US2210761A - Cathode - Google Patents

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US2210761A
US2210761A US104465A US10446536A US2210761A US 2210761 A US2210761 A US 2210761A US 104465 A US104465 A US 104465A US 10446536 A US10446536 A US 10446536A US 2210761 A US2210761 A US 2210761A
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cathode
wire
core
tungsten
filaments
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US104465A
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Edward F Hennelly
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General Electric Co
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General Electric Co
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J1/00Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
    • H01J1/02Main electrodes
    • H01J1/13Solid thermionic cathodes
    • H01J1/15Cathodes heated directly by an electric current

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  • the present invention relates to improvements in cathodes for electric discharge devices.
  • An important aspect of the invention consists ii in improvements in the structure and materials of cathodes of the so-called overwound filamen type.
  • a specific feature which is consid ered to be of particular importance in this connection consists in the application to a conductive core member of a composite overwinding structure which consists of a plurality of separate wires assembled in inter-engaging relation to form a framework having a large number of crevices suitable for the retention of emissive material.
  • Fig. l is a side elevation of a discharge device suitably incorporating my invention
  • Fig. 2 is a view in partial section showing in enlarged detail the structural features of the invention
  • Fig. 3 is a sectional view of a fragmentary portion of the structure of Fig. 2.
  • a central supporting member I which for convenience may be referred to as a wire mandrel and which preferably consists of a refractory electrical conductor such as tungsten wire. It will be understood that the drawing greatly magnifies the dimensions of this mandrel, and that its actual diameter may be on the order of a small fraction of an inch, for example, 4 mils.
  • the structure-which overlies the central element I is of complex nature comprising a filamentary core 2 having a second filament 4 helically wound in open convolutions thereon.
  • the composite structure is coated with a quantity of highly electron emissive material 5 which preferably only partially fills
  • the novel features of my invention which the spaces or grooves formed between the various turns of the overwound filaments.
  • this coating is illustrated only in Fig. 3 which shows a straightened section of the core 2 and the filamentary overwinding 3.
  • the emissive material pref- 5 erably covers all parts of the cathode includinB the wire mandrel I.
  • the I various filaments, including the core member I, 10 are of the same material and comprise a metal of the group comprising tungsten and molyb denum. The fulfillment of this condition assures maximum total emission since the fact that all parts of the cathode are of identical composition 18 makes it certain that the entire exposed surface will take part in the electron emission.
  • thorium oxide While other electron emissive substances may be used, for example, barium oxide, I prefer to employ a compound of thorium, such as thoria, 20 as the coating material. With such a material in combination with an overwound cathode of tungsten or molybdenum, extremely long life is realized as well as excellent ability to resist stripping of the cathode surface under the influence 5 of positive ion bombardment. Furthermore, an overwound cathode comprising tungsten coated with thorium oxide (thoria) is characterized by unusual stability or constancy of emission throughout its operative life. I 30 The thorium oxide may be applied in any known manner as by spraying or dipping the base metal.
  • the thorium may be activated by heating the filament to a temperature less than that at which substantial evaporation of the thoria takes place, for example, at about 1600 C., and passing through the cathode a discharge current considerably in excess of its normal rating, such current being maintained only for a relatively brief period of time.
  • the activating process may be carried out either in vacuum or in a blanketing atmosphere such as an atmosphere of argon gas.
  • the preferred arrangement or the overwinding for producing both maximal emission and heat conservation is that in which the spacing between adjacent filamentary turns is on the order of but somewhat less than the diameter of the wires themselves.
  • the desired conditions with respect to spacing will be satisfactorily fulfilled if the product of the wire diameter, expressed in mils, times the number of turns 01' wire per inch is approximately 600.
  • a particular cathode constructed in accordance with this formula may suitably comprise a filament of 2 mil tungsten wound with about 300 turns per inch of a 4 mil tungsten core, the core in turn being wound on a 4 mil wire mandrel in a helix having about 70 turns per inch. From the standpoint of economy of base material best results are obtained when the various filaments used in the overwound assembly are of as nearly the same size as is mechanically practicable.
  • FIG. 1 A typical mode of use of my improved cathode is illustrated inFig. 1.
