US2090899A - Manufacture of articles from malleable cast iron - Google Patents

Manufacture of articles from malleable cast iron Download PDF

Info

Publication number
US2090899A
US2090899A US22114A US2211435A US2090899A US 2090899 A US2090899 A US 2090899A US 22114 A US22114 A US 22114A US 2211435 A US2211435 A US 2211435A US 2090899 A US2090899 A US 2090899A
Authority
US
United States
Prior art keywords
content
iron
articles
cast iron
manganese
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US22114A
Inventor
Roesch Karl
Schleimer Otto Josef
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Application granted granted Critical
Publication of US2090899A publication Critical patent/US2090899A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D5/00Heat treatments of cast-iron
    • C21D5/04Heat treatments of cast-iron of white cast-iron
    • C21D5/06Malleabilising
    • C21D5/08Malleabilising with oxidation of carbon
    • C21D5/10Malleabilising with oxidation of carbon in gaseous agents

Definitions

  • ferritic or pearlitic structure practically free from temper carbon to castings containing from 2.2 to 3.2% carbon, less than 0.6% silicon, from 0.15 to 1.2% manganese, and less than 0.1% sulphur by subjecting them to an oxidizing annealing.
  • the low silicon content prevents the formation of temper carbon which previously made welding of malleable cast iron practically impossible, and it' also improves the quality of the weld.
  • the low sulphur content suppresses the formation of sulphur dioxide gas and the med-shortness normally brought about during welding by a high sulphur content, and thus prevents the occurrence of holes and pores in the weld.
  • the manganese content in thepig iron is at least equal to twice the silicon content, and preferably equal to the sum of twice "the silicon content and three times the sulphur content.
  • a pig iron with 0.6% silicon and 0.10% sulphur should accordingly contain at least 1.2% and preferably 1.5% manganese.
  • the manganese content of the pig iron is adjusted as described up to a total content of 2% the eifect on the capacity of the malleable cast iron for being welded is very satisfactory. This is due to the fact that in comparison with normal malleable cast iron the pig iron is completely deoxidized straight away by the high manganese content. In particular, over-oxidation of the surface layers is avoided by the powerful decarboniz'ation that is effected during the temper process by the manganese in combination with the unusually low silicon content, and
  • the invention is particularly applicable to the manufacture of thin-walled articles, i. e. articles of wall thickness less than an inch and in which decarbonizatlon throughout the whole cross-section can be eflected by the temper process.
  • vcontaining silicon in an amount not exceeding 0.8%, containing sulphur in an amount not exceeding 0.15%, an amount of manganese that is at least equal. to twice the silicon, content but not more than 2%, and the remainder iron and the usual content of phosphorus, in iron oxide material and subjecting them to an oxidizing annealing treatment, whereby decomposition of the -iron carbide is suppressed and the carbon is directly removed from the cementite.
  • the process of producing articles that can be satisfactorily welded which comprises packing iron castings containing 22-33% carbon, containing silicon in an amount not exceeding 0.8%, containing sulphur in an amount not exceeding 0.15%, an amount of manganese that is. equal to at least the sum of twice the silicon content and three times the sulphur content but not substantially more than 2%, and the remainder iron and the usual content of phosphorus, in iron oxide material and subjecting them to an oxidizing annealing treatment, whereby decomposition of the iron carbide is suppressed and the carbon is directly removed from the cementite.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Arc Welding In General (AREA)

