US2294703A - Wrinkle finish composition and method of making - Google Patents

Wrinkle finish composition and method of making Download PDF

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US2294703A
US2294703A US271590A US27159039A US2294703A US 2294703 A US2294703 A US 2294703A US 271590 A US271590 A US 271590A US 27159039 A US27159039 A US 27159039A US 2294703 A US2294703 A US 2294703A
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varnish
oil
wrinkle
resin
thinners
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William A Waldie
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New Wrinkle Inc
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New Wrinkle Inc
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/28—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24446—Wrinkled, creased, crinkled or creped

Definitions

  • My invention relates to coating compositions and more particularly to the method of making wrinkle drying varnishes which can be used to produce difierent textural wrinkle patterns.
  • the invention is applicable for producing clear varnish wrinkle finishes without employing blown oils as a constituent, thereb'y materially reducing the cost and improving the product.
  • fwrinkling oils which oils comprise raw China wood oil, blown drying oils, such as China wood, linseed, perilla, oiticica, etc.
  • Other paint and varnish oils of the so called non-wrinkling type such as soya bean, chia, walnut, hempseed, lumbang, poppy seed. sunflower seed, safilower seed, castor, fish, etc., may be utilized. Large amounts of the non-wrinkling oils, however, cannot be used in the formulation of Wrinkle finishes;
  • Another object of this invention is to eliminate the necessity of using blown oils in making wrinkle finishes.
  • Another object of this invention is to provide a. wrinkle finish composition which is comparable to wrinkle finish compositions made using blown oils.
  • Another object is to provide a wrinkle finish varnish base which can be blended with higher or lower viscosity varnishes so as to produce a light or heavy textural wrinkle finish on drying.
  • Another object is to compound a wrinkle coating composition
  • a wrinkle coating composition comprising a raw wrinkling oil adapted to be blended with low viscosity varnish to produce a wrinkle finish having a pattern scarcely discernible to the naked eye but feeling rough to the touch.
  • Another object is to provide a wrinkle finish coating.
  • composition which is useful as a blending agent to produce wrinkle finishes having finer textural patterns than produced by the use of low viscosity wrinkling varnishes.
  • Typical examples of Wrinkle finish compositions comprising blown drying oils are;
  • Example 1 Resin (Congo, kauri, rosin, cumar or Ambero lbs Lead linoleate or acetate"; do 2-3 Cobalt acetate or linoleate do Blown tung oil gals 8-10 Petroleum naphtha do 9-12 Toluol or xylol do 10-14
  • Example 2 Resin (Congo, kauri, rosin, "cumar or Amberol") lbs 100 Litharge do 3 5 Manganese linoleate or borate do 2-3 Blown linseed oil gals 15-25 Petroleum naphtha do 8-12 Toluol or xylol do 15-20
  • the formula for producing a wrinkling varnish base of my invention is as follows:
  • linseed oil employed is the grade known in the trade as "varnish linseed.” This product comprises linseed oil which has been processed by heat treating the same between 575 to 600 degrees F. until a desired degree of viscosity-is obtained.
  • the preferred method of making varnish A is to heat all of the China wood oil and approximately to A of the resin together in a vessel to a temperature around 540 degrees F. Thereafter the metallic drier, linseed oil and the remainder of the resin are added. When the resin is dissolved the varnish base can be cooled and thinned with the solvent or it can be heated longer to obtain a higher viscosity before thinning.
  • varnish A is the sudden chilling or cooling of the heat treated homogeneous mass at the end of the heat treatment. This may be done in any suitable manner such as by the application of cold water or by refrigeration.
  • a sprayable wrinkle finish product is obtained comparable with that made with blown oils.
  • the wrinkle finish product is also stable and can be stored.
  • the heat treatment of the varnish may be varied between a temperature range of 450 to 550 degrees F. but preferably the heating is conducted above 500 degrees F. a
  • varnish A may be made having relatively low or high viscosity as determined by the Gardner-Holdt standards for varnish. In general the higher the viscosity of the varnish A the coarser the texture of the wrinkle finish.
