US2152994A - Gaseous electric discharge lamp device - Google Patents

Gaseous electric discharge lamp device Download PDF

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US2152994A
US2152994A US132640A US13264037A US2152994A US 2152994 A US2152994 A US 2152994A US 132640 A US132640 A US 132640A US 13264037 A US13264037 A US 13264037A US 2152994 A US2152994 A US 2152994A
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United States
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container
electric discharge
discharge lamp
gaseous
lamp device
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US132640A
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Hanlein Walter
Berlin Wilhelm Hagen
Krefft Hermann
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General Electric Co
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General Electric Co
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/02Details
    • H01J61/30Vessels; Containers
    • H01J61/302Vessels; Containers characterised by the material of the vessel
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/06Glass compositions containing silica with more than 90% silica by weight, e.g. quartz
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • C03C3/087Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2201/00Glass compositions
    • C03C2201/06Doped silica-based glasses
    • C03C2201/30Doped silica-based glasses containing metals
    • C03C2201/32Doped silica-based glasses containing metals containing aluminium
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2201/00Glass compositions
    • C03C2201/06Doped silica-based glasses
    • C03C2201/30Doped silica-based glasses containing metals
    • C03C2201/54Doped silica-based glasses containing metals containing beryllium, magnesium or alkaline earth metals
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2203/00Production processes
    • C03C2203/10Melting processes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S501/00Compositions: ceramic
    • Y10S501/90Optical glass, e.g. silent on refractive index and/or ABBE number
    • Y10S501/905Ultraviolet transmitting or absorbing

Definitions

  • the present invention relates to gaseous elecmercury vapor, electric discharge lamps operattric discharge lamp devices generally and more ing with elevated container temperatures.
  • Such particularly the invention relates to'vapor dis-. glasses have a softening temperature of about charge lamp devices operating with elevated con- '1,000 C., are more easily workable than quartz tainer temperatures and with correspondingly and do not devitrify as rapidly as quartz.
  • the 5 elevated vapor pressures, such as a vapor presultra violet transmission of the glass is comparasure in the order of atmospheres, similar to that ble to that of quartz.
  • tainer exist under service conditions. It is de- In the following table various glass composi- 15 sirable, since the gaseous atmosphere oi the tions which we have discovered are useful as lamp consists of, or comprises mercury vapor, to container glasses for gaseous electric discharge useavitreous container material which transmits lamp devices are listed, together with the coboth the visible and the ultra violet light emitted eilicient of expansion measured at 50 C. and
  • each glass compo- 2 tion of the device has been customary in the sltion.
  • the softening temperature of each glass art, heretofore, to make the lamp container of is the temperature at which a rod 10 cm. long fused silica, or quartz, this being the only ma and about 3 mm. in diameter resting on two terial available which would successfully meet knife edges begins to bend.
  • Quartz containers are 25 diillcult and expensive to fabricate due to the Exlgnision high softening temperature of the quartz and the we c sommm low coefllcient of expansion thereof which make 9 Bao 'fid -i point 8 the sealing of current leads therein, such as 30 tungsten or molybdenum leads, complicated. h 80
  • the useful operating life of such lamps having a. quartz containers is not as long as could be de- 5 gsired due to the fact that the quartz tends to 8 8 1 1.75 175 11 1040 devitrify at high container temperature, such as 4 3 75 temperaturesfrom about 70 C.
  • a aseous electric disdjmlmshes charge lamp device having a container consisting
  • the object of the invention is to an 11 Of One 01' glasses disclosed above 18 Shown expensive gaseous electric discharge lamp device in a side elevation view- 40 capable of operation with an elevated container Referring the wing the gasemls electric temperature and having a long useful operatin discharge lamp device comprises an elongated, life.
  • Another object of the invention is to pro-" tubular container having current leads 2 and vide a vitreous t i 1 1.339, contagner sealed therein, one in each.
  • Said material for gaseous electric discharge devices n leads 2 and consist of 811 elti 45 generally and particularly for such devices op- Point material, h as n n and are s aled erating' with elevated container temperatures. irec ly into the glass of container i.
  • Said con- Further objects and advantages of the invention 811161 I h her n a Starting 8 1101188 will be apparent to those skilled in the art-from arson. 1' startin gas mixture and a quantity 4 the following particular description.
  • the lamp starts alumina (A1201) and from 0 to 8% of alkaline as a gas lamp and operates as a vaporlamp and earth metal oxide, suchasv calcium oxide and the vapor pressure in the lamp is about'ten' barium oxide, is a good'containe'r material for atmospheres or higher during the operation or the lamp device.
  • Theelectrodes I and l are mounted on said leads 2 and 2', respectively.
  • Each 01 said electrodes 3 and 3' consists of a perforated, tungsten shell fllled with a mixture of aluminum oxide, tungsten and an alkaline earth metal oxide and is heated to a high electron emitting temperature by the discharge incident thereat.
  • Said container l consists of a glass having one of the compositions disclosed above and the gaseous electric discharge lamp is a long-lived, high eflicient, inexpensively manufactured source of visible and ultra violet light.
  • the container I is made in other shapes, such as a spherical shape, or a small bore tube.
  • the electrodes are mounted in other positions in the container, when desired other types or thermionic electrodes, such as those requiring a special heater source are used, when desired, and the part of the current leads in the lamp is surrounded by a tube of high melting point, insulating material to protect it from the discharge, when desired.
  • a gaseous electric discharge device comprising a container, a gaseous atmosphere therein and electrodes sealed therein, said container consisting of a glass consisting of about 80 to 98% silica (S102), about 2 to 12% alumina (A120:) and about 0 to 8% alkaline earth metal oxides.
  • a gaseous electric discharge device comprising a container, a gaseous atmosphere therein and electrodes sealed therein, said container consisting of a glass consisting of about 94.5% silica (Sig )2) and 5.5% alumina.
  • 39A gaseous electric discharge device comprising a container, a gaseous atmosphere therein and electrodes sealed therein, said container consisting of a. glass consisting of about 93% silica ($102), alumina (A1203), 1% calcium oxide (09.0) and 1% barium oxide (BaO).
  • a gaseous electric discharge device comprising a container, a gaseous atmosphere therein and electrodes sealed therein, said container consisting of a glass consisting of about 82.5% silica (SiOz'), alumina (A1203), 3.75% calcium oxide (CaO), 3.75% barium oxide (BaO).

