US2235947A - Process for the gaseous cementation of steel pieces - Google Patents

Process for the gaseous cementation of steel pieces Download PDF

Info

Publication number
US2235947A
US2235947A US261668A US26166839A US2235947A US 2235947 A US2235947 A US 2235947A US 261668 A US261668 A US 261668A US 26166839 A US26166839 A US 26166839A US 2235947 A US2235947 A US 2235947A
Authority
US
United States
Prior art keywords
cementation
gaseous
gas
pressure
steel pieces
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US261668A
Inventor
Saives Leon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Application granted granted Critical
Publication of US2235947A publication Critical patent/US2235947A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/20Carburising
    • C23C8/22Carburising of ferrous surfaces

Definitions

  • in gas inlets and outlets are also in the fixed position, and the composition of the gaseous atmosphere will gradually vary throughout the entire path of the gas, from the inlet to the discharge.
  • the pieces which are situated outside this path it will be subjected to a calm atmosphere having slight whirls, and in such places the cementation is imperfect, owing to the exhaustion of the gas.
  • the present invention consists in obtaining, by a static method and without any heated mechpp anism, the homogeneous nature of the gaseous composition throughout the whole of the cementation mume.
  • the frequency of this pulsatory action is sufficiently low in order that at each instant the equilibrium of pressure shall be practically atg; tained at all points of the muffle.
  • the admission 01' gas is sufficiently abrupt in order that the rise or pressure shall be as great as desired.
  • the volume of gas supplied at each pulsation, the time between any two pulsations, and the rapidity of the injection, are regulated according to the volume of the mume, the leakage at the charging door (or at the evacuation conduit), and the supply of gas required for a uniform and homogeneous cementation.
  • the subject-matter of the invention use may be made of various devices adapted to provide a. periodic supply of a large quantity of gas.
  • Fig. i is a diagrammatic view of one form of device for practicing the process of the invention, certain of the parts being shown in full lines and certain other parts shown in section, and
  • Fig. 2 is a similar view of another form of device for practicing the invention.
  • the device which is shown diagrammatically in Fig. 1 comprises a supercompressor I which receives-through the pipe 2--the gas supplied by the preparatory apparatus and delivers this gas into a recipient 3, whose periodic discharge into the cementation muiiie 4 is assured by a gatevalve 5 which is controlled by the maximum pressure prevailing in the recipient 3, or by a clockwork device.
  • a supercompressor I which receives-through the pipe 2--the gas supplied by the preparatory apparatus and delivers this gas into a recipient 3, whose periodic discharge into the cementation muiiie 4 is assured by a gatevalve 5 which is controlled by the maximum pressure prevailing in the recipient 3, or by a clockwork device.
  • the pressure rises rapidly in the interior of the muflie, and then falls more slowly until the next discharge, owing to the exit of the exhausted gas through the evacuation conduit 6 or to leakage which may occur in spite of the tight door I.
  • the recipient 3 is replaced by a compressible rubher bag 8 which is supplied through a gate-valve 9 and discharges through a gate-valve In.
  • the m discharge from the bag may be obtained by compressing the said bag by means of a fluid (compressed air or water under pressure) which is sent around the bag into a recipient containing this latter.
  • the said fluid is delivered into the recipient through a gate-valve l2, and. it is discharged through a gate-valve I3.
  • valves 9 and III on the one hand, and i2 and I3 on the other hand, are automatically controlleid insuch 50 manner (for instance) that the valves 9 and I3 will be opened and the valves in and 12 will be closed during the filling of the bag, and that the valves 9 and I3 will be closed and the valves l0 and I2 opened during the emptying of the bag.
  • valves 9, I0 and l2, l3 may be controlled by electric means or by clockwork; and they may be combined together or assembled in a single apparatus.
  • the step which consists in periodically supplying fresh cementatlon gas under high pressure intermittently to the mume, whereby the pressure in the muille will rise abruptly and will then gradually tall to its initial value whereby fresh cementatlon gas comes in contact with all parts of the surtace 0i 5 the steel articles.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
  • Furnace Details (AREA)

