US2177632A - Production of colored pictures - Google Patents

Production of colored pictures Download PDF

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Publication number
US2177632A
US2177632A US94344A US9434436A US2177632A US 2177632 A US2177632 A US 2177632A US 94344 A US94344 A US 94344A US 9434436 A US9434436 A US 9434436A US 2177632 A US2177632 A US 2177632A
Authority
US
United States
Prior art keywords
silver
picture
pictures
color
diazotate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US94344A
Other languages
English (en)
Inventor
Bauer Ernst
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GAF Chemicals Corp
Original Assignee
Agfa Ansco Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agfa Ansco Corp filed Critical Agfa Ansco Corp
Application granted granted Critical
Publication of US2177632A publication Critical patent/US2177632A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/26Silver halide emulsions for subtractive colour processes
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/46Subtractive processes not covered by the group G03C7/26; Materials therefor; Preparing or processing such materials

Definitions

  • My present invention relates to the production oi colored pictures.
  • the present invention is based on the observation that the'constituent .coior pictures can be harmonized to a great extent, if there is formed on a photographic material, having several layers superimposed on each other on one or both sides of a support, one or more partial color pictures by color development with diethyi-para-phenylene-diamine or the like, and other partial color pictures by the silver diazotate process through coupling with an azo dyestufi' component.
  • the azo-dyestufi pictures may be obtained, in
  • the film to be used in this invention may be built up as follows:
  • the first, not specially sensitized layer contains the substantive compound p-saiicyiic acid benzidide.
  • the second orthochromatic layer contains, for example, i-(diphenyl) -3-methyl-5-pyrazolone. component i.2-hydroxy-naphthoic acid benzidide.
  • the third layer contains as dyestufi August 1'], 1935 layer a red-picture and in the third layer a blue picture. I I i If the latent image is developed with p-dimethylamino-aniline there is produced, besides 1' moi. dyestufi' 4 mols. silver.
  • the silver picture is converted in the known manner into a silver salt and this is converted into silver anti-diazotate by means of a soluble anti-diazotate, for instance diphenyl-dianti-diazotate.
  • a soluble anti-diazotate for instance diphenyl-dianti-diazotate.
  • the liberated diazonium compound couples with the p-salicylic acid benzidide.
  • the silver salt remnant in the several layers is removed by fixing so that pure dyestufi. s
  • the film may also be developed with aid of an ordinary black and white developer. and fixed. This operation produces a better threshold value than the developer p-dimethyiamino-aniiine and better freedom from fog.
  • the silver picture is then convertedinto a silver salt and this salt further developed with p-dimethylamino-aniiine. There is thus produced a silver picture and a dyestun picture.
  • the silver is again converted into a salt and, as described above, caused to react .with anti-diazotate..
  • the order of the treatments may be rever Further, the silver produced in the black-andwhite development may be dissolved and after a second exposure the residual silver bromide may be developed with p-dimethyl-amino-aniline and the metallic silver thus produced converted in known manner by means of silver anti-diazotate into an azo-dyestufl picture.
  • a process of producing a colored photo graphic picture which comprises exposing to,

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
  • Heat Sensitive Colour Forming Recording (AREA)
US94344A 1935-08-17 1936-08-05 Production of colored pictures Expired - Lifetime US2177632A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEI0053054 1935-08-17

Publications (1)

Publication Number Publication Date
US2177632A true US2177632A (en) 1939-10-31

Family

ID=7193509

Family Applications (1)

Application Number Title Priority Date Filing Date
US94344A Expired - Lifetime US2177632A (en) 1935-08-17 1936-08-05 Production of colored pictures

Country Status (5)

Country Link
US (1) US2177632A (en, 2012)
BE (1) BE416920A (en, 2012)
FR (1) FR809319A (en, 2012)
GB (1) GB464398A (en, 2012)
NL (1) NL50474C (en, 2012)

Also Published As

Publication number Publication date
GB464398A (en) 1937-04-13
BE416920A (en, 2012)
NL50474C (en, 2012)
FR809319A (fr) 1937-03-01

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