US2248656A - Metal-washing composition - Google Patents
Metal-washing composition Download PDFInfo
- Publication number
- US2248656A US2248656A US265766A US26576639A US2248656A US 2248656 A US2248656 A US 2248656A US 265766 A US265766 A US 265766A US 26576639 A US26576639 A US 26576639A US 2248656 A US2248656 A US 2248656A
- Authority
- US
- United States
- Prior art keywords
- washing
- boilers
- composition
- metal
- boiler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 21
- 238000005406 washing Methods 0.000 title description 17
- 150000001875 compounds Chemical class 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000003518 caustics Substances 0.000 description 5
- 239000004519 grease Substances 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000011368 organic material Substances 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 3
- 235000011180 diphosphates Nutrition 0.000 description 3
- 229920005610 lignin Polymers 0.000 description 3
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 3
- 229920001864 tannin Polymers 0.000 description 3
- 239000001648 tannin Substances 0.000 description 3
- 235000018553 tannin Nutrition 0.000 description 3
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000009991 scouring Methods 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 235000007173 Abies balsamea Nutrition 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241001070941 Castanea Species 0.000 description 1
- 235000014036 Castanea Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 235000017343 Quebracho blanco Nutrition 0.000 description 1
- 241000065615 Schinopsis balansae Species 0.000 description 1
- 241000381592 Senegalia polyacantha Species 0.000 description 1
- 241000218685 Tsuga Species 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
- 239000005418 vegetable material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/16—Phosphates including polyphosphates
Definitions
- Newly manufactured boilers usually have considerable quantities of grease and oil on their inside surfaces, produced during the fabrication of the boilers.
- the greases and oils are introduced in the form of reaming compounds during the process of manufacture of the boiler. It is desirable that these greases be removed from inside the boiler previous to use. customary in the past to wash out new boilers with an aqueous solution containing caustic soda or soda ash. These compositions have been somewhat undesirable for the washing operation because of the expense involved and the relatively large amount of compositions that must be used to produce the desired result.
- a furthere disadvantage of the caustic ingredients that have been employed in the past for washing out new boilers is that the caustic material has a tendency to collect in the seams of the boiler during the preliminary washing, which often results in subsequent plate cracking due to caustic embrittlement.
- an object of this invention is to provide an easily and cheaply prepared washing composition useful for removing greases and oils from the interior of boilers.
- a further object of this invention is the provision of a method for washing new boilers which acts to prevent subsequent plate cracking in the boilers due to caustic embrittlement.
- a further object of this invention is to provide a method for washing a new boiler which will impart to the boiler a measure of protection against intercrystalline corrosion.
- organic material such as lignin or tannin in the composition functions in part as a filler for the seams in the boiler that is being treated with the composition.
- This organic material also has a tendency to prevent subsequent intercrystalline corrosion within the boiler and cracking of plates due to caustic embrittlement.
- the soluble sulfate also acts as a means for preventing embrittlement of the metal.
- Any of the water-soluble sulfates may be employed in the washing composition of this invention, such as ammonium sulfate, sodium sulfate, potassium sulfate, lithium sulfate, and' the like.
- Sodium sulfate maybe most desirable, since it is readily and cheaply available.
- any of the water-soluble 'tetrabasic phosphates may be employed in the washing composition of this invention, suitable examples being those of sodium, potassium, ammonium, and the like. It may be desirable, however, to employ the tetrasodium pyrophosphate because of its availability and cheapness.
- a washing composition may be prepared in the dry condition in accordance with the following formula:
- the dry ingredients of the mixture prepared in accordance with the above formula are thoroughly mixed and ground, if necessary, in order to produce a homogeneous mixture.
- This mixture has been found to be nearly five times as effective in cleaning solution for the removal of reaming compounds from new boilers as is caustic soda. It is also many more times as effective as soda ash.
- a suitable, concentration for use in the washing of a boiler is approximately pounds per 1000 gallons of boiler capacity.