  • varnish A a varnish-like solution of drying oil fatty acids may be incorporated in varnish A.”
  • articles coated with the coating composition may be made to wrinkle by baking the coating at relatively low or high temperatures.
  • a temperature of to 475 degrees F. may be employed.
  • a somewhat lower temperature on the order of 125 to degrees F. may be used.
  • Ordinarily baking the finish at elevated temperatures accentuates the wrinkling and provides a harder finish.
  • non-drying or semi-drying oils such as castor oil, raw soya bean oil or similar materials may be made.
  • Plasticizers such as dibutyl-phthalate or tricresyl phosphate also may be utilized.
  • An improved method of making a wrinkle finish the steps of (a) mixing 4 to of the total amount of resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw Chinawood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil, and heating to a, temperature between 450 F. to 540 F., (b) adding a metallic drier, adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities.
  • An improved method of making a wrinkle finish the steps of (a) mixing A to of the total amount of resin to be used of the total amount of raw China-wood oil and heat bodied linseed oil, and heating to a temperature between 450 to 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities.
  • An improved method of making a wrinkle finish the steps of (a) mixing to of the total amount of resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw China-wood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil, and heating to a temperature between 450 to 540 F., (b) adding lead acetate, (0) adding the remainder of the resin and dissolving the same in the mixture, ((1) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities.
  • An improved method of making a wrinkle finish the steps of (a) mixing A to of the total amount of resin to be used of the total amount of raw China-wood oil and heat bodied linseed oil, and heating to a temperature between 450 to 540 F., (b) adding lead acetate, (6) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities.
  • An improved method of making a wrinkle finish the steps of (a) mixing 4 to of the total amount of resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw China-wood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil, and heating to a temperature between 450 and 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product, a varnishlike solution of drying oil fatty acids including China-wood oil fatty acids, and toluol.
  • An improved method of making a wrinkle finish the steps of (a) mixing to A of the total amount of resin to be used of the total amount of raw China-wood oil and heat bodied linseed oil, and heating to a, temperature between 450 and 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product, a varnish-like solution of drying oil fatty acids including China wood oil fatty acids, and toluol.
  • An improved method of making a wrinkle finish the steps of (a) mixing 4 to of the total amount of resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw China-wood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil, and heatin to a temperature between 450 and 540 F., (b) adding a, metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, ((1) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product a varnish-like solution of drying oil, fatty acids including Chinawood oil fatty acids and xylol.
  • An improved method of making a wrinkle finish the steps of (a) mixing A to of the total amount of resin to be used of the total amount of raw China-wood oil and heat bodied linseed oil, and heating to a temperature between 450 and 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product, a varnish-like solution of drying oil, fatty acids including China-wood oil fatty acids, and xylol.
  • An improved method of making a wrinkle finish the steps of (a) mixing to of the total amount of resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw China-wood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil, and heating to a temperature between 450 to 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product, a varnish-like solution of drying oil fatty acids including linseed oil fatty acids, China-wood oil fatty acids and toluol.
  • An improved method of making a wrinkle finish the steps of (a) mixing to of the total amount of resin to be used of the total amount of raw China-wood oil and heat bodied linseed oil, and heating to a temperature between 450 to 540" F., (b) adding a metallic drier, (0) adding nish-like solution of drying oil fatty acids ineluding linseed oil fatty acids, China-wood oil fatty acids and toluol.
  • An improved method of making a wrinkle finish the steps of (a) mixing to of the total amount of resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw China-wood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil, and heating to a temperature between 450 to 540 F., (b) adding a metallic drier, adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural finished product a varnish-like solution of drying oil fatty acids including linseed oil fatty acids and xylol.
  • An improved method of making a wrinkle finish the steps of (a) mixing A to A of the total amount of resin to be used of the total amount of raw China-wood oil and heat bodied linseed oil, and heating to a temperature between 450 to 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural finished product a varnish-like solution of drying oil fatty acids including linseed oil fatty acids and xylol;
  • An improved method of making a wrinkle finish the steps of (a) mixing A to A, of the total amount of rosin modified phenol formaldehyde resin to be used of the total'amount of a wrinkle oil selected from the class consisting of raw Chinawo'od oil, raw oiticica oil, and raw poyok oil, .together with heat bodied linseed oil and heating to a temperature between 450 to 540 F., '(b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities.
