US20230002964A1 - Innovative leather and manufacturing method thereof - Google Patents
Innovative leather and manufacturing method thereof Download PDFInfo
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- US20230002964A1 US20230002964A1 US17/845,926 US202217845926A US2023002964A1 US 20230002964 A1 US20230002964 A1 US 20230002964A1 US 202217845926 A US202217845926 A US 202217845926A US 2023002964 A1 US2023002964 A1 US 2023002964A1
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- polyester
- leather
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- thermoplastic
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- 239000010985 leather Substances 0.000 title claims abstract description 44
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 28
- 229920000728 polyester Polymers 0.000 claims abstract description 196
- 239000010410 layer Substances 0.000 claims abstract description 58
- 239000000758 substrate Substances 0.000 claims abstract description 49
- 239000002344 surface layer Substances 0.000 claims abstract description 42
- 239000000463 material Substances 0.000 claims abstract description 39
- 239000002245 particle Substances 0.000 claims description 64
- 229920001169 thermoplastic Polymers 0.000 claims description 54
- 239000004416 thermosoftening plastic Substances 0.000 claims description 54
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 37
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 36
- 238000007664 blowing Methods 0.000 claims description 30
- 238000002844 melting Methods 0.000 claims description 18
- 230000008018 melting Effects 0.000 claims description 18
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 15
- -1 Polyethylene Terephthalate Polymers 0.000 claims description 10
- 229920001971 elastomer Polymers 0.000 claims description 6
- 239000000806 elastomer Substances 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- 238000004064 recycling Methods 0.000 abstract description 7
- 239000000835 fiber Substances 0.000 description 22
- 238000000034 method Methods 0.000 description 16
- 229920000742 Cotton Polymers 0.000 description 15
- 238000001035 drying Methods 0.000 description 12
- 238000009987 spinning Methods 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000004745 nonwoven fabric Substances 0.000 description 11
- 239000002649 leather substitute Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 8
- 238000004049 embossing Methods 0.000 description 7
- 239000002131 composite material Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 238000004080 punching Methods 0.000 description 5
- 239000002759 woven fabric Substances 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 229920006351 engineering plastic Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0009—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using knitted fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0036—Polyester fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
- D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
- D06N3/009—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin by spraying components on the web
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/121—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/121—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds
- D06N3/123—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds with polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2203/00—Macromolecular materials of the coating layers
- D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06N2203/061—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2205/00—Condition, form or state of the materials
- D06N2205/06—Melt
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2213/00—Others characteristics
- D06N2213/02—All layers being of the same kind of material, e.g. all layers being of polyolefins, all layers being of polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
Definitions
- the disclosure relates to an innovative artificial leather and a manufacturing method thereof.
- an innovative leather includes a Polyester substrate, a Polyester adhering layer and a Polyester surface layer:
- the Polyester adhering layer is disposed on the Polyester substrate.
- the Polyester surface layer is disposed on the Polyester adhering layer.
- a manufacturing method of an innovative leather includes: providing a Polyester substrate; melt-blowing a Polyester adhering layer onto the Polyester substrate; melt-blowing a Polyester surface layer onto the Polyester adhering layer; and thermally compressing and bonding the Polyester substrate, the Polyester adhering layer and the Polyester surface layer.
- FIG. 1 is a schematic structural diagram showing an innovative leather according to an embodiment of the present disclosure.
- FIG. 2 shows a flowchart of a manufacturing method of an innovative leather according to an embodiment of the present disclosure.
- FIG. 1 is a schematic structural diagram showing an innovative leather according to an embodiment of the present disclosure.
- the leather 10 of the present disclosure includes a Polyester substrate 11 , a Polyester adhering layer 12 and a Polyester surface layer 13 .
- the Polyester substrate 11 has a first surface 111 and a second surface 112 .
- the second surface 112 is opposite to the first surface 111 .
- the Polyester substrate 11 is made of a PET (Polyethylene Terephthalate) material, which is an engineering plastic.
- the Polyester substrate 11 may be a non-woven fabric formed by bonding 100% PET recycled cotton or a mixture of 60% PET recycled cotton and 40% PET cotton by needle punching; or a woven fabric formed by weaving 100% recycled PET fibers or common PET fibers. Therefore, the Polyester substrate 11 is completely made of the Polyester material.
- the Polyester substrate 11 may be made of a TPEE (Thermoplastic Polyether Elastomer) material or a PBT (Polybutylene Terephthalate) material.
- TPEE Thermoplastic Polyether Elastomer
- PBT Polybutylene Terephthalate
- the Polyester adhering layer 12 is disposed on the first surface 111 of the Polyester substrate 11 .
- the Polyester adhering layer 12 may be made of a TPEE (Thermoplastic Polyether Elastomer) material, which is an engineering plastic having properties of an elastomer; or a PBT (Polybutylene Terephthalate) material, which is a thermoplastic engineering polymer.
