US2163068A - Procedure for the improvement of textiles - Google Patents
Procedure for the improvement of textiles Download PDFInfo
- Publication number
- US2163068A US2163068A US64177A US6417736A US2163068A US 2163068 A US2163068 A US 2163068A US 64177 A US64177 A US 64177A US 6417736 A US6417736 A US 6417736A US 2163068 A US2163068 A US 2163068A
- Authority
- US
- United States
- Prior art keywords
- alcohols
- resin
- resinic
- acid
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 14
- 239000004753 textile Substances 0.000 title description 11
- 239000000463 material Substances 0.000 description 24
- 150000001298 alcohols Chemical class 0.000 description 20
- 238000004513 sizing Methods 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 240000000972 Agathis dammara Species 0.000 description 9
- 229920002871 Dammar gum Polymers 0.000 description 9
- 239000000025 natural resin Substances 0.000 description 9
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 8
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 8
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 8
- 239000004859 Copal Substances 0.000 description 8
- 241000782205 Guibourtia conjugata Species 0.000 description 8
- 238000001035 drying Methods 0.000 description 8
- 150000002170 ethers Chemical class 0.000 description 7
- 239000004744 fabric Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 6
- 239000008149 soap solution Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 4
- -1 glycerin ethers Chemical class 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 229920002955 Art silk Polymers 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- MLKXDPUZXIRXEP-UHFFFAOYSA-N 2-[6-fluoro-2-methyl-3-[(4-methylsulfinylphenyl)methylidene]-1-indenyl]acetic acid Chemical class CC1=C(CC(O)=O)C2=CC(F)=CC=C2C1=CC1=CC=C(S(C)=O)C=C1 MLKXDPUZXIRXEP-UHFFFAOYSA-N 0.000 description 1
- 241000016649 Copaifera officinalis Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N methyl undecanoic acid Natural products CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/17—Natural resins, resinous alcohols, resinous acids, or derivatives thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2938—Coating on discrete and individual rods, strands or filaments
Definitions
- alcohols derived from natural resins or resinic acids such as copals, dammar resin, abietic acid, colophony, talloil-resin acids, etc., and easily obtainable from said stufis by reducing-processes, e. g. by a catalytic high-pressure reduction, are of a different efiect. Owing to a certain gluing-power they are able of joining the single fibres to form compact cords but without imparting to the same a sticking power by which they would conglutinate.
- resinic alcohols compared with resinic acids, are quite easily emulsifiable so that their quantitative removal from the fibre will be possible without ado, e. g. by means of aqueous soap-solutions.
- This peculiarity is not confined merely to the resinic alcohols but also to their derivates, such as esters and ethers and particularly to the corresponding glycoland glycerin ethers. All these products may be applied in the form either of solutions in organic solvents or in the form of aqueous emulsions.
- the resinic alcohols are absolutely fast to light and only small amounts of resinic alcohol need .be worked into the cords in orderto get them closed and well-joined. Distinguishing itself from other sizing methods the resinic alcohol 5 size shows never any overageing-symptom, i. e. it does not become insoluble, nor causes any difficulties at the desizing process, etc. 'Its removal from the fibre by means of soap-baths and the lik is quite easily and smoothly performed.
- Example 1 By the'treatment of corded artificial silk in the ordinary way with a 23% solution of resinic alcohol (acetyl-s'aponification number 168, boiling point 190-230 C. at 3 mm. Hg-pressure) obtained by the reduction of colophony, in trichlorethylene, one gets an excellently sized material which allows of being easily desized. by means of soap solutions.
- resinic alcohol acetyl-s'aponification number 168, boiling point 190-230 C. at 3 mm. Hg-pressure
- Example 2 For the sizing of cotton warp-yarn one em- 55 ploys most advantageously an emulsion produced by stirring 50 weight parts of resinic alcohol, ob-
- Example 3 To "render an artificial silk fabric fast to shifting, one passes the material for a rather long time through an aqueous, cold to lukewarm treatment bath, in which resinic alcohols of the described form or a mixture of fatty alcohols and resinic alcohols had previously been emulsified with soap or sulfuric acid esters of the fatty alcohols.
