US20240301537A1 - Hot-rolled steel sheet - Google Patents

Hot-rolled steel sheet Download PDF

Info

Publication number
US20240301537A1
US20240301537A1 US18/578,652 US202218578652A US2024301537A1 US 20240301537 A1 US20240301537 A1 US 20240301537A1 US 202218578652 A US202218578652 A US 202218578652A US 2024301537 A1 US2024301537 A1 US 2024301537A1
Authority
US
United States
Prior art keywords
less
hot
steel sheet
content
rolled steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
US18/578,652
Other languages
English (en)
Inventor
Mitsuru Yoshida
Kazuo Hikida
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Assigned to NIPPON STEEL CORPORATION reassignment NIPPON STEEL CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: HIKIDA, Kazuo, YOSHIDA, MITSURU
Publication of US20240301537A1 publication Critical patent/US20240301537A1/en
Pending legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/02—Hardening articles or materials formed by forging or rolling, with no further heating beyond that required for the formation
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/001—Heat treatment of ferrous alloys containing Ni
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/002—Heat treatment of ferrous alloys containing Cr
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/005—Heat treatment of ferrous alloys containing Mn
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/008—Heat treatment of ferrous alloys containing Si
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/02—Hardening by precipitation
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D7/00—Modifying the physical properties of iron or steel by deformation
    • C21D7/13—Modifying the physical properties of iron or steel by deformation by hot working
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205—
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226—Hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/001—Austenite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/002—Bainite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/004—Dispersions; Precipitations
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/005—Ferrite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/008—Martensite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/009—Pearlite

