US2213972A - Artificial fiber suitable for yielding dyeings fast to fulling - Google Patents
Artificial fiber suitable for yielding dyeings fast to fulling Download PDFInfo
- Publication number
- US2213972A US2213972A US164334A US16433437A US2213972A US 2213972 A US2213972 A US 2213972A US 164334 A US164334 A US 164334A US 16433437 A US16433437 A US 16433437A US 2213972 A US2213972 A US 2213972A
- Authority
- US
- United States
- Prior art keywords
- fulling
- fibers
- fast
- artificial
- wool
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002994 synthetic fiber Polymers 0.000 title description 23
- 238000004043 dyeing Methods 0.000 title description 21
- 238000009963 fulling Methods 0.000 title description 16
- 239000000835 fiber Substances 0.000 description 16
- 210000002268 wool Anatomy 0.000 description 13
- 229920000297 Rayon Polymers 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 229920000768 polyamine Polymers 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 6
- 238000009987 spinning Methods 0.000 description 6
- 239000004744 fabric Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- BJQWYEJQWHSSCJ-UHFFFAOYSA-N Heptacosane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCC BJQWYEJQWHSSCJ-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229920001281 polyalkylene Polymers 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- PAAZPARNPHGIKF-UHFFFAOYSA-N 1,2-dibromoethane Chemical compound BrCCBr PAAZPARNPHGIKF-UHFFFAOYSA-N 0.000 description 1
- KNKRKFALVUDBJE-UHFFFAOYSA-N 1,2-dichloropropane Chemical compound CC(Cl)CCl KNKRKFALVUDBJE-UHFFFAOYSA-N 0.000 description 1
- BUEWYDIBDQYWNO-UHFFFAOYSA-N 7,12-dihydroxynaphtho[2,3-f]quinoline-5,6-dione Chemical compound Oc1c2C(=O)C(=O)c3ncccc3-c2c(O)c2ccccc12 BUEWYDIBDQYWNO-UHFFFAOYSA-N 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000792765 Minous Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- QKSIFUGZHOUETI-UHFFFAOYSA-N copper;azane Chemical compound N.N.N.N.[Cu+2] QKSIFUGZHOUETI-UHFFFAOYSA-N 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- ORFSSYGWXNGVFB-UHFFFAOYSA-N sodium 4-amino-6-[[4-[4-[(8-amino-1-hydroxy-5,7-disulfonaphthalen-2-yl)diazenyl]-3-methoxyphenyl]-2-methoxyphenyl]diazenyl]-5-hydroxynaphthalene-1,3-disulfonic acid Chemical compound COC1=C(C=CC(=C1)C2=CC(=C(C=C2)N=NC3=C(C4=C(C=C3)C(=CC(=C4N)S(=O)(=O)O)S(=O)(=O)O)O)OC)N=NC5=C(C6=C(C=C5)C(=CC(=C6N)S(=O)(=O)O)S(=O)(=O)O)O.[Na+] ORFSSYGWXNGVFB-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
- D06P5/225—Aminalization of cellulose; introducing aminogroups into cellulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/22—Cellulose xanthate
- C08L1/24—Viscose
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/64—Natural or regenerated cellulose using mordant dyes or metallisable dyes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S106/00—Compositions: coating or plastic
- Y10S106/07—Asphalt binders in coating compositions
Definitions
- Our present invention is a continuation in part of the said application and relates likewise to artificial fibers suitable for yielding dyeings fast to fulling and process of making same.
- artificial fibers suitable for yielding dyeings fast to fulling' are obtained by incorporating to artificial fibers during their process of manufacture either single or as mixtures nitrogenous bases which contain on the one side an aliphatic radicle of a long chain of carbon atoms, on the other side the chloride and other similar halogenidesd which are fast to boiling.
- Artificial fibers of the aforesaid kind may be mixed with wool and such mixtures may be dyed according to the single-bath process by means of metachrome dyestufls with the production of equal dyeings, fast to fulling.
- nitrogenous base which are to be incorporated in the artificial fibers there may be named particularly the condensation product of halogenation products of hard'paraffin (i. e., the well known technical product-of 54 to 56 melting point, consisting of a mixture of saturated hydrocarbons ranging from tetracosan C24H5o to heptacosan Cz'zHss, cf. Ullmann, Enzyklopadie der ischen Chemie, second edition (1912) vol. 2, page 611 ff.) with 'polyalkylene polyamines.
- hard'paraffin i. e., the well known technical product-of 54 to 56 melting point, consisting of a mixture of saturated hydrocarbons ranging from tetracosan C24H5o to heptacosan Cz'zHss, cf. Ullmann, Enzyklopadie der ischen Chemie, second edition (1912) vol. 2, page 611 ff.
- polyalkylene polyamines there may be usedfor the purpose of the present invention particularly the reaction products of ammonia with alkylenc polyhalogenides like ethylene dichloride, ethylene dibromide, propylene dichloride, the halogeno derivatives, of glycerine, butylene dipolyallzylene polyamines thus obtained usually consist of several components of different molecular weight-for example of dialkylene triamines, trialkvlene tetramines and so on. For the present inventionparticularly the crude mixture of these productsmay be used as starting material.
- alkylenc polyhalogenides like ethylene dichloride, ethylene dibromide, propylene dichloride, the halogeno derivatives, of glycerine, butylene dipolyallzylene polyamines thus obtained usually consist of several components of different molecular weight-for example of dialkylene triamines, trialkvlene tetramines and so on.
- the crude mixture of these products may be used as starting material.
