US2303375A - Rochelle salt piezoelectric crystal apparatus - Google Patents
Rochelle salt piezoelectric crystal apparatus Download PDFInfo
- Publication number
- US2303375A US2303375A US397377A US39737741A US2303375A US 2303375 A US2303375 A US 2303375A US 397377 A US397377 A US 397377A US 39737741 A US39737741 A US 39737741A US 2303375 A US2303375 A US 2303375A
- Authority
- US
- United States
- Prior art keywords
- thickness
- dimension
- shear
- crystal element
- axis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000013078 crystal Substances 0.000 title description 140
- LJCNRYVRMXRIQR-OLXYHTOASA-L potassium sodium L-tartrate Chemical compound [Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O LJCNRYVRMXRIQR-OLXYHTOASA-L 0.000 title description 61
- 235000011006 sodium potassium tartrate Nutrition 0.000 title description 61
- 230000001419 dependent effect Effects 0.000 description 15
- 230000003247 decreasing effect Effects 0.000 description 5
- 238000007747 plating Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000000576 coating method Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- YUBJPYNSGLJZPQ-UHFFFAOYSA-N Dithiopyr Chemical compound CSC(=O)C1=C(C(F)F)N=C(C(F)(F)F)C(C(=O)SC)=C1CC(C)C YUBJPYNSGLJZPQ-UHFFFAOYSA-N 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000003340 mental effect Effects 0.000 description 2
- QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical compound Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 description 1
- 241001523162 Helle Species 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000012858 resilient material Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000001476 sodium potassium tartrate Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H9/00—Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
- H03H9/46—Filters
- H03H9/54—Filters comprising resonators of piezoelectric or electrostrictive material
- H03H9/56—Monolithic crystal filters
Definitions
- This invention relates to piezoelectric crystal apparatus and particularly to high frequency piezoelectric Rochelle salt or sodium potassium tartrate crystal elements suitable for use as cir-' cuit elements in electric wave filter systems and oscillator systems, for example.
- One of the objects of this invention is to provide a Rochelle salt piezoelectric crystal element having one or more useful high frequency or thickness modes of motion that may be utilized alone or simultaneously without interference with other modes of motion therein.
- Another object of this invention is to provide a Rochelle salt crystal element having a plurality of simultaneously useful and independently controlled thickness mode frequencies.
- Another object of this invention is to provide Rochelle salt crystal elements utilizing either the first shear thickness mode of motion thereof or the second shear thickness mode of motion thereof.
- Another object of this invention is to reduce the number and the cost of. crystals used in high frequency electric wave filter systems and other wave transmission networks, and 'to take advantage of the high piezoelectric activity and low cost of Rochelle salt.
- Rochelle salt piezoelectric crystal elements generally may be excited in many different modes of motion such as extensional or longitudinal modes of motion, fiexural modes of motion, and shear modes of motion, for example.
- extensional or longitudinal modes of motion such as extensional or longitudinal modes of motion, fiexural modes of motion, and shear modes of motion, for example.
- shear modes of motion for example.
- the desired main mode or modes of motion-of a crystal element be substantially independent of other modes of motion and independently controlled in order that such desired mode or modes of motion-may be given any desired frequencyyalues to obtain prescribed frequency characteristics.
- wave filters and other systems may comprise as a component provide either separately or simultaneously useful effective resonances which may be independently controlled andplaced-at predetermined frequencies of nearly the same value or of difierent values, for use in an electric wavefilter, or elsewhere.
- the crystal element may be a Rochelle salt a type crystal plate of suitabl orientation with respect to the X, Y and Z axes thereof, and of suitable dimensional proportions, and provided with a suitable electrode arrangement and connections for separately driving either or simultaneously driving both of two thickness modes of motion therein, and independently controlling the relative strengths of such resonances.
- the orientation of the Rochelle salt crystal element may be such element thereof, a single piezoelectric crystal element of Rochelle salt which maybe adapted to vibrate simultaneously. in a plurality of high frequency or thickness modes of motion in order to that one of the major surface dimensions thereof, such as the length dimension, lies along one of the X, Y and Z axes thereof, and the other dimension, such as the width dimension of the.
- the major surfaces is rotated in eflect a selected angle in degrees to a position intermediate or midway between the other two of the X, Y and Z axes.
- the major surfaces may be of rectangular or square shape.
- the frequency-determining thickness dimension between the major surfaces of the crystal element and the length dimension thereof may be'made of selected and related values, as a dimensional ratio of the length dimension with respect ,to the thickness dimension in the region from 10 to 50, in order -to obtain therefrom, separately or simultaneously, either or both of two useful independently controlled resonant frequencies resulting from two independently controlled thickness modes of motion, one particular set of which is described herein as the fundamental or first shear thickness mode of 'motion and the other as the second shear thickness mode of motion. Both the first and second shear mode frequencies are controlled mainly by the thickness dimension of the'crystal element andvary inversely as the value of the thickness dimension of the crystal element.
- the Rochelle salt crystal elements described herein may have the same or similar orientations as those described in my United States Patent 2,178,146, dated October 31, 1939, but herein they are adapted for a plurality of thickness mode ,vibrations of the shear type including the first shear and also the second shear modes of motion. 4 Such Rochelle salt crystal'elements when provided with suitable electrodes may be connected into a filter circuit'in sucha way that one of the resonances of each crystal element is effective asosevs n.
- l, 2 and 3 are perspective views of three forms of piezoelectric Ro helle salt crystal elements in accordance with this invention, and respwtively illustrate particularly the orientation thereof with respect to the and Z axes of the nding of the nature of Rochelle salt crystal material from which the 7 crystal elements be cut:
- Figs. l to 8 are views illustrating types of electrodes and connections which may be utilized with any of the Rochelle salt crystal elements of Fig. l, 2 or 3 to drive the crystal element sepa rately in either, or simultaneously in both, of two independent shear thickness modes of motion, in order to obtain the desired resonance frequency Or frequencies;
- Fig. 4 is a perspective view of an electrode arrangement that may be used to driveany or the piezoelectric crystal elements of Fig. 1, 2 or 3 in the fundamental or first shear thickness mode of motion;
- Figsj5 and 6 are perspective views of electrode arrangements that may be used to drive any of the crystal elements of Fig. 1, 2 or '3 in the second shear thickness mode of motion and the fundamental or first shear thickness mode of motion, separately or simultaneously;
- Fig. '7 is a schematic diagram illustrating an example of balanced filter connections that may be used with the crystal element electrodes oi
- Fig. 8 is a schematic diagram illustrating an example of unbalanced n or connections that may be used with the electrodes of the crystal element of Fig. 6;
- FIG. 9 is a graph illustrating the thickness mode frequency-dimension constants of the fundamental or first shear mode of motion and of the second shear mode of motion in the Rochelle salt crystal element illustrated in Fig. 1 having a dimensional ratio of its X axis length L with respect to its thickness '1 in the region from 12 to 30.
- Figs. 10 and 11 are graphs illustrating the thickness-mode i *equency-dimcnsion constants of the first and second shear mode vibrations of the Rochelle salt crystal elements illustrated in Figs. 2 and 3 respectively, for ratios of the length L with respect to the thickness T in the region from about 12 to 30.
- Rochelle salt 45 degrees designate in degrees the effective angular position oi the width axis dimension W of the crystal plate as measured from one of the other two of the X, Y and Z axes.
- the relation of ie X, Y and Z axes to the outer of a grown. Rochelle salt crystal body are illustrated in W. P. Mason United States Patent 2,178,146, dated October 31, 1939.
- Rochelle salt belongs to the rhombic hemihedral class of crystals and has three orthogonal or mutually perpendicular axes generally designated as the h, and c axes or the X, Y and Z axes, respectively.
- Figs. 1 represent perspective views of thin bare piezoelectric Rochelle salt crystal elements l, 2 and 3 out from crystalline Rochelle salt free from defects and made into a plate of substantially rectangular parallelepiped shape with its major surfaces having a length dimension L, and a width dimension W which is perpendicular to and may be equal to or longer or shorter than the length dimension L.
- the frequency-determining thickness or thin dimension T between the major surfaces is perpendicular to the other two dimensions L and W.
- the 1, 2 and 3 may be made of a, suitable value with respect to the thickness dimension T according to the desired resonant frequency.
- the width dimension W also may be equal to or otherwise related to the length dimension L to remove spurious frequencies from the region of the desired resonant frequency.
- the thickness dimension T may be of the order 2 and 3 of 1 millimeter more or less and made ofany suitablevalue to obtain the desired thickness mode frequency or frequencies for the crystal element I, 2 or 3 of Figs. 1, 2 and 3.
- the length dimension L of the Rochelle salt crystal elementgl illustrated in Fig. 1 lies substantially along or parallel to the X axis, the X axis being perpendicular to the plane of the mechanical axis Y and the optic axis Z of the Rochelle salt crystal material from which the element I is cut.
- the width dimension W which is perpendicular to the length dimension L, is inclined at an angle of a degrees with respect to said Z axis, the angle a being one of the values inthe region of substantially 45 degrees (45).
