US20190040280A1 - Packaging And Liquid Stabilizing Material - Google Patents

Packaging And Liquid Stabilizing Material Download PDF

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Publication number
US20190040280A1
US20190040280A1 US16/154,004 US201816154004A US2019040280A1 US 20190040280 A1 US20190040280 A1 US 20190040280A1 US 201816154004 A US201816154004 A US 201816154004A US 2019040280 A1 US2019040280 A1 US 2019040280A1
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United States
Prior art keywords
latex
liquid
packaging
desired shape
recycled
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
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US16/154,004
Inventor
Alfred Seto
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Envirosystems Inc
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Envirosystems Inc
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Filing date
Publication date
Priority claimed from US14/744,222 external-priority patent/US9856379B2/en
Application filed by Envirosystems Inc filed Critical Envirosystems Inc
Priority to US16/154,004 priority Critical patent/US20190040280A1/en
Publication of US20190040280A1 publication Critical patent/US20190040280A1/en
Abandoned legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D197/00Coating compositions based on lignin-containing materials
    • C09D197/005Lignin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/04Recovery or working-up of waste materials of polymers
    • C08J11/06Recovery or working-up of waste materials of polymers without chemical reactions
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • C08L101/02Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/005Lignin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D101/00Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
    • C09D101/02Cellulose; Modified cellulose
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2007/00Use of natural rubber as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2401/00Use of cellulose, modified cellulose or cellulose derivatives, e.g. viscose, as filler
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/712Containers; Packaging elements or accessories, Packages
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/143Feedstock the feedstock being recycled material, e.g. plastics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling
    • Y02W30/70

Definitions

  • the field of the present disclosure generally relates to recycling of certain waste. More particularly, the field of the present disclosure relates to recycling of latex paints and other similar materials to be utilized as an ingredient in a packaging and liquid stabilizing material which may be used as an alternative to vermiculite-based packaging materials and may also be used as a stabilizing agent for application to liquid spills.
  • Latex paint is in exceedingly common usage not only by the general public but also by businesses. In recent years there has been a direction of movement from solvent-based paint to the latex type of paint. The main objection to a solvent-based paint is to its emission within the air of a petroleum based substance which when breathed is believed to be damaging to humans and is also potentially explosive. The result has been a substantial increase in the volume of usage of latex paints which similarly increased the waste of latex paint.
  • Packaging materials are widely used industrially and domestically to cushion products ranging from delicate equipment to office supplies so as to prevent damage to the products during shipment and handling. Suitable packaging materials often are composed of an expanded foam providing a low density, flexible packaging that protects a product from damage without adding significantly to the weight of the product when shipped. Although conventional expanded foam materials adequately cushion a product, disposal of the materials is difficult because they may not be biodegradable or recyclable.
  • Expanded vermiculite is a moisture absorbent packaging material which is suitable for packaging glass containers filled with liquid. Vermiculite, however, exhibits fine dust which adheres to glass and plastic. The fine dust can contaminate solvents and damage electronic equipment when the dust remains on the products after being unpackaged. Although a product may be sealed with a packaging film, the fine dust often sticks to the product as it is being removed from the film. Vermiculite is also environmentally harmful because it is not biodegradable and cannot be recycled.
  • Starch based formulations have also been used to prepare biodegradable packaging materials.
  • Starch based peanuts may also be unsuitable for packaging breakable containers because they may dissolve in the presence of liquid which may leak from the containers.
  • Starch based products also tend to become tacky when exposed to conditions of high humidity which may exist upon shipping and handling of a product.
  • Recycled newspaper has been used to form a biodegradable, recyclable packaging material.
  • These materials formed from aqueous slurries of chopped newspapers, are molded into thin hollow walled shells or are extruded as pellets. Although these materials employ waste paper materials, they have several drawbacks.
  • Such packaging materials do not have the cushioning properties and low density provided by expanded foam materials. The materials also require a significant amount of storage space before they are reused or transported for recycling.
  • the latex-based packaging and liquid stabilizing material comprises a portion of a latex-based waste formulated into a recycled latex emulsion, and a portion of particulate material into which the recycled latex emulsion is mixed so as to form a latex-based pulp.
  • additional components such as any of various plasticizers, coloring agents, or hardeners, may be included in the latex-base pulp.
  • the latex-based pulp is dispensed and dried so as to form the latex-based packaging and liquid stabilizing material in a variety of desired shapes.
  • the desired shape of the packaging and liquid stabilizing material comprises latex-based packaging peanuts suitable for separating and cushioning forces between containers during transportation in a larger container.
  • the desired shape may be selected so as to simplify cleanup of the packaging and liquid stabilizing material after having absorbed a liquid spilled from the containers.
  • an apparatus for a latex-based packaging and liquid stabilizing material comprises a portion of a latex-based waste formulated into a recycled latex emulsion; and a portion of particulate material into which the recycled latex emulsion is mixed, thereby forming a pulp which may be dispensed and dried so as to form the latex-based packaging and liquid stabilizing material in a desired shape.
  • the pulp further comprises portions of additional components, such as any of various plasticizers, coloring agents, or hardeners.
  • the desired shape comprises latex-based packaging peanuts suitable for separating and cushioning forces between containers during transportation in a larger container.
  • the latex-based waste is recycled liquid latex paint. In another exemplary embodiment, the latex-based waste comprises recycled semi-liquid latex paint and coatings. In another exemplary embodiment, the particulate material comprises a mixture of cellulose and lignin. In another exemplary embodiment, the particulate material comprises sawdust.
