US20230002964A1 - Innovative leather and manufacturing method thereof - Google Patents

Innovative leather and manufacturing method thereof Download PDF

Info

Publication number
US20230002964A1
US20230002964A1 US17/845,926 US202217845926A US2023002964A1 US 20230002964 A1 US20230002964 A1 US 20230002964A1 US 202217845926 A US202217845926 A US 202217845926A US 2023002964 A1 US2023002964 A1 US 2023002964A1
Authority
US
United States
Prior art keywords
polyester
leather
particles
melt
thermoplastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
US17/845,926
Inventor
Chih-Yi Lin
Kuo-Kuang Cheng
Li-Yuan Chen
Yung-Yu Fu
En-Chih Chang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
San Fang Chemical Industry Co Ltd
Original Assignee
San Fang Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by San Fang Chemical Industry Co Ltd filed Critical San Fang Chemical Industry Co Ltd
Assigned to SAN FANG CHEMICAL INDUSTRY CO., LTD. reassignment SAN FANG CHEMICAL INDUSTRY CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CHANG, EN-CHIH, CHEN, LI-YUAN, CHENG, KUO-KUANG, FU, YUNG-YU, LIN, CHIH-YI
Publication of US20230002964A1 publication Critical patent/US20230002964A1/en
Pending legal-status Critical Current

Links

Images

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0011Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0009Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using knitted fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0036Polyester fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • D06N3/009Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin by spraying components on the web
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/121Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/121Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds
    • D06N3/123Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds with polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00Macromolecular materials of the coating layers
    • D06N2203/06Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/061Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00Condition, form or state of the materials
    • D06N2205/06Melt
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/28Artificial leather
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2213/00Others characteristics
    • D06N2213/02All layers being of the same kind of material, e.g. all layers being of polyolefins, all layers being of polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin

Definitions

  • the disclosure relates to an innovative artificial leather and a manufacturing method thereof.
  • an innovative leather includes a Polyester substrate, a Polyester adhering layer and a Polyester surface layer:
  • the Polyester adhering layer is disposed on the Polyester substrate.
  • the Polyester surface layer is disposed on the Polyester adhering layer.
  • a manufacturing method of an innovative leather includes: providing a Polyester substrate; melt-blowing a Polyester adhering layer onto the Polyester substrate; melt-blowing a Polyester surface layer onto the Polyester adhering layer; and thermally compressing and bonding the Polyester substrate, the Polyester adhering layer and the Polyester surface layer.
  • FIG. 1 is a schematic structural diagram showing an innovative leather according to an embodiment of the present disclosure.
  • FIG. 2 shows a flowchart of a manufacturing method of an innovative leather according to an embodiment of the present disclosure.
  • FIG. 1 is a schematic structural diagram showing an innovative leather according to an embodiment of the present disclosure.
  • the leather 10 of the present disclosure includes a Polyester substrate 11 , a Polyester adhering layer 12 and a Polyester surface layer 13 .
  • the Polyester substrate 11 has a first surface 111 and a second surface 112 .
  • the second surface 112 is opposite to the first surface 111 .
  • the Polyester substrate 11 is made of a PET (Polyethylene Terephthalate) material, which is an engineering plastic.
  • the Polyester substrate 11 may be a non-woven fabric formed by bonding 100% PET recycled cotton or a mixture of 60% PET recycled cotton and 40% PET cotton by needle punching; or a woven fabric formed by weaving 100% recycled PET fibers or common PET fibers. Therefore, the Polyester substrate 11 is completely made of the Polyester material.
  • the Polyester substrate 11 may be made of a TPEE (Thermoplastic Polyether Elastomer) material or a PBT (Polybutylene Terephthalate) material.
  • TPEE Thermoplastic Polyether Elastomer
  • PBT Polybutylene Terephthalate
  • the Polyester adhering layer 12 is disposed on the first surface 111 of the Polyester substrate 11 .
  • the Polyester adhering layer 12 may be made of a TPEE (Thermoplastic Polyether Elastomer) material, which is an engineering plastic having properties of an elastomer; or a PBT (Polybutylene Terephthalate) material, which is a thermoplastic engineering polymer.
  • the Polyester adhering layer 12 has a weight of 50-400 g/m 2 and a density of 0.2-0.8 g/cm 3 .
  • the Polyester adhering layer 12 is thermoplastic, in an embodiment, the Polyester adhering layer 12 may be made of a PET material.
  • the Polyester surface layer 13 is disposed on the Polyester adhering layer 12 .
  • the Polyester surface layer 13 may be made of a PET, TPEE or PBT material.
  • the Polyester surface layer 13 has a weight of 50-400 g/m 2 and a density of 0.5-0.9 g/cm 3 .
  • the Polyester surface layer 13 is thermoplastic.
  • the leather 10 of the present disclosure includes the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 .
  • the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 are made of a single Polyester material without other materials. Therefore, all materials of the leather 10 of the present disclosure are the same Polyester materials, thus the leather 10 of the present disclosure can be recycled and granulated after the leather of the present disclosure is used.
  • the leather of the present disclosure has environmental benefit.
  • thermoplastic Polyester recycled particles obtained after recycling and granulation may be added to the manufacturing process of the leather 10 of the present disclosure to further enhance the recycling benefit, thereby saving the manufacturing cost.
  • the leather 10 of the present disclosure is made of the single Polyester material which has higher glass transition temperature and melting point, when the leather 10 of the present disclosure is applied to a product, the product may have higher temperature resistance and thermal stability. Moreover, since the Polyester material has more excellent mechanical strength, when the leather 10 of the present disclosure is applied to a product, the mechanical strength of the product may be increased. For example, when the leather of the present disclosure is applied to a shoe material, the tensile strength and the tear strength may be increased, so the usability of the product may be enhanced. Furthermore, since the Polyester material has lower density, when the leather 10 of the present disclosure is applied to a product, the overall weight of the product may be decreased, which makes the product lighter and more suitable to wear for a long time.
  • thermoplastic Polyester recycled particles obtained after recycling and granulation may be added to the manufacturing process of the leather 10 of the present disclosure.
  • the Polyester surface layer 13 includes a thermoplastic Polyester material and a thermoplastic Polyester recycled material.
  • the thermoplastic Polyester material and the thermoplastic Polyester recycled material are mixed in a weight ratio of 75%:25% to 100%:0%.
  • FIG. 2 shows a flowchart of a manufacturing method of an innovative leather according to an embodiment of the present disclosure.
  • a Polyester substrate 11 is provided.
  • the Polyester substrate 11 has a first surface 111 and a second surface 112 .
  • the second surface 112 is opposite to the first surface 111 .
  • the Polyester substrate 11 is made of a PET (Polyethylene Terephthalates) material.
  • the Polyester substrate 11 may be a non-woven fabric formed by bonding 100% PET recycled cotton or a mixture of 60% PET recycled cotton and 40% PET cotton by needle punching; or a woven fabric formed by weaving 100% recycled PET fibers or common PET fibers. Therefore, the Polyester substrate 11 is completely made of the Polyester material.
  • a Polyester adhering layer 12 is melt-blown onto the first surface 111 of the Polyester substrate 11 .
  • the step of melt-blowing the Polyester adhering layer 12 further includes using first thermoplastic Polyester particles (not shown) having a melting point of 120-150° C.
  • the first thermoplastic Polyester particles may be PBT particles or TPEE particles.
  • a melt-blowing distance is 250-350 mm.
  • a Polyester surface layer 13 is melt-blown onto the Polyester adhering layer 12 .
  • the step of melt-blowing the Polyester surface layer 13 further includes using second thermoplastic Polyester particles (not shown) having a melting point of 130-170° C.
  • the second thermoplastic Polyester particles may be TPEE particles.
  • a melt-blowing distance is 150-250 mm.
  • the step of melt-blowing the Polyester surface layer further includes using thermoplastic Polyester recycled particles.
  • the second thermoplastic Polyester particles and the thermoplastic Polyester recycled particles are mixed in a weight ratio of 75%:25% to 100%:0%.
  • the thermoplastic Polyester recycled particles may be thermoplastic Polyester recycled particles obtained by recycling and granulating the leather of the present disclosure after use.
  • the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 are thermally compressing and bonding.
  • a temperature is 140° C.-160° C.
  • the Thermally compressing and bonding step since the temperature is higher than the melting point of the first thermoplastic Polyester particles, the Polyester adhering layer 12 may be melted and then bonded with the Polyester substrate 11 and the Polyester surface layer 13 .
  • the leather of the present disclosure may be subjected to surface thermoplastic processing, such as a thermoplastic embossing process, such that the leather of the present disclosure has different surface textures.
  • the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 are made of the single Polyester material, and thus prepared from the single raw material, so the process and material preparation of the manufacturing method of the leather of the present disclosure are simplified, which can enhance the manufacturing efficiency and lower the manufacturing cost.
  • the leather 10 of the present disclosure can be recycled and granulated after being used.
  • the leather of the present disclosure has environmental benefit.
  • thermoplastic Polyester recycled particles obtained after recycling and granulation may be added to the manufacturing process of the leather 10 of the present disclosure to further enhance the recycling benefit, thereby saving the manufacturing cost.
  • TPEE particles having a Shore hardness of 80 A and a melting point of 145° C., were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder.
  • the first extruder had a temperature of 170° C., 190° C., 210° C., 230° C. and 250° C. sequentially from a feed port to a discharge port, a die-head temperature of 250° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 275° C.
  • a spinneret pressure was controlled at 1.0-3.0 MPa.
  • a melt-blowing distance from the die to a mesh curtain was 300 mm.
  • the melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner.
  • a stacking density was 0.6-0.8 g/cm 3
  • a fiber fineness was 3-50 micrometers
  • a stacking weight was 200 g/m 2 .
  • TPEE particles having a Shore hardness of 80 A and a melting point of 160° C., were dried at a set drying temperature of 80° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a second extruder.
  • the second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C.
  • a spinneret pressure was controlled at 1.0-3.0 MPa.
  • a melt-blowing distance from the die to a mesh curtain was 250 mm.
  • the melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner.