  • a sealed envelope 8 suitably of glass having at the lower end a reentrant stem 9 terminating in a press It.
  • a conventional anode II for example, of graphite supported on and supplied with energizing current through a suitable leadin conductor l3.
  • a cathode ii supported on lead-in conductors l1 and I8 which in turn are sealed into the press It.
  • the cathode as a whole is of helical configuration, the helix being formed by bending the central element of the cathode, corresponding to the mandrel I of Fig. 2, into the desired shape.
  • the envelope I may suitably enclose an ionizing medium comprising gas or vapor at a pressure of from a fraction of a millimeter to a few centimeters.
  • an ionizing medium comprising gas or vapor at a pressure of from a fraction of a millimeter to a few centimeters.
  • argon having a pressure of from 1 to 2 millimeters in combination with mercury having at the operating temperature of the device a vapor pressure of from about millimeter to about 3 millimeters.
  • the cathodes of my invention are not limited to this particular field but are equally useful in connection with high vacuum discharge devices such as are conventionally used in radio and therapeutic applications.
  • a first wire serving as a corexnember and having a second wire overwound thereon in such a manner that the spacing between adjacent turns is of the order of I but somewhat less than the diameter of the second wire, and a quantity of highly electron emissive material only partially filling the grooves formed between such adjacent turns.
  • An electrode structure comprising a tungsten wire having wound thereon an open helix comprising a first filament serving as a core member and a second filament helically wound in open convolutions on said core member, said first and second filaments also consisting of tungsten, and means for augmenting the electron emissivity of said filaments.
  • a cathode comprising two or more filaments each constituted of a metal of the group consisting of tungsten and molybdenum, said filaments being arranged in successively overwound relation and being provided with a coating of highly electron emissive material.
  • a cathode which includes a wire core member having a second wire helically wound in open convolutions thereon, and a quantity of thorium oxide disposed in the grooves formed by said convolutions, said wires being constituted of a metal of the group consisting of tungsten and molybdenum.
  • a cathode comprising an elongated metal wire having applied thereto a composite structure including a first metal filament serving as a core member, a second metal filament wound on said core member and means for augmenting the electron emissivity of said filaments.
  • a cathode comprising a tungsten wire having wound thereon a composite structure consisting of a first tungsten filament serving as a core member, a second tungsten filament wound on the core member and a coating of thorium oxide applied to said filaments.
  • An incandescible cathode comprising a metal core wire; a helix of thin metal wire, said helix being helically wound on said core wire and embracing same therewith, and a highly electronemissive substance carried by said helically wound helix.
  • An incandescible cathode comprising a metal core wire, a coil of thin metal wire, said coil being coiled around said core wire and forming a coiled coil, each turn of the outer coil being in contact with the core, and a highly electron-emissive substance carried by said coiled-coil and at least partly filling the hollows and recesses thereof.
  • An incandescible cathode comprising a metal core wire serving as a support and current conductor, a skeleton wire structure surrounding said core wire and having a plurality of apertured layer-like portions formed of helically-wound metal wire, adjacent portions being electrically connected only at interspaced points and the inner portion embracing said core wire, and a highly electron-emissive substance at least partly filling the spaces formed within said structure and securely held thereby.
  • a cathode including an elongated metal core serving as a support and current conductor, a metallic overwinding closely embracing the core so as to be in contact with the core throughout a substantial portion of its length, the member forming the said overwinding being characterized by irregularities from point to point along its length so as to provide a materially larger number of crevices than would be provided by a helically applied overwinding of straight wire,
  • An incandescible cathode comprising an elongated metal core serving as a support and current conductor, a discontinuous metallic structure closely embracing the core so as to be in contact therewith throughout a substantial portion of its length, the said structure being constituted of a plurality of wires assembled in interengaging relation to form a framework which provides a large number of crevices both at and slightly spaced from the surface of the core, and a quantity of highly emissive material at least partially filling the said crevices.
  • a cathode comprising an elongated metal core serving as a support and current conductor. a metallic structure closely embracing the core so as to be in contact therewith throughout a substantial portion of its length, the said structure being constituted of a plurality of interengaging wires assembled in repetitively intersecting relation to form a framework which provides a large number of crevices both at and slightly spaced from the surface of the core, and a quantity of highly emissive material at least partially filling the said crevices.