- the bath should contain about 1 g.
- textile material may signify fibres, threads, filaments, yarns, cords, skeins, tissues and fabrics of all usual kinds.
- non-drying liquid carrier is used in theclaims to define either the non-drying organic solvent or water in which the material is dispersedv by emulsion and to distinguish over drying oils and the like used as carriers for varnishes and some other materials.
- the method of preparing textile material for subsequent working which comprises sizing the same with estersand ethers of alcohols obtainable by the reduction of natural resin materials of the group consisting of copal, dammar resin, colophony, abietic acid, and talloil-resin acid.
- the method of preparing textile material for subsequent working which comprises sizing the same with derivatives of alcohols of the group consisting of glycol ethers and glycerol ethers of alcohols obtainable by the reduction of natural resin materials of the group consisting of copal, dammar resin, colophony, abietic acid, and talloil-resin acid.
- the method of preparing textile material for subsequent working which comprises sizing the same with a solution of a sulfate of alcohol obtainable by the reduction of natural resin materials of the group consisting of copal, dammar resin, colophony, abietic acid and talloil-resin acid.
- the method of preparing textile material for subsequent working which comprises sizing the same with a sizeconsisting principally of material of the group consisting of alcohols obtainable by the reduction of natural resin ma terials of the group consisting of copal, dammar resin, colophony, abietic acid and talloil-resin acid and the esters and ethers of said alcohols together with a non-drying organic solvent, said size being easily removable upon washing in aqueous soap solution.
- the method of preparing textile material for subsequent working which comprises sizing the same with a size characterized by being easily removable upon washing in aqueous soap solution and consisting principally of material of the group consisting of alcohols obtainable by the reduction of natural resin materials of the group consisting of copal'; dammar resin, colophony, abietic acid and talloil-resin acid and the esters and ethers of said alcohols and a non-drying organic solvent together with products to reduce sticking of the group consisting of starch paste, size solutions, fats and waxes.
- the method of preparing warp yarn for subsequent working which comprises sizing the same with a size consisting of material of the group consisting of alcohols obtainable by the reduction of natural resin materials of the group consisting of copal, dammar resin, colophony, abietic acid and talloil-resin acid and the esters and ethers of said alcohols together with a non-drying organic solvent, said size being easily removable upon washing in aqueous soap solution.
- the method of working textile material which comprises preparing yarn by sizing the same with a size containing alcohol obtainable by reduction of material of the group consisting of copal, dammar resin, colophony, abietic 'acid and talloil-resin acid and the esters and ethers of said alcohols, weaving the yarn into cloth and washing out said size.
- the method of preparing textile material for subsequent working which comprises sizing the same with a size consisting principally of material of the group consisting of alcohols obtainable by the reduction of natural resin materials of the group consisting of copal, dammar resin, colophony, abietic acid and talloil-resin acid and the esters and ethers of said alcohols together with a non-drying liquid carrier, said size being easily removable upon washing in aqueous soap solu tion.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE208283X | 1935-02-16 | ||
CH198105T | 1936-02-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
US2163068A true US2163068A (en) | 1939-06-20 |
Family
ID=25723062
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US64177A Expired - Lifetime US2163068A (en) | 1935-02-16 | 1936-02-15 | Procedure for the improvement of textiles |
Country Status (4)
Country | Link |
---|---|
US (1) | US2163068A (enrdf_load_stackoverflow) |
CH (1) | CH208283A (enrdf_load_stackoverflow) |
GB (1) | GB470424A (enrdf_load_stackoverflow) |
NL (1) | NL42424C (enrdf_load_stackoverflow) |
-
0
- NL NL42424D patent/NL42424C/xx active
-
1936
- 1936-02-14 CH CH208283D patent/CH208283A/de unknown
- 1936-02-15 US US64177A patent/US2163068A/en not_active Expired - Lifetime
- 1936-02-15 GB GB4674/36A patent/GB470424A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
CH208283A (de) | 1940-01-15 |
GB470424A (en) | 1937-08-16 |
NL42424C (enrdf_load_stackoverflow) |
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