US20210054516A1 - Electrochemical additive manufacturing method using deposition feedback control - Google Patents
Electrochemical additive manufacturing method using deposition feedback control Download PDFInfo
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- C—CHEMISTRY; METALLURGY
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- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
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- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/38—Electroplating: Baths therefor from solutions of copper
Definitions
- One or more embodiments of the invention are related to the fields of electronics and 3D printing. More particularly, but not by way of limitation, one or more embodiments of the invention enable a method of electrochemical additive manufacturing using deposition feedback control.
- Additive manufacturing also known as 3D Printing
- 3D Printing is often used for the production of complex structural and functional parts via a layer-by-layer process, directly from CAD (computer aided drafting) models.
- Additive manufacturing processes are considered additive because materials are selectively deposited on a substrate to construct the product.
- Additive manufacturing processes are also typically layered meaning that layers of the product to be produced are fabricated sequentially.
- An emerging alternative for additive metal manufacturing is to use electrochemical reactions.
- a metal part is constructed by plating charged metal ions onto a surface in an electrolyte solution.
- This technique relies on placing a deposition anode physically close to a substrate in the presence of a deposition solution (the electrolyte), and energizing the anode causing charge to flow through the anode.
- An illustrative apparatus that enables additive manufacturing via electroplating is described for example in U.S. Utility Pat. No. 10,465,307, “Apparatus for Electrochemical Additive Manufacturing,” by the inventors of the instant application.
- This apparatus demonstrated a novel approach to electrochemical additive manufacturing that uses a printhead with an array of anodes to build portions of each layer of a part in parallel, instead of moving a single anode across a part to sequentially construct portions of the layer.
- Additive manufacturing processes known in the art typically add material in pre-programmed patterns. For example, material may be emitted from a printhead for a preprogrammed period of time at a preprogrammed rate to construct a layer of a part.
- rate and pattern of material deposition depends on many dynamic factors, such as the distance between the printhead and each location of the part, the local density of metal ions in the electrolyte, and electrolyte flow patterns. As a result, it is difficult or impossible to achieve high quality parts using strictly preprogrammed (“open loop”) control.
- feedback control methods for electrochemical additive manufacturing processes are not well-developed.
- An object to be manufactured may be constructed by placing a cathode and an anode array into an electrolyte solution.
- Deposition anodes of the anode array may provide current that flows from the anode to the cathode through the electrolyte solution, resulting in deposition of the material onto the cathode.
- the manufacturing process may use a build plan with a layer description for multiple layers of the object; each layer description may include a target map, which describes the presence or absence of material at locations within the layer, and one or more process parameters that affect the layer build.
- Manufacturing of a layer may begin by setting or confirming the position of the cathode relative to the anode array.
- control signals may be sent to the anode array based on the layer description.
- One or more feedback signals may be measured across the anode array, and these signals may be analyzed to generate a deposition analysis that indicates the extent to which deposition has progressed at locations within the layer.
- the deposition analysis may be used to determine whether the layer is complete, and to modify the process parameters associated with the layer. When a layer is complete, manufacturing may continue for a subsequent layer.
- the layer description of one or more layers may be modified before manufacturing the layers. For example, layer densities may be changed.
- Analysis of feedback signals may apply one or more transformations to these signals, such as morphological filters or Boolean operators.
- Feedback signals may for example include a map of current across the anode array.
- the deposition analysis may be generated by applying a thresholding operation to this current map.
- Determining whether a layer is complete may for example include comparing the number of actual deposited pixels to the number of desired deposited pixels within the layer. In one or more embodiments, a layer may be complete when the ratio of actual to desired deposited pixels reaches or exceeds a threshold value. In one or more embodiments, a layer may be complete when a desired fraction of the desired deposited pixels are within a threshold distance from an actual deposited pixel. In one or more embodiments, the layer may be divided into components, and completion tests may be applied to each component; a layer may be considered complete when all components are complete. For example, a component may be complete when the ratio of actual to desired deposited pixels within the component reaches or exceeds a threshold value, or when a desired fraction of the desired deposited pixels within the component are within a threshold distance from an actual deposited pixel.
- a layer target map may be divided into regions, and construction of the layer may include alternately activating deposition anodes associated with each region.
- manufacturing of a layer may include calculating a map of desired current output from each deposition anode, so that this current output will generate deposition corresponding to the layer's target map.
- This current map calculation may involve applying one or more transformations to the layer target map.
- modification of process parameters associated with a layer may include calculation of voltage, current, or time of activation for one or more deposition anodes.
- setting or confirming the position of the cathode relative to the anode may include obtaining sensor signals that vary based on this relative position, such as a current value or a voltage value.
- manufacturing of a layer may include one or more maintenance actions that maintain the condition of the anode array or the electrolyte solution. For example, these maintenance actions may replace material onto one or more deposition anodes that have eroded. Maintenance actions may activate one or more deposition anodes to remove a film that has formed. Maintenance actions may include removal of bubbles from the electrolyte solution.
- FIG. 1 shows a flowchart of an embodiment of the invention that successively manufactures layers using feedback control to assess layer completion and to adjust parameters during manufacturing.
- FIG. 2 shows an architectural block diagram of illustrative electrodeposition equipment that may be used to implement one or more embodiments of the invention.
- FIG. 3 shows an illustrative build plan for layers of an object, with target maps for each layer showing desired areas of deposited material, and process parameters describing how the layer is to be manufactured.
- FIG. 4 illustrates density manipulation to generate a porous base layer that facilitates part removal.
- FIG. 5 illustrates detection of an overhang in a layer.
- FIG. 6 illustrates manufacturing steps for the overhang detected in FIG. 5 .
- FIG. 7 shows an illustrative embodiment of feedback using current sensors across the anode array.
- FIG. 8 shows an illustrative map of current sensor feedback signals, and processing of these signals to form a map of deposition areas within a layer.
- FIG. 9A shows an illustrative method to test for layer completion based on the current sensor data of FIG. 8 .
- FIG. 9B shows an extension of the layer completion test of FIG. 9A , which tests separately for completion of all connected components of the layer.
- FIG. 10 illustrates update of anode outputs based on the current sensor feedback signals of FIG. 8 .
- FIGS. 11A, 11B, and 11C illustrate a potentially complex relationship between anode currents and deposited material, which may require pre-processing to obtain the desired deposition pattern.
- FIG. 12A illustrates calculation of anode currents to obtain a desired deposition pattern.
- FIG. 12B shows an illustrative two-dimensional example of calculating a pattern of anode currents to obtain a desired deposition pattern.
- FIG. 13 shows an illustrative embodiment that alternates anode output across different regions.
- FIG. 14 shows illustrative maintenance actions that may be performed during layer manufacturing to address issues in the anode array or the electrolyte.
- FIG. 15 shows an illustrative part manufactured using an embodiment of the invention.
- One or more embodiments of the invention may enable manufacturing of objects by passing electrical current through an electrolyte to deposit material onto the object, and by monitoring feedback signals during deposition to adjust manufacturing process parameters throughout the process.
- numerous specific details are set forth in order to provide a more thorough understanding of embodiments of the invention. It will be apparent, however, to an artisan of ordinary skill that embodiments of the invention may be practiced without incorporating all aspects of the specific details described herein. In other instances, specific features, quantities, or measurements well known to those of ordinary skill in the art have not been described in detail so as not to obscure the invention. Readers should note that although examples of the invention are set forth herein, the claims, and the full scope of any equivalents, are what define the metes and bounds of the invention.
- a metal part is constructed by reducing charged metal ions onto a surface in an electrolyte solution.
- This technique relies on placing a deposition anode physically close to a substrate in the presence of a deposition solution (the electrolyte), and energizing the anode causing charge to flow through the anode. This creates an electrochemical reduction reaction to occur at the substrate near the anode and deposition of material on the substrate.
- a particular challenge of electrochemical manufacturing is that the rate and quality of deposition of material may be highly variable, and may vary across time and across locations based on multiple factors such as current density, electrolyte composition, fluid flows within the electrolyte, and distances between anodes and previously deposited material.
- FIG. 1 shows illustrative steps for an electrochemical additive manufacturing process that incorporates deposition feedback control. These steps are illustrative; one or more embodiments may use different or additional steps and may perform operations in different orders.
- the manufacturing process illustrated in FIG. 1 has a planning phase 100 , and a building phase 120 .
- a model 101 of an object is analyzed by planning step or steps 102 to generate a build plan 103 for construction of the object.
- the planning step or steps 102 may execute on any processor or processors, such as for example, without limitation, a computer, a microprocessor, a microcontroller, a desktop, a laptop, a notebook, a server, a mobile device, a tablet, or a network of any of these processors.
- the planning step (or steps) 102 may for example slice a 3D object model 101 into layers, and develop a plan to construct each layer.
- the build plan 103 may include a layer description for each layer; a layer description may include for example a target map for the layer and various process parameter values for construction of the layer.
- the target map may include a two-dimensional grid or image showing locations within the layer where material is to be deposited.
- the process parameters for a layer may include any variables that affect the physical or electrical processes that construct the layer; these parameters may include for example, without limitation, current density range, voltage range, layer height, movement parameters, overhang controls, safety thresholds, leakage thresholds, short circuit determination threshold values, pixel mapping intervals and thresholds, debubble values, fusing, anode cleaning, islanding, distance to short, distance to short percentage, pixel limits, slow current control values, and maximum blob size.
- FIG. 1 shows an illustrative layer description 111 for a first layer of an object, which includes a target map 112 for the layer and process parameters 113 for the layer; subsequent layers have similar layer descriptions with target maps and process parameters.
- the build planning step or steps 102 may also generate overall process parameters 115 that apply to all of the layers in the build, or that may be used as default values that apply unless a layer description overrides the defaults.
- the build phase 120 of the process constructs an object from the build plan 103 , using for example equipment that performs electrochemical deposition. Illustrative equipment that may be used in one or more embodiments of the invention is described below with respect to FIG. 2 .
- a surface of a cathode may be placed in contact with an electrolyte solution in step 121 ; the object may be constructed by electrochemically depositing material onto the cathode by passing current through an anode array that is also in contact with the solution. Layers in build plan 103 may then be built successively onto the base of the cathode or onto previously constructed layers, effectively enlarging the cathode for purposes of deposition.
- the layer description is retrieved or loaded in step 122 .
- the layer description may for example be loaded into a memory accessible to a controller of the electrochemical deposition equipment; this controller may be any type or types of processors.
- the first layer description 111 may be loaded or retrieved.
