CN100564023C - A kind of kenaf-plastics composite sheet material and preparation method thereof - Google Patents
A kind of kenaf-plastics composite sheet material and preparation method thereof Download PDFInfo
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- CN100564023C CN100564023C CNB2008100206121A CN200810020612A CN100564023C CN 100564023 C CN100564023 C CN 100564023C CN B2008100206121 A CNB2008100206121 A CN B2008100206121A CN 200810020612 A CN200810020612 A CN 200810020612A CN 100564023 C CN100564023 C CN 100564023C
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Abstract
What a kind of kenaf-plastics composite sheet material of the present invention and preparation method thereof related to is a kind of composite, environment-friendly material and preparation method thereof, be applicable to the shelf plate of making the field of traffic such as the vehicles such as automobile, aircraft, door inner panel etc., the decorative panel of building field, fence, railing etc., the pallet of packaging field, shelf etc.Kenaf-plastics composite sheet material is made of two-layer fibrilia modified plastic layer, flaxen fiber cloth reinforced plastic layer, and mold pressing has flaxen fiber cloth reinforced plastic layer between two-layer fibrilia modified plastic layer; Fibrilia modified plastic layer mixes calendering by modified plastics particle, flaxen fiber, interface bulking agent and forms; The flaxen fiber cloth mold pressing that flaxen fiber cloth reinforced plastic layer was handled by plastic pellet and several layers silane coupler forms.
Description
Technical field
What a kind of kenaf-plastics composite sheet material of the present invention and preparation method thereof related to is a kind of composite, environment-friendly material and preparation method thereof.Be applicable to the shelf plate of making the field of traffic such as the vehicles such as automobile, aircraft, door inner panel etc., the decorative panel of building field, fence, railing etc., the pallet of packaging field, shelf etc.
Background technology
In recent years, along with the enhancing of people's environmental protection consciousness, environmental friendliness, degradable, the recyclable demand of material of utilizing are more and more vigorous, and application is more and more wider.The fiberglass reinforced plastics composite (is commonly called as fiberglass, GRP) goods make it be able to extensive use because of light weight, specific strength advantages of higher, but exist simultaneously obviously not enough, as not degrading, recycle inconvenience, and glass fibre energy consumption is big etc. in process of production.So development of new fiber reinforced plastic composite material goods are very necessary.The natural plant fibre that comprises flaxen fiber, wood powder, agricultural crop straw has good degradability and environment friendly, is used to polymer compoundly more and more, and substitutes in many occasions and maybe can substitute GRP and use.In numerous natural fibers, flaxen fiber has higher mechanical property, thereby the potentiality of application are more arranged.But the same with other polymer matrix composite, in use there is aging phenomenon in kenaf-plastics composite, adds proper assistant and can improve its ageing properties, but tend to cause mechanical properties decrease.So, develop a kind of higher intensity that both had, the kenaf-plastics composite that has good anti ageing property again is very necessary.
Summary of the invention
The objective of the invention is provides a kind of kenaf-plastics composite sheet material and preparation method thereof at above-mentioned weak point, and this sheet material degradable, recovery, easy-formation are processed, have higher mechanical strength, anti-aging, can be repeated the processing use.
A kind of kenaf-plastics composite sheet material and preparation method thereof takes following scheme to realize:
A kind of kenaf-plastics composite sheet material is made of two-layer fibrilia modified plastic layer, flaxen fiber cloth reinforced plastic layer, and mold pressing has flaxen fiber cloth reinforced plastic layer between two-layer fibrilia modified plastic layer.
Fibrilia modified plastic layer mixes calendering by modified plastics particle, flaxen fiber, interface bulking agent and forms.The modified plastics particle is formed by modified nano-titanium dioxide, antioxidant, plastic pellet mixing extruding pelletization.Modified nano-titanium dioxide is mixed with silane coupler by nano titanium oxide, and vacuum drying is made.
The flaxen fiber cloth mold pressing that flaxen fiber cloth reinforced plastic layer was handled by plastic pellet and several layers silane coupler forms.
Described plastic pellet adopts a kind of in polyethylene, polypropylene, polystyrene, the polyvinyl chloride.
Described flaxen fiber adopts a kind of or its mixture in ramee, hemp, flax fiber, sisal fiber, the tossa.
Described flaxen fiber cloth adopts a kind of in ramee cloth, hemp cloth, flax fiber cloth, sisal fiber cloth, the tossa cloth.
Described interface bulking agent adopts a kind of in maleic anhydride inoculated polypropylene (MAPP), maleic anhydride grafted polyethylene, the maleic anhydride graft polystyrene;
Described antioxidant adopts a kind of among 1010 (A), the BHT.1010 (A) are four (β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester.BHT is 2, the 6-di-tert-butyl-4-methy phenol.
Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane.
A kind of kenaf-plastics composite preparation of plates method, its preparation process is:
(1) silane coupler and water are mixed by mass ratio 1: 1～5, wherein water is solvent.
(2) silane coupler with nano titanium oxide and dilution mixes by mass ratio 100: 2～6, and under 40 ℃～80 ℃ temperature, the modified nano-titanium dioxide particle is made in vacuum drying 3～6 hours;
(3) press flaxen fiber cloth and silane coupler mass ratio 100: 1～5, take by weighing silane coupler, the dilute with water silane coupler, water consumption is as the criterion with submergence flaxen fiber cloth; Flaxen fiber cloth is immersed in the silane coupler of dilute with water, soaks after 30～120 minutes, take out flaxen fiber cloth, drain, put into vacuum drying oven, under 40 ℃～80 ℃ temperature, vacuum drying 3～6 hours;
(4) plastic pellet and modified nano-titanium dioxide particle, antioxidant are pressed mass ratio 100: 1～5: 0.5～2.0, mechanical mixture is even, uses the extruder extruding pelletization, and the extruding pelletization temperature is 140 ℃～200 ℃, obtains the modified plastics particle;
(5) 100: 1～20: 10～30 mechanical mixture are even above-mentioned modified plastics particle and interface bulking agent, flaxen fiber to be pressed mass ratio, roll into fibrilia modified plastic layer through calender then; Fibrilia modified plastic layer is 0.5～2mm, and flaxen fiber length is 0.5～10mm;
(6) place a fibrilia modified plastic layer in the bottom of compression molding mold cavity, lay plastic pellet on fibrilia modified plastic layer, put on the plastic pellet upper berth and to state the flaxen fiber cloth of handling with silane coupler, lay plastic pellet on the above-mentioned flaxen fiber cloth of handling with silane coupler again, the flaxen fiber cloth mass ratio 100: 10～50 that plastic pellet and silane coupler were handled, the fibrilia modified plastic layer of lay one deck above plastic pellet more at last, matched moulds, preheating is after 5～10 minutes in 145 ℃～210 ℃ scopes, adopt the pressure compression molding of 5MPa～20MPa, make kenaf-plastics composite sheet material.
The described flaxen fiber cloth of handling with silane coupler can be provided with several layers, and all lay has plastic pellet between every two-layer flaxen fiber cloth of handling with silane coupler.
Kenaf-plastics composite sheet material of the present invention mold pressing between two-layer fibrilia modified plastic layer has flaxen fiber cloth reinforced plastic layer.The flaxen fiber cloth mold pressing that flaxen fiber cloth reinforced plastic layer was handled by plastic pellet and several layers silane coupler forms.
