US2097211A - Protective treatment of metals and alloys - Google Patents

Protective treatment of metals and alloys Download PDF

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Publication number
US2097211A
US2097211A US32117A US3211735A US2097211A US 2097211 A US2097211 A US 2097211A US 32117 A US32117 A US 32117A US 3211735 A US3211735 A US 3211735A US 2097211 A US2097211 A US 2097211A
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US
United States
Prior art keywords
treatment
iron
phosphate
solution
alloys
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US32117A
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English (en)
Inventor
Davies Herbert Tasman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
METALLURG TREAT SYNDICATE Ltd
METALLURGICAL TREATMENT SYNDICATE Ltd
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METALLURG TREAT SYNDICATE Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by METALLURG TREAT SYNDICATE Ltd filed Critical METALLURG TREAT SYNDICATE Ltd
Application granted granted Critical
Publication of US2097211A publication Critical patent/US2097211A/en
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Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/78Pretreatment of the material to be coated

Definitions

  • the present invention relates Salt solution as well as with the copper or nickel to that class of treatment in which phosphoric s t s lution I ay u a simple Zinc s t s u- 5 acid or a phosphate salt solution is used to protion or I may use a solution of zinc sulphate conduce a coating or integral surface layer of phostaining small amounts of common salt, boric acid,
  • a protective treatment for metallic articles taneously or prior to such treatment I may treat consisting essentially of iron comprising subjectthe articles with a solution of a zinc salt.
  • the treatment or treatments may be an imabout one per cent strength of a water-soluble mersion at ordinary room temperature or at a salt of a metal taken from the group consisting somewhat raised temperature, but preferably an of copper and nickel for a period ranging from electric current is employed to facilitate or hasten a few seconds to a few minutes while simultanethe action, the article to be treated being made a ously passing an electric current through the cathode. solution using the article as a cathode, and then The efiect of the treatment or treatments treating the article to formation of a metallic seems to be to prepare an advantageously smooth phosphate coating. surface on the foundation metal so that the sub- 2.
  • a protective treatment for metallic articles sequent treatment in a bath of iron phosphate or co sisting essentially of iron compri jectphosphoric acid with or without added iron or ing said articles as the cathode of an electric iron phosphate in the known manner ensures an circuit to the action of a solution of a water improved union of the resultant phosphate coatsoluble coppe Salt of about One p cent.
  • a protective treatment for metallic articles 35 immersed in a bath of copper and/or nickel sulconsisting essentially of iron comprising subjectphate solution of about one per cent. strength ing said articles as the cathode of an electric and made the cathode for an electric current for circuit to the action of a solution of about one a period of from a few seconds to a few minutes, per cent strength of a mixture of water soluble the time being to some extent dependent on nickel and copper salts for aperiod ranging from 40 the strength of the solution and the temperature. a few seconds to a few minutes and then forming If a composite treatment is desired, a similar thereon ametallic phosphate coating. treatment in a zinc sulphate bath may precede 4.
  • a protective treatment for metallic articles the treatment in the copper and/or nickel sulconsisting essentially of iron comprising subjectphate bath, or the zinc sulphate may be added ing said articles as the cathode of an electric 5 to the copper and/or nickel sulphate bath. circuit to the action of an aqueous solution of a The article thus pretreated is then given the zinc salt, simultaneously to the action of an phosphate coating by treatment in a bath conaqueous solution of a salt of a metal taken from taining merely phosphoric acid or iron phosthe group consisting of copper and nickel, the
  • I may employ a bath of mixed phosphates, strengtnand finally subjecting the articles to the the added metallic phosphate, for example chroformation of a metallic phosphate coating.
  • mlum nickel or copper phosphate serving to cause the formation of a deposit or coating of HERBERT TASMAN DAVIES.

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)
US32117A 1934-08-13 1935-07-18 Protective treatment of metals and alloys Expired - Lifetime US2097211A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB23328/34A GB438816A (en) 1934-08-13 1934-08-13 Improvements relating to a protective treatment of metals and alloys

Publications (1)

Publication Number Publication Date
US2097211A true US2097211A (en) 1937-10-26

Family

ID=10193827

Family Applications (1)

Application Number Title Priority Date Filing Date
US32117A Expired - Lifetime US2097211A (en) 1934-08-13 1935-07-18 Protective treatment of metals and alloys

Country Status (4)

Country Link
US (1) US2097211A (ko)
BE (1) BE410815A (ko)
FR (1) FR793729A (ko)
GB (1) GB438816A (ko)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3468724A (en) * 1966-03-31 1969-09-23 Amchem Prod Metal coating process
US3544390A (en) * 1967-12-04 1970-12-01 Siderurgie Fse Inst Rech Phosphatizing process for iron products and products obtained thereby
US4437947A (en) 1980-02-21 1984-03-20 Nippon Steel Corporation Cold rolled steel strip having an excellent phosphatizing property and process for producing the same
US4522892A (en) * 1982-04-17 1985-06-11 Nippon Steel Corporation Method for producing a steel strip having an excellent phosphate-coating property
US5160551A (en) * 1990-04-21 1992-11-03 Metallgesellschaft Aktiengesellschaft Activator for use in phosphating processes
US20090084682A1 (en) * 2007-09-28 2009-04-02 Ppg Industries Ohio, Inc. Methods for coating a metal substrate and related coated metal substrates
US20100159258A1 (en) * 2008-12-18 2010-06-24 Ppg Industries Ohio, Inc. Methods for passivating a metal substrate and related coated metal substrates

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3468724A (en) * 1966-03-31 1969-09-23 Amchem Prod Metal coating process
US3544390A (en) * 1967-12-04 1970-12-01 Siderurgie Fse Inst Rech Phosphatizing process for iron products and products obtained thereby
US4437947A (en) 1980-02-21 1984-03-20 Nippon Steel Corporation Cold rolled steel strip having an excellent phosphatizing property and process for producing the same
US4522892A (en) * 1982-04-17 1985-06-11 Nippon Steel Corporation Method for producing a steel strip having an excellent phosphate-coating property
US5160551A (en) * 1990-04-21 1992-11-03 Metallgesellschaft Aktiengesellschaft Activator for use in phosphating processes
US20090084682A1 (en) * 2007-09-28 2009-04-02 Ppg Industries Ohio, Inc. Methods for coating a metal substrate and related coated metal substrates
US9574093B2 (en) 2007-09-28 2017-02-21 Ppg Industries Ohio, Inc. Methods for coating a metal substrate and related coated metal substrates
US20100159258A1 (en) * 2008-12-18 2010-06-24 Ppg Industries Ohio, Inc. Methods for passivating a metal substrate and related coated metal substrates
US8282801B2 (en) 2008-12-18 2012-10-09 Ppg Industries Ohio, Inc. Methods for passivating a metal substrate and related coated metal substrates

Also Published As

Publication number Publication date
BE410815A (ko)
FR793729A (fr) 1936-01-30
GB438816A (en) 1935-11-25

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