- the controller may then perform step 123 to set or confirm the relative position between the anode and the cathode. As layers are successively built, the distance between the anode and the cathode may need to be modified so that the anode distance from the most recently deposited surfaces remains within a range that enables sufficient control of the deposition process.
- the electrochemical deposition equipment may include an actuator that can move either or both of the cathode and the anode, as illustrated below with respect to FIG. 2 .
- step 123 may for example involve a “zeroing” procedure that sets the initial relative position between the anode and the cathode to a desired initial value.
- the specific methods used for zeroing may vary depending on the deposition equipment.
- the controller may move the cathode or anode until one or more sensors indicate contact (or sufficiently close proximity) between the two, and it may then offset a desired distance from this contacting position.
- there may be sensors such as absolute or relative encoders on the position actuator that assist in zeroing.
- step 123 may ensure that the relative position between the anode and cathode is correct to begin deposition of material for the new layer. In some cases this may require modifications to the relative position, for example using an actuator that moves the anode or the cathode. For example, in some situations an object may be constructed by successively depositing material for a layer, then repositioning the cathode relative to the anode to move the cathode away from the anode to prepare for the next layer, and then depositing material for the next layer. In other situations relative movement between the anode and cathode may be performed throughout construction of a layer, sometimes referred to as “gliding,” so that no additional repositioning is required at step 123 when a new layer is loaded.
- Step 122 After a layer description is loaded in step 122 , and the relative position of the cathode and anode is set or confirmed in step 123 , the build process 120 enters an inner loop 140 of steps that may be executed to construct the loaded layer. As described above, this loop may be a closed loop with feedback control, so that build steps and process parameters may be modified throughout the loop based on measured feedback signals.
- Step 125 may include various actions to deposit material via electrochemical reactions (for example, by passing current through anodes) as well as actions that maintain or adjust the state or health of the anode array and the electrolyte.
- Illustrative maintenance actions may include for example, without limitation, removal of bubbles from the electrolyte, agitation of the electrolyte to modify flow rates or to modify distribution of ions in the electrolyte, and actions to remove films from anodes or to replenish anode surfaces. Any of these maintenance actions may be interleaved with deposition actions in any desired manner.
- step 126 may be performed to obtain feedback signals that may for example indicate how deposition is progressing.
- One or more embodiments may use any type or types of sensors to obtain feedback signals.
- the current through each anode in an anode array may be measured (for example with a fixed voltage); a higher current may correspond to a lower impedance between the anode and the cathode, which may be correlated with the amount of material deposited on the cathode in the vicinity of each anode.
- a variable voltage waveform may be used, and alternating current (AC) signals may be measured.
- One or more embodiments may use other feedback signals such as optical images of the cathode or distance measurements to points on the cathode.
- these feedback signals may be analyzed to generate a deposition analysis 128 , which may include estimates of the amount of material deposited at locations within the layer.
- a determination 129 may be made as to whether construction of the layer is complete. If the layer is complete, and if test 132 indicates that there are more layers to be constructed, then a next layer is loaded in step 122 and the layer construction loop 140 is executed for that next layer; otherwise construction of the object is finished.
- the generation of deposition maps may be performed concurrently with the deposition process.
- additional sensing elements may be incorporated into the fabrication of the anode array to enable continuous characterization of the current flowing through each deposition anode, or the voltage at each deposition anode surface. This could be performed, for instance, by an Analog to Digital converter (ADC) whose inputs are sequentially connected to successive rows of deposition anodes in a multiplexing method similar to that used in the addressing of the anode array.
- ADC Analog to Digital converter
- test 129 indicates that deposition for a layer is not complete, then in some situations the deposition analysis 128 or other data from the feedback signals may be used to modify the parameters and control signals that are used to construct the layer.
- a test 130 may be performed to determine whether any adjustments are required. If they are required, then one or more process parameters 131 may be modified, and this may modify the control signals 124 that drive the deposition (and maintenance) actions. As one example, if the deposition analysis 128 indicates that enough material has been deposited in certain areas of a layer, then current may be turned off (or turned down) for anodes corresponding to those areas.
- FIG. 2 shows an architectural diagram of illustrative equipment that may be used to perform build steps of one or more embodiments of the invention.
- the system has a printhead 200 that contains an array 201 of deposition anodes, and a corresponding array 202 of deposition control circuits for the deposition anodes.
- the deposition control circuits 202 may be organized in a matrix arrangement, thereby supporting high resolution anode arrays.
- the deposition anode array 201 may be organized in a two-dimensional grid; FIG. 2 shows a cross sectional view.
- a grid control circuit 203 transmits control signals to the deposition control circuits 202 to control the amount of current flowing through each deposition anode in anode array 201 .
- Printhead 200 may also contain other elements such as insulation layers, for example to protect elements of the printhead from the electrolyte solution.
- the deposition anode array 201 of printhead 200 may be placed in an electrolyte solution 210 . Electrochemical reactions may then cause plating of metal onto a manufactured part 230 that is coupled to cathode 220 . Intricate and detailed shapes may be built in part 230 by modifying the current flowing through each anode of deposition anode array 201 . For example, in the snapshot shown in FIG. 2 , anode 211 is energized, so that metal is being deposited onto part 230 near this anode, but anode 212 is not energized so no metal is being deposited near that anode.
- printhead 200 may be integrated with a processor 222 .
- This processor may transmit signals to grid control circuit 203 , which sends signals to the individual deposition control circuits 202 to turn anodes in deposition anode array 201 on or off (or to modify the intensity of current flow through each anode).
- Processor 222 may be for example, without limitation, a microcontroller, a microprocessor, a GPU, a FPGA, a SoC, a single-board computer, a laptop, a notebook, a desktop computer, a server, or a network or combination of any of these devices.
- Processor 222 may be the same as or different from a processor or processors that analyze an object model to construct a build plan.
- Processor 222 may communicate with one or more sensors 223 that may generate the feedback signals that measure the progress of metal deposition on part 230 .
- Sensors 223 may include for example, without limitation, current sensors, voltage sensors, timers, cameras, rangefinders, scales, force sensors, or pressure sensors.
- One or more of the sensors 223 may also be used to measure the distance between the cathode and the anode, for example for zeroing to begin manufacturing an object, or to set or confirm the relative position between the anode and cathode at the beginning of each layer.
- the accurate positioning of the build plate relative to the electrode array at the initialization of the deposition process may have a significant impact on the success and quality of the completed deposit.
- Embodiments may use various types of sensors for this positioning, including for example, without limitation, mechanical, electrical, or optical sensors, or combinations thereof.
- mechanical sensors such as a pressure sensor, switch, or load cell may be employed, which detects when the build plate is moved and reaches the required location.
- portions of the system may be energized, and the cathode may be moved to proximity to the energized component at a known location. When a voltage or current is detected on the cathode or build plate the build plate may be known to be at a given location.
- One or more embodiments may use other types of sensors that detect for example capacitance, impedance, magnetic fields, or that utilize the Hall Effect to determine the location of the cathode/build plate relative to a known position.
- One or more embodiments may use optical sensors such as laser rangefinders or sensors that detect interference with an optical path.
- cathode 220 and printhead 200 may be attached to one or more position actuators 224 , which may control the relative position of the cathode and the deposition anode array.
- Position actuator 224 may control vertical movement 225 , so that the cathode may be raised (or alternatively the anode lowered) as the part 230 is built in successive layers.
- position actuator 224 may also move the cathode or deposition anode array horizontally relative to one another, for example so that large parts may be manufactured in tiles.
- Printhead 200 may be connected to a power supply (or multiple power supplies) 221 , which supplies current 244 that flows through the deposition anode array to drive metal deposition on part 230 .
- Current may be distributed throughout the array of deposition control circuits via power distribution circuit 204 , which may for example include one or more power busses.
- the system may also include a fluid chamber to contain the electrolyte solution (not shown in FIG. 2 ), and a fluid handling system (also not shown).
- the fluid system may include for example a tank, a particulate filter, chemically resistant tubing and a pump.
- Analytical equipment may enable continuous characterization of bath pH, temperature, and ion concentration using methods such as conductivity, High Performance Liquid Chromatography, mass spectrometry, Cyclic Voltammetry Stripping, spectrophotometer measurements, or the like. Bath conditions may be maintained with a chiller, heater and/or an automated replenishment system to replace solution lost to evaporation and/or ions of deposited material.
- one or more embodiments may incorporate multiple deposition anode arrays. These multiple anode arrays may for example operate simultaneously in different chambers filled with electrolyte solution, or they may be tiled in a manner where the anode arrays work together to deposit material on a shared cathode or series of cathodes.
- FIG. 3 shows illustrative elements of a build plan for an object with an object model 101 a .
- the object model 101 a may be for example a 3D CAD model, or any description of the geometric or material properties of an object.
- the build planning process may slice this model into layers, and may develop a layer description for each layer.
- FIG. 3 shows four illustrative layers, each of which corresponds to a horizontal slice through model 101 a .
- Build plans may have any number of layers and slices may be of any desired thickness, shape, and orientation.
- Associated with each layer is a layer description that includes a target map, and one or more process parameters. The four layers shown in FIG.
- target maps 112 a through 112 d have target maps 112 a through 112 d , and process parameters 113 a through 113 d , respectively.
- the target map may for example be a two-dimensional image that shows where material is to be deposited in the layer. In FIG. 3 the target maps are shown with black pixels indicating that material is to be deposited at the corresponding layer position, and white pixels indicating that no material is to be deposited.
- the target map may have non-binary values at positions; for example, target maps may be described as grayscale images.
- target maps may have additional information such as the type of material or materials to be deposited at each location.
- FIG. 3 shows three illustrative process parameters 301 through 303 for each layer.
- a process parameter may describe any factor that affects the manufacturing of a layer or that affects any maintenance activities to be performed.
- Illustrative parameter 301 defines the current density that may be set to construct the layer, which is specified for example as a percentage of the maximum current density supported by the manufacturing equipment.
- Illustrative parameter 302 indicates whether a layer may require lateral deposition of material. This parameter may be based on whether the build planning system detects overhangs, as described below with respect to FIG. 6 .
- the manufacturing system may reposition the cathode vertically relative to the anode throughout the manufacturing of the layer, so that deposited material remains at a relatively fixed distance from the anode as it accumulates on the layer; this “gliding” movement may for example reduce the chance of short-circuits developing between the anode and the cathode.
