US2215295A - Surface insulation for magnetic sheet steel - Google Patents

Surface insulation for magnetic sheet steel Download PDF

Info

Publication number
US2215295A
US2215295A US79941A US7994136A US2215295A US 2215295 A US2215295 A US 2215295A US 79941 A US79941 A US 79941A US 7994136 A US7994136 A US 7994136A US 2215295 A US2215295 A US 2215295A
Authority
US
United States
Prior art keywords
vermiculite
steel
coating
sheet steel
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US79941A
Inventor
Morrill Weston
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co
Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Priority to US79941A priority Critical patent/US2215295A/en
Priority to DEA82923D priority patent/DE706944C/en
Application granted granted Critical
Publication of US2215295A publication Critical patent/US2215295A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F27/00Details of transformers or inductances, in general
    • H01F27/24Magnetic cores
    • H01F27/245Magnetic cores made from sheets, e.g. grain-oriented
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F41/00Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
    • H01F41/02Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
    • H01F41/0206Manufacturing of magnetic cores by mechanical means
    • H01F41/0233Manufacturing of magnetic circuits made from sheets
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/90Magnetic feature

Definitions

  • expanded vermiculite which is an aluminum-magnesium silicate sold under 25 the trade name Zonolite
  • the expanded material is obtained by introducing crude vermiculite into an expansion furnace heated at about 2000 F. This results in the production of a honeycombed 30 brittle granule which immediate cooling toughens into a durable aggregate in a manner well known inthe art.
  • the mixing of the water and expanded vermiculite is effected by grinding the vermiculite and water mixture until the ver- 35 miculite is in an extremely finely divided state producing a suspension of vermiculite in water and having about the consistency of house paint. This condition may be obtained by ball milling the water vermiculite mixture for about 20 to 24,
  • the vermiculite initially being capable of passing through a 60 mesh screen.
  • the particles of vermiculite after mixing in the ball mill are in the form of small leaves or fiat crystals.
  • the water-vermiculite mixture thus prepared 45 is in effect a paint in which water is the vehicle instead of oil. It may be applied to sheet steel by means of a brush, spray, or rubber rolls and then dried in an oven at a temperature suinciently high to evaporate the water.
  • the coated 50 sheets may be annealed in the usual manner, i. e.,
  • the water vermiculite coating applied to silicon steel laminations as heretofore 55 pointed out provides a high degree of insulation between successive laminations andappears to give a relatively small reduction in total watt loss, i. e., up to about 2.5% as compared with laminated sheets having a core plate enamel coating. This reduction in watt loss is possibly due to the fact-that the coating prevents excessive oxidation of the sheet steel. Furthermore, the coating prevents sticking together of the steel sheets during the annealing process.
  • vermiculite forms a very tight coating which cannot be rubbed off the steel or removed any easier than the regular anneal scale and gives a surface insulation resistance which is greater in both air and hot oil than that which can be obtained with core plate enamel heretofore employed in transformer construction.
  • vermiculite insulation forms a very thin film coating and causes no appreciable increase in the space factor permissible in transformer construction.
  • the vermiculite during the annealing process, apparently combines with the natural scale formation on the steel thereby providing a highly insulating coat. vermiculite, however, even without the assistance of the steel scale is a particularly efilcient insulator due to its leafing action.
  • vermiculite While I prefer to employ a mixture of about 20 parts vermiculite and about 100 parts of water, these quantities are not critical and may be varied widely. Also, instead of employing water, I may mix the vermiculite with Water solutions which may be beneficial to the steel. Although I prefer to employ a mixture of vermiculite and water, I may employ instead of the vermiculite other materials having approximately the same chemical analysis or crystallographic form.
  • the method of electrically insulating sheet steel which comprises applying to the steel a film consisting of a mixture of water and expanded vermiculite, drying the mixture to evaporatethe water and baking the vermiculite onto the steel during an anneal.
  • Silicon steel sheets suitable for use in transformer laminations said sheets having an electrically insulating film thereon, said film consisting substantially of vermiculite baked thereon.
  • Annealed silicon steel having a coating thereon, said coating consisting of vermiculite bonded to the natural scale formation of the steel.
  • Annealed silicon steel having a coating thereon, said coating consisting of vermiculite bonded to the natural scale formation of the steel, said coating being free from alkaline bonding ma- 10 terial.
  • Siliconsteel having a thin, tight, insulating coating thereon, said coating consisting substantially of vermiculitebonded to said steel and having the property of preventing sticking and excessive oxidation during anneal and causing no appreciable increase in the space factor when the coated steel is employed as laminations in transformer cores.