Kenaf-plastics composite sheet material of the present invention is reasonable in design, simple in structure, adopts the kenaf-plastics composite sheet material of preparation method's preparation of the present invention to compare with fiberglass (GRP): recyclable usefulness again, can degrade, and energy consumption is low, and environmental friendliness can repeat processing and use.No toxic and harmful produces in the kenaf-plastics composite sheet material preparation process, and raw material is non-stimulated to human body skin.Machine equipment cleaning used in the production process is very convenient; Product density can be lower, reduces cost of transportation, also do not resemble the skin that the dust that produces the fiberglass (GRP) stimulates the people in the product cutting processing, and with short production cycle, 1～2 people can finish production, and the production of GRP then needs more people, so the production efficiency height; Fiberglass (GRP) also need add curing agent when producing, if the amount improper use of curing agent may cause the product failure, quality is wayward, and kenaf-plastics composite sheet material this kind phenomenon can not occur.
Kenaf-plastics composite sheet material of the present invention is compared with traditional wood plastic composite, but ultraviolet resistance is aging, heat oxygen aging resistance, antibiotic, have mechanical strengths such as higher stretching, bending, impact, Young's modulus is higher, creep resistance is stronger.
Description of drawings
The invention will be further described below with reference to accompanying drawing.
Fig. 1 is a kind of kenaf-plastics composite plate construction schematic diagram.
The specific embodiment
With reference to accompanying drawing 1, a kind of kenaf-plastics composite sheet material is made of two-layer fibrilia modified plastic layer 1,3, flaxen fiber cloth plastic layer 2, and mold pressing has flaxen fiber cloth plastic layer 2 between fibrilia modified plastic layer 1 and fibrilia modified plastic layer 3.
Fibrilia modified plastic layer 1,3 mixes calendering by modified plastics particle 4, flaxen fiber 5, interface bulking agent and forms.Modified plastics particle 4 is formed by nano titanium oxide, silane coupler, antioxidant, plastic pellet mixing extruding pelletization.
Described plastic pellet adopts a kind of in polyethylene, polypropylene, polystyrene, the polyvinyl chloride.
Described flaxen fiber cloth adopts a kind of in ramee cloth, hemp cloth, sisal fiber cloth, flax fiber cloth, the tossa cloth.
Described flaxen fiber adopts a kind of or its mixture in ramee, hemp, sisal fiber, flax fiber, the tossa.
Described interface bulking agent adopts a kind of in maleic anhydride inoculated polypropylene (MAPP), maleic anhydride grafted polyethylene, the maleic anhydride graft polystyrene;
Described antioxidant adopts a kind of among 1010 (A), the BHT.1010 (A) are four (β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester.BHT is 2, the 6-di-tert-butyl-4-methy phenol.
Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane.
Embodiment 1: a kind of kenaf-plastics composite preparation of plates method, and its preparation process is:
(1) silane coupler and water were pressed mass ratio 1: 1, take by weighing silane coupler 1g, water 1g mixes, wherein water is solvent; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(2) silane coupler of nano titanium oxide and dilution was pressed mass ratio 100: 2, the silane coupler 0.002kg that takes by weighing nano titanium oxide 0.1kg and above-mentioned dilution mixes, under 40 ℃ of temperature, the modified nano-titanium dioxide particle is made in vacuum drying 6 hours; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(3) press flaxen fiber cloth and silane coupler mass ratio 100: 1, take by weighing silane coupler 0.01kg, the dilute with water silane coupler, water consumption is as the criterion with submergence flaxen fiber cloth; Flaxen fiber cloth 1kg is immersed in the silane coupler of dilute with water, soaks after 30 minutes, take out flaxen fiber cloth, drain, put into vacuum drying oven, under 40 ℃ of temperature, vacuum drying 3 hours; Described flaxen fiber cloth adopts ramee cloth;
(4) vinyon particle and modified nano-titanium dioxide particle, antioxidant were pressed mass ratio 100: 1: 0.5, take by weighing vinyon particle plastic pellet 10kg, modified nano-titanium dioxide particle 0.1kg, antioxidant 1010 (A) 0.05kg, mechanical mixture is even, use the extruder extruding pelletization, the extruding pelletization temperature is 140 ℃, obtains the modified poly ethylene plastic pellet;
(5) above-mentioned modified poly ethylene plastic pellet and interface bulking agent, flaxen fiber were pressed mass ratio 100: 1: 10, take by weighing modified poly ethylene plastic pellet 10kg, interface bulking agent maleic anhydride grafted polyethylene 0.1kg, flaxen fiber 1kg, put into container, mechanical mixture is even, rolls into fibrilia modified vinyon layer through calender then; Fibrilia modified vinyon layer thickness is 0.5～2mm, and flaxen fiber length is 0.5～10mm; Described flaxen fiber adopts ramee;
(6) place a fibrilia modified vinyon layer in the bottom of compression molding mold cavity, lay vinyon particle on fibrilia modified vinyon layer, put on vinyon particle upper berth and to state the flaxen fiber cloth of handling with silane coupler, lay vinyon particle on the above-mentioned flaxen fiber cloth of handling with silane coupler again, the fibrilia modified vinyon layer of lay one deck above the vinyon particle more at last, matched moulds, preheating is after 5 minutes under 145 ℃ of temperature, adopt the pressure compression molding of 5MPa, make kenaf-plastics composite sheet material; Wherein the flaxen fiber cloth mass ratio handled of vinyon particle and silane coupler is 100: 10, takes by weighing the flaxen fiber cloth 1kg that vinyon particle 10kg, silane coupler handled.
The mold pressing between two-layer fibrilia modified vinyon layer of this embodiment of the invention kenaf-plastics composite sheet material has flaxen fiber cloth reinforced plastic layer.The flaxen fiber cloth mold pressing that flaxen fiber cloth reinforced plastic layer was handled by vinyon particle and silane coupler forms.
Above-mentioned after testing kenaf-plastics composite sheet material hot strength 35MPa, stretch modulus 3.6GPa, bending strength 71.6MPa, bending modulus 1.9GPa, 90 ℃ were quickened thermo-oxidative ageing 600 hours, hot strength retention rate 56%.