Definitions

  • the present invention relates to a hot-rolled steel sheet. Specifically, the present invention relates to a hot-rolled steel sheet that is formed into various shapes by press working or the like to be used, and particularly relates to a hot-rolled steel sheet that has high strength and excellent shearing workability.
  • Vehicle members are formed by press forming, and the press-formed blank sheet is often manufactured by shearing, which is highly productive.
  • a blank sheet manufactured by shearing needs to be excellent in terms of end surface accuracy after shearing. For example, when a surface roughness of a fractured surface after shearing becomes large, fatigue properties and bendability decrease.
  • Patent Document 1 discloses a technique for controlling a burr height after punching by controlling a ratio ds/db of a ferrite grain size ds of a surface layer to a ferrite grain db of an inside to 0.95 or less.
  • Patent Document 2 discloses a technique for improving peeling or warpage on an end surface of a sheet by reducing a P content.
  • Patent Document 1 is targeted at IF steel, and there are cases where it is difficult to apply Patent Document 1 to members having a strength as high as 980 MPa or more.
  • Patent Document 2 a strength of 980 MPa or more cannot be obtained, and a fractured surface roughness at a sheared end surface after shearing is not examined.
  • the present invention has been made in view of the above problems of the related art, and an object of the present invention is to provide a hot-rolled steel sheet having high strength and excellent shearing workability.
  • having excellent shearing workability indicates that a surface roughness Rz of a fractured surface at a sheared end surface after shearing is 30.0 ⁇ m or less.
  • having high strength indicates that a tensile strength is 980 MPa or more.
  • the present inventors obtained the following findings (a) to (d) as a result of intensive studies on a relationship between the chemical composition of the hot-rolled steel sheet and a microstructure, and mechanical properties, and completed the present invention.
  • the gist of the present invention made based on the above findings is as follows.
  • the hot-rolled steel sheet according to the above aspect of the present invention is suitable as an industrial material used for vehicle members, mechanical structural members, and building members.
  • FIG. 1 is a diagram showing a sheared end surface after shearing.
  • a hot-rolled steel sheet according to an embodiment of the present invention has a predetermined chemical composition, in which, when a region of 1 ⁇ 8 to 3 ⁇ 8 of a sheet thickness in a sheet thickness direction from a surface is defined as a 1 ⁇ 4 depth position, a microstructure at the 1 ⁇ 4 depth position includes, by area fraction, retained austenite: less than 3.0%, ferrite: less than 30.0%, and pearlite: less than 5.0%, at the 1 ⁇ 4 depth position, an average number density of Ti-based carbides having a longest diameter of 15 nm or more is 1 ⁇ 10 4 /mm 2 or more, and an average grain size dq is 15.0 ⁇ m or less, and a tensile strength is 980 MPa or more.
  • the present invention is not limited to configurations disclosed in the present embodiment, and various modifications can be made without departing from the gist of the present invention.
  • the numerical limit range described below with “to” includes the lower limit and the upper limit. Numerical values indicated as “less than” or “more than” do not fall within the numerical range.
  • C is an element that increases a fraction of a hard phase, and increase strength of ferrite by being bonded to a precipitation-hardening element such as Ti, Nb, or V.
  • a C content is less than 0.050%, it is difficult to obtain a desired strength. Therefore, the C content is set to 0.050% or more.
  • the C content is preferably 0.060% or more, more preferably 0.070% or more, and still more preferably 0.080% or more.
  • the C content is set to 0.200% or less.
  • the C content is preferably 0.150% or less.
  • Mn is an element having an action of suppressing ferritic transformation and achieving high-strengthening of the hot-rolled steel sheet.
  • a Mn content is set to 0.50% or more.
  • the Mn content is preferably 0.80% or more, and more preferably 1.00% or more.
  • the Mn content is still more preferably 1.40% or more, and even more preferably 1.50% or more.
  • the Mn content is set to 4.00% or less.
  • the Mn content is preferably 3.50% or less, and more preferably 3.00% or less.
  • P is an element that is generally contained as an impurity.
  • P is an element that is easily segregated, and when a P content is more than 0.100%, bending workability decreases due to boundary segregation. Therefore, the P content is set to 0.100% or less.
  • the P content is preferably 0.030% or less.
  • S is an element that is contained as an impurity and is an element that forms a sulfide-based inclusion in steel and decreases bending workability of the hot-rolled steel sheet.
  • the S content is set to 0.0100% or less.
  • the S content is preferably 0.0050% or less.
  • a lower limit of the S content does not need to be particularly specified, but the S content preferably set to 0.0001% or more from the viewpoint of the refining cost.
  • Al is an element having an action of deoxidizing steel and achieving soundness of steel.
  • a sol. Al content is set to 0.001% or more.
  • the sol. Al content is preferably 0.01% or more.
  • the sol. Al content is set to 1.00% or less.
  • the sol. Al content is preferably 0.80% or less, and more preferably 0.60% or less.
  • sol. Al means acid-soluble Al, and indicates Al present in the steel in a solid solution state.
  • Ti is an element that precipitates as coarse Ti-based carbides in a high temperature range of hot rolling and reduces the surface roughness of the fractured surface in the sheared end surface.
  • Ti is an element that suppresses recovery, recrystallization, and grain growth of an austenite structure and refines a microstructure after transformation.
  • Ti is an element that precipitates as fine Ti-based carbides during cooling after hot rolling (after completion of finish rolling) and improves the strength of steel by precipitation hardening.
  • the Ti content is set to 0.150% or more.
  • the Ti content is preferably 0.170% or more, more preferably 0.190% or more, and still more preferably 0.210% or more.
  • the Ti content is set to 0.400% or less.
  • the Ti content is preferably 0.350% or less, and more preferably 0.300% or less.