Landscapes

  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Paints Or Removers (AREA)
  • Soft Magnetic Materials (AREA)

Description

Patented Sept. 17, 1940 UNITED STATES PATENT OFFICE SURFACE INSULATION FOR MAGNETIC SHEET STEEL Weston Morrill, Pittsfield, Mass., assignor to General Electric Company, a corporation of New The present invention relates to the use of insulated coatings on sheet steel and more particularly to the use of very thin inorganic coatings adapted for use on transformer laminations.
Prior to the present invention, it has been customary in the construction of laminated transformer cores to coat thesheet steel laminations after anneal with a core plate enamel to provide a .suitable space relation between the laminated sheets.
It is one of the objects of the presentinvention to provide an inexpensive insulation coating on sheet steel which is suitable for use on transformer laminations and may be applied to the laminations before annealing. It is also an object of my invention to provide an insulating coating which not only has the ability to so insulate the surface of the steel that the use of a core plate enamel may be eliminated but also 0 the ability to prevent the laminations from sticking together during the annealing process.
In carrying out my invention, I mix about 20 parts by weight of expanded vermiculite, which is an aluminum-magnesium silicate sold under 25 the trade name Zonolite, with about 100 parts by weight of water. The expanded material is obtained by introducing crude vermiculite into an expansion furnace heated at about 2000 F. This results in the production of a honeycombed 30 brittle granule which immediate cooling toughens into a durable aggregate in a manner well known inthe art. The mixing of the water and expanded vermiculite is effected by grinding the vermiculite and water mixture until the ver- 35 miculite is in an extremely finely divided state producing a suspension of vermiculite in water and having about the consistency of house paint. This condition may be obtained by ball milling the water vermiculite mixture for about 20 to 24,
40 hours, the vermiculite initially being capable of passing through a 60 mesh screen. The particles of vermiculite after mixing in the ball mill are in the form of small leaves or fiat crystals.
The water-vermiculite mixture thus prepared 45 is in effect a paint in which water is the vehicle instead of oil. It may be applied to sheet steel by means of a brush, spray, or rubber rolls and then dried in an oven at a temperature suinciently high to evaporate the water. The coated 50 sheets may be annealed in the usual manner, i. e.,
in a pack in a furnace having a roof temperature of about 875 C. and an atmosphere of air or neutral gas. The water vermiculite coating applied to silicon steel laminations as heretofore 55 pointed out provides a high degree of insulation between successive laminations andappears to give a relatively small reduction in total watt loss, i. e., up to about 2.5% as compared with laminated sheets having a core plate enamel coating. This reduction in watt loss is possibly due to the fact-that the coating prevents excessive oxidation of the sheet steel. Furthermore, the coating prevents sticking together of the steel sheets during the annealing process. The vermiculite forms a very tight coating which cannot be rubbed off the steel or removed any easier than the regular anneal scale and gives a surface insulation resistance which is greater in both air and hot oil than that which can be obtained with core plate enamel heretofore employed in transformer construction.
The vermiculite insulation forms a very thin film coating and causes no appreciable increase in the space factor permissible in transformer construction. The vermiculite, during the annealing process, apparently combines with the natural scale formation on the steel thereby providing a highly insulating coat. vermiculite, however, even without the assistance of the steel scale is a particularly efilcient insulator due to its leafing action.
While I prefer to employ a mixture of about 20 parts vermiculite and about 100 parts of water, these quantities are not critical and may be varied widely. Also, instead of employing water, I may mix the vermiculite with Water solutions which may be beneficial to the steel. Although I prefer to employ a mixture of vermiculite and water, I may employ instead of the vermiculite other materials having approximately the same chemical analysis or crystallographic form.
What I claim as new. and desire to secure by Letters Patent of the United States, is:
l. The method of electrically insulating sheet steel which comprises applying to the steel a film consisting of a mixture of water and expanded vermiculite, drying the mixture to evaporatethe water and baking the vermiculite onto the steel during an anneal.
2. In the'manfacture of magnetic sheet steel, 5 the process which comprises coating said steel sheets prior to annealing with an electrically insulating film consisting of a water-vermiculite mixture.
3. Sheet steel suitable for use as a transformer lamination and having an insulating coating thereon, said coating consisting substantially of a vermiculite film baked onto said sheet steel.
Silicon steel sheets suitable for use in transformer laminations, said sheets having an electrically insulating film thereon, said film consisting substantially of vermiculite baked thereon.
5. Annealed silicon steel having a coating thereon, said coating consisting of vermiculite bonded to the natural scale formation of the steel.
6. Annealed silicon steel having a coating thereon, said coating consisting of vermiculite bonded to the natural scale formation of the steel, said coating being free from alkaline bonding ma- 10 terial.
7. Siliconsteel having a thin, tight, insulating coating thereon, said coating consisting substantially of vermiculitebonded to said steel and having the property of preventing sticking and excessive oxidation during anneal and causing no appreciable increase in the space factor when the coated steel is employed as laminations in transformer cores.
WESTON MQRRILL. 10
US79941A 1936-05-15 1936-05-15 Surface insulation for magnetic sheet steel Expired - Lifetime US2215295A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US79941A US2215295A (en) 1936-05-15 1936-05-15 Surface insulation for magnetic sheet steel
DEA82923D DE706944C (en) 1936-05-15 1937-05-12 Insulating material, especially for magnetic sheets