- the Polyester adhering layer 12 has a weight of 50-400 g/m 2 and a density of 0.2-0.8 g/cm 3 .
- the Polyester adhering layer 12 is thermoplastic, in an embodiment, the Polyester adhering layer 12 may be made of a PET material.
- the Polyester surface layer 13 is disposed on the Polyester adhering layer 12 .
- the Polyester surface layer 13 may be made of a PET, TPEE or PBT material.
- the Polyester surface layer 13 has a weight of 50-400 g/m 2 and a density of 0.5-0.9 g/cm 3 .
- the Polyester surface layer 13 is thermoplastic.
- the leather 10 of the present disclosure includes the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 .
- the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 are made of a single Polyester material without other materials. Therefore, all materials of the leather 10 of the present disclosure are the same Polyester materials, thus the leather 10 of the present disclosure can be recycled and granulated after the leather of the present disclosure is used.
- the leather of the present disclosure has environmental benefit.
- thermoplastic Polyester recycled particles obtained after recycling and granulation may be added to the manufacturing process of the leather 10 of the present disclosure to further enhance the recycling benefit, thereby saving the manufacturing cost.
- the leather 10 of the present disclosure is made of the single Polyester material which has higher glass transition temperature and melting point, when the leather 10 of the present disclosure is applied to a product, the product may have higher temperature resistance and thermal stability. Moreover, since the Polyester material has more excellent mechanical strength, when the leather 10 of the present disclosure is applied to a product, the mechanical strength of the product may be increased. For example, when the leather of the present disclosure is applied to a shoe material, the tensile strength and the tear strength may be increased, so the usability of the product may be enhanced. Furthermore, since the Polyester material has lower density, when the leather 10 of the present disclosure is applied to a product, the overall weight of the product may be decreased, which makes the product lighter and more suitable to wear for a long time.
- thermoplastic Polyester recycled particles obtained after recycling and granulation may be added to the manufacturing process of the leather 10 of the present disclosure.
- the Polyester surface layer 13 includes a thermoplastic Polyester material and a thermoplastic Polyester recycled material.
- the thermoplastic Polyester material and the thermoplastic Polyester recycled material are mixed in a weight ratio of 75%:25% to 100%:0%.
- FIG. 2 shows a flowchart of a manufacturing method of an innovative leather according to an embodiment of the present disclosure.
- a Polyester substrate 11 is provided.
- the Polyester substrate 11 has a first surface 111 and a second surface 112 .
- the second surface 112 is opposite to the first surface 111 .
- the Polyester substrate 11 is made of a PET (Polyethylene Terephthalates) material.
- the Polyester substrate 11 may be a non-woven fabric formed by bonding 100% PET recycled cotton or a mixture of 60% PET recycled cotton and 40% PET cotton by needle punching; or a woven fabric formed by weaving 100% recycled PET fibers or common PET fibers. Therefore, the Polyester substrate 11 is completely made of the Polyester material.
- a Polyester adhering layer 12 is melt-blown onto the first surface 111 of the Polyester substrate 11 .
- the step of melt-blowing the Polyester adhering layer 12 further includes using first thermoplastic Polyester particles (not shown) having a melting point of 120-150° C.
- the first thermoplastic Polyester particles may be PBT particles or TPEE particles.
- a melt-blowing distance is 250-350 mm.
- a Polyester surface layer 13 is melt-blown onto the Polyester adhering layer 12 .
- the step of melt-blowing the Polyester surface layer 13 further includes using second thermoplastic Polyester particles (not shown) having a melting point of 130-170° C.
- the second thermoplastic Polyester particles may be TPEE particles.
- a melt-blowing distance is 150-250 mm.
- the step of melt-blowing the Polyester surface layer further includes using thermoplastic Polyester recycled particles.
- the second thermoplastic Polyester particles and the thermoplastic Polyester recycled particles are mixed in a weight ratio of 75%:25% to 100%:0%.
- the thermoplastic Polyester recycled particles may be thermoplastic Polyester recycled particles obtained by recycling and granulating the leather of the present disclosure after use.
- the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 are thermally compressing and bonding.
- a temperature is 140° C.-160° C.
- the Thermally compressing and bonding step since the temperature is higher than the melting point of the first thermoplastic Polyester particles, the Polyester adhering layer 12 may be melted and then bonded with the Polyester substrate 11 and the Polyester surface layer 13 .
- the leather of the present disclosure may be subjected to surface thermoplastic processing, such as a thermoplastic embossing process, such that the leather of the present disclosure has different surface textures.
- the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 are made of the single Polyester material, and thus prepared from the single raw material, so the process and material preparation of the manufacturing method of the leather of the present disclosure are simplified, which can enhance the manufacturing efficiency and lower the manufacturing cost.
- the leather 10 of the present disclosure can be recycled and granulated after being used.