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Vessels And Coating Films For Discharge Lamps (AREA)

Description

April 1939- w. HANLEIN ET AL 2,994 7 GASEOU S ELECTRIC DISCHARGE LAMP DEVICE Filed March 23, 1957 INVENITORS Walt er Hanlem Wilhelm Hagen Hermann Kreffc. BY
ATTOR N EY Patented Apr..4,1939- it H I 2,152,994
UNITED STATES PATENT OFFICE Walter Hiinlein, Berlin-Spandau, Wilhelm Hagen, Berlin, and Hermann Kreflt, Berlin-Friedriclis-- hagen, Germany, assignors to General Electris Company, a corporation oi New York Application March 23, 1937, Serial No. 132,640
.In Germany March 30, 1936 4 Claims. (Cl. 176-422) The present invention relates to gaseous elecmercury vapor, electric discharge lamps operattric discharge lamp devices generally and more ing with elevated container temperatures. Such particularly the invention relates to'vapor dis-. glasses have a softening temperature of about charge lamp devices operating with elevated con- '1,000 C., are more easily workable than quartz tainer temperatures and with correspondingly and do not devitrify as rapidly as quartz. \The 5 elevated vapor pressures, such as a vapor presultra violet transmission of the glass is comparasure in the order of atmospheres, similar to that ble to that of quartz. Perhaps the chief advandisclosed in co-pending application, Serial No. tags of the glasses of the invention over quartz 120,066, filed January 11, 1937, inventors Wilis that while the coefiiclent of expansion thereof l helm Hagen and Wolfgang Thouret. is low enough to avoid breaking strains under I'he containers of-such devices are at a temlarge differences of temperature it is such that perature of about 600 'C. and higher during the current leads of tungsten or molybdenum can operation of the device and large differences in be sealed directly into a lamp container consisttemperature between different parts of the coning of such glass.
tainer exist under service conditions. It is de- In the following table various glass composi- 15 sirable, since the gaseous atmosphere oi the tions which we have discovered are useful as lamp consists of, or comprises mercury vapor, to container glasses for gaseous electric discharge useavitreous container material which transmits lamp devices are listed, together with the coboth the visible and the ultra violet light emitted eilicient of expansion measured at 50 C. and
2 by the excited mercury vapor during the operathe softening temperature oi. each glass compo- 2 tion of the device. It has been customary in the sltion. The softening temperature of each glass art, heretofore, to make the lamp container of is the temperature at which a rod 10 cm. long fused silica, or quartz, this being the only ma and about 3 mm. in diameter resting on two terial available which would successfully meet knife edges begins to bend.
the above requirements. Quartz containers are 25 diillcult and expensive to fabricate due to the Exlgnision high softening temperature of the quartz and the we c sommm low coefllcient of expansion thereof which make 9 Bao 'fid -i point 8 the sealing of current leads therein, such as 30 tungsten or molybdenum leads, complicated. h 80 The useful operating life of such lamps having a. quartz containers is not as long as could be de- 5 gsired due to the fact that the quartz tends to 8 8 1 1.75 175 11 1040 devitrify at high container temperature, such as 4 3 75 temperaturesfrom about 70 C. to about 870 Y 85 C., and the transmissivity thereof for the light In the drawing accompanying and forming emitted by the gaseous electric discharge rapidly P Of this s ion a aseous electric disdjmlmshes charge lamp device having a container consisting The object of the invention is to an 11 Of One 01' glasses disclosed above 18 Shown expensive gaseous electric discharge lamp device in a side elevation view- 40 capable of operation with an elevated container Referring the wing the gasemls electric temperature and having a long useful operatin discharge lamp device comprises an elongated, life. Another object of the invention is to pro-" tubular container having current leads 2 and vide a vitreous t i 1 1.339, contagner sealed therein, one in each. end thereof. Said material for gaseous electric discharge devices n leads 2 and consist of 811 elti 45 generally and particularly for such devices op- Point material, h as n n and are s aled erating' with elevated container temperatures. irec ly into the glass of container i. Said con- Further objects and advantages of the invention 811161 I h her n a Starting 8 1101188 will be apparent to those skilled in the art-from arson. 1' startin gas mixture and a quantity 4 the following particular description. of vaporizable material such as mercury, the 50 We havehi'scovered that a glass consisting of vapor of which is luminosity producing during from 80 to 98% silica (SiO'i), from -'2 to 12% the operation of the device. The lamp starts alumina (A1201) and from 0 to 8% of alkaline as a gas lamp and operates as a vaporlamp and earth metal oxide, suchasv calcium oxide and the vapor pressure in the lamp is about'ten' barium oxide, is a good'containe'r material for atmospheres or higher during the operation or the lamp device. Theelectrodes I and l are mounted on said leads 2 and 2', respectively. Each 01 said electrodes 3 and 3' consists of a perforated, tungsten shell fllled with a mixture of aluminum oxide, tungsten and an alkaline earth metal oxide and is heated to a high electron emitting temperature by the discharge incident thereat.