  • a stacking density was 0.6-0.8 g/cm 3
  • a fiber fineness was 3-50 micrometers
  • a stacking weight was 250 g/m 2 .
  • the melt-blown and stacked three-layer structure (the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 ) was thermally compressed and bonded on a crawler belt.
  • a heating temperature of the crawler belt was set to 150° C., a pressure was 2-5 Kg, an operating speed was 3 m/min.
  • the composite structure was obtained.
  • thermoplastic embossing process such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
  • PBT particles having a melting point of 145° C.
  • the first extruder had a temperature of 170° C., 185° C., 205° C., 225° C. and 245° C. sequentially from a feed port to a discharge port, a die-head temperature of 255° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 280° C.
  • a spinneret pressure was controlled at 1.0-3.0 MPa.
  • a melt-blowing distance from the die to a mesh curtain was 300 mm.
  • the melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner.
  • a stacking density was 0.2-0.4 g/cm 3
  • a fiber fineness was 3-50 micrometers
  • a stacking weight was 150 g/m 2 .
  • TPEE particles having a Shore hardness of 80 A and a melting point of 165° C., were dried at a set drying temperature of 80° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a second extruder.
  • the second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C.
  • a spinneret pressure was controlled at 1.0-3.0 MPa.
  • a melt-blowing distance from the die to a mesh curtain was 200 mm.
  • the melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner.
  • a stacking density was 0.6-0.8 g/cm 3
  • a fiber fineness was 3-50 micrometers
  • a stacking weight was 200 g/m 2 .
  • the melt-blown and stacked three-layer structure (the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 ) was thermally compressed and bonded on a crawler belt.
  • a heating temperature of the crawler belt was set to 155° C., a pressure was 2-5 Kg, an operating speed was 3 m/min.
  • the composite structure was obtained.
  • thermoplastic embossing process such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
  • TPEE particles having a Shore hardness of 80 A and a melting point of 130° C., were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder.
  • the first extruder had a temperature of 170° C., 190° C., 210° C., 230° C. and 250° C. sequentially from a feed port to a discharge port, a die-head temperature of 250° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 275° C.
  • a spinneret pressure was controlled at 1.0-3.0 MPa.
  • a melt-blowing distance from the die to a mesh curtain was 300 mm.
  • the melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner.
  • a stacking density was 0.6-0.8 g/cm 3
  • a fiber fineness was 3-50 micrometers
  • a stacking weight was 150 g/m 2 .
  • TPEE particles having a Shore hardness of 80 A and a melting point of 150° C., were dried at a set drying temperature of 75° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a second extruder.
  • the second extruder had a temperature of 220° C., 210° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C.
  • a spinneret pressure was controlled at 1.0-3.0 MPa.
  • a melt-blowing distance from the die to a mesh curtain was 250 mm.
  • the melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner.
  • a stacking density was 0.6-0.8 g/cm 3
  • a fiber fineness was 3-50 micrometers
  • a stacking weight was 200 g/m 2 .
  • the melt-blown and stacked three-layer structure (the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 ) was thermally compressed and bonded on a crawler belt.
  • a heating temperature of the crawler belt was set to 140° C.
  • a pressure was 2-5 Kg, an operating speed was 3 m/min.
  • the composite structure was obtained.
  • thermoplastic embossing process such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
  • PBT particles having a melting point of 145° C.
  • the first extruder had a temperature of 170° C. 185° C., 205° C., 225° C. and 245° C. sequentially from a feed port to a discharge port, a die-head temperature of 255° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 280° C.
  • a spinneret pressure was controlled at 1.0-3.0 MPa.
  • a melt-blowing distance from the die to a mesh curtain was 300 mm.
  • the melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner.
  • a stacking density was 0.2-0.4 g/cm 3
  • a fiber fineness was 3-50 micrometers
  • a stacking weight was 150 g/m 2 .
  • TPEE particles having a Shore hardness of 80 A and a melting point of 155° C., were dried at a set drying temperature of 80° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a second extruder.
  • the second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C.
  • a spinneret pressure was controlled at 1.0-3.0 MPa.
  • a melt-blowing distance from the die to a mesh curtain was 250 mm.
  • the melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner.
  • a stacking density was 0.6-0.8 g/cm 3
  • a fiber fineness was 3-50 micrometers
  • a stacking weight was 200 g/m 2 .
  • the melt-blown and stacked three-layer structure (the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 ) was thermally compressed and bonded on a crawler belt.
  • a heating temperature of the crawler belt was set to 150° C., a pressure was 2-5 Kg, an operating speed was 3 m/min.
  • the composite structure was obtained.
  • thermoplastic embossing process such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
  • the whole leather product of this disclosure in the above embodiments 1-4 is crushed and then melted and granulated to form thermoplastic polyester recycled particles.
  • TPEE particles having a Shore hardness of 80 A and a melting point of 125° C., were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder.
  • the first extruder had a temperature of 170° C., 190° C., 210° C., 230° C. and 250° C. sequentially from a feed port to a discharge port, a die-head temperature of 250° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 275° C.
  • a spinneret pressure was controlled at 1.0-3.0 MPa.
  • a melt-blowing distance from the die to a mesh curtain was 300 mm.
  • the melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner.
  • a stacking density was 0.6-0.8 g/cm 3
  • a fiber fineness was 3-50 micrometers
  • a stacking weight was 200 g/m 2 .
  • thermoplastic polyester recycled particles having a Shore hardness of 80 A and a melting point of 140° C.
  • thermoplastic polyester recycled particles were mixed and were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below.
  • the thermoplastic polyester recycled particles are mixed into the TPEE particles, and the TPEE particles and the thermoplastic polyester recycled particles were mixed in a weight ratio of 85%:15%. Then, the mixed TPEE particles and the thermoplastic polyester recycled particles were molten by a second extruder.
  • the second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C.
  • melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner.
  • a stacking density was 0.6-0.8 g/cm 3
  • a fiber fineness was 3-50 micrometers
  • a stacking weight was 200 g/m 2 .
  • the melt-blown and stacked three-layer structure (the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 ) was thermally compressed and bonded on a crawler belt.
  • a heating temperature of the crawler belt was set to 130° C., a pressure was 2-5 Kg, an operating speed was 3 m/min.
  • the composite structure was obtained.
  • thermoplastic embossing process such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
  • the whole leather product of this disclosure in the above embodiments 1-4 is crushed and then melted and granulated to form thermoplastic polyester recycled particles.
  • TPEE particles having a Shore hardness of 80 A and a melting point of 130° C., were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder.
  • the first extruder had a temperature of 170° C., 190° C., 210° C., 230° C. and 250° C. sequentially from a feed port to a discharge port, a die-head temperature of 250° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 275° C.
  • a spinneret pressure was controlled at 1.0-3.0 MPa.
  • a melt-blowing distance from the die to a mesh curtain was 300 mm.
  • the melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner.
  • a stacking density was 0.6-0.8 g/cm 3
  • a fiber fineness was 3-50 micrometers
  • a stacking weight was 150 g/m 2 .
  • thermoplastic polyester recycled particles having a Shore hardness of 80 A and a melting point of 150° C.
  • thermoplastic polyester recycled particles were mixed and were dried at a set drying temperature of 75° C. for 4 hours until the measured water content was 200 ppm or below.
  • the thermoplastic polyester recycled particles were mixed into the TPEE particles, and the TPEE particles and the thermoplastic polyester recycled particles were mixed in a weight ratio of 75%:25%. Then, the mixed TPEE particles and the thermoplastic polyester recycled particles were molten by a second extruder.
  • the second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C.
  • melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner.
  • a stacking density was 0.6-0.8 g/cm 3
  • a fiber fineness was 3-50 micrometers
  • a stacking weight was 200 g/m 2 .
  • the melt-blown and stacked three-layer structure (the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 ) was thermally compressed and bonded on a crawler belt.
  • a heating temperature of the crawler belt was set to 140° C., a pressure was 2-5 Kg, an operating speed was 3 m/min.
  • the composite structure was obtained.
  • thermoplastic embossing process such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.