  • a method for preparing a packaging and liquid stabilizing material comprises receiving a portion of latex-based waste; formulating the latex-based waste into a recycled latex emulsion; acquiring a portion of suitable particulate material; mixing and blending the latex-based emulsion with the particulate material so as to form a latex-based pulp; dispensing the latex-based pulp so as to form a desired shape; drying to cure the latex-based pulp into the desired shape; and treating the latex-based shape to limit moisture absorption.
  • the latex-based waste is recycled liquid latex paint. In another exemplary embodiment, the latex-based waste comprises recycled semi-liquid latex paint and coatings. In another exemplary embodiment, the particulate material comprises cellulose and lignin. In another exemplary embodiment, the particulate material comprises sawdust.
  • mixing further comprises including portions of additional components, such as any of various plasticizers, coloring agents, or hardeners.
  • additional components such as any of various plasticizers, coloring agents, or hardeners.
  • the desired shape of the packaging and liquid stabilizing material comprises latex-based packaging peanuts configured to provide a substantially dust-free alternative to vermiculite packaging peanuts.
  • drying comprises allowing the latex-based pulp to dry naturally by way of unaided atmospheric evaporation.
  • mixing further comprises incorporating a drying agent or a solidifier so as to reduce the time required to complete drying of the latex-based pulp.
  • the latex-based pulp is dried by way of conventional drying methods, such as hot air, microwave heating, or radiant infrared heating.
  • regulating a moisture level within the desired shape comprises measuring a moisture level within the desired shape. In another exemplary embodiment, regulating comprises applying additional drying to the desired shape when too much moisture is measured.
  • a packaging and liquid stabilizing material suitable for dispensing and drying into a desired shape comprises a first portion comprising latex; a second portion comprising a particulate material; and a third portion comprising additional components.
  • the first portion comprises latex-based waste formulated into a recycled latex emulsion.
  • the latex-based waste is recycled liquid latex paint.
  • the latex-based waste comprises recycled semi-liquid latex paint and coatings.
  • the particulate material comprises a mixture of cellulose and lignin.
  • the particulate material comprises sawdust.
  • the additional components comprise any of various plasticizers, coloring agents, or hardeners.
  • the desired shape is selected so as to simplify cleanup of the packaging and liquid stabilizing material after having absorbed a liquid.
  • the desired shape comprises latex-based packaging peanuts suitable for separating and cushioning forces between containers during transportation in a larger container.
  • the latex-based packaging peanuts have a size suitable for absorbing liquid which may spill from the containers during transportation in the larger container.
  • a method for preparing a packaging and liquid stabilizing material suitable for dispensing and drying into a desired shape comprises formulating a first portion comprising a recycled latex emulsion; acquiring a second portion comprising a suitable particulate material which includes at least cellulose and lignin; mixing and blending the second portion with the first portion so as to form a latex-based pulp; and including a third portion comprising any of various plasticizers, coloring agents, hardeners, drying agents, or solidifiers.
  • formulating further comprises receiving a portion of latex-based waste.
  • the latex-based waste is recycled liquid latex paint.
  • the latex-based waste comprises recycled semi-liquid latex paint and coatings.
  • the method further comprises regulating a moisture level within the desired shape.
  • regulating comprises measuring a moisture level within the desired shape.
  • regulating comprises applying additional drying to the desired shape when too much moisture is measured.
  • drying further comprises subjecting the desired shape to conventional drying methods, such as hot air, microwave heating, or radiant infrared heating.
  • the method further comprises treating the desired shape to limit future moisture absorption.
  • FIG. 1 illustrates an exemplary embodiment of a preparation process for a vermiculite alternative suitable for use as a packaging and liquid stabilizing material.
  • the present disclosure describes an apparatus and a method for a latex-based packaging and liquid stabilizing material configured to provide a dust-free alternative to vermiculite packaging materials.
  • the latex-based packaging and liquid stabilizing material comprises a portion of a latex-based waste formulated into a recycled latex emulsion, and a portion of particulate material into which the recycled latex emulsion is mixed so as to form a latex-based pulp.
  • the latex-based waste is recycled liquid latex paint, or recycled semi-liquid latex paint and coatings.
  • the particulate material generally comprises a source of cellulose and lignin, such as sawdust.
  • additional components such as any of various plasticizers, coloring agents, or hardeners, may be included in the latex-base pulp.
  • the latex-based pulp is dispensed and dried so as to form the latex-based packaging and liquid stabilizing material in a variety of desired shapes. Drying may be accomplished by way of unaided atmospheric evaporation, or by way of various conventional drying methods. Further, a drying agent or a solidifier may be included so as to reduce the time required to complete drying of the latex-based pulp.
  • the desired shape of the packaging and liquid stabilizing material comprises latex-based packaging peanuts suitable for separating and cushioning forces between containers during transportation in a larger container.
  • FIG. 1 illustrates an exemplary embodiment of a preparation process 100 for a vermiculite alternative suitable for use as a packaging and liquid stabilizing material.
  • the preparation process 100 begins at a latex acquisition step 104 and a particulate material acquisition step 108 .
  • a suitable portion of latex-based waste is acquired for use in the preparation process 100 .
  • the latex-based waste is recycled liquid latex paint.
  • the latex-based waste comprises recycled semi-liquid latex paint and coatings. It will be appreciated that the latex-based waste may be acquired by way of various waste recycling programs.