  • the Ti-based carbide refers to a carbide having a NaCl-type crystal structure containing Ti. As long as such a carbide contains Ti, a small amount of other carbide-generating alloy elements such as Mo. Nb, V, Cr, and W are also contained in the range of the chemical composition specified in the present embodiment. In addition, carbonitrides in which some of carbon atoms are replaced with nitrogen atoms are also contained.
  • N is an element having an action of forming nitrides or carbonitrides with Ti, Nb, V, or the like and suppressing the coarsening of austenite during heating of a slab, thereby refining the microstructure.
  • a N content is less than 0.0010%, it becomes difficult to exhibit the above action. Therefore, the N content is set to 0.0010% or more.
  • the N content is preferably 0.0015% or more.
  • the N content is set to 0.0200% or less.
  • the N content is preferably 0.0150% or less, more preferably 0.0100% or less, and still more preferably 0.0060% or less.
  • a remainder of the chemical composition of the hot-rolled steel sheet according to the present embodiment may be Fe and impurities.
  • the impurities mean substances that are incorporated from ore as a raw material, scrap, a manufacturing environment, or the like and/or substances that are permitted to an extent that the hot-rolled steel sheet according to the present embodiment is not adversely affected.
  • the hot-rolled steel sheet according to the present embodiment may contain one or two or more of Nb, V, Mo, Cu, Ni. Cr, W, B, Ca, Mg, REM, and Bi as optional elements instead of a portion of Fe. Since it is not essential to contain the above optional elements, a lower limit of the amounts thereof is 0%.
  • Nb, V, Mo, Cu, Ni. Cr, W, B, Ca, Mg, REM, and Bi as optional elements instead of a portion of Fe. Since it is not essential to contain the above optional elements, a lower limit of the amounts thereof is 0%.
  • the above optional elements will be described in detail.
  • Nb is an optional element.
  • Nb is an element that has effects of precipitating in steel as a carbide, a nitride, a carbonitride, or the like and increasing the tensile strength of the steel sheet.
  • a Nb content is preferably set to 0.001% or more.
  • the Nb content is more preferably 0.005% or more.
  • the Nb content is set to 0.200% or less.
  • the Nb content is preferably 0.170% or less, more preferably 0.140% or less, and still more preferably 0.110% or less.
  • V is an optional element.
  • V is an element that has effects of precipitating in steel as a carbide, a nitride, a carbonitride, or the like and improving the tensile strength of the steel sheet.
  • a V content is preferably set to 0.005% or more.
  • the V content is more preferably 0.010% or more.
  • Mo is an optional element.
  • Mo is an element that has effects of increasing hardenability of steel, forming a carbide or a carbonitride, and achieving high-strengthening of the steel sheet.
  • a Mo content is preferably set to 0.001% or more.
  • the Mo content is more preferably 0.005% or more.
  • the Mo content is set to 1.000% or less.
  • the Mo content is more preferably 0.800% or less, and still more preferably 0.600% or less.
  • Cu is an optional element.
  • Cu is an element having an effect of improving toughness of steel and an effect of increasing the tensile strength.
  • a Cu content is preferably set to 0.02% or more.
  • the Cu content is more preferably 0.08% or more.
  • the Cu content is set to 1.00% or less.
  • the Cu content is more preferably 0.50% or less, and still more preferably 0.30% or less.
  • Ni is an optional element. Ni has an effect of improving the toughness of steel and an effect of increasing the tensile strength. In order to obtain these effects, a Ni content is preferably set to 0.02% or more. The Ni content is more preferably 0.10% or more.
  • the Ni content is set to 1.00% or less.
  • the Ni content is more preferably 0.50% or less, and still more preferably 0.30% or less.
  • the Cr content is set to 2.00% or less.
  • the Cr content is more preferably 1.50% or less, still more preferably 1.00% or less, and particularly preferably 0.50% or less.
  • W is an optional element.
  • W is an element having an effect of forming a carbide or a carbonitride and increasing the tensile strength.
  • a W content is preferably set to 0.02% or more.
  • the W content is set to 1.00% or less.
  • the W content is preferably 0.80% or less.
  • B is an optional element.
  • B is an element that has an effect of increasing the tensile strength of the steel sheet by grain boundary strengthening and solid solution strengthening.
  • a B content is preferably set to 0.0001% or more.
  • the B content is more preferably 0.0002% or more.
  • the B content is set to 0.0040% or less.
  • the B content is more preferably 0.0030% or less, and still more preferably 0.0020% or less.
  • Ca is an optional element.
  • Ca is an element that has an effect of dispersing a number of fine oxides in molten steel to refine the microstructure of the steel sheet.
  • Ca is an element that has an effect of improving stretch flangeability of the steel sheet by fixing S in molten steel as spherical CaS and suppressing the generation of an elongated inclusion such as MnS.
  • a Ca content is preferably set to 0.0002% or more.
  • the Ca content is more preferably 0.0005% or more.
  • the Ca content is set to 0.0100% or less.
  • the Ca content is more preferably 0.0050% or less, and still more preferably 0.0030% or less.
  • Mg is an optional element. Similar to Ca, Mg is an element that has effects of suppressing the formation of coarse MnS by forming an oxide or a sulfide in molten steel and refining the microstructure of the steel sheet by dispersing a number of fine oxides. In order to obtain these effects, a Mg content is preferably set to 0.0002% or more. The Mg content is more preferably 0.0005% or more.
  • the Mg content is set to 0.0100% or less.
  • the Mg content is more preferably 0.0050% or less, and still more preferably 0.0030% or less.
  • REM is an optional element. Similar to Ca, REM is an element that also has effects of suppressing the formation of coarse MnS by forming an oxide or a sulfide in molten steel and refining the microstructure of the steel sheet by dispersing a number of fine oxides. In a case of obtaining these effects, a REM content is preferably set to 0.0002% or more. The REM content is more preferably 0.0005% or more.
  • the REM content is preferably set to 0.0100% or less.
  • the REM content is more preferably 0.0050% or less, and still more preferably 0.0030% or less.
  • REM rare earth metal
  • the REM content refers to the total amount of these elements.