Description

Patented Aug. 24, 1937 UNITED STATES PATENT OFFICE MANUFACTURE or Aarrcms mom- MAL- mAsm c s'r mos Karl Roesch and sch Otto Josef schleim er, nemeid, Germany No Drawing. Application May 1'1, 1985, Serial 4 No. 22,114. In Germany October 31,1984
2 Claims. (c1. nil-21.8)
ferritic or pearlitic structure practically free from temper carbon to castings containing from 2.2 to 3.2% carbon, less than 0.6% silicon, from 0.15 to 1.2% manganese, and less than 0.1% sulphur by subjecting them to an oxidizing annealing.
treatment in which decomposition of the iron carbide is. suppressed and the carbon is directly removed fromthe cementite. The low silicon content prevents the formation of temper carbon which previously made welding of malleable cast iron practically impossible, and it' also improves the quality of the weld. The low sulphur content suppresses the formation of sulphur dioxide gas and the med-shortness normally brought about during welding by a high sulphur content, and thus prevents the occurrence of holes and pores in the weld.
It has now been found that it is preferable to adjust the manganese content in accordance with an absolutely definite law. According to the invention the manganese content in thepig iron is at least equal to twice the silicon content, and preferably equal to the sum of twice "the silicon content and three times the sulphur content. A pig iron with 0.6% silicon and 0.10% sulphur should accordingly contain at least 1.2% and preferably 1.5% manganese. I
If this law is observed it has been found that it is no longer necessary to adhere so closely to the low silicon and sulphur contents as is stated in our application Ser. No. 739,056, a fact which much facilitates the melting of the cast iron. It .has now been found that the capacity of the malleable caste-iron for being satisfactorily welded does not suffer if the silicon content of the casting is as high as 0.8% and the sulphur content as high as 0.15%. The corresponding manganese content according to this invention is then at least 1.6% and preferably 2%. A manganese content higher than 2% is not desirable.
If the manganese content of the pig iron is adjusted as described up to a total content of 2% the eifect on the capacity of the malleable cast iron for being welded is very satisfactory. This is due to the fact that in comparison with normal malleable cast iron the pig iron is completely deoxidized straight away by the high manganese content. In particular, over-oxidation of the surface layers is avoided by the powerful decarboniz'ation that is effected during the temper process by the manganese in combination with the unusually low silicon content, and
this is very important for good and reliable welding. Moreoventhe high manganese content leads to a fluid slag during welding. which is desirable. Finally the manganese helps to prevent the decomposition' of the carbide and coniblues with the sulphur to form manganese sulphide which is harmless. Therefore a high manganese content makes it possible to use a somewhat higher. silicon content without there being any need to fear precipitation of carbide, and
also allows the use of a somewhat higher sulphur content.
Finally, the fused metal produced on welding malleable cast iron made according to the invention runs easily and adheres well to the work, so that even overhead welding can be carried on without much difnculty.
The invention is particularly applicable to the manufacture of thin-walled articles, i. e. articles of wall thickness less than an inch and in which decarbonizatlon throughout the whole cross-section can be eflected by the temper process.
We claim; 1. The process of producing articles that can be satisfactorily welded, which comprises packing iron castings containing 2.2-3.2% carbon,
vcontaining silicon in an amount not exceeding 0.8%, containing sulphur in an amount not exceeding 0.15%, an amount of manganese that is at least equal. to twice the silicon, content but not more than 2%, and the remainder iron and the usual content of phosphorus, in iron oxide material and subjecting them to an oxidizing annealing treatment, whereby decomposition of the -iron carbide is suppressed and the carbon is directly removed from the cementite.
2; The process of producing articles that can be satisfactorily welded, which comprises packing iron castings containing 22-33% carbon, containing silicon in an amount not exceeding 0.8%, containing sulphur in an amount not exceeding 0.15%, an amount of manganese that is. equal to at least the sum of twice the silicon content and three times the sulphur content but not substantially more than 2%, and the remainder iron and the usual content of phosphorus, in iron oxide material and subjecting them to an oxidizing annealing treatment, whereby decomposition of the iron carbide is suppressed and the carbon is directly removed from the cementite.
KARL ROESCH. o'rro JOBEF scmmmn.
US22114A 1934-10-31 1935-05-17 Manufacture of articles from malleable cast iron Expired - Lifetime US2090899A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2090899X 1934-10-31

Publications (1)

Publication Number Publication Date
US2090899A true US2090899A (en) 1937-08-24

Family

ID=7984473

Family Applications (1)

Application Number Title Priority Date Filing Date
US22114A Expired - Lifetime US2090899A (en) 1934-10-31 1935-05-17 Manufacture of articles from malleable cast iron

Country Status (1)

Country Link
US (1) US2090899A (en)

Similar Documents

Publication Publication Date Title
US4000011A (en) Method of surface hardening
US2126074A (en) Brazing
US2090899A (en) Manufacture of articles from malleable cast iron
US2046638A (en) Process of treating metal
US3723094A (en) Electroflux slags and methods of electroflux remelting
US2450395A (en) Malleable cast iron
US1888132A (en) Method of casting steel ingots
US2077568A (en) Process for purifying ferrous metals
US2458651A (en) Processes for producing low carbon chromium steels
GB428950A (en) Improvements in processes for the manufacture of ironchromium alloys
US980369A (en) Manufacture of steel.
US1727088A (en) Method of making rimming steel
US2102539A (en) Process of treating metal
US2225968A (en) Decarburized white iron casting
US2316948A (en) Aluminum-treated cast steel
US2233726A (en) Method of treating low carbon open hearth steel
US1674438A (en) Process of producing nickel alloys
US3309194A (en) Purification of alloys
US2380385A (en) Process of producing ferrous metal articles
US2157674A (en) Process of manufacturing a free machining case-hardening steel
US1437405A (en) Method and means of treating molten metal
US1423847A (en) Method of producing silicon-manganese-chrome steel
US1915400A (en) Preparation of alloy steels
US1132661A (en) Method of preparing iron for castings.
US1075782A (en) Method of raising the alloying qualification of titanium.