  • the latex-based waste may be received from any of a variety of institutions, companies, corporations, or other such entities, that perform waste recycling operations. Any of various procedures may be used to formulate the latex-based waste into a recycled latex emulsion suitable for use in the process 100 .
  • a suitable particulate material is acquired for use in the preparation process 100 .
  • the particulate material is of a variety suitable for forming a packaging and liquid stabilizing material useable as an alternative to vermiculite.
  • the particulate material comprises cellulose and lignin, such as is found in sawdust. It has been observed that using sawdust in the preparation process 100 produces a packaging and liquid stabilizing material which exhibits a substantial reduction of fine dust often encountered with vermiculite-based packaging materials, as described herein.
  • a suitable portion of the recycled latex emulsion is mixed with a suitable portion of the particulate material.
  • the mixing step 112 may further comprise including with the recycled latex emulsion and particulate material suitable portions of additional desired components, such as by way of non-limiting example, various plasticizers, coloring agents, or hardeners.
  • additional desired components such as by way of non-limiting example, various plasticizers, coloring agents, or hardeners.
  • the types and quantities of additional components will depend upon desired properties of the end-product of the preparation process 100 .
  • the mixing may be accomplished by way of a typical mixing apparatus, such as a pug mill, or other similar tank-like container within which an auger is mounted.
  • the auger is rotated so as to achieve a desired blending of the particulate material and the recycled latex emulsion within the tank.
  • the recycled latex emulsion operates as an agglomeration agent to bind the particulate material and the additional components, thereby forming a latex-based pulp.
  • the preparation process 100 advances to a dispensing step 116 , wherein the latex-based pulp may be dispensed so as to form a desired shape.
  • the latex-based pulp can be formed into any desired shape, such as by way of non-limiting example, latex-based packaging peanuts which provide an advantageously dust-free alternative to vermiculite packaging peanuts.
  • the latex-based pulp is dispensed by way of industrial extruders.
  • the particular dispensing or extruding machinery will depend upon the desired shape of the end-product of the preparation process 100 .
  • the latex-based pulp may be dispensed by way of food processing extruders which are well known in the art and are commercially available from a wide variety of manufacturers for the production of cheese puff snack foods.
  • the preparation process 100 advances to a drying step 120 wherein the latex-based pulp is dried and cured in the desired shape.
  • a specific method for drying the latex-based pulp, as well as the amount of time required for drying will depend upon the particular shape of the end-product of the process 100 .
  • the latex-based shape is dried naturally by way of unaided atmospheric evaporation.
  • a drying agent or a solidifier 124 may be incorporated into the mixing step 112 so as to reduce the time required to complete the drying step 120 .
  • the latex-based shape may be dried by using conventional drying methods, such as by way of non-limiting example, hot air, microwave heating, or radiant infrared heating.
  • conventional drying methods such as by way of non-limiting example, hot air, microwave heating, or radiant infrared heating.
  • the latex-based shaped may be preliminarily dried by way of microwave heating and then finally dried by way of a hot air furnace.
  • cooling methods may be coupled with the heating methods so as to achieve a desired level of moisture within each cured latex-based shape.
  • Various other methods for drying and curing the latex-based shapes will be apparent to those skilled in the art without detracting from the spirit and scope of the present disclosure.
  • the preparation process 100 advances to a moisture regulation step 128 , wherein a moisture level of the latex-based shape is measured.
  • a moisture level of the latex-based shape is measured.
  • the desired level of moisture within the latex-based shape will depend upon the particular end-product of the preparation process 100 .
  • an additional drying step 132 is applied to the latex-based shape. Similar to the drying step 120 , in the additional drying step 132 the latex-based shape may be dried naturally by way of unaided atmospheric evaporation.
  • the additional drying step 132 may comprise using conventional drying methods, such as hot air, microwave heating, or radiant infrared heating to regulate the moisture within the latex-based shape. Further, a cooling process may be incorporated into the conventional drying methods so as to achieve a desired level of moisture content within the latex-based shape.
  • the preparation process 100 proceeds to an absorption treatment step 136 .
  • the latex-based shape may be exposed to moisture from a variety of sources, such as atmospheric moisture or direct contact with various liquids. An absorption of moisture may have a detrimental effect on the structural integrity of the latex-based shape. For this reason, protecting the finished latex-based shape from future liquid exposure, due either to atmospheric moisture or direct liquid contact, operates advantageously to preserve the structural integrity and longevity of the latex-based shape.
  • the absorption treatment step 136 the latex-based shape is surface treated so as to limit absorption of moisture.
  • the surface treatment may comprise applying a chemical coating to the latex-based shape wherein the chemical coating limits moisture absorption by the latex-based shape.
  • the surface treatment may comprise any of various well known mechanical surface treatments to limit moisture absorption by the latex-based shape. As will be appreciated by those skilled in the art, a wide variety of surface treatments and methods for limiting moisture absorption by the latex-based may be practiced, without limitation, and within the spirit and the scope of the present disclosure.
  • the preparation process 100 finishes at a step 140 wherein the latex-based shape is yielded as an end-product, having the desired shape and properties.
  • the end-product is a resilient and absorbent packaging and liquid stabilizing material.
  • the end-product comprises latex-based packaging peanuts
  • the end-product comprises a resilient, absorbent, and loose packaging material advantageously suited to be used so as to separate and cushion forces between containers during transportation in a larger container.