  • Bi is an optional element.
  • B is an element that has an effect of improving formability of the steel sheet by refining a solidification structure.
  • a Bi content is preferably set to 0.0001% or more.
  • the Bi content is more preferably 0.0005% or more.
  • the Bi content is set to 0.0200% or less.
  • the Bi content is more preferably 0.0100% or less, and still more preferably 0.0070% or less.
  • the chemical composition of the above-described hot-rolled steel sheet may be measured by a general analytical method.
  • the chemical composition may be measured using inductively coupled plasma-atomic emission spectrometry (ICP-AES).
  • ICP-AES inductively coupled plasma-atomic emission spectrometry
  • sol. Al may be measured by ICP-AES using a filtrate obtained by heating and decomposing a sample with an acid.
  • C and S may be measured using a combustion-infrared absorption method, and N may be measured using an inert gas fusion-thermal conductivity method.
  • a microstructure at the 1 ⁇ 4 depth position includes, by area fraction, less than 30.0% of ferrite, less than 3.0% of retained austenite, and less than 5.0% of pearlite.
  • an average grain size is 15.0 ⁇ m or less
  • an average number density of Ti-based carbides having a longest diameter of 15 nm or more is 1.0 ⁇ 10 4 /mm 2 or more (10,000/mm 2 or more)
  • Ti-based carbide of 15 nm or more are precipitated in an average number density of 1.0 ⁇ 10 4 /mm 2 or more.
  • the reason for specifying the microstructure in the region of 1 ⁇ 8 to 3 ⁇ 8 (1 ⁇ 4 depth position) of the sheet thickness from the surface of the steel sheet is that the microstructure at this position represents a typical microstructure of the steel sheet.
  • Ferrite is a structure generated when fcc transforms into bcc at a relatively high temperature. Since ferrite has a high work hardening ability, when the area fraction of ferrite is too large, the amount of deformation of the fractured surface at the sheared end surface increases, and the fractured surface roughness increases. Therefore, the area fraction of ferrite is set to less than 30.0%.
  • the area fraction of ferrite is preferably 20.0% or less, more preferably 10.0% or less, and still more preferably 8.0% or less.
  • the area fraction of ferrite is preferably as small as possible and may be 0%, but the area fraction of ferrite may be set to 1.0% or more, 2.0% or more, or 3.0% or more in consideration of productivity and the like.
  • the area fraction of retained austenite when the area fraction of retained austenite is too large, there are cases where the surface roughness of the fractured surface at the sheared end surface increases. It is presumed that this is because retained austenite forms coarse voids.
  • the area fraction of retained austenite is set to less than 3.0%.
  • the area fraction of retained austenite is preferably less than 1.5% and more preferably less than 1.0%. Since retained austenite is preferably as small as possible, the area fraction of retained austenite may be 0%.
  • Pearlite is a lamellar microstructure in which cementite is precipitated in layers between ferrite grains.
  • pearlite is a soft microstructure compared to bainite and martensite.
  • the area fraction of pearlite is 5.0% or more, carbon is consumed by cementite contained in pearlite, and strengths of martensite, tempered martensite, and bainite, which are remaining structures, decrease, and a tensile strength of 980 MPa or more cannot be obtained. Therefore, the area fraction of pearlite is set to less than 5.0%.
  • the area fraction of pearlite may be preferably 3.0% or less, more preferably 2.0%, still more preferably 1.0% or less, or 0%.
  • the remaining structures other than retained austenite, ferrite, and pearlite preferably include one or two or more of bainite, martensite, and tempered martensite, which are hard structures.
  • An area fraction of one or two or more of bainite, martensite, and tempered martensite is preferably 70.0% or more, more preferably 80.0% or more, and still more preferably 90.0% or more.
  • the area fraction of each structure forming the microstructure is measured by the following method.
  • a sheet thickness cross section parallel to a rolling direction is mirror-finished and, furthermore, polished at room temperature with colloidal silica not containing an alkaline solution for 8 minutes, thereby removing strain introduced into a surface layer of a sample.
  • a region having a length of 50 ⁇ m from a depth of 1 ⁇ 8 of the sheet thickness from the surface to a depth of 3 ⁇ 8 of the sheet thickness from the surface is measured by electron backscatter diffraction at a measurement interval of 0.1 ⁇ m to obtain crystal orientation information.
  • an EBSD apparatus including a thermal field-emission scanning electron microscope (JSM-7001F manufactured by JEOL Ltd.) and an EBSD detector (DVC5 type detector manufactured by TSL solutions) is used.
  • a degree of vacuum in the EBSD apparatus is set to 9.6 ⁇ 10 ⁇ 5 Pa or less
  • an accelerating voltage is set to 15 kV
  • an irradiation current level is set to 13
  • an irradiation level of an electron beam is set to 62.
  • a reflected electron image is taken in the same visual field.
  • crystal grains where ferrite and cementite are precipitated in layers are specified from the reflected electron image, and the area fraction of the crystal grains is calculated, thereby obtaining the area fraction of pearlite.
  • regions having a grain average misorientation value of 1.0° or less are determined to be ferrite using a “Grain Average Misorientation” function installed in software “OIM Analysis (registered trademark)” included in an EBSD analyzer.
  • the area fraction of the regions determined to be ferrite is obtained, thereby obtaining the area fraction of ferrite.
  • a grain boundary of 5° or more is defined as a grain boundary in the remaining region (a region having a grain average misorientation value of more than 1.0°)
  • a maximum value of “Grain Average IQ” of a ferrite region is indicated as I ⁇
  • a region of more than I ⁇ /2 is extracted as bainite
  • a region of I ⁇ /2 or less is extracted as “pearlite, martensite, and tempered martensite”.
  • the area fraction of bainite is obtained by calculating the area fraction of the extracted bainite.
  • a sum of the area fractions of martensite and tempered martensite is obtained by calculating the area fractions of the extracted “pearlite, martensite, and tempered martensite” and subtracting the area fraction of pearlite obtained by the above EBSD analysis.
