US2061468A - Soap preparation - Google Patents
Soap preparation Download PDFInfo
- Publication number
- US2061468A US2061468A US614628A US61462832A US2061468A US 2061468 A US2061468 A US 2061468A US 614628 A US614628 A US 614628A US 61462832 A US61462832 A US 61462832A US 2061468 A US2061468 A US 2061468A
- Authority
- US
- United States
- Prior art keywords
- soap
- soaps
- preparation
- agents
- sulphuric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000344 soap Substances 0.000 title description 21
- 238000002360 preparation method Methods 0.000 title description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- -1 aliphatic hydroxy hydrocarbons Chemical class 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 150000001447 alkali salts Chemical class 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 2
- 230000001225 therapeutic effect Effects 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- JEGNXMUWVCVSSQ-ISLYRVAYSA-N (e)-octadec-1-en-1-ol Chemical compound CCCCCCCCCCCCCCCC\C=C\O JEGNXMUWVCVSSQ-ISLYRVAYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical class [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 229940053200 antiepileptics fatty acid derivative Drugs 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 230000037307 sensitive skin Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- SZGKXOCIHKEMHV-UHFFFAOYSA-M sodium;octadec-1-ene-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCCC=CS([O-])(=O)=O SZGKXOCIHKEMHV-UHFFFAOYSA-M 0.000 description 1
- 229940124597 therapeutic agent Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/925—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of animal origin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/03—Organic sulfoxy compound containing
Definitions
- This invention relates to soap compositions of such high quality as to be especially suitable as toilet soaps and as medicinal soaps, soaps of this character intended for use on the body being referred to herein as bath soaps to distinguish from industrial soaps and the like of a coarser nature.
- soap preparations having as the principal constituent one or more alkali salts of sulphuric derivatives of the higher aliphatic hydroxy hydrocarbons.
- the soap compositions constituting the present invention contain in addition to these salts a superfatting agent, and one or more agents to give to the preparation some special property or properties, as will hereinafter be more clearly explained.
- the sulphuric derivatives of the higher aliphatic hydroxy hydrocarbons from which the alkali salts are obtained may be esters, sulphonates, or mixed esters and sulphonates.
- the method by which these sulphuric derivatives are produced does not constitute part of the present invention, for suitable methods of producing the same are already known.
- the hydroxy hydrocarbons themselves may be obtained in the form of alcohols from natural waxes, or by the oxidation of saturated aliphatic hydrocarbons, or by the reduction of fatty acids or fatty acid derivatives. Instead of first producing the hydroxy hydrocarbon and then sulphonating, the reverse order may be followed.
- salts of sulphuric derivatives of higher aliphatic hydroxy hydrocarbons found suitable are those containing more than eight carbon atoms in the chain, such for example, as sodium dodecyl sulphate and sodium octadecenyl sulphonate.
- the superfatting agents employed include, for example, wool fat, lanolin, higher aliphatic alcohols such as octadecenol and octadecanol, and other like products having similar properties.
- the soap preparations of the present invention may be compounded by incorporating the superfatting agent or agents into the sulphuric. derivative of the higher aliphatic hydroxy hydrocarbon before the same is neutralized for the formation of the sodium or other alkali salt.
- the preparation may also be produced by partially sulphonating or sulphating a suitable fattralizing the sulphuric derivative.
- the unreacted excess of the higher aliphatic alcohol acts as the superfatting agent in the final product.
- the therapeutic agent may be added to any of the ingredients used or to any mixture thereof so long as it does not interfere with the production of a composition of proper consistency, or will not itself be destroyed or otherwise rendered ineffective by the subsequent treatment in completing the preparation.
- the proportions of the components in the soap preparations are not critical, but may be varied within wide limits, according to the particular agents used and the properties desired in the final product.
- Example for the production of a soap composition suitable as a shaving soap 90 kgs. of sodium dodecyl sulphate are mixed in any suitable machine with kgs. of lanolin and a small quantity of perfume.
- the soap preparations of the present invention have exceptionally high cleansing power and will not cause irritation of any kind on even the most sensitive skin.
- ordinary soaps they have the advantage that they are not adversely aifected by use in very hard or even sea water, this quality being due to their absolute stability in the presence of lime and magnesia salts.
- a bath soap composition adapted to produce When the mass becomes homogeneous, the V a non-alkaline solution upon hydrolysis in water,
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Zoology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Description
Patented Nov. 17, 1936 UNITED STATES SOAP PREPARATION Walter Kling, Chemnitz, Germany, assignor to H. Th. Bohme Aktiengesellschaft, Chemnitz, Germany, a corporation of Germany No Drawing. Application May 31, 1932, Serial No. 614,628. In Germany June 12, 1931 2 Claims.
This invention relates to soap compositions of such high quality as to be especially suitable as toilet soaps and as medicinal soaps, soaps of this character intended for use on the body being referred to herein as bath soaps to distinguish from industrial soaps and the like of a coarser nature.
