US2058788A - Lubricating compound - Google Patents
Lubricating compound Download PDFInfo
- Publication number
- US2058788A US2058788A US679717A US67971733A US2058788A US 2058788 A US2058788 A US 2058788A US 679717 A US679717 A US 679717A US 67971733 A US67971733 A US 67971733A US 2058788 A US2058788 A US 2058788A
- Authority
- US
- United States
- Prior art keywords
- oil
- water
- soluble
- mixture
- lubricating compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001875 compounds Chemical class 0.000 title description 3
- 230000001050 lubricating effect Effects 0.000 title 1
- 239000003921 oil Substances 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000000203 mixture Substances 0.000 description 9
- 239000010665 pine oil Substances 0.000 description 8
- 239000000344 soap Substances 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 7
- 239000010730 cutting oil Substances 0.000 description 4
- 239000010688 mineral lubricating oil Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000010687 lubricating oil Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 2
- 241000723346 Cinnamomum camphora Species 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229930008380 camphor Natural products 0.000 description 2
- 229960000846 camphor Drugs 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- KQSJSRIUULBTSE-UHFFFAOYSA-M sodium;3-(3-ethylcyclopentyl)propanoate Chemical compound [Na+].CCC1CCC(CCC([O-])=O)C1 KQSJSRIUULBTSE-UHFFFAOYSA-M 0.000 description 2
- 150000003505 terpenes Chemical class 0.000 description 2
- 235000007586 terpenes Nutrition 0.000 description 2
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- 229930006727 (-)-endo-fenchol Natural products 0.000 description 1
- REPVLJRCJUVQFA-UHFFFAOYSA-N (-)-isopinocampheol Natural products C1C(O)C(C)C2C(C)(C)C1C2 REPVLJRCJUVQFA-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Chemical class C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAIHUHQCLTYTSF-MRTMQBJTSA-N Fenchyl alcohol Chemical compound C1C[C@]2(C)[C@H](O)C(C)(C)[C@H]1C2 IAIHUHQCLTYTSF-MRTMQBJTSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Chemical class O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- -1 alkali metal sodium naphthenate Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 description 1
- 229940116229 borneol Drugs 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- IAIHUHQCLTYTSF-UHFFFAOYSA-N fenchyl alcohol Natural products C1CC2(C)C(O)C(C)(C)C1C2 IAIHUHQCLTYTSF-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- 125000005608 naphthenic acid group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Chemical class OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/08—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/16—Naphthenic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/20—Rosin acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
Definitions
- a highly satisfactory soluble oil which is stable under all normal conditions of use and which does not precipitate gummy compounds, may be prepared from.
- a petroleum hydrocarbon lubricating oil in which there has been dissolved an oiland water-solm ble soap and a small quantity of pine oil.
- a soluble oil prepared in this manner is mixed with water, a cutting oil emulsion of extremely high stability results.
- any one of the well-lmownalkali metal soaps may be used as an emulsifying agent.
- These include the soaps of fatty acids, rosin acids, sulionic acids, as well as naphthenic acids recoverable from petroleum.
- Thesodium naphthenates are particularly valuable in that they are extremely stable and in that they do not aflect deleteriously the metals with which they come in contact. in use.
- pine oil has been found to be a most satisfactory stabilizing agent
- oxygenated terpene derivatives such as terpineol, borneol, ienchyl alcohol and camphor or mixtures of the same may be employed.
- I give herewith a typical composition which, when mixed with from 5-50 parts of water, yields a cutting oil emulsion of extremely high stabllityr Per cent Lubricating oil having a viscosity of 100 seconds Saybolt universal Sodium naphthenate 16 Water 2 Pine oil 2 acids with the proper amount of a. caustic soda solution. The mixture is then boiled under carefully controlled conditions to bring about the vaporization of the Water. When the mixture is reduced to the proper water content, the proper proportion of pine oil and the remainder of the mineral oil is added and dissolved in the mixture with stirring.
- Petroleum hydrocarbon oils of widely varying characteristics may be found suitable in preparing soluble oils .inaccordance with the present invention.
- the proper choice of the particular oil is dictated at all times by the use to which the final cutting oil emulsion is to be subjected.
- a soluble oil consisting essentially of a mixture of a low viscosity mineral lubricating oil, sodium naphthenate, from 1-5% of pine oil, and about 2% of water.
- a soluble oil consisting of from 78-82% of 4.