- Illustrative parameter 303 is the target height of the layer. In some situations the layer height may be higher on initial layers (such as layer 112 d ) to allow for easier bubble clearing. Layers with overhangs (such as layer 112 b ) may have lower heights to allow them to build with more dimensional stability, for example.
- Process parameters for a layer may also include the target output from each anode in the anode array when constructing the layer. In simple situations this output may match the target map for the layer: anodes may be turned on if they are in the position where material is to be deposited, and turned off otherwise. In other situations the relationship between anode output and the target map may be more complex, as illustrated for example below with respect to FIGS. 11A, 11B, 11C, and 12 .
- FIG. 4 illustrates density manipulation on the base layer 112 d of object 101 a .
- This layer is added first to the cathode, and other layers are then constructed on top of the base layer.
- the porosity of the layer may make it easier to remove the object from the cathode after manufacturing is complete.
- Density may be reduced by manipulating the target map to reduce the number of pixels where material is to be deposited. For example, deposition may be turned off at random positions with a probability equal to 100% less the target density.
- the density 401 parameter is applied to the original target map 112 d to generate a modified target map 402 , where 70% of the pixels of the original target map have been turned off (“off” pixels are shown as white in the image).
- This modified target map 402 results in base layer 403 deposited onto cathode 220 (shown as a vertical cross section in FIG. 4 ). Additional layers 404 are constructed on top of the base layer to form the complete part. Removal 405 of the part from the cathode 220 may be facilitated by the porosity of the base layer 403 .
- FIGS. 5 and 6 show illustrative build planning and manufacturing for a layer that has significant overhang.
- Overhangs are features that extend horizontally without material to support them in the layer below.
- supports In traditional 3D printing with plastics, supports must often be added explicitly to support these overhangs, and then removed in a post-production step.
- FIG. 5 illustrates how overhangs may be identified in one or more embodiments.
- the target map 112 b of a layer may be compared to the target map 112 c of the layer underneath (or to several such layers), for example with a differencing operation 501 .
- FIG. 6 shows illustrative steps to manufacture a small portion 601 b of the overhang of layer 112 b above area 601 c in the layer 112 c below. This portion 601 b is effectively a “bridge” that rests on two supporting columns below. The columns 610 have been constructed in previous layers, with the top of these columns corresponding to region 601 c of target map 112 c .
- Construction of the bridge proceeds in three illustrative sub-steps within layer 112 b .
- material 611 is added on top of columns 610 ; this sub-step corresponds to a subset 621 of the target map 112 b .
- material 612 is added laterally out from the columns, corresponding to a subset 622 of the target map 112 b .
- material 613 is added laterally in the middle, corresponding to a subset 623 of the target map 112 b , resulting in final structure 614 .
- the number of lateral build steps required may vary based for example on the size of the overhang and on the binding strength of the material.
- overhang processing may also include reducing the height of layers in the regions of overhangs in order to achieve the deposit required. This may be done for example by changing the layer height to make the overhang distance match some ratio of the pixel pitch. For example, with a 45 degree overhang and a pixel pitch of 50 um, the layer height may be set to 50 um, which will cause the overhang distance to be 50 um (1 pixel width). On a 60 degree overhang, the layer height would be ⁇ 29 um in order to have an overhang distance of 50 um. These two examples show a 1:1 ratio, where the overhang distance is increased by 1 pixel per layer. For a 2:1 ratio, the layer heights would be doubled, resulting in an overhang distance of 100 um or 2 pixels for each layer. This may be done because it results in a more stable and consistent build of the overhang regardless of overhang angle.
- FIGS. 7 through 10 show illustrative feedback signals and analysis of these feedback signals to determine whether a layer is complete or to modify process parameters for layer manufacturing.
- FIG. 7 shows an illustrative method of feedback based on current sensors 223 a that may for example be connected to the anodes of the deposition anode array 201 .
- Current sensors may be used to estimate the extent of deposition proximal to each anode in the anode array, since the impedance between an anode and the cathode may vary based on the proximity of the anode to the deposited conductive material on the cathode.
- anodes may be set to a known voltage, and the current flowing from each anode may then be inversely proportional to this impedance.
- FIG. 7 shows an illustrative method of feedback based on current sensors 223 a that may for example be connected to the anodes of the deposition anode array 201 .
- Current sensors may be used to estimate the extent of deposition
- FIG. 7 shows illustrative anodes 701 through 706 , and an illustrative part 230 a that has been partially constructed.
- Current sensors 223 a measure currents 710 through each anode.
- the anode has formed a short-circuit with the deposited material; thus the measured current 713 is very high.
- the anode 704 the anode is very close to the deposited material, but is not quite short-circuited, so the measured current 714 is below the level 713 of the short-circuited anode 703 .
- Anode 701 is far from the deposited material, so the measured current 711 is very small.
- the feedback signals such as current sensor data 710 may be processed further to generate an analysis of the extent of deposition at locations within the part. This processing may for example be based on known or estimated relationships between the extent of deposition and the feedback signals.
- FIG. 8 shows an illustrative analysis of a two-dimensional map 801 of current measured by current sensors 223 a . In this map 801 , brighter pixels correspond to higher measured current. Analysis 127 of the current map 801 may for example apply a thresholding operation 802 to select pixels that exceed a specified current level, resulting in preliminary deposition analysis 128 .
- This illustrative deposition analysis 128 is a binary image, with white pixels showing regions of high deposition and black pixels showing regions of lower deposition.
- Thresholding operation 802 is illustrative; one or more embodiments may analyze feedback signals 801 in any desired manner to generate a deposition analysis.
- the deposition analysis 128 may then be used to make determination 129 of whether deposition of a layer is complete, and determination 130 of whether modifications to any process parameters are needed for continued construction of a layer.
- FIGS. 9A and 9B show an illustrative analysis 129 to determine layer completeness
- FIG. 10 shows an illustrative analysis 130 of how to modify process parameters.
- FIG. 9A shows an illustrative process to compare deposition analysis 128 to a layer target map 900 to determine whether manufacturing of the layer is complete.
- the target map 900 indicates where material should be deposited in the layer, with black pixels corresponding to material and white pixels corresponding to no material.
- the deposition analysis 128 shows areas of high current, which may for example indicate areas of short circuits where the anode and deposited material are in contact or are very close.
- the deposition analysis 128 may be further processed to form an estimate of where material has been deposited in the layer.
- image 128 may be modified using any transformations including for example, without limitation, morphological filters, linear or nonlinear filters, or Boolean operations.
- the resulting modified map 911 may provide an improved indicator of where deposition has occurred, since for example locations close to short-circuited anodes may also have high levels of deposition.
- This modified map 911 may then be compared to the target map to determine the extent to which the estimated deposition matches the desired deposition for the layer.
- First the target map 900 may be inverted in operation 902 , so that in both the resulting inverted target map 912 and the modified deposition analysis 911 the white pixels correspond to deposition locations.
- a count 913 of the white (“on”) pixels in inverted target map 912 indicates how many positions in the layer should receive deposited material.
- the modified deposition map 911 and the inverted target map 912 may then be ANDed in operation 920 ; the resulting map 921 shows the pixels that correspond to positions that should have deposited material (according to the target map) and that do have deposited material (according to the deposition analysis).
- the count 922 of white (“on”) pixels in 921 may then be compared to the count 913 of desired “on” pixels; the ratio of these values 923 is a percentage of completion measure for the layer. In one or more embodiments, this completion percentage ratio may be compared to a threshold, and the layer may be considered complete when the threshold percentage is reached or exceeded.
- 9A are illustrative; one or more embodiments may apply any transformations or operations to the deposition analysis 128 or the target map 900 to determine whether a layer is complete, including but not limited to morphological operations such as 901 or Boolean operations such as 902 and 920 .
- FIG. 9A shows an illustrative extension of the method of 9 A that applies a completion threshold to subregions.
- subregions may be defined in any desired manner. For example, a layer may be divided into a regular grid of tiles of any resolution, and completion criteria may be applied to each tile.
- FIG. 9B illustrates an approach that divides the target map into “islands” of connected components, and that applies completion criteria separately to each island.
- Target map 912 (inverted as in FIG.
- the modified deposition analysis map 911 is partitioned into these island regions, resulting in four deposition analyses 921 a through 921 d , corresponding to the islands 912 a through 912 d .
- the percentage of white (“on”) pixels indicates the level of completion of deposition within the associated island.
- These individual island completion percentages 923 a through 923 d may then be analyzed to determine whether the layer is complete. For example, a threshold may be applied to each of the island completion percentages, and the layer may be complete only when all of the islands meet or exceed this threshold. In one or more embodiments, different completion criteria may be applied to different islands, and the overall layer may be complete only when each island meets its respective completion criterion.
- completion criteria for a layer or for individual islands may be based on other factors instead of or in addition to a percentage of completion of desired deposited pixels.
- a layer or an island may be considered complete if all or a certain number or fraction of pixels within the layer or island where deposition is desired are within a specified threshold distance of one or more deposited pixels.
- the set of pixels where deposition is desired, and the set of pixels where deposition has occurred (to a desired level of completion) may be determined as described above.
- elapsed time of deposition, charge used for deposition, overall current, and/or impedance between the electrodes may be used as part of the determination whether a layer is done.
- FIG. 10 shows an illustrative example of how the deposition analysis 128 may be used to adjust process parameters during the construction of the associated layer until the layer is determined to be complete.
- the deposition analysis 128 may first be transformed using any type of filters or operations.
- FIG. 10 shows an erosion operation 1001 applied to the deposition analysis 128 to generate a modified deposition analysis 1002 .
- This erosion operation 1001 which is an example of a morphological filter, shrinks regions of white pixels by removing pixels from region boundaries. The resulting map 1002 therefore may represent a more conservative estimate of where deposition has occurred.
- the erosion operation 1001 is illustrative; one or more embodiments may apply any type of transformation to deposition analysis 128 , including for example, without limitation, morphological filters, linear or nonlinear filters, or Boolean operations.
- Modified map 1002 may then be inverted in operation 1003 to yield map 1004 , where the black pixels correspond to the eroded regions of deposition, and the white pixels correspond to locations with potential lack of sufficient deposition.
- This map 1004 may then be ANDed with the inverted target map 912 , yielding a map 1006 that may be used to modify the process parameters for further construction of the layer.
- white (“on”) pixels correspond to locations where deposition is desired but may not yet be sufficiently complete.
- This map may therefore be used to set the outputs 1007 of the anodes in the anode array, so that deposition continues for anodes that correspond to the “on” pixels of map 1006 .