More particularly, it relates to soap preparations having as the principal constituent one or more alkali salts of sulphuric derivatives of the higher aliphatic hydroxy hydrocarbons.
The soap compositions constituting the present invention contain in addition to these salts a superfatting agent, and one or more agents to give to the preparation some special property or properties, as will hereinafter be more clearly explained.
The sulphuric derivatives of the higher aliphatic hydroxy hydrocarbons from which the alkali salts are obtained may be esters, sulphonates, or mixed esters and sulphonates. The method by which these sulphuric derivatives are produced does not constitute part of the present invention, for suitable methods of producing the same are already known. The hydroxy hydrocarbons themselves may be obtained in the form of alcohols from natural waxes, or by the oxidation of saturated aliphatic hydrocarbons, or by the reduction of fatty acids or fatty acid derivatives. Instead of first producing the hydroxy hydrocarbon and then sulphonating, the reverse order may be followed.
The salts of sulphuric derivatives of higher aliphatic hydroxy hydrocarbons found suitable are those containing more than eight carbon atoms in the chain, such for example, as sodium dodecyl sulphate and sodium octadecenyl sulphonate.
The superfatting agents employed include, for example, wool fat, lanolin, higher aliphatic alcohols such as octadecenol and octadecanol, and other like products having similar properties.
In order to give the soap some special property making it suitable for a particular purpose, there is added a quantity of one or more therapeutic substances, antiseptic agents, dyestufis or perfumes, as is done in the preparation of ordinary bath soaps.
The soap preparations of the present invention may be compounded by incorporating the superfatting agent or agents into the sulphuric. derivative of the higher aliphatic hydroxy hydrocarbon before the same is neutralized for the formation of the sodium or other alkali salt.
The preparation may also be produced by partially sulphonating or sulphating a suitable fattralizing the sulphuric derivative.
ty alcohol or mixture of fatty alcohols, and neu- In this case, the unreacted excess of the higher aliphatic alcohol acts as the superfatting agent in the final product.
The therapeutic agent may be added to any of the ingredients used or to any mixture thereof so long as it does not interfere with the production of a composition of proper consistency, or will not itself be destroyed or otherwise rendered ineffective by the subsequent treatment in completing the preparation.
The proportions of the components in the soap preparations are not critical, but may be varied within wide limits, according to the particular agents used and the properties desired in the final product.
Example For the production of a soap composition suitable as a shaving soap, 90 kgs. of sodium dodecyl sulphate are mixed in any suitable machine with kgs. of lanolin and a small quantity of perfume.
same is shaped and pressed into bars in the usual manner, by means of a bar press.
In similar fashion special toilet and medicinal soaps may be made by adding to the basic mass, in addition to the superfatting agent, in the usual amounts, other agents customarily added to soaps, in particular, antiseptic or other therapeutic substances.
The soap preparations of the present invention have exceptionally high cleansing power and will not cause irritation of any kind on even the most sensitive skin. As contrasted with ordinary soaps, they have the advantage that they are not adversely aifected by use in very hard or even sea water, this quality being due to their absolute stability in the presence of lime and magnesia salts.
Having thus described the invention, what is claimed as new and desired to be secured by Letters Patent is:
1. A bath soap composition adapted to produce When the mass becomes homogeneous, the V a non-alkaline solution upon hydrolysis in water,
WALTER KLING.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2061468X | 1931-06-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2061468A true US2061468A (en) | 1936-11-17 |
Family
ID=7983107
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US614628A Expired - Lifetime US2061468A (en) | 1931-06-12 | 1932-05-31 | Soap preparation |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2061468A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2503338A (en) * | 1945-09-12 | 1950-04-11 | Celanese Corp | Precipitation of emulsions of styrene and copolymers thereof |
| US2679482A (en) * | 1949-10-08 | 1954-05-25 | Colgate Palmolive Co | Synthetic detergent compositions |
| US2756178A (en) * | 1953-06-17 | 1956-07-24 | Jack R Verblen | Residual lanolin hair shampoo |
| US4014807A (en) * | 1974-06-10 | 1977-03-29 | Henkel & Cie G.M.B.H. | Shaped washing agents having an improved resistance to cracking |
-
1932
- 1932-05-31 US US614628A patent/US2061468A/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2503338A (en) * | 1945-09-12 | 1950-04-11 | Celanese Corp | Precipitation of emulsions of styrene and copolymers thereof |
| US2679482A (en) * | 1949-10-08 | 1954-05-25 | Colgate Palmolive Co | Synthetic detergent compositions |
| US2756178A (en) * | 1953-06-17 | 1956-07-24 | Jack R Verblen | Residual lanolin hair shampoo |
| US4014807A (en) * | 1974-06-10 | 1977-03-29 | Henkel & Cie G.M.B.H. | Shaped washing agents having an improved resistance to cracking |
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