- a soluble oil consisting essentially of a mixa light mineral lubricating oil, from 14-18% of ture of mineral lubricating oil, an alkali metal sodium naphthenate, 2% of pine oil, and 2% of soap, from 1-5% of oxygenated terpene selected water. from the group consisting o1 pine oil, terplneol,
- a soluble oil consisting essentially of a mixborneol, fenchyl alcohol and camphor, and about 6 ture of mineral lubricating oil, an alkali metal 2% of water.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Description
tented Get. 27, W36
attests ILWRHGATHNG QQIWEPQWND Waldersee h. Hendrey, Beacon, N. W assignor to The Texas Company, New York, N. 21., a corporation of Delaware No Drawing. Application .llniy llll, i933,
- Serial No. 67931? t Claims.
chiefly to keep the soap and oil from separating. f
When this mixture is added to water, an oil-lnwater emulsion forms, the soap acting as an emulsifying agent. It has been found that when emulsions of this type are used as Coolants in the cutting or shaping of metals, the conditions to which the emulsions are subjected often bring about the separation of the oil from its emulsified form. Furthermore, gummy compounds may performed by the oxidation of the soaps.
I have discovered that a highly satisfactory soluble oil, which is stable under all normal conditions of use and which does not precipitate gummy compounds, may be prepared from. a petroleum hydrocarbon lubricating oil in which there has been dissolved an oiland water-solm ble soap and a small quantity of pine oil. When a soluble oil prepared in this manner is mixed with water, a cutting oil emulsion of extremely high stability results.
In preparing soluble oils of the type disclosed above, any one of the well-lmownalkali metal soaps may be used as an emulsifying agent. These include the soaps of fatty acids, rosin acids, sulionic acids, as well as naphthenic acids recoverable from petroleum. Thesodium naphthenates are particularly valuable in that they are extremely stable and in that they do not aflect deleteriously the metals with which they come in contact. in use.
Although pine oil has been found to be a most satisfactory stabilizing agent, oxygenated terpene derivatives such as terpineol, borneol, ienchyl alcohol and camphor or mixtures of the same may be employed.
I have also discovered that the presence of a small quantity of water is desirable in the soluble oil base in that it greatly enhances the emulsification of the base with water in forming the cutting oil emulsion. The most desirable quantity of water for this purpose has been found to be in the neighborhood of 2% but smaller or larger percentages than this may be found advantageous in particular cases.
As an example of the application of my invention, I give herewith a typical composition which, when mixed with from 5-50 parts of water, yields a cutting oil emulsion of extremely high stabllityr Per cent Lubricating oil having a viscosity of 100 seconds Saybolt universal Sodium naphthenate 16 Water 2 Pine oil 2 acids with the proper amount of a. caustic soda solution. The mixture is then boiled under carefully controlled conditions to bring about the vaporization of the Water. When the mixture is reduced to the proper water content, the proper proportion of pine oil and the remainder of the mineral oil is added and dissolved in the mixture with stirring.
Petroleum hydrocarbon oils of widely varying characteristics may be found suitable in preparing soluble oils .inaccordance with the present invention. The proper choice of the particular oil is dictated at all times by the use to which the final cutting oil emulsion is to be subjected. In some cases, instead of using a particular hydrocarbon oil fraction, it may be found advantageous to use a mixture of petroleum. hydrocarbons, which mixture may consist of a heavy lubricating oil out back or diluted with lighter hydrocarbons.
Obviously many modifications and variations of the invention, as hereinbeforeiset forth, may be made without departing from the spirit and scope thereof, and therefore only such limitations should be imposed as are indicated in the appended claims.
I claim:
1. A soluble oil consisting essentially of a mixture of a low viscosity mineral lubricating oil, sodium naphthenate, from 1-5% of pine oil, and about 2% of water.
2. A soluble oil consisting of from 78-82% of 4. A soluble oil consisting essentially of a mixa light mineral lubricating oil, from 14-18% of ture of mineral lubricating oil, an alkali metal sodium naphthenate, 2% of pine oil, and 2% of soap, from 1-5% of oxygenated terpene selected water. from the group consisting o1 pine oil, terplneol,
3. A soluble oil consisting essentially of a mixborneol, fenchyl alcohol and camphor, and about 6 ture of mineral lubricating oil, an alkali metal 2% of water.
soap, from 1-5% of pine oil and about 2% of WALDERSEE B. HENDR-EY. water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US679717A US2058788A (en) | 1933-07-10 | 1933-07-10 | Lubricating compound |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US679717A US2058788A (en) | 1933-07-10 | 1933-07-10 | Lubricating compound |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2058788A true US2058788A (en) | 1936-10-27 |
Family
ID=24728060
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US679717A Expired - Lifetime US2058788A (en) | 1933-07-10 | 1933-07-10 | Lubricating compound |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2058788A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2689222A (en) * | 1951-12-15 | 1954-09-14 | Standard Oil Dev Co | Soluble cutting oil |
| US4759860A (en) * | 1983-08-18 | 1988-07-26 | Honda Giken Kogyo Kabushiki Kaisha | Two-cycle engine oil composition |
-
1933
- 1933-07-10 US US679717A patent/US2058788A/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2689222A (en) * | 1951-12-15 | 1954-09-14 | Standard Oil Dev Co | Soluble cutting oil |
| US4759860A (en) * | 1983-08-18 | 1988-07-26 | Honda Giken Kogyo Kabushiki Kaisha | Two-cycle engine oil composition |
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