- Anode outputs may be set for example by setting anode currents 1011 , by setting anode voltages 1012 , or by setting anode duty cycles 1013 , or by using a combination of these methods.
- FIG. 10 illustrates feedback control that generates essentially binary control signals for anodes, such as map 1006 . Anodes may then be turned on or off based on these control signals.
- anode control (or control of any other process parameters) may use non-binary control signals; for example, anode currents may be varied continuously from zero to a maximum value based on analysis of the feedback signals.
- FIGS. 11A, 11B, 11C, and 12A illustrate this process using a one-dimensional model of anode arrays for ease of presentation. Similar concepts may be applied in one or more embodiments to two-dimensional anode arrays; an example in two dimensions is shown in FIG. 12B .
- FIG. 11A shows illustrative deposition 1111 onto cathode 220 when only a single anode 1101 of anode array 201 is energized.
- material may be deposited onto the cathode at positions that are not directly across from the energized anode.
- deposition 1111 may occur in an approximately Gaussian pattern that is centered across from an energized anode, and that spreads out laterally from this center.
- FIG. 11B shows an illustrative deposition pattern 1112 when multiple anodes 1101 , 1102 , and 1103 are energized.
- the deposition pattern may be approximately the sum of the deposition patterns from each of the individual anodes 1101 , 1102 , and 1103 .
- FIG. 11B illustrates that deposition may be higher at the center (across from anode 1101 ) than at the edges, due to the additive effects from all three of the anodes.
- FIGS. 11A and 11B may be to modify the pattern of anode outputs via a convolution 1141 with a point spread function 1140 that describes the spread of deposition from a single anode point source.
- FIG. 11C shows an illustrative pattern 1130 of anode current that is constant within a range from 1121 to 1122 , and zero outside this range. Because of convolution 1141 , the actual deposition thickness will not match the input shape 1130 , but instead will have shape 1150 with higher accumulation in the center, and with some deposition extending beyond the bounds 1121 and 1122 .
- FIG. 12A shows an illustrative approach that may be used in one or more embodiments.
- the build planning process may perform a deconvolution 1210 or other transformation to reverse the effects of the distortion illustrated in FIGS. 11A through 11C .
- target map 1201 with a constant thickness between bounds 1121 and 1122 may be deconvolved to an anode current pattern 1211 .
- the illustrative anode current has a higher value 1212 at the edges, and some anodes such as 1214 within the central region of the rectangular pattern may be turned off entirely. In addition, some anodes such as anode 1213 may have nonzero currents even if they are outside the bounds 1121 and 1122 .
- Transformations 1210 may include any deconvolution methods or any other function transformation or image processing methods. These transformations may be based on any measurements or models of the deposition process, including for example a point spread function 1140 that describes how anode currents are mapped to deposition patterns.
- FIG. 12B shows a two-dimensional example of transformation of a target map into a desired anode current pattern.
- Target map 1220 shows areas of desired deposition (in black) for a particular layer of a part build.
- transformations 1210 which may for example include deconvolution or any other type of image processing, may be applied to this target map 1220 to generate a pattern 1230 that indicates the anode current pattern that may be generated to achieve the desired deposition.
- anodes are turned on for the anodes that correspond to anodes with desired deposition, and additional anodes (shown as cross-hatched regions) are turned on around the edges and the corners of the deposition area.
- edge anodes are turned on around each outer edge, such as anodes 1231 along the top edge, and additional anodes are turned on around the corners, such as anodes 1232 around the top right corner. Turning on these additional edge and corner anodes helps to shape the field of current to drive deposition of material more evenly at the corresponding edges and corners of target map 1220 .
- One or more embodiments may also modify anode currents over time in a preprogrammed or adaptive pattern, as illustrated in FIG. 13 .
- subsets of anodes may be successively switched on and off during the manufacturing of a layer. This alternation may for example compensate for potential depletion of metal ions in the electrolyte that might occur if anodes output a constant current throughout the construction of a layer. It may also prevent formation of bubbles in the electrolyte.
- target map 112 e has a square central area 1301 where material is to be deposited.
- one or more embodiments may alternate current from two subregions 1311 and 1312 , which partition the region 1301 into a checkerboard pattern.
- anodes in region 1311 emit current 1331
- anodes in region 1312 are switched off
- anodes in region 1311 are switched off
- anodes in region 1312 emit current 1332 .
- This alternation may for example allow ions 1310 in the electrolyte to diffuse into the regions adjacent to the switched-off anodes so that these regions are not depleted.
- the checkerboard pattern of regions 1311 and 1312 is illustrative; one or more embodiments may divide anodes into any number of regions of any shape and size, and may switch anodes of these regions on and off in any desired pattern with any desired duty cycles.
- FIG. 14 shows illustrative maintenance actions that may be performed during the manufacturing process in one or more embodiments. These actions may for example be interleaved with deposition, or they may be performed between manufacturing of layers. The actions shown are illustrative; one or more embodiments may perform any desired maintenance activities at any point in the manufacturing process.
- FIG. 14 shows three illustrative issues that may arise during manufacturing that may require maintenance activities. First, anodes in the anode array 201 may erode, such as anode 1401 , and may need to be replenished or resurfaced. Second, films such as film 1402 may form over anodes and prevent them from effectively driving deposition onto the cathode. Third, bubbles such as 1403 may form in the electrolyte between the anode array and the deposited material 230 .
- anodes such as anode 1401 may erode, even if anodes are constructed of a largely insoluble material.
- One or more embodiments may periodically or as-needed reverse this erosion using a secondary anode 1410 .
- the deposition process may for example be paused and the power supply 221 may be reversed using switches 1411 and 1412 , so that the anode array temporarily acts as a cathode, and the secondary anode 1410 acts as the anode.
- Current flowing from the secondary anode 1410 may then cause material 1413 to flow from the secondary anode to the eroded anodes in array 201 .
- the secondary anode 1410 may for example be a large bulk anode that is composed of an inert material like platinum.
- the secondary anode may be composed of the metal that is used for electrodeposition, such as copper for example; this metal will dissolve and plate onto the anodes of anode array 201 without depleting the metal in the electrolyte solution.
- the switches 1411 and 1412 are reversed again, the metal plated onto the anode array then plates onto the cathode.
- target deposition material such as copper from a copper electrolyte bath
- target deposition material may end up plated onto a surface of the electrode array as a film 1402 .
- This film of target material may bridge between multiple deposition electrodes and may impact their ability to be individually addressed.
- a film may be detected from the feedback signals, for example when a group of adjacent anodes shows an abnormally high current.
- a film may be removed for example by moving cathode 220 far away from the anode array and activating the anodes covered by the film. This action dissolves the film while not causing an unintended deposit on the cathode.
- Bubbles 1403 may form in the space between the anode array 201 and the part 230 .
- Bubbles may be removed for example by manipulating or modifying the flow 1420 of electrolyte, for example with pumps or agitators, or by inducing vibrations 1421 in the electrolyte to dissipate the bubbles. Vibrations may be introduced into the electrolyte using a vibration oscillator in contact with the electrolyte, or by vibrating the cathode, anode array, or reaction chamber.
- Flow manipulation may also include purposefully increasing the distance between the build and the anode array to allow for greater fluid flow and/or bubble removal, while either keeping the anodes energized or de-energized until the flow manipulation is complete.
- all or portions of the feedback signals, control parameters, and deposition analyses measured or generated throughout a build of a part may be maintained as quality control records.
- This data may be used for any or all of several purposes, including for example facilitating or eliminating part inspections, supporting certification of parts or manufacturing processes, and post-mortem analysis of part failures or part performance issues.
- this quality control data may be aggregated across parts, lots, or facilities and used for statistical process control and for continuous process improvement. For example, data on part performance in the field (such as failure rates or part lifetimes) may be correlated with the part quality control data to discover correlations between process parameters and part performance; these correlations may then be used to improve future part build processes.
- machine learning techniques or other artificial intelligence techniques may be used to automatically discover relationships between build record information and part performance. For example, analysis of large numbers of parts and their associated quality control records may show that a lower current density for particular types of layers results in higher part failures; a manufacturer may use this type of information to modify build processes to reduce future failure rates.
- the database of build quality information for parts may be used to predict failures for previously built parts, allowing them to be potentially recalled or replaced prior to failure.
- FIG. 15 shows an illustrative part 1501 that was manufactured using an embodiment of the invention. Feedback control of the manufacturing process using techniques described above enables the extremely fine resolution and high quality of this completed part.
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Abstract
Description
- This patent application claims the benefit of U.S. Provisional Patent Application Ser. No. 62/983,274, filed 28 Feb. 2020 and U.S. Provisional Patent Application Ser. No. 62/890,815, filed 23 Aug. 2019, the specifications of which are hereby incorporated herein by reference.
- One or more embodiments of the invention are related to the fields of electronics and 3D printing. More particularly, but not by way of limitation, one or more embodiments of the invention enable a method of electrochemical additive manufacturing using deposition feedback control.
- Additive manufacturing, also known as 3D Printing, is often used for the production of complex structural and functional parts via a layer-by-layer process, directly from CAD (computer aided drafting) models. Additive manufacturing processes are considered additive because materials are selectively deposited on a substrate to construct the product. Additive manufacturing processes are also typically layered meaning that layers of the product to be produced are fabricated sequentially.
- Currently, widespread use of metal additive manufacturing techniques is limited due to the high cost associated with selective laser melting (SLM) and electron beam melting (EBM) systems. Further, most metal additive manufacturing devices currently in the industry use powdered metals which are thermally fused together to produce a part, but due to most metals' high thermal conductivity this approach leaves a rough surface finish because unmelted metal powder is often sintered to the outer edges of the finished product.
- An emerging alternative for additive metal manufacturing is to use electrochemical reactions. In an electrochemical manufacturing process, a metal part is constructed by plating charged metal ions onto a surface in an electrolyte solution. This technique relies on placing a deposition anode physically close to a substrate in the presence of a deposition solution (the electrolyte), and energizing the anode causing charge to flow through the anode. This creates an electrochemical reduction reaction to occur at the substrate near the anode and deposition of material on the substrate. An illustrative apparatus that enables additive manufacturing via electroplating is described for example in U.S. Utility Pat. No. 10,465,307, “Apparatus for Electrochemical Additive Manufacturing,” by the inventors of the instant application. This apparatus demonstrated a novel approach to electrochemical additive manufacturing that uses a printhead with an array of anodes to build portions of each layer of a part in parallel, instead of moving a single anode across a part to sequentially construct portions of the layer.
