US20200047981A1 - Dosing valve for a fluid product dispenser - Google Patents
Dosing valve for a fluid product dispenser Download PDFInfo
- Publication number
- US20200047981A1 US20200047981A1 US16/604,302 US201816604302A US2020047981A1 US 20200047981 A1 US20200047981 A1 US 20200047981A1 US 201816604302 A US201816604302 A US 201816604302A US 2020047981 A1 US2020047981 A1 US 2020047981A1
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- US
- United States
- Prior art keywords
- valve
- metering
- pbt
- glass microspheres
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
- B65D83/44—Valves specially adapted therefor; Regulating devices
- B65D83/52—Valves specially adapted therefor; Regulating devices for metering
- B65D83/54—Metering valves ; Metering valve assemblies
Definitions
- the present invention relates to a metering valve for a fluid dispenser.
- valve The preferred field of application of such a valve is the field of pharmacy, but this type of valve may also be used in other fields, e.g. the fields of cosmetics or perfumery.
- the metering valves of the prior art comprise a valve body that defines a metering chamber in which a valve member slides between a rest position and an actuated position.
- the valve body and the valve member are usually made by molding plastics materials of the polymer type, such as polyethylene (PE), polypropylene (PP), polyacetal or polyoxymethylene (POM), or polybutylene terephthalate (PBT).
- PE polyethylene
- PP polypropylene
- POM polyacetal or polyoxymethylene
- PBT polybutylene terephthalate
- metering valves must satisfy requirements for small manufacturing tolerances, and they must provide great dimensional stability for the very small components making them up. There is also a requirement for the metering-valve components to be accurately cylindrical, which is necessary for maintaining the points of sealing in the valve, despite a pressure of 5 bars that exists in the reservoir.
- the materials used in the components that constitute the metering valves are also requirements for the materials used in the components that constitute the metering valves to have excellent mechanical properties, in particular given the high level of stresses to which they may be subjected, in particular while filling the reservoir through said metering valve and/or while the metering valve is being used by the patient.
- Other constraints can also affect the reliability of metering valves, such as operating with significant pressure differentials, or abrasion associated with the presence of powder.
- Injection molding is very widely used for producing parts intended for applications in the packaging, electricity, automotive, cosmetics, and consumer goods industries.
- the method is also used in high-tech industries such as the medical, pharmaceutical, aeronautical, and nuclear industries.
- the appearance of the injected parts is a very important criterion, in particular for medical applications for which a high level of quality is essential in order to guarantee the safety of patients.
- certain defects in appearance may be generated while manufacturing the parts, and monitoring such defects in large scale production can turn out to be tricky.
- the presence of defects, in particular on safety parts may generate malfunctions or fragility of devices such as metering valves.
- Various types of defect exist, in particular burrs, webs, air bubbles, streaks, or even incomplete parts.
- Such defects can be remedied in several ways, e.g. by modifying the parameters of the injection-molding method, by modifying the design of the part to be molded, or by adding additives to the polymers so as to improve their molding performance.
- Nuclei forming agents are the additives most often used, in particular for eliminating surface defects. Nuclei forming agents act by modifying the crystallization kinetics. Nuclei forming agents may be talc-based or they may be organic substances. Other substances, such as foaming agents may also be used. They decompose during the molding process so as to give a foam structure. They may be based on sodium bicarbonate and sodium citrate.
- An object of the present invention is to provide a pump that does not have the above-mentioned difficulties.
- Another object of the present invention is to provide such a metering valve that makes it possible to dispense fluid in reliable, regular, and reproducible manner each time the dispenser is actuated.
- Another object of the present invention is to provide a metering valve that is simple and inexpensive to manufacture and to assemble.
- the present invention thus provides a metering valve for a fluid dispenser, the metering valve comprising a valve body that defines a metering chamber in which a valve member slides between a rest position and an actuated position, said valve body and/or said valve member being made by injection-molding a material comprising a PBT matrix and glass microspheres dispersed in said PBT matrix.
- said glass microspheres have a diameter lying in the range 1 micrometer ( ⁇ m) to 2000 ⁇ m, advantageously in the range 1 ⁇ m to 100 ⁇ m.
- said glass microspheres are added to the PBT matrix at a content lying in the range 1% to 20% by weight, advantageously in the range 1% to 15% by weight.
