US2211369A - Dentifrice - Google Patents

Dentifrice Download PDF

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Publication number
US2211369A
US2211369A US244361A US24436138A US2211369A US 2211369 A US2211369 A US 2211369A US 244361 A US244361 A US 244361A US 24436138 A US24436138 A US 24436138A US 2211369 A US2211369 A US 2211369A
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US
United States
Prior art keywords
dentifrice
magnesium pyrophosphate
finely divided
insoluble
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US244361A
Inventor
Charles B Durgin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Chemicals Ltd
Monsanto Chemical Co
Original Assignee
Monsanto Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Chemicals Ltd filed Critical Monsanto Chemicals Ltd
Priority to US244361A priority Critical patent/US2211369A/en
Application granted granted Critical
Publication of US2211369A publication Critical patent/US2211369A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/24Phosphorous; Compounds thereof

Definitions

  • the present invention relates to an improved dentifrice.
  • One object of the present invention is to provide an improved polishing and cleansing agent a for dentifrice purposes.
  • magnesium pyrophosphate, MgzPzOv in finely divided form is an excellent dentifrice. Its use as a dentifrice or as an ingredient thereof restores the natural color and lustre of the teeth. It can be prepared by precipitation from Water solutions as a soft nonabrasive powder which has no action upon the surfaces of the teeth. Moreover, it is sumciently insoluble both in acid, neutral and basic solution so that it can be used both in acid and in basic dentifrlces.
  • the magnesium pyrophosphate When used in a tooth paste the magnesium pyrophosphate may be combined with varying 95 percentages of glycerine, gums, water, flavoring agents, massing agents, etc.
  • various wetting, emulsifying or foaming agents such as the esters of the higher aliphatic alcohols for example soluble 25 salts of sulfuric acid esters of lauryl or myristyl phate various other dry salts.
  • I may make mixtures of magnesium pyrophosphate and di or tricalcium phosphate, calcium carbonate, insoluble sodium metaphosphate. 1 may also incorporate wetting, em --4;'"
  • a further advantage which may be obtained by the use of magnesium pyrophosphate is the w inherently lower abrasive index commensurate with absorption of glycerine in the manufacture of pastes. It is generally known that materials which are inherently light and bulky, will gen- ,erally exhibit low abrasive characteristics. As
  • MgzPzOr the anhydrous form of magnesium pyrophosphate
  • MgzPzOwBHzO the trihydrated form
  • a dentifrice base comprising finely divided, W insoluble magnesium pyrophosphate.
  • a dentifrice comprising finely divided, insoluble magnesium pyrophosphate and a wetting emulsifying or sudsing agent.
  • a dentifrice comprising finely divided, insoluble magnesium pyrophosphate, MgzPzOr, and an alkali metal Salt of an allnvlated aromatic sulfonic acid whereinthe alkyl group contains more than eight and less than sixteen carbon atoms.
  • a dentifrice comprising finely divided, in- 35 soluble magnesium pyrophosphate trihydrate.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Description

Patented Aug. i3, 194@ tjharies B. Dun-gin, ton, assignor to Monsanto Chemical Company, a corporation of Delaware No Drawing. Application December 7, 1938, Serial No. 2%,361
The present invention relates to an improved dentifrice.
One object of the present invention is to provide an improved polishing and cleansing agent a for dentifrice purposes.
I have found that magnesium pyrophosphate, MgzPzOv in finely divided form is an excellent dentifrice. Its use as a dentifrice or as an ingredient thereof restores the natural color and lustre of the teeth. It can be prepared by precipitation from Water solutions as a soft nonabrasive powder which has no action upon the surfaces of the teeth. Moreover, it is sumciently insoluble both in acid, neutral and basic solution so that it can be used both in acid and in basic dentifrlces.
I may use this material both in tooth pastes and in tooth powders.
When used in a tooth paste the magnesium pyrophosphate may be combined with varying 95 percentages of glycerine, gums, water, flavoring agents, massing agents, etc. In addition there may be incorporated various wetting, emulsifying or foaming agents such as the esters of the higher aliphatic alcohols for example soluble 25 salts of sulfuric acid esters of lauryl or myristyl phate various other dry salts. In particular I may make mixtures of magnesium pyrophosphate and di or tricalcium phosphate, calcium carbonate, insoluble sodium metaphosphate. 1 may also incorporate wetting, em --4;'"| or sudsing agents in the dry form such as above mentioned.
(CE. res-=93) While it has been proposed to use trimagnesium orthophosphate as a polishing agent for dentifrices the incorporation of the magnesium pyrophosphate presents certain definite advantages. The use of the latter compound in place of the 5 orthophosphate makes it possible to prepare acid dentifrice compositions, as well as neutral or basic compositions.
A further advantage which may be obtained by the use of magnesium pyrophosphate is the w inherently lower abrasive index commensurate with absorption of glycerine in the manufacture of pastes. It is generally known that materials which are inherently light and bulky, will gen- ,erally exhibit low abrasive characteristics. As
the bulk increases the glycerine absorption also 15 increases, which is objectionable from an economic standpoint.
I prefer to use either the anhydrous form of magnesium pyrophosphate, MgzPzOr, or the trihydrated form, MgzPzOwBHzO. This material is til very finely divided for this purpose it being desirable that the material be passed through a 200 mesh screen prior to such use.
What I claim is:
1. A dentifrice base comprising finely divided, W insoluble magnesium pyrophosphate.
2. A dentifrice comprising finely divided, insoluble magnesium pyrophosphate and a wetting emulsifying or sudsing agent.
3. A dentifrice comprising finely divided, insoluble magnesium pyrophosphate, MgzPzOr, and an alkali metal Salt of an allnvlated aromatic sulfonic acid whereinthe alkyl group contains more than eight and less than sixteen carbon atoms.
a. A dentifrice comprising finely divided, in- 35 soluble magnesium pyrophosphate trihydrate.
CHARLES B. D'URGIN.
US244361A 1938-12-07 1938-12-07 Dentifrice Expired - Lifetime US2211369A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US244361A US2211369A (en) 1938-12-07 1938-12-07 Dentifrice

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2673364A (en) * 1948-05-04 1954-03-30 Twix Inc Dental cleaning pad
US2941926A (en) * 1954-12-14 1960-06-21 Colgate Palmolive Co Chlorophyll dental powder
US3227617A (en) * 1955-04-25 1966-01-04 Colgate Palmolive Co Fluoride dentifrice composition

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2673364A (en) * 1948-05-04 1954-03-30 Twix Inc Dental cleaning pad
US2941926A (en) * 1954-12-14 1960-06-21 Colgate Palmolive Co Chlorophyll dental powder
US3227617A (en) * 1955-04-25 1966-01-04 Colgate Palmolive Co Fluoride dentifrice composition

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