- the major surfaces and the major plane of the Rochelle salt crystal element I are disposed parallel or nearly parallel with respect to the X axis, the length dimension L and the width dimension W lying along the X axis and the Z axis, respectively, the Z axis being inclined at the angle a with respect to the optic axis Z.
- the axis Z is accordingly the result of a single rotation of the width dimension W about the X axis degrees.
- the crystal element I of Fig. l is in effect a Y-cut Rochelle salt crystal plate rotated at degrees about the X axis.
- Fig. 3 represents a Rochelle salt crystal element 3 having its length dimension L along or parallel to the Z axis and its width dimension W inclined at an angle which may be any angle in the region of'45 degrees intermediate the X and -Y axes, the major surfaces of the crystal element 3 being parallel or nearly parallel to the Z axis.
- Figs. 1, 2 and 3 represent Rochelle salt piezoelectric crystal ele-, ments I, 2 and 3, respectively, which may be adapted for a plurality of independently controlled thickness mode vibrations of the shear motion type, which may be utilized either alone or simultaneously, according to the arrangement of the electrodes and connections that are used therewith, and the dimension-frequency constants that are selected therefor.
- the crystal element have apiezoelectric' constant which will generate a first shear motion along the thickness dimension T and also a piezoelectric constant that will generate a second shear motion along the thicknessdimension T.
- the requirement of suitable piezoelectric constants may be met when the width dimension W or the length dimension L is inclined at any suitable angle win the region to apply electric field excitation to the Rochelle salt plate.
- I, 2 or 3 which may be vibrated alone or simultaneously in the desired thickness T fundamental or first shear mode of motion and/or the thickness T second shear mode of motion at independently controlled resonant response. frequencies which depend upon dimensions involving the thickness dimension T and i also the width dimension W or the length dimension L, the fundamental shear thickness mode frequencies for the three cuts of Figs. 1,- 2 and 3 being values roughly ranging from about 940 to 1272 kilocycles per second'per millimeter of the thickness dimension T and varying inversely as the value of the thickness dimension T.
- Such Rochelle salt crystal elements I of- Fig. 1 havean electromechanical coupling which varies with temperature change, and are easily driven by" 45 degrees with respect to the Z axis and the X axis also may be used as a doubly resonant crystal element. Such an element has an electromechanical coupling that does not vary much in "fig.
- o e n nearly parallel to the e-Xis also may l e used to g a nerate thickness mode firt J vibrations of the k nd useful for a crystal e'len n' then the s soon *he lie 1 o. near mo uaviug the orienor 3 "may conto r b.0113 illustrated oiled by the value or t dii "nd the dimension ng 't' th re 111i d sion co ouencies ely the second sheer indanientai or first motio c with respect to the vmclrness dimer sion T is in a region and in this region the resonances of these two modes are substantially uncoupled. sir-only very loosely coupled.
- the frequencies of these two independent modes of vibration may be placed close together but sufliciently uncoupled or separated to provide simultaneously two independently controlled frequencies from the same Rochelle salt crystal element, which may be usefully employed in a filter system I mental shear thic for example, to give conveniently two useful frewhen used c.
- e rreduency of 1e cry any number of in frequen 3. than oi hiclrness mode frequency, and er stern, one resonance fro i one arm, and the other ,ency the other so that a we attenuation peaks can he made from one crystal.
- the first shear and the second shear thickness anode quencies of the crys elements 2 and 3 may be utilized.
- the grenh oi. illustrates the measured resonanc Ireouencies associated with the funda mental or first shear thickness mode oi ion (curve A) and also those associated with. the t end shear thickness node of motion (curve 33'), in a Rochelle c1 tal element cving square or nearly square major surfaces orientation angl of suostantially as degrees as illus trated i. g. 1. In Figv the funds.
- the second overtone shear thickness mode frequency is represented by the downwardly sloping inclined curve B and has a frequency-dimension constant from about 945 to 990 kilocycles per second per millimeter of thickness dimension T dependent upon the value of the selected dimensional ratio of the X axis length dimension L with respect to the thickness dimension T within the dimensional ratio range from about 12 to 30, the frequency constant values gradually decreasing with increasing values for the dimensional ratio.
- the freselected the IZZY fir quency' in resonance freo quency of the second shear mode of motion and by the curves of Figs. and 11, similar in form' to the downwardly sloping first and second shear mode curves A and B of Fig. 9 for. the crystal element l of Fig. 1 but are somewhat higher in frequency thanthe first and second shear mode frequencies of the crystal element I of Figs. 1 and 9 for a given dimensional ratio of the length L or the width W with respect to the thickness T.
- the thickness mode frequency-dimension constants for thedsecond shear thickness mode of motion in the Rochelle salt crystal element 2 of Fig.2 are roughly from 1277 to 1330 kilocycles per second per millimeter of the thickness dimension T within a range of dimensional ratios of the length L and width W with respect to the thickness T from about 12 to 30, the frequency constant values gradually decreasing with increasing values for the dimensional ratio as illustrated by the downwardly sloping curve B of Fig. 10; and the frequency-dimension constants for the second shear thickness mode of motion in the Rochelle salt crystal element 3 of Fig. 3 are, as illustrated .by theclownwardly sloping curve B" of Fig.
- the thickness mode frequency-dimension constants for the fundamental or first shear mode of motion are somewhat lower than those given above for the second shear mode of motion; and as illustrated by the curves A, A and A" 9, 10 and 11 for the Rochelle salt crystal elements l, 2 and 3 of Figs. 1, 2 and 3 are respectively, expressed in kilocycles per second, about from 942.5 to 948, from 1265 to 1272 and from 1052 to 1060, respectively, for dimensional ratios of the length L and width W with respect to the thickness T in the range about from 12 to 30, the frequency constant values gradually decreasing with increasing values for the dimensional ratio in accordance with the form of the slightly downwardly sloping curve B of Fig. 9.
- Fig. 4 which is a perspective view of the Rochelle salt crystal element of Fig. 1, 2 or 3, the pair of opposite electrodes 9 and I5 may be utilized to usefully operate separately in the crystal element I, 2 or 3 of Figs. 1 to 3, the fundamental or any odd order harmonic thickness shear mode of motion, the fundamental frequency being roughly one of the values from about 942 to 1272 kilocycles per second per millimeter of thickness dimension T, dependent upon the orientation selected.
- the electrodes 9 and I5 may partially or wholly cover the major surfaces of the crystal element I, 2 or 3 and may be connected in circuit by a conductive member disposed in contact with each of the electrodes 9 and I5 at or near the corners thereof.
- Rochelle salt crystal elements having the orientations illustrated in Figs. 1, 2 and 3 and provided with electrodes of the type illustrated in Fig. 4 may be utilized to obtain a desired fundamental or odd order harmonic shear mode vibrational frequency that is dependent substantially upon the thickness dimension T.
- the harmonic frequency may be values hereinbefore given for such frequencies.
- Figs. 4, 5 and 6 illustrate forms'of electrode arrangements which may be utilized to drive any of the crystal elements of Fig. 1, 2 or 3.
- the single pair of electrodes 9 and I 5 may be used to drive either the thickness T shear fundamental mode of motion or any odd harmonic such as third, fifth, etc., harmonic thereof to obtainseparately but not simultaneously any of -of any desired odd order and may be obtained by the use of electrode-arrangement shown in Fig. 4.
- the second shear thickness mode of motion may be driven by means of two pairs of divided electrodes H), II, l2 and I3 placed on both of the major surfaces of the crystal element of Fig. 1, 2 or 3; and with suit able connections, the fundamental or first shear mode of motion may be driven at the same time by one of the connected sets of electrode platings, with the result that the two useful andindependently controlled thickness mode resonance frequencies of the crystal element L2 'or 3 may be made to appear simultaneously.
- the Rochelle salt crystal element I, 2 or 3 of Fig. 1, 2 or 3 may be provided with four equal area electrodes I 0, ll, l2 and I3, two
- the electrodes l0 and H being placed on one major surface of the crystal element with a centrally located narrow transverse split or gap 1 therebetween, and the other two electrodes l2 and I3, being oppositely disposed and placed on the opposite major surface of the crystal element and separated with a similar narrow and oppositely disposed split or dividing line 1 therebetween, the dividing lines 1 extending generally in the direction of the width W axis of the crystal element, according to the value of the angle selected between the direction of the dividing line I and the direction of the length. dimension L.
- the gap or separation 1 between the electrode coatings or platings on each of the major surfaces of the crystal element may be of the order of about 0.3 millimeter, the center line of such splits in the platings on the opposite sides of the crystal plate I being aligned with respect to each other.
- the fundamental thickness shear vibration of the crystal element When the electrode plates have the same sign across the Whole surface of the major surface, the fundamental thickness shear vibration of the crystal element is excited; and when the electrode plates have opposite signs on'the same major surface of the crystal element, the second thickness shear mode vibration, corresponding to the fundamental shear mode for a crystal plate half as long as the length L of the original crystal element, is excited, the second shear orancii oi the equivalent late diagonal branch there- *ully in connection with i and 3 application, Serial ,lli'? referred to hereinceiore.
- oe balanced circuit of Fig. 5' may be con" ted into an unbalanced filter structure by inectirlg the t o electrodes '3? and on no major 5 aces of the crystal element.