- the present invention also provides a fluid dispenser comprising a reservoir containing fluid to be dispensed, and a metering valve as described above.
- said dispenser contains a hydrofluoroalkane (HFA) gas as a propellant gas.
- HFA hydrofluoroalkane
- FIG. 1 is a diagrammatic section view of a metering valve in an advantageous embodiment
- FIG. 2 is a bar chart comparing the Young's modulus of PBT on its own and with various additives, with the Young's modulus of PBT including microspheres of the invention.
- FIG. 3 is a graph comparing the coefficient of friction of PBT on its own with the coefficient of friction of PBT including microspheres of the invention.
- the terms “upper”, “lower”, “top” and “bottom” refer to the upright position shown in FIG. 1
- the terms “axial” and “radial” refer to the longitudinal axis of the valve shown in FIG. 1 .
- the metering valve shown in FIG. 1 is of the retention type. However, it should be understood that this is merely an example, and that the present invention applies to any type of metering valve.
- the valve includes a valve body 10 that extends along a longitudinal axis A. Inside said valve body 10 , a valve member 30 slides between a rest position, that is the position shown in FIG. 1 , and a dispensing position in which the valve member 30 has been pushed into the valve body 10 .
- the valve is for assembling on a reservoir 1 , preferably by means of a fastener element 5 that may be a crimpable, screw-fastenable, or snap-fastenable capsule, and a neck gasket 6 is advantageously interposed between the fastener element and the reservoir.
- a ring 4 may be assembled around the valve body, in particular so as to decrease the dead volume in the upsidedown position, and so as to limit contact between the fluid and the neck gasket.
- the ring may be of any shape, and the example in FIG. 1 is not limiting.
- valve member 30 is urged towards its rest position by a spring 8 that is arranged in the valve body 10 and that co-operates firstly with the valve body 10 and secondly with the valve member 30 , preferably with a radial collar 320 of the valve member 30 .
- a metering chamber 20 is defined inside the valve body 10 , said valve member 30 sliding inside said metering chamber so as to enable its contents to be dispensed when the valve is actuated.
- the metering chamber is preferably defined between two annular gaskets, namely a valve-member gasket 21 , and a chamber gasket 22 .
- FIG. 1 shows the valve in the upright storage position, i.e. the position in which the metering chamber 20 is arranged above the reservoir 1 .
- the valve member 30 includes an outlet orifice 301 that is connected to an inlet orifice 302 that is arranged in the metering chamber 20 when the valve member 30 is in its dispensing position.
- the valve member 30 may be made of two portions, namely an upper portion 31 (also known as a valve-member top) and a lower portion 32 (also known as a valve-member bottom). In this embodiment, the lower portion 32 is assembled inside the upper portion 31 .
- An internal channel 33 is provided in the valve member 30 that makes it possible to connect the metering chamber 20 to the reservoir 1 , so as to fill said metering chamber 20 after each actuation of the valve when the valve member 30 returns to its rest position under the effect of the spring 8 . Filling is performed when the device is still in its upsidedown working position, with the valve arranged below the reservoir.
- valve body and/or said valve member is/are made by injection-molding a material comprising a PBT matrix and glass microspheres dispersed in said PBT matrix.
- the solid glass microspheres are made of glass, advantageously recycled glass, and present the advantage of containing neither free silica nor heavy metals. They are in powder form. They have a basic pH, which is favorable when it is desired to limit interaction with the active ingredients. They may be subjected to a surface treatment with a coupling agent, which is selected as a function of the nature of the matrix, and which enables better adhesion between the microsphere and the matrix, and also better dispersion.
- the glass microspheres typically have a diameter lying in the range 1 ⁇ m to 2000 ⁇ m. In the various tests performed and described below, glass microspheres were used of diameter lying in the range 3 ⁇ m to 100 ⁇ m, with a median diameter lying in the range 10 ⁇ m to 30 ⁇ m.
- the microspheres may be added to the PBT matrix at a content lying in the range 1% to 20% by weight, advantageously in the range 1% to 15% by weight.
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Valve Housings (AREA)
- Nozzles (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
A metering valve for a fluid dispenser, the metering valve having a valve body that defines a metering chamber in which a valve member slides between a rest position and an actuated position, the valve body and/or the valve member being made by injection-molding a material having a PBT matrix and glass microspheres dispersed in said PBT matrix.