Abstract

The present disclosure relates to an innovative leather and a manufacturing method thereof. The innovative leather includes a Polyester substrate, a Polyester adhering layer, and a Polyester surface layer. The Polyester adhering layer is disposed on the Polyester substrate. The Polyester surface layer is disposed on the Polyester adhering layer. All materials of the innovative leather of the present disclosure are the same Polyester materials, thus the innovative leather of the present disclosure can be recycled after the innovative leather of the present disclosure is used. The innovative leather of the present disclosure has recycling benefit.

Description

    FIELD
  • The disclosure relates to an innovative artificial leather and a manufacturing method thereof.
  • BACKGROUND
  • Conventional methods for manufacturing an artificial leather generally use various complicated processes, and some of the processes require the use of a solvent, which is harmful to the environment and does not meet requirements for environmental friendliness. Moreover, the artificial leather manufactured by the conventional methods is made of different raw materials, so that the conventional artificial leather cannot be recycled after being used.
  • SUMMARY OF THE INVENTION
  • In accordance with one aspect of the present disclosure, an innovative leather includes a Polyester substrate, a Polyester adhering layer and a Polyester surface layer: The Polyester adhering layer is disposed on the Polyester substrate. The Polyester surface layer is disposed on the Polyester adhering layer.
  • In accordance with another aspect of the present disclosure, a manufacturing method of an innovative leather includes: providing a Polyester substrate; melt-blowing a Polyester adhering layer onto the Polyester substrate; melt-blowing a Polyester surface layer onto the Polyester adhering layer; and thermally compressing and bonding the Polyester substrate, the Polyester adhering layer and the Polyester surface layer.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • Aspects of the present disclosure are understood from the following detailed description when read with the accompanying figures. It is emphasized that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
  • FIG. 1 is a schematic structural diagram showing an innovative leather according to an embodiment of the present disclosure.
  • FIG. 2 shows a flowchart of a manufacturing method of an innovative leather according to an embodiment of the present disclosure.
  • DETAILED DESCRIPTION OF THE INVENTION
  • It is to be understood that the following disclosure provides many different embodiments or examples, for implementing different features of various embodiments. Specific examples of components and arrangements are described below to simplify the present disclosure. The present disclosure may, however, be embodied in many different forms and should not be construed as being limited to the embodiments set forth herein; rather, these embodiments are provided so that this description will be thorough and complete, and will fully convey the present disclosure to those of ordinary skill in the art. It will be apparent, however, that one or more embodiments may be practiced without these specific details.
  • In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
  • It will be understood that when an element is referred to as being “on” another element, it can be directly on the other element or intervening elements may be present. In contrast, when an element is referred to as being “directly on” another element, there are no intervening elements present.
  • It will be understood that singular forms “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise.
  • Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this disclosure belongs. It will be further understood that terms; such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and the present disclosure, and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
  • FIG. 1 is a schematic structural diagram showing an innovative leather according to an embodiment of the present disclosure. In an embodiment, the leather 10 of the present disclosure includes a Polyester substrate 11, a Polyester adhering layer 12 and a Polyester surface layer 13.
  • In an embodiment, the Polyester substrate 11 has a first surface 111 and a second surface 112. The second surface 112 is opposite to the first surface 111. The Polyester substrate 11 is made of a PET (Polyethylene Terephthalate) material, which is an engineering plastic. The Polyester substrate 11 may be a non-woven fabric formed by bonding 100% PET recycled cotton or a mixture of 60% PET recycled cotton and 40% PET cotton by needle punching; or a woven fabric formed by weaving 100% recycled PET fibers or common PET fibers. Therefore, the Polyester substrate 11 is completely made of the Polyester material. In an embodiment, the Polyester substrate 11 may be made of a TPEE (Thermoplastic Polyether Elastomer) material or a PBT (Polybutylene Terephthalate) material.
  • In an embodiment, the Polyester adhering layer 12 is disposed on the first surface 111 of the Polyester substrate 11. The Polyester adhering layer 12 may be made of a TPEE (Thermoplastic Polyether Elastomer) material, which is an engineering plastic having properties of an elastomer; or a PBT (Polybutylene Terephthalate) material, which is a thermoplastic engineering polymer. The Polyester adhering layer 12 has a weight of 50-400 g/m2 and a density of 0.2-0.8 g/cm3. The Polyester adhering layer 12 is thermoplastic, in an embodiment, the Polyester adhering layer 12 may be made of a PET material.
  • In an embodiment, the Polyester surface layer 13 is disposed on the Polyester adhering layer 12. The Polyester surface layer 13 may be made of a PET, TPEE or PBT material. The Polyester surface layer 13 has a weight of 50-400 g/m2 and a density of 0.5-0.9 g/cm3. The Polyester surface layer 13 is thermoplastic.
  • In an embodiment, the leather 10 of the present disclosure includes the Polyester substrate 11, the Polyester adhering layer 12 and the Polyester surface layer 13. The Polyester substrate 11, the Polyester adhering layer 12 and the Polyester surface layer 13 are made of a single Polyester material without other materials. Therefore, all materials of the leather 10 of the present disclosure are the same Polyester materials, thus the leather 10 of the present disclosure can be recycled and granulated after the leather of the present disclosure is used. The leather of the present disclosure has environmental benefit. Moreover, thermoplastic Polyester recycled particles obtained after recycling and granulation may be added to the manufacturing process of the leather 10 of the present disclosure to further enhance the recycling benefit, thereby saving the manufacturing cost.
  • In an embodiment, Since the leather 10 of the present disclosure is made of the single Polyester material which has higher glass transition temperature and melting point, when the leather 10 of the present disclosure is applied to a product, the product may have higher temperature resistance and thermal stability. Moreover, since the Polyester material has more excellent mechanical strength, when the leather 10 of the present disclosure is applied to a product, the mechanical strength of the product may be increased. For example, when the leather of the present disclosure is applied to a shoe material, the tensile strength and the tear strength may be increased, so the usability of the product may be enhanced. Furthermore, since the Polyester material has lower density, when the leather 10 of the present disclosure is applied to a product, the overall weight of the product may be decreased, which makes the product lighter and more suitable to wear for a long time.