- a narrow grounding strip i i of metallic or conductive coating or plating may be placed on one major surface of the crystal element between the electrodes if and The strip l4 may extend around one edge of the crystal element to the opposite major suriace thereof where it may be.
- the ground strip is may be approximately 1 millimeter in width and may be placed between and separated from the two electrodes Ill and H on the same major surface of the crystal element 1, in order to provide shielding and to reduce stray capacities to a minimum.
- the strip of plating 14 may extend from one major surface continuously over and around one edge only or both edges of the crystal plate I to the opposite major face thereof where it may make contact with the integral electrode 15 on that surface.
- one-half ofthe crystal plate I is made of opposite polarity to that of the other half, as indicated by the and signs in Fig. 6, and that this may be accomplished by utilizing a crystal element having divided metallic coatings l0 and l!.placed on one of its major surfaces and connected in the form of a T network, for example, as illustrated in Fig. 8.
- Inductance coils may be added in the usual manner in series or in parallel with the network of Fig. 8 to produce broad band low or high impedance filters for example.
- the crystal impedance may appear in both arms of the lattice structure of Fig.
- both modes are driven when the terminals 2
- the crystal electrodes associated with one half of the major suriace or surfaces of crystal element l, 2 or 3 of Figs. 5 and 6 may be extended to cover a portion of the other half thereof. This may be done, for example, by adjustment of the position of the electrode dividing line angle with respect to the length dimension L. The angle may be any desired value over a wide range of angles. This adjustment does not materially affect the impedance of the first shear mode resonance, but with decreasing values for the SO-degree' angle shown in Figs.
- circuit illustrated in Figs. 7 and 8 represent particular circuits. These and other forms of filter circuits, which doubly resonant crystal element may be utilized, are described in W. P. Mason application Serial No. 303,757, hereinbefore referred to. If desired, mutual inductance may be used between the end coils of the crystal filter to obtain improved attenuation characteristics as described in United States Patent No. 2,198,684, granted April 30, 1940, to R. A. Sykes.
- the electrode doubly resonant crystal elements of Figs. 4, 5 and 6 may be mounted in any suitable manner, such as by clamping or otherwise. Where the clamping form of mounting is used, one or more pairs such as four pairs of opposite conductive clamping projections may resiliently contact the electroded crystal element at or near its four corners only in order to support and to establish individual electrical connections therewith.
- the electroded crystal plate may be mounted and electrically connected by cementing or otherwise firmly attaching fine conductive supporting wires directly to a thickened part of the electrodes of the crystal element at or near its four corners only.
- Such fine supporting wires secured to the electrodcd crystal element may extend horizontally from the vertical disposed major surfaces of the crystal element, and at their other ends be attached by solder, for example, to vertical conductive wires or rods carried by the press or other part of an evacuated or sealed glass or metal tube.
- the supporting wires and rods may have one or more bends therein to resiliently absorb mechanical vibrations.
- bumpers or stops of soft resilient material such as mica may be spaced closely adjacent the edges, ends or other parts of the electroded crystal element in order to limit the bodily displacement thereof when the device is subjected to mechanical shock.
- Fig. 8 for example, of A. W. Ziegler United States Patent 2,275,122, granted March 3, 1942, on application Serial No. 338,871, filed June 5, 1940, illustrates a suitable mounting of this type for the crystal element, the horizontal supporting wires being spaced along the vertical rods to suit the comer spacing of the electroded crystal element. It will be understood that any holder which will give stability, substantial freedom from spurious frequencies and a, relatively high Q or reactance-resistance ratio for the crystal element may be utilized for mounting the crystal element.
- a high frequencysecond shear thickness mode piezoelectric Rochelle salt type crystal ele-' ment having its substantially square major surfaces substantially parallel to an X axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Z axis and the Y axis, the dimensional ratio of said X axis dimension of said major surfaces with respect to the thickness dimension between said major surfaces being one of the values between substantially 12 and 30, said thickness dimension .expressed in millimeters being one of the values between substantially 948 and 990 divided by the value of said frequency expressed in kilocycles per second.
- a high frequency second shear thickness mode piezoelectric Rochelle salt type crystal element having its substantially square major surfaces substantially parallel to a Y axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Z axis and the X axis, the dimensional ratio of said Y axis dimension of said major surfaces with respect to the thickness dimension between said major surfaces being one of the values between substantially l2 and 30, said thickness dimension expressed in millimeters being one of the values substantially from 1277 to 1330 divided by the value of said frequency expressed in kilocycles per second.
- a high frequency second shear thickness mode piezoelectric Rochelle salt type crystal element having its substantially square major surfaces substantially parallel to a Z axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect tothe Y axis and the X axis, the dimensional ratio'of said Z axis dimension of said major surfaces with respect to the thickness dimension between said major surfaces being one of the values between substantially 12 and 30, said thickness dimension expressed in millimeters being one of the values substantially from 1060 t 1107 divided by the value of said frequency expressed in kilocycles per second.
- a piezoelectric Rochelle salt type crystal element having its substantially rectangular major surfaces substantially parallel to one of the three mutually perpendicular X, Y and Z axes thereof, 'said major surfaces being inclined at an angle intermediate the other two of said three X, Y and Z axes, the dimensional ratio of the dimension of said major surfaces along said one of said X, Y and Z axes with respect to the thickness dimension between said major surfaces being one of the values between substantially 12 and 30, and means including a plurality of sets of functionally independent electrodes adjacent [said major surfaces for operating said element simultaneously at a plurality of independently controlled frequencies dependent upon said dimensions, one of said frequencies being dependent upon the second shear thickness mode vibration.
- a piezoelectric Rochelle salt type crystal element having its substantially rectangular major surfaces substantially parallel to one of the three mutually perpendicular X, Y and Z axes thereof, said major surfacesv being inclined at an angle of substantially 45 degrees with respect to the other two of said three X, Y and Z axes, the dimensional ratioof the dimension of said major surfaces along said one of said X, Y and Z axes with respect to the thickness dimension between said major surfaces being one of the values substantially in the region of from 10 to 5b, and
- means including a plurality of sets of functionally independent electrodes adjacent said major surfaces for operating said element simultaneously at a plurality of independently controlled frequencies dependent upon said dimensions, one of said frequencies being dependent upon the fundamental or first shear mode vibration along said thickness dimension, and another of said frequencies being dependent upon the second shear mode vibration along said thickness dimension.
- a piezoelectric Rochelle salt type crystal I element adapted to vibrate simultaneously at desired independently controlled first and second shear thickness mode frequencies dependent mainly upon the length dimension of and the thickness dimension between its substantially rectangular major surfaces, said length dimension being substantially parallel to an X axis, said major surfaces being inclined at an angle 'of substantially 45,degrees with respect to the Z axis, the ratio of said length dimension of said major surfaces with respect to said thickness dimension being one of the values within the region from substantially l2'to 30, said thickness dimension expressed in millimeters being one of the values from about 948 to 990v divided by the value of said second shear mode frequency expressed in kilocyclesl per second.
- a piezoelectric Rochelle salt type crystal element adapted to vibrate simultaneously at desired independently controlled first and second shear thickness mode frequencies dependent mainly upon the length dimension of and the .thickness dimensionv between its substantially rectangular major surfaces, said length dimension being substantially parallel to a Y axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Z axis, the ratio of said Y axis length dimension of said major surfaces with respect to said thickness dimension being one of the values within the region substantially from 12 to 30, said thickness dimension expressed in millimeters being one of the values substantially from 1277 to 1330 divided by the value of said second shear mode frequency expressed in kilocycles per second.
- a piezoelectric Rochelle salt type crystal element adapted to vibrate simultaneously at desired independently controlled first and second shear thickness mode frequencies dependent mainly upon the length dimension of and the thickness dimension between its substantially rectangular major surfaces, said length dimension being substantially parallel to a Z axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the if axis, the ratio of said axis length dimension of said major surfaces with respect to said.
- thickness dimension being one of the values within the region substantially from 12 to 30, said thickness dimension expressed in millimeters being one of the values substantially from 1060 to ill)? divided by the value of said second shear mode frequency expressed in kilocycles per second.
- a piezoelectric Rochelle salt type crystal element adapted to vibrate simultaneously at independently controlled first and second shear thickness mode frequencies dependent mainly upon its length and thickness dimensions, said length dimension of the major surfaces being substantially parallel to an X axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Z axis, said major surfaces being substantially square, the ratio of said X axis length dimension of said major surfaces with respect to said thickness dimension being one of the values within the range from substantially 12 to 30, said thickness dimension and said X axis length dimension being a set of corresponding values in accordance with the values of said first shear and second shear frequencies.
- a piezoelectric Rochelle salt type crystal element adapted --to vibrate simultaneously at desired independently controlled first and second shear thickness mode frequencies dependent mainly upon its length and thickness dimensions, said length dimension 'of the major surfaces being substantially parallel to a Y axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Z axis, said major surfaces being substantially square, the ratio of said Y axis length dimension of said major surfaces with respect to said thickness dimension being one of the values within the range from substantially 12 to 30, said thickness dimension and said Y axis length dimension being a set of corresponding values in accordance with the values of said first shear and second shear frequencies.