- Additive manufacturing processes known in the art typically add material in pre-programmed patterns. For example, material may be emitted from a printhead for a preprogrammed period of time at a preprogrammed rate to construct a layer of a part. In electrochemical manufacturing, the rate and pattern of material deposition depends on many dynamic factors, such as the distance between the printhead and each location of the part, the local density of metal ions in the electrolyte, and electrolyte flow patterns. As a result, it is difficult or impossible to achieve high quality parts using strictly preprogrammed (“open loop”) control. However, feedback control methods for electrochemical additive manufacturing processes are not well-developed.
- One or more embodiments described in the specification are related to an electrochemical additive manufacturing method using deposition feedback control. An object to be manufactured may be constructed by placing a cathode and an anode array into an electrolyte solution. Deposition anodes of the anode array may provide current that flows from the anode to the cathode through the electrolyte solution, resulting in deposition of the material onto the cathode. The manufacturing process may use a build plan with a layer description for multiple layers of the object; each layer description may include a target map, which describes the presence or absence of material at locations within the layer, and one or more process parameters that affect the layer build. Manufacturing of a layer may begin by setting or confirming the position of the cathode relative to the anode array. Then control signals may be sent to the anode array based on the layer description. One or more feedback signals may be measured across the anode array, and these signals may be analyzed to generate a deposition analysis that indicates the extent to which deposition has progressed at locations within the layer. The deposition analysis may be used to determine whether the layer is complete, and to modify the process parameters associated with the layer. When a layer is complete, manufacturing may continue for a subsequent layer.
- In one or more embodiments, the layer description of one or more layers may be modified before manufacturing the layers. For example, layer densities may be changed.
- Analysis of feedback signals may apply one or more transformations to these signals, such as morphological filters or Boolean operators.
- Feedback signals may for example include a map of current across the anode array. The deposition analysis may be generated by applying a thresholding operation to this current map.
- Determining whether a layer is complete may for example include comparing the number of actual deposited pixels to the number of desired deposited pixels within the layer. In one or more embodiments, a layer may be complete when the ratio of actual to desired deposited pixels reaches or exceeds a threshold value. In one or more embodiments, a layer may be complete when a desired fraction of the desired deposited pixels are within a threshold distance from an actual deposited pixel. In one or more embodiments, the layer may be divided into components, and completion tests may be applied to each component; a layer may be considered complete when all components are complete. For example, a component may be complete when the ratio of actual to desired deposited pixels within the component reaches or exceeds a threshold value, or when a desired fraction of the desired deposited pixels within the component are within a threshold distance from an actual deposited pixel.
- In one or more embodiments, a layer description may include identification of whether a layer has an overhang. Manufacturing of a layer with an overhang may include successively depositing portions of the overhang so that they extend laterally from one or more previously deposited portions.
- In one or more embodiments, a layer target map may be divided into regions, and construction of the layer may include alternately activating deposition anodes associated with each region.
- In one or more embodiments, manufacturing of a layer may include calculating a map of desired current output from each deposition anode, so that this current output will generate deposition corresponding to the layer's target map. This current map calculation may involve applying one or more transformations to the layer target map.
- In one or more embodiments, modification of process parameters associated with a layer may include calculation of voltage, current, or time of activation for one or more deposition anodes.
- In one or more embodiments, setting or confirming the position of the cathode relative to the anode may include obtaining sensor signals that vary based on this relative position, such as a current value or a voltage value.
- In one or more embodiments, manufacturing of a layer may include one or more maintenance actions that maintain the condition of the anode array or the electrolyte solution. For example, these maintenance actions may replace material onto one or more deposition anodes that have eroded. Maintenance actions may activate one or more deposition anodes to remove a film that has formed. Maintenance actions may include removal of bubbles from the electrolyte solution.
- The above and other aspects, features and advantages of the invention will be more apparent from the following more particular description thereof, presented in conjunction with the following drawings wherein:
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FIG. 1 shows a flowchart of an embodiment of the invention that successively manufactures layers using feedback control to assess layer completion and to adjust parameters during manufacturing. -
FIG. 2 shows an architectural block diagram of illustrative electrodeposition equipment that may be used to implement one or more embodiments of the invention. -
FIG. 3 shows an illustrative build plan for layers of an object, with target maps for each layer showing desired areas of deposited material, and process parameters describing how the layer is to be manufactured. -
FIG. 4 illustrates density manipulation to generate a porous base layer that facilitates part removal. -
FIG. 5 illustrates detection of an overhang in a layer. -
FIG. 6 illustrates manufacturing steps for the overhang detected inFIG. 5 . -
FIG. 7 shows an illustrative embodiment of feedback using current sensors across the anode array. -
FIG. 8 shows an illustrative map of current sensor feedback signals, and processing of these signals to form a map of deposition areas within a layer. -
FIG. 9A shows an illustrative method to test for layer completion based on the current sensor data ofFIG. 8 . -
FIG. 9B shows an extension of the layer completion test ofFIG. 9A , which tests separately for completion of all connected components of the layer. -
FIG. 10 illustrates update of anode outputs based on the current sensor feedback signals ofFIG. 8 . -
FIGS. 11A, 11B, and 11C illustrate a potentially complex relationship between anode currents and deposited material, which may require pre-processing to obtain the desired deposition pattern. -
FIG. 12A illustrates calculation of anode currents to obtain a desired deposition pattern. -
FIG. 12B shows an illustrative two-dimensional example of calculating a pattern of anode currents to obtain a desired deposition pattern. -
FIG. 13 shows an illustrative embodiment that alternates anode output across different regions. -
FIG. 14 shows illustrative maintenance actions that may be performed during layer manufacturing to address issues in the anode array or the electrolyte. -
FIG. 15 shows an illustrative part manufactured using an embodiment of the invention. - An electrochemical additive manufacturing method using deposition feedback control will now be described. One or more embodiments of the invention may enable manufacturing of objects by passing electrical current through an electrolyte to deposit material onto the object, and by monitoring feedback signals during deposition to adjust manufacturing process parameters throughout the process. In the following exemplary description, numerous specific details are set forth in order to provide a more thorough understanding of embodiments of the invention. It will be apparent, however, to an artisan of ordinary skill that embodiments of the invention may be practiced without incorporating all aspects of the specific details described herein. In other instances, specific features, quantities, or measurements well known to those of ordinary skill in the art have not been described in detail so as not to obscure the invention. Readers should note that although examples of the invention are set forth herein, the claims, and the full scope of any equivalents, are what define the metes and bounds of the invention.
- In an electrochemical additive manufacturing process, a metal part is constructed by reducing charged metal ions onto a surface in an electrolyte solution. This technique relies on placing a deposition anode physically close to a substrate in the presence of a deposition solution (the electrolyte), and energizing the anode causing charge to flow through the anode. This creates an electrochemical reduction reaction to occur at the substrate near the anode and deposition of material on the substrate. A particular challenge of electrochemical manufacturing is that the rate and quality of deposition of material may be highly variable, and may vary across time and across locations based on multiple factors such as current density, electrolyte composition, fluid flows within the electrolyte, and distances between anodes and previously deposited material. For this reason, the inventors have discovered that an important factor in constructing high-quality parts with electrochemical additive manufacturing is to employ a “closed loop” feedback control system that monitors deposition throughout the manufacturing process, and that adjusts manufacturing parameters accordingly. This approach contrasts with a typical “open loop” additive manufacturing process used by most 3D printers, for example, where layers are constructed successively based on pre-programmed commands.