- composition of thi's invention may also be employed for the scouring or washing of metallic or other surfaces in various types of apparatus.
- it may be employed in removing greasy materials from the interior of cooling and heating systems.
- the composition employed in connection with the present invention is not to be construed as limited to boiler operation alone.
- the ratios of the various compounds contained within the mixture may be varied widely depending upon the use to which the particular compound is to be put or upon the characteristics of the particular kind of material to be washed. Thus, a greater scouring effect may be obtained by increasing the rela- .tive proportions of the pyrophosphate and the sulfate.
- a composition for use in removing grease and reaming compounds from the interior of boilers and the like comprising approximately 30 parts by weight of tetrasodium pyrophosphate,
- a composition for 'use in removing grease and reaming compounds from the interior of boilers and the like comprising substantially equal amounts by weight of a tetrabasic watersoluble pyrophosphate, an alkali metal sulfate, and sulfite waste liquor solids.
- Process for removing grinding and reaming compounds from the interior of boilers and the like which comprises washing the boilers with an aqueous solution of a composition consisting lof substantially equal amounts by weight of a
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Detergent Compositions (AREA)
Description
Patented July 8, 1941 METAL-WASHING COMPOSITION Paul G. Bird, Western Springs, Ill.
No Drawing. Application April 3, 1939, Serial No. 265,766
4 Claims. (Cl. 252135) useful for removing grease and oils from metal surfaces.
Newly manufactured boilers usually have considerable quantities of grease and oil on their inside surfaces, produced during the fabrication of the boilers. The greases and oils are introduced in the form of reaming compounds during the process of manufacture of the boiler. It is desirable that these greases be removed from inside the boiler previous to use. customary in the past to wash out new boilers with an aqueous solution containing caustic soda or soda ash. These compositions have been somewhat undesirable for the washing operation because of the expense involved and the relatively large amount of compositions that must be used to produce the desired result. A furthere disadvantage of the caustic ingredients that have been employed in the past for washing out new boilers is that the caustic material has a tendency to collect in the seams of the boiler during the preliminary washing, which often results in subsequent plate cracking due to caustic embrittlement.
Accordingly an object of this invention is to provide an easily and cheaply prepared washing composition useful for removing greases and oils from the interior of boilers.
A further object of this invention is the provision of a method for washing new boilers which acts to prevent subsequent plate cracking in the boilers due to caustic embrittlement.
A further object of this invention is to provide a method for washing a new boiler which will impart to the boiler a measure of protection against intercrystalline corrosion.
"Further and additional objects will appear from the following description and the appended claims.
In accordance with this invention, the washing composition that maybe employed for the removal of grease from boilers or other metallic surfaces comprises a mixture of a water-soluble tetrabasic pyrophosphate, a water-soluble sulfate, and a complex organic material such as tannin or lignin, which may be extracted from wood or other vegetable materials in accordance bilize the greasy material, whereby it is readily.
removed from the surface under treatment. The
It has been complex organic material such as lignin or tannin in the composition functions in part as a filler for the seams in the boiler that is being treated with the composition. This organic material also has a tendency to prevent subsequent intercrystalline corrosion within the boiler and cracking of plates due to caustic embrittlement. The soluble sulfate also acts as a means for preventing embrittlement of the metal.
Examples of organic materials that may be employed in a washing composition prepared in accordance with this invention are tannins and lignins such as are obtainable from cutch, quebracho, hemlock, chestnut, residues from paper mill sulfite liquors, and the like. Any of the water-soluble sulfates may be employed in the washing composition of this invention, such as ammonium sulfate, sodium sulfate, potassium sulfate, lithium sulfate, and' the like. Sodium sulfate, however, maybe most desirable, since it is readily and cheaply available. In like manner, any of the water-soluble 'tetrabasic phosphates may be employed in the washing composition of this invention, suitable examples being those of sodium, potassium, ammonium, and the like. It may be desirable, however, to employ the tetrasodium pyrophosphate because of its availability and cheapness.