  • An improved method of making a wrinkle finish the steps of (a) mixing to A, of the total amount of rosin modified phenol formaldehyde resin to be used of the total amount of raw China wood oil and heat bodied linseed oil, and heating to a temperature between 450 to 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities.
  • An improved method of making a wrinkle finish the steps of (a) mixing ,4; to A of the total amount of rosin modified phenol formaldehyde resin to be used of the total amount of a wrinkle oil selected from the class consisting of amount of rosin modified phenol formaldehyde resin to be used of the total amount of raw China wood oil and heat bodied linseed oil, and heating to a temperature between 450 to 540 F., (b) adding lead acetate, (c) adding the remainder of the resin and dissolving the same in the mixture, ((1) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities.
  • An improved method of making a wrinkle finish the steps of (a) mixing A to of the total amount of rosin modified phenol formaldehyde resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw China wood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil, and heating to a temperature between 450 and 540 F., (1)) adding a metallic drier, (c) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a. finer textural pattern in the finished product a varnish-like solution of drying oil fatty acids including China wood oil fatty acids and toluoi.
  • An improved method of making a wrinkle finish the steps of (a) mixing A to of the total amount of rosin modified phenol formalc hyde resin to be used of the total amount of raw China wood oil and heat bodied linseed oil, and heating to a temperature between 450 and 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer'textural pattern in the finished product, a varnish, like solution of drying oil fatty acids including China wood oil fatty acids and toluol.
  • An improved method of making a wrinkle finish the steps of (a) mixing to of the total amount of rosin modified phenol formaldehyde resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw China wood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil, and heating to a temperature between 450 and 540 F., (b) adding a metallic drier, (c) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly'chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product a varnish-like solution of drying oil fatty acids including China wood oil fatty acids and xy 0].
  • An improved method of making a wrinkle finish the steps of (a) mixing to of the total amount of rosin modified phenol formaldehyde resin to be used of the total amount of raw China wood oil and heat bodied linseed oil, and heating to a temperature between 450 and 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product a varnish-like solution of drying oil, fatty acids, including China wood oil fatty acids, and xylol.
  • An improved method of making a wrinkle finish the steps of (a) mixing A to of the total amount of rosin modified phenol formaldehyde resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw China wood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil and heating to a temperature between 450 to 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product a varnish-like solution of drying oil fatty acids including linseed oil fatty acids, China wood oil fatty acids, and toluol.
  • An improved method of making a wrinkle finish the steps of (a) mixing 4 to of the total amount of rosin modified phenol formaldehyde resin to be used of the total amount of raw China wood oil and head bodied linseed oil, and heating to a temperature between 450 to 540 F., (b)
  • An improved method of making a wrinkle finish the steps of (a) mixing 4 to of the total amount of rosin modified phenol formaldehyde resin to be used of the total amount of raw Chinawood oil and heat bodied linseed oil, and heating to a temperature between 450 to 540 F'., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (cl) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural finished product a varnish-like solution of drying oil fatty acids including linseed oil fatty acids and xylol.

Description

Patented Sept. 1, 1942 VVRINKLE FINISH COMPOSITION AND METHOD OF MAKING William A. Waldie, Dayton, Ohio, assignor to New Wrinkle, Inc., Dayton, Ohio, a corporation of Delaware No Drawing. Application May 3, 1939, Serial No. 271,590
24 Claims.
My invention relates to coating compositions and more particularly to the method of making wrinkle drying varnishes which can be used to produce difierent textural wrinkle patterns. The invention is applicable for producing clear varnish wrinkle finishes without employing blown oils as a constituent, thereb'y materially reducing the cost and improving the product.