Embodiment 2: a kind of kenaf-plastics composite preparation of plates method, and its preparation process is:
(1) silane coupler and water were pressed mass ratio 1: 5, take by weighing silane coupler 5g, water 25g mixes, wherein water is solvent; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(2) silane coupler of nano titanium oxide and dilution was pressed quality 100: 6, the silane coupler 0.03kg that takes by weighing nano titanium oxide 0.5kg and above-mentioned dilution mixes, and under 80 ℃ of temperature, the modified nano-titanium dioxide particle is made in vacuum drying 3 hours; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(3) press flaxen fiber cloth and silane coupler mass ratio 100: 5, take by weighing silane coupler 0.25kg, the dilute with water silane coupler, water consumption is as the criterion with submergence flaxen fiber cloth; Flaxen fiber cloth 5kg is immersed in the silane coupler of dilute with water, soaks after 120 minutes, take out flaxen fiber cloth, drain, put into vacuum drying oven, under 80 ℃ of temperature, vacuum drying 6 hours; Described flaxen fiber cloth adopts hemp cloth;
(4) polypropylene plastics particle and modified nano-titanium dioxide particle, antioxidant were pressed mass ratio 100: 5: 2, take by weighing polypropylene plastics particle plastic pellet 10kg, modified nano-titanium dioxide particle 0.5kg, antioxidant BHT 0.2kg, mechanical mixture is even, use the extruder extruding pelletization, the extruding pelletization temperature is 175 ℃, obtains the modified polypropylene plastic particle;
(5) above-mentioned modified polypropylene plastic particle and interface bulking agent, flaxen fiber were pressed mass ratio 100: 20: 30, take by weighing modified polypropylene plastic particle 10kg, interface bulking agent maleic anhydride inoculated polypropylene (MAPP) 2kg, flaxen fiber 3kg, put into container, mechanical mixture is even, rolls into the fibrilia modified polypropylene plastics bed of material through calender then; Fibrilia modified polypropylene plastics thickness of feed layer is 0.5～2mm, and flaxen fiber length is 0.5～10mm; Described flaxen fiber adopts hemp;
(6) place a fibrilia modified polypropylene plastics bed of material in the bottom of compression molding mold cavity, put the polypropylene plastics particle on fibrilia modified polypropylene plastics bed of material upper berth, put on polypropylene plastics particle upper berth and to state the flaxen fiber cloth of handling with silane coupler, lay polypropylene plastics particle on the above-mentioned flaxen fiber cloth of handling with silane coupler, on the polypropylene plastics particle, repave to put and state the flaxen fiber cloth of handling with silane coupler, lay polypropylene plastics particle on the flaxen fiber cloth of handling with silane coupler, on the polypropylene plastics particle, repave to put and state the flaxen fiber cloth of handling with silane coupler, on the flaxen fiber cloth of handling with silane coupler, repave and put the polypropylene plastics particle, the fibrilia modified polypropylene plastics bed of material of lay one deck above the polypropylene plastics particle more at last, matched moulds, preheating is after 10 minutes under 175 ℃ of temperature, adopt the pressure compression molding of 20MPa, make kenaf-plastics composite sheet material; Wherein the flaxen fiber cloth mass ratio handled of polypropylene plastics particle and silane coupler is 100: 50, takes by weighing the flaxen fiber cloth 5kg that polypropylene plastics particle 10kg, silane coupler handled.
The mold pressing between the two-layer fibrilia modified polypropylene plastics bed of material of this embodiment of the invention kenaf-plastics composite sheet material has flaxen fiber cloth reinforced plastic layer.The flaxen fiber cloth mold pressing that flaxen fiber cloth reinforced plastic layer was handled by polypropylene plastics particle and three layers of silane coupler forms.
Above-mentioned after testing kenaf-plastics composite sheet material hot strength 45MPa, stretch modulus 4.0GPa, bending strength 91.6MPa, bending modulus 2.1GPa, 90 ℃ were quickened thermo-oxidative ageing 600 hours, hot strength retention rate 61%.
Embodiment 3: a kind of kenaf-plastics composite preparation of plates method, and its preparation process is:
(1) silane coupler and water were pressed mass ratio 1: 1, take by weighing silane coupler 5g, water 5g mixes, wherein water is solvent; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(2) silane coupler of nano titanium oxide and dilution was pressed mass ratio 100: 2, the silane coupler 0.01kg that takes by weighing nano titanium oxide 0.5kg and above-mentioned dilution mixes, under 40 ℃ of temperature, the modified nano-titanium dioxide particle is made in vacuum drying 6 hours; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(3) press flaxen fiber cloth and silane coupler mass ratio 100: 1, take by weighing silane coupler 0.05kg, the dilute with water silane coupler, water consumption is as the criterion with submergence flaxen fiber cloth; Flaxen fiber cloth 5kg is immersed in the silane coupler of dilute with water, soaks after 30 minutes, take out flaxen fiber cloth, drain, put into vacuum drying oven, under 40 ℃ of temperature, vacuum drying 6 hours; Described flaxen fiber cloth adopts sisal fiber cloth;
(4) igelite particle and modified nano-titanium dioxide particle, antioxidant were pressed mass ratio 100: 5: 2, take by weighing igelite particle plastic pellet 10kg, modified nano-titanium dioxide particle 0.5kg, antioxidant BHT 0.2kg, mechanical mixture is even, use the extruder extruding pelletization, the extruding pelletization temperature is 180 ℃, obtains the modified polyvinyl chloride plastic pellet;
(5) above-mentioned modified polyvinyl chloride plastic pellet and interface bulking agent, flaxen fiber were pressed mass ratio 100: 1: 10, take by weighing modified polyvinyl chloride plastic pellet 10kg, interface bulking agent maleic anhydride inoculated polypropylene 0.1kg, flaxen fiber 1kg, put into container, mechanical mixture is even, rolls into the fibrilia modified polyvinyl chloride plastic bed of material through calender then; Fibrilia modified polyvinyl chloride plastic thickness of feed layer is 0.5～2mm, and flaxen fiber length is 0.5～10mm; Described flaxen fiber adopts sisal fiber;
(6) place a fibrilia modified polyvinyl chloride plastic bed of material in the bottom of compression molding mold cavity, put the igelite particle on fibrilia modified polyvinyl chloride plastic bed of material upper berth, put on igelite particle upper berth and to state the flaxen fiber cloth of handling with silane coupler, lay igelite particle on the above-mentioned flaxen fiber cloth of handling with silane coupler again, the flaxen fiber cloth mass ratio that igelite particle and silane coupler were handled 100: 10, the fibrilia modified polyvinyl chloride plastic bed of material of lay one deck above plastic pellet more at last, matched moulds, preheating is after 5 minutes in 185 ℃ of scopes, adopt the pressure compression molding of 5MPa, make kenaf-plastics composite sheet material.Wherein the flaxen fiber cloth mass ratio handled of vinyon particle and silane coupler is 100: 10, takes by weighing the flaxen fiber cloth 5kg that vinyon particle 50kg, silane coupler handled.
The mold pressing between the two-layer fibrilia modified polyvinyl chloride plastic bed of material of this embodiment of the invention kenaf-plastics composite sheet material has flaxen fiber cloth reinforced plastic layer.The flaxen fiber cloth mold pressing that flaxen fiber cloth reinforced plastic layer was handled by igelite particle and silane coupler forms.
Above-mentioned after testing kenaf-plastics composite sheet material hot strength 33.9MPa, stretch modulus 3.4GPa, bending strength 66.6MPa, bending modulus 1.9GPa, 90 ℃ were quickened thermo-oxidative ageing 600 hours, hot strength retention rate 55%.
Embodiment 4: a kind of kenaf-plastics composite preparation of plates method, and its preparation process is:
(1) silane coupler and water were pressed mass ratio 1: 3, take by weighing silane coupler 3g, water 9g mixes, wherein water is solvent; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(2) silane coupler of nano titanium oxide and dilution was pressed mass ratio 100: 4, the silane coupler 0.012kg that takes by weighing nano titanium oxide 0.3kg and above-mentioned dilution mixes, under 60 ℃ of temperature, the modified nano-titanium dioxide particle is made in vacuum drying 4.5 hours; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(3) press flaxen fiber cloth and silane coupler mass ratio 100: 3, take by weighing silane coupler 0.09kg, the dilute with water silane coupler, water consumption is as the criterion with submergence flaxen fiber cloth; Flaxen fiber cloth 3kg is immersed in the silane coupler of dilute with water, soaks after 80 minutes, take out flaxen fiber cloth, drain, put into vacuum drying oven, under 60 ℃ of temperature, vacuum drying 4.5 hours; Described flaxen fiber cloth adopts flax fiber cloth;
(4) polystyrene plastics particle and modified nano-titanium dioxide particle, antioxidant were pressed mass ratio 100: 3: 1.3, take by weighing vinyon particle plastic pellet 10kg, modified nano-titanium dioxide particle 0.3kg, antioxidant 1010 (A) 0.13kg, mechanical mixture is even, use the extruder extruding pelletization, the extruding pelletization temperature is 200 ℃, obtains the modified polystyrene plastic particle;
(5) above-mentioned modified polystyrene plastic particle and interface bulking agent, flaxen fiber were pressed mass ratio 100: 10: 20, take by weighing modified polystyrene plastic particle 10kg, interface bulking agent maleic anhydride graft polystyrene 1kg, flaxen fiber 2kg, put into container, mechanical mixture is even, rolls into fibrilia modified polystyrene plastics layer through calender then; Fibrilia modified polystyrene plastics layer thickness is 0.5～2mm, and flaxen fiber length is 0.5～10mm; Described flaxen fiber adopts flax fiber;
(6) place a fibrilia modified polystyrene plastics layer in the bottom of compression molding mold cavity, lay polystyrene plastics particle on fibrilia modified polystyrene plastics layer, put on polystyrene plastics particle upper berth and to state the flaxen fiber cloth of handling with silane coupler, lay polystyrene plastics particle on the above-mentioned flaxen fiber cloth of handling with silane coupler, on the polystyrene plastics particle, repave to put and state the flaxen fiber cloth of handling with silane coupler, lay polystyrene plastics particle on the flaxen fiber cloth of handling with silane coupler, the fibrilia modified polystyrene plastics layer of lay one deck above the polystyrene plastics particle more at last, matched moulds, preheating is after 8 minutes under 210 ℃ of temperature, adopt the pressure compression molding of 20MPa, make kenaf-plastics composite sheet material; Wherein the flaxen fiber cloth mass ratio handled of polystyrene plastics particle and silane coupler is 100: 30, takes by weighing the flaxen fiber cloth 3kg that polystyrene plastics particle 10kg, silane coupler handled.
The mold pressing between two-layer fibrilia modified polystyrene plastics layer of this embodiment of the invention kenaf-plastics composite sheet material has flaxen fiber cloth reinforced plastic layer.The flaxen fiber cloth mold pressing that flaxen fiber cloth reinforced plastic layer was handled by polystyrene plastics particle and two-layer silane coupler forms.
Above-mentioned after testing kenaf-plastics composite sheet material hot strength 34.5MPa, stretch modulus 3.8GPa, bending strength 78.5MPa, bending modulus 2.5GPa, 90 ℃ were quickened thermo-oxidative ageing 600 hours, hot strength retention rate 60.1%.
Embodiment 5: a kind of kenaf-plastics composite preparation of plates method, and its preparation process is:
(1) silane coupler and water were pressed mass ratio 1: 5, take by weighing silane coupler 5g, water 25g mixes, wherein water is solvent; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(2) silane coupler of nano titanium oxide and dilution was pressed quality 100: 6, the silane coupler 0.03kg that takes by weighing nano titanium oxide 0.5kg and above-mentioned dilution mixes, and under 80 ℃ of temperature, the modified nano-titanium dioxide particle is made in vacuum drying 3 hours; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(3) press flaxen fiber cloth and silane coupler mass ratio 100: 5, take by weighing silane coupler 0.25kg, the dilute with water silane coupler, water consumption is as the criterion with submergence flaxen fiber cloth; Flaxen fiber cloth 5kg is immersed in the silane coupler of dilute with water, soaks after 120 minutes, take out flaxen fiber cloth, drain, put into vacuum drying oven, under 80 ℃ of temperature, vacuum drying 6 hours; Described flaxen fiber cloth adopts ramee cloth;
(4) vinyon particle and modified nano-titanium dioxide particle, antioxidant were pressed mass ratio 100: 5: 2.0, take by weighing vinyon particle plastic pellet 10kg, modified nano-titanium dioxide particle 0.5kg, antioxidant BHT 0.2kg, mechanical mixture is even, use the extruder extruding pelletization, the extruding pelletization temperature is 140 ℃, obtains the modified poly ethylene plastic pellet;
(5) above-mentioned modified poly ethylene plastic pellet and interface bulking agent, flaxen fiber were pressed mass ratio 100: 20: 30, take by weighing modified poly ethylene plastic pellet 10kg, interface bulking agent maleic anhydride grafted polyethylene 2kg, flaxen fiber 3kg, put into container, mechanical mixture is even, rolls into fibrilia modified vinyon layer through calender then; Fibrilia modified vinyon layer thickness is 0.5～2mm, and flaxen fiber length is 0.5～10mm; Described flaxen fiber adopts ramee;
(6) place a fibrilia modified vinyon layer in the bottom of compression molding mold cavity, lay vinyon particle on fibrilia modified vinyon layer, put on vinyon particle upper berth and to state the flaxen fiber cloth of handling with silane coupler, lay vinyon particle on the above-mentioned flaxen fiber cloth of handling with silane coupler, on the vinyon particle, repave to put and state the flaxen fiber cloth of handling with silane coupler, lay vinyon particle on the flaxen fiber cloth of handling with silane coupler, on the vinyon particle, repave to put and state the flaxen fiber cloth of handling with silane coupler, on the flaxen fiber cloth of handling with silane coupler, repave and put the vinyon particle, the fibrilia modified vinyon layer of lay one deck above the vinyon particle more at last, matched moulds, preheating is after 10 minutes under 145 ℃ of temperature, adopt the pressure compression molding of 20MPa, make kenaf-plastics composite sheet material; Wherein the flaxen fiber cloth mass ratio handled of vinyon particle and silane coupler is 100: 50, takes by weighing the flaxen fiber cloth 5kg that vinyon particle 10kg, silane coupler handled.
The mold pressing between two-layer fibrilia modified vinyon layer of this embodiment of the invention kenaf-plastics composite sheet material has flaxen fiber cloth reinforced plastic layer.The flaxen fiber cloth mold pressing that flaxen fiber cloth reinforced plastic layer was handled by vinyon particle and three layers of silane coupler forms.
Above-mentioned after testing kenaf-plastics composite sheet material hot strength 40.6MPa, stretch modulus 3.9GPa, bending strength 75.5MPa, bending modulus 3.1GPa, 90 ℃ were quickened thermo-oxidative ageing 600 hours, hot strength retention rate 60%.
Embodiment 6: a kind of kenaf-plastics composite preparation of plates method, and its preparation process is:
(1) silane coupler and water were pressed mass ratio 1: 3, take by weighing silane coupler 3g, water 9g mixes, wherein water is solvent; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(2) silane coupler of nano titanium oxide and dilution was pressed mass ratio 100: 4, the silane coupler 0.012kg that takes by weighing nano titanium oxide 0.3kg and above-mentioned dilution mixes, under 60 ℃ of temperature, the modified nano-titanium dioxide particle is made in vacuum drying 4.5 hours; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(3) press flaxen fiber cloth and silane coupler mass ratio 100: 3, take by weighing silane coupler 0.09kg, the dilute with water silane coupler, water consumption is as the criterion with submergence flaxen fiber cloth; Flaxen fiber cloth 3kg is immersed in the silane coupler of dilute with water, soaks after 80 minutes, take out flaxen fiber cloth, drain, put into vacuum drying oven, under 60 ℃ of temperature, vacuum drying 4.5 hours; Described flaxen fiber cloth adopts ramee cloth;
(4) vinyon particle and modified nano-titanium dioxide particle, antioxidant were pressed mass ratio 100: 3: 1.3, take by weighing vinyon particle plastic pellet 10kg, modified nano-titanium dioxide particle 0.3kg, antioxidant 1010 (A) 0.13Kg, mechanical mixture is even, use the extruder extruding pelletization, the extruding pelletization temperature is 200 ℃, obtains the modified poly ethylene plastic pellet;
(5) above-mentioned modified poly ethylene plastic pellet and interface bulking agent, flaxen fiber were pressed mass ratio 100: 10: 20, take by weighing modified poly ethylene plastic pellet 10kg, interface bulking agent maleic anhydride grafted polyethylene 1kg, flaxen fiber 2kg, put into container, mechanical mixture is even, rolls into fibrilia modified vinyon layer through calender then; Fibrilia modified vinyon layer thickness is 0.5～2mm, and flaxen fiber length is that the described flaxen fiber of 0.5～10mm adopts ramee;
(6) place a fibrilia modified vinyon layer in the bottom of compression molding mold cavity, lay vinyon particle on fibrilia modified vinyon layer, put on vinyon particle upper berth and to state the flaxen fiber cloth of handling with silane coupler, lay vinyon particle on the above-mentioned flaxen fiber cloth of handling with silane coupler, on the vinyon particle, repave to put and state the flaxen fiber cloth of handling with silane coupler, lay vinyon particle on the flaxen fiber cloth of handling with silane coupler, the fibrilia modified vinyon layer of lay one deck above the vinyon particle more at last, matched moulds, preheating is after 8 minutes under 145 ℃ of temperature, adopt the pressure compression molding of 20MPa, make kenaf-plastics composite sheet material; Wherein the flaxen fiber cloth mass ratio handled of vinyon particle and silane coupler is 100: 30, takes by weighing the flaxen fiber cloth 3kg that vinyon particle 10kg, silane coupler handled.
The mold pressing between two-layer fibrilia modified vinyon layer of this embodiment of the invention kenaf-plastics composite sheet material has flaxen fiber cloth reinforced plastic layer.The flaxen fiber cloth mold pressing that flaxen fiber cloth reinforced plastic layer was handled by vinyon particle and two-layer silane coupler forms.
Above-mentioned after testing kenaf-plastics composite sheet material hot strength 47.8MPa, stretch modulus 3.5GPa, bending strength 70.9MPa, bending modulus 2.3GPa, 90 ℃ were quickened thermo-oxidative ageing 600 hours, hot strength retention rate 68%.
Embodiment 7: a kind of kenaf-plastics composite preparation of plates method, and its preparation process is:
(1) silane coupler and water were pressed mass ratio 1: 1, take by weighing silane coupler 1g, water 1g mixes, wherein water is solvent; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(2) silane coupler of nano titanium oxide and dilution was pressed mass ratio 100: 2, the silane coupler 0.002kg that takes by weighing nano titanium oxide 0.1kg and above-mentioned dilution mixes, under 40 ℃ of temperature, the modified nano-titanium dioxide particle is made in vacuum drying 6 hours; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(3) press flaxen fiber cloth and silane coupler mass ratio 100: 1, take by weighing silane coupler 0.01kg, the dilute with water silane coupler, water consumption is as the criterion with submergence flaxen fiber cloth; Flaxen fiber cloth 1kg is immersed in the silane coupler of dilute with water, soaks after 30 minutes, take out flaxen fiber cloth, drain, put into vacuum drying oven, under 40 ℃ of temperature, vacuum drying 3 hours; Described flaxen fiber cloth adopts hemp cloth;
(4) polypropylene plastics particle and modified nano-titanium dioxide particle, antioxidant were pressed mass ratio 100: 1: 0.5, take by weighing polypropylene plastics particle plastic pellet 10kg, modified nano-titanium dioxide particle 0.1kg, antioxidant 1010 (A) 0.05kg, mechanical mixture is even, use the extruder extruding pelletization, the extruding pelletization temperature is 175 ℃, obtains the modified polypropylene plastic particle;
(5) above-mentioned modified polypropylene plastic particle and interface bulking agent, flaxen fiber were pressed mass ratio 100: 1: 10, take by weighing modified polypropylene plastic particle 10kg, interface bulking agent maleic anhydride inoculated polypropylene (MAPP) 0.1kg, flaxen fiber 1kg, put into container, mechanical mixture is even, rolls into the fibrilia modified polypropylene plastics bed of material through calender then; Fibrilia modified polypropylene plastics thickness of feed layer is 0.5～2mm, and flaxen fiber length is 0.5～10mm; Described flaxen fiber adopts hemp;
(6) place a fibrilia modified polypropylene plastics bed of material in the bottom of compression molding mold cavity, put the polypropylene plastics particle on fibrilia modified polypropylene plastics bed of material upper berth, put on polypropylene plastics particle upper berth and to state the flaxen fiber cloth of handling with silane coupler, lay polypropylene plastics particle on the above-mentioned flaxen fiber cloth of handling with silane coupler again, the fibrilia modified polypropylene plastics bed of material of lay one deck above the polypropylene plastics particle more at last, matched moulds, preheating is after 5 minutes under 180 ℃ of temperature, adopt the pressure compression molding of 5MPa, make kenaf-plastics composite sheet material; Wherein the flaxen fiber cloth mass ratio handled of polypropylene plastics particle and silane coupler is 100: 10, takes by weighing the flaxen fiber cloth 1kg that polypropylene plastics particle 10kg, silane coupler handled.
The mold pressing between the two-layer fibrilia modified polypropylene plastics bed of material of this embodiment of the invention kenaf-plastics composite sheet material has flaxen fiber cloth reinforced plastic layer.The flaxen fiber cloth mold pressing that flaxen fiber cloth reinforced plastic layer was handled by polypropylene plastics particle and silane coupler forms.
Above-mentioned after testing kenaf-plastics composite sheet material hot strength 41.5MPa, stretch modulus 2.7GPa, bending strength 64.6MPa, bending modulus 1.8GPa, 90 ℃ were quickened thermo-oxidative ageing 600 hours, hot strength retention rate 53%.
Embodiment 8: a kind of kenaf-plastics composite preparation of plates method, and its preparation process is:
(1) silane coupler and water were pressed mass ratio 1: 3, take by weighing silane coupler 3g, water 9g mixes, wherein water is solvent; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(2) silane coupler of nano titanium oxide and dilution was pressed mass ratio 100: 4, the silane coupler 0.012kg that takes by weighing nano titanium oxide 0.3kg and above-mentioned dilution mixes, under 60 ℃ of temperature, the modified nano-titanium dioxide particle is made in vacuum drying 4.5 hours; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(3) press flaxen fiber cloth and silane coupler mass ratio 100: 3, take by weighing silane coupler 0.09kg, the dilute with water silane coupler, water consumption is as the criterion with submergence flaxen fiber cloth; Flaxen fiber cloth 3kg is immersed in the silane coupler of dilute with water, soaks after 80 minutes, take out flaxen fiber cloth, drain, put into vacuum drying oven, under 60 ℃ of temperature, vacuum drying 4.5 hours; Described flaxen fiber cloth adopts hemp cloth;
(4) polypropylene plastics particle and modified nano-titanium dioxide particle, antioxidant were pressed mass ratio 100: 3: 1.3, take by weighing polypropylene plastics particle plastic pellet 10kg, modified nano-titanium dioxide particle 0.3kg, antioxidant 1010 (A) 0.13Kg, mechanical mixture is even, use the extruder extruding pelletization, the extruding pelletization temperature is 175 ℃, obtains the modified polypropylene plastic particle;
(5) above-mentioned modified polypropylene plastic particle and interface bulking agent, flaxen fiber were pressed mass ratio 100: 10: 20, take by weighing modified polypropylene plastic particle 10kg, interface bulking agent maleic anhydride inoculated polypropylene (MAPP) 1kg, flaxen fiber 2kg, put into container, mechanical mixture is even, rolls into the fibrilia modified polypropylene plastics bed of material through calender then; Fibrilia modified polypropylene plastics thickness of feed layer is 0.5～2mm, and flaxen fiber length is 0.5～10mm; Described flaxen fiber adopts hemp;
(6) place a fibrilia modified polypropylene plastics bed of material in the bottom of compression molding mold cavity, put the polypropylene plastics particle on fibrilia modified polypropylene plastics bed of material upper berth, put on polypropylene plastics particle upper berth and to state the flaxen fiber cloth of handling with silane coupler, lay polypropylene plastics particle on the above-mentioned flaxen fiber cloth of handling with silane coupler, on the polypropylene plastics particle, repave to put and state the flaxen fiber cloth of handling with silane coupler, lay polypropylene plastics particle on the flaxen fiber cloth of handling with silane coupler, the fibrilia modified polypropylene plastics bed of material of lay one deck above the polypropylene plastics particle more at last, matched moulds, preheating is after 8 minutes under 180 ℃ of temperature, adopt the pressure compression molding of 20MPa, make kenaf-plastics composite sheet material; Wherein the flaxen fiber cloth mass ratio handled of polypropylene plastics particle and silane coupler is 100: 30, takes by weighing the flaxen fiber cloth 3kg that polypropylene plastics particle 10kg, silane coupler handled.
The mold pressing between the two-layer fibrilia modified polypropylene plastics bed of material of this embodiment of the invention kenaf-plastics composite sheet material has flaxen fiber cloth reinforced plastic layer.The flaxen fiber cloth mold pressing that flaxen fiber cloth reinforced plastic layer was handled by polypropylene plastics particle and two-layer silane coupler forms.
Above-mentioned after testing kenaf-plastics composite sheet material hot strength 45.6MPa, stretch modulus 3.8GPa, bending strength 86.4Pa, bending modulus 3.1GPa, 90 ℃ were quickened thermo-oxidative ageing 600 hours, hot strength retention rate 64%.
Embodiment 9: a kind of kenaf-plastics composite preparation of plates method, and its preparation process is:
(1) silane coupler and water were pressed mass ratio 1: 5, take by weighing silane coupler 5g, water 25g mixes, wherein water is solvent; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(2) silane coupler of nano titanium oxide and dilution was pressed quality 100: 6, the silane coupler 0.03kg that takes by weighing nano titanium oxide 0.5kg and above-mentioned dilution mixes, and under 80 ℃ of temperature, the modified nano-titanium dioxide particle is made in vacuum drying 3 hours; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(3) press flaxen fiber cloth and silane coupler mass ratio 100: 5, take by weighing silane coupler 0.25kg, the dilute with water silane coupler, water consumption is as the criterion with submergence flaxen fiber cloth; Flaxen fiber cloth 5kg is immersed in the silane coupler of dilute with water, soaks after 120 minutes, take out flaxen fiber cloth, drain, put into vacuum drying oven, under 80 ℃ of temperature, vacuum drying 6 hours; Described flaxen fiber cloth adopts sisal fiber cloth;
(4) igelite particle and modified nano-titanium dioxide particle, antioxidant were pressed mass ratio 100: 5: 2.0, take by weighing igelite particle plastic pellet 10kg, modified nano-titanium dioxide particle 0.5kg, antioxidant BHT 0.2kg, mechanical mixture is even, use the extruder extruding pelletization, the extruding pelletization temperature is 180 ℃, obtains the modified polyvinyl chloride plastic pellet;
(5) above-mentioned modified polyvinyl chloride plastic pellet and interface bulking agent, flaxen fiber were pressed mass ratio 100: 20: 30, take by weighing modified polyvinyl chloride plastic pellet 10kg, interface bulking agent maleic anhydride inoculated polypropylene (MAPP) 2kg, flaxen fiber 3kg, put into container, mechanical mixture is even, rolls into the fibrilia modified polyvinyl chloride plastic bed of material through calender then; Fibrilia modified polyvinyl chloride plastic thickness of feed layer is 0.5～2mm, and flaxen fiber length is 0.5～10mm; Described flaxen fiber adopts flax fiber, sisal fiber, tossa mixture;
(6) place a fibrilia modified polyvinyl chloride plastic bed of material in the bottom of compression molding mold cavity, put the polypropylene plastics particle on fibrilia modified polyvinyl chloride plastic bed of material upper berth, put on igelite particle upper berth and to state the flaxen fiber cloth of handling with silane coupler, lay igelite particle on the above-mentioned flaxen fiber cloth of handling with silane coupler, on the igelite particle, repave to put and state the flaxen fiber cloth of handling with silane coupler, lay igelite particle on the flaxen fiber cloth of handling with silane coupler, on the igelite particle, repave to put and state the flaxen fiber cloth of handling with silane coupler, on the flaxen fiber cloth of handling with silane coupler, repave and put the igelite particle, the fibrilia modified polyvinyl chloride plastic bed of material of lay one deck above the igelite particle more at last, matched moulds, preheating is after 10 minutes under 185 ℃ of temperature, adopt the pressure compression molding of 20MPa, make kenaf-plastics composite sheet material; Wherein the flaxen fiber cloth mass ratio handled of igelite particle and silane coupler is 100: 50, takes by weighing the flaxen fiber cloth 5kg that igelite particle 10kg, silane coupler handled.
The mold pressing between the two-layer fibrilia modified polyvinyl chloride plastic bed of material of this embodiment of the invention kenaf-plastics composite sheet material has flaxen fiber cloth reinforced plastic layer.The flaxen fiber cloth mold pressing that flaxen fiber cloth reinforced plastic layer was handled by igelite particle and three layers of silane coupler forms.
Above-mentioned after testing kenaf-plastics composite sheet material hot strength 33.8MPa, stretch modulus 3.2GPa, bending strength 76.8MPa, bending modulus 2.5GPa, 90 ℃ were quickened thermo-oxidative ageing 600 hours, hot strength retention rate 57%.
Embodiment 10: a kind of kenaf-plastics composite preparation of plates method, and its preparation process is:
(1) silane coupler and water were pressed mass ratio 1: 3, take by weighing silane coupler 3g, water 9g mixes, wherein water is solvent; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(2) silane coupler of nano titanium oxide and dilution was pressed mass ratio 100: 4, the silane coupler 0.012kg that takes by weighing nano titanium oxide 0.3kg and above-mentioned dilution mixes, under 60 ℃ of temperature, the modified nano-titanium dioxide particle is made in vacuum drying 4.5 hours; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(3) press flaxen fiber cloth and silane coupler mass ratio 100: 3, take by weighing silane coupler 0.09kg, the dilute with water silane coupler, water consumption is as the criterion with submergence flaxen fiber cloth; Flaxen fiber cloth 3kg is immersed in the silane coupler of dilute with water, soaks after 80 minutes, take out flaxen fiber cloth, drain, put into vacuum drying oven, under 60 ℃ of temperature, vacuum drying 4.5 hours; Described flaxen fiber cloth adopts sisal fiber cloth;
(4) igelite particle and modified nano-titanium dioxide particle, antioxidant were pressed mass ratio 100: 3: 1.3, take by weighing igelite particle plastic pellet 10kg, modified nano-titanium dioxide particle 0.3kg, antioxidant 1010 (A) 0.13kg, mechanical mixture is even, use the extruder extruding pelletization, the extruding pelletization temperature is 180 ℃, obtains the modified polyvinyl chloride plastic pellet;
(5) above-mentioned modified polyvinyl chloride plastic pellet and interface bulking agent, flaxen fiber were pressed mass ratio 100: 10: 20, take by weighing modified polyvinyl chloride plastic pellet 10kg, interface bulking agent maleic anhydride inoculated polypropylene (MAPP) 1kg, flaxen fiber 2kg, put into container, mechanical mixture is even, rolls into the fibrilia modified polyvinyl chloride plastic bed of material through calender then; Fibrilia modified polyvinyl chloride plastic thickness of feed layer is 0.5～2mm, and flaxen fiber length is 0.5～10mm; Described flaxen fiber adopts sisal fiber;
(6) place a fibrilia modified polyvinyl chloride plastic bed of material in the bottom of compression molding mold cavity, put the igelite particle on fibrilia modified polyvinyl chloride plastic bed of material upper berth, put on igelite particle upper berth and to state the flaxen fiber cloth of handling with silane coupler, lay igelite particle on the above-mentioned flaxen fiber cloth of handling with silane coupler, on the igelite particle, repave to put and state the flaxen fiber cloth of handling with silane coupler, lay igelite particle on the flaxen fiber cloth of handling with silane coupler, the fibrilia modified polyvinyl chloride plastic bed of material of lay one deck above the igelite particle more at last, matched moulds, preheating is after 8 minutes under 185 ℃ of temperature, adopt the pressure compression molding of 20MPa, make kenaf-plastics composite sheet material; Wherein the flaxen fiber cloth mass ratio handled of igelite particle and silane coupler is 100: 30, takes by weighing the flaxen fiber cloth 3kg that igelite particle 10kg, silane coupler handled.
The mold pressing between the two-layer fibrilia modified polyvinyl chloride plastic bed of material of this embodiment of the invention kenaf-plastics composite sheet material has flaxen fiber cloth reinforced plastic layer.The flaxen fiber cloth mold pressing that flaxen fiber cloth reinforced plastic layer was handled by igelite particle and two-layer silane coupler forms.
Composite board hot strength 42.4MPa, stretch modulus 2.8GPa, bending strength 75.4MPa, bending modulus 2.3GPa, 90 ℃ were quickened thermo-oxidative ageing 600 hours, hot strength retention rate 58%.
Embodiment 11: a kind of kenaf-plastics composite preparation of plates method, and its preparation process is:
(1) silane coupler and water were pressed mass ratio 1: 5, take by weighing silane coupler 5g, water 25g mixes, wherein water is solvent; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(2) silane coupler of nano titanium oxide and dilution was pressed quality 100: 6, the silane coupler 0.03kg that takes by weighing nano titanium oxide 0.5kg and above-mentioned dilution mixes, and under 80 ℃ of temperature, the modified nano-titanium dioxide particle is made in vacuum drying 3 hours; Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane;
(3) press flaxen fiber cloth and silane coupler mass ratio 100: 5, take by weighing silane coupler 0.25kg, the dilute with water silane coupler, water consumption is as the criterion with submergence flaxen fiber cloth; Flaxen fiber cloth 5kg is immersed in the silane coupler of dilute with water, soaks after 120 minutes, take out flaxen fiber cloth, drain, put into vacuum drying oven, under 80 ℃ of temperature, vacuum drying 6 hours; Described flaxen fiber cloth adopts tossa cloth;
(4) vinyon particle and modified nano-titanium dioxide particle, antioxidant were pressed mass ratio 100: 5: 2.0, take by weighing vinyon particle plastic pellet 10kg, modified nano-titanium dioxide particle 0.5kg, antioxidant BHT 0.2kg, mechanical mixture is even, use the extruder extruding pelletization, the extruding pelletization temperature is 140 ℃, obtains the modified poly ethylene plastic pellet;
(5) above-mentioned modified poly ethylene plastic pellet and interface bulking agent, flaxen fiber were pressed mass ratio 100: 20: 30, take by weighing modified poly ethylene plastic pellet 10kg, interface bulking agent maleic anhydride grafted polyethylene 2kg, flaxen fiber 3kg, put into container, mechanical mixture is even, rolls into fibrilia modified vinyon layer through calender then; Fibrilia modified vinyon layer thickness is 0.5～2mm, and flaxen fiber length is 0.5～10mm; Described flaxen fiber adopts tossa, ramee, hemp mixture;
(6) place a fibrilia modified vinyon layer in the bottom of compression molding mold cavity, lay vinyon particle on fibrilia modified vinyon layer, put on vinyon particle upper berth and to state the flaxen fiber cloth of handling with silane coupler, lay vinyon particle on the above-mentioned flaxen fiber cloth of handling with silane coupler, on the vinyon particle, repave to put and state the flaxen fiber cloth of handling with silane coupler, lay vinyon particle on the flaxen fiber cloth of handling with silane coupler, on the vinyon particle, repave to put and state the flaxen fiber cloth of handling with silane coupler, on the flaxen fiber cloth of handling with silane coupler, repave and put the vinyon particle, the fibrilia modified vinyon layer of lay one deck above the vinyon particle more at last, matched moulds, preheating is after 10 minutes under 145 ℃ of temperature, adopt the pressure compression molding of 20MPa, make kenaf-plastics composite sheet material; Wherein the flaxen fiber cloth mass ratio handled of vinyon particle and silane coupler is 100: 50, takes by weighing the flaxen fiber cloth 5kg that vinyon particle 10kg, silane coupler handled.
The mold pressing between two-layer fibrilia modified vinyon layer of this embodiment of the invention kenaf-plastics composite sheet material has flaxen fiber cloth reinforced plastic layer.The flaxen fiber cloth mold pressing that flaxen fiber cloth reinforced plastic layer was handled by vinyon particle and three layers of silane coupler forms.
Above-mentioned after testing kenaf-plastics composite sheet material hot strength 38.8MPa, stretch modulus 3.2GPa, bending strength 73.6MPa, bending modulus 2.7GPa, 90 ℃ were quickened thermo-oxidative ageing 600 hours, hot strength retention rate 63%.
Claims (9)
1, a kind of kenaf-plastics composite sheet material is characterized in that being made of two-layer fibrilia modified plastic layer, flaxen fiber cloth reinforced plastic layer, and mold pressing has flaxen fiber cloth reinforced plastic layer between two-layer fibrilia modified plastic layer; Fibrilia modified plastic layer mixes calendering by modified plastics particle, flaxen fiber, interface bulking agent and forms; The flaxen fiber cloth mold pressing that flaxen fiber cloth reinforced plastic layer was handled by plastic pellet and several layers silane coupler forms;
The described flaxen fiber cloth of handling with silane coupler is provided with several layers, and all lay has plastic pellet between every two-layer flaxen fiber cloth of handling with silane coupler;
Described modified plastics particle is formed by modified nano-titanium dioxide, antioxidant, plastic pellet mixing extruding pelletization; Modified nano-titanium dioxide is mixed with silane coupler by nano titanium oxide, and vacuum drying is made.
2, a kind of kenaf-plastics composite sheet material according to claim 1 is characterized in that described plastic pellet adopts a kind of in polyethylene, polypropylene, polystyrene, the polyvinyl chloride.
3, a kind of kenaf-plastics composite sheet material according to claim 1 is characterized in that described flaxen fiber adopts a kind of or its mixture in ramee, hemp, flax fiber, sisal fiber, the tossa.
4, a kind of kenaf-plastics composite sheet material according to claim 1 is characterized in that described flaxen fiber cloth adopts a kind of in ramee cloth, hemp cloth, flax fiber cloth, sisal fiber cloth, the tossa cloth.
5, a kind of kenaf-plastics composite sheet material according to claim 1 is characterized in that described interface bulking agent adopts a kind of in maleic anhydride inoculated polypropylene, maleic anhydride grafted polyethylene, the maleic anhydride graft polystyrene.
6, a kind of kenaf-plastics composite sheet material according to claim 1 is characterized in that described antioxidant adopts a kind of among 1010 (A), the BHT; 1010 (A) are four (β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester; BHT is 2, the 6-di-tert-butyl-4-methy phenol.
7, a kind of kenaf-plastics composite sheet material according to claim 1 is characterized in that described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane.
8, the described a kind of kenaf-plastics composite preparation of plates method of claim 1 is characterized in that its preparation process is:
(1) silane coupler and water are mixed by mass ratio 1: 1～5, wherein water is solvent;
(2) silane coupler with nano titanium oxide and dilution mixes by mass ratio 100: 2～6, and under 40 ℃～80 ℃ temperature, the modified nano-titanium dioxide particle is made in vacuum drying 3～6 hours;
(3) press flaxen fiber cloth and silane coupler mass ratio 100: 1～5, take by weighing silane coupler, the dilute with water silane coupler, water consumption is as the criterion with submergence flaxen fiber cloth; Flaxen fiber cloth is immersed in the silane coupler of dilute with water, soaks after 30～120 minutes, take out flaxen fiber cloth, drain, put into vacuum drying oven, under 40 ℃～80 ℃ temperature, vacuum drying 3～6 hours;
(4) plastic pellet and modified nano-titanium dioxide particle, antioxidant are pressed mass ratio 100: 1～5: 0.5～2.0, mechanical mixture is even, uses the extruder extruding pelletization, and the extruding pelletization temperature is 140 ℃～200 ℃, obtains the modified plastics particle;
(5) 100: 1～20: 10～30 mechanical mixture are even above-mentioned modified plastics particle and interface bulking agent, flaxen fiber to be pressed mass ratio, roll into fibrilia modified plastic layer through calender then; Fibrilia modified plastic layer is 0.5～2mm, and flaxen fiber length is 0.5～10mm;
(6) place a fibrilia modified plastic layer in the bottom of compression molding mold cavity, lay plastic pellet on fibrilia modified plastic layer, put on the plastic pellet upper berth and to state the flaxen fiber cloth of handling with silane coupler, lay plastic pellet on the above-mentioned flaxen fiber cloth of handling with silane coupler again, the flaxen fiber cloth mass ratio 100: 10～50 that plastic pellet and silane coupler were handled, the fibrilia modified plastic layer of lay one deck above plastic pellet more at last, matched moulds, preheating is after 5～10 minutes in 145 ℃～210 ℃ scopes, adopt the pressure compression molding of 5MPa～20MPa, make kenaf-plastics composite sheet material;
Described plastic pellet adopts a kind of in polyethylene, polypropylene, polystyrene, the polyvinyl chloride;
Described flaxen fiber adopts a kind of or its mixture in ramee, hemp, flax fiber, sisal fiber, the tossa;
Described flaxen fiber cloth adopts a kind of in ramee cloth, hemp cloth, flax fiber cloth, sisal fiber cloth, the tossa cloth;
Described interface bulking agent adopts a kind of in maleic anhydride inoculated polypropylene, maleic anhydride grafted polyethylene, the maleic anhydride graft polystyrene;
Described antioxidant adopts a kind of among 1010 (A), the BHT; 1010 (A) are four (β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid) pentaerythritol ester; BHT is 2, the 6-di-tert-butyl-4-methy phenol;
Described silane coupler adopts γ-(methacryloxypropyl) propyl trimethoxy silicane.
9, a kind of kenaf-plastics composite preparation of plates method according to claim 8, it is characterized in that the described flaxen fiber cloth of handling with silane coupler is provided with several layers, all lay has plastic pellet between every two-layer flaxen fiber cloth of handling with silane coupler.
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| CN106084840A (en) * | 2016-07-12 | 2016-11-09 | 志邦厨柜股份有限公司 | A kind of polypropylene-base bamboo modified with graphene oxide grafting POE bulking agent moulds cabinet slab and preparation method thereof |
| CN106883543A (en) * | 2017-04-27 | 2017-06-23 | 南通容润汽车配件有限公司 | A kind of automobile multifunctional macromolecule resin material |
| CN107955248B (en) * | 2017-11-21 | 2020-06-30 | 南京林业大学 | Internal reinforced composite board prepared from traditional Chinese medicine dregs and preparation method thereof |
| CN110202906B (en) * | 2019-06-20 | 2021-06-04 | 山东拓研新材料科技有限公司 | Preparation process of plant fiber reinforced thermoplastic composite material |
| CN113733681A (en) * | 2021-07-23 | 2021-12-03 | 苏州大学 | Method for preparing composite material |
-
2008
- 2008-02-15 CN CNB2008100206121A patent/CN100564023C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011140706A1 (en) * | 2010-05-12 | 2011-11-17 | 昆山博富新材料科技股份有限公司 | Hemp fiber for plastic reinforcement and preparation method thereof |
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| CN101229700A (en) | 2008-07-30 |
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