Description

Aug. 6, 1940. HENNELLY 2.210,761
CATHODE Filed Oct. 7, 1956 Ihventor Edward F Henhel l g,
His Attorneg.
Patented Aug. 6, 1940 UNITED STATES PATENT OFFICE CATHODE New York Application October 1, 1936, Serial No. 104,465
12 Claims. (01. 250-215) The present invention relates to improvements in cathodes for electric discharge devices.
It is an object of the invention to provide in a filamentary type cathode an improved combination of base and coating materials conducive to long life, improved emission, and stability of emission.
It is a further object to provide an improved cathode structure which will produce a given thermionic electron emission with less power input, or which with a given power input will produce greater emission than the cathodes heretofore available.
An important aspect of the invention consists ii in improvements in the structure and materials of cathodes of the so-called overwound filamen type. A specific feature which is consid ered to be of particular importance in this connection consists in the application to a conductive core member of a composite overwinding structure which consists of a plurality of separate wires assembled in inter-engaging relation to form a framework having a large number of crevices suitable for the retention of emissive material.
I desire to protect herein will be pointed out with particularity in the appended claims. The invention itself, however, together with further objects and advantages thereof, will best be understood by reference to the following specification taken in connection with the drawing, in which Fig. l is a side elevation of a discharge device suitably incorporating my invention; Fig. 2 is a view in partial section showing in enlarged detail the structural features of the invention; and Fig. 3 is a sectional view of a fragmentary portion of the structure of Fig. 2.
Referring first to the cathode structure shown in Fig. 2, there is illustrated a central supporting member I which for convenience may be referred to as a wire mandrel and which preferably consists of a refractory electrical conductor such as tungsten wire. It will be understood that the drawing greatly magnifies the dimensions of this mandrel, and that its actual diameter may be on the order of a small fraction of an inch, for example, 4 mils.
In the example illustrated the structure-which overlies the central element I is of complex nature comprising a filamentary core 2 having a second filament 4 helically wound in open convolutions thereon. The composite structure is coated with a quantity of highly electron emissive material 5 which preferably only partially fills The novel features of my invention which the spaces or grooves formed between the various turns of the overwound filaments. For the sake of simplicity this coating is illustrated only in Fig. 3 which shows a straightened section of the core 2 and the filamentary overwinding 3. In actual use, however, the emissive material pref- 5 erably covers all parts of the cathode includinB the wire mandrel I.
In preparing composite cathodes in accordance with my invention best results are obtained if the I various filaments, including the core member I, 10 are of the same material and comprise a metal of the group comprising tungsten and molyb denum. The fulfillment of this condition assures maximum total emission since the fact that all parts of the cathode are of identical composition 18 makes it certain that the entire exposed surface will take part in the electron emission.
While other electron emissive substances may be used, for example, barium oxide, I prefer to employ a compound of thorium, such as thoria, 20 as the coating material. With such a material in combination with an overwound cathode of tungsten or molybdenum, extremely long life is realized as well as excellent ability to resist stripping of the cathode surface under the influence 5 of positive ion bombardment. Furthermore, an overwound cathode comprising tungsten coated with thorium oxide (thoria) is characterized by unusual stability or constancy of emission throughout its operative life. I 30 The thorium oxide may be applied in any known manner as by spraying or dipping the base metal. Thereafter the thorium may be activated by heating the filament to a temperature less than that at which substantial evaporation of the thoria takes place, for example, at about 1600 C., and passing through the cathode a discharge current considerably in excess of its normal rating, such current being maintained only for a relatively brief period of time. The activating process may be carried out either in vacuum or in a blanketing atmosphere such as an atmosphere of argon gas.
The high efilciency obtained by the combination of materials as set forth in the preceding paragraphs is still further enhanced by using complex overwinding such as is illustrated in Fig.