?Wrinkle finishes as heretofore made in the art have been compounded from so called fwrinkling oils which oils comprise raw China wood oil, blown drying oils, such as China wood, linseed, perilla, oiticica, etc. Other paint and varnish oils of the so called non-wrinkling type, such as soya bean, chia, walnut, hempseed, lumbang, poppy seed. sunflower seed, safilower seed, castor, fish, etc., may be utilized. Large amounts of the non-wrinkling oils, however, cannot be used in the formulation of Wrinkle finishes;
otherwise the wrinkling of the finish on drying is inhibited. Prior to my invention, it has been necessary to use blown or preoxidized oils in compounding wrinkle finishes in order to obtain the most satisfactory results. This was particularly true where clear wrinkle varnishes of sprayable consistency were desired.
The disadvantage of using blown oils lies in their instability. This instability results from the preoxidation of the oil which oxidation continues in a progressive manner after termination of the blowing treatment. At the beginning of the treatment the oil is soluble in the conventional petroleum or coal tar solvents but as oxidation progresses the oil becomes increasingly less soluble until finally it precipitates out in a rubber-like mass. This renders the wrinkle composition unfit for use. Wrinkle finish coating compositions comprising blown oil constituents, therefore, cannot be stored for any length of time before use.
It has also been found that in using wrinkle coating com-positions made with blown oils, a wrinkle finish having very fine texture can not be produced, the tendency being for the finish to form a coarse or heavy textural wrinkle pattern on drying.
It is an object of this invention to make a wrinkle finish composition which is stable on storing and can be readily modified so as to produce coarse, medium or fine textural wrinkle pattern.
Another object of this invention is to eliminate the necessity of using blown oils in making wrinkle finishes.
Another object of this invention is to provide a. wrinkle finish composition which is comparable to wrinkle finish compositions made using blown oils.
Another object is to provide a wrinkle finish varnish base which can be blended with higher or lower viscosity varnishes so as to produce a light or heavy textural wrinkle finish on drying.
Another object is to compound a wrinkle coating composition comprising a raw wrinkling oil adapted to be blended with low viscosity varnish to produce a wrinkle finish having a pattern scarcely discernible to the naked eye but feeling rough to the touch.
Another object is to provide a wrinkle finish coating. composition which is useful as a blending agent to produce wrinkle finishes having finer textural patterns than produced by the use of low viscosity wrinkling varnishes.
Another object is to compound a composition which will dry to a wrinkle finish whereby the desired pattern or texture of wrinkle finish can be varied by the addition of drying oil fatty acids. Still another object is to produce a wrinkle drying varnish of sprayable consistency without the use of blown oils.
Typical examples of Wrinkle finish compositions comprising blown drying oils are;
Example 1 Resin (Congo, kauri, rosin, cumar or Ambero lbs Lead linoleate or acetate"; do 2-3 Cobalt acetate or linoleate do Blown tung oil gals 8-10 Petroleum naphtha do 9-12 Toluol or xylol do 10-14 Example 2 Resin (Congo, kauri, rosin, "cumar or Amberol") lbs 100 Litharge do 3 5 Manganese linoleate or borate do 2-3 Blown linseed oil gals 15-25 Petroleum naphtha do 8-12 Toluol or xylol do 15-20 In order to eliminate the use of blown oils as illustrated in the typical examples of wrinkle finishes given, the formula for producing a wrinkling varnish base of my invention is as follows:
In the foregoing varnish formula it will be understood that various resins may be utilized in place of those mentioned. Resins which are suitable are kauri, dammar, Congo, "cumar, pontianak, Manila, Zanzibar, elemi, mastic, copal, sandarac and the like. Further other phenol formaldehyde resins of the rosin. fossil resin and ester gum modified type which are readily compatible with the oil vehicle may be used. Also glycerol phthalic resins of the oil soluble type may be utilized, or mixtures of the above resins.
Similarly other wrinkle oils such, as raw oiticica, poyok and equivalent oils may be substituted for raw China wood oil. The bodied linseed oil employed is the grade known in the trade as "varnish linseed." This product comprises linseed oil which has been processed by heat treating the same between 575 to 600 degrees F. until a desired degree of viscosity-is obtained.