  • latex-based packaging peanuts are very well suited for filling voids disposed between containers, as well as various other objects, and provide an advantageously dust-free alternative to vermiculite-based packaging peanuts, as mentioned herein. Furthermore, once the latex-based end-product of the present disclosure reaches an end of its useful life, due to physical degradation, the latex-based end-product may be used as a feedstock for any of various well known waste to energy processes, thereby substantially eliminating an environmental impact associated with conventional packaging materials.
  • liquid-filled containers may be shipped, and in many cases the liquids may be comprised of dangerous goods or hazardous materials. Since liquid leaks and spills are very likely to occur during transit, International Air Transport Association (IATA) regulations and International Maritime Dangerous Goods (IMDG) Code require absorbent and cushioning material to be used when transporting liquid hazardous materials.
  • IATA International Air Transport Association
  • IMDG International Maritime Dangerous Goods
  • the latex-based packaging and liquid stabilizing material disclosed herein is particularly well-suited for absorbing liquid spills that may occur while shipping liquids.
  • the latex-based packaging and liquid stabilizing material is configured to form a viscous mixture with a liquid so as to prevent the liquid from seeping or draining away from a spill site.
  • particles of the latex-based packaging and liquid stabilizing material are configured with a shape, size, and a density which, when mixed with a spilled liquid, facilitates being scooped up for safe transfer away from the spill site.
  • the shape, size and density of the particles are such that, once mixed with a liquid, the particles are light enough to be handled, such as during cleaning up, but are heavy enough to resist being carried away by wind.
  • the latex-based packaging and liquid stabilizing material may be implemented with various sizes, shapes, and densities suitable for cushioning a wide variety of containers and other objects, as well as absorbing spilled liquids therefrom, without limitation and without deviating beyond the spirit and the scope of the present disclosure.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Sustainable Development (AREA)
  • Wrappers (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Buffer Packaging (AREA)
  • Paints Or Removers (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

An apparatus and a method are provided for a packaging and liquid stabilizing material suitable for dispensing and drying into a desired shape. In some embodiments, the desired shape may be selected so as to simplify cleanup of the packaging and liquid stabilizing material after having absorbed a liquid spilled from containers during transportation in a larger container. A first portion of the packaging and liquid stabilizing material comprises latex-based waste which is formulated into a recycled latex emulsion. The latex-based waste generally comprises recycled liquid latex paint, as well as recycled semi-liquid latex paint and coatings. A second portion comprises a particulate material which includes a mixture of at least cellulose and lignin, such as sawdust. A third portion comprises additional components including any of various plasticizers, coloring agents, hardeners, drying agents, or solidifiers.

Description

    PRIORITY
  • This application is a continuation application and claims the benefit of U.S. patent application Ser. No. 15/857,393, filed Dec. 28, 2017, now U.S. Pat. No. 10,093,832, which is a divisional and claims the benefit of U.S. patent application Ser. No. 14/744,222, filed Jun. 19, 2015, now U.S. Pat. No. 9,856,379, the entirety of said applications are incorporated herein by reference.
  • FIELD
  • The field of the present disclosure generally relates to recycling of certain waste. More particularly, the field of the present disclosure relates to recycling of latex paints and other similar materials to be utilized as an ingredient in a packaging and liquid stabilizing material which may be used as an alternative to vermiculite-based packaging materials and may also be used as a stabilizing agent for application to liquid spills.
  • BACKGROUND
  • Latex paint is in exceedingly common usage not only by the general public but also by businesses. In recent years there has been a direction of movement from solvent-based paint to the latex type of paint. The main objection to a solvent-based paint is to its emission within the air of a petroleum based substance which when breathed is believed to be damaging to humans and is also potentially explosive. The result has been a substantial increase in the volume of usage of latex paints which similarly increased the waste of latex paint.
  • Whenever a decision is made to paint a given structure, invariably there will be provided an amount in excess of that which is actually needed. This excess becomes waste which usually is discarded. Disposal of latex paint within landfills has been increasingly objected to, which has resulted in increasingly restrictive state, local, and federal regulations, requiring that latex paint waste is to be handled as hazardous waste. As will be appreciated, since disposing of hazardous waste is extremely expensive, it is desirable and advantageous to instead use the hazardous waste in a process which produces other useful materials, thereby eliminating a need for disposing of the hazardous waste.
  • Packaging materials are widely used industrially and domestically to cushion products ranging from delicate equipment to office supplies so as to prevent damage to the products during shipment and handling. Suitable packaging materials often are composed of an expanded foam providing a low density, flexible packaging that protects a product from damage without adding significantly to the weight of the product when shipped. Although conventional expanded foam materials adequately cushion a product, disposal of the materials is difficult because they may not be biodegradable or recyclable.
  • Several problems are associated with conventional packaging materials, such as expanded polystyrene peanuts. Safety problems arise during manufacture because the peanuts are formed from styrene monomer which is hazardous to workers if inhaled or ingested. The packaging peanuts also accumulate static charges that cause them to stick to a product when the peanuts are closely packed around the product within a shipping carton. Another disadvantage associated with the polystyrene peanuts arises when the packaged product is a breakable container filled with a solvent, solution, or other liquid. If the container breaks during shipment, or is not sealed properly, the liquid will leak throughout the shipping carton. Polystyrene peanuts do not absorb the liquid to minimize such leakage, and often shrink considerably when exposed to liquid, losing their cushioning effect. Furthermore, the nonbiodegradable peanuts are often discarded after use, adding to existing landfill waste disposal problems.
