[Co] LSSAUVYLDMOABJ-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- ATTFYOXEMHAYAX-UHFFFAOYSA-N magnesium nickel Chemical compound [Mg].[Ni] ATTFYOXEMHAYAX-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 231100001010 corrosive Toxicity 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 238000007645 offset printing Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 150000003567 thiocyanates Chemical class 0.000 description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N thiocyanic acid Chemical compound SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 2
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- -1 ferricyanide ions Chemical class 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 229910001867 inorganic solvent Inorganic materials 0.000 description 1
- 239000003049 inorganic solvent Substances 0.000 description 1
- 238000007644 letterpress printing Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N3/00—Preparing for use and conserving printing surfaces
- B41N3/08—Damping; Neutralising or similar differentiation treatments for lithographic printing formes; Gumming or finishing solutions, fountain solutions, correction or deletion fluids, or on-press development
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/04—Printing plates or foils; Materials therefor metallic
- B41N1/08—Printing plates or foils; Materials therefor metallic for lithographic printing
- B41N1/10—Printing plates or foils; Materials therefor metallic for lithographic printing multiple
Definitions
- the flat or offset printing is based on' the fact that the fat printing ink is repelled by the por-' tions moistened with water, or the so-called etched portions.
- etching with salt or acid solutions
- these portions become water-carrying while the image or letters, con sisting of fat substances or lacquers, constantly take 'up the'printing ink (the level which is continually moistened does not take on any ink).
- the flat printing plates of known type continuous re-etching is necessary. The latter must,
- a known method of this kind provides that the plate or carrier metalis uniformly coated printing is based on the principle that the inking with a thin film of another metal, that then the image is applied and that the non-covered image portions are removed by etching down to the carrier metal.
- Another proposition consists in bringing the picture in some way, in this case negatively, onto the carrier metal, and in depos- I iting galvanically another metal unto the unnon-printing portions of water-attracting metal,
- the invention proposes an absolutelynew method for attaining this aim by ina printing plates with one of the substances known from the flotation as so-called flotation additions .so that the moistening capability, as regards fat and oil or water, is respectively increased.
- the flotation or floating dressing is based on When producing fiat printing plates the purpose is of course different because molstenmg with oil takes place during the printing. Consequently, one added medium will generally be sufficient for the method according to the invention (compare for instance Ullmann, Encyclopaedia of the Technical Chemistry, volume 1, 1928, page 796 .and following). Alkaline additions or such which reduce the formation of ilakes or such which possess eii'ects similar to those of the oil also can be considered. The additions used for differential flotation and such additions which cause a chemical alteration of the surface, as for instance sulfidizing additions, have proved to be particularly suitable. It has further shown to be suitable in individual cases to add in fine distribution to the treating liquid (etch) an oil or the type of the flotation oils.
- the treatment can be carried out with solutions suitable alloys for the level metal are nickelmagnesium on a copper plate or cobalt-magnesium on a zinc plate.
- an aqueous solution of xanthogenic alkali salts and hydroferrocyanic salts preferably at a pH of about 8 to 9 can be used for the treatment according to the invention.
- the same liquid can be used for other metal combinations, such as zinc with cobalt-magnesium.
- the value of the xanthogenic salts is preferably preponderate, and the pH value is located at about 6 to 7.
- the surface of a metal plate may bear a non-electric insulating coating, such as lacquer or ink, the plate being galvanized with a metal of the iron group. Then follows the treatment with the solutions according to the invention.
- the production of the plate may, however, be
- the oil and the addition dissolve completely, in inorganic media, especially water, the additions may be dissolved and the oil emulsified.
- the treatment in such a solution of flotation additions is suificient, in other instances, however, it is advisable to provide further a treatment with the socalled lithographic etches as have been used up to the present in order to make the level water-carrying.
- This etching can take place before the treatment with the flotation additions or more advantageously after the same.
- An especially advantageous embodiment of the invention consists, however, in the simultaneous flotating and etching. This is carried out by employment of a solution which contains both the flotation media and lithographic etches.
- the selection of the-flotation addition depends chiefly on the nature of the image metal which is used, however, also on the nature of the level metal. In every individual case an addition of the kind has to be employed which renders the surface of the image the most capable of oilmo-istening but which has the least possible influence on the level metal and does not disturb the etching effect.
- Suitable metal combinations depends on the existing conditions. In many cases it is especially advisable to use as fatcarrying metal a metal or an alloy of the copper group, for instance a nickel-cobalt alloy.
- a brass sheet metal plate might, for instance, be coated with a suitably thick layer of cobalt, an image be produced on this layer (the image resisting corrosives, for instance a lacquer copy), whereupon the cobalt layer is etched through down to the brass plate at the uncovered portions, for instance by means of chromic acid solution.
- Example 1 the image is produced in any suitable manner in fat ink on a brass plate. This can be obtained by transferring or by printing down, by hand-drawing, or in a similar manner. The level, that is the unprotected parts, is then nickeled, or coated with a deposit of, for instance, magnesium containing nickel.
- the flat printing plate thus obtained is lithographically etched, preferably with an etch consisting of l to 20%, preferably 1 to 5% hydroferrocyanic potassium solution, to which alkali is added perhaps up to the pH value of 9.
- the plate is then placed in the machine.
- a fountain etch which is suitably diluted and besides contains kanthogenic light metal salt, is used. If the plate has to be washed out for any reason, this is done with pure solvents, for instance benzene, benzol or the like, and the plate can be etched in this washed out state with a liquid preferably of the following composition.-
- the liquid has always the property to render one of the metals, in this instance the brass, extraordinarily receptive to fat. whereas the second metal, nickelmagnesium, is strongly etched lithogralphically and thereby becomes strongly ink-repellent.
- the etch to be used for the above combination brass-nickel-magnesium is composed as follows:
- Example 3 For a printing plate, the image portions of which consist of copper and the level portions of iron, asolution of the following composition is used:
- Process of producing printing plates having an image metal portion of zinc and a level metal portion of nickel comprising treating said plates with a solution comprising approximately 1000 cubic centimeters of water, 10 to grams of sodium hydroterricyanide, 2 to 8 grams of oxalic acid and 1 to 10 grams of diphenylsulfourea.
Landscapes
- Printing Plates And Materials Therefor (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEH0160581 | 1939-09-14 | ||
DEH0000415 | 1940-08-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
US2369567A true US2369567A (en) | 1945-02-13 |
Family
ID=25979255
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US356190A Expired - Lifetime US2369567A (en) | 1939-09-14 | 1940-09-10 | Method of producing printing plates |
Country Status (5)
Country | Link |
---|---|
US (1) | US2369567A (en)) |
BE (1) | BE439146A (en)) |
CH (1) | CH220509A (en)) |
FR (1) | FR873405A (en)) |
NL (1) | NL59210C (en)) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2582347A (en) * | 1945-03-08 | 1952-01-15 | Columbia Ribbon & Carbon | Planographic printing |
-
0
- NL NL59210D patent/NL59210C/xx active
- BE BE439146D patent/BE439146A/xx unknown
-
1940
- 1940-08-28 CH CH220509D patent/CH220509A/de unknown
- 1940-09-10 US US356190A patent/US2369567A/en not_active Expired - Lifetime
-
1941
- 1941-06-28 FR FR873405D patent/FR873405A/fr not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2582347A (en) * | 1945-03-08 | 1952-01-15 | Columbia Ribbon & Carbon | Planographic printing |
Also Published As
Publication number | Publication date |
---|---|
NL59210C (en)) | |
BE439146A (en)) | |
FR873405A (fr) | 1942-07-08 |
CH220509A (de) | 1942-04-15 |
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