The preferred method of making varnish A is to heat all of the China wood oil and approximately to A of the resin together in a vessel to a temperature around 540 degrees F. Thereafter the metallic drier, linseed oil and the remainder of the resin are added. When the resin is dissolved the varnish base can be cooled and thinned with the solvent or it can be heated longer to obtain a higher viscosity before thinning.
I have discovered, however, that if the varnish base is cooled quickly after the second portion of resin is dissolved a clear wrinkle varnish can be made having improved spraying and wrinkling properties. The essential step in making varnish A is the sudden chilling or cooling of the heat treated homogeneous mass at the end of the heat treatment. This may be done in any suitable manner such as by the application of cold water or by refrigeration. By this method of making the wrinkle finish composition a sprayable wrinkle finish product is obtained comparable with that made with blown oils. The wrinkle finish product is also stable and can be stored. The heat treatment of the varnish may be varied between a temperature range of 450 to 550 degrees F. but preferably the heating is conducted above 500 degrees F. a
By maintaining the percentage amount of the total solids in the composition the same and heating the product for different lengths of time, I can regulate the viscosity of the varnish. The longer the varnish is heated the higher becomes its viscosity and correspondingly the shorter the period the lower the viscosity. This is true even though the amount of solvent or thinner added may be the same in both cases.
In making a clear wrinkle varnish there is added to the above varnish "A about 2 to 5 per cent of a liquid drier. A drier composition which has been found to be very satisfactor for this purpose is as follows:
Liquid Drier ".4.
Cobalt linoleate solid lbs 12-16 China wood oil fatty acids do 8-10 Toluol, xylol, petroleum naphtha or coal tar solvent gals 6-8 Other examples of liquid driers which may be For producing a wrinkle finish composition of the desired textural wrinkle pattern, varnish A may be made having relatively low or high viscosity as determined by the Gardner-Holdt standards for varnish. In general the higher the viscosity of the varnish A the coarser the texture of the wrinkle finish.
Where a finer textural pattern of a wrink-le finish is desired than can be obtained by the use of a low viscosity varnish. a varnish-like solution of drying oil fatty acids may be incorporated in varnish A." The following examples are typical:
Varnish "B China wood oil fatty acids lbs 8-10 Toluol or xylol gal 1 Varnish "C Linseed oil fatty acids lbs 2-5 China wood oil fatty acids -do 3-8 Toluol or xyl gal 1 By adding various proportions of varnish B or varnish "C" to a low viscosity wrinkle varnish base made according to varnish "A," the texture or pattern of the wrinkle produced on drying is modified. The higher the proportion of varnish' B or C added to varnish A, the finer the texture of the wrinkle finish produced.
In producing the improved wrinkle finish of this invention, articles coated with the coating composition may be made to wrinkle by baking the coating at relatively low or high temperatures. For metallic and similar surfaces a temperature of to 475 degrees F. may be employed. For application of the coating on wood, paper and similar materials a somewhat lower temperature on the order of 125 to degrees F. may be used. Ordinarily baking the finish at elevated temperatures accentuates the wrinkling and provides a harder finish. Where a highly elastic film is desired, the addition of small amounts of non-drying or semi-drying oils, such as castor oil, raw soya bean oil or similar materials may be made. Plasticizers such as dibutyl-phthalate or tricresyl phosphate also may be utilized.
It will be understood that I desire-to comprehend within my invention such modifications as come within the scope of the claims and the vention.
Having thus fully described my invention, what I claim as new and desire to secure by Letters Patent is:
1. An improved method of making a wrinkle finish the steps of (a) mixing 4 to of the total amount of resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw Chinawood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil, and heating to a, temperature between 450 F. to 540 F., (b) adding a metallic drier, adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities.
2. An improved method of making a wrinkle finish the steps of (a) mixing A to of the total amount of resin to be used of the total amount of raw China-wood oil and heat bodied linseed oil, and heating to a temperature between 450 to 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities.