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FIG. 1 shows illustrative steps for an electrochemical additive manufacturing process that incorporates deposition feedback control. These steps are illustrative; one or more embodiments may use different or additional steps and may perform operations in different orders. The manufacturing process illustrated inFIG. 1 has aplanning phase 100, and abuilding phase 120. In theplanning phase 100, amodel 101 of an object is analyzed by planning step orsteps 102 to generate abuild plan 103 for construction of the object. The planning step orsteps 102 may execute on any processor or processors, such as for example, without limitation, a computer, a microprocessor, a microcontroller, a desktop, a laptop, a notebook, a server, a mobile device, a tablet, or a network of any of these processors. In one or more embodiments, the planning step (or steps) 102 may for example slice a3D object model 101 into layers, and develop a plan to construct each layer. Thebuild plan 103 may include a layer description for each layer; a layer description may include for example a target map for the layer and various process parameter values for construction of the layer. The target map may include a two-dimensional grid or image showing locations within the layer where material is to be deposited. The process parameters for a layer may include any variables that affect the physical or electrical processes that construct the layer; these parameters may include for example, without limitation, current density range, voltage range, layer height, movement parameters, overhang controls, safety thresholds, leakage thresholds, short circuit determination threshold values, pixel mapping intervals and thresholds, debubble values, fusing, anode cleaning, islanding, distance to short, distance to short percentage, pixel limits, slow current control values, and maximum blob size.FIG. 1 shows anillustrative layer description 111 for a first layer of an object, which includes atarget map 112 for the layer andprocess parameters 113 for the layer; subsequent layers have similar layer descriptions with target maps and process parameters. The build planning step orsteps 102 may also generateoverall process parameters 115 that apply to all of the layers in the build, or that may be used as default values that apply unless a layer description overrides the defaults. - The
build phase 120 of the process constructs an object from thebuild plan 103, using for example equipment that performs electrochemical deposition. Illustrative equipment that may be used in one or more embodiments of the invention is described below with respect toFIG. 2 . To initiate the build process, a surface of a cathode may be placed in contact with an electrolyte solution instep 121; the object may be constructed by electrochemically depositing material onto the cathode by passing current through an anode array that is also in contact with the solution. Layers inbuild plan 103 may then be built successively onto the base of the cathode or onto previously constructed layers, effectively enlarging the cathode for purposes of deposition. For each layer in the build plan, the layer description is retrieved or loaded instep 122. The layer description may for example be loaded into a memory accessible to a controller of the electrochemical deposition equipment; this controller may be any type or types of processors. For example, to start object construction, thefirst layer description 111 may be loaded or retrieved. The controller may then performstep 123 to set or confirm the relative position between the anode and the cathode. As layers are successively built, the distance between the anode and the cathode may need to be modified so that the anode distance from the most recently deposited surfaces remains within a range that enables sufficient control of the deposition process. For example, the electrochemical deposition equipment may include an actuator that can move either or both of the cathode and the anode, as illustrated below with respect toFIG. 2 . For the first layer,step 123 may for example involve a “zeroing” procedure that sets the initial relative position between the anode and the cathode to a desired initial value. The specific methods used for zeroing may vary depending on the deposition equipment. For example, in one or more embodiments the controller may move the cathode or anode until one or more sensors indicate contact (or sufficiently close proximity) between the two, and it may then offset a desired distance from this contacting position. In one or more embodiments there may be sensors such as absolute or relative encoders on the position actuator that assist in zeroing. - For layers after the first layer,
step 123 may ensure that the relative position between the anode and cathode is correct to begin deposition of material for the new layer. In some cases this may require modifications to the relative position, for example using an actuator that moves the anode or the cathode. For example, in some situations an object may be constructed by successively depositing material for a layer, then repositioning the cathode relative to the anode to move the cathode away from the anode to prepare for the next layer, and then depositing material for the next layer. In other situations relative movement between the anode and cathode may be performed throughout construction of a layer, sometimes referred to as “gliding,” so that no additional repositioning is required atstep 123 when a new layer is loaded. - After a layer description is loaded in
step 122, and the relative position of the cathode and anode is set or confirmed instep 123, thebuild process 120 enters aninner loop 140 of steps that may be executed to construct the loaded layer. As described above, this loop may be a closed loop with feedback control, so that build steps and process parameters may be modified throughout the loop based on measured feedback signals. Step 125 may include various actions to deposit material via electrochemical reactions (for example, by passing current through anodes) as well as actions that maintain or adjust the state or health of the anode array and the electrolyte. Illustrative maintenance actions may include for example, without limitation, removal of bubbles from the electrolyte, agitation of the electrolyte to modify flow rates or to modify distribution of ions in the electrolyte, and actions to remove films from anodes or to replenish anode surfaces. Any of these maintenance actions may be interleaved with deposition actions in any desired manner. - At selected times or periodically during the construction of a layer,
step 126 may be performed to obtain feedback signals that may for example indicate how deposition is progressing. One or more embodiments may use any type or types of sensors to obtain feedback signals. For example, in one or more embodiments the current through each anode in an anode array may be measured (for example with a fixed voltage); a higher current may correspond to a lower impedance between the anode and the cathode, which may be correlated with the amount of material deposited on the cathode in the vicinity of each anode. In other embodiments, a variable voltage waveform may be used, and alternating current (AC) signals may be measured. One or more embodiments may use other feedback signals such as optical images of the cathode or distance measurements to points on the cathode. Instep 127 these feedback signals may be analyzed to generate adeposition analysis 128, which may include estimates of the amount of material deposited at locations within the layer. Based on thedeposition analysis 128, adetermination 129 may be made as to whether construction of the layer is complete. If the layer is complete, and iftest 132 indicates that there are more layers to be constructed, then a next layer is loaded instep 122 and thelayer construction loop 140 is executed for that next layer; otherwise construction of the object is finished. In some embodiments, the generation of deposition maps may be performed concurrently with the deposition process. For example, additional sensing elements may be incorporated into the fabrication of the anode array to enable continuous characterization of the current flowing through each deposition anode, or the voltage at each deposition anode surface. This could be performed, for instance, by an Analog to Digital converter (ADC) whose inputs are sequentially connected to successive rows of deposition anodes in a multiplexing method similar to that used in the addressing of the anode array. - If
test 129 indicates that deposition for a layer is not complete, then in some situations thedeposition analysis 128 or other data from the feedback signals may be used to modify the parameters and control signals that are used to construct the layer. Atest 130 may be performed to determine whether any adjustments are required. If they are required, then one ormore process parameters 131 may be modified, and this may modify the control signals 124 that drive the deposition (and maintenance) actions. As one example, if thedeposition analysis 128 indicates that enough material has been deposited in certain areas of a layer, then current may be turned off (or turned down) for anodes corresponding to those areas. -
FIG. 2 shows an architectural diagram of illustrative equipment that may be used to perform build steps of one or more embodiments of the invention. The system has aprinthead 200 that contains anarray 201 of deposition anodes, and acorresponding array 202 of deposition control circuits for the deposition anodes. In one or more embodiments, thedeposition control circuits 202 may be organized in a matrix arrangement, thereby supporting high resolution anode arrays. Thedeposition anode array 201 may be organized in a two-dimensional grid;FIG. 2 shows a cross sectional view. Agrid control circuit 203 transmits control signals to thedeposition control circuits 202 to control the amount of current flowing through each deposition anode inanode array 201. Current flowing through the anodes is provided by apower distribution circuit 204 that routes power from one ormore power supplies 221 to the deposition control circuits and then to the anodes.Printhead 200 may also contain other elements such as insulation layers, for example to protect elements of the printhead from the electrolyte solution. - The
deposition anode array 201 ofprinthead 200 may be placed in anelectrolyte solution 210. Electrochemical reactions may then cause plating of metal onto amanufactured part 230 that is coupled tocathode 220. Intricate and detailed shapes may be built inpart 230 by modifying the current flowing through each anode ofdeposition anode array 201. For example, in the snapshot shown inFIG. 2 ,anode 211 is energized, so that metal is being deposited ontopart 230 near this anode, butanode 212 is not energized so no metal is being deposited near that anode. - In one or more embodiments,
printhead 200 may be integrated with aprocessor 222. This processor may transmit signals togrid control circuit 203, which sends signals to the individualdeposition control circuits 202 to turn anodes indeposition anode array 201 on or off (or to modify the intensity of current flow through each anode).Processor 222 may be for example, without limitation, a microcontroller, a microprocessor, a GPU, a FPGA, a SoC, a single-board computer, a laptop, a notebook, a desktop computer, a server, or a network or combination of any of these devices.Processor 222 may be the same as or different from a processor or processors that analyze an object model to construct a build plan.Processor 222 may communicate with one ormore sensors 223 that may generate the feedback signals that measure the progress of metal deposition onpart 230.Sensors 223 may include for example, without limitation, current sensors, voltage sensors, timers, cameras, rangefinders, scales, force sensors, or pressure sensors. One or more of thesensors 223 may also be used to measure the distance between the cathode and the anode, for example for zeroing to begin manufacturing an object, or to set or confirm the relative position between the anode and cathode at the beginning of each layer. The accurate positioning of the build plate relative to the electrode array at the initialization of the deposition process may have a significant impact on the success and quality of the completed deposit. Embodiments may use various types of sensors for this positioning, including for example, without limitation, mechanical, electrical, or optical sensors, or combinations thereof. In one or more embodiments, mechanical sensors such as a pressure sensor, switch, or load cell may be employed, which detects when the build plate is moved and reaches the required location. In one or more embodiments, portions of the system may be energized, and the cathode may be moved to proximity to the energized component at a known location. When a voltage or current is detected on the cathode or build plate the build plate may be known to be at a given location. One or more embodiments may use other types of sensors that detect for example capacitance, impedance, magnetic fields, or that utilize the Hall Effect to determine the location of the cathode/build plate relative to a known position. One or more embodiments may use optical sensors such as laser rangefinders or sensors that detect interference with an optical path. - Either or both of
cathode 220 andprinthead 200 may be attached to one ormore position actuators 224, which may control the relative position of the cathode and the deposition anode array.Position actuator 224 may controlvertical movement 225, so that the cathode may be raised (or alternatively the anode lowered) as thepart 230 is built in successive layers. In one or more embodiments positionactuator 224 may also move the cathode or deposition anode array horizontally relative to one another, for example so that large parts may be manufactured in tiles. -
Printhead 200 may be connected to a power supply (or multiple power supplies) 221, which supplies current 244 that flows through the deposition anode array to drive metal deposition onpart 230. Current may be distributed throughout the array of deposition control circuits viapower distribution circuit 204, which may for example include one or more power busses. - In one or more embodiments, the system may also include a fluid chamber to contain the electrolyte solution (not shown in
FIG. 2 ), and a fluid handling system (also not shown). The fluid system may include for example a tank, a particulate filter, chemically resistant tubing and a pump. Analytical equipment may enable continuous characterization of bath pH, temperature, and ion concentration using methods such as conductivity, High Performance Liquid Chromatography, mass spectrometry, Cyclic Voltammetry Stripping, spectrophotometer measurements, or the like. Bath conditions may be maintained with a chiller, heater and/or an automated replenishment system to replace solution lost to evaporation and/or ions of deposited material. - Although the system shown in
FIG. 2 has a single array of deposition anodes, one or more embodiments may incorporate multiple deposition anode arrays. These multiple anode arrays may for example operate simultaneously in different chambers filled with electrolyte solution, or they may be tiled in a manner where the anode arrays work together to deposit material on a shared cathode or series of cathodes. -