  • In an embodiment, as described above, the thermoplastic Polyester recycled particles obtained after recycling and granulation may be added to the manufacturing process of the leather 10 of the present disclosure. The Polyester surface layer 13 includes a thermoplastic Polyester material and a thermoplastic Polyester recycled material. The thermoplastic Polyester material and the thermoplastic Polyester recycled material are mixed in a weight ratio of 75%:25% to 100%:0%.
  • FIG. 2 shows a flowchart of a manufacturing method of an innovative leather according to an embodiment of the present disclosure. With reference to FIG. 1 and FIG. 2 , referring to step S21 first, a Polyester substrate 11 is provided. The Polyester substrate 11 has a first surface 111 and a second surface 112. The second surface 112 is opposite to the first surface 111. In an embodiment, the Polyester substrate 11 is made of a PET (Polyethylene Terephthalates) material. The Polyester substrate 11 may be a non-woven fabric formed by bonding 100% PET recycled cotton or a mixture of 60% PET recycled cotton and 40% PET cotton by needle punching; or a woven fabric formed by weaving 100% recycled PET fibers or common PET fibers. Therefore, the Polyester substrate 11 is completely made of the Polyester material.
  • Referring to step S22, a Polyester adhering layer 12 is melt-blown onto the first surface 111 of the Polyester substrate 11. In an embodiment, the step of melt-blowing the Polyester adhering layer 12 further includes using first thermoplastic Polyester particles (not shown) having a melting point of 120-150° C. The first thermoplastic Polyester particles may be PBT particles or TPEE particles. In an embodiment, in the step of melt-blowing the Polyester adhering layer 12, a melt-blowing distance is 250-350 mm.
  • Referring to step S23, a Polyester surface layer 13 is melt-blown onto the Polyester adhering layer 12. In an embodiment, the step of melt-blowing the Polyester surface layer 13 further includes using second thermoplastic Polyester particles (not shown) having a melting point of 130-170° C. The second thermoplastic Polyester particles may be TPEE particles. In an embodiment, in the step of melt-blowing the Polyester surface layer 13, a melt-blowing distance is 150-250 mm.
  • In an embodiment, the step of melt-blowing the Polyester surface layer further includes using thermoplastic Polyester recycled particles. The second thermoplastic Polyester particles and the thermoplastic Polyester recycled particles are mixed in a weight ratio of 75%:25% to 100%:0%. The thermoplastic Polyester recycled particles may be thermoplastic Polyester recycled particles obtained by recycling and granulating the leather of the present disclosure after use.
  • Referring to step S24, the Polyester substrate 11, the Polyester adhering layer 12 and the Polyester surface layer 13 are thermally compressing and bonding. In an embodiment, in the thermally compressing and bonding step, a temperature is 140° C.-160° C. In the thermally compressing and bonding step, since the temperature is higher than the melting point of the first thermoplastic Polyester particles, the Polyester adhering layer 12 may be melted and then bonded with the Polyester substrate 11 and the Polyester surface layer 13.
  • In an embodiment, after the thermally compressing and bonding step, the leather of the present disclosure may be subjected to surface thermoplastic processing, such as a thermoplastic embossing process, such that the leather of the present disclosure has different surface textures.
  • Therefore, according to the manufacturing method of the leather of the present disclosure, the Polyester substrate 11, the Polyester adhering layer 12 and the Polyester surface layer 13 are made of the single Polyester material, and thus prepared from the single raw material, so the process and material preparation of the manufacturing method of the leather of the present disclosure are simplified, which can enhance the manufacturing efficiency and lower the manufacturing cost. In addition, the leather 10 of the present disclosure can be recycled and granulated after being used. The leather of the present disclosure has environmental benefit. Moreover, thermoplastic Polyester recycled particles obtained after recycling and granulation may be added to the manufacturing process of the leather 10 of the present disclosure to further enhance the recycling benefit, thereby saving the manufacturing cost.
  • Embodiment 1
  • 100% recycled PET cotton or a mixture of 60% recycled PET cotton and 40% common PET cotton was bonded into a non-woven fabric by needle punching as a Polyester substrate 11.
  • TPEE particles, having a Shore hardness of 80 A and a melting point of 145° C., were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder. The first extruder had a temperature of 170° C., 190° C., 210° C., 230° C. and 250° C. sequentially from a feed port to a discharge port, a die-head temperature of 250° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 275° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 300 mm. The melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 200 g/m2.
  • TPEE particles, having a Shore hardness of 80 A and a melting point of 160° C., were dried at a set drying temperature of 80° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a second extruder. The second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 250 mm. The melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 250 g/m2.
  • The melt-blown and stacked three-layer structure (the Polyester substrate 11, the Polyester adhering layer 12 and the Polyester surface layer 13) was thermally compressed and bonded on a crawler belt. A heating temperature of the crawler belt was set to 150° C., a pressure was 2-5 Kg, an operating speed was 3 m/min. The composite structure was obtained.
  • Then, surface textures were made by a thermoplastic embossing process, such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
  • Embodiment 2
  • 100% recycled PET cotton or a mixture of 60% recycled PET cotton and 40% common PET cotton was bonded into a non-woven fabric by needle punching as a Polyester substrate 11.
  • PBT particles, having a melting point of 145° C., were dried at a set drying temperature of 75° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder. The first extruder had a temperature of 170° C., 185° C., 205° C., 225° C. and 245° C. sequentially from a feed port to a discharge port, a die-head temperature of 255° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 280° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 300 mm. The melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner. A stacking density was 0.2-0.4 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 150 g/m2.
  • TPEE particles, having a Shore hardness of 80 A and a melting point of 165° C., were dried at a set drying temperature of 80° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a second extruder. The second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 200 mm. The melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 200 g/m2.
  • The melt-blown and stacked three-layer structure (the Polyester substrate 11, the Polyester adhering layer 12 and the Polyester surface layer 13) was thermally compressed and bonded on a crawler belt. A heating temperature of the crawler belt was set to 155° C., a pressure was 2-5 Kg, an operating speed was 3 m/min. The composite structure was obtained.
  • Then, surface textures were made by a thermoplastic embossing process, such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
  • Embodiment 3
  • 100% recycled PET fibers or common PET fibers were woven into a woven fabric as the Polyester substrate 11.