3. An improved method of making a wrinkle finish the steps of (a) mixing to of the total amount of resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw China-wood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil, and heating to a temperature between 450 to 540 F., (b) adding lead acetate, (0) adding the remainder of the resin and dissolving the same in the mixture, ((1) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities.
4. An improved method of making a wrinkle finish the steps of (a) mixing A to of the total amount of resin to be used of the total amount of raw China-wood oil and heat bodied linseed oil, and heating to a temperature between 450 to 540 F., (b) adding lead acetate, (6) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities.
5. An improved method of making a wrinkle finish the steps of (a) mixing 4 to of the total amount of resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw China-wood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil, and heating to a temperature between 450 and 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product, a varnishlike solution of drying oil fatty acids including China-wood oil fatty acids, and toluol.
6. An improved method of making a wrinkle finish the steps of (a) mixing to A of the total amount of resin to be used of the total amount of raw China-wood oil and heat bodied linseed oil, and heating to a, temperature between 450 and 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product, a varnish-like solution of drying oil fatty acids including China wood oil fatty acids, and toluol.
'7. An improved method of making a wrinkle finish the steps of (a) mixing 4 to of the total amount of resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw China-wood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil, and heatin to a temperature between 450 and 540 F., (b) adding a, metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, ((1) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product a varnish-like solution of drying oil, fatty acids including Chinawood oil fatty acids and xylol.
8. An improved method of making a wrinkle finish the steps of (a) mixing A to of the total amount of resin to be used of the total amount of raw China-wood oil and heat bodied linseed oil, and heating to a temperature between 450 and 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product, a varnish-like solution of drying oil, fatty acids including China-wood oil fatty acids, and xylol.
9. An improved method of making a wrinkle finish the steps of (a) mixing to of the total amount of resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw China-wood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil, and heating to a temperature between 450 to 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product, a varnish-like solution of drying oil fatty acids including linseed oil fatty acids, China-wood oil fatty acids and toluol.
10. An improved method of making a wrinkle finish the steps of (a) mixing to of the total amount of resin to be used of the total amount of raw China-wood oil and heat bodied linseed oil, and heating to a temperature between 450 to 540" F., (b) adding a metallic drier, (0) adding nish-like solution of drying oil fatty acids ineluding linseed oil fatty acids, China-wood oil fatty acids and toluol.
11. An improved method of making a wrinkle finish the steps of (a) mixing to of the total amount of resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw China-wood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil, and heating to a temperature between 450 to 540 F., (b) adding a metallic drier, adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural finished product a varnish-like solution of drying oil fatty acids including linseed oil fatty acids and xylol. i
12. An improved method of making a wrinkle finish the steps of (a) mixing A to A of the total amount of resin to be used of the total amount of raw China-wood oil and heat bodied linseed oil, and heating to a temperature between 450 to 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural finished product a varnish-like solution of drying oil fatty acids including linseed oil fatty acids and xylol;
13. An improved method of making a wrinkle finish the steps of (a) mixing A to A, of the total amount of rosin modified phenol formaldehyde resin to be used of the total'amount of a wrinkle oil selected from the class consisting of raw Chinawo'od oil, raw oiticica oil, and raw poyok oil, .together with heat bodied linseed oil and heating to a temperature between 450 to 540 F., '(b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities.
14. An improved method of making a wrinkle finish the steps of (a) mixing to A, of the total amount of rosin modified phenol formaldehyde resin to be used of the total amount of raw China wood oil and heat bodied linseed oil, and heating to a temperature between 450 to 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities.
15. An improved method of making a wrinkle finish the steps of (a) mixing ,4; to A of the total amount of rosin modified phenol formaldehyde resin to be used of the total amount of a wrinkle oil selected from the class consisting of amount of rosin modified phenol formaldehyde resin to be used of the total amount of raw China wood oil and heat bodied linseed oil, and heating to a temperature between 450 to 540 F., (b) adding lead acetate, (c) adding the remainder of the resin and dissolving the same in the mixture, ((1) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities.