  • the area fraction of retained austenite As a measurement method of the area fraction of retained austenite, there are methods by X-ray diffraction, electron back scattering diffraction pattern (EBSD) analysis, and magnetic measurement, and the like and measured values may differ depending on the measurement method.
  • the area fraction of retained austenite is measured by X-ray diffraction.
  • the integrated intensities of a total of 6 peaks of ⁇ (110), ⁇ (200), ⁇ (211), ⁇ (111), ⁇ (200), and ⁇ (220) are obtained at a 1 ⁇ 4 depth position (a region from a depth of 1 ⁇ 8 of the sheet thickness from the surface to a depth of 3 ⁇ 8 of the sheet thickness from the surface) of the hot-rolled steel sheet using Co-K ⁇ rays, and the area fraction of retained austenite is obtained by calculation using an intensity averaging method.
  • the average number density of Ti-based carbides having a longest diameter of 15 nm or more needs to be 1.0 ⁇ 10 4 (10,000)/mm 2 or more.
  • the average number density of Ti-based carbides having a longest diameter of 15 nm or more is preferably 2.0 ⁇ 10 4 /mm 2 or more, and more preferably 4.0 ⁇ 10 4 /mm 2 or more.
  • the average number density of Ti-based carbides having a longest diameter of 15 nm or more is preferably as large as possible, but may be set to 5.0 ⁇ 10 6 /mm 2 or less because there are cases where a decrease in the amount of solute C required for strengthening of fine Ti-based carbides, bainite, and martensite precipitated during cooling after the completion of hot rolling is incurred, resulting in a decrease in strength.
  • the Ti-based carbide refers to a carbide having a NaCl-type crystal structure containing Ti. As long as the carbide contains Ti, a small amount of other carbide-generating alloy elements may be contained.
  • the Ti-based carbides may contain the other carbide-generating alloy elements such as Mo, Nb, V, Cr, and W. Furthermore, the Ti-based carbide may be a carbonitride in which some of carbon atoms are replaced with nitrogen atoms.
  • the average number density of the Ti-based carbides 20 visual fields at the 1 ⁇ 4 depth position are photographed at a magnification of 50,000-fold with transmission electron microscope (TEM) by setting a region of 2.0 ⁇ m ⁇ 2.0 ⁇ m region as one visual field, precipitates observed in the visual fields are analyzed by energy dispersive X-ray spectroscopy (EDS), precipitates in which Ti and C are detected are determined to be Ti-based carbides, and a longest diameter of each of the precipitates (Ti-based carbide) is measured. Then, the number of Ti-based carbides having a longest diameter of 15 nm or more per 1 mm 2 is examined to obtain the number density.
  • TEM transmission electron microscope
  • the average grain size (dq) at the 1 ⁇ 4 depth position is set to 15.0 ⁇ m or less.
  • the average grain size is preferably 12.0 ⁇ m or less, and more preferably 10.0 ⁇ m or less.
  • the average grain size is preferably as small as possible, and thus a lower limit thereof is not particularly limited. However, it is technically difficult to refine grains by normal hot rolling such that the average grain size becomes smaller than 1.0 ⁇ m. Therefore, the average grain size may be set to 1.0 ⁇ m or more or 4.0 ⁇ m or more.
  • inside bend cracking As the strength of the hot-rolled steel sheet increases, it is more likely that cracking occurs from the inside bend during bending (hereinafter, referred to as inside bend cracking). In particular, in a case where the tensile strength is 980 MPa or more as in the hot-rolled steel sheet according to the present embodiment, inside bend cracking is likely to occur.
  • the mechanism of the inside bend cracking is presumed as follows. That is, during bending, compressive stress is generated inside the bend. In the beginning, working proceeds while the entire inside of the bend is uniformly deformed; however, as the working amount increases, the deformation cannot proceed only with the uniform deformation, and deformation progresses with local concentration of strain (generation of a shear deformation band). As this shear deformation band further grows, cracks are initiated along the shear band from the surface of the inside of the bend and propagate.
  • the present inventors examined a method for suppressing inside bend cracking in a high strength steel sheet. As a result, the present inventors found that, as the grain size of the surface layer portion of the hot-rolled steel sheet becomes finer, local strain concentration is further suppressed, and it becomes more unlikely that inside bend cracking occurs.
  • ds/dq which is a ratio of an average grain size ds of the surface layer portion of the hot-rolled steel sheet to an average grain size dq at the 1 ⁇ 4 depth position, to 0.95 or less.
  • ds/dq is preferably set to 0.95 or less, ds/dq is more preferably 0.90 or less, and still more preferably 0.85 or less.
  • a lower limit of ds/dq is not particularly specified and may be set to 0.50 or more.
  • each of the surface layer portion of the hot-rolled steel sheet (a region from the surface to a position at a depth of 50 ⁇ m from the surface) and the 1 ⁇ 4 depth position (a region from a depth of 1 ⁇ 8 of the sheet thickness from the surface to a depth of 3 ⁇ 8 of the sheet thickness from surface) is analyzed and measured using EBSD in at least five visual fields at a magnification of 1.200-fold by setting a region of 40 ⁇ m ⁇ 30 ⁇ m as one visual field.
  • a region where an angle difference between adjacent measurement points is 15° or more and a circle equivalent diameter is 0.3 ⁇ m or more is defined as a grain boundary, and an area-averaged grain size is calculated.
  • the area-averaged grain sizes obtained at the individual measurement positions are regarded as the average grain size of the surface layer portion and the average grain size at the 1 ⁇ 4 depth position.
  • the hot-rolled steel sheet according to the present embodiment has a tensile (maximum) strength of 980 MPa or more.
  • tensile strength is less than 980 MPa, an applicable component is limited, and the contribution to a reduction in weight of a vehicle body is small.
  • the tensile strength is preferably 1,000 MPa or more, more preferably 1,080 MPa or more, and still more preferably 1,180 MPa or more.
  • An upper limit does not need to be particularly limited, but the tensile strength may be set to 1.780 MPa or less from the viewpoint of suppressing wearing of a die.
  • the tensile strength of the hot-rolled steel sheet is evaluated according to JIS Z 2241: 2011.
  • a No. 5 test piece of JIS Z 2241: 2011 is used as a test piece, and a test direction is set to a direction perpendicular to the rolling direction.