- a piezoelectric'Rochelle salt type crystal element adapted to vibrate simultaneously at desired independently controlled first and second shear thickness mode frequencies dependent mainly upon its length and thickness dimensions
- said length dimension of the major surfaces being substantially parallel to a Z axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Y axis, said major surfaces being substantially square, the ratio of said Z axis length dimension of said major surfaces with respect to said thickness dimension being one of the values within the range from substantially 12 to 30, said thickness dimensionand said Z axis length dimension being a set of corresponding values in accordance with the values of said first shear and second shear frequencies.
- a Rochelle salt type piez'oelectric crystal element adapted to vibrate at a desired second shear thickness mode frequency, said crystal element having substantially rectangular shaped major surfaces, said major surfaces having a.
- said thickness dimension and said length dimension being made of values in accordance with the value of said desired second shear frequency
- said major surfaces and said length dimension being substantially parallel to an X axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Z axis
- said thickness dimension expressed in millimeters being one of the values substantially from 948 to 990 divided by said desired frequency expressed in kilocycles per second
- the ratio of said X axis length dimension with respect to said thickness dimension being one of the values substantially from 30 to l2
- said thickness dimension and said dimensional ratio being corresponding values in accordance with the value of said frequency, as given by the curve B of Fig. 9.
- a Rochelle salt type piezoelectric crystal element adapted to vibrate at a desired second shear thickness mode frequency, said crystal element having substantially rectangular shaped major surfaces, said major surfaces having a length dimension and a thickness or thin dimension therebetween, said thickness dimension and said length dimension being made of values in accordance with the value of said desired second shear frequency, said major surfaces and said length dimension being substantially parallel to a Y axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Z axis, said thickness dimension expressed in millimeters being one of the values substantially from 1277 to 1330 divided by said desired frequency expressed in kilocycles per second, and the ratio of said Y axis length dimension with respect to said thickness dimension being one of the values substantially from 12 to 30, said thickness dimension and said dimensional ratio being corresponding values in accordance with the value of said frequency.
- a Rochelle salt type piezoelectric crystal element adapted to vibrate at a desired second shear thickness mode frequency, said crystal element having substantially rectangular shaped major surfaces, said major surfaces having a length dimension and a thickness or thin dimension therebetween, said thickness dimension and said length dimension being made of values in accordance with the value of said desired second shear frequency, said major surfaces and said length dimension being substantially parallel to a Z axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Y axis, said thickness dimension expressed in millimeters being one of the values substantially from 1060 to 1107 divided by said desired frequency expressed in kilocycles per second, and the ratio of said Z axis length dimension with respect to said thickness dimension being one of the values substantially from 12 to 30, said thickness dimension and said dimensional ratio being corresponding values in accordance with the value of said frequency.
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Acoustics & Sound (AREA)
- Piezo-Electric Or Mechanical Vibrators, Or Delay Or Filter Circuits (AREA)
Description
Dec. 1, 1942. w. P. MASON 2,393,375
ROCHELLE SALT PIEZOELEC TRIC CRYSTAL APPARATUS Filed June 10, 1941 3 Sheets-Sheet 1 /NVEN7'0R W R MASON A TTORNE V Dec. 1, 1942. w p MASON 2,303,375
ROCHELLE SALT PIEZOELECTRIC CRYS TAL APPARATUS Filed June 10, 1941 3 Sheets-Sheet 2 FIG. 7 FIG. 8
7 /0\ I /o ,4 /2 [7 v/s T F IG. .9
/0 II l2 I! I4 I5 I617 I6 I9 202/ 22 28242528 272! 2980 RATIO, X AXIS LENGTH L DIMENSION T0 Y AXIS THICKNESS 7' DIMENSION lNl/ENTOR W P. MASON A TTORNE) 1942- w. P. MASON 2,303,375
ROCHELLE SALT PIEZOELECTRIC CRYSTAL APPARATUS Filed June 10, 1941 3 Sheets-Sheet 3 FIG. I0
I Z 1.120 L ous" SECOND SHEAR MODE IJIO X SHEAR M005 FREQUENCY IIV KILOCYCLES PER SECOND PER MILL/METER 0F THICKNESS T 1o 11 12 1.1 14 '15 1a 17 1a .19 2a 21 22 2a 24 2s 2s 27 2a 29 30 T10 r 4x1: 1:11am I. DIMENSION 70 7111001255 1 mums/01v RATIO Z AXIS LENGTH L DIMENSION T0 THICKNESS T DIMENSION mum/r01? W P MASON A TTORNEY' Patented Dec. 1, 1942 ROCHELLE SALT PIEZOELECTRIC QRYSTAL APPARATUS Warren P. Mason, West Orange, N. J., assignor to Bell Telephone Laboratories, Incorporated, New York, N. Y., a corporation of New York Application june 10, 1941, Serial No. 397,377
14 Claims. (01. 171-327) This invention relates to piezoelectric crystal apparatus and particularly to high frequency piezoelectric Rochelle salt or sodium potassium tartrate crystal elements suitable for use as cir-' cuit elements in electric wave filter systems and oscillator systems, for example.
One of the objects of this invention is to provide a Rochelle salt piezoelectric crystal element having one or more useful high frequency or thickness modes of motion that may be utilized alone or simultaneously without interference with other modes of motion therein.
Another object of this invention is to provide a Rochelle salt crystal element having a plurality of simultaneously useful and independently controlled thickness mode frequencies.
Another object of this invention is to provide Rochelle salt crystal elements utilizing either the first shear thickness mode of motion thereof or the second shear thickness mode of motion thereof.
Another object of this invention is to reduce the number and the cost of. crystals used in high frequency electric wave filter systems and other wave transmission networks, and 'to take advantage of the high piezoelectric activity and low cost of Rochelle salt.
Rochelle salt piezoelectric crystal elements generally may be excited in many different modes of motion such as extensional or longitudinal modes of motion, fiexural modes of motion, and shear modes of motion, for example. When crystals are to be applied to filter systems, for example, it is generally desirable to have all of the undesired or extraneous modes of motion therein uncoupled with and considerably higher, or lower in frequency than the desired main mode or modes of motion of the crystal element since otherwise the extraneous resonance frequencies therein may introduce undesirable frequencies or pass bands in the filter characteristics. Accordingly, it is often desirable in filter systems and elsewhere that the desired main mode or modes of motion-of a crystal element be substantially independent of other modes of motion and independently controlled in order that such desired mode or modes of motion-may be given any desired frequencyyalues to obtain prescribed frequency characteristics.
In accordance with this invention, wave filters and other systems may comprise as a component provide either separately or simultaneously useful effective resonances which may be independently controlled andplaced-at predetermined frequencies of nearly the same value or of difierent values, for use in an electric wavefilter, or elsewhere. 1 Y
The crystal element may be a Rochelle salt a type crystal plate of suitabl orientation with respect to the X, Y and Z axes thereof, and of suitable dimensional proportions, and provided with a suitable electrode arrangement and connections for separately driving either or simultaneously driving both of two thickness modes of motion therein, and independently controlling the relative strengths of such resonances.
In particular embodiments, the orientation of the Rochelle salt crystal element may be such element thereof, a single piezoelectric crystal element of Rochelle salt which maybe adapted to vibrate simultaneously. in a plurality of high frequency or thickness modes of motion in order to that one of the major surface dimensions thereof, such as the length dimension, lies along one of the X, Y and Z axes thereof, and the other dimension, such as the width dimension of the.
major surfaces, is rotated in eflect a selected angle in degrees to a position intermediate or midway between the other two of the X, Y and Z axes. The major surfaces may be of rectangular or square shape. The frequency-determining thickness dimension between the major surfaces of the crystal element and the length dimension thereof may be'made of selected and related values, as a dimensional ratio of the length dimension with respect ,to the thickness dimension in the region from 10 to 50, in order -to obtain therefrom, separately or simultaneously, either or both of two useful independently controlled resonant frequencies resulting from two independently controlled thickness modes of motion, one particular set of which is described herein as the fundamental or first shear thickness mode of 'motion and the other as the second shear thickness mode of motion. Both the first and second shear mode frequencies are controlled mainly by the thickness dimension of the'crystal element andvary inversely as the value of the thickness dimension of the crystal element.