2. In addition to the increase in the emitting surface produced by this structure, the heat required to maintain a given cathode emission may be considerably reduced. This latter effect appears to be due to the mutual heat shielding provided, by the opposed surfaces of adjacent turns of each winding layer, so that an appreciable amount of heat is retained or conserved in 5 the grooves. Otherwise expressed, the portion of the surface of the combined assembly'capableof losing heat by free radiation may be made a'small part of thehtotal surface which contributes to the electron emission. In consequence, a given operating temperature may be maintained with from 10 to 20 per cent less wattage input than would be required for equivalent smooth or plane surfaces of equal electron emission.
The preferred arrangement or the overwinding for producing both maximal emission and heat conservation is that in which the spacing between adjacent filamentary turns is on the order of but somewhat less than the diameter of the wires themselves. Thus, the desired conditions with respect to spacing will be satisfactorily fulfilled if the product of the wire diameter, expressed in mils, times the number of turns 01' wire per inch is approximately 600. For example, a particular cathode constructed in accordance with this formula may suitably comprise a filament of 2 mil tungsten wound with about 300 turns per inch of a 4 mil tungsten core, the core in turn being wound on a 4 mil wire mandrel in a helix having about 70 turns per inch. From the standpoint of economy of base material best results are obtained when the various filaments used in the overwound assembly are of as nearly the same size as is mechanically practicable.
A typical mode of use of my improved cathode is illustrated inFig. 1. In this figure there is shown a sealed envelope 8 suitably of glass having at the lower end a reentrant stem 9 terminating in a press It. At the upper end of the envelope is mounted a conventional anode II, for example, of graphite supported on and supplied with energizing current through a suitable leadin conductor l3. In cooperative relation with the anode is provided a cathode ii supported on lead-in conductors l1 and I8 which in turn are sealed into the press It. It will be noted that, in the case illustrated, the cathode as a whole is of helical configuration, the helix being formed by bending the central element of the cathode, corresponding to the mandrel I of Fig. 2, into the desired shape.
For one field of use the envelope I may suitably enclose an ionizing medium comprising gas or vapor at a pressure of from a fraction of a millimeter to a few centimeters. For example, one may employ argon having a pressure of from 1 to 2 millimeters in combination with mercury having at the operating temperature of the device a vapor pressure of from about millimeter to about 3 millimeters. It should be understood, however, that the cathodes of my invention are not limited to this particular field but are equally useful in connection with high vacuum discharge devices such as are conventionally used in radio and therapeutic applications.
The principle of double overwinding may advantageously be extended to include a series any number of filaments in successively overwound relation, the only limitation being a mechanical one disposed by the difliculty of fabricating the more complex structures. Furthermore, while I have illustrated a particular form 01' the invention many modifications may be made -by those skilled in the art without departing from the invention, and I aim in the appended claims to cover all such equivalent constructions as come within the true spirit and scope of the invention.
What I claim as new and desire to secure by Letters Patent 0! the United States is:
1. In a cathode structure, a first wire serving as a corexnember and having a second wire overwound thereon in such a manner that the spacing between adjacent turns is of the order of I but somewhat less than the diameter of the second wire, and a quantity of highly electron emissive material only partially filling the grooves formed between such adjacent turns.
2. An electrode structure comprising a tungsten wire having wound thereon an open helix comprising a first filament serving as a core member and a second filament helically wound in open convolutions on said core member, said first and second filaments also consisting of tungsten, and means for augmenting the electron emissivity of said filaments.
3. A cathode comprising two or more filaments each constituted of a metal of the group consisting of tungsten and molybdenum, said filaments being arranged in successively overwound relation and being provided with a coating of highly electron emissive material.
4. In a cathode the combination which includes a wire core member having a second wire helically wound in open convolutions thereon, and a quantity of thorium oxide disposed in the grooves formed by said convolutions, said wires being constituted of a metal of the group consisting of tungsten and molybdenum.
5. A cathode comprising an elongated metal wire having applied thereto a composite structure including a first metal filament serving as a core member, a second metal filament wound on said core member and means for augmenting the electron emissivity of said filaments.
6. A cathode comprising a tungsten wire having wound thereon a composite structure consisting of a first tungsten filament serving as a core member, a second tungsten filament wound on the core member and a coating of thorium oxide applied to said filaments.
7. An incandescible cathode comprising a metal core wire; a helix of thin metal wire, said helix being helically wound on said core wire and embracing same therewith, and a highly electronemissive substance carried by said helically wound helix.