- the aforesaid nitrogenous bases may be incorporated single or a plurality thereof, in a given case in admixture with a suitable aliphatic polyamine which has not been subjected to the above condensation reaction.
- the artificial fiber is a viscose material
- agents capable of removing water for instance an artificial fiber which is obtained by treatment with agents capable of removing water.
- the fibers before the dyeing process to a cleansing operation using reducing agents such as for example hydrosulfite.
- Example 1 YA viscose material whichis prepared by employing a viscose ripened below the usual ripeness is mixed before spinning in a suitable mixfly-- ing vessel for instance in a Werner-Pfleiderer apparatus with 3% of its-weight (with respect to the content of cellulose) of an aqueous suspension of a base obtained by condensing trichloro-hard parafiine with polyethylene-polyamine.
- trichloroderivative hard parafiine of 54 to 56 C. melting point has been chlorinated by introducing chlorine at temperatures beginning at 80 and ending at 50-60% until an increase in weight corresponding'to the entrance of three chlorine atoms has taken place (cf. U. S.
- Patent 1,948,- 924 The above polyethylene polyamine mixture has been prepared by acting with aqueous ammonia on ethylene chloride and removing the fractions, boiling under 10 mm. pressure up to 220, by distillation. The residue thus obtained is a viscous brown liquor). The viscose material is spun, acidified, washed and drawn through a hot hydrosulfite bath in order to cleanse it. Then it is washed again and finally treated with alcohol in accordance with the process of our U. S. Patent 2,109,306, February 22, 1938. The fiber thus obtained is distinguished by a woollike appearance.
- A' textile fabric obtained from the new fiber mixed with wool may be dyed for example with Metachrome Brilliant Blue 8RL (Schultz, Farbstofitabellen, 7th edition, supplement, vol. I, page 111) whereby equal dyeings are obtained, fast to fulling.
- Metachrome Brilliant Blue 8RL Schotz, Farbstofitabellen, 7th edition, supplement, vol. I, page 111
- Example 2 In a viscose material of the usual degree of ripeness 2% f its weight of the same base as used in Example 1 are incorporated in the above described manner and the viscose is spun in the usual manner. The well washed product is treated at about 50 with a solution of hydrogen peroxide of 1% strength whereby a light fibrous material is obtained, even when a remarkably colored base is used.
- a textile fabric obtained from the new fiber may be mixed with wool and dyed for example with Metachrome-olive brown (Schultz, Farbstofftabellen, 7th edition, N0. 142) or Metachromebrown CG (1. 0., vol. 11, page 146) whereby intense and equal dyeings are obtained, entirely fast to fulling.
- Example 3 In a viscose material as used in Example 1 immediately while dissolving it or thereafter 4% of its weight of a mixture are incorporated, which consists in the same proportions of the base used in the foregoing examples, of the condensation exhibits a very wool like character and yields,
- Example 4 A copper-ammonia cellulose spinning solution as usual for spinning copper silk is mixed in a good mixing vessel with 2% ofits weight (related to the cellulose content of the solution) of the condensationproduct as' described in Example 1. Then the solution is shortly deaerated and spun in a spinning funnel into water, soured, cut up and worked up as usual. In a given case to the after-treating bath hydrogen peroxide may be added. In this manner a textile fabric is obtainable whichmay be dyed in admixture with wool with a suitable dyestuff, for instance a metachrome dyestuif, thus yielding dyeings, fast to fulling.
- a suitable dyestuff for instance a metachrome dyestuif
- An artificial fiber in accordance with claim 3 dyed with a metachrome dyestufi.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEI53759D DE734243C (de) | 1935-11-30 | 1935-11-30 | Verfahren zur Herstellung von beispielsweise mit Farbstoffen von Typus der Metachromfarbstoffe walkecht faerbbaren Kunstfasern aus regenerierter Cellulose |
| GB942636A GB472964A (en) | 1936-03-30 | 1936-03-30 | Improvements in or relating to the manufacture of artificial fibres suitable for admixture with wool and the dyeing of such mixed goods |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2213972A true US2213972A (en) | 1940-09-10 |
Family
ID=25981914
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US164334A Expired - Lifetime US2213972A (en) | 1935-11-30 | 1937-09-17 | Artificial fiber suitable for yielding dyeings fast to fulling |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US2213972A (en, 2012) |
| BE (1) | BE418585A (en, 2012) |
| DE (1) | DE734243C (en, 2012) |
| FR (1) | FR813716A (en, 2012) |
| NL (1) | NL50595C (en, 2012) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3066032A (en) * | 1959-05-26 | 1962-11-27 | Kurashiki Rayon Co | Method of making fibers of regenerated cellulose of improved dyeing properties |
-
0
- BE BE418585D patent/BE418585A/xx unknown
- NL NL50595D patent/NL50595C/xx active
-
1935
- 1935-11-30 DE DEI53759D patent/DE734243C/de not_active Expired
-
1936
- 1936-11-18 FR FR813716D patent/FR813716A/fr not_active Expired
-
1937
- 1937-09-17 US US164334A patent/US2213972A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3066032A (en) * | 1959-05-26 | 1962-11-27 | Kurashiki Rayon Co | Method of making fibers of regenerated cellulose of improved dyeing properties |
Also Published As
| Publication number | Publication date |
|---|---|
| FR813716A (fr) | 1937-06-08 |
| BE418585A (en, 2012) | |
| NL50595C (en, 2012) | |
| DE734243C (de) | 1943-04-10 |
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