  • Expanded vermiculite is a moisture absorbent packaging material which is suitable for packaging glass containers filled with liquid. Vermiculite, however, exhibits fine dust which adheres to glass and plastic. The fine dust can contaminate solvents and damage electronic equipment when the dust remains on the products after being unpackaged. Although a product may be sealed with a packaging film, the fine dust often sticks to the product as it is being removed from the film. Vermiculite is also environmentally harmful because it is not biodegradable and cannot be recycled.
  • Starch based formulations have also been used to prepare biodegradable packaging materials. Starch based peanuts, however, may also be unsuitable for packaging breakable containers because they may dissolve in the presence of liquid which may leak from the containers. Starch based products also tend to become tacky when exposed to conditions of high humidity which may exist upon shipping and handling of a product.
  • Recycled newspaper has been used to form a biodegradable, recyclable packaging material. These materials, formed from aqueous slurries of chopped newspapers, are molded into thin hollow walled shells or are extruded as pellets. Although these materials employ waste paper materials, they have several drawbacks. Such packaging materials do not have the cushioning properties and low density provided by expanded foam materials. The materials also require a significant amount of storage space before they are reused or transported for recycling.
  • What is needed, therefore, is a packaging material which overcomes the disadvantages associated with conventional packaging materials while also reducing the need for disposing of latex-based hazardous waste. The present disclosure provides such an improved packaging material.
  • SUMMARY
  • An apparatus and a method are provided for a latex-based packaging and liquid stabilizing material configured to provide a dust-free alternative to vermiculite packaging materials. The latex-based packaging and liquid stabilizing material comprises a portion of a latex-based waste formulated into a recycled latex emulsion, and a portion of particulate material into which the recycled latex emulsion is mixed so as to form a latex-based pulp. In some embodiments, additional components, such as any of various plasticizers, coloring agents, or hardeners, may be included in the latex-base pulp. The latex-based pulp is dispensed and dried so as to form the latex-based packaging and liquid stabilizing material in a variety of desired shapes. Drying may be accomplished by way of unaided atmospheric evaporation, or by way of various conventional drying methods. In some embodiments, the desired shape of the packaging and liquid stabilizing material comprises latex-based packaging peanuts suitable for separating and cushioning forces between containers during transportation in a larger container. In some embodiments, the desired shape may be selected so as to simplify cleanup of the packaging and liquid stabilizing material after having absorbed a liquid spilled from the containers.
  • In an exemplary embodiment, an apparatus for a latex-based packaging and liquid stabilizing material comprises a portion of a latex-based waste formulated into a recycled latex emulsion; and a portion of particulate material into which the recycled latex emulsion is mixed, thereby forming a pulp which may be dispensed and dried so as to form the latex-based packaging and liquid stabilizing material in a desired shape.
  • In another exemplary embodiment, the pulp further comprises portions of additional components, such as any of various plasticizers, coloring agents, or hardeners. In another exemplary embodiment, the desired shape comprises latex-based packaging peanuts suitable for separating and cushioning forces between containers during transportation in a larger container.
  • In another exemplary embodiment, the latex-based waste is recycled liquid latex paint. In another exemplary embodiment, the latex-based waste comprises recycled semi-liquid latex paint and coatings. In another exemplary embodiment, the particulate material comprises a mixture of cellulose and lignin. In another exemplary embodiment, the particulate material comprises sawdust.
  • In an exemplary embodiment, a method for preparing a packaging and liquid stabilizing material comprises receiving a portion of latex-based waste; formulating the latex-based waste into a recycled latex emulsion; acquiring a portion of suitable particulate material; mixing and blending the latex-based emulsion with the particulate material so as to form a latex-based pulp; dispensing the latex-based pulp so as to form a desired shape; drying to cure the latex-based pulp into the desired shape; and treating the latex-based shape to limit moisture absorption.
  • In another exemplary embodiment, the latex-based waste is recycled liquid latex paint. In another exemplary embodiment, the latex-based waste comprises recycled semi-liquid latex paint and coatings. In another exemplary embodiment, the particulate material comprises cellulose and lignin. In another exemplary embodiment, the particulate material comprises sawdust.
  • In another exemplary embodiment, mixing further comprises including portions of additional components, such as any of various plasticizers, coloring agents, or hardeners. In another exemplary embodiment, the desired shape of the packaging and liquid stabilizing material comprises latex-based packaging peanuts configured to provide a substantially dust-free alternative to vermiculite packaging peanuts.
  • In another exemplary embodiment, drying comprises allowing the latex-based pulp to dry naturally by way of unaided atmospheric evaporation. In another exemplary embodiment, mixing further comprises incorporating a drying agent or a solidifier so as to reduce the time required to complete drying of the latex-based pulp. In another exemplary embodiment, the latex-based pulp is dried by way of conventional drying methods, such as hot air, microwave heating, or radiant infrared heating.
  • In another exemplary embodiment, regulating a moisture level within the desired shape. In another exemplary embodiment, regulating comprises measuring a moisture level within the desired shape. In another exemplary embodiment, regulating comprises applying additional drying to the desired shape when too much moisture is measured.
  • In an exemplary embodiment, a packaging and liquid stabilizing material suitable for dispensing and drying into a desired shape comprises a first portion comprising latex; a second portion comprising a particulate material; and a third portion comprising additional components. In another exemplary embodiment, the first portion comprises latex-based waste formulated into a recycled latex emulsion. In another exemplary embodiment, the latex-based waste is recycled liquid latex paint. In another exemplary embodiment, the latex-based waste comprises recycled semi-liquid latex paint and coatings. In another exemplary embodiment, the particulate material comprises a mixture of cellulose and lignin. In another exemplary embodiment, the particulate material comprises sawdust. In another exemplary embodiment, the additional components comprise any of various plasticizers, coloring agents, or hardeners.