In accordance with one specific embodiment of this invention, a washing composition may be prepared in the dry condition in accordance with the following formula:
Parts by weight Tetrasodium pyrophosphate .Sodium sulfate 40 Dried sulfite waste liquors", 30
The dry ingredients of the mixture prepared in accordance with the above formula are thoroughly mixed and ground, if necessary, in order to produce a homogeneous mixture. This mixture has been found to be nearly five times as effective in cleaning solution for the removal of reaming compounds from new boilers as is caustic soda. It is also many more times as effective as soda ash. A suitable, concentration for use in the washing of a boiler is approximately pounds per 1000 gallons of boiler capacity.
While the above description has had particular reference to the washing of the interior of new boilers git will be evident that the composition of thi's invention may also be employed for the scouring or washing of metallic or other surfaces in various types of apparatus. For example, it may be employed in removing greasy materials from the interior of cooling and heating systems. The composition employed in connection with the present invention is not to be construed as limited to boiler operation alone. Furthermore, it will be evident to those skilled in the art that the ratios of the various compounds contained within the mixture may be varied widely depending upon the use to which the particular compound is to be put or upon the characteristics of the particular kind of material to be washed. Thus, a greater scouring effect may be obtained by increasing the rela- .tive proportions of the pyrophosphate and the sulfate.
While a particular embodiment of this invention is shown above, it will be understood, of course, that the invention is not to be limited thereto since many modifications may be made, and it is contemplated, therefore, by the appended claims to cover any such modifications as fall within the true spirit and scope of this invention.
I claim:
1. A composition for use in removing grease and reaming compounds from the interior of boilers and the like, comprising approximately 30 parts by weight of tetrasodium pyrophosphate,
40 parts by weight of sodium sulfate, and 30 parts by weight of sulfite waste liquor solids.
2. A composition for 'use in removing grease and reaming compounds from the interior of boilers and the like comprising substantially equal amounts by weight of a tetrabasic watersoluble pyrophosphate, an alkali metal sulfate, and sulfite waste liquor solids.
3. Process for removing grinding and reaming compounds from the interior of boilers and the like which comprises washing the boilers with an aqueous solution of a composition consisting lof substantially equal amounts by weight of a
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US265766A US2248656A (en) | 1939-04-03 | 1939-04-03 | Metal-washing composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US265766A US2248656A (en) | 1939-04-03 | 1939-04-03 | Metal-washing composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2248656A true US2248656A (en) | 1941-07-08 |
Family
ID=23011809
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US265766A Expired - Lifetime US2248656A (en) | 1939-04-03 | 1939-04-03 | Metal-washing composition |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2248656A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2428187A (en) * | 1943-08-26 | 1947-09-30 | Wyandotte Chemicals Corp | Method of inhibiting attack on glass surfaces by caustic soda solutions |
| US2439784A (en) * | 1944-12-30 | 1948-04-13 | Hall Lab Inc | Process of boiling out steam boilers prior to placing them in operation and composition therefor |
| US2782162A (en) * | 1952-07-07 | 1957-02-19 | Hagan Corp | Method of treating sea water |
| US2901437A (en) * | 1955-05-03 | 1959-08-25 | Wright Chem Corp | Corrosion inhibiting composition |
-
1939
- 1939-04-03 US US265766A patent/US2248656A/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2428187A (en) * | 1943-08-26 | 1947-09-30 | Wyandotte Chemicals Corp | Method of inhibiting attack on glass surfaces by caustic soda solutions |
| US2439784A (en) * | 1944-12-30 | 1948-04-13 | Hall Lab Inc | Process of boiling out steam boilers prior to placing them in operation and composition therefor |
| US2782162A (en) * | 1952-07-07 | 1957-02-19 | Hagan Corp | Method of treating sea water |
| US2901437A (en) * | 1955-05-03 | 1959-08-25 | Wright Chem Corp | Corrosion inhibiting composition |
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