- the leather of the present disclosure has environmental benefit.
- thermoplastic Polyester recycled particles obtained after recycling and granulation may be added to the manufacturing process of the leather 10 of the present disclosure to further enhance the recycling benefit, thereby saving the manufacturing cost.
- TPEE particles having a Shore hardness of 80 A and a melting point of 145° C., were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder.
- the first extruder had a temperature of 170° C., 190° C., 210° C., 230° C. and 250° C. sequentially from a feed port to a discharge port, a die-head temperature of 250° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 275° C.
- a spinneret pressure was controlled at 1.0-3.0 MPa.
- a melt-blowing distance from the die to a mesh curtain was 300 mm.
- the melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner.
- a stacking density was 0.6-0.8 g/cm 3
- a fiber fineness was 3-50 micrometers
- a stacking weight was 200 g/m 2 .
- TPEE particles having a Shore hardness of 80 A and a melting point of 160° C., were dried at a set drying temperature of 80° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a second extruder.
- the second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C.
- a spinneret pressure was controlled at 1.0-3.0 MPa.
- a melt-blowing distance from the die to a mesh curtain was 250 mm.
- the melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner.
- a stacking density was 0.6-0.8 g/cm 3
- a fiber fineness was 3-50 micrometers
- a stacking weight was 250 g/m 2 .
- the melt-blown and stacked three-layer structure (the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 ) was thermally compressed and bonded on a crawler belt.
- a heating temperature of the crawler belt was set to 150° C., a pressure was 2-5 Kg, an operating speed was 3 m/min.
- the composite structure was obtained.
- thermoplastic embossing process such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
- PBT particles having a melting point of 145° C.
- the first extruder had a temperature of 170° C., 185° C., 205° C., 225° C. and 245° C. sequentially from a feed port to a discharge port, a die-head temperature of 255° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 280° C.
- a spinneret pressure was controlled at 1.0-3.0 MPa.
- a melt-blowing distance from the die to a mesh curtain was 300 mm.
- the melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner.
- a stacking density was 0.2-0.4 g/cm 3
- a fiber fineness was 3-50 micrometers
- a stacking weight was 150 g/m 2 .
- TPEE particles having a Shore hardness of 80 A and a melting point of 165° C., were dried at a set drying temperature of 80° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a second extruder.
- the second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C.
- a spinneret pressure was controlled at 1.0-3.0 MPa.
- a melt-blowing distance from the die to a mesh curtain was 200 mm.
- the melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner.
- a stacking density was 0.6-0.8 g/cm 3
- a fiber fineness was 3-50 micrometers
- a stacking weight was 200 g/m 2 .
- the melt-blown and stacked three-layer structure (the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 ) was thermally compressed and bonded on a crawler belt.
- a heating temperature of the crawler belt was set to 155° C., a pressure was 2-5 Kg, an operating speed was 3 m/min.
- the composite structure was obtained.
- thermoplastic embossing process such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
- TPEE particles having a Shore hardness of 80 A and a melting point of 130° C., were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder.
- the first extruder had a temperature of 170° C., 190° C., 210° C., 230° C. and 250° C. sequentially from a feed port to a discharge port, a die-head temperature of 250° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 275° C.
- a spinneret pressure was controlled at 1.0-3.0 MPa.
- a melt-blowing distance from the die to a mesh curtain was 300 mm.
- the melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner.
- a stacking density was 0.6-0.8 g/cm 3
- a fiber fineness was 3-50 micrometers
- a stacking weight was 150 g/m 2 .
- TPEE particles having a Shore hardness of 80 A and a melting point of 150° C., were dried at a set drying temperature of 75° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a second extruder.
- the second extruder had a temperature of 220° C., 210° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C.
- a spinneret pressure was controlled at 1.0-3.0 MPa.
- a melt-blowing distance from the die to a mesh curtain was 250 mm.
- the melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner.
- a stacking density was 0.6-0.8 g/cm 3
- a fiber fineness was 3-50 micrometers
- a stacking weight was 200 g/m 2 .
- the melt-blown and stacked three-layer structure (the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 ) was thermally compressed and bonded on a crawler belt.
- a heating temperature of the crawler belt was set to 140° C.
- a pressure was 2-5 Kg, an operating speed was 3 m/min.
- the composite structure was obtained.
- thermoplastic embossing process such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
- PBT particles having a melting point of 145° C.
- the first extruder had a temperature of 170° C. 185° C., 205° C., 225° C. and 245° C. sequentially from a feed port to a discharge port, a die-head temperature of 255° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 280° C.
- a spinneret pressure was controlled at 1.0-3.0 MPa.
- a melt-blowing distance from the die to a mesh curtain was 300 mm.
- the melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner.
- a stacking density was 0.2-0.4 g/cm 3
- a fiber fineness was 3-50 micrometers
- a stacking weight was 150 g/m 2 .