  • TPEE particles, having a Shore hardness of 80 A and a melting point of 130° C., were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder. The first extruder had a temperature of 170° C., 190° C., 210° C., 230° C. and 250° C. sequentially from a feed port to a discharge port, a die-head temperature of 250° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 275° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 300 mm. The melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 150 g/m2.
  • TPEE particles, having a Shore hardness of 80 A and a melting point of 150° C., were dried at a set drying temperature of 75° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a second extruder. The second extruder had a temperature of 220° C., 210° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 250 mm. The melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 200 g/m2.
  • The melt-blown and stacked three-layer structure (the Polyester substrate 11, the Polyester adhering layer 12 and the Polyester surface layer 13) was thermally compressed and bonded on a crawler belt. A heating temperature of the crawler belt was set to 140° C. a pressure was 2-5 Kg, an operating speed was 3 m/min. The composite structure was obtained.
  • Then, surface textures were made by a thermoplastic embossing process, such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
  • Embodiment 4
  • 100% recycled PET fibers or common PET fibers were woven into a woven fabric as the Polyester substrate 11.
  • PBT particles, having a melting point of 145° C., were dried at a set drying temperature of 75° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder. The first extruder had a temperature of 170° C. 185° C., 205° C., 225° C. and 245° C. sequentially from a feed port to a discharge port, a die-head temperature of 255° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 280° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 300 mm. The melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner. A stacking density was 0.2-0.4 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 150 g/m2.
  • TPEE particles, having a Shore hardness of 80 A and a melting point of 155° C., were dried at a set drying temperature of 80° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a second extruder. The second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 250 mm. The melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 200 g/m2.
  • The melt-blown and stacked three-layer structure (the Polyester substrate 11, the Polyester adhering layer 12 and the Polyester surface layer 13) was thermally compressed and bonded on a crawler belt. A heating temperature of the crawler belt was set to 150° C., a pressure was 2-5 Kg, an operating speed was 3 m/min. The composite structure was obtained.
  • Then, surface textures were made by a thermoplastic embossing process, such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
  • Embodiment 5
  • The whole leather product of this disclosure in the above embodiments 1-4 is crushed and then melted and granulated to form thermoplastic polyester recycled particles.
  • 100% recycled PET cotton or a mixture of 60% recycled PET cotton and 40% common PET cotton was bonded into a non-woven fabric by needle punching as a Polyester substrate 11.
  • TPEE particles, having a Shore hardness of 80 A and a melting point of 125° C., were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder. The first extruder had a temperature of 170° C., 190° C., 210° C., 230° C. and 250° C. sequentially from a feed port to a discharge port, a die-head temperature of 250° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 275° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 300 mm. The melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 200 g/m2.
  • TPEE particles, having a Shore hardness of 80 A and a melting point of 140° C., and the above thermoplastic polyester recycled. particles were mixed and were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. The thermoplastic polyester recycled particles are mixed into the TPEE particles, and the TPEE particles and the thermoplastic polyester recycled particles were mixed in a weight ratio of 85%:15%. Then, the mixed TPEE particles and the thermoplastic polyester recycled particles were molten by a second extruder. The second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 250 mm. The melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 200 g/m2.
  • The melt-blown and stacked three-layer structure (the Polyester substrate 11, the Polyester adhering layer 12 and the Polyester surface layer 13) was thermally compressed and bonded on a crawler belt. A heating temperature of the crawler belt was set to 130° C., a pressure was 2-5 Kg, an operating speed was 3 m/min. The composite structure was obtained.
  • Then, surface textures were made by a thermoplastic embossing process, such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
  • Embodiment 6
  • The whole leather product of this disclosure in the above embodiments 1-4 is crushed and then melted and granulated to form thermoplastic polyester recycled particles.
  • 100% recycled PET fibers or common PET fibers were woven into a woven fabric as the Polyester substrate 11.
  • TPEE particles, having a Shore hardness of 80 A and a melting point of 130° C., were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder. The first extruder had a temperature of 170° C., 190° C., 210° C., 230° C. and 250° C. sequentially from a feed port to a discharge port, a die-head temperature of 250° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 275° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 300 mm. The melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 150 g/m2.
  • TPEE particles, having a Shore hardness of 80 A and a melting point of 150° C., and the above thermoplastic polyester recycled particles were mixed and were dried at a set drying temperature of 75° C. for 4 hours until the measured water content was 200 ppm or below. The thermoplastic polyester recycled particles were mixed into the TPEE particles, and the TPEE particles and the thermoplastic polyester recycled particles were mixed in a weight ratio of 75%:25%. Then, the mixed TPEE particles and the thermoplastic polyester recycled particles were molten by a second extruder. The second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 150 mm. The melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 200 g/m2.
  • The melt-blown and stacked three-layer structure (the Polyester substrate 11, the Polyester adhering layer 12 and the Polyester surface layer 13) was thermally compressed and bonded on a crawler belt. A heating temperature of the crawler belt was set to 140° C., a pressure was 2-5 Kg, an operating speed was 3 m/min. The composite structure was obtained.
  • Then, surface textures were made by a thermoplastic embossing process, such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
  • Moreover, the scope of the present application is not intended to be limited to the particular embodiments of the process, machine, manufacture, and composition of matter, means, methods and steps described in the specification. As those skilled in the art will readily appreciate form the present disclosure, processes, machines, manufacture, compositions of matter, means, methods, or steps, presently existing or later to be developed, that perform substantially the same function or achieve substantially the same result as the corresponding embodiments described herein may be utilized in accordance with some embodiments of the present disclosure.
  • Accordingly, the appended claims are intended to include within their scope such processes, machines, manufacture, and compositions of matter, means, methods or steps. In addition, each claim constitutes a separate embodiment, and the combination of various claims and embodiments are within the scope of the disclosure.