  • In another exemplary embodiment, the desired shape is selected so as to simplify cleanup of the packaging and liquid stabilizing material after having absorbed a liquid. In another exemplary embodiment, the desired shape comprises latex-based packaging peanuts suitable for separating and cushioning forces between containers during transportation in a larger container. In another exemplary embodiment, the latex-based packaging peanuts have a size suitable for absorbing liquid which may spill from the containers during transportation in the larger container.
  • In an exemplary embodiment, a method for preparing a packaging and liquid stabilizing material suitable for dispensing and drying into a desired shape comprises formulating a first portion comprising a recycled latex emulsion; acquiring a second portion comprising a suitable particulate material which includes at least cellulose and lignin; mixing and blending the second portion with the first portion so as to form a latex-based pulp; and including a third portion comprising any of various plasticizers, coloring agents, hardeners, drying agents, or solidifiers.
  • In another exemplary embodiment, formulating further comprises receiving a portion of latex-based waste. In another exemplary embodiment, the latex-based waste is recycled liquid latex paint. In another exemplary embodiment, the latex-based waste comprises recycled semi-liquid latex paint and coatings.
  • In another exemplary embodiment, the method further comprises regulating a moisture level within the desired shape. In another exemplary embodiment, regulating comprises measuring a moisture level within the desired shape. In another exemplary embodiment, regulating comprises applying additional drying to the desired shape when too much moisture is measured. In another exemplary embodiment, drying further comprises subjecting the desired shape to conventional drying methods, such as hot air, microwave heating, or radiant infrared heating. In another exemplary embodiment, the method further comprises treating the desired shape to limit future moisture absorption.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The drawings refer to embodiments of the present disclosure in which:
  • FIG. 1 illustrates an exemplary embodiment of a preparation process for a vermiculite alternative suitable for use as a packaging and liquid stabilizing material.
  • While the present disclosure is subject to various modifications and alternative forms, specific embodiments thereof have been shown by way of example in the drawings and will herein be described in detail. The invention should be understood to not be limited to the particular forms disclosed, but on the contrary, the intention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the present disclosure.
  • DETAILED DESCRIPTION
  • In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present disclosure. It will be apparent, however, to one of ordinary skill in the art that the invention disclosed herein may be practiced without these specific details. In other instances, specific numeric references such as “first material,” may be made. However, the specific numeric reference should not be interpreted as a literal sequential order but rather interpreted that the “first material” is different than a “second material.” Thus, the specific details set forth are merely exemplary. The specific details may be varied from and still be contemplated to be within the spirit and scope of the present disclosure. The terms “coupled” is defined as meaning connected either directly to the component or indirectly to the component through another component. Further, as used herein, the terms “about,” “approximately,” or “substantially” for any numerical values or ranges indicate a suitable dimensional tolerance that allows the part or collection of components to function for its intended purpose as described herein.
  • In general, the present disclosure describes an apparatus and a method for a latex-based packaging and liquid stabilizing material configured to provide a dust-free alternative to vermiculite packaging materials. The latex-based packaging and liquid stabilizing material comprises a portion of a latex-based waste formulated into a recycled latex emulsion, and a portion of particulate material into which the recycled latex emulsion is mixed so as to form a latex-based pulp. The latex-based waste is recycled liquid latex paint, or recycled semi-liquid latex paint and coatings. The particulate material generally comprises a source of cellulose and lignin, such as sawdust. In some embodiments, additional components, such as any of various plasticizers, coloring agents, or hardeners, may be included in the latex-base pulp. The latex-based pulp is dispensed and dried so as to form the latex-based packaging and liquid stabilizing material in a variety of desired shapes. Drying may be accomplished by way of unaided atmospheric evaporation, or by way of various conventional drying methods. Further, a drying agent or a solidifier may be included so as to reduce the time required to complete drying of the latex-based pulp. In some embodiments, the desired shape of the packaging and liquid stabilizing material comprises latex-based packaging peanuts suitable for separating and cushioning forces between containers during transportation in a larger container.
  • FIG. 1 illustrates an exemplary embodiment of a preparation process 100 for a vermiculite alternative suitable for use as a packaging and liquid stabilizing material. The preparation process 100 begins at a latex acquisition step 104 and a particulate material acquisition step 108. In the latex acquisition step 104, a suitable portion of latex-based waste is acquired for use in the preparation process 100. In some embodiments, the latex-based waste is recycled liquid latex paint. In some embodiments, the latex-based waste comprises recycled semi-liquid latex paint and coatings. It will be appreciated that the latex-based waste may be acquired by way of various waste recycling programs. In some embodiments, the latex-based waste may be received from any of a variety of institutions, companies, corporations, or other such entities, that perform waste recycling operations. Any of various procedures may be used to formulate the latex-based waste into a recycled latex emulsion suitable for use in the process 100.
  • In the particulate material acquisition step 108, a suitable particulate material is acquired for use in the preparation process 100. Preferably, the particulate material is of a variety suitable for forming a packaging and liquid stabilizing material useable as an alternative to vermiculite. In some embodiments, the particulate material comprises cellulose and lignin, such as is found in sawdust. It has been observed that using sawdust in the preparation process 100 produces a packaging and liquid stabilizing material which exhibits a substantial reduction of fine dust often encountered with vermiculite-based packaging materials, as described herein.
