US2131320A - Printing with mordant dyestuffs - Google Patents
Printing with mordant dyestuffs Download PDFInfo
- Publication number
- US2131320A US2131320A US123726A US12372637A US2131320A US 2131320 A US2131320 A US 2131320A US 123726 A US123726 A US 123726A US 12372637 A US12372637 A US 12372637A US 2131320 A US2131320 A US 2131320A
- Authority
- US
- United States
- Prior art keywords
- printing
- mordant
- lactate
- chromium
- thickening
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011651 chromium Substances 0.000 description 10
- 230000008719 thickening Effects 0.000 description 10
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 9
- 229920000084 Gum arabic Polymers 0.000 description 9
- 239000000205 acacia gum Substances 0.000 description 9
- 235000010489 acacia gum Nutrition 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 241000978776 Senegalia senegal Species 0.000 description 8
- 229920002955 Art silk Polymers 0.000 description 7
- XFJRTXJMYXFAEE-UHFFFAOYSA-K [Cr+3].CC(O)C([O-])=O.CC(O)C([O-])=O.CC(O)C([O-])=O Chemical compound [Cr+3].CC(O)C([O-])=O.CC(O)C([O-])=O.CC(O)C([O-])=O XFJRTXJMYXFAEE-UHFFFAOYSA-K 0.000 description 7
- 229910052804 chromium Inorganic materials 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- -1 aliphatic oXy Chemical class 0.000 description 5
- 150000001447 alkali salts Chemical class 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229920000297 Rayon Polymers 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 3
- 229940001447 lactate Drugs 0.000 description 3
- 150000003893 lactate salts Chemical group 0.000 description 3
- 239000004627 regenerated cellulose Substances 0.000 description 3
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 3
- 229960002167 sodium tartrate Drugs 0.000 description 3
- 239000001433 sodium tartrate Substances 0.000 description 3
- 235000011004 sodium tartrates Nutrition 0.000 description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- VILMUCRZVVVJCA-UHFFFAOYSA-M sodium glycolate Chemical compound [Na+].OCC([O-])=O VILMUCRZVVVJCA-UHFFFAOYSA-M 0.000 description 2
- 239000001540 sodium lactate Substances 0.000 description 2
- 229940005581 sodium lactate Drugs 0.000 description 2
- 235000011088 sodium lactate Nutrition 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 244000171897 Acacia nilotica subsp nilotica Species 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- GRWZHXKQBITJKP-UHFFFAOYSA-N dithionous acid Chemical compound OS(=O)S(O)=O GRWZHXKQBITJKP-UHFFFAOYSA-N 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/36—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using mordant dyes ; using metallisable dyes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/917—Wool or silk
Definitions
- the principal advantage of the processes is to be found in the fact that the soft feel and the lustre of the fibre, which in the absence of the lactate group, owing to coagulation of thearabic gum thickening in presence of the chromium mordant, would suffer, are retained. According to a particularly advantageous form of the processes chromium lactate is used.
- the processes may also be combined with advantage with the process of U. S. Patent No. 1,848,589, according to which urea is also used in the printing paste.
- the present invention relates to an improvement whereby the treatment with lukewarm water is rendered unnecessary, and a completely soft feel of the fibres is attained by simply washing the printed material with cold water after steaming.
- the printing paste sodium tartrate or, in general, an alkali salt of an aliphatic oXy acid such as tartaric acid, lactic acid, glycollic acid and so on.
- chromium' lactate is used in the known process the present invention may be carried into effect by adding an alkali lactate, alkali tartrate or alkali glyco1- late to the printing paste in addition to chromium lactate.
- Example 2 the duration of the steaming can be appreciably shortened by increasing the quantity of urea to 100 grams.
- Sodium lactate or sodium glycollate can be used instead of sodium tartratein the foregoing examples with similar effect.
- the invention may also be applied in printing fabrics of other artificial silks, such as fabrics of cuprammonium artificial silk.
- a printing paste containing a mordant dyestufi, a gum arabic thickening, a chromium mordant having Cr in the cation in the presence of a lactate groupand an alkali salt of an aliphatic hydroxy acid As a new composition of matter, a printing paste containing a mordant dyestufi, a gum arabic thickening, a chromium mordant having Cr in the cation in the presence of a lactate groupand an alkali salt of an aliphatic hydroxy acid.
- a printing paste containing a mordant dyestufi, a gum arabic thickening, chromiumlactate and an alkali salt of an aliphatic hydroxy acid 4.
- a printing paste containing a mordant dyestuif, a gum arabic thickening, chromium lactate and sodium tartrate 4.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
Patented Sept. 27, 1938 PRINTING WITH MORDANT DYESTUFFS Emil Gubler, Basel, Switzerland, assignor to the firm Durand & Huguensin S. A. Basel, Switzerland No Drawing. Applicatio rial No. 123,726. In 1936 7 Claims.