Claims (16)

What is claimed is:
1. An innovative leather, comprising:
a Polyester substrate;
a Polyester adhering layer, disposed on the Polyester substrate; and
a Polyester surface layer, disposed on the Polyester adhering layer.
2. The innovative leather of claim 1, wherein the Polyester substrate is a PET (Polyethylene Terephthalate) material, a TPEE (Thermoplastic Polyether Elastomer) material or a PBT (Polybutylene Terephthalate) material.
3. The innovative leather of claim 1, wherein the Polyester adhering layer is a PET (Polyethylene Terephthalate) material, a TPEE (Thermoplastic Polyether Elastomer) material or a PBT (Polybutylene Terephthalate) material.
4. The innovative leather of claim 3, wherein the Polyester adhering layer has a weight of 50-400 g/m2 and a density of 0.2-0.8 g/cm3.
5. The innovative leather of claim 1, wherein the Polyester surface layer is a PET (Polyethylene Terephthalate) material, a TPEE (Thermoplastic Polyether Elastomer) material or a PBT (Polybutylene Terephthalate) material.
6. The innovative leather of claim 5, wherein the Polyester surface layer has a weight of 50-400 g/m2 and a density of 0.5-0.9 g/cm3.
7. The innovative leather of claim 1, wherein The Polyester surface layer comprises a thermoplastic Polyester material and a thermoplastic Polyester recycled material, the thermoplastic Polyester material and the thermoplastic Polyester recycled material are mixed in a weight ratio of 75%:25% to 100%:0%.
8. A manufacturing method of an innovative leather, comprising:
providing a Polyester substrate;
melt-blowing a Polyester adhering layer onto the Polyester substrate;
melt-blowing a Polyester surface layer onto the Polyester adhering layer; and
thermally compressing and bonding the Polyester substrate, the Polyester adhering layer and the Polyester surface layer.
8. The manufacturing method of claim 8, wherein the step of melt-blowing the Polyester adhering layer further comprises using first thermoplastic Polyester particles having a melting point of 120-150° C.
10. The manufacturing method of claim 9, wherein the first thermoplastic Polyester particles are PBT particles or TPEE particles.
11. The manufacturing method of claim 8, wherein the step of melt-blowing the Polyester surface layer further comprises using second thermoplastic Polyester particles having a melting point of 130-170° C.
12. The manufacturing method of claim 11, wherein the second thermoplastic Polyester particles are TPEE particles.
13. The manufacturing method of claim 11, wherein the step of melt-blowing the Polyester surface layer further comprises using thermoplastic Polyester recycled particles, the second thermoplastic Polyester particles and the thermoplastic Polyester recycled particles are mixed in a weight ratio of 75%:25% to 100%:0%.
14. The manufacturing method of claim 8, wherein in the thermally bonding step, a temperature is 140° C.-160° C.
15. The manufacturing method of claim 8, wherein in the step of melt-blowing the Polyester adhering layer, a melt-blowing distance is 250-350 mm.
16. The manufacturing method of claim 8, wherein in the step of melt-blowing the Polyester surface layer, a melt-blowing distance is 150-250 mm.
US17/845,926 2021-06-30 2022-06-21 Innovative leather and manufacturing method thereof Pending US20230002964A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TW110124178 2021-06-30
TW110124178A TW202302959A (en) 2021-06-30 2021-06-30 Innovative leather and manufacturing method thereof

Publications (1)

Publication Number Publication Date
US20230002964A1 true US20230002964A1 (en) 2023-01-05

Family

ID=84723007

Family Applications (1)

Application Number Title Priority Date Filing Date
US17/845,926 Pending US20230002964A1 (en) 2021-06-30 2022-06-21 Innovative leather and manufacturing method thereof

Country Status (3)

Country Link
US (1) US20230002964A1 (en)
CN (1) CN115538177A (en)
TW (1) TW202302959A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5993944A (en) * 1996-04-22 1999-11-30 Teijin Limited Non-impregnated type substrate useful as base fabric for artificial leather, artificial leather made therefrom, and process for their production
US20140079943A1 (en) * 2012-09-14 2014-03-20 San Fang Chemical Industry Co., Ltd. Artificial leather and method for making the same
US20150259484A1 (en) * 2012-09-27 2015-09-17 Toyobo Co., Ltd. Polyester film
US20170305126A1 (en) * 2015-01-15 2017-10-26 Kyowa Leather Cloth Co., Ltd. Skin material and method for producing skin material
KR20180045544A (en) * 2016-10-26 2018-05-04 주식회사 서연이화 Altificial leather for use as vehicle interior material and method for manufacturing same
US20180148891A1 (en) * 2015-08-10 2018-05-31 Jeongsan International Co., Ltd. Artificial leather using polyester and manufacturing method therefor
WO2021001070A1 (en) * 2019-07-02 2021-01-07 Kvadrat A/S Artificial leather product and process for producing same