8. An incandescible cathode comprising a metal core wire, a coil of thin metal wire, said coil being coiled around said core wire and forming a coiled coil, each turn of the outer coil being in contact with the core, and a highly electron-emissive substance carried by said coiled-coil and at least partly filling the hollows and recesses thereof.
9. An incandescible cathode comprising a metal core wire serving as a support and current conductor, a skeleton wire structure surrounding said core wire and having a plurality of apertured layer-like portions formed of helically-wound metal wire, adjacent portions being electrically connected only at interspaced points and the inner portion embracing said core wire, and a highly electron-emissive substance at least partly filling the spaces formed within said structure and securely held thereby.
10. A cathode including an elongated metal core serving as a support and current conductor, a metallic overwinding closely embracing the core so as to be in contact with the core throughout a substantial portion of its length, the member forming the said overwinding being characterized by irregularities from point to point along its length so as to provide a materially larger number of crevices than would be provided by a helically applied overwinding of straight wire,
and a quantity oi. electron emissive material at least partly filling the crevices.
11. An incandescible cathode comprising an elongated metal core serving as a support and current conductor, a discontinuous metallic structure closely embracing the core so as to be in contact therewith throughout a substantial portion of its length, the said structure being constituted of a plurality of wires assembled in interengaging relation to form a framework which provides a large number of crevices both at and slightly spaced from the surface of the core, and a quantity of highly emissive material at least partially filling the said crevices.
12. A cathode comprising an elongated metal core serving as a support and current conductor. a metallic structure closely embracing the core so as to be in contact therewith throughout a substantial portion of its length, the said structure being constituted of a plurality of interengaging wires assembled in repetitively intersecting relation to form a framework which provides a large number of crevices both at and slightly spaced from the surface of the core, and a quantity of highly emissive material at least partially filling the said crevices.
EDWARD F, HENNELLY.
US104465A 1936-10-07 1936-10-07 Cathode Expired - Lifetime US2210761A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2420942A (en) * 1941-02-21 1947-05-20 Gen Electric Electric discharge device and circuit therefor
US2433821A (en) * 1945-05-23 1947-12-30 Sylvania Electric Prod Electron emissive cathode
US2438732A (en) * 1947-03-15 1948-03-30 Eitel Mcculough Inc Electron tube cathode
US2485668A (en) * 1944-06-23 1949-10-25 Int Standard Electric Corp Thermionic cathode
US2652621A (en) * 1949-02-25 1953-09-22 Gen Electric Method of making a unitary thermionic filament structure
US2726178A (en) * 1950-11-17 1955-12-06 Rca Corp Thermionic cathode with thoria coating
DE1038656B (en) * 1954-06-29 1958-09-11 Western Electric Co Method for coating a cathode for gas-filled tubes
US2882436A (en) * 1955-04-02 1959-04-14 Philips Corp Electric discharge tube and cathode therefor
US20030122464A1 (en) * 2001-03-06 2003-07-03 Akira Kurosawa Electric Lamp

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2420942A (en) * 1941-02-21 1947-05-20 Gen Electric Electric discharge device and circuit therefor
US2485668A (en) * 1944-06-23 1949-10-25 Int Standard Electric Corp Thermionic cathode
US2433821A (en) * 1945-05-23 1947-12-30 Sylvania Electric Prod Electron emissive cathode
US2438732A (en) * 1947-03-15 1948-03-30 Eitel Mcculough Inc Electron tube cathode
US2652621A (en) * 1949-02-25 1953-09-22 Gen Electric Method of making a unitary thermionic filament structure
US2726178A (en) * 1950-11-17 1955-12-06 Rca Corp Thermionic cathode with thoria coating
DE1038656B (en) * 1954-06-29 1958-09-11 Western Electric Co Method for coating a cathode for gas-filled tubes
US2882436A (en) * 1955-04-02 1959-04-14 Philips Corp Electric discharge tube and cathode therefor
US20030122464A1 (en) * 2001-03-06 2003-07-03 Akira Kurosawa Electric Lamp
US6803706B2 (en) * 2001-03-06 2004-10-12 Koninklijke Philips Electronics N.V. Lamp with double layer coiled-coil filament

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