Description
- The present invention relates to a metering valve for a fluid dispenser.
- The preferred field of application of such a valve is the field of pharmacy, but this type of valve may also be used in other fields, e.g. the fields of cosmetics or perfumery.
- The metering valves of the prior art comprise a valve body that defines a metering chamber in which a valve member slides between a rest position and an actuated position. The valve body and the valve member are usually made by molding plastics materials of the polymer type, such as polyethylene (PE), polypropylene (PP), polyacetal or polyoxymethylene (POM), or polybutylene terephthalate (PBT). However, metering valves must satisfy requirements for small manufacturing tolerances, and they must provide great dimensional stability for the very small components making them up. There is also a requirement for the metering-valve components to be accurately cylindrical, which is necessary for maintaining the points of sealing in the valve, despite a pressure of 5 bars that exists in the reservoir. There are also requirements for the materials used in the components that constitute the metering valves to have excellent mechanical properties, in particular given the high level of stresses to which they may be subjected, in particular while filling the reservoir through said metering valve and/or while the metering valve is being used by the patient. Other constraints can also affect the reliability of metering valves, such as operating with significant pressure differentials, or abrasion associated with the presence of powder.
- Injection molding is very widely used for producing parts intended for applications in the packaging, electricity, automotive, cosmetics, and consumer goods industries. The method is also used in high-tech industries such as the medical, pharmaceutical, aeronautical, and nuclear industries.
- The appearance of the injected parts is a very important criterion, in particular for medical applications for which a high level of quality is essential in order to guarantee the safety of patients. Thus, certain defects in appearance may be generated while manufacturing the parts, and monitoring such defects in large scale production can turn out to be tricky. Unfortunately, the presence of defects, in particular on safety parts, may generate malfunctions or fragility of devices such as metering valves. Various types of defect exist, in particular burrs, webs, air bubbles, streaks, or even incomplete parts.
- Such defects can be remedied in several ways, e.g. by modifying the parameters of the injection-molding method, by modifying the design of the part to be molded, or by adding additives to the polymers so as to improve their molding performance.
- Nuclei forming agents are the additives most often used, in particular for eliminating surface defects. Nuclei forming agents act by modifying the crystallization kinetics. Nuclei forming agents may be talc-based or they may be organic substances. Other substances, such as foaming agents may also be used. They decompose during the molding process so as to give a foam structure. They may be based on sodium bicarbonate and sodium citrate.
- Documents FR 3 035 382, WO 2012/072962,
FR 2 767 801, and DE 27 34 950 describe prior-art devices. - An object of the present invention is to provide a pump that does not have the above-mentioned difficulties.
- Another object of the present invention is to provide such a metering valve that makes it possible to dispense fluid in reliable, regular, and reproducible manner each time the dispenser is actuated.
- Another object of the present invention is to provide a metering valve that is simple and inexpensive to manufacture and to assemble.
- The present invention thus provides a metering valve for a fluid dispenser, the metering valve comprising a valve body that defines a metering chamber in which a valve member slides between a rest position and an actuated position, said valve body and/or said valve member being made by injection-molding a material comprising a PBT matrix and glass microspheres dispersed in said PBT matrix.
- Advantageously, said glass microspheres have a diameter lying in the
range 1 micrometer (μm) to 2000 μm, advantageously in therange 1 μm to 100 μm. - Advantageously, said glass microspheres are added to the PBT matrix at a content lying in the
range 1% to 20% by weight, advantageously in therange 1% to 15% by weight. - The present invention also provides a fluid dispenser comprising a reservoir containing fluid to be dispensed, and a metering valve as described above.
- Advantageously, said dispenser contains a hydrofluoroalkane (HFA) gas as a propellant gas.