- TPEE particles having a Shore hardness of 80 A and a melting point of 155° C., were dried at a set drying temperature of 80° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a second extruder.
- the second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C.
- a spinneret pressure was controlled at 1.0-3.0 MPa.
- a melt-blowing distance from the die to a mesh curtain was 250 mm.
- the melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner.
- a stacking density was 0.6-0.8 g/cm 3
- a fiber fineness was 3-50 micrometers
- a stacking weight was 200 g/m 2 .
- the melt-blown and stacked three-layer structure (the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 ) was thermally compressed and bonded on a crawler belt.
- a heating temperature of the crawler belt was set to 150° C., a pressure was 2-5 Kg, an operating speed was 3 m/min.
- the composite structure was obtained.
- thermoplastic embossing process such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
- the whole leather product of this disclosure in the above embodiments 1-4 is crushed and then melted and granulated to form thermoplastic polyester recycled particles.
- TPEE particles having a Shore hardness of 80 A and a melting point of 125° C., were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder.
- the first extruder had a temperature of 170° C., 190° C., 210° C., 230° C. and 250° C. sequentially from a feed port to a discharge port, a die-head temperature of 250° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 275° C.
- a spinneret pressure was controlled at 1.0-3.0 MPa.
- a melt-blowing distance from the die to a mesh curtain was 300 mm.
- the melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner.
- a stacking density was 0.6-0.8 g/cm 3
- a fiber fineness was 3-50 micrometers
- a stacking weight was 200 g/m 2 .
- thermoplastic polyester recycled particles having a Shore hardness of 80 A and a melting point of 140° C.
- thermoplastic polyester recycled particles were mixed and were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below.
- the thermoplastic polyester recycled particles are mixed into the TPEE particles, and the TPEE particles and the thermoplastic polyester recycled particles were mixed in a weight ratio of 85%:15%. Then, the mixed TPEE particles and the thermoplastic polyester recycled particles were molten by a second extruder.
- the second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C.
- melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner.
- a stacking density was 0.6-0.8 g/cm 3
- a fiber fineness was 3-50 micrometers
- a stacking weight was 200 g/m 2 .
- the melt-blown and stacked three-layer structure (the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 ) was thermally compressed and bonded on a crawler belt.
- a heating temperature of the crawler belt was set to 130° C., a pressure was 2-5 Kg, an operating speed was 3 m/min.
- the composite structure was obtained.
- thermoplastic embossing process such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
- the whole leather product of this disclosure in the above embodiments 1-4 is crushed and then melted and granulated to form thermoplastic polyester recycled particles.
- TPEE particles having a Shore hardness of 80 A and a melting point of 130° C., were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder.
- the first extruder had a temperature of 170° C., 190° C., 210° C., 230° C. and 250° C. sequentially from a feed port to a discharge port, a die-head temperature of 250° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 275° C.
- a spinneret pressure was controlled at 1.0-3.0 MPa.
- a melt-blowing distance from the die to a mesh curtain was 300 mm.
- the melt-blown Polyester adhering layer 12 was stacked on the Polyester substrate 11 of the non-woven fabric in a fibrous manner.
- a stacking density was 0.6-0.8 g/cm 3
- a fiber fineness was 3-50 micrometers
- a stacking weight was 150 g/m 2 .
- thermoplastic polyester recycled particles having a Shore hardness of 80 A and a melting point of 150° C.
- thermoplastic polyester recycled particles were mixed and were dried at a set drying temperature of 75° C. for 4 hours until the measured water content was 200 ppm or below.
- the thermoplastic polyester recycled particles were mixed into the TPEE particles, and the TPEE particles and the thermoplastic polyester recycled particles were mixed in a weight ratio of 75%:25%. Then, the mixed TPEE particles and the thermoplastic polyester recycled particles were molten by a second extruder.
- the second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C.
- melt-blown Polyester surface layer 13 was stacked on the Polyester adhering layer 12 in a fibrous manner.
- a stacking density was 0.6-0.8 g/cm 3
- a fiber fineness was 3-50 micrometers
- a stacking weight was 200 g/m 2 .
- the melt-blown and stacked three-layer structure (the Polyester substrate 11 , the Polyester adhering layer 12 and the Polyester surface layer 13 ) was thermally compressed and bonded on a crawler belt.
- a heating temperature of the crawler belt was set to 140° C., a pressure was 2-5 Kg, an operating speed was 3 m/min.
- the composite structure was obtained.
- thermoplastic embossing process such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
Abstract
Description
- The disclosure relates to an innovative artificial leather and a manufacturing method thereof.
- Conventional methods for manufacturing an artificial leather generally use various complicated processes, and some of the processes require the use of a solvent, which is harmful to the environment and does not meet requirements for environmental friendliness. Moreover, the artificial leather manufactured by the conventional methods is made of different raw materials, so that the conventional artificial leather cannot be recycled after being used.