The Rochelle salt crystal elements described herein may have the same or similar orientations as those described in my United States Patent 2,178,146, dated October 31, 1939, but herein they are adapted for a plurality of thickness mode ,vibrations of the shear type including the first shear and also the second shear modes of motion. 4 Such Rochelle salt crystal'elements when provided with suitable electrodes may be connected into a filter circuit'in sucha way that one of the resonances of each crystal element is effective asosevs n. the line branch another of such resonances agonal branch of the lattice of the elect network thereof, in to obtain filter circuits using a single other crystal which are electrically equivalent to circuits requiring two crystals, thereby reducing the and cost numb er Rochelle example stiuctu' of crystals therein. Such elements may be utilized for on my application er ll), 15339, one. in
1, o granted Marc 3i, on application Tole. seas-es, filed December i) 1on9 no- By using two oi su salt crystal elements systems rat .e is inez-ipensively cons several million igher values of in the pass temperature he higher values filters us'sg the vibrat o ob'ain cha'l'acteris obtained when usin cycles per control c te have temperature ntigi de to hold th 'equency.
o ory Rochelle 1 .def 1113613 or for without change in the a long period of characteristics ther For a clearer not 1 this ention and the additional advantages, feat :es and objects t reference made en connection gs, in which like like or similar with the accompan reference characters represent parts and in which: I
l, 2 and 3 are perspective views of three forms of piezoelectric Ro helle salt crystal elements in accordance with this invention, and respwtively illustrate particularly the orientation thereof with respect to the and Z axes of the nding of the nature of Rochelle salt crystal material from which the 7 crystal elements be cut:
Figs. l to 8 are views illustrating types of electrodes and connections which may be utilized with any of the Rochelle salt crystal elements of Fig. l, 2 or 3 to drive the crystal element sepa rately in either, or simultaneously in both, of two independent shear thickness modes of motion, in order to obtain the desired resonance frequency Or frequencies;
Fig. 4 is a perspective view of an electrode arrangement that may be used to driveany or the piezoelectric crystal elements of Fig. 1, 2 or 3 in the fundamental or first shear thickness mode of motion; I
Figsj5 and 6 are perspective views of electrode arrangements that may be used to drive any of the crystal elements of Fig. 1, 2 or '3 in the second shear thickness mode of motion and the fundamental or first shear thickness mode of motion, separately or simultaneously;
Fig. '7 is a schematic diagram illustrating an example of balanced filter connections that may be used with the crystal element electrodes oi Fig. 8 is a schematic diagram illustrating an example of unbalanced n or connections that may be used with the electrodes of the crystal element of Fig. 6;
9 is a graph illustrating the thickness mode frequency-dimension constants of the fundamental or first shear mode of motion and of the second shear mode of motion in the Rochelle salt crystal element illustrated in Fig. 1 having a dimensional ratio of its X axis length L with respect to its thickness '1 in the region from 12 to 30.
Figs. 10 and 11 are graphs illustrating the thickness-mode i *equency-dimcnsion constants of the first and second shear mode vibrations of the Rochelle salt crystal elements illustrated in Figs. 2 and 3 respectively, for ratios of the length L with respect to the thickness T in the region from about 12 to 30.
This specification follows the conventional terminology as applied to crystalline Rochelle salt, which employs three orthogonal. or mutually perpendicular h and c axes or X. Y and axes, respectively, as shown in the drawings, to desigan electric axis, a mechanical axis and the optic axis, respectively, of piezoelectric Rochelle salt or sodium potassium tartrate crystal material, and which employs three orthogonal. axes X, Y and Z to designate the directions of axes of a piezoelectric body singularly oriented with respect to such X, Y and 23 axes thereof. Where the orientation is obtained in effect by a single rotation of the Rochelle salt crystal element, the rotation being in effect substantially about the length dimension axis X, :7 or Z of the piezoelectric body as illustrated in Figs. 1, 2 and 3, respectively, the orientation an les, respectively s=substantially degrees, 6:45 degrees, and
=45 degrees designate in degrees the effective angular position oi the width axis dimension W of the crystal plate as measured from one of the other two of the X, Y and Z axes. The relation of ie X, Y and Z axes to the outer of a grown. Rochelle salt crystal body are illustrated in W. P. Mason United States Patent 2,178,146, dated October 31, 1939. Rochelle salt belongs to the rhombic hemihedral class of crystals and has three orthogonal or mutually perpendicular axes generally designated as the h, and c axes or the X, Y and Z axes, respectively.
Referring to the drawings, Figs. 1, represent perspective views of thin bare piezoelectric Rochelle salt crystal elements l, 2 and 3 out from crystalline Rochelle salt free from defects and made into a plate of substantially rectangular parallelepiped shape with its major surfaces having a length dimension L, and a width dimension W which is perpendicular to and may be equal to or longer or shorter than the length dimension L. The frequency-determining thickness or thin dimension T between the major surfaces is perpendicular to the other two dimensions L and W. In accordance with the particular orientation and mode or modes of motion selected, the final width dimension W or length dimension L of the Rochelle salt crystal element I, 2 or 3 of Figs. 1, 2 and 3 may be made of a, suitable value with respect to the thickness dimension T according to the desired resonant frequency. The width dimension W also may be equal to or otherwise related to the length dimension L to remove spurious frequencies from the region of the desired resonant frequency. The thickness dimension T may be of the order 2 and 3 of 1 millimeter more or less and made ofany suitablevalue to obtain the desired thickness mode frequency or frequencies for the crystal element I, 2 or 3 of Figs. 1, 2 and 3.
As shown in Fig. 1, the length dimension L of the Rochelle salt crystal elementgl illustrated in Fig. 1 lies substantially along or parallel to the X axis, the X axis being perpendicular to the plane of the mechanical axis Y and the optic axis Z of the Rochelle salt crystal material from which the element I is cut. The width dimension W which is perpendicular to the length dimension L, is inclined at an angle of a degrees with respect to said Z axis, the angle a being one of the values inthe region of substantially 45 degrees (45). The major surfaces and the major plane of the Rochelle salt crystal element I are disposed parallel or nearly parallel with respect to the X axis, the length dimension L and the width dimension W lying along the X axis and the Z axis, respectively, the Z axis being inclined at the angle a with respect to the optic axis Z. The axis Z is accordingly the result of a single rotation of the width dimension W about the X axis degrees. It will be noted that the crystal element I of Fig. l is in effect a Y-cut Rochelle salt crystal plate rotated at degrees about the X axis.
Fig. 2 is a perspective view of a Rochelle salt piezoelectric crystal element 2 having its length dimension L along or parallel to the Y axis and its width dimension W inclined at an angle of 0=substantially 45 degrees with respect to the Z axis, the major surfaces of the crystal element 2 being parallel or nearly parallel to the Y axis.
Fig. 3 represents a Rochelle salt crystal element 3 having its length dimension L along or parallel to the Z axis and its width dimension W inclined at an angle which may be any angle in the region of'45 degrees intermediate the X and -Y axes, the major surfaces of the crystal element 3 being parallel or nearly parallel to the Z axis.
The orientations illustrated in Figs. 1, 2 and 3 represent Rochelle salt piezoelectric crystal ele-, ments I, 2 and 3, respectively, which may be adapted for a plurality of independently controlled thickness mode vibrations of the shear motion type, which may be utilized either alone or simultaneously, according to the arrangement of the electrodes and connections that are used therewith, and the dimension-frequency constants that are selected therefor.
Suitable conductive electrodes, such as the crystal electrodes of Fig. 4, 5 or 6, for example,v may be placed on or adjacent to or formed integral with the opposite major surfaces of the crystal plate I, 2 or 3 of Fig. 1, 2 or 3 in order illustrated in Fig. 1, or 0==substantially degrees with respect to the Z axis as illustrated in Fig. 2, or =substantially 45 degrees with respect to the Y axis, asillustrated in Fig. 3, the thickness T shear mode vibrations comprising the first shear mode of motion and the second shear mode of motion in the crystal plate may be used simultaneously,
To obtain the two thickness shear type modes of motion simultaneously, it is necessary that the crystal element have apiezoelectric' constant which will generate a first shear motion along the thickness dimension T and also a piezoelectric constant that will generate a second shear motion along the thicknessdimension T.
In the case of the Rochelle salt crystal element I illustrated in Fig. l, the requirement of suitable piezoelectric constants may be met when the width dimension W or the length dimension L is inclined at any suitable angle win the region to apply electric field excitation to the Rochelle salt plate. I, 2 or 3 which may be vibrated alone or simultaneously in the desired thickness T fundamental or first shear mode of motion and/or the thickness T second shear mode of motion at independently controlled resonant response. frequencies which depend upon dimensions involving the thickness dimension T and i also the width dimension W or the length dimension L, the fundamental shear thickness mode frequencies for the three cuts of Figs. 1,- 2 and 3 being values roughly ranging from about 940 to 1272 kilocycles per second'per millimeter of the thickness dimension T and varying inversely as the value of the thickness dimension T.
of 45 degrees between the Y and Z axes of the YZ plane, the X axis being parallel or nearly parallel to the major planeand the major surfaces of the Rochelle salt crystal element i of Fig. 1. Reference is made to my paper A dynamic measurement of the elastic, electric and piezoelectric constants of Rochelle salt published April 15, 1939, in Physical Review, volume 55, page 775, for information on the piezoelectric constants involved in shear mode vibrations along the thickness dimension T of Rochelle'salt crystal elements. The shear mode piezoelectric constants reach their maximum values when the angle 11:45 degrees or when the plane formed by the width dimension W and the length dimen sion L of the Rochelle salt crystal element I of Fig. l is inclined at an angle of 45 degrees with respect to the Y and Z axes thereof, the major plane and major surfaces thereof being perpendicular or nearly perpendicular to the plane of such Y and Z axes.