- These characteristics and advantages and others appear more clearly from the following detailed description, given by way of non-limiting example, and with reference to the accompanying drawings, in which:
-
FIG. 1 is a diagrammatic section view of a metering valve in an advantageous embodiment; -
FIG. 2 is a bar chart comparing the Young's modulus of PBT on its own and with various additives, with the Young's modulus of PBT including microspheres of the invention; and -
FIG. 3 is a graph comparing the coefficient of friction of PBT on its own with the coefficient of friction of PBT including microspheres of the invention. - In the following description, the terms “upper”, “lower”, “top” and “bottom” refer to the upright position shown in
FIG. 1 , and the terms “axial” and “radial” refer to the longitudinal axis of the valve shown inFIG. 1 . - The metering valve shown in
FIG. 1 is of the retention type. However, it should be understood that this is merely an example, and that the present invention applies to any type of metering valve. - The valve includes a
valve body 10 that extends along a longitudinal axis A. Inside saidvalve body 10, avalve member 30 slides between a rest position, that is the position shown inFIG. 1 , and a dispensing position in which thevalve member 30 has been pushed into thevalve body 10. - The valve is for assembling on a
reservoir 1, preferably by means of afastener element 5 that may be a crimpable, screw-fastenable, or snap-fastenable capsule, and a neck gasket 6 is advantageously interposed between the fastener element and the reservoir. Optionally, a ring 4 may be assembled around the valve body, in particular so as to decrease the dead volume in the upsidedown position, and so as to limit contact between the fluid and the neck gasket. The ring may be of any shape, and the example inFIG. 1 is not limiting. - The
valve member 30 is urged towards its rest position by aspring 8 that is arranged in thevalve body 10 and that co-operates firstly with thevalve body 10 and secondly with thevalve member 30, preferably with aradial collar 320 of thevalve member 30. Ametering chamber 20 is defined inside thevalve body 10, saidvalve member 30 sliding inside said metering chamber so as to enable its contents to be dispensed when the valve is actuated. - In conventional manner, the metering chamber is preferably defined between two annular gaskets, namely a valve-
member gasket 21, and achamber gasket 22. -
FIG. 1 shows the valve in the upright storage position, i.e. the position in which themetering chamber 20 is arranged above thereservoir 1. - The
valve member 30 includes anoutlet orifice 301 that is connected to aninlet orifice 302 that is arranged in themetering chamber 20 when thevalve member 30 is in its dispensing position. Thevalve member 30 may be made of two portions, namely an upper portion 31 (also known as a valve-member top) and a lower portion 32 (also known as a valve-member bottom). In this embodiment, thelower portion 32 is assembled inside theupper portion 31. An internal channel 33 is provided in thevalve member 30 that makes it possible to connect themetering chamber 20 to thereservoir 1, so as to fill saidmetering chamber 20 after each actuation of the valve when thevalve member 30 returns to its rest position under the effect of thespring 8. Filling is performed when the device is still in its upsidedown working position, with the valve arranged below the reservoir. - In the invention, said valve body and/or said valve member is/are made by injection-molding a material comprising a PBT matrix and glass microspheres dispersed in said PBT matrix.
- Although molding PBT is problematic with crystallinity varying greatly from one batch to another, the addition of glass microspheres in a PBT matrix makes it possible to control crystallinity of the material and thus reduce molding problems.
- The solid glass microspheres are made of glass, advantageously recycled glass, and present the advantage of containing neither free silica nor heavy metals. They are in powder form. They have a basic pH, which is favorable when it is desired to limit interaction with the active ingredients. They may be subjected to a surface treatment with a coupling agent, which is selected as a function of the nature of the matrix, and which enables better adhesion between the microsphere and the matrix, and also better dispersion.
- The glass microspheres typically have a diameter lying in the
range 1 μm to 2000 μm. In the various tests performed and described below, glass microspheres were used of diameter lying in the range 3 μm to 100 μm, with a median diameter lying in therange 10 μm to 30 μm. The microspheres may be added to the PBT matrix at a content lying in therange 1% to 20% by weight, advantageously in therange 1% to 15% by weight. - Adding glass microspheres into a PBT matrix makes it possible, in particular, to obtain the following improvements:
-
- during molding, the microspheres make it possible to reduce the variability of crystallinity between the various batches of materials, and thus to reduce difficulties during molding; in particular this makes it possible to reduce substantially or to eliminate difficulties of the components deforming, and to improve their dimensional stability;
- the microspheres make it possible to increase the mechanical properties of the material in which they are dispersed; in order to characterize the mechanical strength of a material, traction measurements are performed, thereby making it possible to obtain breaking stress values or Young's modulus values;
FIG. 2 shows a significant improvement in the Young's modulus for PBT with the glass microspheres compared to PBT on its own, and also compared to PBT with various well known additives, such as a nuclei forming agent, talc, or a foaming agent; - the glass microspheres are of inorganic origin, thus they do not add any additional extractables; on the contrary they have a diluting effect; thus, with a content of glass microspheres of 13% in a PBT matrix, a reduction in extractables of a little more than 15% has been observed.