- In accordance with one aspect of the present disclosure, an innovative leather includes a Polyester substrate, a Polyester adhering layer and a Polyester surface layer: The Polyester adhering layer is disposed on the Polyester substrate. The Polyester surface layer is disposed on the Polyester adhering layer.
- In accordance with another aspect of the present disclosure, a manufacturing method of an innovative leather includes: providing a Polyester substrate; melt-blowing a Polyester adhering layer onto the Polyester substrate; melt-blowing a Polyester surface layer onto the Polyester adhering layer; and thermally compressing and bonding the Polyester substrate, the Polyester adhering layer and the Polyester surface layer.
- Aspects of the present disclosure are understood from the following detailed description when read with the accompanying figures. It is emphasized that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
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FIG. 1 is a schematic structural diagram showing an innovative leather according to an embodiment of the present disclosure. -
FIG. 2 shows a flowchart of a manufacturing method of an innovative leather according to an embodiment of the present disclosure. - It is to be understood that the following disclosure provides many different embodiments or examples, for implementing different features of various embodiments. Specific examples of components and arrangements are described below to simplify the present disclosure. The present disclosure may, however, be embodied in many different forms and should not be construed as being limited to the embodiments set forth herein; rather, these embodiments are provided so that this description will be thorough and complete, and will fully convey the present disclosure to those of ordinary skill in the art. It will be apparent, however, that one or more embodiments may be practiced without these specific details.
- In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
- It will be understood that when an element is referred to as being “on” another element, it can be directly on the other element or intervening elements may be present. In contrast, when an element is referred to as being “directly on” another element, there are no intervening elements present.
- It will be understood that singular forms “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise.
- Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this disclosure belongs. It will be further understood that terms; such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and the present disclosure, and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
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FIG. 1 is a schematic structural diagram showing an innovative leather according to an embodiment of the present disclosure. In an embodiment, theleather 10 of the present disclosure includes aPolyester substrate 11, aPolyester adhering layer 12 and aPolyester surface layer 13. - In an embodiment, the
Polyester substrate 11 has afirst surface 111 and asecond surface 112. Thesecond surface 112 is opposite to thefirst surface 111. ThePolyester substrate 11 is made of a PET (Polyethylene Terephthalate) material, which is an engineering plastic. ThePolyester substrate 11 may be a non-woven fabric formed by bonding 100% PET recycled cotton or a mixture of 60% PET recycled cotton and 40% PET cotton by needle punching; or a woven fabric formed by weaving 100% recycled PET fibers or common PET fibers. Therefore, thePolyester substrate 11 is completely made of the Polyester material. In an embodiment, thePolyester substrate 11 may be made of a TPEE (Thermoplastic Polyether Elastomer) material or a PBT (Polybutylene Terephthalate) material. - In an embodiment, the
Polyester adhering layer 12 is disposed on thefirst surface 111 of thePolyester substrate 11. ThePolyester adhering layer 12 may be made of a TPEE (Thermoplastic Polyether Elastomer) material, which is an engineering plastic having properties of an elastomer; or a PBT (Polybutylene Terephthalate) material, which is a thermoplastic engineering polymer. ThePolyester adhering layer 12 has a weight of 50-400 g/m2 and a density of 0.2-0.8 g/cm3. ThePolyester adhering layer 12 is thermoplastic, in an embodiment, thePolyester adhering layer 12 may be made of a PET material. - In an embodiment, the
Polyester surface layer 13 is disposed on thePolyester adhering layer 12. ThePolyester surface layer 13 may be made of a PET, TPEE or PBT material. ThePolyester surface layer 13 has a weight of 50-400 g/m2 and a density of 0.5-0.9 g/cm3. ThePolyester surface layer 13 is thermoplastic. - In an embodiment, the