While the maximum values of the thickness shear mode piezoelectric constants occur when the angle =45, the angles of a in the region of 45 degrees are near enough thereto obtain good values of piezoelectric constants for the first and second shear thickness modes of motion. Such Rochelle salt crystal elements I of- Fig. 1 havean electromechanical coupling which varies with temperature change, and are easily driven by" 45 degrees with respect to the Z axis and the X axis also may be used as a doubly resonant crystal element. Such an element has an electromechanical coupling that does not vary much in "fig. o e n nearly parallel to the e-Xis also may l e used to g a nerate thickness mode firt J vibrations of the k nd useful for a crystal e'len n' then the s soon *he lie 1 o. near mo uaviug the orienor 3 "may conto r b.0113 illustrated oiled by the value or t dii "nd the dimension ng 't' th re 111i d sion co ouencies ely the second sheer indanientai or first motio c with respect to the vmclrness dimer sion T is in a region and in this region the resonances of these two modes are substantially uncoupled. sir-only very loosely coupled.
Accordingly, when the dimensional ratio of the length L and the width W with respect to the thickness T is in the proper region, and the crystal orientation is that of Fig. l, 2 or 3, the frequencies of these two independent modes of vibration may be placed close together but sufliciently uncoupled or separated to provide simultaneously two independently controlled frequencies from the same Rochelle salt crystal element, which may be usefully employed in a filter system I mental shear thic for example, to give conveniently two useful frewhen used c. A
7 ow -r1) n where L is the value or? the X axis length dimension and T is the value of the thickness dimension of the crystal element l of Fig. 1 expressed in millimeters.
The second shear expressed in iilliJCyC l' crystal plate l of .L. square. major surfaces i mentally determined relation:
end
; iii."
e rreduency of 1e cry any number of in frequen 3. than oi hiclrness mode frequency, and er stern, one resonance fro i one arm, and the other ,ency the other so that a we attenuation peaks can he made from one crystal. Similarly, the first shear and the second shear thickness anode quencies of the crys elements 2 and 3 may be utilized.
The grenh oi. illustrates the measured resonanc Ireouencies associated with the funda mental or first shear thickness mode oi ion (curve A) and also those associated with. the t end shear thickness node of motion (curve 33'), in a Rochelle c1 tal element cving square or nearly square major surfaces orientation angl of suostantially as degrees as illus trated i. g. 1. In Figv the funds.
ess mode i esented by the gen lly horizo .l. wardly sloping curve A and has e. frequenc dimension constant of 94C to Q50 lrilocycles per second per millimeter of thickness dimen sion 1'' which is dependent but little upon the dimensional ratio of the X axis length L with respect to the Y axis thickness T. The second overtone shear thickness mode frequency is represented by the downwardly sloping inclined curve B and has a frequency-dimension constant from about 945 to 990 kilocycles per second per millimeter of thickness dimension T dependent upon the value of the selected dimensional ratio of the X axis length dimension L with respect to the thickness dimension T within the dimensional ratio range from about 12 to 30, the frequency constant values gradually decreasing with increasing values for the dimensional ratio. As shown by the curves A and B of Fig. 9, the freselected the IZZY fir quency' in resonance freo quency of the second shear mode of motion and by the curves of Figs. and 11, similar in form' to the downwardly sloping first and second shear mode curves A and B of Fig. 9 for. the crystal element l of Fig. 1 but are somewhat higher in frequency thanthe first and second shear mode frequencies of the crystal element I of Figs. 1 and 9 for a given dimensional ratio of the length L or the width W with respect to the thickness T.
The thickness mode frequency-dimension constants for thedsecond shear thickness mode of motion in the Rochelle salt crystal element 2 of Fig.2 are roughly from 1277 to 1330 kilocycles per second per millimeter of the thickness dimension T within a range of dimensional ratios of the length L and width W with respect to the thickness T from about 12 to 30, the frequency constant values gradually decreasing with increasing values for the dimensional ratio as illustrated by the downwardly sloping curve B of Fig. 10; and the frequency-dimension constants for the second shear thickness mode of motion in the Rochelle salt crystal element 3 of Fig. 3 are, as illustrated .by theclownwardly sloping curve B" of Fig. 11, roughly from 1060 to 1107 kilocycles per second per millimeter of the thickness dimension T within a range of dimensional ratios of the length L and width W with respect to the thickness T from about 12 to 30, the corresponding curves for such second shear mode frequencies of the crystal element 2 of Fig. 2 and for the crystal element 3 of Fig. 3 being similar in form as hereinbefore stated to the downwardly sloping second shear modecurve B of Fig. 9 but somewhat higher in frequency, for a given dimensional ratio, the frequency constant values gradually decreasing with increasing values for the dimensional ratio in accord ance with the form of the downwardly sloping curve B of Fig. 9.
The thickness mode frequency-dimension constants for the fundamental or first shear mode of motion are somewhat lower than those given above for the second shear mode of motion; and as illustrated by the curves A, A and A" 9, 10 and 11 for the Rochelle salt crystal elements l, 2 and 3 of Figs. 1, 2 and 3 are respectively, expressed in kilocycles per second, about from 942.5 to 948, from 1265 to 1272 and from 1052 to 1060, respectively, for dimensional ratios of the length L and width W with respect to the thickness T in the range about from 12 to 30, the frequency constant values gradually decreasing with increasing values for the dimensional ratio in accordance with the form of the slightly downwardly sloping curve B of Fig. 9.
Accordingly, it will be understood that the curves for the first and second shear mode frequencies givenin Fig. 9 for the crystal element 1 of Fig. 1 also apply to the crystal elements 2 and 3 of Figs. 2 and 3 using the same length to thickness dimensional ratio values of Fig. 9 but changing the ordinate values thereof to correspond with the limiting ranges of the frequency constant such shear thickness mode resonance frequencies of a desired value.
In Fig. 4 which is a perspective view of the Rochelle salt crystal element of Fig. 1, 2 or 3, the pair of opposite electrodes 9 and I5 may be utilized to usefully operate separately in the crystal element I, 2 or 3 of Figs. 1 to 3, the fundamental or any odd order harmonic thickness shear mode of motion, the fundamental frequency being roughly one of the values from about 942 to 1272 kilocycles per second per millimeter of thickness dimension T, dependent upon the orientation selected. The electrodes 9 and I5 may partially or wholly cover the major surfaces of the crystal element I, 2 or 3 and may be connected in circuit by a conductive member disposed in contact with each of the electrodes 9 and I5 at or near the corners thereof. It will be understood that Rochelle salt crystal elements having the orientations illustrated in Figs. 1, 2 and 3 and provided with electrodes of the type illustrated in Fig. 4 may be utilized to obtain a desired fundamental or odd order harmonic shear mode vibrational frequency that is dependent substantially upon the thickness dimension T. Where a harmonic of such fundamental shear mode of motion is used, the harmonic frequency may be values hereinbefore given for such frequencies. I
Figs. 4, 5 and 6 illustrate forms'of electrode arrangements which may be utilized to drive any of the crystal elements of Fig. 1, 2 or 3. In Fig. 4, the single pair of electrodes 9 and I 5 may be used to drive either the thickness T shear fundamental mode of motion or any odd harmonic such as third, fifth, etc., harmonic thereof to obtainseparately but not simultaneously any of -of any desired odd order and may be obtained by the use of electrode-arrangement shown in Fig. 4.
As shown in Fig. 5, the second shear thickness mode of motion may be driven by means of two pairs of divided electrodes H), II, l2 and I3 placed on both of the major surfaces of the crystal element of Fig. 1, 2 or 3; and with suit able connections, the fundamental or first shear mode of motion may be driven at the same time by one of the connected sets of electrode platings, with the result that the two useful andindependently controlled thickness mode resonance frequencies of the crystal element L2 'or 3 may be made to appear simultaneously. As illustrated in Fig. 5, the Rochelle salt crystal element I, 2 or 3 of Fig. 1, 2 or 3 may be provided with four equal area electrodes I 0, ll, l2 and I3, two
of the electrodes l0 and H being placed on one major surface of the crystal element with a centrally located narrow transverse split or gap 1 therebetween, and the other two electrodes l2 and I3, being oppositely disposed and placed on the opposite major surface of the crystal element and separated with a similar narrow and oppositely disposed split or dividing line 1 therebetween, the dividing lines 1 extending generally in the direction of the width W axis of the crystal element, according to the value of the angle selected between the direction of the dividing line I and the direction of the length. dimension L. The gap or separation 1 between the electrode coatings or platings on each of the major surfaces of the crystal element may be of the order of about 0.3 millimeter, the center line of such splits in the platings on the opposite sides of the crystal plate I being aligned with respect to each other.
When the electrode plates have the same sign across the Whole surface of the major surface, the fundamental thickness shear vibration of the crystal element is excited; and when the electrode plates have opposite signs on'the same major surface of the crystal element, the second thickness shear mode vibration, corresponding to the fundamental shear mode for a crystal plate half as long as the length L of the original crystal element, is excited, the second shear orancii oi the equivalent late diagonal branch there- *ully in connection with i and 3 application, Serial ,lli'? referred to hereinceiore. oe balanced circuit of Fig. 5' may be con" ted into an unbalanced filter structure by inectirlg the t o electrodes '3? and on no major 5 aces of the crystal element. his case, the two electrodes and of Figs. nay be replaced by a single electrode i5 ay be connected. as shown 8 and as described more n with Figs. 6 and '7 of the Serial No. 303,757 hereinbefully in. comic Mason applies. lore referred to.