- the microspheres make it possible to reduce the coefficient of friction; the coefficient of friction is the ratio of the traction force (response force enabling the apparatus to move) over the applied force (normal force); two types of coefficient of friction exist: the dynamic coefficient and the static coefficient; the static coefficient is the coefficient measured at the beginning of a test; it is the force necessary to move the sample on the substrate and to initiate movement; the term “coefficient of adhesion” is also used; the dynamic coefficient is the coefficient necessary for movement to be maintained at a constant speed; in this embodiment, values for the dynamic coefficient are used since the system is thus stable and at constant speed; the test consisted in causing a steel ball to rub against a defined material (specifically PBT, with and without microspheres) so as to determine a coefficient of friction; the results obtained are reproduced in
FIG. 3 and they show that adding microspheres makes it possible to reduce the coefficient of friction; in particular, this makes it possible to envisage a reduction in difficulties with friction in valves; - microspheres do not have any impact on compatibility with active ingredients; this has been tested by putting PBT containing microspheres into direct contact with active ingredients (e.g. formoterol fumarate), and by measuring the degradation of the active ingredients using analytical techniques; the tests performed did not show the glass microspheres having any impact on such degradation.
- The present invention is described above with reference to an advantageous embodiment, but naturally any modification could be applied thereto by the person skilled in the art, without going beyond the ambit of the present invention, as defined by the accompanying claims.
Claims (5)
1. A metering valve for a fluid dispenser, the metering valve comprising a valve body that defines a metering chamber in which a valve member slides between a rest position and an actuated position, the metering valve being characterized in that said valve body and/or said valve member is/are made by injection-molding a material comprising a PBT matrix and glass microspheres dispersed in said PBT matrix.
2. A valve according to claim 1 , wherein said glass microspheres have a diameter lying in the range 1 μm to 2000 μm, advantageously in the range 1 μm to 100 μm.
3. A valve according to claim 1 , wherein said glass microspheres are added to the PBT matrix at a content lying in the range 1% to 20% by weight, advantageously in the range 1% to 15% by weight.
4. A fluid dispenser comprising a reservoir (1) containing fluid to be dispensed, said dispenser being characterized in that it further comprises a metering valve according to claim 1 .
5. A dispenser according to claim 5 , containing an HFA gas as a propellant gas.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1753244 | 2017-04-13 | ||
FR1753244A FR3065176B1 (en) | 2017-04-13 | 2017-04-13 | DOSING VALVE FOR FLUID PRODUCT DISPENSER |
PCT/FR2018/050884 WO2018189469A1 (en) | 2017-04-13 | 2018-04-09 | Dosing valve for a fluid product dispenser |
Publications (1)
Publication Number | Publication Date |
---|---|
US20200047981A1 true US20200047981A1 (en) | 2020-02-13 |
Family
ID=58993121
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US16/604,302 Abandoned US20200047981A1 (en) | 2017-04-13 | 2018-04-09 | Dosing valve for a fluid product dispenser |
Country Status (6)
Country | Link |
---|---|
US (1) | US20200047981A1 (en) |
EP (1) | EP3609809B1 (en) |
JP (1) | JP2020520859A (en) |
CN (1) | CN110650899A (en) |
FR (1) | FR3065176B1 (en) |
WO (1) | WO2018189469A1 (en) |
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US4111893A (en) * | 1977-05-20 | 1978-09-05 | Gaf Corporation | Polybutylene terephthalate molding resin |
US20060249543A1 (en) * | 2003-03-13 | 2006-11-09 | Jean-Marc Pardonge | Distribution device for fluid product |
