US2177632A - Production of colored pictures - Google Patents
Production of colored pictures Download PDFInfo
- Publication number
- US2177632A US2177632A US94344A US9434436A US2177632A US 2177632 A US2177632 A US 2177632A US 94344 A US94344 A US 94344A US 9434436 A US9434436 A US 9434436A US 2177632 A US2177632 A US 2177632A
- Authority
- US
- United States
- Prior art keywords
- silver
- picture
- pictures
- color
- diazotate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 16
- 239000004332 silver Substances 0.000 description 16
- 229910052709 silver Inorganic materials 0.000 description 16
- 238000000034 method Methods 0.000 description 12
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- BZORFPDSXLZWJF-UHFFFAOYSA-N N,N-dimethyl-1,4-phenylenediamine Chemical compound CN(C)C1=CC=C(N)C=C1 BZORFPDSXLZWJF-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 150000001989 diazonium salts Chemical class 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- HKOOXMFOFWEVGF-UHFFFAOYSA-N phenylhydrazine Chemical compound NNC1=CC=CC=C1 HKOOXMFOFWEVGF-UHFFFAOYSA-N 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/26—Silver halide emulsions for subtractive colour processes
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/46—Subtractive processes not covered by the group G03C7/26; Materials therefor; Preparing or processing such materials
Definitions
- My present invention relates to the production oi colored pictures.
- the present invention is based on the observation that the'constituent .coior pictures can be harmonized to a great extent, if there is formed on a photographic material, having several layers superimposed on each other on one or both sides of a support, one or more partial color pictures by color development with diethyi-para-phenylene-diamine or the like, and other partial color pictures by the silver diazotate process through coupling with an azo dyestufi' component.
- the azo-dyestufi pictures may be obtained, in
- the film to be used in this invention may be built up as follows:
- the first, not specially sensitized layer contains the substantive compound p-saiicyiic acid benzidide.
- the second orthochromatic layer contains, for example, i-(diphenyl) -3-methyl-5-pyrazolone. component i.2-hydroxy-naphthoic acid benzidide.
- the third layer contains as dyestufi August 1'], 1935 layer a red-picture and in the third layer a blue picture. I I i If the latent image is developed with p-dimethylamino-aniline there is produced, besides 1' moi. dyestufi' 4 mols. silver.
- the silver picture is converted in the known manner into a silver salt and this is converted into silver anti-diazotate by means of a soluble anti-diazotate, for instance diphenyl-dianti-diazotate.
- a soluble anti-diazotate for instance diphenyl-dianti-diazotate.
- the liberated diazonium compound couples with the p-salicylic acid benzidide.
- the silver salt remnant in the several layers is removed by fixing so that pure dyestufi. s
- the film may also be developed with aid of an ordinary black and white developer. and fixed. This operation produces a better threshold value than the developer p-dimethyiamino-aniiine and better freedom from fog.
- the silver picture is then convertedinto a silver salt and this salt further developed with p-dimethylamino-aniiine. There is thus produced a silver picture and a dyestun picture.
- the silver is again converted into a salt and, as described above, caused to react .with anti-diazotate..
- the order of the treatments may be rever Further, the silver produced in the black-andwhite development may be dissolved and after a second exposure the residual silver bromide may be developed with p-dimethyl-amino-aniline and the metallic silver thus produced converted in known manner by means of silver anti-diazotate into an azo-dyestufl picture.
- a process of producing a colored photo graphic picture which comprises exposing to,
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEI0053054 | 1935-08-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
US2177632A true US2177632A (en) | 1939-10-31 |
Family
ID=7193509
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US94344A Expired - Lifetime US2177632A (en) | 1935-08-17 | 1936-08-05 | Production of colored pictures |
Country Status (5)
Country | Link |
---|---|
US (1) | US2177632A (en, 2012) |
BE (1) | BE416920A (en, 2012) |
FR (1) | FR809319A (en, 2012) |
GB (1) | GB464398A (en, 2012) |
NL (1) | NL50474C (en, 2012) |
-
0
- NL NL50474D patent/NL50474C/xx active
- BE BE416920D patent/BE416920A/xx unknown
-
1935
- 1935-09-13 GB GB25468/35A patent/GB464398A/en not_active Expired
-
1936
- 1936-08-05 US US94344A patent/US2177632A/en not_active Expired - Lifetime
- 1936-08-11 FR FR809319D patent/FR809319A/fr not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB464398A (en) | 1937-04-13 |
BE416920A (en, 2012) | |
NL50474C (en, 2012) | |
FR809319A (fr) | 1937-03-01 |
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