  • At a mixing step 112, a suitable portion of the recycled latex emulsion is mixed with a suitable portion of the particulate material. In some embodiments, the mixing step 112 may further comprise including with the recycled latex emulsion and particulate material suitable portions of additional desired components, such as by way of non-limiting example, various plasticizers, coloring agents, or hardeners. As will be appreciated, the types and quantities of additional components will depend upon desired properties of the end-product of the preparation process 100. In some embodiments, the mixing may be accomplished by way of a typical mixing apparatus, such as a pug mill, or other similar tank-like container within which an auger is mounted. In some embodiments, the auger is rotated so as to achieve a desired blending of the particulate material and the recycled latex emulsion within the tank. It will be appreciated that the recycled latex emulsion operates as an agglomeration agent to bind the particulate material and the additional components, thereby forming a latex-based pulp.
  • Once the mixing step 112 is complete, the preparation process 100 advances to a dispensing step 116, wherein the latex-based pulp may be dispensed so as to form a desired shape. It should be understood that the latex-based pulp can be formed into any desired shape, such as by way of non-limiting example, latex-based packaging peanuts which provide an advantageously dust-free alternative to vermiculite packaging peanuts. In some embodiments, the latex-based pulp is dispensed by way of industrial extruders. As will be appreciated, the particular dispensing or extruding machinery will depend upon the desired shape of the end-product of the preparation process 100. In some embodiments, the latex-based pulp may be dispensed by way of food processing extruders which are well known in the art and are commercially available from a wide variety of manufacturers for the production of cheese puff snack foods.
  • After having been dispensed and formed into desired latex-based shapes, the preparation process 100 advances to a drying step 120 wherein the latex-based pulp is dried and cured in the desired shape. It will be appreciated that a specific method for drying the latex-based pulp, as well as the amount of time required for drying, will depend upon the particular shape of the end-product of the process 100. In some embodiments, the latex-based shape is dried naturally by way of unaided atmospheric evaporation. In some embodiments, a drying agent or a solidifier 124 may be incorporated into the mixing step 112 so as to reduce the time required to complete the drying step 120. Further, in some embodiments the latex-based shape may be dried by using conventional drying methods, such as by way of non-limiting example, hot air, microwave heating, or radiant infrared heating. For instance, in some embodiments the latex-based shaped may be preliminarily dried by way of microwave heating and then finally dried by way of a hot air furnace. In some embodiments, cooling methods may be coupled with the heating methods so as to achieve a desired level of moisture within each cured latex-based shape. Various other methods for drying and curing the latex-based shapes will be apparent to those skilled in the art without detracting from the spirit and scope of the present disclosure.
  • Once the drying of the latex-based shape is complete, the preparation process 100 advances to a moisture regulation step 128, wherein a moisture level of the latex-based shape is measured. As will be appreciated, the desired level of moisture within the latex-based shape will depend upon the particular end-product of the preparation process 100. When the latex-based shape is found to contain too much moisture, an additional drying step 132 is applied to the latex-based shape. Similar to the drying step 120, in the additional drying step 132 the latex-based shape may be dried naturally by way of unaided atmospheric evaporation. In some embodiments, the additional drying step 132 may comprise using conventional drying methods, such as hot air, microwave heating, or radiant infrared heating to regulate the moisture within the latex-based shape. Further, a cooling process may be incorporated into the conventional drying methods so as to achieve a desired level of moisture content within the latex-based shape.
  • Once the desired level of moisture content has been achieved, the preparation process 100 proceeds to an absorption treatment step 136. As will be appreciated, once finished, the latex-based shape may be exposed to moisture from a variety of sources, such as atmospheric moisture or direct contact with various liquids. An absorption of moisture may have a detrimental effect on the structural integrity of the latex-based shape. For this reason, protecting the finished latex-based shape from future liquid exposure, due either to atmospheric moisture or direct liquid contact, operates advantageously to preserve the structural integrity and longevity of the latex-based shape. In the absorption treatment step 136, the latex-based shape is surface treated so as to limit absorption of moisture. In some embodiments, the surface treatment may comprise applying a chemical coating to the latex-based shape wherein the chemical coating limits moisture absorption by the latex-based shape. In some embodiments, the surface treatment may comprise any of various well known mechanical surface treatments to limit moisture absorption by the latex-based shape. As will be appreciated by those skilled in the art, a wide variety of surface treatments and methods for limiting moisture absorption by the latex-based may be practiced, without limitation, and within the spirit and the scope of the present disclosure.
  • Once the desired level of moisture content has been achieved, and the latex-based shape has been treated to limit future moisture absorption, the preparation process 100 finishes at a step 140 wherein the latex-based shape is yielded as an end-product, having the desired shape and properties. Preferably, the end-product is a resilient and absorbent packaging and liquid stabilizing material. In a preferred embodiment, wherein the end-product comprises latex-based packaging peanuts, the end-product comprises a resilient, absorbent, and loose packaging material advantageously suited to be used so as to separate and cushion forces between containers during transportation in a larger container. As will be appreciated, latex-based packaging peanuts are very well suited for filling voids disposed between containers, as well as various other objects, and provide an advantageously dust-free alternative to vermiculite-based packaging peanuts, as mentioned herein. Furthermore, once the latex-based end-product of the present disclosure reaches an end of its useful life, due to physical degradation, the latex-based end-product may be used as a feedstock for any of various well known waste to energy processes, thereby substantially eliminating an environmental impact associated with conventional packaging materials.