US7234460B2 (en) * | 2002-09-06 | 2007-06-26 | 3M Innovative Properties Company | Metering valve for a metered dose inhaler providing consistent delivery |
US20080121666A1 (en) * | 2003-07-07 | 2008-05-29 | Purkins Graham R | Multi-Component Valve Stems |
US7503469B2 (en) * | 2005-03-09 | 2009-03-17 | Rexam Closure Systems Inc. | Integrally molded dispensing valve and method of manufacture |
US20090321381A1 (en) * | 2008-06-30 | 2009-12-31 | Paas Edward L | Overcap for and a method of actuating a volatile material dispenser |
US8336854B2 (en) * | 2008-02-08 | 2012-12-25 | Greif International Holding B.V. | Valve for liquid containers |
US20160280888A1 (en) * | 2013-06-28 | 2016-09-29 | Altachem Nv | Valve member |
GB2537756A (en) * | 2015-04-24 | 2016-10-26 | Nemera La Verpillière | Improved metering valve for dispensing an aerosol comprising a valve stem |
US20180169549A1 (en) * | 2016-12-16 | 2018-06-21 | Clarcor Engine Mobile Solutions, Llc | Filter assembly with primer |
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US20190225355A1 (en) * | 2016-09-12 | 2019-07-25 | Alpla Werke Alwin Lehner Gmbh & Co. Kg | Aerosol container made of plastic |
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FR2968283B1 (en) * | 2010-12-03 | 2013-01-04 | Valois Sas | VALVE OF DISTRIBUTION OF FLUID PRODUCT. |
FR2971772B1 (en) * | 2011-02-17 | 2013-03-22 | Valois Sas | DEVICE FOR DISPENSING FLUID PRODUCT. |
CN103756298B (en) * | 2013-12-03 | 2017-01-04 | 惠州市昌亿科技股份有限公司 | A kind of thermoplastic polymer based thermal conductive composite and its preparation method and application |
-
2017
- 2017-04-13 FR FR1753244A patent/FR3065176B1/en not_active Expired - Fee Related
-
2018
- 2018-04-09 US US16/604,302 patent/US20200047981A1/en not_active Abandoned
- 2018-04-09 JP JP2019555897A patent/JP2020520859A/en active Pending
- 2018-04-09 EP EP18724939.6A patent/EP3609809B1/en active Active
- 2018-04-09 WO PCT/FR2018/050884 patent/WO2018189469A1/en unknown
- 2018-04-09 CN CN201880033525.1A patent/CN110650899A/en active Pending
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US4111893A (en) * | 1977-05-20 | 1978-09-05 | Gaf Corporation | Polybutylene terephthalate molding resin |
US7234460B2 (en) * | 2002-09-06 | 2007-06-26 | 3M Innovative Properties Company | Metering valve for a metered dose inhaler providing consistent delivery |
US20060249543A1 (en) * | 2003-03-13 | 2006-11-09 | Jean-Marc Pardonge | Distribution device for fluid product |
US20080121666A1 (en) * | 2003-07-07 | 2008-05-29 | Purkins Graham R | Multi-Component Valve Stems |
US7503469B2 (en) * | 2005-03-09 | 2009-03-17 | Rexam Closure Systems Inc. | Integrally molded dispensing valve and method of manufacture |
US8336854B2 (en) * | 2008-02-08 | 2012-12-25 | Greif International Holding B.V. | Valve for liquid containers |
US20090321381A1 (en) * | 2008-06-30 | 2009-12-31 | Paas Edward L | Overcap for and a method of actuating a volatile material dispenser |
US20160280888A1 (en) * | 2013-06-28 | 2016-09-29 | Altachem Nv | Valve member |
GB2537756A (en) * | 2015-04-24 | 2016-10-26 | Nemera La Verpillière | Improved metering valve for dispensing an aerosol comprising a valve stem |
US20180222647A1 (en) * | 2015-08-04 | 2018-08-09 | Coster Tecnologie Speciali S.p. A. | Valve cups and containers for use in fluid medium dispensing systems |
US20190225355A1 (en) * | 2016-09-12 | 2019-07-25 | Alpla Werke Alwin Lehner Gmbh & Co. Kg | Aerosol container made of plastic |
US20180169549A1 (en) * | 2016-12-16 | 2018-06-21 | Clarcor Engine Mobile Solutions, Llc | Filter assembly with primer |
Also Published As
Publication number | Publication date |
---|---|
FR3065176B1 (en) | 2019-06-07 |
EP3609809B1 (en) | 2021-06-09 |
CN110650899A (en) | 2020-01-03 |
WO2018189469A1 (en) | 2018-10-18 |
EP3609809A1 (en) | 2020-02-19 |
JP2020520859A (en) | 2020-07-16 |
FR3065176A1 (en) | 2018-10-19 |
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