17. An improved method of making a wrinkle finish the steps of (a) mixing A to of the total amount of rosin modified phenol formaldehyde resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw China wood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil, and heating to a temperature between 450 and 540 F., (1)) adding a metallic drier, (c) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a. finer textural pattern in the finished product a varnish-like solution of drying oil fatty acids including China wood oil fatty acids and toluoi.
18. An improved method of making a wrinkle finish the steps of (a) mixing A to of the total amount of rosin modified phenol formalc hyde resin to be used of the total amount of raw China wood oil and heat bodied linseed oil, and heating to a temperature between 450 and 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer'textural pattern in the finished product, a varnish, like solution of drying oil fatty acids including China wood oil fatty acids and toluol.
19. An improved method of making a wrinkle finish the steps of (a) mixing to of the total amount of rosin modified phenol formaldehyde resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw China wood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil, and heating to a temperature between 450 and 540 F., (b) adding a metallic drier, (c) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly'chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product a varnish-like solution of drying oil fatty acids including China wood oil fatty acids and xy 0].
20. An improved method of making a wrinkle finish the steps of (a) mixing to of the total amount of rosin modified phenol formaldehyde resin to be used of the total amount of raw China wood oil and heat bodied linseed oil, and heating to a temperature between 450 and 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product a varnish-like solution of drying oil, fatty acids, including China wood oil fatty acids, and xylol.
21. An improved method of making a wrinkle finish the steps of (a) mixing A to of the total amount of rosin modified phenol formaldehyde resin to be used of the total amount of a wrinkle oil selected from the class consisting of raw China wood oil, raw oiticica oil, and raw poyok oil, together with heat bodied linseed oil and heating to a temperature between 450 to 540 F., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product a varnish-like solution of drying oil fatty acids including linseed oil fatty acids, China wood oil fatty acids, and toluol.
22. An improved method of making a wrinkle finish the steps of (a) mixing 4 to of the total amount of rosin modified phenol formaldehyde resin to be used of the total amount of raw China wood oil and head bodied linseed oil, and heating to a temperature between 450 to 540 F., (b)
adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural pattern in the finished product a varnish-like solution of drying oil fatty F., (b) adding a metallic drier, (c)-adding the remainder of the resin and dissolving the same 'in the mixture, (d) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural finished product a varnish-like solution of drying oil fatty acids including linseed oil fatty acids and xylol.
24. An improved method of making a wrinkle finish the steps of (a) mixing 4 to of the total amount of rosin modified phenol formaldehyde resin to be used of the total amount of raw Chinawood oil and heat bodied linseed oil, and heating to a temperature between 450 to 540 F'., (b) adding a metallic drier, (0) adding the remainder of the resin and dissolving the same in the mixture, (cl) rapidly chilling the liquid without the use of thinners, and adding thinners to produce a spray varnish having low viscosity and superior spray qualities, and incorporating in said varnish to produce a finer textural finished product a varnish-like solution of drying oil fatty acids including linseed oil fatty acids and xylol.
WILLIAM A. WALDIE.
US271590A 1939-05-03 1939-05-03 Wrinkle finish composition and method of making Expired - Lifetime US2294703A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2428901A (en) * 1947-10-14 Polymerization nucleus fob
US2431357A (en) * 1947-11-25 Polymerization nucleus for
US2441739A (en) * 1947-04-09 1948-05-18 New Wrinkle Inc Method of polymerizing nonwrinkling oils to wrinkling oils
US2441738A (en) * 1948-05-18 Method of polymerizing nonwrin
US2456670A (en) * 1945-08-13 1948-12-21 New Wrinkle Inc Cellulose compound wrinkle composition

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2428901A (en) * 1947-10-14 Polymerization nucleus fob
US2431357A (en) * 1947-11-25 Polymerization nucleus for
US2441738A (en) * 1948-05-18 Method of polymerizing nonwrin
US2456670A (en) * 1945-08-13 1948-12-21 New Wrinkle Inc Cellulose compound wrinkle composition
US2441739A (en) * 1947-04-09 1948-05-18 New Wrinkle Inc Method of polymerizing nonwrinkling oils to wrinkling oils

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