  • As will be appreciated, in many instances liquid-filled containers may be shipped, and in many cases the liquids may be comprised of dangerous goods or hazardous materials. Since liquid leaks and spills are very likely to occur during transit, International Air Transport Association (IATA) regulations and International Maritime Dangerous Goods (IMDG) Code require absorbent and cushioning material to be used when transporting liquid hazardous materials. In addition to being well suited for filling voids between containers, the latex-based packaging and liquid stabilizing material disclosed herein is particularly well-suited for absorbing liquid spills that may occur while shipping liquids. Generally, the latex-based packaging and liquid stabilizing material is configured to form a viscous mixture with a liquid so as to prevent the liquid from seeping or draining away from a spill site. In some embodiments, particles of the latex-based packaging and liquid stabilizing material are configured with a shape, size, and a density which, when mixed with a spilled liquid, facilitates being scooped up for safe transfer away from the spill site. Preferably, the shape, size and density of the particles are such that, once mixed with a liquid, the particles are light enough to be handled, such as during cleaning up, but are heavy enough to resist being carried away by wind. As will be appreciated by those skilled in the art, the latex-based packaging and liquid stabilizing material may be implemented with various sizes, shapes, and densities suitable for cushioning a wide variety of containers and other objects, as well as absorbing spilled liquids therefrom, without limitation and without deviating beyond the spirit and the scope of the present disclosure.
  • While the invention has been described in terms of particular variations and illustrative FIGURES, those of ordinary skill in the art will recognize that the invention is not limited to the variations or FIGURES described. In addition, where methods and steps described above indicate certain events occurring in certain order, those of ordinary skill in the art will recognize that the ordering of certain steps may be modified and that such modifications are in accordance with the variations of the invention. Additionally, certain of the steps may be performed concurrently in a parallel process when possible, as well as performed sequentially as described above. To the extent there are variations of the invention, which are within the spirit of the disclosure or equivalent to the inventions found in the claims, it is the intent that this patent will cover those variations as well. Therefore, the present disclosure is to be understood as not limited by the specific embodiments described herein, but only by scope of the appended claims.

Claims (19)

What is claimed is:
1. A packaging and liquid stabilizing material suitable for dispensing and drying into a desired shape, comprising:
a first portion comprising latex;
a second portion comprising a particulate material; and
a third portion comprising additional components.
2. The material of claim 1, wherein the first portion comprises latex-based waste formulated into a recycled latex emulsion.
3. The material of claim 2, wherein the latex-based waste is recycled liquid latex paint.
4. The material of claim 3, wherein the latex-based waste comprises recycled semi-liquid latex paint and coatings.
5. The material of claim 1, wherein the particulate material comprises a mixture of cellulose and lignin.
6. The material of claim 5, wherein the particulate material comprises sawdust.
7. The material of claim 1, wherein the additional components comprise any of various plasticizers, coloring agents, or hardeners.
8. The material of claim 1, wherein the desired shape is selected so as to simplify cleanup of the packaging and liquid stabilizing material after having absorbed a liquid.
9. The material of claim 1, wherein the desired shape comprises latex-based packaging peanuts suitable for separating and cushioning forces between containers during transportation in a larger container.
10. The material of claim 9, wherein the latex-based packaging peanuts have a size suitable for absorbing liquid which may spill from the containers during transportation in the larger container.
11. A method for preparing a packaging and liquid stabilizing material suitable for dispensing and drying into a desired shape, comprising:
formulating a first portion comprising a recycled latex emulsion;
acquiring a second portion comprising a suitable particulate material which includes at least cellulose and lignin;
mixing and blending the second portion with the first portion so as to form a latex-based pulp; and
including a third portion comprising any of various plasticizers, coloring agents, hardeners, drying agents, or solidifiers.
12. The method of claim 11, wherein formulating further comprises receiving a portion of latex-based waste.
13. The method of claim 12, wherein the latex-based waste is recycled liquid latex paint.
14. The method of claim 12, wherein the latex-based waste comprises recycled semi-liquid latex paint and coatings.
15. The method of claim 11, further comprising regulating a moisture level within the desired shape.
16. The method of claim 15, wherein regulating comprises measuring a moisture level within the desired shape.
17. The method of claim 16, wherein regulating comprises applying additional drying to the desired shape when too much moisture is measured.
18. The method of claim 15, wherein drying further comprises subjecting the desired shape to conventional drying methods, such as hot air, microwave heating, or radiant infrared heating.
19. The method of claim 11, further comprising treating the desired shape to limit future moisture absorption.
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Citations (3)

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Publication number Priority date Publication date Assignee Title
US5244729A (en) * 1991-02-04 1993-09-14 Imperial Chemical Industries Plc Polymeric film comprising a coating layer of vermiculite platelets
US20090275687A1 (en) * 2008-03-06 2009-11-05 Dan Chrzanowski Process of recycling paint sludge and component made thereof
US20110210164A1 (en) * 2009-05-05 2011-09-01 Vladislav Babinsky Packaging Materials With Enhanced Thermal-Insulating Performance

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5244729A (en) * 1991-02-04 1993-09-14 Imperial Chemical Industries Plc Polymeric film comprising a coating layer of vermiculite platelets
US20090275687A1 (en) * 2008-03-06 2009-11-05 Dan Chrzanowski Process of recycling paint sludge and component made thereof
US20110210164A1 (en) * 2009-05-05 2011-09-01 Vladislav Babinsky Packaging Materials With Enhanced Thermal-Insulating Performance

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