leather 10 of the present disclosure includes thePolyester substrate 11, thePolyester adhering layer 12 and thePolyester surface layer 13. ThePolyester substrate 11, thePolyester adhering layer 12 and thePolyester surface layer 13 are made of a single Polyester material without other materials. Therefore, all materials of theleather 10 of the present disclosure are the same Polyester materials, thus theleather 10 of the present disclosure can be recycled and granulated after the leather of the present disclosure is used. The leather of the present disclosure has environmental benefit. Moreover, thermoplastic Polyester recycled particles obtained after recycling and granulation may be added to the manufacturing process of theleather 10 of the present disclosure to further enhance the recycling benefit, thereby saving the manufacturing cost. - In an embodiment, Since the
leather 10 of the present disclosure is made of the single Polyester material which has higher glass transition temperature and melting point, when theleather 10 of the present disclosure is applied to a product, the product may have higher temperature resistance and thermal stability. Moreover, since the Polyester material has more excellent mechanical strength, when theleather 10 of the present disclosure is applied to a product, the mechanical strength of the product may be increased. For example, when the leather of the present disclosure is applied to a shoe material, the tensile strength and the tear strength may be increased, so the usability of the product may be enhanced. Furthermore, since the Polyester material has lower density, when theleather 10 of the present disclosure is applied to a product, the overall weight of the product may be decreased, which makes the product lighter and more suitable to wear for a long time. - In an embodiment, as described above, the thermoplastic Polyester recycled particles obtained after recycling and granulation may be added to the manufacturing process of the
leather 10 of the present disclosure. ThePolyester surface layer 13 includes a thermoplastic Polyester material and a thermoplastic Polyester recycled material. The thermoplastic Polyester material and the thermoplastic Polyester recycled material are mixed in a weight ratio of 75%:25% to 100%:0%. -
FIG. 2 shows a flowchart of a manufacturing method of an innovative leather according to an embodiment of the present disclosure. With reference toFIG. 1 andFIG. 2 , referring to step S21 first, aPolyester substrate 11 is provided. ThePolyester substrate 11 has afirst surface 111 and asecond surface 112. Thesecond surface 112 is opposite to thefirst surface 111. In an embodiment, thePolyester substrate 11 is made of a PET (Polyethylene Terephthalates) material. ThePolyester substrate 11 may be a non-woven fabric formed by bonding 100% PET recycled cotton or a mixture of 60% PET recycled cotton and 40% PET cotton by needle punching; or a woven fabric formed by weaving 100% recycled PET fibers or common PET fibers. Therefore, thePolyester substrate 11 is completely made of the Polyester material. - Referring to step S22, a
Polyester adhering layer 12 is melt-blown onto thefirst surface 111 of thePolyester substrate 11. In an embodiment, the step of melt-blowing thePolyester adhering layer 12 further includes using first thermoplastic Polyester particles (not shown) having a melting point of 120-150° C. The first thermoplastic Polyester particles may be PBT particles or TPEE particles. In an embodiment, in the step of melt-blowing thePolyester adhering layer 12, a melt-blowing distance is 250-350 mm. - Referring to step S23, a
Polyester surface layer 13 is melt-blown onto thePolyester adhering layer 12. In an embodiment, the step of melt-blowing thePolyester surface layer 13 further includes using second thermoplastic Polyester particles (not shown) having a melting point of 130-170° C. The second thermoplastic Polyester particles may be TPEE particles. In an embodiment, in the step of melt-blowing thePolyester surface layer 13, a melt-blowing distance is 150-250 mm. - In an embodiment, the step of melt-blowing the Polyester surface layer further includes using thermoplastic Polyester recycled particles. The second thermoplastic Polyester particles and the thermoplastic Polyester recycled particles are mixed in a weight ratio of 75%:25% to 100%:0%. The thermoplastic Polyester recycled particles may be thermoplastic Polyester recycled particles obtained by recycling and granulating the leather of the present disclosure after use.
- Referring to step S24, the
Polyester substrate 11, thePolyester adhering layer 12 and thePolyester surface layer 13 are thermally compressing and bonding. In an embodiment, in the thermally compressing and bonding step, a temperature is 140° C.-160° C. In the thermally compressing and bonding step, since the temperature is higher than the melting point of the first thermoplastic Polyester particles, thePolyester adhering layer 12 may be melted and then bonded with thePolyester substrate 11 and thePolyester surface layer 13. - In an embodiment, after the thermally compressing and bonding step, the leather of the present disclosure may be subjected to surface thermoplastic processing, such as a thermoplastic embossing process, such that the leather of the present disclosure has different surface textures.