Description

arch 25, 1941.2 s s 2,235,947
PROCESS FOR THE GASEOUS GEMENTAI'ION OF STEEL PIECES Filed March 13, 1-939 In vie 77%,;
Patented Mar. 25, 1941 PATENT OFFICE PROCESS FOR THE GASEOUS CEMENTATION OF STEEL PIECES Leon Salves, Billancourt,
France, assignor to Louis Renault, Billancourt, France Application March 13, 1939, Serial No.
In France March 30, 1938 1 Claim.
The modern methods for gaseous cementation by carbon may give uniform and constant results when these are applied to furnaces in which the pieces are subject to movement, such as fura naces with rotating retort for small pieces, continuous furnaces oi the propelling type, furnaces with revolving hearth, and the like, but the results are irregular in the case oi cementation. in. stationary muilies of large size. In fact, the
in gas inlets and outlets are also in the fixed position, and the composition of the gaseous atmosphere will gradually vary throughout the entire path of the gas, from the inlet to the discharge. The pieces which are situated outside this path it will be subjected to a calm atmosphere having slight whirls, and in such places the cementation is imperfect, owing to the exhaustion of the gas.
The same is true for the cementation of small pieces contained in baskets, or for the cementapn tion in the cavities of the pieces; in this case the gas is imperfectly renewed by difiusion, it becomes exhausted, and the cementation will not continue.
in the case of gaseous cementation by ampm monia. at about 520 0., such drawbacks have been obviated by stirring up the atmosphere by a tan which is located in the mufiie and is driven by a shaft passing through the same, but for cementation by carbon, this method cannot be an employed, owing to the very high temperature, which is between 800 and 1000 according to the case (usually about 930).
The present invention consists in obtaining, by a static method and without any heated mechpp anism, the homogeneous nature of the gaseous composition throughout the whole of the cementation mume.
For this purpose, I produce sudden periodic variations of pressure having a great value. For
it instance, by any suitable method which can be readily conceived, I suddenly send into the cementation muflle a volume of gas comparable with the volume of the muiiie. This will cause a sudden increase of pressure, but owing to the gas discharge conduit and to the inevitable leakage at the charging door (even though this is as tight as possible), the pressure will gradually fall to a value near atmospheric pressure. At this time,
50 i. e., in a few minutes, another sudden supply of gas will increase the pressure.
The frequency of this pulsatory action is sufficiently low in order that at each instant the equilibrium of pressure shall be practically atg; tained at all points of the muffle. The admission 01' gas is sufficiently abrupt in order that the rise or pressure shall be as great as desired.
The volume of gas supplied at each pulsation, the time between any two pulsations, and the rapidity of the injection, are regulated according to the volume of the mume, the leakage at the charging door (or at the evacuation conduit), and the supply of gas required for a uniform and homogeneous cementation.
For operating the process, the subject-matter of the invention, use may be made of various devices adapted to provide a. periodic supply of a large quantity of gas.
As examples which are not of a iimitative nature, the following description relates to two such devices, with reference to the two figures of the accompanying drawing, in which Fig. i is a diagrammatic view of one form of device for practicing the process of the invention, certain of the parts being shown in full lines and certain other parts shown in section, and
Fig. 2 is a similar view of another form of device for practicing the invention.
The device which is shown diagrammatically in Fig. 1 comprises a supercompressor I which receives-through the pipe 2--the gas supplied by the preparatory apparatus and delivers this gas into a recipient 3, whose periodic discharge into the cementation muiiie 4 is assured by a gatevalve 5 which is controlled by the maximum pressure prevailing in the recipient 3, or by a clockwork device. At each discharge, the pressure rises rapidly in the interior of the muflie, and then falls more slowly until the next discharge, owing to the exit of the exhausted gas through the evacuation conduit 6 or to leakage which may occur in spite of the tight door I.
In the device shown diagrammatically in Fig. 2, the recipient 3 is replaced by a compressible rubher bag 8 which is supplied through a gate-valve 9 and discharges through a gate-valve In. The m discharge from the bag may be obtained by compressing the said bag by means of a fluid (compressed air or water under pressure) which is sent around the bag into a recipient containing this latter. The said fluid is delivered into the recipient through a gate-valve l2, and. it is discharged through a gate-valve I3. The valves 9 and III on the one hand, and i2 and I3 on the other hand, are automatically controlleid insuch 50 manner (for instance) that the valves 9 and I3 will be opened and the valves in and 12 will be closed during the filling of the bag, and that the valves 9 and I3 will be closed and the valves l0 and I2 opened during the emptying of the bag. I:
The valves 9, I0 and l2, l3 may be controlled by electric means or by clockwork; and they may be combined together or assembled in a single apparatus.
I claim:
In a process for the cementation of steel articles in a stationary muflle, the step which consists in periodically supplying fresh cementatlon gas under high pressure intermittently to the mume, whereby the pressure in the muille will rise abruptly and will then gradually tall to its initial value whereby fresh cementatlon gas comes in contact with all parts of the surtace 0i 5 the steel articles.
LEON SAIVES.
US261668A 1938-03-30 1939-03-13 Process for the gaseous cementation of steel pieces Expired - Lifetime US2235947A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR835931T 1938-03-30