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US79941A US2215295A (en) 1936-05-15 1936-05-15 Surface insulation for magnetic sheet steel

Publications (1)

Publication Number Publication Date
US2215295A true US2215295A (en) 1940-09-17

Family

ID=22153798

Family Applications (1)

Application Number Title Priority Date Filing Date
US79941A Expired - Lifetime US2215295A (en) 1936-05-15 1936-05-15 Surface insulation for magnetic sheet steel

Country Status (2)

Country Link
US (1) US2215295A (en)
DE (1) DE706944C (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2426445A (en) * 1943-07-07 1947-08-26 Gen Electric Insulation for magnetic steel and the like
US2457515A (en) * 1941-11-13 1948-12-28 Bell Telephone Labor Inc Insulating coating compositions and method of making
US2558411A (en) * 1945-05-22 1951-06-26 Battelle Development Corp Ceramic coating composition, coated article, and method of making same
US2704978A (en) * 1953-03-12 1955-03-29 Du Pont Electrically fired gas expansion blasting device
US2906649A (en) * 1955-04-07 1959-09-29 Siemens Ag Heat-resistant electric insulation and method of manufacture
US3001571A (en) * 1957-08-05 1961-09-26 Minnesota Mining & Mfg Synthetic mica flakes and structures
US3274019A (en) * 1964-11-06 1966-09-20 Alton V Oberholtzer Impregnation and coating with splitoffs of vermiculite and products thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2457515A (en) * 1941-11-13 1948-12-28 Bell Telephone Labor Inc Insulating coating compositions and method of making
US2426445A (en) * 1943-07-07 1947-08-26 Gen Electric Insulation for magnetic steel and the like
US2558411A (en) * 1945-05-22 1951-06-26 Battelle Development Corp Ceramic coating composition, coated article, and method of making same
US2704978A (en) * 1953-03-12 1955-03-29 Du Pont Electrically fired gas expansion blasting device
US2906649A (en) * 1955-04-07 1959-09-29 Siemens Ag Heat-resistant electric insulation and method of manufacture
US3001571A (en) * 1957-08-05 1961-09-26 Minnesota Mining & Mfg Synthetic mica flakes and structures
US3274019A (en) * 1964-11-06 1966-09-20 Alton V Oberholtzer Impregnation and coating with splitoffs of vermiculite and products thereof

Also Published As

Publication number Publication date
DE706944C (en) 1941-06-10

Similar Documents

Publication Publication Date Title
US1924311A (en) Insulating material
US4496399A (en) Method and aqueous coating compositions for forming anti-stick and insulative coatings on semi-processed and fully-processed electrical steels
CN110643796B (en) Preparation method of high-magnetic-induction oriented silicon steel with good bottom layer adhesion
CN109628717B (en) Method for manufacturing low-temperature high-magnetic-induction oriented silicon steel with excellent bottom layer
US2215295A (en) Surface insulation for magnetic sheet steel
AU2020102813A4 (en) Insulation coating solution for improving cracks on coating of grain oriented silicon steel, method for making same, and grain oriented silicon steel sheet
US4318758A (en) Method for producing a grain-oriented magnetic steel sheet having good magnetic properties
US2385332A (en) Production of silicon steel sheet stock having insulative surfaces
US2364436A (en) Insulation for magnetic steel and the like
KR100967049B1 (en) Method for manufacturing a high-silicon steel sheet
JPS6253589B2 (en)
WO2020143168A1 (en) Coating for directional electromagnetic steel plate and preparation method therefor
JP2018028140A (en) Chromium-free tensile film-forming process liquid, chromium-free tensile film-attached grain-oriented electromagnetic steel sheet, method for producing chromium-free tensile film-attached grain-oriented electromagnetic steel sheet, and transformer core
US2426445A (en) Insulation for magnetic steel and the like
US3073722A (en) Process for coating ferrous material and material coated by such process
US3150015A (en) Insulation for silicon steel
US2809137A (en) Insulating coating for magnetic sheet material and method of making the same
JPS60255980A (en) Insulative coating composition for electric steel
KR880001310B1 (en) Low temperature cure interlaminar coating
JP5422937B2 (en) Insulating film coating solution and method for forming insulating film for grain-oriented electrical steel sheet
JP2654862B2 (en) Method for forming insulation film on grain-oriented electrical steel sheet with excellent core workability and dust resistance
JPH101779A (en) High tensile strength insulating coating film forming agent, its formation and grain oriented silicon steel sheet having high tensile strength insulating coating film
US3082133A (en) High temperature electrical insulating tape
US4207123A (en) Coatings for reduced losses in (110) [001] oriented silicon iron
WO2019188585A1 (en) Coating liquid for forming insulating coating film for grain-oriented electromagnetic steel sheets, method for producing grain-oriented electromagnetic steel sheet, and grain-oriented electromagnetic steel sheet