- Therefore, according to the manufacturing method of the leather of the present disclosure, the
Polyester substrate 11, thePolyester adhering layer 12 and thePolyester surface layer 13 are made of the single Polyester material, and thus prepared from the single raw material, so the process and material preparation of the manufacturing method of the leather of the present disclosure are simplified, which can enhance the manufacturing efficiency and lower the manufacturing cost. In addition, theleather 10 of the present disclosure can be recycled and granulated after being used. The leather of the present disclosure has environmental benefit. Moreover, thermoplastic Polyester recycled particles obtained after recycling and granulation may be added to the manufacturing process of theleather 10 of the present disclosure to further enhance the recycling benefit, thereby saving the manufacturing cost. - 100% recycled PET cotton or a mixture of 60% recycled PET cotton and 40% common PET cotton was bonded into a non-woven fabric by needle punching as a
Polyester substrate 11. - TPEE particles, having a Shore hardness of 80 A and a melting point of 145° C., were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder. The first extruder had a temperature of 170° C., 190° C., 210° C., 230° C. and 250° C. sequentially from a feed port to a discharge port, a die-head temperature of 250° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 275° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 300 mm. The melt-blown
Polyester adhering layer 12 was stacked on thePolyester substrate 11 of the non-woven fabric in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 200 g/m2. - TPEE particles, having a Shore hardness of 80 A and a melting point of 160° C., were dried at a set drying temperature of 80° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a second extruder. The second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 250 mm. The melt-blown
Polyester surface layer 13 was stacked on thePolyester adhering layer 12 in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 250 g/m2. - The melt-blown and stacked three-layer structure (the
Polyester substrate 11, thePolyester adhering layer 12 and the Polyester surface layer 13) was thermally compressed and bonded on a crawler belt. A heating temperature of the crawler belt was set to 150° C., a pressure was 2-5 Kg, an operating speed was 3 m/min. The composite structure was obtained. - Then, surface textures were made by a thermoplastic embossing process, such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
- 100% recycled PET cotton or a mixture of 60% recycled PET cotton and 40% common PET cotton was bonded into a non-woven fabric by needle punching as a
Polyester substrate 11. - PBT particles, having a melting point of 145° C., were dried at a set drying temperature of 75° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder. The first extruder had a temperature of 170° C., 185° C., 205° C., 225° C. and 245° C. sequentially from a feed port to a discharge port, a die-head temperature of 255° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 280° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 300 mm. The melt-blown
Polyester adhering layer 12 was stacked on thePolyester substrate 11 of the non-woven fabric in a fibrous manner. A stacking density was 0.2-0.4 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 150 g/m2. - TPEE particles, having a Shore hardness of 80 A and a melting point of 165° C., were dried at a set drying temperature of 80° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a second extruder. The second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 200 mm. The melt-blown
Polyester surface layer 13 was stacked on thePolyester adhering layer 12 in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 200 g/m2. - The melt-blown and stacked three-layer structure (the
Polyester substrate 11, thePolyester adhering layer 12 and the Polyester surface layer 13) was thermally compressed and bonded on a crawler belt. A heating temperature of the crawler belt was set to 155° C., a pressure was 2-5 Kg, an operating speed was 3 m/min. The composite structure was obtained. - Then, surface textures were made by a thermoplastic embossing process, such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
- 100% recycled PET fibers or common PET fibers were woven into a woven fabric as the
Polyester substrate 11. - TPEE particles, having a Shore hardness of 80 A and a melting point of 130° C., were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder. The first extruder had a temperature of 170° C., 190° C., 210° C., 230° C. and 250° C. sequentially from a feed port to a discharge port, a die-head temperature of 250° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 275° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 300 mm. The melt-blown
Polyester adhering layer 12 was stacked on thePolyester substrate 11 of the non-woven fabric in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 150 g/m2. - TPEE particles, having a Shore hardness of 80 A and a melting point of 150° C., were dried at a set drying temperature of 75° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a second extruder. The second extruder had a temperature of 220° C., 210° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 250 mm. The melt-blown
Polyester surface layer 13 was stacked on thePolyester adhering layer 12 in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 200 g/m2. - The melt-blown and stacked three-layer structure (the
Polyester substrate 11, thePolyester adhering layer 12 and the Polyester surface layer 13) was thermally compressed and bonded on a crawler belt. A heating temperature of the crawler belt was set to 140° C. a pressure was 2-5 Kg, an operating speed was 3 m/min. The composite structure was obtained. - Then, surface textures were made by a thermoplastic embossing process, such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
- 100% recycled PET fibers or common PET fibers were woven into a woven fabric as the
Polyester substrate 11. - PBT particles, having a melting point of 145° C., were dried at a set drying temperature of 75° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder. The first extruder had a temperature of 170° C. 185° C., 205° C., 225° C. and 245° C. sequentially from a feed port to a discharge port, a die-head temperature of 255° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 280° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 300 mm. The melt-blown
Polyester adhering layer 12 was stacked on thePolyester substrate 11 of the non-woven fabric in a fibrous manner. A stacking density was 0.2-0.4 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 150 g/m2. - TPEE particles, having a Shore hardness of 80 A and a melting point of 155° C., were dried at a set drying temperature of 80° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a second extruder. The second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 250 mm. The melt-blown
Polyester surface layer 13 was stacked on thePolyester adhering layer 12 in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 200 g/m2. - The melt-blown and stacked three-layer structure (the
Polyester substrate 11, thePolyester adhering layer 12 and the Polyester surface layer 13) was thermally compressed and bonded on a crawler belt. A heating temperature of the crawler belt was set to 150° C., a pressure was 2-5 Kg, an operating speed was 3 m/min. The composite structure was obtained. - Then, surface textures were made by a thermoplastic embossing process, such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
- The whole leather product of this disclosure in the above embodiments 1-4 is crushed and then melted and granulated to form thermoplastic polyester recycled particles.
