US2139668A - Oil composition - Google Patents

Oil composition Download PDF

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Publication number
US2139668A
US2139668A US83268A US8326836A US2139668A US 2139668 A US2139668 A US 2139668A US 83268 A US83268 A US 83268A US 8326836 A US8326836 A US 8326836A US 2139668 A US2139668 A US 2139668A
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United States
Prior art keywords
oil
residuum
oiliness
residue
pennsylvania
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Expired - Lifetime
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US83268A
Inventor
Ferdinand W Breth
Kinsel Anton
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L SONNEBORN SONS Inc
SONNEBORN SONS Inc L
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SONNEBORN SONS Inc L
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Priority to US83268A priority Critical patent/US2139668A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104Aromatic fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106Naphthenic fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108Residual fractions, e.g. bright stocks

Definitions

  • This invention relates to an oil composition the addition of various amounts of proto oil to a and more particularly to an oil composition having Texas pale oil, when tested under the same conimproved oiliness. ditions as described above for the Pennsylvania Pennsylvania oils and their derivatives posoil: sess a high degree of oiliness. Solvent refined gg g 5 oils, and oils derived from a non-parafiinic base, Texas pale Oil SAIL 20 32 such as the naphthenic or asphaltic base oils of California and Russia, are relatively deficient in oiliness. We have discovered that the oiliness of these latter oils may be improved by adding $32: 5: ⁇ : 3;; g g gggg g T 10 proto oil thereto.
  • the proto oil should be added in amount and potency uffici nt t appreciably It is understood that we are not to be limited increase the oiliness of the deficient 011.
  • additions of up to about 10% of proto any Solvent, in W h t e probe 011 is preferen- Texas pale oil S.A.E. plus 1% roto oil 3. 50 Texas pale oil S.A.E. 20 plus 2% proto oil 3. 745
  • a lubricating O11 composition comprising a 5%?2233511333:::::::::::::::::::::::::::: 933 i: it?- mineral Oil distillate deficient i oiliness, and a so residue obtained by exhaustively extracting a Pennsylvania residuum with a solvent having substantially the same solvent properties upon said residuum as acetone, said residue being present in amount and potency sufiicient to appreciably increase the oiliness of said distillate.
  • a lubricating oil composition comprising a lubricating oil deficient in oiliness, and a residue obtained by exhaustively extracting a Pennsylvania residuum with a solvent having substantially the same solvent properties upon said residuum as acetone, said residue being present in amount and potency suificient to appreciably increase the oiliness of said lubricating oil.
  • a lubricating oil composition comprising a I mineral oil derivative deficient in oiliness, and a Pe sy lublleetlng 01L
  • a Penna residue obtained by exhaustively extracting a sylvania lubricating oil with a Saybolt viscosity Pennsylvania, residuum it l t having of 57 s con s pp to the band, With rotation substantially the same solvent properties upon at 6,000 B. P. M. for 15 minutes at 210 F., about said residuum as acetone, said residue being 50 5.65 milligrams remain on the band.
  • a lubricating oil composition comprising a invention. naphthenic base mineral oil, and a residue ob-
  • the following examples illustrate the effect of tained by exhaustively extracting a Pennsylvania 55
  • the degree of oiliness may be determined by means of the Sperry-Cammen Adher-o-scope, which utilizes a thin metal band of known weight and constant dimensions, to which is applied an oil film. The band is then placed on a disc and rotated at several thousand r. p. m. at a controlled temperature and humidity for a standard 40 period of time, after which the band is removed and Weighed.
  • the amount of oil adhering thereto is a function of the oiliness.
  • oil deficient in oiliness we mean 45 an oil which has poor adhesive capacity to metallic surfaces as compared with that possessed by residuum with a solvent having substantially the same solvent properties upon said residuum as acetone, said residue being present in amount and potency suificient to appreciably increase the oiliness of said mineral oil.
  • a lubricating oil composition comprising a solvent refined mineral oil, and a residue obtained by exhaustively extracting a Pennsylvania residuum with a solvent having substantially the same solvent properties upon said residuum as acetone, said residue being present in amount and potency sufiicient to appreciably increase the oiliness of said mineral oil.
  • a lubricating oil composition in accordance with claim 3 in which said residue is obtained by exhaustively extracting a Pennsylvania residuum with acetone.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Description