As illustrated in Fig. 8 to reduce the magnitude of the shunting capacitance appearing in the line branch of the lattice portion, a narrow grounding strip i i of metallic or conductive coating or plating may be placed on one major surface of the crystal element between the electrodes if and The strip l4 may extend around one edge of the crystal element to the opposite major suriace thereof where it may be.
electrically connected to the large electrode IS. The ground strip is may be approximately 1 millimeter in width and may be placed between and separated from the two electrodes Ill and H on the same major surface of the crystal element 1, in order to provide shielding and to reduce stray capacities to a minimum. The strip of plating 14 may extend from one major surface continuously over and around one edge only or both edges of the crystal plate I to the opposite major face thereof where it may make contact with the integral electrode 15 on that surface.
It will be noted that in order to drive the electroded crystal element of Fig. 6 in the second shear thickness mode of motion, one-half ofthe crystal plate I is made of opposite polarity to that of the other half, as indicated by the and signs in Fig. 6, and that this may be accomplished by utilizing a crystal element having divided metallic coatings l0 and l!.placed on one of its major surfaces and connected in the form of a T network, for example, as illustrated in Fig. 8. Inductance coils may be added in the usual manner in series or in parallel with the network of Fig. 8 to produce broad band low or high impedance filters for example. In order that the crystal impedance may appear in both arms of the lattice structure of Fig. 8, one mode is driven when the terminals 2| and 23 are both of same polarity, and the other mode is driven when these terminals 2| and 23 are of opposite polarity. Since both modes are substantially uncoupled or independent, they may produce simultaneously two independently controlled resonances of predetermined frequencies of desired values.
ce uencies, one of which may and the electroded crystal in order to control the relative impedance levels of the two desired. crystal resonances, the crystal electrodes associated with one half of the major suriace or surfaces of crystal element l, 2 or 3 of Figs. 5 and 6 may be extended to cover a portion of the other half thereof. This may be done, for example, by adjustment of the position of the electrode dividing line angle with respect to the length dimension L. The angle may be any desired value over a wide range of angles. This adjustment does not materially affect the impedance of the first shear mode resonance, but with decreasing values for the SO-degree' angle shown in Figs. 5 and 6, will increase the im pedance level and cut down the drive on second shear mode resonance, without materially affooting the impedance of the first shear modc resonance. Thus, by changing the angle of inclination of the split or division line I between the electrodes and i l with respect to the length dimension L of the crystal element, illustrated by the QO-degree angle in Figs. 5 and 6, the internalcepacity associated with the second shear mode resonance, which is nearly a maximum value when the angle equals degrees as shown in Figs. and 6, may be varied and adjusted to a desired value without changing the internal capacity associated with the first shear mode resonance.
It will be understood that the circuit illustrated in Figs. 7 and 8 represent particular circuits. These and other forms of filter circuits, which doubly resonant crystal element may be utilized, are described in W. P. Mason application Serial No. 303,757, hereinbefore referred to. If desired, mutual inductance may be used between the end coils of the crystal filter to obtain improved attenuation characteristics as described in United States Patent No. 2,198,684, granted April 30, 1940, to R. A. Sykes.
The electrode doubly resonant crystal elements of Figs. 4, 5 and 6 may be mounted in any suitable manner, such as by clamping or otherwise. Where the clamping form of mounting is used, one or more pairs such as four pairs of opposite conductive clamping projections may resiliently contact the electroded crystal element at or near its four corners only in order to support and to establish individual electrical connections therewith.
Alternatively, instead of being mounted by clamping, the electroded crystal plate may be mounted and electrically connected by cementing or otherwise firmly attaching fine conductive supporting wires directly to a thickened part of the electrodes of the crystal element at or near its four corners only. Such fine supporting wires secured to the electrodcd crystal element may extend horizontally from the vertical disposed major surfaces of the crystal element, and at their other ends be attached by solder, for example, to vertical conductive wires or rods carried by the press or other part of an evacuated or sealed glass or metal tube. The supporting wires and rods may have one or more bends therein to resiliently absorb mechanical vibrations. Also, bumpers or stops of soft resilient material such as mica may be spaced closely adjacent the edges, ends or other parts of the electroded crystal element in order to limit the bodily displacement thereof when the device is subjected to mechanical shock. Fig. 8, for example, of A. W. Ziegler United States Patent 2,275,122, granted March 3, 1942, on application Serial No. 338,871, filed June 5, 1940, illustrates a suitable mounting of this type for the crystal element, the horizontal supporting wires being spaced along the vertical rods to suit the comer spacing of the electroded crystal element. It will be understood that any holder which will give stability, substantial freedom from spurious frequencies and a, relatively high Q or reactance-resistance ratio for the crystal element may be utilized for mounting the crystal element.
Although this invention had been described and illustrated in relation to specific arrangements, it is to be understood that it is capable of application in other organizations and is, therefore, not to be limited "to the particular embodiments disclosed, but only by the scope of the appended claims and the state of the prior art.
What is claimed is:
1. A high frequencysecond shear thickness mode piezoelectric Rochelle salt type crystal ele-' ment having its substantially square major surfaces substantially parallel to an X axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Z axis and the Y axis, the dimensional ratio of said X axis dimension of said major surfaces with respect to the thickness dimension between said major surfaces being one of the values between substantially 12 and 30, said thickness dimension .expressed in millimeters being one of the values between substantially 948 and 990 divided by the value of said frequency expressed in kilocycles per second.
2. A high frequency second shear thickness mode piezoelectric Rochelle salt type crystal element having its substantially square major surfaces substantially parallel to a Y axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Z axis and the X axis, the dimensional ratio of said Y axis dimension of said major surfaces with respect to the thickness dimension between said major surfaces being one of the values between substantially l2 and 30, said thickness dimension expressed in millimeters being one of the values substantially from 1277 to 1330 divided by the value of said frequency expressed in kilocycles per second.
3. A high frequency second shear thickness mode piezoelectric Rochelle salt type crystal element having its substantially square major surfaces substantially parallel to a Z axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect tothe Y axis and the X axis, the dimensional ratio'of said Z axis dimension of said major surfaces with respect to the thickness dimension between said major surfaces being one of the values between substantially 12 and 30, said thickness dimension expressed in millimeters being one of the values substantially from 1060 t 1107 divided by the value of said frequency expressed in kilocycles per second.
4. A piezoelectric Rochelle salt type crystal element having its substantially rectangular major surfaces substantially parallel to one of the three mutually perpendicular X, Y and Z axes thereof, 'said major surfaces being inclined at an angle intermediate the other two of said three X, Y and Z axes, the dimensional ratio of the dimension of said major surfaces along said one of said X, Y and Z axes with respect to the thickness dimension between said major surfaces being one of the values between substantially 12 and 30, and means including a plurality of sets of functionally independent electrodes adjacent [said major surfaces for operating said element simultaneously at a plurality of independently controlled frequencies dependent upon said dimensions, one of said frequencies being dependent upon the second shear thickness mode vibration. 1
5. A piezoelectric Rochelle salt type crystal element having its substantially rectangular major surfaces substantially parallel to one of the three mutually perpendicular X, Y and Z axes thereof, said major surfacesv being inclined at an angle of substantially 45 degrees with respect to the other two of said three X, Y and Z axes, the dimensional ratioof the dimension of said major surfaces along said one of said X, Y and Z axes with respect to the thickness dimension between said major surfaces being one of the values substantially in the region of from 10 to 5b, and
means including a plurality of sets of functionally independent electrodes adjacent said major surfaces for operating said element simultaneously at a plurality of independently controlled frequencies dependent upon said dimensions, one of said frequencies being dependent upon the fundamental or first shear mode vibration along said thickness dimension, and another of said frequencies being dependent upon the second shear mode vibration along said thickness dimension.
6. A piezoelectric Rochelle salt type crystal I element adapted to vibrate simultaneously at desired independently controlled first and second shear thickness mode frequencies dependent mainly upon the length dimension of and the thickness dimension between its substantially rectangular major surfaces, said length dimension being substantially parallel to an X axis, said major surfaces being inclined at an angle 'of substantially 45,degrees with respect to the Z axis, the ratio of said length dimension of said major surfaces with respect to said thickness dimension being one of the values within the region from substantially l2'to 30, said thickness dimension expressed in millimeters being one of the values from about 948 to 990v divided by the value of said second shear mode frequency expressed in kilocyclesl per second.
'7. A piezoelectric Rochelle salt type crystal element adapted to vibrate simultaneously at desired independently controlled first and second shear thickness mode frequencies dependent mainly upon the length dimension of and the .thickness dimensionv between its substantially rectangular major surfaces, said length dimension being substantially parallel to a Y axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Z axis, the ratio of said Y axis length dimension of said major surfaces with respect to said thickness dimension being one of the values within the region substantially from 12 to 30, said thickness dimension expressed in millimeters being one of the values substantially from 1277 to 1330 divided by the value of said second shear mode frequency expressed in kilocycles per second.