- 100% recycled PET cotton or a mixture of 60% recycled PET cotton and 40% common PET cotton was bonded into a non-woven fabric by needle punching as a
Polyester substrate 11. - TPEE particles, having a Shore hardness of 80 A and a melting point of 125° C., were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder. The first extruder had a temperature of 170° C., 190° C., 210° C., 230° C. and 250° C. sequentially from a feed port to a discharge port, a die-head temperature of 250° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 275° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 300 mm. The melt-blown
Polyester adhering layer 12 was stacked on thePolyester substrate 11 of the non-woven fabric in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 200 g/m2. - TPEE particles, having a Shore hardness of 80 A and a melting point of 140° C., and the above thermoplastic polyester recycled. particles were mixed and were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. The thermoplastic polyester recycled particles are mixed into the TPEE particles, and the TPEE particles and the thermoplastic polyester recycled particles were mixed in a weight ratio of 85%:15%. Then, the mixed TPEE particles and the thermoplastic polyester recycled particles were molten by a second extruder. The second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 250 mm. The melt-blown
Polyester surface layer 13 was stacked on thePolyester adhering layer 12 in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 200 g/m2. - The melt-blown and stacked three-layer structure (the
Polyester substrate 11, thePolyester adhering layer 12 and the Polyester surface layer 13) was thermally compressed and bonded on a crawler belt. A heating temperature of the crawler belt was set to 130° C., a pressure was 2-5 Kg, an operating speed was 3 m/min. The composite structure was obtained. - Then, surface textures were made by a thermoplastic embossing process, such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
- The whole leather product of this disclosure in the above embodiments 1-4 is crushed and then melted and granulated to form thermoplastic polyester recycled particles.
- 100% recycled PET fibers or common PET fibers were woven into a woven fabric as the
Polyester substrate 11. - TPEE particles, having a Shore hardness of 80 A and a melting point of 130° C., were dried at a set drying temperature of 70° C. for 4 hours until the measured water content was 200 ppm or below. Then, the TPEE particles were molten by a first extruder. The first extruder had a temperature of 170° C., 190° C., 210° C., 230° C. and 250° C. sequentially from a feed port to a discharge port, a die-head temperature of 250° C., a die temperature of 255° C. and a spinning nozzle hot air temperature of 275° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 300 mm. The melt-blown
Polyester adhering layer 12 was stacked on thePolyester substrate 11 of the non-woven fabric in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 150 g/m2. - TPEE particles, having a Shore hardness of 80 A and a melting point of 150° C., and the above thermoplastic polyester recycled particles were mixed and were dried at a set drying temperature of 75° C. for 4 hours until the measured water content was 200 ppm or below. The thermoplastic polyester recycled particles were mixed into the TPEE particles, and the TPEE particles and the thermoplastic polyester recycled particles were mixed in a weight ratio of 75%:25%. Then, the mixed TPEE particles and the thermoplastic polyester recycled particles were molten by a second extruder. The second extruder had a temperature of 220° C., 240° C., 260° C., 280° C. and 290° C. sequentially from a feed port to a discharge port, a die-head temperature of 290° C., a die temperature of 300° C. and a spinning nozzle hot air temperature of 320° C. A spinneret pressure was controlled at 1.0-3.0 MPa. A melt-blowing distance from the die to a mesh curtain was 150 mm. The melt-blown
Polyester surface layer 13 was stacked on thePolyester adhering layer 12 in a fibrous manner. A stacking density was 0.6-0.8 g/cm3, a fiber fineness was 3-50 micrometers, and a stacking weight was 200 g/m2. - The melt-blown and stacked three-layer structure (the
Polyester substrate 11, thePolyester adhering layer 12 and the Polyester surface layer 13) was thermally compressed and bonded on a crawler belt. A heating temperature of the crawler belt was set to 140° C., a pressure was 2-5 Kg, an operating speed was 3 m/min. The composite structure was obtained. - Then, surface textures were made by a thermoplastic embossing process, such that a complete-Polyester recyclable environmentally-friendly synthetic leather could be obtained.
- Moreover, the scope of the present application is not intended to be limited to the particular embodiments of the process, machine, manufacture, and composition of matter, means, methods and steps described in the specification. As those skilled in the art will readily appreciate form the present disclosure, processes, machines, manufacture, compositions of matter, means, methods, or steps, presently existing or later to be developed, that perform substantially the same function or achieve substantially the same result as the corresponding embodiments described herein may be utilized in accordance with some embodiments of the present disclosure.
- Accordingly, the appended claims are intended to include within their scope such processes, machines, manufacture, and compositions of matter, means, methods or steps. In addition, each claim constitutes a separate embodiment, and the combination of various claims and embodiments are within the scope of the disclosure.
Claims (16)
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TWI754091B (en) * | 2018-08-08 | 2022-02-01 | 三芳化學工業股份有限公司 | Artificial leather and manufacturing method thereof |
KR20200093500A (en) * | 2020-07-28 | 2020-08-05 | 이호영 | Recyclable laminated fabric for synthetic leather or tarpaulin |
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- 2021-09-29 CN CN202111150238.9A patent/CN115538177A/en active Pending
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