Publications (1)

Publication Number Publication Date
US2235947A true US2235947A (en) 1941-03-25

Family

ID=9297844

Family Applications (1)

Application Number Title Priority Date Filing Date
US261668A Expired - Lifetime US2235947A (en) 1938-03-30 1939-03-13 Process for the gaseous cementation of steel pieces

Country Status (4)

Country Link
US (1) US2235947A (en)
DE (1) DE726134C (en)
FR (1) FR835931A (en)
GB (1) GB527081A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2975083A (en) * 1959-11-05 1961-03-14 William E Engelhard Carburizing procedure

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1041067B (en) * 1955-12-06 1958-10-16 Elino Ind Ofenbau Carl Hanf & Process for carburizing, nitriding or carbonitriding of steel parts
FR2356104A1 (en) * 1976-06-23 1978-01-20 Alco Standard Corp Heat treating furnace gas circulation - using opposed plunger assemblies to pulsate gas flow through chamber
CH632013A5 (en) * 1977-09-22 1982-09-15 Ipsen Ind Int Gmbh METHOD FOR GAS CARBONING WORKPIECE FROM STEEL.
DE3038078A1 (en) * 1980-10-08 1982-05-06 Linde Ag, 6200 Wiesbaden METHOD AND DEVICE FOR CARBONING METAL WORKPIECES
DE3038082A1 (en) * 1980-10-08 1982-05-06 Linde Ag, 6200 Wiesbaden METHOD FOR USEFUL METAL WORKPIECES
DE3038081A1 (en) * 1980-10-08 1982-05-06 Linde Ag, 6200 Wiesbaden METHOD FOR CARBONING AND CARBON-NEUTRAL GLOWING OF WORKPIECES
DE3146042A1 (en) * 1981-11-20 1983-05-26 Linde Ag, 6200 Wiesbaden METHOD FOR USEFUL METAL WORKPIECES

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2975083A (en) * 1959-11-05 1961-03-14 William E Engelhard Carburizing procedure

Also Published As

Publication number Publication date
DE726134C (en) 1942-10-07
GB527081A (en) 1940-10-02
FR835931A (en) 1939-01-05

Similar Documents

Publication Publication Date Title
US2235947A (en) Process for the gaseous cementation of steel pieces
US3796615A (en) Method of vacuum carburizing
JPS60138065A (en) Gas carburizing and quenching method and continuous gas carburizing and quenching equipment
US2857155A (en) Apparatus for reducing ores
US3821026A (en) Scrap metal recovery method and apparatus
US2792438A (en) Apparatus for producing titanium metal
JPS55125267A (en) Surface treating method of improving abrasion resistance and corrosion resistance of iron and steel
US2404650A (en) Processing kiln
US2565360A (en) Method for nitriding
GB2087058A (en) Method of feeding powder-like fuel mixture to blast furnace tuyeres
US2461020A (en) Production of tantalum nitride
GB576462A (en) Improvements in kilns
JPS5792127A (en) Continuous bright heat treatment of metal in furnace containing gaseous atmosphere
US1907331A (en) Apparatus for hardening metals
US2382909A (en) Manufacture of strontium oxide
US766903A (en) Charging device for furnaces, gas-generators, &c.
US1597718A (en) Apparatus for recovering heat from coke, slags, ashes, and other solid substances
US1586823A (en) Process of producing nitrogen compounds and apparatus therefor
US2181094A (en) Metallurgical process
DE482881C (en) Procedure for loading horizontal retorts by means of spinning
JPS5735621A (en) Heat treatment installation for metal
US1065697A (en) Annealing process, &c.
US2872176A (en) Rotary furnaces
US2255844A (en) Metallurgical furnace
US680613A (en) Ore roasting and desulfurizing furnace.