FIG. 3 shows illustrative elements of a build plan for an object with anobject model 101 a. Theobject model 101 a may be for example a 3D CAD model, or any description of the geometric or material properties of an object. The build planning process may slice this model into layers, and may develop a layer description for each layer.FIG. 3 shows four illustrative layers, each of which corresponds to a horizontal slice throughmodel 101 a. Build plans may have any number of layers and slices may be of any desired thickness, shape, and orientation. Associated with each layer is a layer description that includes a target map, and one or more process parameters. The four layers shown inFIG. 3 havetarget maps 112 a through 112 d, andprocess parameters 113 a through 113 d, respectively. The target map may for example be a two-dimensional image that shows where material is to be deposited in the layer. InFIG. 3 the target maps are shown with black pixels indicating that material is to be deposited at the corresponding layer position, and white pixels indicating that no material is to be deposited. In one or more embodiments the target map may have non-binary values at positions; for example, target maps may be described as grayscale images. In one or more embodiments, target maps may have additional information such as the type of material or materials to be deposited at each location. -
FIG. 3 shows threeillustrative process parameters 301 through 303 for each layer. One or more embodiments may associate any number of process parameters with layer descriptions. A process parameter may describe any factor that affects the manufacturing of a layer or that affects any maintenance activities to be performed.Illustrative parameter 301 defines the current density that may be set to construct the layer, which is specified for example as a percentage of the maximum current density supported by the manufacturing equipment.Illustrative parameter 302 indicates whether a layer may require lateral deposition of material. This parameter may be based on whether the build planning system detects overhangs, as described below with respect toFIG. 6 . For layers that do not require lateral deposition, in one or more embodiments the manufacturing system may reposition the cathode vertically relative to the anode throughout the manufacturing of the layer, so that deposited material remains at a relatively fixed distance from the anode as it accumulates on the layer; this “gliding” movement may for example reduce the chance of short-circuits developing between the anode and the cathode.Illustrative parameter 303 is the target height of the layer. In some situations the layer height may be higher on initial layers (such aslayer 112 d) to allow for easier bubble clearing. Layers with overhangs (such aslayer 112 b) may have lower heights to allow them to build with more dimensional stability, for example. - Process parameters for a layer may also include the target output from each anode in the anode array when constructing the layer. In simple situations this output may match the target map for the layer: anodes may be turned on if they are in the position where material is to be deposited, and turned off otherwise. In other situations the relationship between anode output and the target map may be more complex, as illustrated for example below with respect to
FIGS. 11A, 11B, 11C, and 12 . -
FIG. 4 illustrates density manipulation on thebase layer 112 d ofobject 101 a. This layer is added first to the cathode, and other layers are then constructed on top of the base layer. For a base layer (or a set of base layers) in particular, it may be beneficial to reduce the layer density to make the layer porous. The porosity of the layer may make it easier to remove the object from the cathode after manufacturing is complete. Density may be reduced by manipulating the target map to reduce the number of pixels where material is to be deposited. For example, deposition may be turned off at random positions with a probability equal to 100% less the target density. InFIG. 4 , thedensity 401 parameter is applied to theoriginal target map 112 d to generate a modifiedtarget map 402, where 70% of the pixels of the original target map have been turned off (“off” pixels are shown as white in the image). This modifiedtarget map 402 results inbase layer 403 deposited onto cathode 220 (shown as a vertical cross section inFIG. 4 ).Additional layers 404 are constructed on top of the base layer to form the complete part.Removal 405 of the part from thecathode 220 may be facilitated by the porosity of thebase layer 403. -
FIGS. 5 and 6 show illustrative build planning and manufacturing for a layer that has significant overhang. Overhangs are features that extend horizontally without material to support them in the layer below. In traditional 3D printing with plastics, supports must often be added explicitly to support these overhangs, and then removed in a post-production step. For electrochemical additive manufacturing, many overhangs can be constructed directly, without supports, since metal ions can accumulate laterally and fuse to the overhang structure with sufficient strength that underlying supports may be unnecessary.FIG. 5 illustrates how overhangs may be identified in one or more embodiments. Thetarget map 112 b of a layer may be compared to thetarget map 112 c of the layer underneath (or to several such layers), for example with adifferencing operation 501. This comparison yields adelta map 502, which showsareas 503 where material is being added without material below. If the size of these areas within 503 are sufficiently large, the build planning system may make adetermination 504 that the overhangs require special processing such as lateral construction, as illustrated inFIG. 6 .FIG. 6 shows illustrative steps to manufacture asmall portion 601 b of the overhang oflayer 112 b abovearea 601 c in thelayer 112 c below. Thisportion 601 b is effectively a “bridge” that rests on two supporting columns below. Thecolumns 610 have been constructed in previous layers, with the top of these columns corresponding toregion 601 c oftarget map 112 c. Construction of the bridge proceeds in three illustrative sub-steps withinlayer 112 b. First,material 611 is added on top ofcolumns 610; this sub-step corresponds to asubset 621 of thetarget map 112 b. Second,material 612 is added laterally out from the columns, corresponding to asubset 622 of thetarget map 112 b. Third,material 613 is added laterally in the middle, corresponding to asubset 623 of thetarget map 112 b, resulting infinal structure 614. The number of lateral build steps required may vary based for example on the size of the overhang and on the binding strength of the material. - In one or more embodiments, overhang processing may also include reducing the height of layers in the regions of overhangs in order to achieve the deposit required. This may be done for example by changing the layer height to make the overhang distance match some ratio of the pixel pitch. For example, with a 45 degree overhang and a pixel pitch of 50 um, the layer height may be set to 50 um, which will cause the overhang distance to be 50 um (1 pixel width). On a 60 degree overhang, the layer height would be ˜29 um in order to have an overhang distance of 50 um. These two examples show a 1:1 ratio, where the overhang distance is increased by 1 pixel per layer. For a 2:1 ratio, the layer heights would be doubled, resulting in an overhang distance of 100 um or 2 pixels for each layer. This may be done because it results in a more stable and consistent build of the overhang regardless of overhang angle.
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FIGS. 7 through 10 show illustrative feedback signals and analysis of these feedback signals to determine whether a layer is complete or to modify process parameters for layer manufacturing.FIG. 7 shows an illustrative method of feedback based oncurrent sensors 223 a that may for example be connected to the anodes of thedeposition anode array 201. Current sensors may be used to estimate the extent of deposition proximal to each anode in the anode array, since the impedance between an anode and the cathode may vary based on the proximity of the anode to the deposited conductive material on the cathode. For example, anodes may be set to a known voltage, and the current flowing from each anode may then be inversely proportional to this impedance.FIG. 7 showsillustrative anodes 701 through 706, and anillustrative part 230 a that has been partially constructed.Current sensors 223 ameasure currents 710 through each anode. Foranode 703, the anode has formed a short-circuit with the deposited material; thus the measured current 713 is very high. Foranode 704, the anode is very close to the deposited material, but is not quite short-circuited, so the measured current 714 is below thelevel 713 of the short-circuitedanode 703.Anode 701 is far from the deposited material, so the measured current 711 is very small. - In one or more embodiments, the feedback signals such as
current sensor data 710 may be processed further to generate an analysis of the extent of deposition at locations within the part. This processing may for example be based on known or estimated relationships between the extent of deposition and the feedback signals.FIG. 8 shows an illustrative analysis of a two-dimensional map 801 of current measured bycurrent sensors 223 a. In thismap 801, brighter pixels correspond to higher measured current.Analysis 127 of thecurrent map 801 may for example apply athresholding operation 802 to select pixels that exceed a specified current level, resulting inpreliminary deposition analysis 128. Thisillustrative deposition analysis 128 is a binary image, with white pixels showing regions of high deposition and black pixels showing regions of lower deposition.Thresholding operation 802 is illustrative; one or more embodiments may analyzefeedback signals 801 in any desired manner to generate a deposition analysis. Thedeposition analysis 128 may then be used to makedetermination 129 of whether deposition of a layer is complete, anddetermination 130 of whether modifications to any process parameters are needed for continued construction of a layer.FIGS. 9A and 9B show anillustrative analysis 129 to determine layer completeness, andFIG. 10 shows anillustrative analysis 130 of how to modify process parameters. -
FIG. 9A shows an illustrative process to comparedeposition analysis 128 to alayer target map 900 to determine whether manufacturing of the layer is complete. Thetarget map 900 indicates where material should be deposited in the layer, with black pixels corresponding to material and white pixels corresponding to no material. Thedeposition analysis 128 shows areas of high current, which may for example indicate areas of short circuits where the anode and deposited material are in contact or are very close. In one or more embodiments, thedeposition analysis 128 may be further processed to form an estimate of where material has been deposited in the layer. For example,image 128 may be modified using any transformations including for example, without limitation, morphological filters, linear or nonlinear filters, or Boolean operations.Illustrative operation 901 shown inFIG. 9A is a dilation operation (which is a morphological filter); this operation expands regions of white pixels by adding pixels out from the region boundaries. The resulting modifiedmap 911 may provide an improved indicator of where deposition has occurred, since for example locations close to short-circuited anodes may also have high levels of deposition. This modifiedmap 911 may then be compared to the target map to determine the extent to which the estimated deposition matches the desired deposition for the layer. First thetarget map 900 may be inverted inoperation 902, so that in both the resultinginverted target map 912 and the modifieddeposition analysis 911 the white pixels correspond to deposition locations. Acount 913 of the white (“on”) pixels ininverted target map 912 indicates how many positions in the layer should receive deposited material. The modifieddeposition map 911 and theinverted target map 912 may then be ANDed inoperation 920; the resultingmap 921 shows the pixels that correspond to positions that should have deposited material (according to the target map) and that do have deposited material (according to the deposition analysis). Thecount 922 of white (“on”) pixels in 921 may then be compared to thecount 913 of desired “on” pixels; the ratio of thesevalues 923 is a percentage of completion measure for the layer. In one or more embodiments, this completion percentage ratio may be compared to a threshold, and the layer may be considered complete when the threshold percentage is reached or exceeded. Theoperations FIG. 9A are illustrative; one or more embodiments may apply any transformations or operations to thedeposition analysis 128 or thetarget map 900 to determine whether a layer is complete, including but not limited to morphological operations such as 901 or Boolean operations such as 902 and 920. - One potential limitation of the method illustrated in
FIG. 9A is that it is possible for the overall completion percentage for a layer to be high, while completion may be low for specific subregions of the layer. In some situations it may be important that subregions of the layer all be completed to a high percentage.FIG. 9B shows an illustrative extension of the method of 9A that applies a completion threshold to subregions. In one or more embodiments, subregions may be defined in any desired manner. For example, a layer may be divided into a regular grid of tiles of any resolution, and completion criteria may be applied to each tile.FIG. 9B illustrates an approach that divides the target map into “islands” of connected components, and that applies completion criteria separately to each island. Target map 912 (inverted as inFIG. 9A so that white pixels correspond to desired deposition) has fourislands 912 a through 912 d; each island is a connected component and different islands are not connected. The modifieddeposition analysis map 911 is partitioned into these island regions, resulting in fourdeposition analyses 921 a through 921 d, corresponding to theislands 912 a through 912 d. Within each of these island deposition analyses, the percentage of white (“on”) pixels indicates the level of completion of deposition within the associated island. These individualisland completion percentages 923 a through 923 d may then be analyzed to determine whether the layer is complete. For example, a threshold may be applied to each of the island completion percentages, and the layer may be complete only when all of the islands meet or exceed this threshold. In one or more embodiments, different completion criteria may be applied to different islands, and the overall layer may be complete only when each island meets its respective completion criterion. - In one or more embodiments, completion criteria for a layer or for individual islands may be based on other factors instead of or in addition to a percentage of completion of desired deposited pixels. For example, a layer or an island may be considered complete if all or a certain number or fraction of pixels within the layer or island where deposition is desired are within a specified threshold distance of one or more deposited pixels. The set of pixels where deposition is desired, and the set of pixels where deposition has occurred (to a desired level of completion) may be determined as described above. In some embodiments, elapsed time of deposition, charge used for deposition, overall current, and/or impedance between the electrodes may be used as part of the determination whether a layer is done.