  • the sheet thickness of the hot-rolled steel sheet according to the present embodiment is not particularly limited and may be set to 1.2 to 10.0 mm.
  • the sheet thickness of the hot-rolled steel sheet according to the present embodiment may be set to 1.2 mm or more.
  • the sheet thickness is more preferably 1.4 mm or more.
  • the sheet thickness may be set to 10.0 mm or less.
  • the sheet thickness is more preferably 8.0 mm or less.
  • the sheet thickness is still more preferably 6.0 mm or less.
  • a manufacturing method of the hot-rolled steel sheet according to the present embodiment is not particularly limited, but the hot-rolled steel sheet can be obtained by a manufacturing method including the following steps.
  • Heating Temperature Higher than 1,300° C., and Equal to or Higher than SRT (° C.)
  • a heating temperature of the slab or the steel piece that is to be subjected to hot rolling is set to be higher than 1,300° C., and equal to or higher than a temperature SRT (° C.) represented by Expression (1).
  • a temperature SRT ° C.
  • heating to a temperature of higher than 1,300° C. is considered undesirable because a yield decreases due to a mass loss of iron caused by oxides in a heating furnace and surface defects are generated due to melting of scale.
  • the Ti-based carbides need to be sufficiently solutionized in the heating step.
  • the slab or the steel piece that is to be subjected to hot rolling is heated so as to have a temperature of higher than 1.300° C., and equal to or higher than SRT (° C.).
  • the expression “the temperature of the slab or the steel piece is higher than 1.300° C., and equal to or higher than SRT (° C.)” means that the temperature of the slab or the steel piece is higher than the higher of 1,300° C. or SRT (° C.), or, in a case where SRT (° C.) is higher than 1,300° C., SRT and the temperature of the slab or the steel piece are the same.
  • the heating temperature is higher than 1.400° C., there are cases where a thick scale is generated, resulting in a decrease in yield or significant damage to the heating furnace. Therefore, the heating temperature is preferably 1.400° C. or lower.
  • [element symbol] in Expression (1) indicates the amount of each element in the slab or the steel piece by mass %. In is a natural logarithm.
  • the slab or the steel piece to be heated may be a slab or a steel piece obtained by continuous casting or casting and blooming or may be also a slab or a steel piece obtained by additionally performing hot working or cold working on the above-described slab or steel piece.
  • a chemical composition of the slab or the steel piece does not substantially change in the manufacturing process and thus may be the same as the chemical composition of the desired hot-rolled steel sheet.
  • multi-pass hot rolling is performed on the heated slab or steel piece using a plurality of rolling stands to manufacture a hot-rolled steel sheet.
  • the multi-pass hot rolling can be performed using a reverse mill or a tandem mill, and, from the viewpoint of industrial productivity, a tandem mill is preferably used in at least several stands from the end.
  • a total rolling reduction of hot rolling in a temperature range of 1.100° C. or higher and SRT (° C.) or lower is increased to achieve refinement of recrystallized austenite and to precipitate coarse Ti-based carbides having a longest diameter of 15 nm or more within a short period of time in a limited time during rolling by strain-induced precipitation.
  • the total rolling reduction in this temperature range is small, it becomes difficult to obtain a fine structure or a desired Ti-based carbide.
  • the total rolling reduction in the above temperature range is less than 70%, a desired coarse Ti-based carbide cannot be obtained.
  • the total rolling reduction is preferably 75% or more, and more preferably 80% or more.
  • the total rolling reduction in the temperature range of 1.100° C. or higher and SRT (° C.) or lower is preferably as large as possible.
  • the manufacturing method of the hot-rolled steel sheet according to the present embodiment after the rolling reduction in a temperature range of 1,100° C. or higher is controlled as described above, a total rolling reduction in a temperature range of lower than 1.100° C., and FT (° C.) or higher is increased and cooling is further performed after the hot rolling under conditions described later, thereby refining the average grain size.
  • the total rolling reduction in the temperature range of lower than 1.100° C., and FT (C) or higher is less than 80%, the average grain size after transformation becomes coarse. Therefore, the total rolling reduction in the temperature range of lower than 1,100° C., and FT (° C.) or higher is set to 80% or more.
  • the total rolling reduction is preferably 85% or more, and more preferably 90% or more.
  • the total rolling reduction in the temperature range of lower than 1,100° C., and FT (° C.) or higher is preferably as high as possible, but may be set to 99% or less because an industrial limit is approximately 99%.
  • the total rolling reduction in each temperature range in the hot rolling step refers to a percentage of, with respect to an inlet sheet thickness before an initial pass in a predetermined temperature range, a total rolling reduction amount in this temperature range (a difference between the inlet sheet thickness before the initial pass of rolling in this temperature range and an outlet sheet thickness after a final pass of rolling in this temperature range).
  • FT is lower than Ar3 (C)
  • Ar3 ° C.
  • FT is set to 1,050° C. or lower.
  • FT is preferably 1.030° C. or lower, and more preferably 1,010° C. or lower.
  • the temperature during the hot rolling refers to a surface temperature of steel and can be measured using a radiation-type thermometer or the like.
  • Expression (2) indicates the amount of each element by mass %, and 0 is assigned in a case where the element is not contained.
  • accelerated cooling is performed to a temperature range of 600° C. or lower at an average cooling rate of 50° C./sec or faster in order to suppress the generation of ferrite and pearlite.
  • the average cooling rate referred herein is a value obtained by dividing a temperature drop width of the steel sheet from the start of accelerated cooling (when the steel sheet is introduced into a cooling facility) to the completion of accelerated cooling (when the steel sheet is taken out of the cooling facility) by the time required from the start of accelerated cooling to the completion of accelerated cooling.
