US2056926A - Electric gaseous discharge device - Google Patents
Electric gaseous discharge device Download PDFInfo
- Publication number
- US2056926A US2056926A US737829A US73782934A US2056926A US 2056926 A US2056926 A US 2056926A US 737829 A US737829 A US 737829A US 73782934 A US73782934 A US 73782934A US 2056926 A US2056926 A US 2056926A
- Authority
- US
- United States
- Prior art keywords
- mercury
- envelope
- lamp
- discharge device
- gaseous discharge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 15
- 229910052753 mercury Inorganic materials 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 229910052792 caesium Inorganic materials 0.000 description 6
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000000292 calcium oxide Substances 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910011255 B2O3 Inorganic materials 0.000 description 3
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
- 239000000395 magnesium oxide Substances 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- 239000005368 silicate glass Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000010678 Paulownia tomentosa Nutrition 0.000 description 1
- 240000002834 Paulownia tomentosa Species 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 150000001663 caesium Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 150000002730 mercury Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/12—Selection of substances for gas fillings; Specified operating pressure or temperature
- H01J61/18—Selection of substances for gas fillings; Specified operating pressure or temperature having a metallic vapour as the principal constituent
- H01J61/20—Selection of substances for gas fillings; Specified operating pressure or temperature having a metallic vapour as the principal constituent mercury vapour
Definitions
- my novel lamp has a tubular envelope filled with any suitable gas .velope I.
- a tubular jacket 2 Surrounding said envelope I there is a tubular jacket 2.
- the space between the envelope I and the jacket 2 is either evacuated or filled with an indifferent gas, such as nitrogen, at any suitable pressure, such as half an atmosphere.
- the jacket 2 has at one end thereof a stem 3, through the pinch 4 of which two current inleads 5 and 6 are sealed.
- the current inlead 5 is flexibly connected to the inlead I which is fused into the adjacent end of the envelope I.
- Said inlead I carries at its inner end a thermionic cathode 8, while a second thermionic cathode 9 is carried by an inlead Ill which is sealed through the opposite end of the en-
- thermionic electrodes 8 and 9 can be of any desired type and composition, but
- the wire I4 is in practice made an extension of the inlead 6, and the lower end thereof is flexibly connected with the inlead In, so that this wire also serves to conduct the current to the thermionic cathode 9.
- Each metal ring H and 52 has a plurality of spring fingers i 5 affixed to the outside thereof which bear against the inner wall of the jacket 2, and thus 'serve to prevent lateral displacement of the envelope I.
- a screw base 22 is firmly attached to the jacket 2 by means of the clamping band 23, leads 5 and 6 being connected to the tip 24 and sleeve 25 thereof, respectively.
- the glass of the envelope I is preferably an aluminum silicate glass of special composition which I have discovered resists blackening. This glass contains silica of the order of 60% or less,
- This glass has a softening temperature of approximately 750 C., so that a mercury vapor discharge at several atmospheres vapor pressure can be operated in a lamp constructed thereof without danger.
- a mercury vapor arc lamp of the high pressure type comprising a sealed envelopecontaining mercury together with from 0.2 to 5% of caesium, and having electrodes sealed within said envelope.
- said envelope consisting of an aluminum silicate glass having a composition of the order of 60% or less of silica, more than 20% alumina, the balanceconsisting of other glass forming materials such as boric oxide, magnesium oxide and calcium oxide.
- a mercury vapor arc lamp of the high pressure type comprising a sealed envelope having thermionic electrodes sealed therein, said envelope containing mercury together with from 0.2 to 5% of caesium.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Vessels And Coating Films For Discharge Lamps (AREA)
Description
Oct. 6, 1936. H. KREFFT ELECTRIC CASEOUS DISCHARGE DEVICE Filed July 5,1, 1934 INVENTOR Patented Oct. 6, 1936 UNITED STATES PATENT OFFICE $056,926 ELECTRIC GASEOUS DISCHARGE DEVICE Hermann Krefl't, Berlln-Friedrichshagen, Germany, assignor to General Electric Company, a corporation of New York Application July 31, 1934, Serial No. 737,829 In Germany August 21, 1933 2 Claims. (Cl. 176-122) vide a high pressure gaseous discharge lampwhich will have a long useful life. Another object of the invention is to eliminate the blackening of the lamp envelope. Still other objects and advantages of the invention will appear from the following detailed specification or from an inspection of the accompanying drawing.
The invention consists in a new and novel combination of elements, as hereinafter set forth and claimed.
In operating gaseous-discharge devices such asthe high pressure mercury vapor arc lamps with thermionic electrodes which are now coming into considerable use a blackening of the lamp en'- velope has been found to occur heretofore after a relatively short burning period. This rapid blackening of the envelope, which is caused in part by decomposition of the electrodes and in part by the influence of ultraviolet rays and electric particles, has tended to limit the useful life of these devices, and hence is undesirable.
I have now discovered that this undesired blackening of the mercury high pressure lamp is avoided if a small quantity, of the order of (LE-%, of caesium is mixed with the vaporizing mercury base body, provided that a special aluminum silicate glass is used in constructing the discharge vessel of the lamp. This special glass has 60% or less of silica, more than 20% alumina, and also contains small quantities of other glass builders such as boric oxide, magnesium oxide and calcium oxide. With a tube constructed in this manner, in addition to the mercury vapor, a small quantity of caesium vapor is also produced during operation of the lamp by vaporization of the base body. Although this caesium vapor, because of its small quantity,
does not participate in the light radiation to any appreciable extent and therefore does not noticeably change the mercury radiation, nevertheless, in combination with the definite construction of the lamp vessel, it has the effect that the heretofore unavoidable blackening of the lamp vessel is eliminated.
For the purpose of illustrating my invention I have shown an elevational view, in part section, of a preferred embodiment thereof in the accompanying drawing.
As shown in this drawing my novel lamp has a tubular envelope filled with any suitable gas .velope I.
or vapor or mixtures thereof. For example, I have obtained excellent results using argon at 'a pressure of the order of 5 mm. of mercury,
together with just'enough mercury to provide substantially atmospheric pressure when it is 5 all evaporated. Mixed with this mercury is a small quantity of caesium, of the order of 0.2 to 5% of the mercury. Surrounding said envelope I there is a tubular jacket 2. The space between the envelope I and the jacket 2 is either evacuated or filled with an indifferent gas, such as nitrogen, at any suitable pressure, such as half an atmosphere. The jacket 2 has at one end thereof a stem 3, through the pinch 4 of which two current inleads 5 and 6 are sealed. The current inlead 5 is flexibly connected to the inlead I which is fused into the adjacent end of the envelope I. Said inlead I carries at its inner end a thermionic cathode 8, while a second thermionic cathode 9 is carried by an inlead Ill which is sealed through the opposite end of the en- These thermionic electrodes 8 and 9 can be of any desired type and composition, but
-I prefer to use a wound tungs en helix, as shown,
within which there is retained a rod 8' and 9, respectively, of electron emitting material, such as a sintered mixture of 90 parts of barium oxide and calcium oxide with 10 parts of tungsten, since such an electrode has been found to be exceptionally effective in my novel lamp. 0 Dished metal rings H and I 2 are fitted against the ends of the envelope l, and are held in this position by means of rigid longitudinal wires l3 and M which unite them with each other. These wires 13 and M, which together with the rings ll and I2 form a stifi frame surrounding the envelope l, are anchored in the pinch 4. The wire I4 is in practice made an extension of the inlead 6, and the lower end thereof is flexibly connected with the inlead In, so that this wire also serves to conduct the current to the thermionic cathode 9. Each metal ring H and 52 has a plurality of spring fingers i 5 affixed to the outside thereof which bear against the inner wall of the jacket 2, and thus 'serve to prevent lateral displacement of the envelope I. A screw base 22 is firmly attached to the jacket 2 by means of the clamping band 23, leads 5 and 6 being connected to the tip 24 and sleeve 25 thereof, respectively.
The glass of the envelope I is preferably an aluminum silicate glass of special composition which I have discovered resists blackening. This glass contains silica of the order of 60% or less,
and 20% or more of alumina, the remainder of Per cent SiOz 57.6 B203 1.2 A1203 28.4 MgO 8.2 CaO. 4.6
This glass has a softening temperature of approximately 750 C., so that a mercury vapor discharge at several atmospheres vapor pressure can be operated in a lamp constructed thereof without danger.
While I have described my invention by reference to a lamp of particular construction, wherein all of the mercury is vaporized during operation, it is to be understood that it is likewise applicable to other high pressure lamps in which the metal is not all in the vapor phase. It is furthermore to be understood. that my invention is not only useful in lamps containing mercury, but also in devices containing other vaporizable metals, such as cadmium, sodium, or the like, and particularly to devices operating at relatively high temperatures, of the'order of 300 C. Various changes, substitutions and omissions, within the scope of the appended claims may, of course, be made in the structures illustrated and described without departing from the spirit of my invention.
, What I claim as new and desire to secure by Letters Patent of the United States is:
1. A mercury vapor arc lamp of the high pressure type comprising a sealed envelopecontaining mercury together with from 0.2 to 5% of caesium, and having electrodes sealed within said envelope. said envelope consisting of an aluminum silicate glass having a composition of the order of 60% or less of silica, more than 20% alumina, the balanceconsisting of other glass forming materials such as boric oxide, magnesium oxide and calcium oxide.
2. A mercury vapor arc lamp of the high pressure type comprising a sealed envelope having thermionic electrodes sealed therein, said envelope containing mercury together with from 0.2 to 5% of caesium.
' HERMANN KREFFT.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL38405D NL38405C (en) | 1933-08-21 | ||
| GB20256/34A GB432614A (en) | 1933-08-21 | 1934-07-10 | Improvements in luminous electric discharge lamps |
| US26825A US2087762A (en) | 1933-08-21 | 1935-06-15 | Glass composition for electric gaseous discharge devices |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2056926X | 1933-08-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2056926A true US2056926A (en) | 1936-10-06 |
Family
ID=7982922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US737829A Expired - Lifetime US2056926A (en) | 1933-08-21 | 1934-07-31 | Electric gaseous discharge device |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US2056926A (en) |
| FR (1) | FR776601A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2671183A (en) * | 1951-09-12 | 1954-03-02 | Gen Electric | Electric discharge lamp mount |
| US2733363A (en) * | 1956-01-31 | Arc tube mount | ||
| US2961328A (en) * | 1958-12-02 | 1960-11-22 | Owens Illinois Glass Co | Refractory glass composition |
| US2971110A (en) * | 1959-08-26 | 1961-02-07 | Gen Electric | Metal vapor lamps |
| US3054922A (en) * | 1959-08-26 | 1962-09-18 | Gen Electric | Intermediate pressure wall stabilized gas lamp |
| US3259779A (en) * | 1951-11-17 | 1966-07-05 | Westinghouse Electric Corp | Improving efficiency of infrared radiation generation by alkali metal vapor lamps and prolonging their useful lives |
-
1934
- 1934-07-31 US US737829A patent/US2056926A/en not_active Expired - Lifetime
- 1934-07-31 FR FR776601D patent/FR776601A/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2733363A (en) * | 1956-01-31 | Arc tube mount | ||
| US2671183A (en) * | 1951-09-12 | 1954-03-02 | Gen Electric | Electric discharge lamp mount |
| US3259779A (en) * | 1951-11-17 | 1966-07-05 | Westinghouse Electric Corp | Improving efficiency of infrared radiation generation by alkali metal vapor lamps and prolonging their useful lives |
| US2961328A (en) * | 1958-12-02 | 1960-11-22 | Owens Illinois Glass Co | Refractory glass composition |
| US2971110A (en) * | 1959-08-26 | 1961-02-07 | Gen Electric | Metal vapor lamps |
| US3054922A (en) * | 1959-08-26 | 1962-09-18 | Gen Electric | Intermediate pressure wall stabilized gas lamp |
Also Published As
| Publication number | Publication date |
|---|---|
| FR776601A (en) | 1935-01-30 |
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