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FIG. 10 shows an illustrative example of how thedeposition analysis 128 may be used to adjust process parameters during the construction of the associated layer until the layer is determined to be complete. As for completion analysis, thedeposition analysis 128 may first be transformed using any type of filters or operations.FIG. 10 shows anerosion operation 1001 applied to thedeposition analysis 128 to generate a modifieddeposition analysis 1002. Thiserosion operation 1001, which is an example of a morphological filter, shrinks regions of white pixels by removing pixels from region boundaries. The resultingmap 1002 therefore may represent a more conservative estimate of where deposition has occurred. Theerosion operation 1001 is illustrative; one or more embodiments may apply any type of transformation todeposition analysis 128, including for example, without limitation, morphological filters, linear or nonlinear filters, or Boolean operations.Modified map 1002 may then be inverted inoperation 1003 to yieldmap 1004, where the black pixels correspond to the eroded regions of deposition, and the white pixels correspond to locations with potential lack of sufficient deposition. Thismap 1004 may then be ANDed with theinverted target map 912, yielding amap 1006 that may be used to modify the process parameters for further construction of the layer. In thismap 1006, white (“on”) pixels correspond to locations where deposition is desired but may not yet be sufficiently complete. This map may therefore be used to set theoutputs 1007 of the anodes in the anode array, so that deposition continues for anodes that correspond to the “on” pixels ofmap 1006. Anode outputs may be set for example by settinganode currents 1011, by settinganode voltages 1012, or by settinganode duty cycles 1013, or by using a combination of these methods. -
FIG. 10 illustrates feedback control that generates essentially binary control signals for anodes, such asmap 1006. Anodes may then be turned on or off based on these control signals. In one or more embodiments, anode control (or control of any other process parameters) may use non-binary control signals; for example, anode currents may be varied continuously from zero to a maximum value based on analysis of the feedback signals. - Although use of high resolution anode arrays may provide fine control of deposited material, in some situations the pattern of deposition of material onto the cathode may not correspond precisely to the pattern of anode outputs. One or more embodiments may therefore adjust the anode outputs by pre-processing the target map to account for these effects.
FIGS. 11A, 11B, 11C, and 12A illustrate this process using a one-dimensional model of anode arrays for ease of presentation. Similar concepts may be applied in one or more embodiments to two-dimensional anode arrays; an example in two dimensions is shown inFIG. 12B . -
FIG. 11A showsillustrative deposition 1111 ontocathode 220 when only asingle anode 1101 ofanode array 201 is energized. In some environments, material may be deposited onto the cathode at positions that are not directly across from the energized anode. For example,deposition 1111 may occur in an approximately Gaussian pattern that is centered across from an energized anode, and that spreads out laterally from this center.FIG. 11B shows anillustrative deposition pattern 1112 whenmultiple anodes individual anodes FIG. 11B illustrates that deposition may be higher at the center (across from anode 1101) than at the edges, due to the additive effects from all three of the anodes. - If deposition patterns from individual anodes combine additively, the general effect of the phenomena shown in
FIGS. 11A and 11B may be to modify the pattern of anode outputs via aconvolution 1141 with apoint spread function 1140 that describes the spread of deposition from a single anode point source.FIG. 11C shows anillustrative pattern 1130 of anode current that is constant within a range from 1121 to 1122, and zero outside this range. Because ofconvolution 1141, the actual deposition thickness will not match theinput shape 1130, but instead will haveshape 1150 with higher accumulation in the center, and with some deposition extending beyond thebounds current pattern 1130 are smoothed by the effects shown inFIGS. 11A and 11B . One or more embodiments may therefore modify the anode currents to account for thisconvolution 1141 or for other effects that distort the deposition pattern.FIG. 12A shows an illustrative approach that may be used in one or more embodiments. Based on atarget map 1201 that describes the target thickness of a layer as a function of position, the build planning process may perform adeconvolution 1210 or other transformation to reverse the effects of the distortion illustrated inFIGS. 11A through 11C . For example,target map 1201 with a constant thickness betweenbounds current pattern 1211. To compensate for the dispersive effects of the deposition point spread function, the illustrative anode current has ahigher value 1212 at the edges, and some anodes such as 1214 within the central region of the rectangular pattern may be turned off entirely. In addition, some anodes such asanode 1213 may have nonzero currents even if they are outside thebounds current pattern 1211 to achieve the desiredlayer thickness pattern 1201.Transformations 1210 may include any deconvolution methods or any other function transformation or image processing methods. These transformations may be based on any measurements or models of the deposition process, including for example apoint spread function 1140 that describes how anode currents are mapped to deposition patterns. -
FIG. 12B shows a two-dimensional example of transformation of a target map into a desired anode current pattern.Target map 1220 shows areas of desired deposition (in black) for a particular layer of a part build. As described above,transformations 1210, which may for example include deconvolution or any other type of image processing, may be applied to thistarget map 1220 to generate apattern 1230 that indicates the anode current pattern that may be generated to achieve the desired deposition. In this example, anodes are turned on for the anodes that correspond to anodes with desired deposition, and additional anodes (shown as cross-hatched regions) are turned on around the edges and the corners of the deposition area. For example, edge anodes are turned on around each outer edge, such asanodes 1231 along the top edge, and additional anodes are turned on around the corners, such asanodes 1232 around the top right corner. Turning on these additional edge and corner anodes helps to shape the field of current to drive deposition of material more evenly at the corresponding edges and corners oftarget map 1220. - One or more embodiments may also modify anode currents over time in a preprogrammed or adaptive pattern, as illustrated in
FIG. 13 . For example, in one or more embodiments, subsets of anodes may be successively switched on and off during the manufacturing of a layer. This alternation may for example compensate for potential depletion of metal ions in the electrolyte that might occur if anodes output a constant current throughout the construction of a layer. It may also prevent formation of bubbles in the electrolyte. In the example shown inFIG. 13 ,target map 112 e has a squarecentral area 1301 where material is to be deposited. Instead of constantly emitting current from all of the anodes that correspond to thisregion 1301, one or more embodiments may alternate current from twosubregions region 1301 into a checkerboard pattern. Duringphase 1321, anodes inregion 1311 emit current 1331, and anodes inregion 1312 are switched off; duringphase 1322, anodes inregion 1311 are switched off, and anodes inregion 1312 emit current 1332. This alternation may for example allowions 1310 in the electrolyte to diffuse into the regions adjacent to the switched-off anodes so that these regions are not depleted. The checkerboard pattern ofregions -
FIG. 14 shows illustrative maintenance actions that may be performed during the manufacturing process in one or more embodiments. These actions may for example be interleaved with deposition, or they may be performed between manufacturing of layers. The actions shown are illustrative; one or more embodiments may perform any desired maintenance activities at any point in the manufacturing process.FIG. 14 shows three illustrative issues that may arise during manufacturing that may require maintenance activities. First, anodes in theanode array 201 may erode, such asanode 1401, and may need to be replenished or resurfaced. Second, films such asfilm 1402 may form over anodes and prevent them from effectively driving deposition onto the cathode. Third, bubbles such as 1403 may form in the electrolyte between the anode array and the depositedmaterial 230. - Over time, anodes such as
anode 1401 may erode, even if anodes are constructed of a largely insoluble material. One or more embodiments may periodically or as-needed reverse this erosion using asecondary anode 1410. The deposition process may for example be paused and thepower supply 221 may be reversed usingswitches 1411 and 1412, so that the anode array temporarily acts as a cathode, and thesecondary anode 1410 acts as the anode. Current flowing from thesecondary anode 1410 may then cause material 1413 to flow from the secondary anode to the eroded anodes inarray 201. Thesecondary anode 1410 may for example be a large bulk anode that is composed of an inert material like platinum. The secondary anode may be composed of the metal that is used for electrodeposition, such as copper for example; this metal will dissolve and plate onto the anodes ofanode array 201 without depleting the metal in the electrolyte solution. When theswitches 1411 and 1412 are reversed again, the metal plated onto the anode array then plates onto the cathode. - In some cases, target deposition material (such as copper from a copper electrolyte bath) may end up plated onto a surface of the electrode array as a
film 1402. This film of target material may bridge between multiple deposition electrodes and may impact their ability to be individually addressed. A film may be detected from the feedback signals, for example when a group of adjacent anodes shows an abnormally high current. A film may be removed for example by movingcathode 220 far away from the anode array and activating the anodes covered by the film. This action dissolves the film while not causing an unintended deposit on the cathode. - During electrolysis, bubbles 1403 may form in the space between the
anode array 201 and thepart 230. Bubbles may be removed for example by manipulating or modifying theflow 1420 of electrolyte, for example with pumps or agitators, or by inducingvibrations 1421 in the electrolyte to dissipate the bubbles. Vibrations may be introduced into the electrolyte using a vibration oscillator in contact with the electrolyte, or by vibrating the cathode, anode array, or reaction chamber. Flow manipulation may also include purposefully increasing the distance between the build and the anode array to allow for greater fluid flow and/or bubble removal, while either keeping the anodes energized or de-energized until the flow manipulation is complete. - In one or more embodiments, all or portions of the feedback signals, control parameters, and deposition analyses measured or generated throughout a build of a part may be maintained as quality control records. This data may be used for any or all of several purposes, including for example facilitating or eliminating part inspections, supporting certification of parts or manufacturing processes, and post-mortem analysis of part failures or part performance issues. In addition to providing detailed tracing for the specific manufacturing steps and parameters used for each part, this quality control data may be aggregated across parts, lots, or facilities and used for statistical process control and for continuous process improvement. For example, data on part performance in the field (such as failure rates or part lifetimes) may be correlated with the part quality control data to discover correlations between process parameters and part performance; these correlations may then be used to improve future part build processes. In one or more embodiments, machine learning techniques or other artificial intelligence techniques may be used to automatically discover relationships between build record information and part performance. For example, analysis of large numbers of parts and their associated quality control records may show that a lower current density for particular types of layers results in higher part failures; a manufacturer may use this type of information to modify build processes to reduce future failure rates. When relationships between build parameters and part performance are discovered, the database of build quality information for parts may be used to predict failures for previously built parts, allowing them to be potentially recalled or replaced prior to failure.
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FIG. 15 shows anillustrative part 1501 that was manufactured using an embodiment of the invention. Feedback control of the manufacturing process using techniques described above enables the extremely fine resolution and high quality of this completed part. - While the invention herein disclosed has been described by means of specific embodiments and applications thereof, numerous modifications and variations could be made thereto by those skilled in the art without departing from the scope of the invention set forth in the claims.
Claims (30)
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US17/993,277 US12049703B2 (en) | 2019-08-23 | 2022-11-23 | Matrix-controlled printhead for an electrochemical additive manufacturing system |
US18/533,008 US20240162049A1 (en) | 2019-08-23 | 2023-12-07 | Electrochemical additive manufacturing system having conductive seed layer |
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