  • An upper limit of the average cooling rate is not particularly specified, but an increase in the cooling rate causes an increase in size of the cooling facility and an increase in facility cost. Therefore, considering the facility cost, the average cooling rate is preferably 300° C./sec or slower.
  • cooling after the hot rolling it is more preferable to perform cooling by 50° C. or more within 1.0 second after the completion of the hot rolling (set a temperature drop allowance to 50° C. or more) in order to suppress the growth of austenite grains refined by the hot rolling.
  • cooling is performed at a fast average cooling rate immediately after the completion of the hot rolling.
  • the cooling water may be sprayed to the surface of the steel sheet.
  • a stay time in a temperature range of 600° C. to 750° C. which is a ferritic transformation temperature range, is preferably set to 5.0 seconds or shorter.
  • the stay time in the temperature range of 600° C. to 750° C. is more preferably 2.0 seconds or shorter.
  • a coiling temperature (which is substantially equal to a cooling stop temperature) is set to be in a temperature range of lower than 600° C. By setting the coiling temperature to be in this temperature range, a bainite or martensite structure can be obtained. In addition, by suppressing the grain growth after coiling, it is possible to obtain a fine structure with high strength, and as a result, excellent shearing workability can be obtained.
  • the structures and a precipitation state of carbides are controlled in steps up to the coiling step. Therefore, it is preferable not to perform a step that affects the structure or the state of the carbides after the coiling step.
  • a tensile strength TS, shearing workability, and inside bend cracking resistance were evaluated for the obtained hot-rolled steel sheets in the following manner.
  • the tensile strength of the hot-rolled steel sheet was evaluated according to JIS Z 2241: 2011.
  • a No. 5 test piece of JIS Z 2241: 2011 was used as a test piece, and a test direction was set to a direction perpendicular to the rolling direction.
  • the hot-rolled steel sheet was considered to have high strength and determined to be acceptable.
  • the hot-rolled steel sheet was considered to be poor in strength and determined to be unacceptable.
  • the shearing workability of the hot-rolled steel sheet was evaluated by obtaining a surface roughness Rz ( ⁇ m) of a fractured surface at an end surface after punching by a punching test.
  • Punched holes were prepared with a hole diameter of 10 mm, a punching speed of 3 m/s, a clearance of 20%. Next, the surface roughness Rz ( ⁇ m) of the fractured surface of the end surface was measured at a total of four points in a rolling direction and in a rolling orthogonal direction of the punched holes using a laser microscope, and evaluation was performed with the maximum value thereof.
  • the hot-rolled steel sheet was determined to be excellent in shearing workability.
  • the fractured surface is a punched end surface separated by a crack initiated from the vicinity of a cutting edge after the end of the shear deformation.
  • the inside bend cracking resistance was evaluated by the following bending test.
  • a 100 mm ⁇ 30 mm strip-shaped test piece was cut out from the hot-rolled steel sheet to obtain a bending test piece.
  • inside bend cracking resistance was investigated according to JIS Z 2248: 2014 (V block 90° bending test), and minimum bend radii at which cracks were not initiated were obtained.
  • a value obtained by dividing an average value of the minimum bend radii in the L axis and in the C axis by the sheet thickness was regarded as a limit bend R/t and used as an index value of inside bend cracking resistance.
  • R/t was 2.5 or less, the hot-rolled steel sheet was determined to be excellent in inside bend cracking resistance.
  • the hot-rolled steel sheets (Test Nos. 1 to 5 and 11 to 27) according to present invention examples are found to have excellent strength and shearing workability.
  • the hot-rolled steel sheets where ds/dq was 0.95 or less had the above properties and further had excellent inside bend cracking resistance.
  • the hot-rolled steel sheets according to comparative examples did not have any one or more of excellent strength and shearing workability.
  • Test No. 6 the heating temperature of the slab was low. Therefore, the Ti-based carbides were not sufficiently solutionized during heating, and the average number density of Ti-based carbides having a longest diameter of 15 nm or more decreased. As a result, the roughness of the fractured surface became rough (the shearing workability was low).
  • Test No. 7 as a comparative example, the total rolling reduction in the temperature range of 1,100° C. or higher and SRT (° C.) or lower was small. Therefore, the average number density of Ti-based carbides having a longest diameter of 15 nm or more decreased. As a result, the roughness of the fractured surface became rough.
  • Test No. 8 as a comparative example, the total rolling reduction in the temperature range of lower than 1,100° C., and FT (° C.) or higher was small. Therefore, the average grain size increased. As a result, the roughness of the fractured surface became rough.
  • Test No. 9 as a comparative example, after the completion of the hot rolling, the average cooling rate to 600° C. or lower was slow, and the stay time at 600° C. to 750° C. was long. Therefore, the area fraction of ferrite increased, and the average grain size increased. As a result, the tensile strength was low, and the roughness of the fractured surface became rough. In addition, ds/dq was high and the inside bend cracking resistance was also low.
  • Test No. 29 as a comparative example, the Si content was high. As a result, the area of retained austenite increased, and the roughness of the fractured surface became rough.
  • Test No. 30 as a comparative example, the Ti content was low. Therefore, the average number density of Ti-based carbides having a longest diameter of 15 nm or more decreased. As a result, the roughness of the fractured surface became rough.
  • the hot-rolled steel sheet according to the present invention is suitable as an industrial material used for vehicle members, mechanical structural members, and building members, and has high industrial applicability.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Heat Treatment Of Steel (AREA)
US18/578,652 2021-09-08 2022-09-08 Hot-rolled steel sheet Pending US20240301537A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2021146231 2021-09-08
JP2021-146231 2021-09-08
PCT/JP2022/033730 WO2023038084A1 (ja) 2021-09-08 2022-09-08 熱延鋼板

