US2367344A - Lubricant - Google Patents

Lubricant Download PDF

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Publication number
US2367344A
US2367344A US420017A US42001741A US2367344A US 2367344 A US2367344 A US 2367344A US 420017 A US420017 A US 420017A US 42001741 A US42001741 A US 42001741A US 2367344 A US2367344 A US 2367344A
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United States
Prior art keywords
oil
quinone
lubricating
wear
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US420017A
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English (en)
Inventor
Evans Elliott Alfred
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CC Wakefield and Co Ltd
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CC Wakefield and Co Ltd
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Publication of US2367344A publication Critical patent/US2367344A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/08Aldehydes; Ketones
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • C10M2207/404Fatty vegetable or animal oils obtained from genetically modified species
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/04Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
    • C10M2211/042Alcohols; Ethers; Aldehydes; Ketones
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/06Perfluorinated compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/14Containing carbon-to-nitrogen double bounds, e.g. guanidines, hydrazones, semicarbazones
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/16Nitriles
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06Thio-acids; Thiocyanates; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/083Dibenzyl sulfide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/102Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon only in the ring
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106Thiadiazoles

Definitions

  • a lubricating composition especially a lubricating composition intended for use under conditions of extreme pressure, comprises a lubricating oil'and a minor proportion of a ,quinone'or of a quinone derivative.
  • the quinone or quinone derivative contains one or more groups known to convey or to enhance extreme pressure properties in a lubricating oil.
  • groups known to convey or to enhance extreme pressure properties in a lubricating oil for example, there may be present asfsubstituents, halogen atoms, (for example, chlorine atoms), sulphur, nitrogen-containing groups, hy-- Examples of suitable droxyl, and ester groups.
  • quinone derivatives for the purpose of the present invention are. halogen-substituted quinones and N-substituted quinone derivatives (e. g. N-chloroimines) ,and the expression quinone derivative is intended to include such N-substituteda com-
  • the organic compounds employed as additions to a lubricating oil in accordance with the'present invention are preferably incorporated in a proportion which is but a minor fraction of the total weight of the composition; Ingeneral, amounts of said organic compounds up to ab01'1t -10% by weight of thelubricating oil (and preferably substantially below this amount) areemployed. It
  • pos'sessa relatively high boiling-point'arid decomposition temperature so thatit is' stable under service .conditions;' compounds which do not dethisr'espect. a
  • the j addition agents sh' all be. substantially oil-soluble or of such, a nature that they may be included in the lubricating composition in the form of a stable suspension.
  • the device used for testing wear-reducing properties was the ell-known "Avery-Brownsdon" wear and lubricant tester in which a hard steel wheel rapidly In determining the suitability oi particular quinonesor quinone derivatives for use as addirevolved in contact with a smooth steel plate coated with the lubricant makes a mark of measurable length. The wear impression is measured in inches.
  • the oil used was a mineral lubricating oil or a paramnic character andthe table which follows-shows the results of typical tests.
  • a lubricating composition of improved quality can be obtained by incorporating with the lubricating oil not only a quinone or quinone derivative but also a sulphur-containing compound, for example, an organic mercaptan, an organic disulphide, a thiccyanate or a thioether.
  • the results obtained may be divided into two classes (1) those obtained by adding to the oil single substances of the quinone class, and (2) those obtained by adding to the oil mixtures of quinones especially halogenated qulnones with sulphur compounds.
  • Lorol thiocyanate is a mixture of thio-cyanates derived from straight chain fatty alcohols of 8 and 10 carbon atoms.
  • the only mixtures specified (for addition to lubricating oil) are mixther used was di(3zcarbomethoxv-izhydroxyphenyl)' tures oi quinones or quinone derivatives with 5111- phur-containing compoundsbut it will be understood that the lubricating compositions prepared according to this invention may als include other oil improvers including metallic compounds, oxidation inhibitors such as tertiarybutyl cresol or corrosion inhibitors such as mercaptobenztbiaaole.
  • oil used is of a parafllnic mm. nature, but it will be understood that mineral oils u of an asphaltic or naphthenic character may Bulphnrcom und Other com nonts 1" R S ambeused'
  • Some lubricating oils contain a proportion or m a fatty oil or vegetable oil such as rape oil and i 32, such oils may be used in the preparation of lubrif gg% 25 51 3 fiZm 5o eating compositions according to this invention.
  • a lubricating composition suitable for use under conditions oi. extreme pressure comprising a lubricating 'oil and a suflicient amount of a quinone chloro-imlne to impart extreme pressure properties to the composition.
  • quinone compound having at least one substituent group containing nitrogen and a halogen, said compound being in suiilclent amount to impart extreme pressure properties to the composition.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
US420017A 1941-01-08 1941-11-21 Lubricant Expired - Lifetime US2367344A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB273/41A GB566055A (en) 1941-01-08 1941-01-08 Improvements in or relating to lubricants

Publications (1)

Publication Number Publication Date
US2367344A true US2367344A (en) 1945-01-16

Family

ID=9701444

Family Applications (1)

Application Number Title Priority Date Filing Date
US420017A Expired - Lifetime US2367344A (en) 1941-01-08 1941-11-21 Lubricant

Country Status (4)

Country Link
US (1) US2367344A (enrdf_load_stackoverflow)
BE (1) BE464058A (enrdf_load_stackoverflow)
FR (1) FR929470A (enrdf_load_stackoverflow)
GB (1) GB566055A (enrdf_load_stackoverflow)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2477244A (en) * 1946-06-26 1949-07-26 Standard Oil Co Stabilized organic sulfur-containing composition and method of preparing same
US2497097A (en) * 1946-05-31 1950-02-14 Standard Oil Co Method of preparing stabilized organic sulfur-containing compounds
US3189548A (en) * 1963-04-30 1965-06-15 Monsanto Res Corp Polyphenyl ethers containing an extreme pressure additive
US3190834A (en) * 1961-06-28 1965-06-22 Texaco Inc Lubricant compositions comprising chlorinated quinones
US3328301A (en) * 1965-09-23 1967-06-27 Eastman Kodak Co Antioxidants for lubricating oils

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3764535A (en) * 1972-05-25 1973-10-09 Texaco Inc Tetra-t-dodecylamarcapto-p-benzoquinone

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2497097A (en) * 1946-05-31 1950-02-14 Standard Oil Co Method of preparing stabilized organic sulfur-containing compounds
US2477244A (en) * 1946-06-26 1949-07-26 Standard Oil Co Stabilized organic sulfur-containing composition and method of preparing same
US3190834A (en) * 1961-06-28 1965-06-22 Texaco Inc Lubricant compositions comprising chlorinated quinones
US3189548A (en) * 1963-04-30 1965-06-15 Monsanto Res Corp Polyphenyl ethers containing an extreme pressure additive
US3328301A (en) * 1965-09-23 1967-06-27 Eastman Kodak Co Antioxidants for lubricating oils

Also Published As

Publication number Publication date
FR929470A (fr) 1947-12-29
BE464058A (enrdf_load_stackoverflow)
GB566055A (en) 1944-12-12

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