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3086055B2 (en) * 1992-04-27 2000-09-11 帝人株式会社 Laminated biaxially oriented polyester film for magnetic recording media
JP4245284B2 (en) * 2001-05-17 2009-03-25 東洋鋼鈑株式会社 Decorative film material, decorative film, manufacturing method thereof, and decorative plate laminated with decorative film
US20090162610A1 (en) * 2007-12-20 2009-06-25 Jui-Hung Hwang Synthetic Leather and a Manufacturing Process thereof
TWI557291B (en) * 2015-03-18 2016-11-11 三芳化學工業股份有限公司 Thermoplastic artificial leather, manufacturing method thereof and thermoplastic complex laminate
EP3541617A4 (en) * 2016-11-15 2020-05-27 Shaw Industries Group, Inc. Layered composite articles and methods of making same
TWI746877B (en) * 2018-08-08 2021-11-21 三芳化學工業股份有限公司 Environmental-friendly artificial leather and manufacturing method thereof
TWI754091B (en) * 2018-08-08 2022-02-01 三芳化學工業股份有限公司 Artificial leather and manufacturing method thereof
KR20200093500A (en) * 2020-07-28 2020-08-05 이호영 Recyclable laminated fabric for synthetic leather or tarpaulin

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5993944A (en) * 1996-04-22 1999-11-30 Teijin Limited Non-impregnated type substrate useful as base fabric for artificial leather, artificial leather made therefrom, and process for their production
US20140079943A1 (en) * 2012-09-14 2014-03-20 San Fang Chemical Industry Co., Ltd. Artificial leather and method for making the same
US20150259484A1 (en) * 2012-09-27 2015-09-17 Toyobo Co., Ltd. Polyester film
US20170305126A1 (en) * 2015-01-15 2017-10-26 Kyowa Leather Cloth Co., Ltd. Skin material and method for producing skin material
US20180148891A1 (en) * 2015-08-10 2018-05-31 Jeongsan International Co., Ltd. Artificial leather using polyester and manufacturing method therefor
KR20180045544A (en) * 2016-10-26 2018-05-04 주식회사 서연이화 Altificial leather for use as vehicle interior material and method for manufacturing same
WO2021001070A1 (en) * 2019-07-02 2021-01-07 Kvadrat A/S Artificial leather product and process for producing same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"KR20180045544_Machine Translation" is a machine translation of KR-20180045544-A. (Year: 2018) *

Also Published As

Publication number Publication date
TW202302959A (en) 2023-01-16
CN115538177A (en) 2022-12-30

Similar Documents

Publication Publication Date Title
CN100577475C (en) Automobile interior board and method of producing the same
CN103119209B (en) The manufacture method of carbon fiber aggregate and the manufacture method of carbon fibre reinforced plastic
CN100564023C (en) A kind of kenaf-plastics composite sheet material and preparation method thereof
US3914501A (en) Porous products and processes therefor
KR20120123705A (en) Method for producing a flat semi-finished product from fiber composite material
CN113302355B (en) Layered composite material for imitation leather
TWI746877B (en) Environmental-friendly artificial leather and manufacturing method thereof
CA3014638C (en) Thermoplastic bonded preforms and thermoset matrices formed therewith
CN106671545B (en) A kind of high microsteping volume content polylactic acid list polymer composites and preparation method thereof
JP2004284246A (en) Fiber composite resin article and its production method
KR101028021B1 (en) Bio-degradable board comprising polylactic acid sheath containing sheath-core type fiber and natural fiber and its preparation method
EP3854935A1 (en) Artificial leather and manufacturing method thereof
CN111497414A (en) Manufacturing process of biodegradable luggage shell
US20230002964A1 (en) Innovative leather and manufacturing method thereof
KR102244590B1 (en) Artificial turf structure that improves the bonding force between pile yarn and bubble layer
US6539596B1 (en) Nonwovens from polytrimethylene terephthalate based staple fibers
KR102037496B1 (en) Improved Plasticity Spunbonded Nonwoven for Primary Carpet Backing, and Method for Manufacturing the Same
KR20160136981A (en) Scrim reinforced with natural fiber materals and manufacturing metho
EP3705614B1 (en) Fiber-containing structure and method for manufacturing the same
CN103612425A (en) Multilayer hemp/carbon fiber composite board with hamburger structure and manufacturing process of multilayer hemp/carbon fiber composite board
KR101479747B1 (en) The method for promoting abrasion-durability of surface of nano fiber membrane using paper coated with silicon
KR102306736B1 (en) Spunbonded nonwoven and tile carpet using the same
KR102027425B1 (en) manufacturing method of nonwoven for carpet backing with improved forming property
US20220205172A1 (en) Artificial leather and manufacturing method thereof
KR102289605B1 (en) Non woven fabric for shoes having excellent bursting strength and manafacturing method thereof

Legal Events

Date Code Title Description
AS Assignment

Owner name: SAN FANG CHEMICAL INDUSTRY CO., LTD., TAIWAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:LIN, CHIH-YI;CHENG, KUO-KUANG;CHEN, LI-YUAN;AND OTHERS;REEL/FRAME:060267/0843

Effective date: 20220608

STPP Information on status: patent application and granting procedure in general

Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER

STPP Information on status: patent application and granting procedure in general

Free format text: FINAL REJECTION MAILED