8. A piezoelectric Rochelle salt type crystal element adapted to vibrate simultaneously at desired independently controlled first and second shear thickness mode frequencies dependent mainly upon the length dimension of and the thickness dimension between its substantially rectangular major surfaces, said length dimension being substantially parallel to a Z axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the if axis, the ratio of said axis length dimension of said major surfaces with respect to said. thickness dimension being one of the values within the region substantially from 12 to 30, said thickness dimension expressed in millimeters being one of the values substantially from 1060 to ill)? divided by the value of said second shear mode frequency expressed in kilocycles per second.
9. A piezoelectric Rochelle salt type crystal element adapted to vibrate simultaneously at independently controlled first and second shear thickness mode frequencies dependent mainly upon its length and thickness dimensions, said length dimension of the major surfaces being substantially parallel to an X axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Z axis, said major surfaces being substantially square, the ratio of said X axis length dimension of said major surfaces with respect to said thickness dimension being one of the values within the range from substantially 12 to 30, said thickness dimension and said X axis length dimension being a set of corresponding values in accordance with the values of said first shear and second shear frequencies.
10. A piezoelectric Rochelle salt type crystal element adapted --to vibrate simultaneously at desired independently controlled first and second shear thickness mode frequencies dependent mainly upon its length and thickness dimensions, said length dimension 'of the major surfaces being substantially parallel to a Y axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Z axis, said major surfaces being substantially square, the ratio of said Y axis length dimension of said major surfaces with respect to said thickness dimension being one of the values within the range from substantially 12 to 30, said thickness dimension and said Y axis length dimension being a set of corresponding values in accordance with the values of said first shear and second shear frequencies.
11. A piezoelectric'Rochelle salt type crystal element adapted to vibrate simultaneously at desired independently controlled first and second shear thickness mode frequencies dependent mainly upon its length and thickness dimensions,
said length dimension of the major surfaces being substantially parallel to a Z axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Y axis, said major surfaces being substantially square, the ratio of said Z axis length dimension of said major surfaces with respect to said thickness dimension being one of the values within the range from substantially 12 to 30, said thickness dimensionand said Z axis length dimension being a set of corresponding values in accordance with the values of said first shear and second shear frequencies.
12. A Rochelle salt type piez'oelectric crystal element adapted to vibrate at a desired second shear thickness mode frequency, said crystal element having substantially rectangular shaped major surfaces, said major surfaces having a.
asoaevt length dimension and a thickness or thin. dimension therebetween, said thickness dimension and said length dimension being made of values in accordance with the value of said desired second shear frequency, said major surfaces and said length dimension being substantially parallel to an X axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Z axis, said thickness dimension expressed in millimeters being one of the values substantially from 948 to 990 divided by said desired frequency expressed in kilocycles per second, and the ratio of said X axis length dimension with respect to said thickness dimension being one of the values substantially from 30 to l2, said thickness dimension and said dimensional ratio being corresponding values in accordance with the value of said frequency, as given by the curve B of Fig. 9.
13. A Rochelle salt type piezoelectric crystal element adapted to vibrate at a desired second shear thickness mode frequency, said crystal element having substantially rectangular shaped major surfaces, said major surfaces having a length dimension and a thickness or thin dimension therebetween, said thickness dimension and said length dimension being made of values in accordance with the value of said desired second shear frequency, said major surfaces and said length dimension being substantially parallel to a Y axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Z axis, said thickness dimension expressed in millimeters being one of the values substantially from 1277 to 1330 divided by said desired frequency expressed in kilocycles per second, and the ratio of said Y axis length dimension with respect to said thickness dimension being one of the values substantially from 12 to 30, said thickness dimension and said dimensional ratio being corresponding values in accordance with the value of said frequency.
14. A Rochelle salt type piezoelectric crystal element adapted to vibrate at a desired second shear thickness mode frequency, said crystal element having substantially rectangular shaped major surfaces, said major surfaces having a length dimension and a thickness or thin dimension therebetween, said thickness dimension and said length dimension being made of values in accordance with the value of said desired second shear frequency, said major surfaces and said length dimension being substantially parallel to a Z axis, said major surfaces being inclined at an angle of substantially 45 degrees with respect to the Y axis, said thickness dimension expressed in millimeters being one of the values substantially from 1060 to 1107 divided by said desired frequency expressed in kilocycles per second, and the ratio of said Z axis length dimension with respect to said thickness dimension being one of the values substantially from 12 to 30, said thickness dimension and said dimensional ratio being corresponding values in accordance with the value of said frequency.
WARREN P. MASON.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US397377A US2303375A (en) | 1941-06-10 | 1941-06-10 | Rochelle salt piezoelectric crystal apparatus |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US397377A US2303375A (en) | 1941-06-10 | 1941-06-10 | Rochelle salt piezoelectric crystal apparatus |
Publications (1)
Publication Number | Publication Date |
---|---|
US2303375A true US2303375A (en) | 1942-12-01 |
Family
ID=23570937
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US397377A Expired - Lifetime US2303375A (en) | 1941-06-10 | 1941-06-10 | Rochelle salt piezoelectric crystal apparatus |
Country Status (1)
Country | Link |
---|---|
US (1) | US2303375A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2472753A (en) * | 1946-08-16 | 1949-06-07 | Bell Telephone Labor Inc | Piezoelectric crystal apparatus |
US2472691A (en) * | 1946-08-16 | 1949-06-07 | Bell Telephone Labor Inc | Piezoelectric crystal apparatus |
US2484635A (en) * | 1943-08-09 | 1949-10-11 | Bell Telephone Labor Inc | Piezoelectric crystal apparatus |
US2485131A (en) * | 1945-03-19 | 1949-10-18 | Brush Dev Co | Piezoelectric crystal plate |
US3375379A (en) * | 1964-10-08 | 1968-03-26 | Bell Telephone Labor Inc | Rotated y-cut rectangular piezoelectric quartz crystal plates |
US20110167908A1 (en) * | 2008-05-20 | 2011-07-14 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Device For The Gravimetric Detection Of Particles In A Fluid Medium, Comprising An Oscillator Over Which A Fluid Stream Flows, Production Process And Method Of Employing The Device |
-
1941
- 1941-06-10 US US397377A patent/US2303375A/en not_active Expired - Lifetime
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2484635A (en) * | 1943-08-09 | 1949-10-11 | Bell Telephone Labor Inc | Piezoelectric crystal apparatus |
US2485131A (en) * | 1945-03-19 | 1949-10-18 | Brush Dev Co | Piezoelectric crystal plate |
US2472753A (en) * | 1946-08-16 | 1949-06-07 | Bell Telephone Labor Inc | Piezoelectric crystal apparatus |
US2472691A (en) * | 1946-08-16 | 1949-06-07 | Bell Telephone Labor Inc | Piezoelectric crystal apparatus |
US3375379A (en) * | 1964-10-08 | 1968-03-26 | Bell Telephone Labor Inc | Rotated y-cut rectangular piezoelectric quartz crystal plates |
US20110167908A1 (en) * | 2008-05-20 | 2011-07-14 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Device For The Gravimetric Detection Of Particles In A Fluid Medium, Comprising An Oscillator Over Which A Fluid Stream Flows, Production Process And Method Of Employing The Device |
US8844340B2 (en) * | 2008-05-20 | 2014-09-30 | Commissariat a l'Energie et aux Energies Alternatives | Device for the gravimetric detection of particles in a fluid medium, comprising an oscillator over which a fluid stream flows, production process and method of employing the device |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3699484A (en) | Width extensional resonator and coupled mode filter | |
US2306909A (en) | Piezoelectric crystal apparatus | |
US4511202A (en) | Ceramic resonator and a ceramic filter using the same | |
US2373431A (en) | Electric wave filter | |
US2309467A (en) | Rochelle salt piezoelectric crystal apparatus | |
US4066985A (en) | Television IF filter constructed in accordance with the surface wave principle | |
US2271870A (en) | Wave transmission network | |
US2303375A (en) | Rochelle salt piezoelectric crystal apparatus | |
JPH0514442B2 (en) | ||
USRE25413E (en) | Temperature xc | |
US2292886A (en) | Rochelle salt piezoelectric crystal apparatus | |
US2185599A (en) | Piezoelectric apparatus | |
US3396327A (en) | Thickness shear vibration type, crystal electromechanical filter | |
KR20020038462A (en) | Lame mode quartz crystal resonator | |
US3859546A (en) | Rectangular piezoelectric ceramic resonator oppositely poled along opposite side surfaces | |
US2223537A (en) | Piezoelectric crystal apparatus | |
US2292388A (en) | Rochelle salt piezoelectric crystal apparatus | |
US2284753A (en) | Piezoelectric crystal apparatus | |
US2277709A (en) | Piezoelectric crystal apparatus | |
US2292885A (en) | Rochelle salt piezoelectric crystal apparatus | |
US3143672A (en) | Single crystal quartz filter elements, oscillators and transducers | |
US3544926A (en) | Monolithic crystal filter having mass loading electrode pairs having at least one electrically nonconductive electrode | |
US2281778A (en) | Piezoelectric crystal apparatus | |
GB1209808A (en) | Improvements in or relating to electromechanical band-pass filters | |
US2277245A (en) | Piezoelectric crystal apparatus |