Said container l consists of a glass having one of the compositions disclosed above and the gaseous electric discharge lamp is a long-lived, high eflicient, inexpensively manufactured source of visible and ultra violet light.
While we have shown and described and have pointed out in the annexed claims certain novel features of the invention, it will be understood that various omissions, substitutions and changes in the forms and details g the device illustrated and in its use and operation may be made by those skilled in the art without departing from the broad spirit and scope of the invention, for example, the container I is made in other shapes, such as a spherical shape, or a small bore tube. when desired, the electrodes are mounted in other positions in the container, when desired other types or thermionic electrodes, such as those requiring a special heater source are used, when desired, and the part of the current leads in the lamp is surrounded by a tube of high melting point, insulating material to protect it from the discharge, when desired.
What we claim as new and desire to secure by Letters Patent oi the United States is:-
l. A gaseous electric discharge device comprising a container, a gaseous atmosphere therein and electrodes sealed therein, said container consisting of a glass consisting of about 80 to 98% silica (S102), about 2 to 12% alumina (A120:) and about 0 to 8% alkaline earth metal oxides.
2. A gaseous electric discharge device comprising a container, a gaseous atmosphere therein and electrodes sealed therein, said container consisting of a glass consisting of about 94.5% silica (Sig )2) and 5.5% alumina.
39A gaseous electric discharge device comprising a container, a gaseous atmosphere therein and electrodes sealed therein, said container consisting of a. glass consisting of about 93% silica ($102), alumina (A1203), 1% calcium oxide (09.0) and 1% barium oxide (BaO).
4. A gaseous electric discharge device comprising a container, a gaseous atmosphere therein and electrodes sealed therein, said container consisting of a glass consisting of about 82.5% silica (SiOz'), alumina (A1203), 3.75% calcium oxide (CaO), 3.75% barium oxide (BaO).
WALTER WILHELM I-IAGEN. HERMANN KREFFI.
US132640A 1936-03-30 1937-03-23 Gaseous electric discharge lamp device Expired - Lifetime US2152994A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2469410A (en) * 1945-02-05 1949-05-10 Westinghouse Electric Corp Ultraviolet lamp
US2492142A (en) * 1945-10-17 1949-12-27 Kenneth J Germeshausen Electric system embodying coldcathode gaseous discharge device
US2545884A (en) * 1946-01-18 1951-03-20 Gen Electric High-pressure mercury vapor electric discharge lamp
US3007806A (en) * 1957-12-30 1961-11-07 Babcock & Wilcox Co High silica refractory wools
US3031318A (en) * 1960-07-12 1962-04-24 Int Resistance Co Low thermal expansion glass
US3054922A (en) * 1959-08-26 1962-09-18 Gen Electric Intermediate pressure wall stabilized gas lamp
WO2005062343A2 (en) * 2003-12-22 2005-07-07 Patent-Treuhand- Gesellschaft Für Elektrische Glühlampen Mbh Electrode for a high pressure discharge lamp

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2469410A (en) * 1945-02-05 1949-05-10 Westinghouse Electric Corp Ultraviolet lamp
US2492142A (en) * 1945-10-17 1949-12-27 Kenneth J Germeshausen Electric system embodying coldcathode gaseous discharge device
US2545884A (en) * 1946-01-18 1951-03-20 Gen Electric High-pressure mercury vapor electric discharge lamp
US3007806A (en) * 1957-12-30 1961-11-07 Babcock & Wilcox Co High silica refractory wools
US3054922A (en) * 1959-08-26 1962-09-18 Gen Electric Intermediate pressure wall stabilized gas lamp
US3031318A (en) * 1960-07-12 1962-04-24 Int Resistance Co Low thermal expansion glass
WO2005062343A2 (en) * 2003-12-22 2005-07-07 Patent-Treuhand- Gesellschaft Für Elektrische Glühlampen Mbh Electrode for a high pressure discharge lamp
WO2005062343A3 (en) * 2003-12-22 2007-08-09 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Electrode for a high pressure discharge lamp

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