15 oil will give this effect without substantial change tially s u l ay be us d- The above 15 Patented Dec. 13, 1938 7 I OIL COMPOSITION Ferdinand W. Breth, New York, N. Y., and Anton Kinsel, Petrolia, Pa., assignors to L. Sonneborn Sons, Inc., a corporation of Delaware No Drawing. Application June 3, 1936, Serial No. 83,268
12 Claims. (Cl. 196151) This invention relates to an oil composition the addition of various amounts of proto oil to a and more particularly to an oil composition having Texas pale oil, when tested under the same conimproved oiliness. ditions as described above for the Pennsylvania Pennsylvania oils and their derivatives posoil: sess a high degree of oiliness. Solvent refined gg g 5 oils, and oils derived from a non-parafiinic base, Texas pale Oil SAIL 20 32 such as the naphthenic or asphaltic base oils of California and Russia, are relatively deficient in oiliness. We have discovered that the oiliness of these latter oils may be improved by adding $32: 5:}: 3;; g g gggg g T 10 proto oil thereto. The proto oil should be added in amount and potency uffici nt t appreciably It is understood that we are not to be limited increase the oiliness of the deficient 011. For to acetone extraction to obt the p ot as example, additions of up to about 10% of proto any Solvent, in W h t e probe 011 is preferen- Texas pale oil S.A.E. plus 1% roto oil 3. 50 Texas pale oil S.A.E. 20 plus 2% proto oil 3. 745
in the viscosity of the deficient oil. Larger seriptien s y y Of ustration a d not of amounts of proto oil may be added, accompanied llmitatlen, d We are to be limited y by the by increase in viscosity appended claims in which we have; endeavored Proto oil is the residue obtained by exhaustively to Claim the inherent y- 20 extracting a Pennsylvania residuum with acetone. We claim: 20 The physical characteristics of the protooil and A lubricating 011 composition Comprising a the residuum from which it is obtained r as mineral oil deficient in oiliness, and a residue follgws; obtained by exhaustively extracting a Pennsylvania residuum with a solvent having substantially the same solvent properties upon said re- Prom on Residual siduum as acetone, said residue being present in 25 0 it S bOMtIOOOF 9095 2200 amount and potency sufiicient to appreciably inviifioiet $251,011; at 210 FII 452 Si 150 crease the e ness of said mineral 011.
Gravity 35.7 gas 2. A lubricating O11 composition comprising a 5%?2233511333::::::::::::::::::::::::: 933 i: it?- mineral Oil distillate deficient i oiliness, and a so residue obtained by exhaustively extracting a Pennsylvania residuum with a solvent having substantially the same solvent properties upon said residuum as acetone, said residue being present in amount and potency sufiicient to appreciably increase the oiliness of said distillate.
3. A lubricating oil composition comprising a lubricating oil deficient in oiliness, and a residue obtained by exhaustively extracting a Pennsylvania residuum with a solvent having substantially the same solvent properties upon said residuum as acetone, said residue being present in amount and potency suificient to appreciably increase the oiliness of said lubricating oil.
4. A lubricating oil composition comprising a I mineral oil derivative deficient in oiliness, and a Pe sy lublleetlng 01L When a Penna residue obtained by exhaustively extracting a sylvania lubricating oil with a Saybolt viscosity Pennsylvania, residuum it l t having of 57 s con s pp to the band, With rotation substantially the same solvent properties upon at 6,000 B. P. M. for 15 minutes at 210 F., about said residuum as acetone, said residue being 50 5.65 milligrams remain on the band. Oils in present in amount and potency sufi'icient to apwhich a substantially lesser umber o milligrams preciably increase the oiliness of said derivative. remains are deficient in oiliness according to this 5, A lubricating oil composition comprising a invention. naphthenic base mineral oil, and a residue ob- The following examples illustrate the effect of tained by exhaustively extracting a Pennsylvania 55 The degree of oiliness may be determined by means of the Sperry-Cammen Adher-o-scope, which utilizes a thin metal band of known weight and constant dimensions, to which is applied an oil film. The band is then placed on a disc and rotated at several thousand r. p. m. at a controlled temperature and humidity for a standard 40 period of time, after which the band is removed and Weighed. The amount of oil adhering thereto is a function of the oiliness.
By the expression oil deficient in oiliness as used in the specification and claims, we mean 45 an oil which has poor adhesive capacity to metallic surfaces as compared with that possessed by residuum with a solvent having substantially the same solvent properties upon said residuum as acetone, said residue being present in amount and potency suificient to appreciably increase the oiliness of said mineral oil.
6. A lubricating oil composition comprising a solvent refined mineral oil, and a residue obtained by exhaustively extracting a Pennsylvania residuum with a solvent having substantially the same solvent properties upon said residuum as acetone, said residue being present in amount and potency sufiicient to appreciably increase the oiliness of said mineral oil.
7 A lubricating oil composition in accordance with claim 1 in which said residue is obtained by exhaustively extracting a Pennsylvania residuum with acetone.
8. A lubricating oil composition in accordance with claim 2 in which said residue is obtained by exhaustively extracting a Pennsylvania residuum with acetone.
9. A lubricating oil composition in accordance with claim 3 in which said residue is obtained by exhaustively extracting a Pennsylvania residuum with acetone.
10. A lubricating oil composition in accordance with claim 4 in which said residue is obtained by exhaustively extracting a Pennsylvania residuum with acetone.
11. A lubricating oil composition in accordance with claim 5 in which said residue is obtained by exhaustively extracting a Pennsylvania residuum with acetone.
12. A'lubricating oil composition in accordance with claim6 in which said residue is obtained by exhaustively extracting a Pennsylvania residuum with acetone.
FERDINAND W. BRETH. ANTON KINSEL.
US83268A 1936-06-03 1936-06-03 Oil composition Expired - Lifetime US2139668A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2614991A (en) * 1950-03-30 1952-10-21 Standard Oil Dev Co Steam engine lubricants
US2695262A (en) * 1949-12-22 1954-11-23 Phillips Petroleum Co Production of low aniline point oil
US2725345A (en) * 1951-02-21 1955-11-29 Exxon Standard Sa Stabilized mineral oils and method of preparation

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2695262A (en) * 1949-12-22 1954-11-23 Phillips Petroleum Co Production of low aniline point oil
US2614991A (en) * 1950-03-30 1952-10-21 Standard Oil Dev Co Steam engine lubricants
US2725345A (en) * 1951-02-21 1955-11-29 Exxon Standard Sa Stabilized mineral oils and method of preparation

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