In the U. S. patent application Ser. No. 716,001 are described processes for printing with mordant dyestuffs (chrome dyestuffs) on fabrics of animal fibres, namely natural silk, and on fabrics of regenerated cellulose such as viscose artificial silk, cuprammonium artificial silk and so on, in which the printing pastes used contain the mordant dyestuff, gum arabic thickening and a chromium mordant, having Cr in the cation in the presence of a lactate group. The principal advantage of the processes is to be found in the fact that the soft feel and the lustre of the fibre, which in the absence of the lactate group, owing to coagulation of thearabic gum thickening in presence of the chromium mordant, would suffer, are retained. According to a particularly advantageous form of the processes chromium lactate is used. The processes may also be combined with advantage with the process of U. S. Patent No. 1,848,589, according to which urea is also used in the printing paste.
According to the hitherto usual procedure, after the prints thus prepared have been steamed they must be washed first with cold Water and then with lukewarm water at about 40-50 C. in order that the fibres may have the desired soft feel. This procedure involves certain disadvantages. For example, if basic dyestuifs are printed on the material together with the chrome dyestuffs, the prints of the basic dyestuffs are damaged by the treatment with lukewarm water and bleed. Moreover, the apparatus necessary for the treatment is not available in all silk printing works.
The present invention relates to an improvement whereby the treatment with lukewarm water is rendered unnecessary, and a completely soft feel of the fibres is attained by simply washing the printed material with cold water after steaming. For this purpose in accordance with the invention there is added to the printing paste sodium tartrate or, in general, an alkali salt of an aliphatic oXy acid such as tartaric acid, lactic acid, glycollic acid and so on.
If, as has hitherto been preferable, chromium' lactate is used in the known process the present invention may be carried into effect by adding an alkali lactate, alkali tartrate or alkali glyco1- late to the printing paste in addition to chromium lactate.
11 February 2, 1937, Se- Germany February 11,
The following examples illustrate the invention:
The following printing pastes are prepared:
Example l 2 3 Ohromocitronine R (Schultz, Farbstofltabel- Grams Grams Grams tabellen 7th Edn, N0. 999) -l 30 Dyestuil according to Example 1 of German Specification No. 156234.. l. 30 Water 232 192 152 Formic acid (807) 30 .l Phenol l l 30 Furfuryl alcohol 10 Sodium tartrate cryst 30 30 30 Gum arabic thickening (1 1) 610 610 610 Chromium lactate (14.7% OM 38 38 38 Urea 60 60 100 25% solution of hydrosulphite NF The paste is printed on natural silk or viscose artificial silk, and the material is steamed for 45 minutes, then washed with cold water and dried. There are obtained respectively yellow, blue and orange prints whilst the fibre has an unobjectionable soft feel.
In the case of Example 2 the duration of the steaming can be appreciably shortened by increasing the quantity of urea to 100 grams.
Sodium lactate or sodium glycollate can be used instead of sodium tartratein the foregoing examples with similar effect.
The invention may also be applied in printing fabrics of other artificial silks, such as fabrics of cuprammonium artificial silk.
What I claim is:--
1. In a process of steam printing with chromium mordant dyestuffs on lustrous fibres, including natural silk and regenerated cellulose fibre, such as viscose or cuprammonium artificial silk, an improvement consisting in printing the material with a paste containing the mordant dyestuff, a gum arabic thickening, a chromium mordant having Cr in the cation in the presence of a lactate group, and an alkali salt of an aliphatic hydroxy acid, thereby obviating the formation of a harsh feel, uneven dyeing and loss of lustre on the imprinted parts.
2. In a processor steam printing with chromium mordant dyestuffs on lustrous fibres, in-
cluding natural silk and regenerated cellulose V fibre such as viscose or cuprammonium artificial silk, an improvement consisting in printing the material with a paste containing the mordant dyestufi, a gum arabic thickening, chromium lactate, and an alkali salt of an aliphatic hydroxy acid, thereby obviating the formation of a harsh feel, uneven dyeing and loss of lustre on the imprinted parts.
3. As a new composition of matter, a printing paste containing a mordant dyestufi, a gum arabic thickening, a chromium mordant having Cr in the cation in the presence of a lactate groupand an alkali salt of an aliphatic hydroxy acid.
4. A printing paste containing a mordant dyestufi, a gum arabic thickening, chromiumlactate and an alkali salt of an aliphatic hydroxy acid.
5. A printing paste containing a mordant dyestuif, a gum arabic thickening, chromium lactate and sodium tartrate.
6. A printing'paste containing a mordant dyestuff, a gum arabic thickening, chromium lactate and sodium glycollate.
7 A printing paste containing a mordant dyestuff, a gum arabic thickening, chromium lactate and sodium lactate.
EMIL GUBLER.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2131320X | 1936-02-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2131320A true US2131320A (en) | 1938-09-27 |
Family
ID=7986444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US123726A Expired - Lifetime US2131320A (en) | 1936-02-11 | 1937-02-02 | Printing with mordant dyestuffs |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2131320A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2456471A (en) * | 1944-02-17 | 1948-12-14 | Durand & Huguenin Ag | Process and paste for printing fabrics made of cellulose, such as textile fabrics, paper and the like, with chromium mordant dyestuffs |
-
1937
- 1937-02-02 US US123726A patent/US2131320A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2456471A (en) * | 1944-02-17 | 1948-12-14 | Durand & Huguenin Ag | Process and paste for printing fabrics made of cellulose, such as textile fabrics, paper and the like, with chromium mordant dyestuffs |
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