Publications (1)

Publication Number Publication Date
US20240301537A1 true US20240301537A1 (en) 2024-09-12

Family

ID=85506377

Family Applications (1)

Application Number Title Priority Date Filing Date
US18/578,652 Pending US20240301537A1 (en) 2021-09-08 2022-09-08 Hot-rolled steel sheet

Country Status (7)

Country Link
US (1) US20240301537A1 (https=)
EP (1) EP4400621A4 (https=)
JP (1) JP7678370B2 (https=)
KR (1) KR20240038998A (https=)
CN (1) CN117858971A (https=)
MX (1) MX2024002247A (https=)
WO (1) WO2023038084A1 (https=)

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3355970B2 (ja) 1996-12-10 2002-12-09 日本鋼管株式会社 打ち抜き性に優れる冷延鋼板の製造方法
JP4460343B2 (ja) 2004-04-13 2010-05-12 新日本製鐵株式会社 打ち抜き加工性に優れた高強度熱延鋼板及びその製造方法
US11332803B2 (en) 2017-04-21 2022-05-17 Nippon Steel Corporation High strength hot-dip galvanized steel sheet and production method therefor
CN110832098B (zh) * 2017-07-07 2021-11-23 日本制铁株式会社 热轧钢板及其制造方法
JP7277835B2 (ja) * 2019-12-19 2023-05-19 日本製鉄株式会社 鋼板及びめっき鋼板
JP7260824B2 (ja) * 2020-01-27 2023-04-19 日本製鉄株式会社 熱延鋼板
US12435382B2 (en) * 2020-01-27 2025-10-07 Nippon Steel Corporation Hot-rolled steel sheet
JP7660344B2 (ja) 2020-03-16 2025-04-11 ウシオ電機株式会社 ガス供給装置

Also Published As

Publication number Publication date
JP7678370B2 (ja) 2025-05-16
JPWO2023038084A1 (https=) 2023-03-16
KR20240038998A (ko) 2024-03-26
EP4400621A4 (en) 2025-06-11
EP4400621A1 (en) 2024-07-17
CN117858971A (zh) 2024-04-09
WO2023038084A1 (ja) 2023-03-16
MX2024002247A (es) 2024-03-05

Similar Documents

Publication Publication Date Title
US12297524B2 (en) Hot-rolled steel sheet
US12392020B2 (en) Hot-rolled steel sheet
US12534785B2 (en) Hot-rolled steel sheet
US12522884B2 (en) Hot-rolled steel sheet
US20250101553A1 (en) Hot-rolled steel sheet
US20240384378A1 (en) Hot-rolled steel sheet
US12435382B2 (en) Hot-rolled steel sheet
US12516406B2 (en) Hot-rolled steel sheet
US12606895B2 (en) Hot-rolled steel sheet
US20230257845A1 (en) Hot-rolled steel sheet
US12116646B2 (en) Hot-rolled steel sheet
US12203148B2 (en) Hot-rolled steel sheet
US20240318274A1 (en) Hot-rolled steel sheet
US20260022442A1 (en) Hot-rolled steel sheet
KR102941242B1 (ko) 열연 강판
US20240301537A1 (en) Hot-rolled steel sheet
US20260085393A1 (en) Hot-rolled steel sheet

Legal Events

Date Code Title Description
AS Assignment

Owner name: NIPPON STEEL CORPORATION, JAPAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:YOSHIDA, MITSURU;HIKIDA, KAZUO;REEL/FRAME:066111/0500

Effective date: 20240109

STPP Information on status: patent application and granting procedure in general

Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION COUNTED, NOT YET MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED