US20210280804A1 - Organic electroluminescent materials and devices - Google Patents

Organic electroluminescent materials and devices Download PDF

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US20210280804A1
US20210280804A1 US17/179,915 US202117179915A US2021280804A1 US 20210280804 A1 US20210280804 A1 US 20210280804A1 US 202117179915 A US202117179915 A US 202117179915A US 2021280804 A1 US2021280804 A1 US 2021280804A1
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Jerald Feldman
Jui-Yi Tsai
Alexey Borisovich Dyatkin
Zhiqiang Ji
Pierre-Luc T. Boudreault
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Universal Display Corp
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Definitions

  • the present disclosure generally relates to organometallic compounds and formulations and their various uses including as emitters in devices such as organic light emitting diodes and related electronic devices.
  • Opto-electronic devices that make use of organic materials are becoming increasingly desirable for various reasons. Many of the materials used to make such devices are relatively inexpensive, so organic opto-electronic devices have the potential for cost advantages over inorganic devices. In addition, the inherent properties of organic materials, such as their flexibility, may make them well suited for particular applications such as fabrication on a flexible substrate. Examples of organic opto-electronic devices include organic light emitting diodes/devices (OLEDs), organic phototransistors, organic photovoltaic cells, and organic photodetectors. For OLEDs, the organic materials may have performance advantages over conventional materials.
  • OLEDs organic light emitting diodes/devices
  • OLEDs organic phototransistors
  • organic photovoltaic cells organic photovoltaic cells
  • organic photodetectors organic photodetectors
  • OLEDs make use of thin organic films that emit light when voltage is applied across the device. OLEDs are becoming an increasingly interesting technology for use in applications such as flat panel displays, illumination, and backlighting.
  • phosphorescent emissive molecules are full color display. Industry standards for such a display call for pixels adapted to emit particular colors, referred to as “saturated” colors. In particular, these standards call for saturated red, green, and blue pixels.
  • the OLED can be designed to emit white light. In conventional liquid crystal displays emission from a white backlight is filtered using absorption filters to produce red, green and blue emission. The same technique can also be used with OLEDs.
  • the white OLED can be either a single emissive layer (EML) device or a stack structure. Color may be measured using CIE coordinates, which are well known to the art.
  • novel Pt(II) complexes comprising tetradentate pyrimidine and pyrazine ligands. These complexes are useful as phosphorescent emitters in organic electroluminescent devices.
  • the present disclosure provides a compound of
  • each of X 1 and X 2 is independently C or N, with at least one being N; each of X 3 , X 4 , and X 5 is independently C or N; at least one of X 3 , X 4 , and X 5 is C and at least one is N; L 1 and L 2 are linkers that can be present, with at least one of them being present and each independently selected from the group consisting of O, S, Se, CRR′, SiRR′, GeRR′, BR, BRR′, NR, alkyl, cycloalkyl, aryl, and heteroaryl when present; R A , R B , R C , and R D each independently represents zero, mono, or up to the maximum allowed number of substitutions to its associated ring; each of R, R′, R A , R B , R C , and R D is independently a hydrogen or a substituent selected from the group consisting of the general substituents defined herein; M is Pt, Pd, Au, Ag, Cu or Z
  • the present disclosure provides a formulation of a compound of Formula I as described herein.
  • the present disclosure provides an OLED having an organic layer comprising a compound of Formula I as described herein.
  • the present disclosure provides a consumer product comprising an OLED with an organic layer comprising a compound of Formula I as described herein.
  • FIG. 1 shows an organic light emitting device
  • FIG. 2 shows an inverted organic light emitting device that does not have a separate electron transport layer.
  • organic includes polymeric materials as well as small molecule organic materials that may be used to fabricate organic opto-electronic devices.
  • Small molecule refers to any organic material that is not a polymer, and “small molecules” may actually be quite large. Small molecules may include repeat units in some circumstances. For example, using a long chain alkyl group as a substituent does not remove a molecule from the “small molecule” class. Small molecules may also be incorporated into polymers, for example as a pendent group on a polymer backbone or as a part of the backbone. Small molecules may also serve as the core moiety of a dendrimer, which consists of a series of chemical shells built on the core moiety.
  • the core moiety of a dendrimer may be a fluorescent or phosphorescent small molecule emitter.
  • a dendrimer may be a “small molecule,” and it is believed that all dendrimers currently used in the field of OLEDs are small molecules.
  • top means furthest away from the substrate, while “bottom” means closest to the substrate.
  • first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer.
  • a cathode may be described as “disposed over” an anode, even though there are various organic layers in between.
  • solution processable means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form.
  • a ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material.
  • a ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand.
  • a first “Highest Occupied Molecular Orbital” (HOMO) or “Lowest Unoccupied Molecular Orbital” (LUMO) energy level is “greater than” or “higher than” a second HOMO or LUMO energy level if the first energy level is closer to the vacuum energy level.
  • IP ionization potentials
  • a higher HOMO energy level corresponds to an IP having a smaller absolute value (an IP that is less negative).
  • a higher LUMO energy level corresponds to an electron affinity (EA) having a smaller absolute value (an EA that is less negative).
  • the LUMO energy level of a material is higher than the HOMO energy level of the same material.
  • a “higher” HOMO or LUMO energy level appears closer to the top of such a diagram than a “lower” HOMO or LUMO energy level.
  • a first work function is “greater than” or “higher than” a second work function if the first work function has a higher absolute value. Because work functions are generally measured as negative numbers relative to vacuum level, this means that a “higher” work function is more negative. On a conventional energy level diagram, with the vacuum level at the top, a “higher” work function is illustrated as further away from the vacuum level in the downward direction. Thus, the definitions of HOMO and LUMO energy levels follow a different convention than work functions.
  • halo halogen
  • halide halogen
  • fluorine chlorine, bromine, and iodine
  • acyl refers to a substituted carbonyl radical (C(O)—R s ).
  • esters refers to a substituted oxycarbonyl (—O—C(O)—R s or —C(O)—O—R s ) radical.
  • ether refers to an —OR s radical.
  • sulfanyl or “thio-ether” are used interchangeably and refer to a —SR s radical.
  • sulfinyl refers to a —S(O)—R s radical.
  • sulfonyl refers to a —SO 2 —R s radical.
  • phosphino refers to a —P(R s ) 3 radical, wherein each R s can be same or different.
  • sil refers to a —Si(R s ) 3 radical, wherein each R s can be same or different.
  • boryl refers to a —B(R s ) 2 radical or its Lewis adduct —B(R s ) 3 radical, wherein R s can be same or different.
  • R s can be hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, and combination thereof.
  • Preferred R s is selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, and combination thereof.
  • alkyl refers to and includes both straight and branched chain alkyl radicals.
  • Preferred alkyl groups are those containing from one to fifteen carbon atoms and includes methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, and the like. Additionally, the alkyl group may be optionally substituted.
  • cycloalkyl refers to and includes monocyclic, polycyclic, and spiro alkyl radicals.
  • Preferred cycloalkyl groups are those containing 3 to 12 ring carbon atoms and includes cyclopropyl, cyclopentyl, cyclohexyl, bicyclo[3.1.1]heptyl, spiro[4.5]decyl, spiro[5.5]undecyl, adamantyl, and the like. Additionally, the cycloalkyl group may be optionally substituted.
  • heteroalkyl or “heterocycloalkyl” refer to an alkyl or a cycloalkyl radical, respectively, having at least one carbon atom replaced by a heteroatom.
  • the at least one heteroatom is selected from O, S, N, P, B, Si and Se, preferably, O, S or N.
  • the heteroalkyl or heterocycloalkyl group may be optionally substituted.
  • alkenyl refers to and includes both straight and branched chain alkene radicals.
  • Alkenyl groups are essentially alkyl groups that include at least one carbon-carbon double bond in the alkyl chain.
  • Cycloalkenyl groups are essentially cycloalkyl groups that include at least one carbon-carbon double bond in the cycloalkyl ring.
  • heteroalkenyl refers to an alkenyl radical having at least one carbon atom replaced by a heteroatom.
  • the at least one heteroatom is selected from O, S, N, P, B, Si, and Se, preferably, O, S, or N.
  • alkenyl, cycloalkenyl, or heteroalkenyl groups are those containing two to fifteen carbon atoms. Additionally, the alkenyl, cycloalkenyl, or heteroalkenyl group may be optionally substituted.
  • alkynyl refers to and includes both straight and branched chain alkyne radicals.
  • Alkynyl groups are essentially alkyl groups that include at least one carbon-carbon triple bond in the alkyl chain.
  • Preferred alkynyl groups are those containing two to fifteen carbon atoms. Additionally, the alkynyl group may be optionally substituted.
  • aralkyl or “arylalkyl” are used interchangeably and refer to an alkyl group that is substituted with an aryl group. Additionally, the aralkyl group may be optionally substituted.
  • heterocyclic group refers to and includes aromatic and non-aromatic cyclic radicals containing at least one heteroatom.
  • the at least one heteroatom is selected from O, S, N, P, B, Si, and Se, preferably, O, S, or N.
  • Hetero-aromatic cyclic radicals may be used interchangeably with heteroaryl.
  • Preferred hetero-non-aromatic cyclic groups are those containing 3 to 7 ring atoms which includes at least one hetero atom, and includes cyclic amines such as morpholino, piperidino, pyrrolidino, and the like, and cyclic ethers/thio-ethers, such as tetrahydrofuran, tetrahydropyran, tetrahydrothiophene, and the like. Additionally, the heterocyclic group may be optionally substituted.
  • aryl refers to and includes both single-ring aromatic hydrocarbyl groups and polycyclic aromatic ring systems.
  • the polycyclic rings may have two or more rings in which two carbons are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is an aromatic hydrocarbyl group, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls.
  • Preferred aryl groups are those containing six to thirty carbon atoms, preferably six to twenty carbon atoms, more preferably six to twelve carbon atoms. Especially preferred is an aryl group having six carbons, ten carbons or twelve carbons.
  • Suitable aryl groups include phenyl, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene, preferably phenyl, biphenyl, triphenyl, triphenylene, fluorene, and naphthalene. Additionally, the aryl group may be optionally substituted.
  • heteroaryl refers to and includes both single-ring aromatic groups and polycyclic aromatic ring systems that include at least one heteroatom.
  • the heteroatoms include, but are not limited to O, S, N, P, B, Si, and Se. In many instances, O, S, or N are the preferred heteroatoms.
  • Hetero-single ring aromatic systems are preferably single rings with 5 or 6 ring atoms, and the ring can have from one to six heteroatoms.
  • the hetero-polycyclic ring systems can have two or more rings in which two atoms are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is a heteroaryl, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls.
  • the hetero-polycyclic aromatic ring systems can have from one to six heteroatoms per ring of the polycyclic aromatic ring system.
  • Preferred heteroaryl groups are those containing three to thirty carbon atoms, preferably three to twenty carbon atoms, more preferably three to twelve carbon atoms.
  • Suitable heteroaryl groups include dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, qui
  • aryl and heteroaryl groups listed above the groups of triphenylene, naphthalene, anthracene, dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, pyrazine, pyrimidine, triazine, and benzimidazole, and the respective aza-analogs of each thereof are of particular interest.
  • alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aralkyl, heterocyclic group, aryl, and heteroaryl, as used herein, are independently unsubstituted, or independently substituted, with one or more general substituents.
  • the general substituents are selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
  • the preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof.
  • the preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, alkoxy, aryloxy, amino, silyl, boryl, aryl, heteroaryl, sulfanyl, and combinations thereof.
  • the more preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, aryl, heteroaryl, and combinations thereof.
  • substitution refers to a substituent other than H that is bonded to the relevant position, e.g., a carbon or nitrogen.
  • R 1 represents mono-substitution
  • one R 1 must be other than H (i.e., a substitution).
  • R 1 represents di-substitution, then two of R 1 must be other than H.
  • R 1 represents zero or no substitution
  • R 1 can be a hydrogen for available valencies of ring atoms, as in carbon atoms for benzene and the nitrogen atom in pyrrole, or simply represents nothing for ring atoms with fully filled valencies, e.g., the nitrogen atom in pyridine.
  • the maximum number of substitutions possible in a ring structure will depend on the total number of available valencies in the ring atoms.
  • substitution includes a combination of two to four of the listed groups.
  • substitution includes a combination of two to three groups.
  • substitution includes a combination of two groups.
  • Preferred combinations of substituent groups are those that contain up to fifty atoms that are not hydrogen or deuterium, or those which include up to forty atoms that are not hydrogen or deuterium, or those that include up to thirty atoms that are not hydrogen or deuterium. In many instances, a preferred combination of substituent groups will include up to twenty atoms that are not hydrogen or deuterium.
  • aza-dibenzofuran i.e. aza-dibenzofuran, aza-dibenzothiophene, etc.
  • azatriphenylene encompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline.
  • deuterium refers to an isotope of hydrogen.
  • Deuterated compounds can be readily prepared using methods known in the art. For example, U.S. Pat. No. 8,557,400, Patent Pub. No. WO 2006/095951, and U.S. Pat. Application Pub. No. US 2011/0037057, which are hereby incorporated by reference in their entireties, describe the making of deuterium-substituted organometallic complexes. Further reference is made to Ming Yan, et al., Tetrahedron 2015, 71, 1425-30 and Atzrodt et al., Angew. Chem. Int. Ed. ( Reviews ) 2007, 46, 7744-65, which are incorporated by reference in their entireties, describe the deuteration of the methylene hydrogens in benzyl amines and efficient pathways to replace aromatic ring hydrogens with deuterium, respectively.
  • a pair of adjacent substituents can be optionally joined or fused into a ring.
  • the preferred ring is a five, six, or seven-membered carbocyclic or heterocyclic ring, includes both instances where the portion of the ring formed by the pair of substituents is saturated and where the portion of the ring formed by the pair of substituents is unsaturated.
  • “adjacent” means that the two substituents involved can be on the same ring next to each other, or on two neighboring rings having the two closest available substitutable positions, such as 2, 2′ positions in a biphenyl, or 1, 8 position in a naphthalene, as long as they can form a stable fused ring system.
  • the present disclosure provides a compound of
  • each of X 1 and X 2 is independently C or N, with at least one being N; each of X 3 , X 4 , and X 5 is independently C or N; at least one of X 3 , X 4 , and X 5 is C and at least one is N; L 1 and L 2 are linkers that can be present, with at least one of them being present and each independently selected from the group consisting of O, S, Se, CRR′, SiRR′, GeRR′, BR, BRR′, NR, alkyl, cycloalkyl, aryl, and heteroaryl when present; R A , R B , R C , and R D each independently represents zero, mono, or up to the maximum allowed number of substitutions to its associated ring; each of R, R′, R A , R B , R C , and R D is independently a hydrogen or a substituent selected from the group consisting of the general substituents defined herein;
  • M is Pt, Pd, Au, Ag, Cu or Zn;
  • any two adjacent R, R′, R A , R B , R C , and R D can be joined or fused together to form a ring, with the proviso that the compound is not the one shown below:
  • each of R, R′, R A , R B , R C , and R D can be independently a hydrogen or a substituent selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof.
  • X 1 can be N and X 2 can be C. In some embodiments, X 1 can be C and X 2 can be N. In some embodiments, X 1 and X 2 can each be N. In some embodiments, X 3 can be N, and X 4 and X 5 can both be C. In some embodiments, X 4 can be N, and X 3 and X 5 can both be C. In some embodiments, X 4 can be C, and X 3 and X 5 can both be N.
  • L 1 may be absent and L 2 can be present. In some embodiments, L 2 can be absent and L 1 can be present. In some embodiments, L 1 and L 2 can both be present. In some embodiments, L 1 and L 2 can each be independently selected from the group consisting of O, S, CRR′, SiRR′, and NR when present. In some embodiments, L 1 can be O, CRR′, SiRR′, or NR when present. In some embodiments, L 2 can be O or NR when present. In some embodiments, R and R′ can each be independently selected from the group consisting of hydrogen, deuterium, alkyl, heteroalkyl, cycloalkyl, heterocycloalkyl, aryl, heteroaryl, and combinations thereof.
  • R and R′ can each be independently an alkyl, cycloalkyl, aryl or heteroaryl group. In some embodiments, R can be an aryl or heteroaryl group. In some embodiments, R can be a 6-membered aryl ring.
  • two adjacent R A substituents can be joined to form a fused 5-membered or 6-membered aromatic ring.
  • two adjacent R B substituents can be joined to form a fused 5-membered or 6-membered aromatic ring.
  • two adjacent R C substituents can be joined to form a fused 5-membered or 6-membered aromatic ring.
  • two adjacent R D substituents can be joined to form a fused 5-membered or 6-membered aromatic ring.
  • the 5-membered or 6-membered aromatic ring can be selected from the group consisting of benzene, pyridine, pyrimidine, pyridazine, pyrazine, imidazole, pyrazole, pyrrole, oxazole, furan, thiophene, or thiazole.
  • the 5-membered or 6-membered aromatic ring can be further fused to form a multiple fused ring system.
  • At least one of R A , R B , R C , and R D can be selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, aryl, heteroaryl, and combinations thereof.
  • M can be Pt or Pd.
  • the compound can be selected from the group consisting of:
  • L 1 can be O, CRR′, SiRR′, or NR.
  • L 2 can be O or NR.
  • R and R′ can each be independently selected from the group consisting of hydrogen, deuterium, alkyl, heteroalkyl, cycloalkyl, heterocycloalkyl, aryl, heteroaryl, and combinations thereof.
  • R can be an aromatic group.
  • R can be a 6-membered aromatic ring.
  • two adjacent R A substituents can be joined to form a fused 5-membered or 6-membered aromatic ring.
  • two adjacent R B substituents can be joined to form a fused 5-membered or 6-membered aromatic ring.
  • two adjacent R C substituents can be joined to form a fused 5-membered or 6-membered aromatic ring.
  • two adjacent R D substituents can be joined to form a fused 5-membered or 6-membered aromatic ring.
  • the 5-membered or 6-membered aromatic ring can be selected from the group consisting of benzene, pyridine, pyrimidine, pyridazine, pyrazine, imidazole, pyrazole, pyrrole, oxazole, furan, thiophene, or thiazole.
  • the 5-membered or 6-membered aromatic can be further fused to form a multiple fused ring system.
  • At least one of R A , R B , R C , and R D can be selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, aryl, heteroaryl, and combinations thereof.
  • M can be Pt or Pd. In some of the above embodiments, M can be Pt.
  • the compound can be selected from the group consisting of:
  • the compound can be selected from the group consisting of:
  • the compound can be selected from the group consisting of:
  • the present disclosure also provides an OLED device comprising an organic layer that contains a compound as disclosed in the above compounds section of the present disclosure.
  • the organic layer may comprise a compound of
  • each of X 1 and X 2 is independently C or N, with at least one being N; each of X 3 , X 4 , and X 5 is independently C or N; at least one of X 3 , X 4 , and X 5 is C and at least one is N; L 1 and L 2 are linkers that are optionally present, with at least one of them being present and each independently selected from the group consisting of O, S, Se, CRR′, SiRR′, GeRR′, BR, BRR′, NR, alkyl, cycloalkyl, aryl, and heteroaryl when present; R A , R B , R C , and R D each independently represent zero, mono, or up to the maximum allowed number of substitutions to its associated ring; each of R, R′, R A , R B , R C , and R D is independently a hydrogen or a substituent selected from the group consisting of the general substituents defined herein; M is Pt, Pd, Au, Ag, Cu or
  • the organic layer may be an emissive layer and the compound as described herein may be an emissive dopant or a non-emissive dopant.
  • the organic layer may further comprise a host, wherein the host comprises a triphenylene containing benzo-fused thiophene or benzo-fused furan, wherein any substituent in the host is an unfused substituent independently selected from the group consisting of C n H 2n+1 , OC n H 2n+1 , OAr 1 , N(C n H 2n+1 ) 2 , N(Ar 1 )(Ar 2 ), CH ⁇ CH—C n H 2n+1 , C ⁇ CC n H 2n+1 , Ar 1 , Ar 1 —Ar 2 , C n H 2n —Ar 1 , or no substitution, wherein n is from 1 to 10; and wherein Ar 1 and Ar 2 are independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof.
  • the organic layer may further comprise a host, wherein host comprises at least one chemical moiety selected from the group consisting of naphthalene, fluorene, triphenylene, carbazole, indolocarbazole, dibenzothiphene, dibenzofuran, dibenzoselenophene, 5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene, aza-naphthalene, aza-fluorene, aza-triphenylene, aza-carbazole, aza-indolocarbazole, aza-dibenzothiophene, aza-dibenzofuran, aza-dibenzoselenophene, and aza-(5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene).
  • host comprises at least one chemical moiety selected from the group consisting of naphthalene, fluorene
  • the host may be selected from the host group consisting of:
  • the organic layer may further comprise a host, wherein the host comprises a metal complex.
  • the compound as described herein may be a sensitizer; wherein the device may further comprise an acceptor; and wherein the acceptor may be selected from the group consisting of fluorescent emitter, delayed fluorescence emitter, and combination thereof.
  • the OLED of the present disclosure may also comprise an emissive region containing a compound as disclosed in the above compounds section of the present disclosure.
  • the emissive region may comprise a compound of
  • each of X 1 and X 2 is independently C or N, with at least one being N; each of X 3 , X 4 , and X 5 is independently C or N; at least one of X 3 , X 4 , and X 5 is C and at least one is N; L 1 and L 2 are linkers that can be present, with at least one of them being present and each independently selected from the group consisting of O, S, Se, CRR′, SiRR′, GeRR′, BR, BRR′, NR, alkyl, cycloalkyl, aryl, and heteroaryl when present; R A , R B , R C , and R D each independently represents zero, mono, or up to the maximum allowed number of substitutions to its associated ring; each of R, R′, R A , R B , R C , and R D is independently a hydrogen or a substituent selected from the group consisting of the general substituents defined herein; M is Pt, Pd, Au, Ag, Cu or Z
  • the enhancement layer comprises a plasmonic material exhibiting surface plasmon resonance that non-radiatively couples to the emitter material and transfers excited state energy from the emitter material to non-radiative mode of surface plasmon polariton.
  • the enhancement layer is provided no more than a threshold distance away from the organic emissive layer, wherein the emitter material has a total non-radiative decay rate constant and a total radiative decay rate constant due to the presence of the enhancement layer and the threshold distance is where the total non-radiative decay rate constant is equal to the total radiative decay rate constant.
  • the OLED further comprises an outcoupling layer.
  • the outcoupling layer is disposed over the enhancement layer on the opposite side of the organic emissive layer.
  • the outcoupling layer is disposed on opposite side of the emissive layer from the enhancement layer but still outcouples energy from the surface plasmon mode of the enhancement layer.
  • the outcoupling layer scatters the energy from the surface plasmon polaritons. In some embodiments this energy is scattered as photons to free space. In other embodiments, the energy is scattered from the surface plasmon mode into other modes of the device such as but not limited to the organic waveguide mode, the substrate mode, or another waveguiding mode.
  • one or more intervening layer can be disposed between the enhancement layer and the outcoupling layer.
  • the examples for interventing layer(s) can be dielectric materials, including organic, inorganic, perovskites, oxides, and may include stacks and/or mixtures of these materials.
  • the enhancement layer modifies the effective properties of the medium in which the emitter material resides resulting in any or all of the following: a decreased rate of emission, a modification of emission line-shape, a change in emission intensity with angle, a change in the stability of the emitter material, a change in the efficiency of the OLED, and reduced efficiency roll-off of the OLED device. Placement of the enhancement layer on the cathode side, anode side, or on both sides results in OLED devices which take advantage of any of the above-mentioned effects.
  • the OLEDs according to the present disclosure may include any of the other functional layers often found in OLEDs.
  • the enhancement layer can be comprised of plasmonic materials, optically active metamaterials, or hyperbolic metamaterials.
  • a plasmonic material is a material in which the real part of the dielectric constant crosses zero in the visible or ultraviolet region of the electromagnetic spectrum.
  • the plasmonic material includes at least one metal.
  • the metal may include at least one of Ag, Al, Au, Ir, Pt, Ni, Cu, W, Ta, Fe, Cr, Mg, Ga, Rh, Ti, Ru, Pd, In, Bi, Ca alloys or mixtures of these materials, and stacks of these materials.
  • a metamaterial is a medium composed of different materials where the medium as a whole acts differently than the sum of its material parts.
  • optically active metamaterials as materials which have both negative permittivity and negative permeability.
  • Hyperbolic metamaterials are anisotropic media in which the permittivity or permeability are of different sign for different spatial directions.
  • Optically active metamaterials and hyperbolic metamaterials are strictly distinguished from many other photonic structures such as Distributed Bragg Reflectors (“DBRs”) in that the medium should appear uniform in the direction of propagation on the length scale of the wavelength of light.
  • DBRs Distributed Bragg Reflectors
  • the dielectric constant of the metamaterials in the direction of propagation can be described with the effective medium approximation. Plasmonic materials and metamaterials provide methods for controlling the propagation of light that can enhance OLED performance in a number of ways.
  • the enhancement layer is provided as a planar layer.
  • the enhancement layer has wavelength-sized features that are arranged periodically, quasi-periodically, or randomly, or sub-wavelength-sized features that are arranged periodically, quasi-periodically, or randomly.
  • the wavelength-sized features and the sub-wavelength-sized features have sharp edges.
  • the outcoupling layer has wavelength-sized features that are arranged periodically, quasi-periodically, or randomly, or sub-wavelength-sized features that are arranged periodically, quasi-periodically, or randomly.
  • the outcoupling layer may be composed of a plurality of nanoparticles and in other embodiments the outcoupling layer is composed of a plurality of nanoparticles disposed over a material.
  • the outcoupling may be tunable by at least one of varying a size of the plurality of nanoparticles, varying a shape of the plurality of nanoparticles, changing a material of the plurality of nanoparticles, adjusting a thickness of the material, changing the refractive index of the material or an additional layer disposed on the plurality of nanoparticles, varying a thickness of the enhancement layer, and/or varying the material of the enhancement layer.
  • the plurality of nanoparticles of the device may be formed from at least one of metal, dielectric material, semiconductor materials, an alloy of metal, a mixture of dielectric materials, a stack or layering of one or more materials, and/or a core of one type of material and that is coated with a shell of a different type of material.
  • the outcoupling layer is composed of at least metal nanoparticles wherein the metal is selected from the group consisting of Ag, Al, Au, Ir, Pt, Ni, Cu, W, Ta, Fe, Cr, Mg, Ga, Rh, Ti, Ru, Pd, In, Bi, Ca, alloys or mixtures of these materials, and stacks of these materials.
  • the plurality of nanoparticles may have additional layer disposed over them.
  • the polarization of the emission can be tuned using the outcoupling layer. Varying the dimensionality and periodicity of the outcoupling layer can select a type of polarization that is preferentially outcoupled to air. In some embodiments the outcoupling layer also acts as an electrode of the device.
  • the present disclosure also provides a consumer product comprising an organic light-emitting device (OLED) having an anode; a cathode; and an organic layer disposed between the anode and the cathode, wherein the organic layer may comprise a compound as disclosed in the above compounds section of the present disclosure.
  • OLED organic light-emitting device
  • the present disclosure also provides a consumer product comprising an organic light-emitting device (OLED) having an anode; a cathode; and an organic layer disposed between the anode and the cathode, wherein the organic layer may comprise a compound as disclosed in the above compounds section of the present disclosure.
  • OLED organic light-emitting device
  • the consumer product comprises an organic light-emitting device (OLED) having an anode; a cathode; and an organic layer disposed between the anode and the cathode, wherein the organic layer may comprise a compound of
  • each of X 1 and X 2 is independently C or N, with at least one being N; each of X 3 , X 4 , and X 5 is independently C or N; at least one of X 3 , X 4 , and X 5 is C and at least one is N; L 1 and L 2 are linkers that can be present, with at least one of them being present and each independently selected from the group consisting of O, S, Se, CRR′, SiRR′, GeRR′, BR, BRR′, NR, alkyl, cycloalkyl, aryl, and heteroaryl when present; R A , R B , R C , and R D each independently represents zero, mono, or up to the maximum allowed number of substitutions to its associated ring; each of R, R′, R A , R B , R C , and R D is independently a hydrogen or a substituent selected from the group consisting of the general substituents defined herein; M is Pt, Pd, Au, Ag, Cu or Z
  • the consumer product can be one of a flat panel display, a computer monitor, a medical monitor, a television, a billboard, a light for interior or exterior illumination and/or signaling, a heads-up display, a fully or partially transparent display, a flexible display, a laser printer, a telephone, a cell phone, tablet, a phablet, a personal digital assistant (PDA), a wearable device, a laptop computer, a digital camera, a camcorder, a viewfinder, a micro-display that is less than 2 inches diagonal, a 3-D display, a virtual reality or augmented reality display, a vehicle, a video wall comprising multiple displays tiled together, a theater or stadium screen, a light therapy device, and a sign.
  • PDA personal digital assistant
  • an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode.
  • the anode injects holes and the cathode injects electrons into the organic layer(s).
  • the injected holes and electrons each migrate toward the oppositely charged electrode.
  • an “exciton,” which is a localized electron-hole pair having an excited energy state is formed.
  • Light is emitted when the exciton relaxes via a photoemissive mechanism.
  • the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.
  • the initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.
  • FIG. 1 shows an organic light emitting device 100 .
  • Device 100 may include a substrate 110 , an anode 115 , a hole injection layer 120 , a hole transport layer 125 , an electron blocking layer 130 , an emissive layer 135 , a hole blocking layer 140 , an electron transport layer 145 , an electron injection layer 150 , a protective layer 155 , a cathode 160 , and a barrier layer 170 .
  • Cathode 160 is a compound cathode having a first conductive layer 162 and a second conductive layer 164 .
  • Device 100 may be fabricated by depositing the layers described, in order. The properties and functions of these various layers, as well as example materials, are described in more detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which are incorporated by reference.
  • each of these layers are available.
  • a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety.
  • An example of a p-doped hole transport layer is m-MTDATA doped with F 4 -TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety.
  • Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety.
  • An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety.
  • the theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No.
  • FIG. 2 shows an inverted OLED 200 .
  • the device includes a substrate 210 , a cathode 215 , an emissive layer 220 , a hole transport layer 225 , and an anode 230 .
  • Device 200 may be fabricated by depositing the layers described, in order. Because the most common OLED configuration has a cathode disposed over the anode, and device 200 has cathode 215 disposed under anode 230 , device 200 may be referred to as an “inverted” OLED. Materials similar to those described with respect to device 100 may be used in the corresponding layers of device 200 .
  • FIG. 2 provides one example of how some layers may be omitted from the structure of device 100 .
  • FIGS. 1 and 2 The simple layered structure illustrated in FIGS. 1 and 2 is provided by way of non-limiting example, and it is understood that embodiments of the present disclosure may be used in connection with a wide variety of other structures.
  • the specific materials and structures described are exemplary in nature, and other materials and structures may be used.
  • Functional OLEDs may be achieved by combining the various layers described in different ways, or layers may be omitted entirely, based on design, performance, and cost factors. Other layers not specifically described may also be included. Materials other than those specifically described may be used. Although many of the examples provided herein describe various layers as comprising a single material, it is understood that combinations of materials, such as a mixture of host and dopant, or more generally a mixture, may be used. Also, the layers may have various sublayers.
  • hole transport layer 225 transports holes and injects holes into emissive layer 220 , and may be described as a hole transport layer or a hole injection layer.
  • an OLED may be described as having an “organic layer” disposed between a cathode and an anode. This organic layer may comprise a single layer, or may further comprise multiple layers of different organic materials as described, for example, with respect to FIGS. 1 and 2 .
  • OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety.
  • PLEDs polymeric materials
  • OLEDs having a single organic layer may be used.
  • OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety.
  • the OLED structure may deviate from the simple layered structure illustrated in FIGS. 1 and 2 .
  • the substrate may include an angled reflective surface to improve out-coupling, such as a mesa structure as described in U.S. Pat. No. 6,091,195 to Forrest et al., and/or a pit structure as described in U.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated by reference in their entireties.
  • any of the layers of the various embodiments may be deposited by any suitable method.
  • preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. Pat. No. 7,431,968, which is incorporated by reference in its entirety.
  • OVPD organic vapor phase deposition
  • OJP organic vapor jet printing
  • Other suitable deposition methods include spin coating and other solution based processes.
  • Solution based processes are preferably carried out in nitrogen or an inert atmosphere.
  • preferred methods include thermal evaporation.
  • Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink-jet and organic vapor jet printing (OVJP). Other methods may also be used.
  • the materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing.
  • Substituents having 20 carbons or more may be used, and 3-20 carbons are a preferred range. Materials with asymmetric structures may have better solution processability than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.
  • Devices fabricated in accordance with embodiments of the present disclosure may further optionally comprise a barrier layer.
  • a barrier layer One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc.
  • the barrier layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge.
  • the barrier layer may comprise a single layer, or multiple layers.
  • the barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer.
  • the barrier layer may incorporate an inorganic or an organic compound or both.
  • the preferred barrier layer comprises a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporated by reference in their entireties.
  • the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time.
  • the weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95.
  • the polymeric material and the non-polymeric material may be created from the same precursor material.
  • the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon.
  • Devices fabricated in accordance with embodiments of the present disclosure can be incorporated into a wide variety of electronic component modules (or units) that can be incorporated into a variety of electronic products or intermediate components. Examples of such electronic products or intermediate components include display screens, lighting devices such as discrete light source devices or lighting panels, etc. that can be utilized by the end-user product manufacturers. Such electronic component modules can optionally include the driving electronics and/or power source(s). Devices fabricated in accordance with embodiments of the present disclosure can be incorporated into a wide variety of consumer products that have one or more of the electronic component modules (or units) incorporated therein.
  • a consumer product comprising an OLED that includes the compound of the present disclosure in the organic layer in the OLED is disclosed.
  • Such consumer products would include any kind of products that include one or more light source(s) and/or one or more of some type of visual displays.
  • Some examples of such consumer products include flat panel displays, curved displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads-up displays, fully or partially transparent displays, flexible displays, rollable displays, foldable displays, stretchable displays, laser printers, telephones, mobile phones, tablets, phablets, personal digital assistants (PDAs), wearable devices, laptop computers, digital cameras, camcorders, viewfinders, micro-displays (displays that are less than 2 inches diagonal), 3-D displays, virtual reality or augmented reality displays, vehicles, video walls comprising multiple displays tiled together, theater or stadium screen, a light therapy device, and a sign.
  • control mechanisms may be used to control devices fabricated in accordance with the present disclosure, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 degrees C. to 30 degrees C., and more preferably at room temperature (20-25° C.), but could be used outside this temperature range, for example, from ⁇ 40 degree C. to +80° C.
  • the materials and structures described herein may have applications in devices other than OLEDs.
  • other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures.
  • organic devices such as organic transistors, may employ the materials and structures.
  • the OLED has one or more characteristics selected from the group consisting of being flexible, being rollable, being foldable, being stretchable, and being curved. In some embodiments, the OLED is transparent or semi-transparent. In some embodiments, the OLED further comprises a layer comprising carbon nanotubes.
  • the OLED further comprises a layer comprising a delayed fluorescent emitter.
  • the OLED comprises a RGB pixel arrangement or white plus color filter pixel arrangement.
  • the OLED is a mobile device, a hand held device, or a wearable device.
  • the OLED is a display panel having less than 10 inch diagonal or 50 square inch area.
  • the OLED is a display panel having at least 10 inch diagonal or 50 square inch area.
  • the OLED is a lighting panel.
  • the compound can be an emissive dopant.
  • the compound can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence; see, e.g., U.S. application Ser. No. 15/700,352, which is hereby incorporated by reference in its entirety), triplet-triplet annihilation, or combinations of these processes.
  • the emissive dopant can be a racemic mixture, or can be enriched in one enantiomer.
  • the compound can be homoleptic (each ligand is the same).
  • the compound can be heteroleptic (at least one ligand is different from others).
  • the ligands can all be the same in some embodiments.
  • at least one ligand is different from the other ligands.
  • every ligand can be different from each other. This is also true in embodiments where a ligand being coordinated to a metal can be linked with other ligands being coordinated to that metal to form a tridentate, tetradentate, pentadentate, or hexadentate ligands.
  • the coordinating ligands are being linked together, all of the ligands can be the same in some embodiments, and at least one of the ligands being linked can be different from the other ligand(s) in some other embodiments.
  • the compound can be used as a phosphorescent sensitizer in an OLED where one or multiple layers in the OLED contains an acceptor in the form of one or more fluorescent and/or delayed fluorescence emitters.
  • the compound can be used as one component of an exciplex to be used as a sensitizer.
  • the compound must be capable of energy transfer to the acceptor and the acceptor will emit the energy or further transfer energy to a final emitter.
  • the acceptor concentrations can range from 0.001% to 100%.
  • the acceptor could be in either the same layer as the phosphorescent sensitizer or in one or more different layers.
  • the acceptor is a TADF emitter.
  • the acceptor is a fluorescent emitter.
  • the emission can arise from any or all of the sensitizer, acceptor, and final emitter.
  • a formulation comprising the compound described herein is also disclosed.
  • the OLED disclosed herein can be incorporated into one or more of a consumer product, an electronic component module, and a lighting panel.
  • the organic layer can be an emissive layer and the compound can be an emissive dopant in some embodiments, while the compound can be a non-emissive dopant in other embodiments.
  • a formulation that comprises the novel compound disclosed herein is described.
  • the formulation can include one or more components selected from the group consisting of a solvent, a host, a hole injection material, hole transport material, electron blocking material, hole blocking material, and an electron transport material, disclosed herein.
  • the present disclosure encompasses any chemical structure comprising the novel compound of the present disclosure, or a monovalent or polyvalent variant thereof.
  • the inventive compound, or a monovalent or polyvalent variant thereof can be a part of a larger chemical structure.
  • Such chemical structure can be selected from the group consisting of a monomer, a polymer, a macromolecule, and a supramolecule (also known as supermolecule).
  • a “monovalent variant of a compound” refers to a moiety that is identical to the compound except that one hydrogen has been removed and replaced with a bond to the rest of the chemical structure.
  • a “polyvalent variant of a compound” refers to a moiety that is identical to the compound except that more than one hydrogen has been removed and replaced with a bond or bonds to the rest of the chemical structure. In the instance of a supramolecule, the inventive compound can also be incorporated into the supramolecule complex without covalent bonds.
  • the materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device.
  • emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present.
  • the materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.
  • a charge transport layer can be doped with conductivity dopants to substantially alter its density of charge carriers, which will in turn alter its conductivity.
  • the conductivity is increased by generating charge carriers in the matrix material, and depending on the type of dopant, a change in the Fermi level of the semiconductor may also be achieved.
  • Hole-transporting layer can be doped by p-type conductivity dopants and n-type conductivity dopants are used in the electron-transporting layer.
  • Non-limiting examples of the conductivity dopants that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP01617493, EP01968131, EP2020694, EP2684932, US20050139810, US20070160905, US20090167167, US2010288362, WO06081780, WO2009003455, WO2009008277, WO2009011327, WO2014009310, US2007252140, US2015060804, US20150123047, and US2012146012.
  • a hole injecting/transporting material to be used in the present disclosure is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material.
  • the material include, but are not limited to: a phthalocyanine or porphyrin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/PSS; a self-assembly monomer derived from compounds such as phosphonic acid and silane derivatives; a metal oxide derivative, such as MoO x ; a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and a cross-linkable compounds.
  • aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures:
  • Each of Ar 1 to Ar 9 is selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine
  • Each Ar may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
  • a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkeny
  • Ar 1 to Ar 9 is independently selected from the group consisting of:
  • k is an integer from 1 to 20;
  • X 101 to X 108 is C (including CH) or N;
  • Z 101 is NAr 1 , O, or S;
  • Ar 1 has the same group defined above.
  • metal complexes used in HIL or HTL include, but are not limited to the following general formula:
  • Met is a metal, which can have an atomic weight greater than 40;
  • (Y 101 -Y 102 ) is a bidentate ligand, Y 101 and Y 102 are independently selected from C, N, O, P, and S;
  • L 101 is an ancillary ligand;
  • k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and
  • k′+k′′ is the maximum number of ligands that may be attached to the metal.
  • (Y 101 -Y 102 ) is a 2-phenylpyridine derivative. In another aspect, (Y 101 -Y 102 ) is a carbene ligand. In another aspect, Met is selected from Ir, Pt, Os, and Zn. In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc + /Fc couple less than about 0.6 V.
  • Non-limiting examples of the HIL and HTL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334, EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701, EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765, JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473, TW201139402, U.S. Ser.
  • An electron blocking layer may be used to reduce the number of electrons and/or excitons that leave the emissive layer.
  • the presence of such a blocking layer in a device may result in substantially higher efficiencies, and/or longer lifetime, as compared to a similar device lacking a blocking layer.
  • a blocking layer may be used to confine emission to a desired region of an OLED.
  • the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than the emitter closest to the EBL interface.
  • the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the EBL interface.
  • the compound used in EBL contains the same molecule or the same functional groups used as one of the hosts described below.
  • the light emitting layer of the organic EL device of the present disclosure preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material.
  • the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant. Any host material may be used with any dopant so long as the triplet criteria is satisfied.
  • metal complexes used as host are preferred to have the following general formula:
  • Met is a metal
  • (Y 103 -Y 104 ) is a bidentate ligand, Y 103 and Y 104 are independently selected from C, N, O, P, and S
  • L 101 is an another ligand
  • k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal
  • k′+k′′ is the maximum number of ligands that may be attached to the metal.
  • the metal complexes are:
  • (O—N) is a bidentate ligand, having metal coordinated to atoms O and N.
  • Met is selected from Ir and Pt.
  • (Y 103 -Y 104 ) is a carbene ligand.
  • the host compound contains at least one of the following groups selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadia
  • Each option within each group may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
  • the host compound contains at least one of the following groups in the molecule:
  • R 101 is selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, and when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above.
  • k is an integer from 0 to 20 or 1 to 20.
  • X 101 to X 108 are independently selected from C (including CH) or N.
  • Z 101 and Z 102 are independently selected from NR 101 , O, or S.
  • Non-limiting examples of the host materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP2034538, EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644, KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919, US20060280965, US20090017330, US20090030202, US20090167162, US20090302743, US20090309488, US20100012931, US20100084966, US20100187984, US2010187984, US2012075273, US2012126221, US2013009543, US2013105787, US2013175519, US2014001446, US20140183503, US20140225088, US2014034914, U.S.
  • One or more additional emitter dopants may be used in conjunction with the compound of the present disclosure.
  • the additional emitter dopants are not particularly limited, and any compounds may be used as long as the compounds are typically used as emitter materials.
  • suitable emitter materials include, but are not limited to, compounds which can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.
  • Non-limiting examples of the emitter materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526, EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907, EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652, KR20120032054, KR20130043460, TW201332980, U.S. Ser. No. 06/699,599, U.S. Ser. No.
  • a hole blocking layer may be used to reduce the number of holes and/or excitons that leave the emissive layer.
  • the presence of such a blocking layer in a device may result in substantially higher efficiencies and/or longer lifetime as compared to a similar device lacking a blocking layer.
  • a blocking layer may be used to confine emission to a desired region of an OLED.
  • the HBL material has a lower HOMO (further from the vacuum level) and/or higher triplet energy than the emitter closest to the HBL interface.
  • the HBL material has a lower HOMO (further from the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the HBL interface.
  • compound used in HBL contains the same molecule or the same functional groups used as host described above.
  • compound used in HBL contains at least one of the following groups in the molecule:
  • Electron transport layer may include a material capable of transporting electrons. Electron transport layer may be intrinsic (undoped), or doped. Doping may be used to enhance conductivity. Examples of the ETL material are not particularly limited, and any metal complexes or organic compounds may be used as long as they are typically used to transport electrons.
  • compound used in ETL contains at least one of the following groups in the molecule:
  • R 101 is selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above.
  • Ar 1 to Ar 3 has the similar definition as Ar's mentioned above.
  • k is an integer from 1 to 20.
  • X 101 to X 108 is selected from C (including CH) or N.
  • the metal complexes used in ETL contains, but not limit to the following general formula:
  • (O—N) or (N—N) is a bidentate ligand, having metal coordinated to atoms O, N or N, N; L 101 is another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal.
  • Non-limiting examples of the ETL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103508940, EP01602648, EP01734038, EP01956007, JP2004-022334, JP2005149918, JP2005-268199, KR0117693, KR20130108183, US20040036077, US20070104977, US2007018155, US20090101870, US20090115316, US20090140637, US20090179554, US2009218940, US2010108990, US2011156017, US2011210320, US2012193612, US2012214993, US2014014925, US2014014927, US20140284580, U.S.
  • the CGL plays an essential role in the performance, which is composed of an n-doped layer and a p-doped layer for injection of electrons and holes, respectively. Electrons and holes are supplied from the CGL and electrodes. The consumed electrons and holes in the CGL are refilled by the electrons and holes injected from the cathode and anode, respectively; then, the bipolar currents reach a steady state gradually.
  • Typical CGL materials include n and p conductivity dopants used in the transport layers.
  • the hydrogen atoms can be partially or fully deuterated.
  • any specifically listed substituent such as, without limitation, methyl, phenyl, pyridyl, etc. may be undeuterated, partially deuterated, and fully deuterated versions thereof.
  • classes of substituents such as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc. also may be undeuterated, partially deuterated, and fully deuterated versions thereof.
  • reaction was monitored by LCMS, after complete consumption of starting material, the reaction mixture was cooled to RT and filtered through Celite. The organic solution was washed with water and aq. sat. NaCl solution, then organic layer was dried over Na 2 SO 4 , filtered, and concentrated. The crude product was subjected to column chromatography on silica gel column using 0-15% EtOAc in Hexane as eluent. Pure fractions were collected and concentrated to dryness to afford pure pale-yellow foam, then it was stirred in 250 mL hexane for 1 hour to get free flow solids and filtered.
  • N-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-N-(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)aniline (17.3 g, 34.8 mmol)
  • 2-bromopyrimidine (16.6 g, 104 mmol)
  • potassium carbonate (19.1 g, 138 mmol) were suspended in the mixture of THF (270 ml) and water (90 ml).
  • the reaction mixture was degassed and heated to 60° C. for 14-18 hours. Reaction was monitored by LCMS, after complete consumption of starting material, the reaction mixture was cooled to RT and 600 mL of water were added.
  • the crude residue was purified on basic alumina column, eluting with a gradient of 0 to 100% dichloromethane in heptane to give desired product with impurities.
  • the material was triturated with a 5 to 1 mixture of dichloromethane in methanol (10 mL) at 45° C., the suspension filtered, and the solid dried under vacuum at 40° C. for 2 hours to give the platinum complex of N-phenyl-3-(pyrimidin-2-yl)-N-(3-(pyrimidin-2-yl)phenyl)aniline (1.8 g, 58% yield) as a dark solid.
  • All devices were fabricated by high vacuum ( ⁇ 10 ⁇ 7 Torr) thermal evaporation.
  • the anode electrode was 80 nm of indium tin oxide (ITO).
  • the cathode electrode consisted of 1 nm of LiQ followed by 100 nm of Al. All devices were encapsulated with a glass lid sealed with an epoxy resin in a nitrogen glove box ( ⁇ 1 ppm of H 2 O and O 2 ) immediately after fabrication, and a moisture getter was incorporated inside the package.
  • the organic stack of the device examples consisted of sequentially, from the ITO surface, 10 nm of LG-101 (available from LG Chem. Inc.) as the hole injection layer (HIL), 40 nm of PPh-TPD as the hole transporting layer (HTL), 5 nm of electron blocking layer comprised of (H-3), 40 nm of emissive layer (EML) comprised of premixed host doped with 3 wt % of the invention compound or comparative compound as the emitter, 35 nm of aDBT-ADN with 35 wt % LiQ as the electron-transport layer (ETL).
  • the premixed host comprises of a mixture of HM1 and HM2 in a weight ratio of 1:1 and was deposited from a single evaporation source.
  • the chemical structures of the compounds used are shown below:
  • Table 1 Provided in Table 1 is a summary of the device data including emission peak wavelength, operating voltage, recorded at 10 mA/cm 2 , and device lifetime (LT95) which is the time for the luminence to decay to 95% of its initial value by aging at 80 mA/cm 2 . All results are normalized to the results of the Comparative example device.

Abstract

Provided are novel metal complexes comprising tetradentate pyrimidine and pyrazine ligands. The organometallic compounds can have the structure ofthat are useful as emitters in OLEDs and when used in OLEDs provides improved device performance. Also provided are formulations comprising these organometallic compounds. Further provided are OLEDs and related consumer products that utilize these organometallic compounds.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • This application claims priority under 35 U.S.C. § 119(e) to U.S. Provisional Application No. 62/986,026, filed on Mar. 6, 2020, and also to U.S. Provisional Application No. 63/082,774, filed on Sep. 24, 2020, the entire contents of both applications are incorporated herein by reference.
    • FIELD
  • The present disclosure generally relates to organometallic compounds and formulations and their various uses including as emitters in devices such as organic light emitting diodes and related electronic devices.
    • BACKGROUND
  • Opto-electronic devices that make use of organic materials are becoming increasingly desirable for various reasons. Many of the materials used to make such devices are relatively inexpensive, so organic opto-electronic devices have the potential for cost advantages over inorganic devices. In addition, the inherent properties of organic materials, such as their flexibility, may make them well suited for particular applications such as fabrication on a flexible substrate. Examples of organic opto-electronic devices include organic light emitting diodes/devices (OLEDs), organic phototransistors, organic photovoltaic cells, and organic photodetectors. For OLEDs, the organic materials may have performance advantages over conventional materials.
  • OLEDs make use of thin organic films that emit light when voltage is applied across the device. OLEDs are becoming an increasingly interesting technology for use in applications such as flat panel displays, illumination, and backlighting.
  • One application for phosphorescent emissive molecules is a full color display. Industry standards for such a display call for pixels adapted to emit particular colors, referred to as “saturated” colors. In particular, these standards call for saturated red, green, and blue pixels. Alternatively, the OLED can be designed to emit white light. In conventional liquid crystal displays emission from a white backlight is filtered using absorption filters to produce red, green and blue emission. The same technique can also be used with OLEDs. The white OLED can be either a single emissive layer (EML) device or a stack structure. Color may be measured using CIE coordinates, which are well known to the art.
    • SUMMARY
  • Provided are novel Pt(II) complexes comprising tetradentate pyrimidine and pyrazine ligands. These complexes are useful as phosphorescent emitters in organic electroluminescent devices.
  • In one aspect, the present disclosure provides a compound of
  • Figure US20210280804A1-20210909-C00002
  • wherein each of X1 and X2 is independently C or N, with at least one being N; each of X3, X4, and X5 is independently C or N; at least one of X3, X4, and X5 is C and at least one is N; L1 and L2 are linkers that can be present, with at least one of them being present and each independently selected from the group consisting of O, S, Se, CRR′, SiRR′, GeRR′, BR, BRR′, NR, alkyl, cycloalkyl, aryl, and heteroaryl when present; RA, RB, RC, and RD each independently represents zero, mono, or up to the maximum allowed number of substitutions to its associated ring; each of R, R′, RA, RB, RC, and RD is independently a hydrogen or a substituent selected from the group consisting of the general substituents defined herein; M is Pt, Pd, Au, Ag, Cu or Zn; and any two adjacent R, R′, RA, RB, RC, and RD can be joined or fused together to form a ring, with the proviso that the compound is not the one shown below:
  • Figure US20210280804A1-20210909-C00003
  • In another aspect, the present disclosure provides a formulation of a compound of Formula I as described herein.
  • In yet another aspect, the present disclosure provides an OLED having an organic layer comprising a compound of Formula I as described herein.
  • In yet another aspect, the present disclosure provides a consumer product comprising an OLED with an organic layer comprising a compound of Formula I as described herein.
    • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 shows an organic light emitting device.
  • FIG. 2 shows an inverted organic light emitting device that does not have a separate electron transport layer.
    •  DETAILED DESCRIPTION A. Terminology
  • Unless otherwise specified, the below terms used herein are defined as follows:
  • As used herein, the term “organic” includes polymeric materials as well as small molecule organic materials that may be used to fabricate organic opto-electronic devices. “Small molecule” refers to any organic material that is not a polymer, and “small molecules” may actually be quite large. Small molecules may include repeat units in some circumstances. For example, using a long chain alkyl group as a substituent does not remove a molecule from the “small molecule” class. Small molecules may also be incorporated into polymers, for example as a pendent group on a polymer backbone or as a part of the backbone. Small molecules may also serve as the core moiety of a dendrimer, which consists of a series of chemical shells built on the core moiety. The core moiety of a dendrimer may be a fluorescent or phosphorescent small molecule emitter. A dendrimer may be a “small molecule,” and it is believed that all dendrimers currently used in the field of OLEDs are small molecules.
  • As used herein, “top” means furthest away from the substrate, while “bottom” means closest to the substrate. Where a first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode may be described as “disposed over” an anode, even though there are various organic layers in between.
  • As used herein, “solution processable” means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form.
  • A ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material. A ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand.
  • As used herein, and as would be generally understood by one skilled in the art, a first “Highest Occupied Molecular Orbital” (HOMO) or “Lowest Unoccupied Molecular Orbital” (LUMO) energy level is “greater than” or “higher than” a second HOMO or LUMO energy level if the first energy level is closer to the vacuum energy level. Since ionization potentials (IP) are measured as a negative energy relative to a vacuum level, a higher HOMO energy level corresponds to an IP having a smaller absolute value (an IP that is less negative). Similarly, a higher LUMO energy level corresponds to an electron affinity (EA) having a smaller absolute value (an EA that is less negative). On a conventional energy level diagram, with the vacuum level at the top, the LUMO energy level of a material is higher than the HOMO energy level of the same material. A “higher” HOMO or LUMO energy level appears closer to the top of such a diagram than a “lower” HOMO or LUMO energy level.
  • As used herein, and as would be generally understood by one skilled in the art, a first work function is “greater than” or “higher than” a second work function if the first work function has a higher absolute value. Because work functions are generally measured as negative numbers relative to vacuum level, this means that a “higher” work function is more negative. On a conventional energy level diagram, with the vacuum level at the top, a “higher” work function is illustrated as further away from the vacuum level in the downward direction. Thus, the definitions of HOMO and LUMO energy levels follow a different convention than work functions.
  • The terms “halo,” “halogen,” and “halide” are used interchangeably and refer to fluorine, chlorine, bromine, and iodine.
  • The term “acyl” refers to a substituted carbonyl radical (C(O)—Rs).
  • The term “ester” refers to a substituted oxycarbonyl (—O—C(O)—Rs or —C(O)—O—Rs) radical.
  • The term “ether” refers to an —ORs radical.
  • The terms “sulfanyl” or “thio-ether” are used interchangeably and refer to a —SRs radical.
  • The term “sulfinyl” refers to a —S(O)—Rs radical.
  • The term “sulfonyl” refers to a —SO2—Rs radical.
  • The term “phosphino” refers to a —P(Rs)3 radical, wherein each Rs can be same or different.
  • The term “silyl” refers to a —Si(Rs)3 radical, wherein each Rs can be same or different.
  • The term “boryl” refers to a —B(Rs)2 radical or its Lewis adduct —B(Rs)3 radical, wherein Rs can be same or different.
  • In each of the above, Rs can be hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, and combination thereof. Preferred Rs is selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, and combination thereof.
  • The term “alkyl” refers to and includes both straight and branched chain alkyl radicals. Preferred alkyl groups are those containing from one to fifteen carbon atoms and includes methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, and the like. Additionally, the alkyl group may be optionally substituted.
  • The term “cycloalkyl” refers to and includes monocyclic, polycyclic, and spiro alkyl radicals. Preferred cycloalkyl groups are those containing 3 to 12 ring carbon atoms and includes cyclopropyl, cyclopentyl, cyclohexyl, bicyclo[3.1.1]heptyl, spiro[4.5]decyl, spiro[5.5]undecyl, adamantyl, and the like. Additionally, the cycloalkyl group may be optionally substituted.
  • The terms “heteroalkyl” or “heterocycloalkyl” refer to an alkyl or a cycloalkyl radical, respectively, having at least one carbon atom replaced by a heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si and Se, preferably, O, S or N. Additionally, the heteroalkyl or heterocycloalkyl group may be optionally substituted.
  • The term “alkenyl” refers to and includes both straight and branched chain alkene radicals. Alkenyl groups are essentially alkyl groups that include at least one carbon-carbon double bond in the alkyl chain. Cycloalkenyl groups are essentially cycloalkyl groups that include at least one carbon-carbon double bond in the cycloalkyl ring. The term “heteroalkenyl” as used herein refers to an alkenyl radical having at least one carbon atom replaced by a heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si, and Se, preferably, O, S, or N. Preferred alkenyl, cycloalkenyl, or heteroalkenyl groups are those containing two to fifteen carbon atoms. Additionally, the alkenyl, cycloalkenyl, or heteroalkenyl group may be optionally substituted.
  • The term “alkynyl” refers to and includes both straight and branched chain alkyne radicals. Alkynyl groups are essentially alkyl groups that include at least one carbon-carbon triple bond in the alkyl chain. Preferred alkynyl groups are those containing two to fifteen carbon atoms. Additionally, the alkynyl group may be optionally substituted.
  • The terms “aralkyl” or “arylalkyl” are used interchangeably and refer to an alkyl group that is substituted with an aryl group. Additionally, the aralkyl group may be optionally substituted.
  • The term “heterocyclic group” refers to and includes aromatic and non-aromatic cyclic radicals containing at least one heteroatom. Optionally the at least one heteroatom is selected from O, S, N, P, B, Si, and Se, preferably, O, S, or N. Hetero-aromatic cyclic radicals may be used interchangeably with heteroaryl. Preferred hetero-non-aromatic cyclic groups are those containing 3 to 7 ring atoms which includes at least one hetero atom, and includes cyclic amines such as morpholino, piperidino, pyrrolidino, and the like, and cyclic ethers/thio-ethers, such as tetrahydrofuran, tetrahydropyran, tetrahydrothiophene, and the like. Additionally, the heterocyclic group may be optionally substituted.
  • The term “aryl” refers to and includes both single-ring aromatic hydrocarbyl groups and polycyclic aromatic ring systems. The polycyclic rings may have two or more rings in which two carbons are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is an aromatic hydrocarbyl group, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. Preferred aryl groups are those containing six to thirty carbon atoms, preferably six to twenty carbon atoms, more preferably six to twelve carbon atoms. Especially preferred is an aryl group having six carbons, ten carbons or twelve carbons. Suitable aryl groups include phenyl, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene, preferably phenyl, biphenyl, triphenyl, triphenylene, fluorene, and naphthalene. Additionally, the aryl group may be optionally substituted.
  • The term “heteroaryl” refers to and includes both single-ring aromatic groups and polycyclic aromatic ring systems that include at least one heteroatom. The heteroatoms include, but are not limited to O, S, N, P, B, Si, and Se. In many instances, O, S, or N are the preferred heteroatoms. Hetero-single ring aromatic systems are preferably single rings with 5 or 6 ring atoms, and the ring can have from one to six heteroatoms. The hetero-polycyclic ring systems can have two or more rings in which two atoms are common to two adjoining rings (the rings are “fused”) wherein at least one of the rings is a heteroaryl, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls. The hetero-polycyclic aromatic ring systems can have from one to six heteroatoms per ring of the polycyclic aromatic ring system. Preferred heteroaryl groups are those containing three to thirty carbon atoms, preferably three to twenty carbon atoms, more preferably three to twelve carbon atoms. Suitable heteroaryl groups include dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine, preferably dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, triazine, benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine, and aza-analogs thereof. Additionally, the heteroaryl group may be optionally substituted.
  • Of the aryl and heteroaryl groups listed above, the groups of triphenylene, naphthalene, anthracene, dibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine, pyrazine, pyrimidine, triazine, and benzimidazole, and the respective aza-analogs of each thereof are of particular interest.
  • The terms alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aralkyl, heterocyclic group, aryl, and heteroaryl, as used herein, are independently unsubstituted, or independently substituted, with one or more general substituents.
  • In many instances, the general substituents are selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
  • In some instances, the preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof.
  • In some instances, the preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, alkoxy, aryloxy, amino, silyl, boryl, aryl, heteroaryl, sulfanyl, and combinations thereof.
  • In yet other instances, the more preferred general substituents are selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, aryl, heteroaryl, and combinations thereof.
  • The terms “substituted” and “substitution” refer to a substituent other than H that is bonded to the relevant position, e.g., a carbon or nitrogen. For example, when R1 represents mono-substitution, then one R1 must be other than H (i.e., a substitution). Similarly, when R1 represents di-substitution, then two of R1 must be other than H. Similarly, when R1 represents zero or no substitution, R1, for example, can be a hydrogen for available valencies of ring atoms, as in carbon atoms for benzene and the nitrogen atom in pyrrole, or simply represents nothing for ring atoms with fully filled valencies, e.g., the nitrogen atom in pyridine. The maximum number of substitutions possible in a ring structure will depend on the total number of available valencies in the ring atoms.
  • As used herein, “combinations thereof” indicates that one or more members of the applicable list are combined to form a known or chemically stable arrangement that one of ordinary skill in the art can envision from the applicable list. For example, an alkyl and deuterium can be combined to form a partial or fully deuterated alkyl group; a halogen and alkyl can be combined to form a halogenated alkyl substituent; and a halogen, alkyl, and aryl can be combined to form a halogenated arylalkyl. In one instance, the term substitution includes a combination of two to four of the listed groups. In another instance, the term substitution includes a combination of two to three groups. In yet another instance, the term substitution includes a combination of two groups. Preferred combinations of substituent groups are those that contain up to fifty atoms that are not hydrogen or deuterium, or those which include up to forty atoms that are not hydrogen or deuterium, or those that include up to thirty atoms that are not hydrogen or deuterium. In many instances, a preferred combination of substituent groups will include up to twenty atoms that are not hydrogen or deuterium.
  • The “aza” designation in the fragments described herein, i.e. aza-dibenzofuran, aza-dibenzothiophene, etc. means that one or more of the C—H groups in the respective aromatic ring can be replaced by a nitrogen atom, for example, and without any limitation, azatriphenylene encompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline. One of ordinary skill in the art can readily envision other nitrogen analogs of the aza-derivatives described above, and all such analogs are intended to be encompassed by the terms as set forth herein.
  • As used herein, “deuterium” refers to an isotope of hydrogen. Deuterated compounds can be readily prepared using methods known in the art. For example, U.S. Pat. No. 8,557,400, Patent Pub. No. WO 2006/095951, and U.S. Pat. Application Pub. No. US 2011/0037057, which are hereby incorporated by reference in their entireties, describe the making of deuterium-substituted organometallic complexes. Further reference is made to Ming Yan, et al., Tetrahedron 2015, 71, 1425-30 and Atzrodt et al., Angew. Chem. Int. Ed. (Reviews) 2007, 46, 7744-65, which are incorporated by reference in their entireties, describe the deuteration of the methylene hydrogens in benzyl amines and efficient pathways to replace aromatic ring hydrogens with deuterium, respectively.
  • It is to be understood that when a molecular fragment is described as being a substituent or otherwise attached to another moiety, its name may be written as if it were a fragment (e.g. phenyl, phenylene, naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g. benzene, naphthalene, dibenzofuran). As used herein, these different ways of designating a substituent or attached fragment are considered to be equivalent.
  • In some instance, a pair of adjacent substituents can be optionally joined or fused into a ring. The preferred ring is a five, six, or seven-membered carbocyclic or heterocyclic ring, includes both instances where the portion of the ring formed by the pair of substituents is saturated and where the portion of the ring formed by the pair of substituents is unsaturated. As used herein, “adjacent” means that the two substituents involved can be on the same ring next to each other, or on two neighboring rings having the two closest available substitutable positions, such as 2, 2′ positions in a biphenyl, or 1, 8 position in a naphthalene, as long as they can form a stable fused ring system.
    • B. The Compounds of the Present Disclosure
  • In one aspect, the present disclosure provides a compound of
  • Figure US20210280804A1-20210909-C00004
  • wherein:
    each of X1 and X2 is independently C or N, with at least one being N;
    each of X3, X4, and X5 is independently C or N;
    at least one of X3, X4, and X5 is C and at least one is N;
    L1 and L2 are linkers that can be present, with at least one of them being present and each independently selected from the group consisting of O, S, Se, CRR′, SiRR′, GeRR′, BR, BRR′, NR, alkyl, cycloalkyl, aryl, and heteroaryl when present;
    RA, RB, RC, and RD each independently represents zero, mono, or up to the maximum allowed number of substitutions to its associated ring;
    each of R, R′, RA, RB, RC, and RD is independently a hydrogen or a substituent selected from the group consisting of the general substituents defined herein;
    • M is Pt, Pd, Au, Ag, Cu or Zn; and
  • any two adjacent R, R′, RA, RB, RC, and RD can be joined or fused together to form a ring,
    with the proviso that the compound is not the one shown below:
  • Figure US20210280804A1-20210909-C00005
  • In some embodiments, each of R, R′, RA, RB, RC, and RD can be independently a hydrogen or a substituent selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof.
  • In some embodiments, X1 can be N and X2 can be C. In some embodiments, X1 can be C and X2 can be N. In some embodiments, X1 and X2 can each be N. In some embodiments, X3 can be N, and X4 and X5 can both be C. In some embodiments, X4 can be N, and X3 and X5 can both be C. In some embodiments, X4 can be C, and X3 and X5 can both be N.
  • In some embodiments, L1 may be absent and L2 can be present. In some embodiments, L2 can be absent and L1 can be present. In some embodiments, L1 and L2 can both be present. In some embodiments, L1 and L2 can each be independently selected from the group consisting of O, S, CRR′, SiRR′, and NR when present. In some embodiments, L1 can be O, CRR′, SiRR′, or NR when present. In some embodiments, L2 can be O or NR when present. In some embodiments, R and R′ can each be independently selected from the group consisting of hydrogen, deuterium, alkyl, heteroalkyl, cycloalkyl, heterocycloalkyl, aryl, heteroaryl, and combinations thereof. In some embodiments, R and R′ can each be independently an alkyl, cycloalkyl, aryl or heteroaryl group. In some embodiments, R can be an aryl or heteroaryl group. In some embodiments, R can be a 6-membered aryl ring.
  • In some embodiments, two adjacent RA substituents can be joined to form a fused 5-membered or 6-membered aromatic ring. In some embodiments, two adjacent RB substituents can be joined to form a fused 5-membered or 6-membered aromatic ring. In some embodiments, two adjacent RC substituents can be joined to form a fused 5-membered or 6-membered aromatic ring. In some embodiments, two adjacent RD substituents can be joined to form a fused 5-membered or 6-membered aromatic ring. In some embodiments, the 5-membered or 6-membered aromatic ring can be selected from the group consisting of benzene, pyridine, pyrimidine, pyridazine, pyrazine, imidazole, pyrazole, pyrrole, oxazole, furan, thiophene, or thiazole. In some embodiments, the 5-membered or 6-membered aromatic ring can be further fused to form a multiple fused ring system.
  • In some embodiments, at least one of RA, RB, RC, and RD can be selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, aryl, heteroaryl, and combinations thereof.
  • In some embodiments, M can be Pt or Pd.
  • In some embodiments, the compound can be selected from the group consisting of:
  • Figure US20210280804A1-20210909-C00006
    Figure US20210280804A1-20210909-C00007
    Figure US20210280804A1-20210909-C00008
  • wherein all the variables are the same as previously defined.
  • In some of the above embodiments, L1 can be O, CRR′, SiRR′, or NR. In some of the above embodiments, L2 can be O or NR. In some of the above embodiments, R and R′ can each be independently selected from the group consisting of hydrogen, deuterium, alkyl, heteroalkyl, cycloalkyl, heterocycloalkyl, aryl, heteroaryl, and combinations thereof. In some of the above embodiments, R can be an aromatic group. In some of the above embodiments, R can be a 6-membered aromatic ring.
  • In some of the above embodiments, two adjacent RA substituents can be joined to form a fused 5-membered or 6-membered aromatic ring. In some of the above embodiments, two adjacent RB substituents can be joined to form a fused 5-membered or 6-membered aromatic ring. In some of the above embodiments, two adjacent RC substituents can be joined to form a fused 5-membered or 6-membered aromatic ring. In some of the above embodiments, two adjacent RD substituents can be joined to form a fused 5-membered or 6-membered aromatic ring.
  • In some of the above embodiments, the 5-membered or 6-membered aromatic ring can be selected from the group consisting of benzene, pyridine, pyrimidine, pyridazine, pyrazine, imidazole, pyrazole, pyrrole, oxazole, furan, thiophene, or thiazole. In some of the above embodiments, the 5-membered or 6-membered aromatic can be further fused to form a multiple fused ring system.
  • In some of the above embodiments, at least one of RA, RB, RC, and RD can be selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, aryl, heteroaryl, and combinations thereof.
  • In some of the above embodiments, M can be Pt or Pd. In some of the above embodiments, M can be Pt.
  • In some of the above embodiments, the compound can be selected from the group consisting of:
  • Figure US20210280804A1-20210909-C00009
    Figure US20210280804A1-20210909-C00010
    Figure US20210280804A1-20210909-C00011
    Figure US20210280804A1-20210909-C00012
  • wherein all the variables are the same as previously defined.
  • In some embodiments, the compound can be selected from the group consisting of:
  • Figure US20210280804A1-20210909-C00013
    Figure US20210280804A1-20210909-C00014
    Figure US20210280804A1-20210909-C00015
    Figure US20210280804A1-20210909-C00016
  • wherein all the variables are the same as previously defined.
  • In some embodiments, the compound can be selected from the group consisting of:
  •
    Compound 1-1, Compound 1-2,
    Compound 1-3, and Compound 1-4
    having the following structure
    Figure US20210280804A1-20210909-C00017
    wherein,
    in Compound 1-1, L2 = NPh,
    in Compound 1-2, L2 = O,
    in Compound 1-3, L2 = CMe2, and
    in Compound 1-4 L2 = SiPh2,
    Compound 2-1, Compound 2-2,
    Compound 2-3, and Compound 2-4
    having the following structure
    Figure US20210280804A1-20210909-C00018
    wherein,
    in Compound 2-1, L2 = Ph,
    in Compound 2-2, L2 = O,
    in Compound 2-3, L2 = CMe2, and
    in Compound 2-4, L2 = SiPh2.,
    Compound 3-1, Compound 3-2,
    Compound 3-3, and Compound 3-4
    having the following structure
    Figure US20210280804A1-20210909-C00019
    wherein,
    in Compound 3-1, L2 = Ph,
    in Compound 3-2, L2 = O,
    in Compound 3-3, L2 = CMe2, and
    in Compound 3-4, L2 = SiPh2.,
    Compound 4-1, Compound 4-2,
    Compound 4-3, and Compound 4-4
    having the following structure
    Figure US20210280804A1-20210909-C00020
    wherein,
    in Compound 4-1, L2 = NPh,
    in Compound 4-2, L2 = O,
    in Compound 4-3, L2 = CMe2, and
    in Compound 4-4, L2 = SiPh2.,
    Compound 5-1, Compound 5-2,
    Compound 5-3, and Compound 5-4
    having the following structure
    Figure US20210280804A1-20210909-C00021
    whereien,
    in Compound 5-1, L2 = NPh,
    in Compound 5-2, L2 = O,
    in Compound 5-3, L2 = CMe2, and
    in Compound 5-4, L2 = SiPh2.,
    Compound 6-1, Compound 6-2,
    Compound 6-3, and Compound 6-4
    having the following structure
    Figure US20210280804A1-20210909-C00022
    wherien,
    in Compound 6-1, L2 = NPh,
    in Compound 6-2, L2 = O,
    in Compound 6-3, L2 = CMe2, and
    in Compound 6-4, L2 = SiPh2.,
    Compound 7-1, Compound 7-2,
    Compound 7-3, and Compound 7-4
    having the following structure
    Figure US20210280804A1-20210909-C00023
    wherein,
    in Compound 7-1, L2 = NPh,
    in Compound 7-2, L2 = O,
    in Compound 7-3, L2 = CMe2, and
    in Compound 7-4, L2 = SiPh2.,
    Compound 8-1, Compound 8-2,
    Compound 8-3, and Compound 8-4
    having the following structure
    Figure US20210280804A1-20210909-C00024
    wherein,
    in Compound 8-1, L2 = NPh,
    in Compound 8-2, L2 = O,
    in Compound 8-3, L2 = CMe2, and
    in Compound 8-4, L2 = SiPh2.,
    Compound 9-1, Compound 9-2,
    Compound 9-3, and Compound 9-4
    having the following structure
    Figure US20210280804A1-20210909-C00025
    wherein,
    in Compound 9-1, L2 = NPh,
    in Compound 9-2, L2 = O,
    in Compound 9-3, L2 = CMe2, and
    in Compound 9-4, L2 = SiPh2.,
    Compound 11-1, Compound 11-2,
    Compound 11-3, and Compound 11-4
    having the following structure
    Figure US20210280804A1-20210909-C00026
    wherein,
    in Compound 11-1, L2 = NPh,
    in Compound 11-2, L2 = O,
    in Compound 11-3, L2 = CMe2, and
    in Compound 11-4, L2 = SiPh2.,
    Compound 12-1, Compound 12-2,
    Compound 12-3, and Compound 12-4
    having the following structure
    Figure US20210280804A1-20210909-C00027
    wherein,
    in Compound 12-1, L2 = NPh,
    in Compound 12-2, L2 = O,
    in Compound 12-3, L2 = CMe2, and
    in Compound 12-4, L2 = SiPh2.,
    Compound 13-1, Compound 13-2,
    Compound 13-3, and Compound 13-4
    having the following structure
    Figure US20210280804A1-20210909-C00028
    wherein,
    in Compound 13-1, L2 = NPh,
    in Compound 13-2, L2 = O,
    in Compound 13-3, L2 = CMe2, and
    in Compound 13-4, L2 = SiPh2.,
    Compound 14-1, Compound 14-2,
    Compound 14-3, and Compound 14-4
    having the following structure
    Figure US20210280804A1-20210909-C00029
    wherein,
    in Compound 14-1, L2 = NPh,
    in Compound 14-2, L2 = O,
    in Compound 14-3, L2 = CMe2, and
    in Compound 14-4, L2 = SiPh2.,
    Compound 15-1, Compound 15-2,
    Compound 15-3, and Compound 15-4
    having the following structure
    Figure US20210280804A1-20210909-C00030
    wherein,
    in Compound 15-1, L2 = NPh,
    in Compound 15-2, L2 = O,
    in Compound 15-3, L2 = CMe2, and
    in Compound 15-4 L2 = SiPh2.,
    Compound 16-1, Compound 16-2,
    Compound 16-3, and Compound 16-4
    having the following structure
    Figure US20210280804A1-20210909-C00031
    wherein,
    in Compound 16-1, L2 = NPh,
    in Compound 16-2, L2 = O,
    in Compound 16-3, L2 = CMe2, and
    in Compound 16-4, L2 = SiPh2.,
    Compound 17-1, Compound 17-2,
    Compound 17-3, and Compound 17-4
    having the following structure
    Figure US20210280804A1-20210909-C00032
    wherein,
    in Compound 17-1, L2 = NPh,
    in Compound 17-2, L2 = O,
    in Compound 17-3, L2 = CMe2, and
    in Compound 17-4, L2 = SiPh2.,
    Compound 18-1, Compound 18-2,
    Compound 18-3, and Compound 18-4
    having the following structure
    Figure US20210280804A1-20210909-C00033
    wherein,
    in Compound 18-1, L2 = NPh,
    in Compound 18-2, L2 = O,
    in Compound 18-3, L2 = CMe2, and
    in Compound 18-4, L2 = SiPh2.,
    Compound 19-1, Compound 19-2,
    Compound 19-3, and Compound 19-4
    having the following structure
    Figure US20210280804A1-20210909-C00034
    wherein,
    in Compound 19-1, L2 = NPh,
    in Compound 19-2, L2 = O,
    in Compound 19-3, L2 = CMe2, and
    in Compound 19-4, L2 = SiPh2.,
    Compound 20-1, Compound 20-2,
    Compound 20-3, and Compound 20-4
    having the following structure
    Figure US20210280804A1-20210909-C00035
    wherein,
    in Compound 20-1, L2 = NPh,
    in Compound 20-2, L2 = O,
    in Compound 20-3, L2 = CMe2, and
    in Compound 20-4, L2 = SiPh2.,
    Compound 21-1, Compound 21-2,
    Compound 21-3, and Compound 21-4
    having the following structure
    Figure US20210280804A1-20210909-C00036
    wherein,
    in Compound 21-1, L2 = NPh,
    in Compound 21-2, L2 = O,
    in Compound 21-3, L2 = CMe2, and
    in Compound 21-4, L2 = SiPh2.,
    Compound 25-1, Compound 25-2,
    Compound 25-3, and Compound 25-4
    having the following structure
    Figure US20210280804A1-20210909-C00037
    wherein,
    in Compound 25-1, L2 = NPh,
    in Compound 25-2, L2 = O,
    in Compound 25-3, L2 = CMe2, and
    in Compound 25-4, L2 = SiPh2.,
    Compound 26-1, Compound 26-2,
    Compound 26-3, and Compound 26-4
    having the following structure
    Figure US20210280804A1-20210909-C00038
    wherein,
    in Compound 26-1, L2 = NPh,
    in Compound 26-2, L2 = O,
    in Compound 26-3, L2 = CMe2, and
    in Compound 26-4, L2 = SiPh2.,
    Compound 27-1, Compound 27-2,
    Compound 27-3, and Compound 27-4
    having the following structure
    Figure US20210280804A1-20210909-C00039
    wherein,
    in Compound 27-1, L2 = NPh,
    in Compound 27-2, L2 = O,
    in Compound 27-3, L2 = CMe2, and
    in Compound 27-4, L2 = SiPh2.,
    Compound 28-1, Compound 28-2,
    Compound 28-3, and Compound 28-4
    having the following structure
    Figure US20210280804A1-20210909-C00040
    wherein,
    in Compound 28-1, L2 = NPh,
    in Compound 28-2, L2 = O,
    in Compound 28-3, L2 = CMe2, and
    in Compound 28-4, L2 = SiPh2.,
    Compound 29-1, Compound 29-2,
    Compound 29-3, and Compound 29-4
    having the following structure
    Figure US20210280804A1-20210909-C00041
    wherein,
    in Compound 29-1, L2 = NPh,
    in Compound 29-2, L2 = O,
    in Compound 29-3, L2 = CMe2, and
    in Compound 29-4, L2 = SiPh2.,
    Compound 31-1, Compound 31-2,
    Compound 31-3, and Compound 31-4
    having the following structure
    Figure US20210280804A1-20210909-C00042
    wherein,
    in Compound 31-1, L2 = NPh,
    in Compound 31-2, L2 = O,
    in Compound 31-3, L2 = CMe2, and
    in Compound 31-4, L2 = SiPh2.,
    Compound 32-1, Compound 32-2,
    Compound 32-3, and Compound 32-4
    having the following structure
    Figure US20210280804A1-20210909-C00043
    wherein,
    in Compound 32-1, L2 = NPh,
    in Compound 32-3, L2 = O,
    in Compound 32-3, L2 = CMe2, and
    in Compound 32-4, L2 = SiPh2.,
    Compound 33-1, Compound 33-2,
    Compound 33-3, and Compound 33-4
    having the following structure
    Figure US20210280804A1-20210909-C00044
    wherein,
    in Compound 33-1, L2 = NPh,
    in Compound 33-2, L2 = O,
    in Compound 33-3, L2 = CMe2, and
    in Compound 33-4, L2 = SiPh2.,
    Compound 34-1, Compound 34-2,
    Compound 34-3, and Compound 34-4
    having the following structure
    Figure US20210280804A1-20210909-C00045
    wherein,
    in Compound 34-1, L2 = NPh,
    in Compound 34-2, L2 = O,
    in Compound 34-3, L2 = CMe2, and
    Compound 34-4, L2 in = SiPh2.,
    Compound 36-1, Compound 36-2,
    Compound 36-3, and Compound 36-4
    having the following structure
    Figure US20210280804A1-20210909-C00046
    wherein,
    in Compound 36-1, L2 = NPh,
    in Compound 36-2, L2 = O,
    in Compound 36-3, L2 = CMe2, and
    in Compound 36-4, L2 = SiPh2.,
    Compound 37-1, Compound 37-2,
    Compound 37-3, and Compound 37-4
    having the following structure
    Figure US20210280804A1-20210909-C00047
    wherein,
    in Compound 37-1, L2 = NPh,
    in Compound 37-2, L2 = O,
    in Compound 37-3, L2 = CMe2, and
    in Compound 37-4, L2 = SiPh2.,
    Compound 38-1, Compound 38-2,
    Compound 38-3, and Compound 38-4
    having the following structure
    Figure US20210280804A1-20210909-C00048
    wherein,
    in Compound 38-1, L2 = NPh,
    in Compound 38-2, L2 = O,
    in Compound 38-3, L2 = CMe2, and
    in Compound 38-4, L2 = SiPh2.,
    Compound 39-1, Compound 39-2,
    Compound 39-3, and Compound 39-4
    having the following structure
    Figure US20210280804A1-20210909-C00049
    wherein,
    in Compound 39-1, L2 = NPh,
    in Compound 39-2, L2 = O,
    in Compound 39-3, L2 = CMe2, and
    in Compound 39-4, L2 = SiPh2.,
    Compound 40-1, Compound 40-2,
    Compound 40-3, and Compound 40-4
    having the following structure
    Figure US20210280804A1-20210909-C00050
    wherein,
    in Compound 40-1, L2 = NPh,
    in Compound 40-2, L2 = O,
    in Compound 40-3, L2 = CMe2, and
    in Compound 40-4, L2 = SiPh2.,
    Compound 40-1, Compound 40-2,
    Compound 40-3, and Compound 40-4
    having the following structure
    Figure US20210280804A1-20210909-C00051
    wherein,
    in Compound 41-1, L2 = NPh,
    in Compound 41-2, L2 = O,
    in Compound 41-3, L2 = CMe2, and
    in Compound 41-4, L2 = SiPh2.,
    Compound 42-1, Compound 42-2,
    Compound 42-3, and Compound 42-4
    having the following structure
    Figure US20210280804A1-20210909-C00052
    wherein,
    in Compound 42-1, L2 = NPh,
    in Compound 42-2, L2 = O,
    in Compound 42-3, L2 = CMe2, and
    in Compound 42-4, L2 = SiPh2.,
    Compound 43-1, Compound 43-2,
    Compound 43-3, and Compound 43-4
    having the following structure
    Figure US20210280804A1-20210909-C00053
    wherein,
    in Compound 43-1, L2 = NPh,
    in Compound 43-2, L2 = O,
    in Compound 43-3, L2 = CMe2, and
    in Compound 43-4, L2 = SiPh2, and
    Compound 44-1, Compound 44-2,
    Compound 44-3, and Compound 44-4
    having the following structure
    Figure US20210280804A1-20210909-C00054
    wherein,
    in Compound 44-1, L2 = NPh,
    in Compound 44-2, L2= O,
    in Compound 44-3, L2 = CMe2, and
    in Compound 44-4, L2 = SiPh2..
    • C. The OLEDs and the Devices of the Present Disclosure
  • In another aspect, the present disclosure also provides an OLED device comprising an organic layer that contains a compound as disclosed in the above compounds section of the present disclosure.
  • In some embodiments, the organic layer may comprise a compound of
  • Figure US20210280804A1-20210909-C00055
  • wherein each of X1 and X2 is independently C or N, with at least one being N; each of X3, X4, and X5 is independently C or N; at least one of X3, X4, and X5 is C and at least one is N; L1 and L2 are linkers that are optionally present, with at least one of them being present and each independently selected from the group consisting of O, S, Se, CRR′, SiRR′, GeRR′, BR, BRR′, NR, alkyl, cycloalkyl, aryl, and heteroaryl when present; RA, RB, RC, and RD each independently represent zero, mono, or up to the maximum allowed number of substitutions to its associated ring; each of R, R′, RA, RB, RC, and RD is independently a hydrogen or a substituent selected from the group consisting of the general substituents defined herein; M is Pt, Pd, Au, Ag, Cu or Zn; and any two adjacent R, R′, RA, RB, RC, and RD can be joined or fused together to form a ring, with the proviso that the compound is not the one shown below:
  • Figure US20210280804A1-20210909-C00056
  • In some embodiments, the organic layer may be an emissive layer and the compound as described herein may be an emissive dopant or a non-emissive dopant.
  • In some embodiments, the organic layer may further comprise a host, wherein the host comprises a triphenylene containing benzo-fused thiophene or benzo-fused furan, wherein any substituent in the host is an unfused substituent independently selected from the group consisting of CnH2n+1, OCnH2n+1, OAr1, N(CnH2n+1)2, N(Ar1)(Ar2), CH═CH—CnH2n+1, C≡CCnH2n+1, Ar1, Ar1—Ar2, CnH2n—Ar1, or no substitution, wherein n is from 1 to 10; and wherein Ar1 and Ar2 are independently selected from the group consisting of benzene, biphenyl, naphthalene, triphenylene, carbazole, and heteroaromatic analogs thereof.
  • In some embodiments, the organic layer may further comprise a host, wherein host comprises at least one chemical moiety selected from the group consisting of naphthalene, fluorene, triphenylene, carbazole, indolocarbazole, dibenzothiphene, dibenzofuran, dibenzoselenophene, 5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene, aza-naphthalene, aza-fluorene, aza-triphenylene, aza-carbazole, aza-indolocarbazole, aza-dibenzothiophene, aza-dibenzofuran, aza-dibenzoselenophene, and aza-(5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene).
  • In some embodiments, the host may be selected from the host group consisting of:
  • Figure US20210280804A1-20210909-C00057
    Figure US20210280804A1-20210909-C00058
    Figure US20210280804A1-20210909-C00059
    Figure US20210280804A1-20210909-C00060
  • and combinations thereof.
  • In some embodiments, the organic layer may further comprise a host, wherein the host comprises a metal complex.
  • In some embodiments, the compound as described herein may be a sensitizer; wherein the device may further comprise an acceptor; and wherein the acceptor may be selected from the group consisting of fluorescent emitter, delayed fluorescence emitter, and combination thereof.
  • In yet another aspect, the OLED of the present disclosure may also comprise an emissive region containing a compound as disclosed in the above compounds section of the present disclosure.
  • In some embodiments, the emissive region may comprise a compound of
  • Figure US20210280804A1-20210909-C00061
  • wherein each of X1 and X2 is independently C or N, with at least one being N; each of X3, X4, and X5 is independently C or N; at least one of X3, X4, and X5 is C and at least one is N; L1 and L2 are linkers that can be present, with at least one of them being present and each independently selected from the group consisting of O, S, Se, CRR′, SiRR′, GeRR′, BR, BRR′, NR, alkyl, cycloalkyl, aryl, and heteroaryl when present; RA, RB, RC, and RD each independently represents zero, mono, or up to the maximum allowed number of substitutions to its associated ring; each of R, R′, RA, RB, RC, and RD is independently a hydrogen or a substituent selected from the group consisting of the general substituents defined herein; M is Pt, Pd, Au, Ag, Cu or Zn; and any two adjacent R, R′, RA, RB, RC, and RD can be joined or fused together to form a ring, with the proviso that the compound is not the one shown below:
  • Figure US20210280804A1-20210909-C00062
  • In some embodiments, at least one of the anode, the cathode, or a new layer disposed over the organic emissive layer functions as an enhancement layer. The enhancement layer comprises a plasmonic material exhibiting surface plasmon resonance that non-radiatively couples to the emitter material and transfers excited state energy from the emitter material to non-radiative mode of surface plasmon polariton. The enhancement layer is provided no more than a threshold distance away from the organic emissive layer, wherein the emitter material has a total non-radiative decay rate constant and a total radiative decay rate constant due to the presence of the enhancement layer and the threshold distance is where the total non-radiative decay rate constant is equal to the total radiative decay rate constant. In some embodiments, the OLED further comprises an outcoupling layer. In some embodiments, the outcoupling layer is disposed over the enhancement layer on the opposite side of the organic emissive layer. In some embodiments, the outcoupling layer is disposed on opposite side of the emissive layer from the enhancement layer but still outcouples energy from the surface plasmon mode of the enhancement layer. The outcoupling layer scatters the energy from the surface plasmon polaritons. In some embodiments this energy is scattered as photons to free space. In other embodiments, the energy is scattered from the surface plasmon mode into other modes of the device such as but not limited to the organic waveguide mode, the substrate mode, or another waveguiding mode. If energy is scattered to the non-free space mode of the OLED other outcoupling schemes could be incorporated to extract that energy to free space. In some embodiments, one or more intervening layer can be disposed between the enhancement layer and the outcoupling layer. The examples for interventing layer(s) can be dielectric materials, including organic, inorganic, perovskites, oxides, and may include stacks and/or mixtures of these materials.
  • The enhancement layer modifies the effective properties of the medium in which the emitter material resides resulting in any or all of the following: a decreased rate of emission, a modification of emission line-shape, a change in emission intensity with angle, a change in the stability of the emitter material, a change in the efficiency of the OLED, and reduced efficiency roll-off of the OLED device. Placement of the enhancement layer on the cathode side, anode side, or on both sides results in OLED devices which take advantage of any of the above-mentioned effects. In addition to the specific functional layers mentioned herein and illustrated in the various OLED examples shown in the figures, the OLEDs according to the present disclosure may include any of the other functional layers often found in OLEDs.
  • The enhancement layer can be comprised of plasmonic materials, optically active metamaterials, or hyperbolic metamaterials. As used herein, a plasmonic material is a material in which the real part of the dielectric constant crosses zero in the visible or ultraviolet region of the electromagnetic spectrum. In some embodiments, the plasmonic material includes at least one metal. In such embodiments the metal may include at least one of Ag, Al, Au, Ir, Pt, Ni, Cu, W, Ta, Fe, Cr, Mg, Ga, Rh, Ti, Ru, Pd, In, Bi, Ca alloys or mixtures of these materials, and stacks of these materials. In general, a metamaterial is a medium composed of different materials where the medium as a whole acts differently than the sum of its material parts. In particular, we define optically active metamaterials as materials which have both negative permittivity and negative permeability. Hyperbolic metamaterials, on the other hand, are anisotropic media in which the permittivity or permeability are of different sign for different spatial directions. Optically active metamaterials and hyperbolic metamaterials are strictly distinguished from many other photonic structures such as Distributed Bragg Reflectors (“DBRs”) in that the medium should appear uniform in the direction of propagation on the length scale of the wavelength of light. Using terminology that one skilled in the art can understand: the dielectric constant of the metamaterials in the direction of propagation can be described with the effective medium approximation. Plasmonic materials and metamaterials provide methods for controlling the propagation of light that can enhance OLED performance in a number of ways.
  • In some embodiments, the enhancement layer is provided as a planar layer. In other embodiments, the enhancement layer has wavelength-sized features that are arranged periodically, quasi-periodically, or randomly, or sub-wavelength-sized features that are arranged periodically, quasi-periodically, or randomly. In some embodiments, the wavelength-sized features and the sub-wavelength-sized features have sharp edges.
  • In some embodiments, the outcoupling layer has wavelength-sized features that are arranged periodically, quasi-periodically, or randomly, or sub-wavelength-sized features that are arranged periodically, quasi-periodically, or randomly. In some embodiments, the outcoupling layer may be composed of a plurality of nanoparticles and in other embodiments the outcoupling layer is composed of a plurality of nanoparticles disposed over a material. In these embodiments the outcoupling may be tunable by at least one of varying a size of the plurality of nanoparticles, varying a shape of the plurality of nanoparticles, changing a material of the plurality of nanoparticles, adjusting a thickness of the material, changing the refractive index of the material or an additional layer disposed on the plurality of nanoparticles, varying a thickness of the enhancement layer, and/or varying the material of the enhancement layer. The plurality of nanoparticles of the device may be formed from at least one of metal, dielectric material, semiconductor materials, an alloy of metal, a mixture of dielectric materials, a stack or layering of one or more materials, and/or a core of one type of material and that is coated with a shell of a different type of material. In some embodiments, the outcoupling layer is composed of at least metal nanoparticles wherein the metal is selected from the group consisting of Ag, Al, Au, Ir, Pt, Ni, Cu, W, Ta, Fe, Cr, Mg, Ga, Rh, Ti, Ru, Pd, In, Bi, Ca, alloys or mixtures of these materials, and stacks of these materials. The plurality of nanoparticles may have additional layer disposed over them. In some embodiments, the polarization of the emission can be tuned using the outcoupling layer. Varying the dimensionality and periodicity of the outcoupling layer can select a type of polarization that is preferentially outcoupled to air. In some embodiments the outcoupling layer also acts as an electrode of the device.
  • In yet another aspect, the present disclosure also provides a consumer product comprising an organic light-emitting device (OLED) having an anode; a cathode; and an organic layer disposed between the anode and the cathode, wherein the organic layer may comprise a compound as disclosed in the above compounds section of the present disclosure.
  • In yet another aspect, the present disclosure also provides a consumer product comprising an organic light-emitting device (OLED) having an anode; a cathode; and an organic layer disposed between the anode and the cathode, wherein the organic layer may comprise a compound as disclosed in the above compounds section of the present disclosure.
  • In some embodiments, the consumer product comprises an organic light-emitting device (OLED) having an anode; a cathode; and an organic layer disposed between the anode and the cathode, wherein the organic layer may comprise a compound of
  • Figure US20210280804A1-20210909-C00063
  • wherein each of X1 and X2 is independently C or N, with at least one being N; each of X3, X4, and X5 is independently C or N; at least one of X3, X4, and X5 is C and at least one is N; L1 and L2 are linkers that can be present, with at least one of them being present and each independently selected from the group consisting of O, S, Se, CRR′, SiRR′, GeRR′, BR, BRR′, NR, alkyl, cycloalkyl, aryl, and heteroaryl when present; RA, RB, RC, and RD each independently represents zero, mono, or up to the maximum allowed number of substitutions to its associated ring; each of R, R′, RA, RB, RC, and RD is independently a hydrogen or a substituent selected from the group consisting of the general substituents defined herein; M is Pt, Pd, Au, Ag, Cu or Zn; and any two adjacent R, R′, RA, RB, RC, and RD can be joined or fused together to form a ring, with the proviso that the compound is not the one shown below:
  • Figure US20210280804A1-20210909-C00064
  • In some embodiments, the consumer product can be one of a flat panel display, a computer monitor, a medical monitor, a television, a billboard, a light for interior or exterior illumination and/or signaling, a heads-up display, a fully or partially transparent display, a flexible display, a laser printer, a telephone, a cell phone, tablet, a phablet, a personal digital assistant (PDA), a wearable device, a laptop computer, a digital camera, a camcorder, a viewfinder, a micro-display that is less than 2 inches diagonal, a 3-D display, a virtual reality or augmented reality display, a vehicle, a video wall comprising multiple displays tiled together, a theater or stadium screen, a light therapy device, and a sign.
  • Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an “exciton,” which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.
  • Several OLED materials and configurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated herein by reference in their entirety.
  • The initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.
  • More recently, OLEDs having emissive materials that emit light from triplet states (“phosphorescence”) have been demonstrated. Baldo et al., “Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices,” Nature, vol. 395, 151-154, 1998; (“Baldo-I”) and Baldo et al., “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference.
  • FIG. 1 shows an organic light emitting device 100. The figures are not necessarily drawn to scale. Device 100 may include a substrate 110, an anode 115, a hole injection layer 120, a hole transport layer 125, an electron blocking layer 130, an emissive layer 135, a hole blocking layer 140, an electron transport layer 145, an electron injection layer 150, a protective layer 155, a cathode 160, and a barrier layer 170. Cathode 160 is a compound cathode having a first conductive layer 162 and a second conductive layer 164. Device 100 may be fabricated by depositing the layers described, in order. The properties and functions of these various layers, as well as example materials, are described in more detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which are incorporated by reference.
  • More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F4-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety.
  • FIG. 2 shows an inverted OLED 200. The device includes a substrate 210, a cathode 215, an emissive layer 220, a hole transport layer 225, and an anode 230. Device 200 may be fabricated by depositing the layers described, in order. Because the most common OLED configuration has a cathode disposed over the anode, and device 200 has cathode 215 disposed under anode 230, device 200 may be referred to as an “inverted” OLED. Materials similar to those described with respect to device 100 may be used in the corresponding layers of device 200. FIG. 2 provides one example of how some layers may be omitted from the structure of device 100.
  • The simple layered structure illustrated in FIGS. 1 and 2 is provided by way of non-limiting example, and it is understood that embodiments of the present disclosure may be used in connection with a wide variety of other structures. The specific materials and structures described are exemplary in nature, and other materials and structures may be used. Functional OLEDs may be achieved by combining the various layers described in different ways, or layers may be omitted entirely, based on design, performance, and cost factors. Other layers not specifically described may also be included. Materials other than those specifically described may be used. Although many of the examples provided herein describe various layers as comprising a single material, it is understood that combinations of materials, such as a mixture of host and dopant, or more generally a mixture, may be used. Also, the layers may have various sublayers. The names given to the various layers herein are not intended to be strictly limiting. For example, in device 200, hole transport layer 225 transports holes and injects holes into emissive layer 220, and may be described as a hole transport layer or a hole injection layer. In one embodiment, an OLED may be described as having an “organic layer” disposed between a cathode and an anode. This organic layer may comprise a single layer, or may further comprise multiple layers of different organic materials as described, for example, with respect to FIGS. 1 and 2.
  • Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in FIGS. 1 and 2. For example, the substrate may include an angled reflective surface to improve out-coupling, such as a mesa structure as described in U.S. Pat. No. 6,091,195 to Forrest et al., and/or a pit structure as described in U.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated by reference in their entireties.
  • Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. Pat. No. 7,431,968, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink-jet and organic vapor jet printing (OVJP). Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons are a preferred range. Materials with asymmetric structures may have better solution processability than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.
  • Devices fabricated in accordance with embodiments of the present disclosure may further optionally comprise a barrier layer. One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc. The barrier layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge. The barrier layer may comprise a single layer, or multiple layers. The barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer. The barrier layer may incorporate an inorganic or an organic compound or both. The preferred barrier layer comprises a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporated by reference in their entireties. To be considered a “mixture”, the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time. The weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95. The polymeric material and the non-polymeric material may be created from the same precursor material. In one example, the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon.
  • Devices fabricated in accordance with embodiments of the present disclosure can be incorporated into a wide variety of electronic component modules (or units) that can be incorporated into a variety of electronic products or intermediate components. Examples of such electronic products or intermediate components include display screens, lighting devices such as discrete light source devices or lighting panels, etc. that can be utilized by the end-user product manufacturers. Such electronic component modules can optionally include the driving electronics and/or power source(s). Devices fabricated in accordance with embodiments of the present disclosure can be incorporated into a wide variety of consumer products that have one or more of the electronic component modules (or units) incorporated therein. A consumer product comprising an OLED that includes the compound of the present disclosure in the organic layer in the OLED is disclosed. Such consumer products would include any kind of products that include one or more light source(s) and/or one or more of some type of visual displays. Some examples of such consumer products include flat panel displays, curved displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads-up displays, fully or partially transparent displays, flexible displays, rollable displays, foldable displays, stretchable displays, laser printers, telephones, mobile phones, tablets, phablets, personal digital assistants (PDAs), wearable devices, laptop computers, digital cameras, camcorders, viewfinders, micro-displays (displays that are less than 2 inches diagonal), 3-D displays, virtual reality or augmented reality displays, vehicles, video walls comprising multiple displays tiled together, theater or stadium screen, a light therapy device, and a sign. Various control mechanisms may be used to control devices fabricated in accordance with the present disclosure, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 degrees C. to 30 degrees C., and more preferably at room temperature (20-25° C.), but could be used outside this temperature range, for example, from −40 degree C. to +80° C.
  • More details on OLEDs, and the definitions described above, can be found in U.S. Pat. No. 7,279,704, which is incorporated herein by reference in its entirety.
  • The materials and structures described herein may have applications in devices other than OLEDs. For example, other optoelectronic devices such as organic solar cells and organic photodetectors may employ the materials and structures. More generally, organic devices, such as organic transistors, may employ the materials and structures.
  • In some embodiments, the OLED has one or more characteristics selected from the group consisting of being flexible, being rollable, being foldable, being stretchable, and being curved. In some embodiments, the OLED is transparent or semi-transparent. In some embodiments, the OLED further comprises a layer comprising carbon nanotubes.
  • In some embodiments, the OLED further comprises a layer comprising a delayed fluorescent emitter. In some embodiments, the OLED comprises a RGB pixel arrangement or white plus color filter pixel arrangement. In some embodiments, the OLED is a mobile device, a hand held device, or a wearable device. In some embodiments, the OLED is a display panel having less than 10 inch diagonal or 50 square inch area. In some embodiments, the OLED is a display panel having at least 10 inch diagonal or 50 square inch area. In some embodiments, the OLED is a lighting panel.
  • In some embodiments, the compound can be an emissive dopant. In some embodiments, the compound can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence; see, e.g., U.S. application Ser. No. 15/700,352, which is hereby incorporated by reference in its entirety), triplet-triplet annihilation, or combinations of these processes. In some embodiments, the emissive dopant can be a racemic mixture, or can be enriched in one enantiomer. In some embodiments, the compound can be homoleptic (each ligand is the same). In some embodiments, the compound can be heteroleptic (at least one ligand is different from others). When there are more than one ligand coordinated to a metal, the ligands can all be the same in some embodiments. In some other embodiments, at least one ligand is different from the other ligands. In some embodiments, every ligand can be different from each other. This is also true in embodiments where a ligand being coordinated to a metal can be linked with other ligands being coordinated to that metal to form a tridentate, tetradentate, pentadentate, or hexadentate ligands. Thus, where the coordinating ligands are being linked together, all of the ligands can be the same in some embodiments, and at least one of the ligands being linked can be different from the other ligand(s) in some other embodiments.
  • In some embodiments, the compound can be used as a phosphorescent sensitizer in an OLED where one or multiple layers in the OLED contains an acceptor in the form of one or more fluorescent and/or delayed fluorescence emitters. In some embodiments, the compound can be used as one component of an exciplex to be used as a sensitizer. As a phosphorescent sensitizer, the compound must be capable of energy transfer to the acceptor and the acceptor will emit the energy or further transfer energy to a final emitter. The acceptor concentrations can range from 0.001% to 100%. The acceptor could be in either the same layer as the phosphorescent sensitizer or in one or more different layers. In some embodiments, the acceptor is a TADF emitter. In some embodiments, the acceptor is a fluorescent emitter. In some embodiments, the emission can arise from any or all of the sensitizer, acceptor, and final emitter.
  • According to another aspect, a formulation comprising the compound described herein is also disclosed.
  • The OLED disclosed herein can be incorporated into one or more of a consumer product, an electronic component module, and a lighting panel. The organic layer can be an emissive layer and the compound can be an emissive dopant in some embodiments, while the compound can be a non-emissive dopant in other embodiments.
  • In yet another aspect of the present disclosure, a formulation that comprises the novel compound disclosed herein is described. The formulation can include one or more components selected from the group consisting of a solvent, a host, a hole injection material, hole transport material, electron blocking material, hole blocking material, and an electron transport material, disclosed herein.
  • The present disclosure encompasses any chemical structure comprising the novel compound of the present disclosure, or a monovalent or polyvalent variant thereof. In other words, the inventive compound, or a monovalent or polyvalent variant thereof, can be a part of a larger chemical structure. Such chemical structure can be selected from the group consisting of a monomer, a polymer, a macromolecule, and a supramolecule (also known as supermolecule). As used herein, a “monovalent variant of a compound” refers to a moiety that is identical to the compound except that one hydrogen has been removed and replaced with a bond to the rest of the chemical structure. As used herein, a “polyvalent variant of a compound” refers to a moiety that is identical to the compound except that more than one hydrogen has been removed and replaced with a bond or bonds to the rest of the chemical structure. In the instance of a supramolecule, the inventive compound can also be incorporated into the supramolecule complex without covalent bonds.
    • D. Combination of the Compounds of the Present Disclosure with Other Materials
  • The materials described herein as useful for a particular layer in an organic light emitting device may be used in combination with a wide variety of other materials present in the device. For example, emissive dopants disclosed herein may be used in conjunction with a wide variety of hosts, transport layers, blocking layers, injection layers, electrodes and other layers that may be present. The materials described or referred to below are non-limiting examples of materials that may be useful in combination with the compounds disclosed herein, and one of skill in the art can readily consult the literature to identify other materials that may be useful in combination.
    • a) Conductivity Dopants:
  • A charge transport layer can be doped with conductivity dopants to substantially alter its density of charge carriers, which will in turn alter its conductivity. The conductivity is increased by generating charge carriers in the matrix material, and depending on the type of dopant, a change in the Fermi level of the semiconductor may also be achieved. Hole-transporting layer can be doped by p-type conductivity dopants and n-type conductivity dopants are used in the electron-transporting layer.
  • Non-limiting examples of the conductivity dopants that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP01617493, EP01968131, EP2020694, EP2684932, US20050139810, US20070160905, US20090167167, US2010288362, WO06081780, WO2009003455, WO2009008277, WO2009011327, WO2014009310, US2007252140, US2015060804, US20150123047, and US2012146012.
  • Figure US20210280804A1-20210909-C00065
    Figure US20210280804A1-20210909-C00066
    • b) HIL/HTL:
  • A hole injecting/transporting material to be used in the present disclosure is not particularly limited, and any compound may be used as long as the compound is typically used as a hole injecting/transporting material. Examples of the material include, but are not limited to: a phthalocyanine or porphyrin derivative; an aromatic amine derivative; an indolocarbazole derivative; a polymer containing fluorohydrocarbon; a polymer with conductivity dopants; a conducting polymer, such as PEDOT/PSS; a self-assembly monomer derived from compounds such as phosphonic acid and silane derivatives; a metal oxide derivative, such as MoOx; a p-type semiconducting organic compound, such as 1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and a cross-linkable compounds.
  • Examples of aromatic amine derivatives used in HIL or HTL include, but not limit to the following general structures:
  • Figure US20210280804A1-20210909-C00067
  • Each of Ar1 to Ar9 is selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each Ar may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
  • In one aspect, Ar1 to Ar9 is independently selected from the group consisting of:
  • Figure US20210280804A1-20210909-C00068
  • wherein k is an integer from 1 to 20; X101 to X108 is C (including CH) or N; Z101 is NAr1, O, or S; Ar1 has the same group defined above.
  • Examples of metal complexes used in HIL or HTL include, but are not limited to the following general formula:
  • Figure US20210280804A1-20210909-C00069
  • wherein Met is a metal, which can have an atomic weight greater than 40; (Y101-Y102) is a bidentate ligand, Y101 and Y102 are independently selected from C, N, O, P, and S; L101 is an ancillary ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.
  • In one aspect, (Y101-Y102) is a 2-phenylpyridine derivative. In another aspect, (Y101-Y102) is a carbene ligand. In another aspect, Met is selected from Ir, Pt, Os, and Zn. In a further aspect, the metal complex has a smallest oxidation potential in solution vs. Fc+/Fc couple less than about 0.6 V.
  • Non-limiting examples of the HIL and HTL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334, EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701, EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765, JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473, TW201139402, U.S. Ser. No. 06/517,957, US20020158242, US20030162053, US20050123751, US20060182993, US20060240279, US20070145888, US20070181874, US20070278938, US20080014464, US20080091025, US20080106190, US20080124572, US20080145707, US20080220265, US20080233434, US20080303417, US2008107919, US20090115320, US20090167161, US2009066235, US2011007385, US20110163302, US2011240968, US2011278551, US2012205642, US2013241401, US20140117329, US2014183517, U.S. Pat. Nos. 5,061,569, 5,639,914, WO05075451, WO07125714, WO08023550, WO08023759, WO2009145016, WO2010061824, WO2011075644, WO2012177006, WO2013018530, WO2013039073, WO2013087142, WO2013118812, WO2013120577, WO2013157367, WO2013175747, WO2014002873, WO2014015935, WO2014015937, WO2014030872 WO2014030921 WO2014034791 WO2014104514 WO2014157018.
  • Figure US20210280804A1-20210909-C00070
    Figure US20210280804A1-20210909-C00071
    Figure US20210280804A1-20210909-C00072
    Figure US20210280804A1-20210909-C00073
    Figure US20210280804A1-20210909-C00074
    Figure US20210280804A1-20210909-C00075
    Figure US20210280804A1-20210909-C00076
    Figure US20210280804A1-20210909-C00077
    • c) EBL:
  • An electron blocking layer (EBL) may be used to reduce the number of electrons and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies, and/or longer lifetime, as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than the emitter closest to the EBL interface. In some embodiments, the EBL material has a higher LUMO (closer to the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the EBL interface. In one aspect, the compound used in EBL contains the same molecule or the same functional groups used as one of the hosts described below.
    • d) Hosts:
  • The light emitting layer of the organic EL device of the present disclosure preferably contains at least a metal complex as light emitting material, and may contain a host material using the metal complex as a dopant material. Examples of the host material are not particularly limited, and any metal complexes or organic compounds may be used as long as the triplet energy of the host is larger than that of the dopant. Any host material may be used with any dopant so long as the triplet criteria is satisfied.
  • Examples of metal complexes used as host are preferred to have the following general formula:
  • Figure US20210280804A1-20210909-C00078
  • wherein Met is a metal; (Y103-Y104) is a bidentate ligand, Y103 and Y104 are independently selected from C, N, O, P, and S; L101 is an another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal; and k′+k″ is the maximum number of ligands that may be attached to the metal.
  • In one aspect, the metal complexes are:
  • Figure US20210280804A1-20210909-C00079
  • wherein (O—N) is a bidentate ligand, having metal coordinated to atoms O and N.
  • In another aspect, Met is selected from Ir and Pt. In a further aspect, (Y103-Y104) is a carbene ligand.
  • In one aspect, the host compound contains at least one of the following groups selected from the group consisting of aromatic hydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene, perylene, and azulene; the group consisting of aromatic heterocyclic compounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene, benzoselenophene, carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine, thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine; and the group consisting of 2 to 10 cyclic structural units which are groups of the same type or different types selected from the aromatic hydrocarbon cyclic group and the aromatic heterocyclic group and are bonded to each other directly or via at least one of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom, chain structural unit and the aliphatic cyclic group. Each option within each group may be unsubstituted or may be substituted by a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
  • In one aspect, the host compound contains at least one of the following groups in the molecule:
  • Figure US20210280804A1-20210909-C00080
    Figure US20210280804A1-20210909-C00081
  • wherein R101 is selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, and when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. k is an integer from 0 to 20 or 1 to 20. X101 to X108 are independently selected from C (including CH) or N. Z101 and Z102 are independently selected from NR101, O, or S.
  • Non-limiting examples of the host materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: EP2034538, EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644, KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919, US20060280965, US20090017330, US20090030202, US20090167162, US20090302743, US20090309488, US20100012931, US20100084966, US20100187984, US2010187984, US2012075273, US2012126221, US2013009543, US2013105787, US2013175519, US2014001446, US20140183503, US20140225088, US2014034914, U.S. Pat. No. 7,154,114, WO2001039234, WO2004093207, WO2005014551, WO2005089025, WO2006072002, WO2006114966, WO2007063754, WO2008056746, WO2009003898, WO2009021126, WO2009063833, WO2009066778, WO2009066779, WO2009086028, WO2010056066, WO2010107244, WO2011081423, WO2011081431, WO2011086863, WO2012128298, WO2012133644, WO2012133649, WO2013024872, WO2013035275, WO2013081315, WO2013191404, WO2014142472, US20170263869, US20160163995, U.S. Pat. No. 9,466,803,
  • Figure US20210280804A1-20210909-C00082
    Figure US20210280804A1-20210909-C00083
    Figure US20210280804A1-20210909-C00084
    Figure US20210280804A1-20210909-C00085
    Figure US20210280804A1-20210909-C00086
    Figure US20210280804A1-20210909-C00087
    Figure US20210280804A1-20210909-C00088
    Figure US20210280804A1-20210909-C00089
    Figure US20210280804A1-20210909-C00090
    Figure US20210280804A1-20210909-C00091
    Figure US20210280804A1-20210909-C00092
    Figure US20210280804A1-20210909-C00093
    Figure US20210280804A1-20210909-C00094
    • e) Additional Emitters:
  • One or more additional emitter dopants may be used in conjunction with the compound of the present disclosure. Examples of the additional emitter dopants are not particularly limited, and any compounds may be used as long as the compounds are typically used as emitter materials. Examples of suitable emitter materials include, but are not limited to, compounds which can produce emissions via phosphorescence, fluorescence, thermally activated delayed fluorescence, i.e., TADF (also referred to as E-type delayed fluorescence), triplet-triplet annihilation, or combinations of these processes.
  • Non-limiting examples of the emitter materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526, EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907, EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652, KR20120032054, KR20130043460, TW201332980, U.S. Ser. No. 06/699,599, U.S. Ser. No. 06/916,554, US20010019782, US20020034656, US20030068526, US20030072964, US20030138657, US20050123788, US20050244673, US2005123791, US2005260449, US20060008670, US20060065890, US20060127696, US20060134459, US20060134462, US20060202194, US20060251923, US20070034863, US20070087321, US20070103060, US20070111026, US20070190359, US20070231600, US2007034863, US2007104979, US2007104980, US2007138437, US2007224450, US2007278936, US20080020237, US20080233410, US20080261076, US20080297033, US200805851, US2008161567, US2008210930, US20090039776, US20090108737, US20090115322, US20090179555, US2009085476, US2009104472, US20100090591, US20100148663, US20100244004, US20100295032, US2010102716, US2010105902, US2010244004, US2010270916, US20110057559, US20110108822, US20110204333, US2011215710, US2011227049, US2011285275, US2012292601, US20130146848, US2013033172, US2013165653, US2013181190, US2013334521, US20140246656, US2014103305, U.S. Pat. Nos. 6,303,238, 6,413,656, 6,653,654, 6,670,645, 6,687,266, 6,835,469, 6,921,915, 7,279,704, 7,332,232, 7,378,162, 7,534,505, 7,675,228, 7,728,137, 7,740,957, 7,759,489, 7,951,947, 8,067,099, 8,592,586, 8,871,361, WO06081973, WO06121811, WO07018067, WO07108362, WO07115970, WO07115981, WO08035571, WO2002015645, WO2003040257, WO2005019373, WO2006056418, WO2008054584, WO2008078800, WO2008096609, WO2008101842, WO2009000673, WO2009050281, WO2009100991, WO2010028151, WO2010054731, WO2010086089, WO2010118029, WO2011044988, WO2011051404, WO2011107491, WO2012020327, WO2012163471, WO2013094620, WO2013107487, WO2013174471, WO2014007565, WO2014008982, WO2014023377, WO2014024131, WO2014031977, WO2014038456, WO2014112450.
  • Figure US20210280804A1-20210909-C00095
    Figure US20210280804A1-20210909-C00096
    Figure US20210280804A1-20210909-C00097
    Figure US20210280804A1-20210909-C00098
    Figure US20210280804A1-20210909-C00099
    Figure US20210280804A1-20210909-C00100
    Figure US20210280804A1-20210909-C00101
    Figure US20210280804A1-20210909-C00102
    Figure US20210280804A1-20210909-C00103
    Figure US20210280804A1-20210909-C00104
    Figure US20210280804A1-20210909-C00105
    Figure US20210280804A1-20210909-C00106
    Figure US20210280804A1-20210909-C00107
    Figure US20210280804A1-20210909-C00108
    Figure US20210280804A1-20210909-C00109
    Figure US20210280804A1-20210909-C00110
    Figure US20210280804A1-20210909-C00111
    Figure US20210280804A1-20210909-C00112
    Figure US20210280804A1-20210909-C00113
    Figure US20210280804A1-20210909-C00114
    Figure US20210280804A1-20210909-C00115
    Figure US20210280804A1-20210909-C00116
    Figure US20210280804A1-20210909-C00117
    • f) HBL:
  • A hole blocking layer (HBL) may be used to reduce the number of holes and/or excitons that leave the emissive layer. The presence of such a blocking layer in a device may result in substantially higher efficiencies and/or longer lifetime as compared to a similar device lacking a blocking layer. Also, a blocking layer may be used to confine emission to a desired region of an OLED. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and/or higher triplet energy than the emitter closest to the HBL interface. In some embodiments, the HBL material has a lower HOMO (further from the vacuum level) and/or higher triplet energy than one or more of the hosts closest to the HBL interface.
  • In one aspect, compound used in HBL contains the same molecule or the same functional groups used as host described above.
  • In another aspect, compound used in HBL contains at least one of the following groups in the molecule:
  • Figure US20210280804A1-20210909-C00118
  • wherein k is an integer from 1 to 20; L101 is another ligand, k′ is an integer from 1 to 3.
    • g) ETL:
  • Electron transport layer (ETL) may include a material capable of transporting electrons. Electron transport layer may be intrinsic (undoped), or doped. Doping may be used to enhance conductivity. Examples of the ETL material are not particularly limited, and any metal complexes or organic compounds may be used as long as they are typically used to transport electrons.
  • In one aspect, compound used in ETL contains at least one of the following groups in the molecule:
  • Figure US20210280804A1-20210909-C00119
  • wherein R101 is selected from the group consisting of hydrogen, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, when it is aryl or heteroaryl, it has the similar definition as Ar's mentioned above. Ar1 to Ar3 has the similar definition as Ar's mentioned above. k is an integer from 1 to 20. X101 to X108 is selected from C (including CH) or N.
  • In another aspect, the metal complexes used in ETL contains, but not limit to the following general formula:
  • Figure US20210280804A1-20210909-C00120
  • wherein (O—N) or (N—N) is a bidentate ligand, having metal coordinated to atoms O, N or N, N; L101 is another ligand; k′ is an integer value from 1 to the maximum number of ligands that may be attached to the metal.
  • Non-limiting examples of the ETL materials that may be used in an OLED in combination with materials disclosed herein are exemplified below together with references that disclose those materials: CN103508940, EP01602648, EP01734038, EP01956007, JP2004-022334, JP2005149918, JP2005-268199, KR0117693, KR20130108183, US20040036077, US20070104977, US2007018155, US20090101870, US20090115316, US20090140637, US20090179554, US2009218940, US2010108990, US2011156017, US2011210320, US2012193612, US2012214993, US2014014925, US2014014927, US20140284580, U.S. Pat. Nos. 6,656,612, 8,415,031, WO2003060956, WO2007111263, WO2009148269, WO2010067894, WO2010072300, WO2011074770, WO2011105373, WO2013079217, WO2013145667, WO2013180376, WO2014104499, WO2014104535,
  • Figure US20210280804A1-20210909-C00121
    Figure US20210280804A1-20210909-C00122
    Figure US20210280804A1-20210909-C00123
    Figure US20210280804A1-20210909-C00124
    Figure US20210280804A1-20210909-C00125
    Figure US20210280804A1-20210909-C00126
    Figure US20210280804A1-20210909-C00127
    Figure US20210280804A1-20210909-C00128
    Figure US20210280804A1-20210909-C00129
    • h) Charge Generation Layer (CGL)
  • In tandem or stacked OLEDs, the CGL plays an essential role in the performance, which is composed of an n-doped layer and a p-doped layer for injection of electrons and holes, respectively. Electrons and holes are supplied from the CGL and electrodes. The consumed electrons and holes in the CGL are refilled by the electrons and holes injected from the cathode and anode, respectively; then, the bipolar currents reach a steady state gradually. Typical CGL materials include n and p conductivity dopants used in the transport layers.
  • In any above-mentioned compounds used in each layer of the OLED device, the hydrogen atoms can be partially or fully deuterated. Thus, any specifically listed substituent, such as, without limitation, methyl, phenyl, pyridyl, etc. may be undeuterated, partially deuterated, and fully deuterated versions thereof. Similarly, classes of substituents such as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc. also may be undeuterated, partially deuterated, and fully deuterated versions thereof.
  • It is understood that the various embodiments described herein are by way of example only and are not intended to limit the scope of the invention. For example, many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the invention. The present invention as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. It is understood that various theories as to why the invention works are not intended to be limiting.
    • E. Experimental Section Synthesis of Exemplary Compounds
  • Figure US20210280804A1-20210909-C00130
    • Synthesis of 3-bromo-N-(3-bromophenyl)-N-phenylaniline
  • A solution of 1,3-dibromobenzene (62.5 g, 265 mmol) and aniline (8.18 g, 88 mmol) in toluene (350.0 ml, 0.25 molar) was degassed, then sodium 2-methylpropan-2-olate (25.4 g, 264 mmol), Pd2(dba)3 (3.80 g, 6.61 mmol) and DPPF (3.94 g, 7.11 mmol) were added. The reaction mixture was heated to reflux at 110° C. for 12 hours. Reaction was monitored by LCMS; after complete consumption of starting material, the reaction mixture was cooled to room temperature (RT), 400 mL of EtOAc were added and the mixture was stirred at RT for 10 min, filtered, and evaporated. The crude product was chromatographed on silica gel column, using 0-1.5% EtOAc in hexane as eluent. Pure fractions were collected and concentrated to dryness to afford pure white solid 3-bromo-N-(3-bromophenyl)-N-phenylaniline (42.4 g, 48.3% yield).
    • Synthesis of N-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-N-(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl) phenyl) aniline
  • 3,3′-Bromo-N-(3-bromophenyl)-N-phenylaniline (19.7 g, 48.9 mmol) 4,4,4′,4′,5,5,5′,5′-octamethyl-2,2′-bi(1,3,2-dioxaborolane) (31.1 g, 122 mmol) and potassium acetate (19.6 g, 200 mmol) were suspended in dioxane (300 ml), the reaction mixture was degassed and XPhos Pd G3 (4.12 g, 4.87 mmol) was added. The reaction mixture was heated to reflux at 100° C. for 4-6 hours. Reaction was monitored by LCMS, after complete consumption of starting material, the reaction mixture was cooled to RT and filtered through Celite. The organic solution was washed with water and aq. sat. NaCl solution, then organic layer was dried over Na2SO4, filtered, and concentrated. The crude product was subjected to column chromatography on silica gel column using 0-15% EtOAc in Hexane as eluent. Pure fractions were collected and concentrated to dryness to afford pure pale-yellow foam, then it was stirred in 250 mL hexane for 1 hour to get free flow solids and filtered. The solid product was dried in vacuo to afford a very pale yellow solid (17.30 g, 71.2% yield) N-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-N-(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)aniline.
    • Synthesis of N-phenyl-3-(pyrimidin-2-yl)-N-(3-(pyrimidin-2-yl) phenyl) aniline
  • N-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-N-(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)aniline (17.3 g, 34.8 mmol), 2-bromopyrimidine (16.6 g, 104 mmol), and potassium carbonate (19.1 g, 138 mmol) were suspended in the mixture of THF (270 ml) and water (90 ml). The reaction mixture was degassed and heated to 60° C. for 14-18 hours. Reaction was monitored by LCMS, after complete consumption of starting material, the reaction mixture was cooled to RT and 600 mL of water were added. The mixture was extracted with 3×200 mL EtOAc. The combined organic layer was washed with 500 mL of saturated NaCl solution, then organic layer was dried over Na2SO4, filtered, and concentrated. The crude product was subjected to column chromatography on silica gel column, with 0-55% EtOAc/Hexane as eluent providing pure off-white solid (5.47 g, 53.2% yield) with purity>99.7%.
    • Platinum Complex of N-phenyl-3-(pyrimidin-2-yl)-N-(3-(pyrimidin-2-yl) phenyl)aniline (Compound 1)
  • A mixture of N-phenyl-3-(pyrimidin-2-yl)-N-(3-(pyrimidin-2-yl)phenyl)aniline (2.0 g, 4.98 mmol, 1.0 equiv) and dichloro(1,5-cyclooctadiene)platinum(II) (1.86 g, 4.98 mmol, 1.0 equiv) in 1,2-dichlorobenzene (15 mL) was sparged with nitrogen for 15 minutes, then heated at 190° C. for 9 days, resulting in 90% conversion to desired product, as determined by LCMS analysis. The mixture was cooled to RT and most of the solvent removed under reduced pressure. The crude residue was purified on basic alumina column, eluting with a gradient of 0 to 100% dichloromethane in heptane to give desired product with impurities. The material was triturated with a 5 to 1 mixture of dichloromethane in methanol (10 mL) at 45° C., the suspension filtered, and the solid dried under vacuum at 40° C. for 2 hours to give the platinum complex of N-phenyl-3-(pyrimidin-2-yl)-N-(3-(pyrimidin-2-yl)phenyl)aniline (1.8 g, 58% yield) as a dark solid.
    • Synthesis of Comparative Example
  • Figure US20210280804A1-20210909-C00131
    • Synthesis of 3-bromo-N-(3-bromophenyl)-N-phenylaniline
  • A solution of 1,3-dibromobenzene (62.5 g, 265 mmol), aniline (8.18 g, 88 mmol) in toluene (350.0 ml, 0.25 molar) was mixed with sodium 2-methylpropan-2-olate (25.4 g, 264 mmol), Pd2(dba)3 (3.80 g, 6.61 mmol) and DPPF (3.94 g, 7.11 mmol). The reaction mixture was degassed and heated to reflux at 110° C. for 12 hours. Reaction was monitored by LCMS, after complete consumption of starting material, the reaction mixture was cooled to RT. Then 400 mL of EtOAc was added and the mixture was stirred at RT for 10 min, the solids were filtered, and combined filtrate were concentrated under reduced pressure. The crude product was subjected to column chromatography on silica gel column, using 0-1.5% EtOAc in hexane as eluent. Pure fractions were collected and concentrated to dryness to afford pure white solid 3-bromo-N-(3-bromophenyl)-N-phenylaniline (42.4 g, 48.6% yield).
    • Synthesis of N-phenyl-3-(pyridin-2-yl)-N-(3-(pyridin-2-yl) phenyl) aniline
  • 3-Bromo-N-(3-bromophenyl)-N-phenylaniline (10 g, 24.81 mmol) and Pd(PPh3)4 (2.87 g, 2.481 mmol) were suspended in THF (100 ml) and the reaction mixture was degassed. Pyridin-2-yl zinc (II) bromide solution in THF (198 ml, 99 mmol) was slowly added to the reaction mixture and the reaction mixture was heated to reflux 72° C. for 12 hours. Reaction was monitored by LCMS, after complete consumption of starting material, the reaction mixture was cooled to RT. Then 500 mL aq. sat NH4Cl was added, and the layers were separated. The aqueous layer was extracted with 3×250 mL of EtOAc. The combined organic layer was washed with 800 mL of saturated NaCl solution, then organic layer was dried over Na2SO4, filtered, and concentrated. The crude product was subjected to column chromatography on silica gel column using 0-40% EtOAc/hexane as an eluent. Pure fractions were collected and concentrated to dryness to afford pure pale-yellow foam (8.20 g, 82.7% yield) as desired product.
    • Platinum Complex of N-phenyl-3-(pyridin-2-yl)-N-(3-(pyridin-2-yl)phenyl) aniline
  • A mixture of N-phenyl-3-(pyridin-2-yl)-N-(3-(pyridin-2-yl) phenyl)aniline (1.8 g, 4.51 mmol, 1.0 equiv) and dichloro(1,5-cyclooctadiene) platinum(II) (1.686 g, 4.51 mmol, 1.0 equiv) in 1,2-dichlorobenzene (15 mL) was sparged with nitrogen for 15 minutes then heated at 190° C. for 6 days, resulting in 75% conversion to desired product as determined by LCMS analysis. The mixture was cooled to room temperature and most of the solvent removed under reduced pressure. The crude residue was purified by column chromatography on neutral alumina, eluting with a gradient of 0 to 80% dichloromethane in heptanes to give desired compound (0.8 g, 97.9% purity UPLC) as a red solid.
    • Device Examples
  • All devices were fabricated by high vacuum (<10−7 Torr) thermal evaporation. The anode electrode was 80 nm of indium tin oxide (ITO). The cathode electrode consisted of 1 nm of LiQ followed by 100 nm of Al. All devices were encapsulated with a glass lid sealed with an epoxy resin in a nitrogen glove box (<1 ppm of H2O and O2) immediately after fabrication, and a moisture getter was incorporated inside the package.
  • The organic stack of the device examples consisted of sequentially, from the ITO surface, 10 nm of LG-101 (available from LG Chem. Inc.) as the hole injection layer (HIL), 40 nm of PPh-TPD as the hole transporting layer (HTL), 5 nm of electron blocking layer comprised of (H-3), 40 nm of emissive layer (EML) comprised of premixed host doped with 3 wt % of the invention compound or comparative compound as the emitter, 35 nm of aDBT-ADN with 35 wt % LiQ as the electron-transport layer (ETL). The premixed host comprises of a mixture of HM1 and HM2 in a weight ratio of 1:1 and was deposited from a single evaporation source. The chemical structures of the compounds used are shown below:
  • Figure US20210280804A1-20210909-C00132
    Figure US20210280804A1-20210909-C00133
    Figure US20210280804A1-20210909-C00134
  • Provided in Table 1 is a summary of the device data including emission peak wavelength, operating voltage, recorded at 10 mA/cm2, and device lifetime (LT95) which is the time for the luminence to decay to 95% of its initial value by aging at 80 mA/cm2. All results are normalized to the results of the Comparative example device.
  • Λmax Voltage LT95
    Device [nm] [a.u.] [a.u.]
    Compound 1 641 0.9 4.6
    Comparative example 617 1.0 1.0

    The data in Table 1 show that the device using the inventive compound as the emitter achieves redshifted emission color (641 vs 617 nm), which provides better color purity for TV and mobile applications. In addition, the device using the inventive examples shows lower operating voltage (0.9 vs 1.0) and substantially longer device lifetime 4.6 times that of the Comparative example device. Based on the fact that the Comparative Compound has a similar structure as the inventive compounds with the only difference being the additional N atom in the original pyridine ring, the significant performance improvement observed in the above data was unexpected.

Claims (20)

What is claimed is:
1. A compound of
Figure US20210280804A1-20210909-C00135
wherein:
each of X1 and X2 is independently C or N, with at least one being N;
each of X3, X4, and X5 is independently C or N;
at least one of X3, X4, and X5 is C and at least one is N;
L1 and L2 are linkers that can be present, with at least one of them being present and each independently selected from the group consisting of O, S, Se, CRR′, SiRR′, GeRR′, BR, BRR′, NR, alkyl, cycloalkyl, aryl, and heteroaryl when present;
RA, RB, RC, and RD each independently represents zero, mono, or up to the maximum allowed number of substitutions to its associated ring;
each of R, R′, RA, RB, RC, and RD is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
M is Pt, Pd, Au, Ag, Cu or Zn; and
any two adjacent R, R′, RA, RB, RC, and RD can be joined or fused together to form a ring,
with the proviso that the compound is not the one shown below:
Figure US20210280804A1-20210909-C00136
2. The compound of claim 1, wherein each of R, R′, RA, RB, RC, and RD is independently a hydrogen or a substituent selected from the group consisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof.
3. The compound of claim 1, wherein one of X1 and X2 is N, and the other is C.
4. The compound of claim 1, wherein one of X3, X4, and X5 is N, and the remaining ones of X3, X4, and X5 are C.
5. The compound of claim 1, wherein one of L1 and L2 is present, and the other is not present.
6. The compound of claim 1, wherein L1 and L2 are each independently selected from the group consisting of O, S, CRR′, SiRR′, and NR when present.
7. The compound of claim 1, wherein R and R′ are each independently selected from the group consisting of hydrogen, deuterium, alkyl, heteroalkyl, cycloalkyl, heterocycloalkyl, aryl, heteroaryl, and combinations thereof.
8. The compound of claim 1, wherein at least one pair of two adjacent RA, RB, RC, and RD are joined or fused together to form a 5-membered or 6-membered aromatic ring.
9. The compound of claim 8, wherein the 5-membered or 6-membered aromatic ring is selected from the group consisting of benzene, pyridine, pyrimidine, pyridazine, pyrazine, imidazole, pyrazole, pyrrole, oxazole, furan, thiophene, or thiazole.
10. The compound of claim 8, wherein the 5-membered or 6-membered aromatic ring is further fused to form a multiple fused ring system
11. The compound of claim 1, wherein at least one of RA, RB, RC, and RD is Selected from the Group Consisting of deuterium, fluorine, alkyl, cycloalkyl, aryl, heteroaryl, and combinations thereof.
12. The compound of claim 1, wherein the compound is selected from the group consisting of:
Figure US20210280804A1-20210909-C00137
Figure US20210280804A1-20210909-C00138
Figure US20210280804A1-20210909-C00139
13. The compound of claim 1, wherein L1 or L2 is independently O, CRR′, SiRR′, or NR.
14. The compound of claim 12, wherein two adjacent RA, RB, RC, and RD are joined or fused together to form a 5-membered or 6-membered aromatic ring.
15. The compound of claim 1, wherein the compound is selected from the group consisting of:
Figure US20210280804A1-20210909-C00140
Figure US20210280804A1-20210909-C00141
Figure US20210280804A1-20210909-C00142
Figure US20210280804A1-20210909-C00143
Figure US20210280804A1-20210909-C00144
Figure US20210280804A1-20210909-C00145
Figure US20210280804A1-20210909-C00146
Figure US20210280804A1-20210909-C00147
16. The compound of claim 1, wherein the compound is selected from the group consisting of:
Compound 1-1, Compound 1-2, Compound 1-3, and Compound 1-4 having the following structure
Figure US20210280804A1-20210909-C00148
 wherein, in Compound 1-1, L2 = NPh, in Compound 1-2, L2 = O, in Compound 1-3, L2 = CMe2, and in Compound 1-4 L2 = SiPh2, Compound 2-1, Compound 2-2, Compound 2-3, and Compound 2-4 having the following structure
Figure US20210280804A1-20210909-C00149
 wherein, in Compound 2-1, L2 = Ph, in Compound 2-2, L2 = O, in Compound 2-3, L2 = CMe2, and in Compound 2-4, L2 = SiPh2., Compound 3-1, Compound 3-2, Compound 3-3, and Compound 3-4 having the following structure
Figure US20210280804A1-20210909-C00150
 wherein, in Compound 3-1, L2 = Ph, in Compound 3-2, L2 = O, in Compound 3-3, L2 = CMe2, and in Compound 3-4, L2 = SiPh2., Compound 4-1, Compound 4-2, Compound 4-3, and Compound 4-4 having the following structure
Figure US20210280804A1-20210909-C00151
 wherein. in Compound 4-1, L2 = NPh, in Compound 4-2, L2 = O, in Compound 4-3, L2 = CMe2, and in Compound 4-4, L2 = SiPh2., Compound 5-1, Compound 5-2, Compound 5-3, and Compound 5-4 having the following structure
Figure US20210280804A1-20210909-C00152
 wherein, in Compound 5-1, L2 = NPh, in Compound 5-2, L2 = O, in Compound 5-3, L2 = CMe2, and in Compound 5-4 L2 = SiPh2., Compound 6-1, Compound 6-2, Compound 6-3, and Compound 6-4 having the following structure
Figure US20210280804A1-20210909-C00153
 wherein, in Compound 6-1, L2 = Ph, in Compound 6-2, L2 = O, in Compound 6-3, L2 = CMe2, and in Compound 6-4, L2 = SiPh2., Compound 7-1, Compound 7-2, Compound 7-3, and Compound 7-4 having the following structure
Figure US20210280804A1-20210909-C00154
 wherein, in Compound 7-1, L2 = Ph, in Compound 7-2, L2 = O, in Compound 7-3, L2 = CMe2, and in Compound 7-4, L2 = SiPh2., Compound 8-1, Compound 8-2, Compound 8-3, and Compound 8-4 having the following structure
Figure US20210280804A1-20210909-C00155
 wherein. in Compound 8-1, L2 = NPh, in Compound 8-2, L2 = O, in Compound 8-3, L2 = CMe2, and in Compound 8-4, L2 = SiPh2., Compound 9-1, Compound 9-2, Compound 9-3, and Compound 9-4 having the following structure
Figure US20210280804A1-20210909-C00156
 wherein, in Compound 9-1, L2 = NPh, in Compound 9-2, L2 = O, in Compound 9-3, L2 = CMe2, and in Compound 9-4, L2 = SiPh2., Compound 11-1, Compound 11-2, Compound 11-3, and Compound 11-4 having the following structure
Figure US20210280804A1-20210909-C00157
 wherein, in Compound 11-1, L2 = NPh, in Compound 11-2, L2 = O, in Compound 11-3, L2 = CMe2, and in Compound 11-4, L2 = SiPh2., Compound 12-1, Compound 12-2, Compound 12-3, and Compound 12-4 having the following structure
Figure US20210280804A1-20210909-C00158
 wherein, in Compound 12-1, L2 = NPh, in Compound 12-2, L2 = O, in Compound 12-3, L2 = CMe2, and in Compound 12-4, L2 = SiPh2., Compound 13-1, Compound 13-2, Compound 13-3, and Compound 13-4 having the following structure
Figure US20210280804A1-20210909-C00159
 wherein, in Compound 13-1, L2 = NPh, in Compound 13-2, L2 = O, in Compound 13-3, L2 = CMe2, and in Compound 13-4, L2 = SiPh2., Compound 14-1, Compound 14-2, Compound 14-3, and Compound 14-4 having the following structure
Figure US20210280804A1-20210909-C00160
 wherein, in Compound 14-1, L2 = NPh, in Compound 14-2, L2 = O, in Compound 14-3, L2 = CMe2, and in Compound 14-4, L2 = SiPh2., Compound 15-1, Compound 15-2, Compound 15-3, and Compound 15-4 having the following structure
Figure US20210280804A1-20210909-C00161
 wherein, in Compound 15-1, L2 = NPh, in Compound 15-2, L2 =O, in Compound 15-3, L2 = CMe2, and in Compound 15-4 L2 = SiPh2., Compound 16-1, Compound 16-2, Compound 16-3, and Compound 16-4, having the following structure
Figure US20210280804A1-20210909-C00162
 wherein, in Compound 16-1, L2 = NPh, in Compound 16-2, L2 = O, in Compound 16-3, L2 = CMe2, and in Compound 16-4, L2 = SiPh2., Compound 17-1, Compound 17-2, Compound 17-3, and Compound 17-4 having the following structure
Figure US20210280804A1-20210909-C00163
 wherein, in Compound 17-1, L2 = NPh, in Compound 17-2, L2 = O, in Compound 17-3, L2 = CMe2, and in Compound 17-4, L2 = SiPhd2., Compound 18-1, Compound 18-2, Compound 18-3, and Compound 18-4 having the following structure
Figure US20210280804A1-20210909-C00164
 wherein, in Compound 18-1, L2 = NPh, in Compound 18-2, L2 = O, in Compound 18-3, L2 = CMe2, and in Compound 18-4, L2 = SiPh2., Compound 19-1, Compound 19-2, Compound 19-3, and Compound 19-4 having the following structure
Figure US20210280804A1-20210909-C00165
 wherein, in Compound 19-1, L2 = NPh, in Compound 19-2, L2 = O, in Compound 19-3, L2 = CMe2, and in Compound 19-4, L2 = SiPh2., Compound 20-1, Compound 20-2, Compound 20-3, and Compound 20-4 having the following structure
Figure US20210280804A1-20210909-C00166
 wherein, in Compound 20-1, L2 = NPh, in Compound 20-2, L2 = O, in Compound 20-3, L2 = CMe2, and in Compound 20-4, L2 = SiPh2., Compound 21-1, Compound 21-2, Compound 21-3, and Compound 21-4 having the following structure
Figure US20210280804A1-20210909-C00167
 wherein, in Compound 21-1, L2 = NPh, in Compound 21-2, L2 = O, in Compound 21-3, L2 = CMe2, and in Compound 21-4, L2 = SiPh2., Compound 25-1, Compound 25-2, Compound 25-3, and Compound 25-4 having the following structure
Figure US20210280804A1-20210909-C00168
 wherein, in Compound 25-1, L2 = NPh, in Compound 25-2, L2 = O, in Compound 25-3, L2 = CMe2, and in Compound 25-4, L2 = SiPh2., Compound 26-1, Compound 26-2, Compound 26-3, and Compound 26-4 having the following structure
Figure US20210280804A1-20210909-C00169
 wherein, in Compound 26-1, L2 = NPh, in Compound 26-2, L2 = O, in Compound 26-3, L2 = CMe2, and in Compound 26-4, L2 = SiPh2., Compound 27-1, Compound 27-2, Compound 27-3, and Compound 27-4 having the following structure
Figure US20210280804A1-20210909-C00170
 wherein, in Compound 27-1, L2 = NPh, in Compound 27-2, L2 = O, in Compound 27-3, L2 = CMe2, and in Compound 27-4, L2 = SiPh2., Compound 28-1, Compound 28-2, Compound 28-3, and Compound 28-4 having the following structure
Figure US20210280804A1-20210909-C00171
 wherein, in Compound 28-1, L2 = NPh, in Compound 28-2, L2 = O, in Compound 28-3, L2 = CMe2, and in Compound 28-4, L2 = SiPh2., Compound 29-1, Compound 29-2, Compound 29-3, and Compound 29-4 having the following structure
Figure US20210280804A1-20210909-C00172
 wherein, in Compound 29-1, L2 = NPh, in Compound 29-2, L2 = O, in Compound 29-3, L2 = CMe2, and in Compound 29-4, L2 = SiPh2., Compound 31-1, Compound 31-2, Compound 31-3, and Compound 31-4 having the following structure
Figure US20210280804A1-20210909-C00173
 wherein, in Compound 31-1, L2 = NPh, in Compound 31-2, L2 = O, in Compound 31-3, L2 = CMe2, and in Compound 31-4, L2 = SiPh2., Compound 32-1, Compound 32-2, Compound 32-3, and Compound 32-4 having the following structure
Figure US20210280804A1-20210909-C00174
 wherein, in Compound 32-1, L2 = NPh, in Compound 32-2, L2 = O, in Compound 32-3, L2 = CMe2, and in Compound 32-4, L2 = SiPh2., Compound 33-1, Compound 33-2, Compound 33-3, and Compound 33-4 having the following structure
Figure US20210280804A1-20210909-C00175
 wherein, in Compound 33-1, L2 = NPh, in Compound 33-2, L2 = O, in Compound 33-3, L2 = CMe2, and in Compound 33-4, L2 = SiPh2., Compound 34-1, Compound 34-2, Compound 34-3, and Compound 34-4 having the following structure
Figure US20210280804A1-20210909-C00176
 wherein, in Compound 34-1, L2 = NPh, in Compound 34-2, L2 = O, in Compound 34-3, L2 = CMe2, and Compound 34-4, L2 in = SiPh2., Compound 36-1, Compound 36-2, Compound 36-3, and Compound 36-4 having the following structure
Figure US20210280804A1-20210909-C00177
 wherein, in Compound 36-1, L2 = NPh, in Compound 36-2, L2 = O, in Compound 36-3, L2 = CMe2, and in Compound 36-4, L2 = SiPh2., Compound 37-1, Compound 37-2, Compound 37-3, and Compound 37-4 having the following structure
Figure US20210280804A1-20210909-C00178
 wherein, in Compound 37-1, L2 = NPh, in Compound 37-2, L2 = O, in Compound 37-3, L2 = CMe2, and in Compound 37-4, L2 = SiPh2., Compound 38-1, Compound 38-2, Compound 38-3, and Compound 38-4 having the following structure
Figure US20210280804A1-20210909-C00179
 wherein, in Compound 38-1, L2 = NPh, in Compound 38-2, L2 = O, in Compound 38-3, L2 = CMe2, and in Compound 38-4, L2 = SiPh2., Compound 39-1, Compound 39-2, Compound 39-3, and Compound 39-4 having the following structure
Figure US20210280804A1-20210909-C00180
 wherein, in Compound 39-1, L2 = NPh, in Compound 39-2, L2 = O, in Compound 39-3, L2 = CMe2, and in Compound 39-4, L2 = SiPh2., Compound 40-1, Compound 40-2, Compound 40-3, and Compound 40-4 having the following structure
Figure US20210280804A1-20210909-C00181
 wherein, in Compound 40-1, L2 = NPh, in Compound 40-2, L2 = O, in Compound 40-3, L2 = CMe2, and in Compound 40-4, L2 = SiPh2., Compound 40-1, Compound 40-2, Compound 40-3, and Compound 40-4 having the following structure
Figure US20210280804A1-20210909-C00182
 wherein, in Compound 41-1, L2 = NPh, in Compound 41-2, L2 = O, in Compound 41-3, L2 = CMe2, and in Compound 41-4, L2 = SiPh2., Compound 42-1, Compound 42-2, Compound 42-3, and Compound 42-4 having the following structure
Figure US20210280804A1-20210909-C00183
 wherein, in Compound 42-1, L2 = NPh, in Compound 42-2, L2 = O, in Compound 42-3, L2 = CMe2, and in Compound 42-4, L2 = SiPh2., Compound 43-1, Compound 43-2, Compound 43-3, and Compound 43-4 having the following structure
Figure US20210280804A1-20210909-C00184
 wherein, in Compound 43-1, L2 = NPh, in Compound 43-2, L2 = O, in Comound 43-3, L2 = CMe2, and in Compound 43-4, L2 = SiPh2., and Compound 44-1, Compound 44-2 Compound 44-3, and Compound 44-4 having the following structure
Figure US20210280804A1-20210909-C00185
 wherein, in Compound 44-1, L2 = NPh, in Compound 44-2, L2 = O, in Compound 44-3, L2 = CMe2, and in Compound 44-4, L2 = SiPh2..
17. An organic light emitting device (OLED) comprising:
an anode;
a cathode; and
an organic layer disposed between the anode and the cathode,
wherein the organic layer comprises a compound of
Figure US20210280804A1-20210909-C00186
wherein:
each of X1 and X2 is independently C or N, with at least one being N;
each of X3, X4, and X5 is independently C or N;
at least one of X3, X4, and X5 is C and at least one is N;
L1 and L2 are linkers that can be present, with at least one of them being present and each independently selected from the group consisting of O, S, Se, CRR′, SiRR′, GeRR′, BR, BRR′, NR, alkyl, cycloalkyl, aryl, and heteroaryl when present;
RA, RB, RC, and RD each independently represents zero, mono, or up to the maximum allowed number of substitutions to its associated ring;
each of R, R′, RA, RB, RC, and RD is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
M is Pt, Pd, Au, Ag, Cu or Zn; and
any two adjacent R, R′, RA, RB, RC, and RD can be joined or fused together to form a ring,
with the proviso that the compound is not the one shown below:
Figure US20210280804A1-20210909-C00187
18. The OLED of claim 17, wherein the organic layer further comprises a host, wherein the host comprises at least one chemical moiety selected from the group consisting of triphenylene, carbazole, indolocarbazole, dibenzothiphene, dibenzofuran, dibenzoselenophene, 5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene, aza-triphenylene, aza-carbazole, aza-indolocarbazole, aza-dibenzothiophene, aza-dibenzofuran, aza-dibenzoselenophene, and aza-(5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene).
19. The OLED of claim 18, wherein the host is selected from the group consisting of:
Figure US20210280804A1-20210909-C00188
Figure US20210280804A1-20210909-C00189
Figure US20210280804A1-20210909-C00190
Figure US20210280804A1-20210909-C00191
Figure US20210280804A1-20210909-C00192
Figure US20210280804A1-20210909-C00193
Figure US20210280804A1-20210909-C00194
and combinations thereof.
20. A consumer product comprising an organic light-emitting device (OLED) comprising:
an anode;
a cathode; and
an organic layer disposed between the anode and the cathode,
wherein the organic layer comprises a compound of
Figure US20210280804A1-20210909-C00195
wherein:
each of X1 and X2 is independently C or N, with at least one being N;
each of X3, X4, and X5 is independently C or N;
at least one of X3, X4, and X5 is C and at least one is N;
L1 and L2 are linkers that can be present, with at least one of them being present and each independently selected from the group consisting of O, S, Se, CRR′, SiRR′, GeRR′, BR, BRR′, NR, alkyl, cycloalkyl, aryl, and heteroaryl when present;
RA, RB, RC, and RD each independently represents zero, mono, or up to the maximum allowed number of substitutions to its associated ring;
each of R, R′, RA, RB, RC, and RD is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
M is Pt, Pd, Au, Ag, Cu or Zn; and
any two adjacent R, R′, RA, RB, RC, and RD can be joined or fused together to form a ring,
with the proviso that the compound is not the one shown below:
Figure US20210280804A1-20210909-C00196
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